US20070011943A1 - Method for manufacturing biodiesel - Google Patents

Method for manufacturing biodiesel Download PDF

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Publication number
US20070011943A1
US20070011943A1 US11/184,652 US18465205A US2007011943A1 US 20070011943 A1 US20070011943 A1 US 20070011943A1 US 18465205 A US18465205 A US 18465205A US 2007011943 A1 US2007011943 A1 US 2007011943A1
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Prior art keywords
oil
biodiesel
petrifaction
manufacturing
catalysts
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Abandoned
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US11/184,652
Inventor
Chung-Jeng Lin
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Individual
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Individual
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Priority to US11/184,652 priority Critical patent/US20070011943A1/en
Publication of US20070011943A1 publication Critical patent/US20070011943A1/en
Abandoned legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/026Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/19Esters ester radical containing compounds; ester ethers; carbonic acid esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1011Biomass
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04Diesel oil
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/20Technologies relating to oil refining and petrochemical industry using bio-feedstock

Definitions

  • the present invention relates to biodiesels, and particularly to a method for manufacturing biodiesel, which is acquired by getting an amount of oil selected from one of planted oil and animal oil; and then adding catalysts to the oil.
  • the time period for manufacturing the biodiesel is short and cost is low without environment pollution. Thereby it is advantageous than the petrifaction fuel.
  • biodiesel now become a popular material for replacing the prior fuel.
  • the biodiesel is also called as fatty acid ester.
  • the biodiesel is poisonless, decompositable biologically, low sulfur, capable of being reused, without aryl, etc. Thereby it partially replaces the petrifaction material.
  • the molecule of diesel has about 15 carbon chains, while the biodiesel has about 14 to 18 carbon chains. This number is approximately equal to that of the diesel.
  • the biodiesel is a high fatty acid methane which is acquired by decomposing the glyceride with non-saturated C18. Many plants are suitable to be as the material for manufacturing biodiesel. Thereby the biodiesel can reduce the wear of engine with very little sulfur gas. It is low environmental polluted and suitable for the requirement of environmental protection.
  • the biodiesel contains very low sulfur and thus exhaust of sulfur dioxide and sulfide are lower than the petrifaction about 30%. If catalyst is used, the value is increased to 70%.
  • the biodiesel has no aryl hydrocarbon. The harm of the biodiesel to the human body is lower than the diesel. Comparing with the diesel, the biodiesel can lower the toxicity to be only 10% of the original diesel and harmfulness is reduced to 6% of the original diesel. Comparing with diesel, only 10% of carbon oxide is exhausted (under 95% of catalyst). Furthermore, the engine can be actuated at a lower temperature with a cool filtering point of ⁇ 20° C. without any additive.
  • the biodiesel is a security oil and thus it is preferred in transformation, storage and use.
  • the biodiesel has sufficient sixteenth alkane. It has preferred properties in combustion. The residue after combustion is slight acidic so as to prolong the lifetime of activity and engine oil. Besides the biodiesel can be reused and is not exhausted. Further, the biodiesel is preferred under consideration of cool filtering point, sparkling, combustion, sulfur containing, oxygen containing, oxygen consumption in combustion, harmfulness to water sources as comparing with the petrifaction.
  • the primary object of the present invention is to provide a method for manufacturing biodiesel, which is acquired by getting an amount of oil selected from one of planted oil and animal oil; and then added catalysts to the oil.
  • the time period for manufacturing the biodiesel is short and cost is low without environment pollution. Thereby it is advantageous than the petrifaction fuel.
  • a method for manufacturing biodiesel comprises the steps of: a) getting an amount of biological oil; b) adding catalysts to the oil; and c) getting the biodiesel.
  • the biological oil is from plants.
  • the volume ratio of the catalysts is between 30% to 70% and the other is the oil.
  • the biological oil is replaced by methyl ester.
  • Or the biological oil is animal oil.
  • the catalyst is alkane or alcohol.
  • the process of the present invention comprises the steps of: a) getting an amount of oil which is selected from one of planted oil and animal oil; b) adding catalysts to the oil; and C) getting the biodiesel.
  • the volume ratio of the catalysts is between 30% to 70% and the other is the oil.
  • the volume ratio of the catalysts is between 30% to 70% and the other is methyl ester.
  • the ratio of the catalyst is equal to the oil.
  • the catalyst is preferably alkane or alcohol.
  • the process can be proceeded quickly and simply. Only several minutes are needed to get the biodiesel, while the conventional petrifaction material needs at least two hours for the reaction. Furthermore, the cost is low.
  • the cost of the present invention is about USD$290/kl, while the conventional petrifaction material needs USD$600 ⁇ 900/kl.
  • the cost for the equipment in the production according to the present invention is about USD$79liquid 2, while the conventional petrifaction material needs about USD$1000-2500/1.
  • the biodiesel of the present invention can achieve the complete combustion of the fuel in the engine.

Abstract

A method for manufacturing biodiesel comprises the steps of: a) getting an amount of biological oil; b) adding catalysts to the oil; and c) getting the biodiesel. The biological oil is from plants. The volume ratio of the catalysts is between 30% to 70% and the other is the oil. The biological oil is replaced by methyl ester. Or the biological oil is animal oil. The catalyst is alkane or alcohol. Time period for manufacturing the biodiesel is short and cost is low without environment pollution. Thereby it is advantageous than the petrifaction fuel.

Description

    FIELD OF THE INVENTION
  • The present invention relates to biodiesels, and particularly to a method for manufacturing biodiesel, which is acquired by getting an amount of oil selected from one of planted oil and animal oil; and then adding catalysts to the oil. The time period for manufacturing the biodiesel is short and cost is low without environment pollution. Thereby it is advantageous than the petrifaction fuel.
  • BACKGROUND OF THE INVENTION
  • In the past, the coals and petrifaction material are main source of fuel. However currently, it is known that these power sources will exhaust in the near future. In some estimation, the reverse of petrifaction material only supports 30 to 40 years for human use and the coal is about 100 years. It is know that the coal and petrifaction materials have serious problems about environmental pollution.
  • Currently, the thickness of the carbon dioxide in atmosphere is about 3.75/10000. In 19 century, the data is 2.75/10000. Most of the reason is induced from the use of petrifaction material. If now human stops to use these material, it is estimated that about 1000 years are needed to make the atmosphere return to the value in 19 century. The Kyoto protocol to the United Nation Framework convention on climate change concluded in 2003 requests all the nations to reduce the use of petrifaction material to only 70% of the original usage. Thereby there is an eager demand for a novel invention which can replace the petrifaction material.
  • In the manufacture process of the current petrifaction material, a great number of steps are necessary, such as adding catalysts, decomposition, combining, separation, withdrawing grease and water, reuse of methyl alcohol, testing, filtering, etc. The time period is at least 12 hours and a great cost is needed.
  • Because above mentioned defects in the petrifaction material, biodiesel now become a popular material for replacing the prior fuel. The biodiesel is also called as fatty acid ester. In that the plant oil from plant fruits, seeds, plant conduits, or some wasted foods are used as original material and then the original material is reacted with catalysts. The biodiesel is poisonless, decompositable biologically, low sulfur, capable of being reused, without aryl, etc. Thereby it partially replaces the petrifaction material.
  • The molecule of diesel has about 15 carbon chains, while the biodiesel has about 14 to 18 carbon chains. This number is approximately equal to that of the diesel. The biodiesel is a high fatty acid methane which is acquired by decomposing the glyceride with non-saturated C18. Many plants are suitable to be as the material for manufacturing biodiesel. Thereby the biodiesel can reduce the wear of engine with very little sulfur gas. It is low environmental polluted and suitable for the requirement of environmental protection.
  • The advantages of the biodiesel will be described herein.
  • The biodiesel contains very low sulfur and thus exhaust of sulfur dioxide and sulfide are lower than the petrifaction about 30%. If catalyst is used, the value is increased to 70%. The biodiesel has no aryl hydrocarbon. The harm of the biodiesel to the human body is lower than the diesel. Comparing with the diesel, the biodiesel can lower the toxicity to be only 10% of the original diesel and harmfulness is reduced to 6% of the original diesel. Comparing with diesel, only 10% of carbon oxide is exhausted (under 95% of catalyst). Furthermore, the engine can be actuated at a lower temperature with a cool filtering point of −20° C. without any additive. Furthermore, it is a preferred lubrication so that the wear to the oil ejection pump, cylinder and linkage is low. Moreover, the biodiesel is a security oil and thus it is preferred in transformation, storage and use. The biodiesel has sufficient sixteenth alkane. It has preferred properties in combustion. The residue after combustion is slight acidic so as to prolong the lifetime of activity and engine oil. Besides the biodiesel can be reused and is not exhausted. Further, the biodiesel is preferred under consideration of cool filtering point, sparkling, combustion, sulfur containing, oxygen containing, oxygen consumption in combustion, harmfulness to water sources as comparing with the petrifaction.
  • In 2003, Europe union has requested all the nations to increase the use of biodiesel to 2% at the end of 2005 and to 5.75% at the end of 2010. However there are some problems occurred in the manufacturing of biodiesel, such as high cost and low production due to complication in the manufacturing process. In use, the oil box, oil circuit, and electric devices and engine must be modified. The burning point is not a safe one and sparkle point is not preferred. Great explosion generates vibrations. High sulfur, high deposition and a great amount of water occur.
  • SUMMARY OF THE INVENTION
  • Accordingly, the primary object of the present invention is to provide a method for manufacturing biodiesel, which is acquired by getting an amount of oil selected from one of planted oil and animal oil; and then added catalysts to the oil. The time period for manufacturing the biodiesel is short and cost is low without environment pollution. Thereby it is advantageous than the petrifaction fuel.
  • A method for manufacturing biodiesel comprises the steps of: a) getting an amount of biological oil; b) adding catalysts to the oil; and c) getting the biodiesel. The biological oil is from plants. The volume ratio of the catalysts is between 30% to 70% and the other is the oil. The biological oil is replaced by methyl ester. Or the biological oil is animal oil. The catalyst is alkane or alcohol.
  • DETAILED DESCRIPTION OF THE INVENTION
  • In order that those skilled in the art can further understand the present invention, a description will be described in the following in details. However, these descriptions and the appended drawings are only used to cause those skilled in the art to understand the objects, features, and characteristics of the present invention, but not to be used to confine the scope and spirit of the present invention defined in the appended claims.
  • Referring to FIGS. 1 and 2, the process of the present invention comprises the steps of: a) getting an amount of oil which is selected from one of planted oil and animal oil; b) adding catalysts to the oil; and C) getting the biodiesel.
  • In the present invention, the volume ratio of the catalysts is between 30% to 70% and the other is the oil. Or the volume ratio of the catalysts is between 30% to 70% and the other is methyl ester. Preferably, the ratio of the catalyst is equal to the oil. The catalyst is preferably alkane or alcohol.
  • The advantages of the present invention will be described herein. Firstly, the process can be proceeded quickly and simply. Only several minutes are needed to get the biodiesel, while the conventional petrifaction material needs at least two hours for the reaction. Furthermore, the cost is low. The cost of the present invention is about USD$290/kl, while the conventional petrifaction material needs USD$600˜900/kl. The cost for the equipment in the production according to the present invention is about USD$79liquid 2, while the conventional petrifaction material needs about USD$1000-2500/1. Furthermore, the biodiesel of the present invention can achieve the complete combustion of the fuel in the engine.
  • The present invention is thus described, it will be obvious that the same may be varied in many ways. Such variations are not to be regarded as a departure from the spirit and scope of the present invention, and all such modifications as would be obvious to one skilled in the art are intended to be included within the scope of the following claims.

Claims (7)

1. A method for manufacturing biodiesel comprising the steps of:
a) preparing biological oil;
b) added catalysts to the oil; and
c) generating the biodiesel.
2. The method of claim 1, wherein the biological oil is from plants.
2. The method of claim 1, wherein the volume ratio of the catalysts is between 30% to 70% and the other is the oil.
3. The method of claim 1, wherein the biological oil is replaced by methyl ester.
4. The method of claim 1, wherein the biological oil is animal oil.
5. The method of claim 1, wherein the catalyst is alkane.
6. The method of claim 1, wherein the catalyst is alcohol.
US11/184,652 2005-07-15 2005-07-15 Method for manufacturing biodiesel Abandoned US20070011943A1 (en)

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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110230687A1 (en) * 2008-11-26 2011-09-22 Luetkens Jr Melvin L Methods of producing jet fuel from natural oil feedstocks through oxygen-cleaved reactions
US20110237850A1 (en) * 2008-11-26 2011-09-29 Elevance Renewable Sciences, Inc Methods of producing jet fuel from natural oil feedstocks through metathesis reactions
US8735640B2 (en) 2009-10-12 2014-05-27 Elevance Renewable Sciences, Inc. Methods of refining and producing fuel and specialty chemicals from natural oil feedstocks
US8957268B2 (en) 2009-10-12 2015-02-17 Elevance Renewable Sciences, Inc. Methods of refining natural oil feedstocks
US9000246B2 (en) 2009-10-12 2015-04-07 Elevance Renewable Sciences, Inc. Methods of refining and producing dibasic esters and acids from natural oil feedstocks
US9051519B2 (en) 2009-10-12 2015-06-09 Elevance Renewable Sciences, Inc. Diene-selective hydrogenation of metathesis derived olefins and unsaturated esters
US9133416B2 (en) 2011-12-22 2015-09-15 Elevance Renewable Sciences, Inc. Methods for suppressing isomerization of olefin metathesis products
US9139493B2 (en) 2011-12-22 2015-09-22 Elevance Renewable Sciences, Inc. Methods for suppressing isomerization of olefin metathesis products
US9169174B2 (en) 2011-12-22 2015-10-27 Elevance Renewable Sciences, Inc. Methods for suppressing isomerization of olefin metathesis products
US9169447B2 (en) 2009-10-12 2015-10-27 Elevance Renewable Sciences, Inc. Methods of refining natural oils, and methods of producing fuel compositions
US9175231B2 (en) 2009-10-12 2015-11-03 Elevance Renewable Sciences, Inc. Methods of refining natural oils and methods of producing fuel compositions
US9222056B2 (en) 2009-10-12 2015-12-29 Elevance Renewable Sciences, Inc. Methods of refining natural oils, and methods of producing fuel compositions
US9365487B2 (en) 2009-10-12 2016-06-14 Elevance Renewable Sciences, Inc. Methods of refining and producing dibasic esters and acids from natural oil feedstocks
US9382502B2 (en) 2009-10-12 2016-07-05 Elevance Renewable Sciences, Inc. Methods of refining and producing isomerized fatty acid esters and fatty acids from natural oil feedstocks
US9388098B2 (en) 2012-10-09 2016-07-12 Elevance Renewable Sciences, Inc. Methods of making high-weight esters, acids, and derivatives thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4364743A (en) * 1979-09-05 1982-12-21 Erner William E Synthetic liquid fuel and fuel mixtures for oil-burning devices
US5578090A (en) * 1995-06-07 1996-11-26 Bri Biodiesel fuel

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4364743A (en) * 1979-09-05 1982-12-21 Erner William E Synthetic liquid fuel and fuel mixtures for oil-burning devices
US5578090A (en) * 1995-06-07 1996-11-26 Bri Biodiesel fuel

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8933285B2 (en) 2008-11-26 2015-01-13 Elevance Renewable Sciences, Inc. Methods of producing jet fuel from natural oil feedstocks through metathesis reactions
US20110237850A1 (en) * 2008-11-26 2011-09-29 Elevance Renewable Sciences, Inc Methods of producing jet fuel from natural oil feedstocks through metathesis reactions
US20110230687A1 (en) * 2008-11-26 2011-09-22 Luetkens Jr Melvin L Methods of producing jet fuel from natural oil feedstocks through oxygen-cleaved reactions
US8889932B2 (en) 2008-11-26 2014-11-18 Elevance Renewable Sciences, Inc. Methods of producing jet fuel from natural oil feedstocks through oxygen-cleaved reactions
US9365487B2 (en) 2009-10-12 2016-06-14 Elevance Renewable Sciences, Inc. Methods of refining and producing dibasic esters and acids from natural oil feedstocks
US9169447B2 (en) 2009-10-12 2015-10-27 Elevance Renewable Sciences, Inc. Methods of refining natural oils, and methods of producing fuel compositions
US9000246B2 (en) 2009-10-12 2015-04-07 Elevance Renewable Sciences, Inc. Methods of refining and producing dibasic esters and acids from natural oil feedstocks
US9051519B2 (en) 2009-10-12 2015-06-09 Elevance Renewable Sciences, Inc. Diene-selective hydrogenation of metathesis derived olefins and unsaturated esters
US10689582B2 (en) 2009-10-12 2020-06-23 Elevance Renewable Sciences, Inc. Methods of refining natural oil feedstocks
US8957268B2 (en) 2009-10-12 2015-02-17 Elevance Renewable Sciences, Inc. Methods of refining natural oil feedstocks
US9732282B2 (en) 2009-10-12 2017-08-15 Elevance Renewable Sciences, Inc. Methods of refining natural oil feedstocks
US9464258B2 (en) 2009-10-12 2016-10-11 Elevance Renewable Sciences, Inc. Diene-selective hydrogenation of metathesis derived olefins and unsaturated esters
US9175231B2 (en) 2009-10-12 2015-11-03 Elevance Renewable Sciences, Inc. Methods of refining natural oils and methods of producing fuel compositions
US9222056B2 (en) 2009-10-12 2015-12-29 Elevance Renewable Sciences, Inc. Methods of refining natural oils, and methods of producing fuel compositions
US9284512B2 (en) 2009-10-12 2016-03-15 Elevance Renewable Sicences, Inc. Methods of refining and producing dibasic esters and acids from natural oil feedstocks
US8735640B2 (en) 2009-10-12 2014-05-27 Elevance Renewable Sciences, Inc. Methods of refining and producing fuel and specialty chemicals from natural oil feedstocks
US9382502B2 (en) 2009-10-12 2016-07-05 Elevance Renewable Sciences, Inc. Methods of refining and producing isomerized fatty acid esters and fatty acids from natural oil feedstocks
US9469827B2 (en) 2009-10-12 2016-10-18 Elevance Renewable Sciences, Inc. Methods of refining natural oil feedstocks
US9139493B2 (en) 2011-12-22 2015-09-22 Elevance Renewable Sciences, Inc. Methods for suppressing isomerization of olefin metathesis products
US9481627B2 (en) 2011-12-22 2016-11-01 Elevance Renewable Sciences, Inc. Methods for suppressing isomerization of olefin metathesis products
US9169174B2 (en) 2011-12-22 2015-10-27 Elevance Renewable Sciences, Inc. Methods for suppressing isomerization of olefin metathesis products
US9133416B2 (en) 2011-12-22 2015-09-15 Elevance Renewable Sciences, Inc. Methods for suppressing isomerization of olefin metathesis products
US9388098B2 (en) 2012-10-09 2016-07-12 Elevance Renewable Sciences, Inc. Methods of making high-weight esters, acids, and derivatives thereof

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