US20070084549A1 - Method of making a privacy film - Google Patents

Method of making a privacy film Download PDF

Info

Publication number
US20070084549A1
US20070084549A1 US11/580,382 US58038206A US2007084549A1 US 20070084549 A1 US20070084549 A1 US 20070084549A1 US 58038206 A US58038206 A US 58038206A US 2007084549 A1 US2007084549 A1 US 2007084549A1
Authority
US
United States
Prior art keywords
light
polymeric material
channel
channels
light directing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US11/580,382
Inventor
Paul Graham
Graham Clarke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Priority to US11/580,382 priority Critical patent/US20070084549A1/en
Assigned to 3M INNOVATIVE PROPERTIES COMPANY reassignment 3M INNOVATIVE PROPERTIES COMPANY ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: CLARKE, GRAHAM M., GRAHAM, PAUL D.
Publication of US20070084549A1 publication Critical patent/US20070084549A1/en
Abandoned legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/42Moulds or cores; Details thereof or accessories therefor characterised by the shape of the moulding surface, e.g. ribs or grooves
    • B29C33/424Moulding surfaces provided with means for marking or patterning
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/42Moulds or cores; Details thereof or accessories therefor characterised by the shape of the moulding surface, e.g. ribs or grooves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/02Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C59/00Surface shaping of articles, e.g. embossing; Apparatus therefor
    • B29C59/02Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
    • B29C59/022Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing characterised by the disposition or the configuration, e.g. dimensions, of the embossments or the shaping tools therefor
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C59/00Surface shaping of articles, e.g. embossing; Apparatus therefor
    • B29C59/02Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
    • B29C59/022Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing characterised by the disposition or the configuration, e.g. dimensions, of the embossments or the shaping tools therefor
    • B29C2059/023Microembossing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S283/00Printed matter
    • Y10S283/901Concealed data
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S283/00Printed matter
    • Y10S283/902Anti-photocopy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/916Fraud or tamper detecting
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/14Layer or component removable to expose adhesive
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24372Particulate matter
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • Y10T428/2457Parallel ribs and/or grooves
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/25Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles

Definitions

  • the present invention relates to a privacy film.
  • the present invention relates to a polymeric based privacy film having a plurality of light directing elements each element being disposed substantially parallel to the next adjacent light directing element, the film being well suited for use with documents.
  • Products capable of providing privacy for the consumer have increased. For example, it is very common today for most personal computers and automatic teller machines to include a privacy screen allowing the user to view the image on the monitor while simultaneously limiting the view for bystanders, or at least those not in the viewing angle of the screen. Some have used light control films to provide privacy to a user who has documents containing sensitive material. The idea is similar in that the user can view the image on the document but bystanders are limited in viewing the document's content.
  • the present invention provides for a privacy film that can be used with documents to limit the angle at which a viewer can read the information on the document.
  • a privacy film that can be used with documents to limit the angle at which a viewer can read the information on the document.
  • the privacy film is placed in the use orientation such that the viewing angle is coincident with the user's line of sight, the user will be able to see the contents of the documents while others will only have a limited view of the document's content.
  • the present invention pertains to a privacy film comprising a light transmissive, polymeric base sheet comprising (i) a first polymeric material, the base sheet having opposing first and second surfaces; and (ii) a plurality of light directing elements comprising a second polymeric material, wherein each element has a base, a height h, and a minor axis disposed along the height, wherein the elements protrude from the first surface of the base sheet, and wherein each element is disposed such that the minor axis of one element is substantially parallel to the minor axis of the next adjacent element and the base of one element is not joined with the base of the next adjacent element.
  • the privacy film comprises elongated light directing elements.
  • the present invention pertains to a method of making a privacy film comprising the steps of (i) providing a polymeric material; (ii) depositing the polymeric material onto a microstructured mold comprising a plurality of substantially parallel, elongated channels, wherein each channel is slanted and is separated from the next channel by a land region, wherein each channel has a base disposed adjacent to and a tip distal from the land region, wherein each channel has a minor axis that runs from the base to the tip; (iii) inducing the polymeric material to flow into the channels of the microstructured mold; (iv) solidifying the polymeric material inside the channels to yield a plurality of light directing elements that are connected with one another via a polymeric base sheet having a first surface from which the light directing elements protrude and an opposing second substantially planar surface; and (iv) separating the privacy film from the microstructured mold.
  • the term “light transmissive” means the ability to transmit visible light.
  • the light transmissive base sheet has an opacity of 90 or less, as measured using a Lab Scan 6000 Tester with a HuterLab Master Color Data Program, commercially available from Hunter Associates Laboratory, Inc., Reston, Va.
  • the term “elongated” generally means that the element has a rail-like appearance.
  • the rails can be continuous along the entire length of the privacy film or they can be discontinuous.
  • the discontinuous light directing elements are discrete bodies having an appearance of a stem, such as, e.g., a stem of a mushroom.
  • One advantage of the present invention is that it provides the privacy feature with flexible construction that is relatively easy to manufacture.
  • the privacy film can be quickly attached to the document in a non-permanent manner.
  • the privacy film is durable so that it can be used repeatedly.
  • FIG. 1 is a perspective view of one exemplary embodiment of a privacy film
  • FIG. 2 is a cross-sectional view of the privacy film of FIG. 1 taken along line 2 - 2 ;
  • FIG. 3 is a cross-sectional view of another exemplary embodiment of a privacy film showing light directing elements with multiple sections;
  • FIG. 4 is a cross-sectional view of another exemplary embodiment of a privacy film showing the tip portions of the light directing elements being covered with a light absorbing coating;
  • FIG. 5 is a cross-sectional view of another exemplary embodiment of a privacy film showing light directing elements at varying cant angles;
  • FIG. 6 is a cross-section view of another exemplary embodiment of a privacy film showing the tip portions of the light directing elements being elongated in a direction parallel to the base layer;
  • FIG. 7 is a perspective of another exemplary embodiment of a privacy film showing a combination of elongated light directing elements.
  • FIGS. 8 a to 8 c are schematic views of an exemplary process that can be used to make the privacy film.
  • FIG. 1 is a perspective view of one exemplary embodiment of the present invention showing privacy film 10 having elongated light directing elements 18 disposed on substrate 50 that may contain sensitive information.
  • the privacy film can be attached using a light transmissive adhesive (not shown).
  • the elements have a major axis L and a minor axis l.
  • One exemplary substrate is a document bearing confidential information that the document owner wants limited viewing access.
  • the privacy film of the present invention is disposed on the document so that the major axis L lies substantially parallel to the image or lines of text on the document.
  • the privacy film would be oriented so that the major axis also lies along the same direction.
  • the privacy film can be disposed on the document temporarily, meaning that the film can be removed from the substrate without damage thereto, or permanently, meaning that removal of the privacy film will most likely cause damage to the document.
  • an adhesive can be used.
  • the adhesive can be pressure sensitive or hot melt.
  • the adhesive can be a repositionable adhesive, meaning that it can be applied and removed from the substrate multiple times without damage to the substrate and without significant loss in adhesion of the repositionable adhesive.
  • the privacy film is formed as a pocket, where the privacy film forms a front, a polymeric backing or the privacy film forms a back, and the privacy film and the back are attached on three sides, leaving the fourth, typically top side, open for insertion and removal of a document. Other configurations can be used.
  • the light directing elements interfere with light transmission thereby providing the privacy feature of the present inventive film.
  • Optically active materials such as light reflecting and or light absorbing materials, may be included.
  • the light directing elements geometry, spacing, and the optically active materials are discussed below in detail.
  • the heights of the light directing elements are substantially the same on the privacy film. There may be some variation in the elements' heights due to the manufacturing conditions. In another exemplary embodiment, the heights of the elements vary from one region of the privacy film to another region and even from one element to the next adjacent element. By variation in height, it is generally meant that one element will be from 75% to 95% in height of another element.
  • FIG. 3 generally illustrates the embodiment having light reflecting elements with varying heights.
  • FIG. 2 shows a cross-section of the privacy film in FIG. 1 taken along line 2 - 2 .
  • the privacy film includes base sheet 12 having opposing first surface 14 and second surface 16 and demarcation line 13 .
  • Light directing elements 18 protrude from the first surface of the base sheet. While FIG. 2 shows that demarcation line 13 is collinear with first surface 14 , the line can be at a different location.
  • Each light directing element has a height h, a width W, and a center-to-center spacing from one element to the next adjacent element P.
  • the height h is measured along the minor axis l from the first surface 14 of the base sheet to tip 20 .
  • the width W is measured perpendicular to the minor axis.
  • the h to P ratio is greater than 0.5. In another embodiment, the h:P ratio is less than 5.
  • the width of the light directing element, as measured proximate to the first surface of the base sheet is greater than 25 microns. In another embodiment, the width is less than 750 microns.
  • the light directing elements are disposed on the base sheet at a cant angle ⁇ .
  • the cant angle is the angle between first surface 14 and the minor axis of each light directing element. In one embodiment, the cant angle is greater than 15°. In another embodiment, the cant angle is less than 90°. In yet another embodiment, the cant angle ranges from 40° to 85°.
  • the cant angle ranges from 55° to 75°.
  • adhesive 22 is provided on the second surface of the base sheet, for attachment to a substrate.
  • the light directing elements of this particular embodiment are substantially uniform in its cross-sectional dimension, there can be a slight draft (i.e., a slight narrowing) to the elements towards tip 20 .
  • the placement of two adjacent light directing elements is such that the tip of one element, taken along an imaginary line normal to the first surface of the base sheet (shown as dotted line N), lies next to the base (shown as reference letter b) of the next element.
  • the light directing element includes either light absorbing materials or light reflecting materials.
  • Suitable light reflecting materials include, e.g., titanium dioxide, zinc oxide, zinc sulfide, zinc phosphate, calcium carbonate, alumina, silica, antimony oxide, barium sulfate, lithopene (a co-precipitate of barium sulfate and zinc oxide), calcined kaolin, lead carbonate, magnesium oxide, and combinations thereof.
  • Suitable light absorbing materials include, e.g., carbon black, spinel black, rutile black, iron black, and combinations thereof.
  • a light absorbing material 0.1 to 50 parts by weight, based on 100 parts by weight total, is added to the polymer resin to form the light directing elements. In some embodiments 1 to 15 parts by weight of light absorbing material is used. In other embodiments, 1 to 5 parts by weight is used.
  • a combination of light reflecting material and light absorbing material can be used to form an individual light directing element, as further discussed below. In other embodiments, color pigments, fluorescent colors, and glitter can be added to the light directing elements.
  • FIG. 3 shows a cross-sectional view of another embodiment of the invention, where privacy film 100 includes base sheet 112 having opposing first surface 114 and second surface 116 .
  • Light directing elements 118 protrude from the first surface of the base sheet.
  • Demarcation line 113 resides slightly within the light directing element.
  • the light directing element include first portion 119 disposed distal to the first surface of the base sheet, second portion 117 disposed proximate to the first surface, and third portion from the first surface to line 113 .
  • the composition of the base sheet and the third portion will be similar, and may even be the same.
  • Line 115 demarcates the first portion from the second portion.
  • the first portion includes a light absorbing material and the second portion includes a light reflecting material.
  • the height of the first portion is denoted as l 119 , and is the distance along the minor axis of the element between line 115 and the tip.
  • the height of the second portion is denoted as l 117 and is the distance along the minor axis of the element between line 113 and 115 .
  • the ratio of l 119 to l 117 is 3 to 0.1.
  • the placement of two adjacent light directing elements is such that the tip of one element, taken along imaginary line N overlaps with the base of the next adjacent element. While the light directing element of FIG. 2 includes a tip that is has substantially straight edges, the tips can be rounded as shown in FIG. 3 . Other geometry can be used, so long as the light directing elements interfere with light transmission so as to provide the privacy feature.
  • FIG. 4 shows a cross-sectional view of another embodiment of the present invention where privacy film 200 includes base sheet 212 having opposing first surface 214 , second surface 216 , and demarcation line 213 .
  • Light directing elements 218 protrude from the first surface. At the tips of the light directing elements, light absorbing coating 219 has been applied. The coating may migrate down the sides of the light directing elements. In this particular embodiment, the light directing element could include light reflecting materials.
  • the coating can be applied to the elements using known coating techniques. In one embodiment, the coating is 0.01 to 1.0 mm in dry thickness.
  • the light absorbing coating is applied to the tips using digital printing methods, such as inkjet printing, color inkjet printing, laser printing, and dye or mass transfer printing or by conventional printing techniques, such as offset lithography, flexography, and gravure.
  • digital printing methods such as inkjet printing, color inkjet printing, laser printing, and dye or mass transfer printing or by conventional printing techniques, such as offset lithography, flexography, and gravure.
  • the tips of the elements are receptive to the ink or the dyes used in the printing process.
  • FIG. 5 shows a cross-sectional view of another embodiment of the present invention, where privacy film 300 includes base sheet 312 having opposing first surface 314 and second surface 316 .
  • Light directing elements 318 protrude from the first surface of the base sheet.
  • the cant angle of each light directing element differs from the next adjacent element.
  • cant angle ⁇ 1 will be similar to cant angle ⁇ 2 .
  • ⁇ 1 may be 90° while ⁇ 1 may be 88°.
  • these two light directing elements will be substantially parallel to one another.
  • the cant angle for the fifth light directing element, ⁇ 5 may be very different than that of the first light directing element. In this figure, if ⁇ 1 is 90°, ⁇ 5 may be 60°, so that the first light directing element will not be considered to be parallel to the fifth light directing element.
  • the magnitude of the varying change in cant angles has been exaggerated in this figure to illustrate the varying cant angles.
  • FIG. 6 shows a cross-sectional view of yet another embodiment of the present invention, where privacy film 400 includes base sheet 412 having opposing first surface 414 , second surface 416 and demarcation line 413 .
  • Light directing elements 418 protrude from the first surface. Each light directing element has first portion 419 distal to the first surface of the base sheet and second portion 417 proximate to the first surface.
  • Line 415 demarcates the first portion from the second portion.
  • Line 413 demarcates the second portion from a third portion.
  • the first portion has one-sided extension, similar to an upside down “L”.
  • the extensions can all be on the same side, e.g., all left facing or all right facing (as shown in the figure), or they can alternate between left facing and right facing.
  • the extensions can also be randomly oriented to the left or to the right or at any angle between the left and the right side. In other words, if one were to take a top view of the embodiment of FIG. 6 so that all that would be seen is first portion 419 , it can be rotated at any of the various angles along a 360° path.
  • at least one of the first and second portion includes light reflecting materials.
  • the first portion includes light absorbing materials and the second portion includes light reflecting materials.
  • a combination of different light directing elements such as, e.g., the elements shown in FIGS. 2, 3 , and 6 are used together to form a privacy film.
  • FIG. 1 shows the light directing elements as elongated rails that run continuously along the length of a document.
  • the elements can include interruptions, either of a specified length to create uniform interruptions, or of a random length to create non-uniform interruptions.
  • FIG. 7 shows an illustrative privacy film 500 disposed on substrate 550 .
  • the privacy film includes light directing elements 518 having uniform interruptions on the left hand side and non-uniform interruptions on the right hand side. Interspersed in between are light directing elements that are continuous over the entire length of the film.
  • the base sheet in all of the embodiments is light transmissive, it may include light reflecting materials.
  • the quantity of light reflecting materials used in the base sheet can, but does not have to, be similar to that used in the light directing elements.
  • the advantage of using similar amounts is that the process of making the privacy film, as further described below, can be simplified to using a single extruder instead of multiple extruders. In the case where substantially the same amount is used, care should be taken to select a sufficient amount to impart the privacy feature to the film without adversely affecting the readability of the underlying document.
  • Suitable materials for use in forming the privacy film include thermoplastic polymers and elastomers.
  • Suitable thermoplastic polymers include, e.g., polyolefins such as polypropylene or polyethylene, polystyrene, polycarbonate, polymethyl methacrylate, ethylene vinyl acetate copolymers, acrylate-modified ethylene vinyl acetate polymers, ethylene acrylic acid copolymers, nylon, polyvinylchloride, and engineering polymers such as polyketones or polymethylpentanes.
  • Suitable elastomers include, e.g., natural or synthetic rubber, styrene block copolymers containing isoprene, butadiene, or ethylene (butylene) blocks, metallocene-catalyzed polyolefins, polyurethane, and polydiorganosiloxanes. Mixtures of thermoplastic polymers and elastomers may also be used.
  • the privacy film of the present invention can be formed by extruding a polymeric web through a die having an opening cut, for example, by electron discharge machining.
  • the web would include the base sheet and the light directing elements disposed thereon.
  • the shape of the die opening is designed to generate a web with a desired cross-sectional shape or profile.
  • the web can be quenched after leaving the die opening by pulling it through a quenching material such as water.
  • a wetting agent may be added to the quenching medium to wet the entire surface of the extruded web, including spaces between the light directing elements.
  • the extruded web may be further processed, e.g., by applying a light absorbing coating to the tips of the elements (as shown in FIG. 4 ) or by cutting the extruded elements and stretching the web to form discontinuous light directing elements.
  • the film can be formed by co extrusion techniques as described, e.g., in PCT application WO 99/17630.
  • the coextrusion technique may involve passing different melt streams from different extruders into a multiple-manifold die or multiple-layer feed block and a film die. The individual streams merge in the feed block and enter the die as a layered stack that flows out into layered sheets as the material leaves the die.
  • FIGS. 8 a , 8 b , and 8 c A second exemplary method of making the privacy film is shown schematically in FIGS. 8 a , 8 b , and 8 c .
  • polymeric material 801 and microstructured mold 800 are provided.
  • the microstructured mold includes a plurality of elongated, slanted channels 808 , each channel being separated from the next by land region 806 .
  • Each channel has a base 808 a disposed adjacent to the land region and a tip 808 b disposed distal to the land region.
  • the channel may have substantially linear walls with distinct sharp edges at the tip.
  • Each channel includes minor axis l that runs from the base to the tip.
  • each channel is slanted at an angle of greater than 15° and less than 90°. In another embodiment, each channel is slanted at angle of greater than 40° and less than 85°. In yet another embodiment, each channel is slanted at angle of greater than 55° and less than 75°. The angle is formed between the intersection of the minor axis of the channel and a line lying in the plane of the land region. Similar to the light directing element as discussed in FIG. 2 , each channel in the mold has a height h, as measured its base to its tip along the minor axis. Two adjacent channels have a center-to-center spacing of P. In one embodiment, the mold has h to P ratio of 0.5 to 5.
  • FIG. 8 a also shows schematically, by use of plunger 804 , that the polymeric material is induced into the channels of the microstructured mold by use of heat and or pressure.
  • FIG. 8 b shows a subsequent step in the process where the polymeric material has flowed into and filled the channels thereby replicating the shape of the channels.
  • the replicated polymeric material solidifies in the mold.
  • the term “solidifies” means generally that the polymeric material cools and hardens sufficiently to allow it to be separated from the mold.
  • the polymeric material includes light reflecting material, such as the ones listed above. When used, the light reflecting material constitutes less than 20%, and in some embodiments, less than 5% of the total weight of the polymeric material.
  • FIG. 8 c shows yet another step in the process where the replicated polymeric material has been separated from the mold to yield privacy film 810 having a plurality of distinct light directing elements 818 , each connected to another by a polymeric base sheet 812 having first surface 812 a from which the light directing elements protrude and opposing second substantially planar surface 812 b .
  • the separation step results in substantially no distortion on the light directing elements of the privacy film. That is, when the replicated polymeric material is separated from the mold, each light directing elements of the resulting privacy film is nearly an exact replica of its corresponding channel, so that there would be less than 20% and preferably less than 10% variation in the dimensions of the light directing element as compared to the dimensions of the corresponding channel.
  • FIG. 8 c further shows light transmissive adhesive 819 is disposed on the second substantially planar surface of the polymeric base sheet.
  • the polymeric material can be in the form of a thermoplastic material, such as a thermoplastic film, a molten resin, or a liquid resin.
  • a thermoplastic material such as a thermoplastic film, a molten resin, or a liquid resin.
  • a combination of heat and pressure can be used to induce the polymeric material to flow into the channels.
  • Such a method can be generally described as compression molding and are discussed in publications such as U.S. Pat. No. 4,244,683 (Rowland) and U.S. Pat. No. 4,601,861 (Pricone et al.).
  • the heat of the molten resin, along with heating the mold are useful steps in inducing it to flow into the channels.
  • 4,097,634 discloses an exemplary extrusion cast and embossing method.
  • heat and or pressure can be used to induce the polymeric material to flow into the channels.
  • Useful liquid resins are light curable resins, such as an ultraviolet light curable resin.
  • the solidifying step will involve exposing the light curable resin to a light source.
  • U.S. Pat. No. 3,869,346 (Rowland); U.S. Pat. No. 4,576,850 (Martens); and U.S. Pat. No. 5,183,597 disclose exemplary liquid cast and light curing processes. These patents are incorporated by reference in their entirety.
  • the polymeric material may include at least two layers, i.e., it may be of a multilayer construction.
  • the polymeric material includes a first layer that is substantially free of light absorbing and light reflecting materials and a second layer that comprises light absorbing materials, light reflecting materials, or a combination thereof.
  • the channels of the microstructured mold contacts the layer containing the light absorbing and/or light reflecting materials.
  • a privacy film made generally according to FIGS. 8 a to 8 c as follows.
  • a microstructured tool was made by machining a copper plate to impart channels thereto.
  • Each channel had a height dimension of 19.3 mil (0.5 mm) measured along its minor axis and slanted at an angle of 63.1 degrees.
  • the tip of each channel had a dimension of 3.8 mil.
  • the base of each channel had a dimension of 6.9 mil (0.18 mm), as measured along a line that lies in the same plane as the land region. As measured near the base along a line that is parallel to the tip, the base had a dimension of 5.5 mil (0.14 mm).
  • the land region distance between one edge of a channel to the nearest edge of the next adjacent angle was 4.9 mil (0.12 mm).
  • a polypropylene film containing 2% by weight of TiO 2 pigment was used as the thermoplastic polymeric film.
  • the polypropylene film was 5 mil (0.13 mm) thick.
  • the film was induced to flow into the channels using a heat press set at 170° C. under a pressure of 160 pounds per square inch (psi) for 30 seconds.
  • the compression molded film was cooled to 100° C. under the same pressure, after which time it was separated from the mold to yield a privacy film having a plurality of light directing elements connected to one another by a base substrate. A small amount of black ink was applied to the top of the light directing elements.

Abstract

A method of making a privacy film includes generally the following steps: providing a polymeric material, depositing the polymeric material onto a microstructured mold comprising a plurality of substantially parallel, elongated channels with specific geometry; inducing the polymeric material to flow into the channels of the microstructured mold; solidifying the polymeric material inside the channels to yield a plurality of light directing elements that are connected with one another via a polymeric base sheet; and separating the privacy film from the microstructured mold.

Description

    CROSS REFERENCE TO RELATED APPLICATION
  • The present application is a continuation-in-part of U.S. patent application Ser. No. 11/250,676 filed on Oct. 14, 2005, which is incorporated by reference in its entirety.
  • FIELD OF INVENTION
  • The present invention relates to a privacy film. In particular, the present invention relates to a polymeric based privacy film having a plurality of light directing elements each element being disposed substantially parallel to the next adjacent light directing element, the film being well suited for use with documents.
  • BACKGROUND
  • Products capable of providing privacy for the consumer have increased. For example, it is very common today for most personal computers and automatic teller machines to include a privacy screen allowing the user to view the image on the monitor while simultaneously limiting the view for bystanders, or at least those not in the viewing angle of the screen. Some have used light control films to provide privacy to a user who has documents containing sensitive material. The idea is similar in that the user can view the image on the document but bystanders are limited in viewing the document's content.
  • The art discloses various light control films that also serve the purpose of providing privacy to the user. However, as document privacy is becoming more and more of a desire for consumers, those skilled in the art seek different solutions to provide this desired feature. Thus, there is a continuing need for new privacy film constructions.
  • SUMMARY
  • The present invention provides for a privacy film that can be used with documents to limit the angle at which a viewer can read the information on the document. In particular, when the privacy film is placed in the use orientation such that the viewing angle is coincident with the user's line of sight, the user will be able to see the contents of the documents while others will only have a limited view of the document's content.
  • In one aspect, the present invention pertains to a privacy film comprising a light transmissive, polymeric base sheet comprising (i) a first polymeric material, the base sheet having opposing first and second surfaces; and (ii) a plurality of light directing elements comprising a second polymeric material, wherein each element has a base, a height h, and a minor axis disposed along the height, wherein the elements protrude from the first surface of the base sheet, and wherein each element is disposed such that the minor axis of one element is substantially parallel to the minor axis of the next adjacent element and the base of one element is not joined with the base of the next adjacent element. In another aspect, the privacy film comprises elongated light directing elements.
  • In another aspect, the present invention pertains to a method of making a privacy film comprising the steps of (i) providing a polymeric material; (ii) depositing the polymeric material onto a microstructured mold comprising a plurality of substantially parallel, elongated channels, wherein each channel is slanted and is separated from the next channel by a land region, wherein each channel has a base disposed adjacent to and a tip distal from the land region, wherein each channel has a minor axis that runs from the base to the tip; (iii) inducing the polymeric material to flow into the channels of the microstructured mold; (iv) solidifying the polymeric material inside the channels to yield a plurality of light directing elements that are connected with one another via a polymeric base sheet having a first surface from which the light directing elements protrude and an opposing second substantially planar surface; and (iv) separating the privacy film from the microstructured mold.
  • As used herein, the term “light transmissive” means the ability to transmit visible light. In one embodiment, the light transmissive base sheet has an opacity of 90 or less, as measured using a Lab Scan 6000 Tester with a HuterLab Master Color Data Program, commercially available from Hunter Associates Laboratory, Inc., Reston, Va. With reference to the light directing element, the term “elongated” generally means that the element has a rail-like appearance. The rails can be continuous along the entire length of the privacy film or they can be discontinuous. In one embodiment, the discontinuous light directing elements are discrete bodies having an appearance of a stem, such as, e.g., a stem of a mushroom.
  • One advantage of the present invention is that it provides the privacy feature with flexible construction that is relatively easy to manufacture. The privacy film can be quickly attached to the document in a non-permanent manner. Furthermore, the privacy film is durable so that it can be used repeatedly.
  • In this document, the term “about” is presumed to modify all numerical values.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • The invention can be better understood with reference to the following drawings, wherein:
  • FIG. 1 is a perspective view of one exemplary embodiment of a privacy film;
  • FIG. 2 is a cross-sectional view of the privacy film of FIG. 1 taken along line 2-2;
  • FIG. 3 is a cross-sectional view of another exemplary embodiment of a privacy film showing light directing elements with multiple sections;
  • FIG. 4 is a cross-sectional view of another exemplary embodiment of a privacy film showing the tip portions of the light directing elements being covered with a light absorbing coating;
  • FIG. 5 is a cross-sectional view of another exemplary embodiment of a privacy film showing light directing elements at varying cant angles;
  • FIG. 6 is a cross-section view of another exemplary embodiment of a privacy film showing the tip portions of the light directing elements being elongated in a direction parallel to the base layer;
  • FIG. 7 is a perspective of another exemplary embodiment of a privacy film showing a combination of elongated light directing elements; and
  • FIGS. 8 a to 8 c are schematic views of an exemplary process that can be used to make the privacy film.
  • These drawings are not drawn to scale and are intended only for illustrative purposes.
  • DETAILED DESCRIPTION
  • FIG. 1 is a perspective view of one exemplary embodiment of the present invention showing privacy film 10 having elongated light directing elements 18 disposed on substrate 50 that may contain sensitive information. In one embodiment, the privacy film can be attached using a light transmissive adhesive (not shown). The elements have a major axis L and a minor axis l. One exemplary substrate is a document bearing confidential information that the document owner wants limited viewing access.
  • In use the privacy film of the present invention is disposed on the document so that the major axis L lies substantially parallel to the image or lines of text on the document. For example, on 8½ by 11 inch paper in portrait orientation where the text lies substantially parallel to the 8½ inch side of the paper, the privacy film would be oriented so that the major axis also lies along the same direction. The privacy film can be disposed on the document temporarily, meaning that the film can be removed from the substrate without damage thereto, or permanently, meaning that removal of the privacy film will most likely cause damage to the document. There exists a variety of means for attaching or disposing the privacy film to the document. For example, an adhesive can be used. The adhesive can be pressure sensitive or hot melt. The adhesive can be a repositionable adhesive, meaning that it can be applied and removed from the substrate multiple times without damage to the substrate and without significant loss in adhesion of the repositionable adhesive. In another application, the privacy film is formed as a pocket, where the privacy film forms a front, a polymeric backing or the privacy film forms a back, and the privacy film and the back are attached on three sides, leaving the fourth, typically top side, open for insertion and removal of a document. Other configurations can be used.
  • The light directing elements interfere with light transmission thereby providing the privacy feature of the present inventive film. Optically active materials, such as light reflecting and or light absorbing materials, may be included. The light directing elements geometry, spacing, and the optically active materials are discussed below in detail.
  • In one exemplary embodiment, the heights of the light directing elements are substantially the same on the privacy film. There may be some variation in the elements' heights due to the manufacturing conditions. In another exemplary embodiment, the heights of the elements vary from one region of the privacy film to another region and even from one element to the next adjacent element. By variation in height, it is generally meant that one element will be from 75% to 95% in height of another element. FIG. 3 generally illustrates the embodiment having light reflecting elements with varying heights.
  • FIG. 2 shows a cross-section of the privacy film in FIG. 1 taken along line 2-2. The privacy film includes base sheet 12 having opposing first surface 14 and second surface 16 and demarcation line 13. Light directing elements 18 protrude from the first surface of the base sheet. While FIG. 2 shows that demarcation line 13 is collinear with first surface 14, the line can be at a different location. Each light directing element has a height h, a width W, and a center-to-center spacing from one element to the next adjacent element P. The height h is measured along the minor axis l from the first surface 14 of the base sheet to tip 20. The width W is measured perpendicular to the minor axis.
  • In one exemplary embodiment the h to P ratio (h:P) is greater than 0.5. In another embodiment, the h:P ratio is less than 5. In one embodiment, the width of the light directing element, as measured proximate to the first surface of the base sheet is greater than 25 microns. In another embodiment, the width is less than 750 microns. In the embodiment of FIG. 2, the light directing elements are disposed on the base sheet at a cant angle θ. The cant angle is the angle between first surface 14 and the minor axis of each light directing element. In one embodiment, the cant angle is greater than 15°. In another embodiment, the cant angle is less than 90°. In yet another embodiment, the cant angle ranges from 40° to 85°. In yet another embodiment, the cant angle ranges from 55° to 75°. If desired, adhesive 22 is provided on the second surface of the base sheet, for attachment to a substrate. While the light directing elements of this particular embodiment are substantially uniform in its cross-sectional dimension, there can be a slight draft (i.e., a slight narrowing) to the elements towards tip 20. Also, as shown in FIG. 2, the placement of two adjacent light directing elements is such that the tip of one element, taken along an imaginary line normal to the first surface of the base sheet (shown as dotted line N), lies next to the base (shown as reference letter b) of the next element. Other placement configurations can be used, so long as the light directing elements provide the privacy feature and provided that the h:P ratio falls within the established range. In this particular embodiment, the light directing element includes either light absorbing materials or light reflecting materials.
  • Suitable light reflecting materials include, e.g., titanium dioxide, zinc oxide, zinc sulfide, zinc phosphate, calcium carbonate, alumina, silica, antimony oxide, barium sulfate, lithopene (a co-precipitate of barium sulfate and zinc oxide), calcined kaolin, lead carbonate, magnesium oxide, and combinations thereof. Suitable light absorbing materials include, e.g., carbon black, spinel black, rutile black, iron black, and combinations thereof. When a light reflecting material is used, 1 to 50 parts by weight, based on 100 parts by weight total, is added to the polymer resin to form the light directing elements. In some embodiments, 1 to 15 parts by weight is used. In other embodiments, 2 to 10 parts by weight is used. When a light absorbing material is used, 0.1 to 50 parts by weight, based on 100 parts by weight total, is added to the polymer resin to form the light directing elements. In some embodiments 1 to 15 parts by weight of light absorbing material is used. In other embodiments, 1 to 5 parts by weight is used. A combination of light reflecting material and light absorbing material can be used to form an individual light directing element, as further discussed below. In other embodiments, color pigments, fluorescent colors, and glitter can be added to the light directing elements.
  • FIG. 3 shows a cross-sectional view of another embodiment of the invention, where privacy film 100 includes base sheet 112 having opposing first surface 114 and second surface 116. Light directing elements 118 protrude from the first surface of the base sheet. Demarcation line 113 resides slightly within the light directing element. In this particular embodiment, the light directing element include first portion 119 disposed distal to the first surface of the base sheet, second portion 117 disposed proximate to the first surface, and third portion from the first surface to line 113. In some embodiments, the composition of the base sheet and the third portion will be similar, and may even be the same. Line 115 demarcates the first portion from the second portion. The first portion includes a light absorbing material and the second portion includes a light reflecting material. The height of the first portion is denoted as l119, and is the distance along the minor axis of the element between line 115 and the tip. The height of the second portion is denoted as l117 and is the distance along the minor axis of the element between line 113 and 115. In one embodiment, the ratio of l119 to l117 is 3 to 0.1. The placement of two adjacent light directing elements is such that the tip of one element, taken along imaginary line N overlaps with the base of the next adjacent element. While the light directing element of FIG. 2 includes a tip that is has substantially straight edges, the tips can be rounded as shown in FIG. 3. Other geometry can be used, so long as the light directing elements interfere with light transmission so as to provide the privacy feature.
  • FIG. 4 shows a cross-sectional view of another embodiment of the present invention where privacy film 200 includes base sheet 212 having opposing first surface 214, second surface 216, and demarcation line 213. Light directing elements 218 protrude from the first surface. At the tips of the light directing elements, light absorbing coating 219 has been applied. The coating may migrate down the sides of the light directing elements. In this particular embodiment, the light directing element could include light reflecting materials. The coating can be applied to the elements using known coating techniques. In one embodiment, the coating is 0.01 to 1.0 mm in dry thickness. In one embodiment, the light absorbing coating is applied to the tips using digital printing methods, such as inkjet printing, color inkjet printing, laser printing, and dye or mass transfer printing or by conventional printing techniques, such as offset lithography, flexography, and gravure. The tips of the elements are receptive to the ink or the dyes used in the printing process.
  • FIG. 5 shows a cross-sectional view of another embodiment of the present invention, where privacy film 300 includes base sheet 312 having opposing first surface 314 and second surface 316. Light directing elements 318 protrude from the first surface of the base sheet. For ease of understanding, only the cross-sections of five light directing elements are shown. In this particular embodiment, the cant angle of each light directing element differs from the next adjacent element. For example, cant angle θ1 will be similar to cant angle θ2. For example, θ1 may be 90° while θ1 may be 88°. Thus, these two light directing elements will be substantially parallel to one another. The cant angle for the fifth light directing element, θ5, however, may be very different than that of the first light directing element. In this figure, if θ1 is 90°, θ5 may be 60°, so that the first light directing element will not be considered to be parallel to the fifth light directing element. The magnitude of the varying change in cant angles has been exaggerated in this figure to illustrate the varying cant angles.
  • FIG. 6 shows a cross-sectional view of yet another embodiment of the present invention, where privacy film 400 includes base sheet 412 having opposing first surface 414, second surface 416 and demarcation line 413. Light directing elements 418 protrude from the first surface. Each light directing element has first portion 419 distal to the first surface of the base sheet and second portion 417 proximate to the first surface. Line 415 demarcates the first portion from the second portion. Line 413 demarcates the second portion from a third portion. The first portion has one-sided extension, similar to an upside down “L”. The extensions can all be on the same side, e.g., all left facing or all right facing (as shown in the figure), or they can alternate between left facing and right facing. The extensions can also be randomly oriented to the left or to the right or at any angle between the left and the right side. In other words, if one were to take a top view of the embodiment of FIG. 6 so that all that would be seen is first portion 419, it can be rotated at any of the various angles along a 360° path. In one embodiment, at least one of the first and second portion includes light reflecting materials. In another embodiment, the first portion includes light absorbing materials and the second portion includes light reflecting materials. In yet another embodiment, a combination of different light directing elements, such as, e.g., the elements shown in FIGS. 2, 3, and 6 are used together to form a privacy film.
  • FIG. 1 shows the light directing elements as elongated rails that run continuously along the length of a document. In other embodiments, the elements can include interruptions, either of a specified length to create uniform interruptions, or of a random length to create non-uniform interruptions. Among all the various elements, there could be light directing elements that are continuous over the length of the entire substrate. For example, FIG. 7 shows an illustrative privacy film 500 disposed on substrate 550. The privacy film includes light directing elements 518 having uniform interruptions on the left hand side and non-uniform interruptions on the right hand side. Interspersed in between are light directing elements that are continuous over the entire length of the film.
  • While the base sheet in all of the embodiments is light transmissive, it may include light reflecting materials. The quantity of light reflecting materials used in the base sheet can, but does not have to, be similar to that used in the light directing elements. The advantage of using similar amounts is that the process of making the privacy film, as further described below, can be simplified to using a single extruder instead of multiple extruders. In the case where substantially the same amount is used, care should be taken to select a sufficient amount to impart the privacy feature to the film without adversely affecting the readability of the underlying document.
  • Suitable materials for use in forming the privacy film include thermoplastic polymers and elastomers. Suitable thermoplastic polymers include, e.g., polyolefins such as polypropylene or polyethylene, polystyrene, polycarbonate, polymethyl methacrylate, ethylene vinyl acetate copolymers, acrylate-modified ethylene vinyl acetate polymers, ethylene acrylic acid copolymers, nylon, polyvinylchloride, and engineering polymers such as polyketones or polymethylpentanes. Suitable elastomers include, e.g., natural or synthetic rubber, styrene block copolymers containing isoprene, butadiene, or ethylene (butylene) blocks, metallocene-catalyzed polyolefins, polyurethane, and polydiorganosiloxanes. Mixtures of thermoplastic polymers and elastomers may also be used.
  • The inventive light directing element can be made in various ways. In a first exemplary method, the privacy film of the present invention can be formed by extruding a polymeric web through a die having an opening cut, for example, by electron discharge machining. The web would include the base sheet and the light directing elements disposed thereon.
  • The shape of the die opening is designed to generate a web with a desired cross-sectional shape or profile. The web can be quenched after leaving the die opening by pulling it through a quenching material such as water. A wetting agent may be added to the quenching medium to wet the entire surface of the extruded web, including spaces between the light directing elements. The extruded web may be further processed, e.g., by applying a light absorbing coating to the tips of the elements (as shown in FIG. 4) or by cutting the extruded elements and stretching the web to form discontinuous light directing elements.
  • When the inventive privacy film contains multiple different layers, as when the base sheet and the light directing elements are of different materials or as when the light directing elements contain multiple sections (see, e.g., FIGS. 3 and 6), the film can be formed by co extrusion techniques as described, e.g., in PCT application WO 99/17630. The coextrusion technique may involve passing different melt streams from different extruders into a multiple-manifold die or multiple-layer feed block and a film die. The individual streams merge in the feed block and enter the die as a layered stack that flows out into layered sheets as the material leaves the die.
  • A second exemplary method of making the privacy film is shown schematically in FIGS. 8 a, 8 b, and 8 c. In the method depicted in FIG. 8 a, polymeric material 801 and microstructured mold 800 are provided. The microstructured mold includes a plurality of elongated, slanted channels 808, each channel being separated from the next by land region 806. Each channel has a base 808 a disposed adjacent to the land region and a tip 808 b disposed distal to the land region. In this embodiment, the channel may have substantially linear walls with distinct sharp edges at the tip. Each channel includes minor axis l that runs from the base to the tip. Each channel is slanted at an angle of greater than 15° and less than 90°. In another embodiment, each channel is slanted at angle of greater than 40° and less than 85°. In yet another embodiment, each channel is slanted at angle of greater than 55° and less than 75°. The angle is formed between the intersection of the minor axis of the channel and a line lying in the plane of the land region. Similar to the light directing element as discussed in FIG. 2, each channel in the mold has a height h, as measured its base to its tip along the minor axis. Two adjacent channels have a center-to-center spacing of P. In one embodiment, the mold has h to P ratio of 0.5 to 5.
  • Two adjacent channels are placed such that, as viewed from an imaginary line normal to the land region, the tip of one channel coincides with the base of the next channel. This feature is similar to that shown in FIG. 2. In an alternative embodiment, two channels are placed such that, as viewed from the imaginary line, the tip of one channel overlaps the base of the next channel. The polymeric material is deposited onto the microstructured mold. FIG. 8 a also shows schematically, by use of plunger 804, that the polymeric material is induced into the channels of the microstructured mold by use of heat and or pressure.
  • FIG. 8 b shows a subsequent step in the process where the polymeric material has flowed into and filled the channels thereby replicating the shape of the channels. The replicated polymeric material solidifies in the mold. The term “solidifies” means generally that the polymeric material cools and hardens sufficiently to allow it to be separated from the mold. In one process, the polymeric material includes light reflecting material, such as the ones listed above. When used, the light reflecting material constitutes less than 20%, and in some embodiments, less than 5% of the total weight of the polymeric material.
  • FIG. 8 c shows yet another step in the process where the replicated polymeric material has been separated from the mold to yield privacy film 810 having a plurality of distinct light directing elements 818, each connected to another by a polymeric base sheet 812 having first surface 812 a from which the light directing elements protrude and opposing second substantially planar surface 812 b. The separation step results in substantially no distortion on the light directing elements of the privacy film. That is, when the replicated polymeric material is separated from the mold, each light directing elements of the resulting privacy film is nearly an exact replica of its corresponding channel, so that there would be less than 20% and preferably less than 10% variation in the dimensions of the light directing element as compared to the dimensions of the corresponding channel. FIG. 8 c further shows light transmissive adhesive 819 is disposed on the second substantially planar surface of the polymeric base sheet.
  • The polymeric material can be in the form of a thermoplastic material, such as a thermoplastic film, a molten resin, or a liquid resin. When in the thermoplastic film form, a combination of heat and pressure can be used to induce the polymeric material to flow into the channels. Such a method can be generally described as compression molding and are discussed in publications such as U.S. Pat. No. 4,244,683 (Rowland) and U.S. Pat. No. 4,601,861 (Pricone et al.). In the molten resin state, the heat of the molten resin, along with heating the mold are useful steps in inducing it to flow into the channels. U.S. Pat. No. 4,097,634 (Bergh) discloses an exemplary extrusion cast and embossing method. In a liquid resin state, heat and or pressure can be used to induce the polymeric material to flow into the channels. Useful liquid resins are light curable resins, such as an ultraviolet light curable resin. In such a case, the solidifying step will involve exposing the light curable resin to a light source. U.S. Pat. No. 3,869,346 (Rowland); U.S. Pat. No. 4,576,850 (Martens); and U.S. Pat. No. 5,183,597 (Lu et al.) disclose exemplary liquid cast and light curing processes. These patents are incorporated by reference in their entirety.
  • The polymeric material may include at least two layers, i.e., it may be of a multilayer construction. In one embodiment, the polymeric material includes a first layer that is substantially free of light absorbing and light reflecting materials and a second layer that comprises light absorbing materials, light reflecting materials, or a combination thereof. In such cases, the channels of the microstructured mold contacts the layer containing the light absorbing and/or light reflecting materials.
  • EXAMPLE Example 1
  • A privacy film, made generally according to FIGS. 8 a to 8 c as follows. A microstructured tool was made by machining a copper plate to impart channels thereto. Each channel had a height dimension of 19.3 mil (0.5 mm) measured along its minor axis and slanted at an angle of 63.1 degrees. The tip of each channel had a dimension of 3.8 mil. The base of each channel had a dimension of 6.9 mil (0.18 mm), as measured along a line that lies in the same plane as the land region. As measured near the base along a line that is parallel to the tip, the base had a dimension of 5.5 mil (0.14 mm). The land region distance between one edge of a channel to the nearest edge of the next adjacent angle was 4.9 mil (0.12 mm).
  • A polypropylene film containing 2% by weight of TiO2 pigment was used as the thermoplastic polymeric film. The polypropylene film was 5 mil (0.13 mm) thick. The film was induced to flow into the channels using a heat press set at 170° C. under a pressure of 160 pounds per square inch (psi) for 30 seconds. The compression molded film was cooled to 100° C. under the same pressure, after which time it was separated from the mold to yield a privacy film having a plurality of light directing elements connected to one another by a base substrate. A small amount of black ink was applied to the top of the light directing elements.

Claims (22)

1. A method of making a privacy film comprising the steps of:
providing a polymeric material;
depositing the polymeric material onto a microstructured mold comprising a plurality of substantially parallel, elongated channels, wherein each channel is slanted and is separated from the next channel by a land region, wherein each channel has a base disposed adjacent to and a tip disposed distal to the land region, wherein each channel has a minor axis that runs from the base to the tip;
inducing the polymeric material to flow into the channels of the microstructured mold;
solidifying the polymeric material inside the channels to yield a plurality of light directing elements that are connected with one another via a polymeric base sheet having a first surface from which the light directing elements protrude and an opposing second substantially planar surface; and
separating the privacy film from the microstructured mold.
2. The method of claim 1, wherein the channels of the microstructured mold are tapered at their tips.
3. The method of claim 1, wherein the polymeric material is a thermoplastic polymer.
4. The method of claim 3, wherein the thermoplastic polymer is selected from the group consisting of polypropylene, polyethylene, polystyrene, polycarbonate, polymethyl methacrylate, ethylene vinyl acetate copolymers, acrylate-modified ethylene vinyl acetate polymers, ethylene acrylic acid copolymers, nylon, polyvinylchloride, and combinations thereof.
5. The method of claim 1, wherein the polymeric material comprises a light reflecting material.
6. The method of claim 5, wherein the light reflecting material is selected from the group consisting of titanium dioxide, zinc oxide, zinc sulfide, zinc phosphate, calcium carbonate, alumina, silica, antimony oxide, barium sulfate, lithopene, calcined kaolin, lead carbonate, magnesium oxide, and combinations thereof.
7. The method of claim 6, wherein privacy film comprises less than 20% by weight of the light reflecting material, based on the total weight of the film.
8. The method of claim 1, wherein each channel has a height h, which is the distance from its base to its tip along its minor axis, and two adjacent channels have a center-to-center spacing P, and wherein the ratio of h to P is from about 0.5 to 5.
9. The method of claim 1, wherein two adjacent channels are placed such that the tip of one channel, as viewed from an imaginary line normal to the land region, overlaps the base of the adjacent channel.
10. The method of claim 1, wherein the polymeric material is molten resin.
11. The method of claim 10, wherein the inducing step comprises heating the microstructured mold.
12. The method of claim 1, wherein the polymeric material is a liquid resin or a thermoplastic film.
13. The method of claim 12, wherein the inducing step comprises applying heat and pressure to the liquid resin.
14. The method of claim 1, wherein the separating step results in substantially no distortion on the light directing elements of the privacy film.
15. The method of claim 1 further comprising laminating a light transmissive adhesive to the second surface of the polymeric base sheet.
16. The method of claim 1, wherein the light transmissive adhesive is a repositionable pressure sensitive adhesive.
17. The method of claim 1, wherein the channels of the microstructured mold are slanted at an angle greater than about 15° and less than about 90°, the angle being formed between the intersection of the minor axis of the channel and a line lying in the plane of the land region.
18. The method of claim 1, wherein two adjacent channels are placed such that the tip of one channel, as viewed from an imaginary line normal to the land region, is coincident with the base of the adjacent channel.
19. The method of claim 1 further comprising applying a light absorbing coating to a top portion of the light directing elements.
20. The method of claim 1, wherein the polymeric material comprises a light absorbing material.
21. The method of claim 1, wherein the polymeric material comprises light absorbing and light reflecting materials.
22. The method of claim 1, wherein the polymeric material comprises at least two layers, wherein a first layer is substantially free of light absorbing and light reflecting materials, and wherein a second layer comprises light absorbing material, light reflecting materials, or a combination thereof.
US11/580,382 2005-10-14 2006-10-13 Method of making a privacy film Abandoned US20070084549A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US11/580,382 US20070084549A1 (en) 2005-10-14 2006-10-13 Method of making a privacy film

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/250,676 US7467873B2 (en) 2005-10-14 2005-10-14 Privacy film
US11/580,382 US20070084549A1 (en) 2005-10-14 2006-10-13 Method of making a privacy film

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
US11/250,676 Continuation-In-Part US7467873B2 (en) 2005-10-14 2005-10-14 Privacy film

Publications (1)

Publication Number Publication Date
US20070084549A1 true US20070084549A1 (en) 2007-04-19

Family

ID=37947069

Family Applications (2)

Application Number Title Priority Date Filing Date
US11/250,676 Expired - Fee Related US7467873B2 (en) 2005-10-14 2005-10-14 Privacy film
US11/580,382 Abandoned US20070084549A1 (en) 2005-10-14 2006-10-13 Method of making a privacy film

Family Applications Before (1)

Application Number Title Priority Date Filing Date
US11/250,676 Expired - Fee Related US7467873B2 (en) 2005-10-14 2005-10-14 Privacy film

Country Status (6)

Country Link
US (2) US7467873B2 (en)
EP (2) EP1943075A4 (en)
JP (2) JP2009511307A (en)
KR (2) KR20080058370A (en)
CN (2) CN101287595B (en)
WO (2) WO2007047745A1 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090237950A1 (en) * 2008-03-24 2009-09-24 I/O Controls Corporation Low glare lighting for a transit vehicle
WO2009096722A3 (en) * 2008-01-29 2009-11-05 Lg Chem, Ltd. Method for making privacy film
WO2011035418A1 (en) * 2009-09-23 2011-03-31 Peter Dobrich Enhanced display
WO2018078493A3 (en) * 2016-10-28 2018-06-07 3M Innovative Properties Company Light control film with varied viewing angle
DE102019006022B3 (en) 2019-08-21 2020-07-23 Sioptica Gmbh Optical element with variable transmission and screen with such an optical element

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102006050047A1 (en) * 2006-10-24 2008-04-30 Giesecke & Devrient Gmbh Transparent security element for security papers, data carrier, particularly valuable documents such as bank note, identification card and for falsification of goods, has transparent substrate and marking layer applied on substrate
US20090242142A1 (en) * 2008-04-01 2009-10-01 International Business Machines Corporation Privacy screen for a display device
KR101578244B1 (en) * 2008-05-16 2015-12-16 쓰리엠 이노베이티브 프로퍼티즈 컴파니 Light control film with off-axis visible indicia
US20100264163A1 (en) * 2008-11-13 2010-10-21 Tevs Nikolai R Product Dispensing Apparatus And Method
US20110227327A1 (en) * 2010-03-16 2011-09-22 Bryan Prichard Privacy card cover
KR101812822B1 (en) 2010-03-25 2017-12-27 쓰리엠 이노베이티브 프로퍼티즈 컴파니 Composite layer
WO2011119323A1 (en) 2010-03-25 2011-09-29 3M Innovative Properties Company Extrusion die element, extrusion die and method for making multiple stripe extrudate
EP2558776B1 (en) 2010-04-16 2022-09-14 Azumo, Inc. Front illumination device comprising a film-based lightguide
US9028123B2 (en) 2010-04-16 2015-05-12 Flex Lighting Ii, Llc Display illumination device with a film-based lightguide having stacked incident surfaces
MX2012012033A (en) 2010-04-16 2013-05-20 Flex Lighting Ii Llc Illumination device comprising a film-based lightguide.
US9057830B2 (en) 2010-07-19 2015-06-16 Massachusetts Institute Of Technology Discriminating electromagnetic radiation based on angle of incidence
US10292784B2 (en) * 2010-12-10 2019-05-21 Illumix Surgical Canada Inc. Illuminating surgical device
KR101245178B1 (en) * 2011-05-09 2013-03-28 주식회사 홀코 Privacy film
WO2013019080A2 (en) * 2011-08-03 2013-02-07 하나마이크로(주) Light control device provided with plurality of light control elements and manufacturing method thereof
BR112014008353A2 (en) 2011-10-05 2017-04-11 3M Innovative Properties Co three-dimensional entanglement of polymeric wick, matrices and methods for its production
CN104321186B (en) 2012-03-26 2017-09-08 3M创新有限公司 A series of film including openings and preparation method thereof
WO2013148149A1 (en) 2012-03-27 2013-10-03 3M Innovative Properties Company Photovoltaic modules comprising light directing mediums and methods of making the same
WO2015178982A2 (en) 2014-02-25 2015-11-26 Massachusetts Institute Of Technology Methods and apparatus for broadband angular selectivity of electromagnetic waves
DE112015004186B4 (en) * 2014-09-12 2022-07-07 Yazaki Corporation Face panel, display unit, in-vehicle display device and dashboard
US20160124126A1 (en) * 2014-10-29 2016-05-05 Sergiy Vasylyev Angular selective light control sheeting and method of making the same
KR20170138478A (en) * 2015-04-17 2017-12-15 쓰리엠 이노베이티브 프로퍼티즈 컴파니 A light redirecting film useful for use with solar modules
EP3362744A4 (en) 2015-10-12 2019-06-12 3M Innovative Properties Company Light redirecting film useful with solar modules
US11947135B2 (en) 2017-12-13 2024-04-02 3M Innovative Properties Company High transmission light control film
CN111465894A (en) 2017-12-13 2020-07-28 3M创新有限公司 High transmittance light control film
CN108508509B (en) 2018-04-12 2019-10-29 京东方科技集团股份有限公司 A kind of peep-proof film and preparation method thereof, backlight module, display device
US20210271095A1 (en) * 2018-07-12 2021-09-02 Lg Innotek Co., Ltd. Optical path control member and display device comprising same
EP3830615A4 (en) 2018-08-01 2022-04-13 3M Innovative Properties Company High transmission light control film
EP3894915A4 (en) 2018-12-14 2022-08-17 3M Innovative Properties Company Liquid crystal display having a frontside light control film
CN109445173B (en) 2019-01-02 2021-01-22 京东方科技集团股份有限公司 Peep-proof film, manufacturing method thereof and display module
JP7446284B2 (en) * 2019-03-26 2024-03-08 デンカ株式会社 Resin sheets with hair-like bodies and molded products thereof
JP7358840B2 (en) 2019-08-22 2023-10-11 大日本印刷株式会社 optical components
KR102517586B1 (en) * 2020-12-03 2023-04-04 주식회사 세코닉스 Optical film for light route control
KR102474165B1 (en) 2022-08-27 2022-12-05 (주)이미지솔루션 Privacy film manufacturing system

Citations (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3524789A (en) * 1967-08-15 1970-08-18 Minnesota Mining & Mfg Louvered transparent sheeting made by skiving
US3689346A (en) * 1970-09-29 1972-09-05 Rowland Dev Corp Method for producing retroreflective material
US3691140A (en) * 1970-03-09 1972-09-12 Spencer Ferguson Silver Acrylate copolymer microspheres
US3707416A (en) * 1970-10-30 1972-12-26 Minnesota Mining & Mfg Skewed billets for making louvered films
US3857731A (en) * 1973-04-06 1974-12-31 Minnesota Mining & Mfg Acrylate microsphere-surfaced sheet material
US4025673A (en) * 1972-04-13 1977-05-24 Reinnagel Richard E Method of forming copy resistant documents by forming an orderly array of fibers extending upward from a surface, coating the fibers and printing the coated fibers and the copy resistant document resulting from said method
US4097634A (en) * 1976-04-19 1978-06-27 Minnesota Mining And Manufacturing Company Thermoplastic resin molding of complex decorative relief
US4166152A (en) * 1977-08-17 1979-08-28 Minnesota Mining And Manufacturing Company Tacky polymeric microspheres
US4244683A (en) * 1979-09-20 1981-01-13 Reflexite Corporation Apparatus for compression molding of retroreflective sheeting
US4495318A (en) * 1984-03-21 1985-01-22 International Cube Corporation Low tack microsphere glue
US4536362A (en) * 1983-10-06 1985-08-20 Mobil Oil Corporation Method for producing longitudinally ribbed plastic film
US4576850A (en) * 1978-07-20 1986-03-18 Minnesota Mining And Manufacturing Company Shaped plastic articles having replicated microstructure surfaces
US4578298A (en) * 1983-07-25 1986-03-25 Kisokaseisangyou Co., Ltd. Composite films for protecting documents from being reproduced
US4601861A (en) * 1982-09-30 1986-07-22 Amerace Corporation Methods and apparatus for embossing a precision optical pattern in a resinous sheet or laminate
US4684593A (en) * 1984-05-08 1987-08-04 Secure Images Inc. Secure and self-verifiable image
US4788094A (en) * 1986-09-25 1988-11-29 Kabushiki Kaisha Tokai Rika Denki Seisakusho Light controlling sheet
US4894060A (en) * 1988-01-11 1990-01-16 Minnesota Mining And Manufacturing Company Disposable diaper with improved hook fastener portion
US4984060A (en) * 1987-09-24 1991-01-08 Tadahiro Ohmi Semiconductor device wirings with hillocks
US5045569A (en) * 1988-11-30 1991-09-03 Minnesota Mining And Manufacturing Company Hollow acrylate polymer microspheres
US5073457A (en) * 1988-12-01 1991-12-17 Minnesota Mining And Manufacturing Company Repositionable adhesive
US5134198A (en) * 1990-10-24 1992-07-28 Minnesota Mining And Manufacturing Company Transparent liquid absorbent materials
US5145544A (en) * 1989-08-01 1992-09-08 Minnesota Mining And Manufacturing Company Method for preparing tape having improved tear strength
US5175030A (en) * 1989-02-10 1992-12-29 Minnesota Mining And Manufacturing Company Microstructure-bearing composite plastic articles and method of making
US5183597A (en) * 1989-02-10 1993-02-02 Minnesota Mining And Manufacturing Company Method of molding microstructure bearing composite plastic articles
US5254388A (en) * 1990-12-21 1993-10-19 Minnesota Mining And Manufacturing Company Light control film with reduced ghost images
US5290068A (en) * 1989-07-05 1994-03-01 Nocopi International Ltd. Document security method and system
US5301981A (en) * 1992-07-09 1994-04-12 Docusafe, Ltd. Copy preventing device and method
US5389723A (en) * 1990-10-24 1995-02-14 Minnesota Mining And Manufacturing Company Transparent liquid absorbent materials for use as ink receptive layers
US5431644A (en) * 1987-12-23 1995-07-11 Minnesota Mining And Manufacturing Company Elastic strand construction
US5571617A (en) * 1993-04-23 1996-11-05 Minnesota Mining And Manufacturing Company Pressure sensitive adhesive comprising tacky surface active microspheres
US5663241A (en) * 1994-12-13 1997-09-02 Minnesota Mining And Manufacturing Company Removable pressure sensitive adhesive and article
US5714237A (en) * 1996-01-16 1998-02-03 Minnesota Mining Manufacturing Company Partially crosslinked microspheres
US5728449A (en) * 1992-08-14 1998-03-17 Emtec Magnetics Gmbh Anti-copy film layer for documents
US5756625A (en) * 1996-10-11 1998-05-26 Minnesota Mining And Manufacturing Company Stabilized adhesive microspheres
US5795643A (en) * 1992-10-29 1998-08-18 Basf Magnetics Gmbh Anticopying film
US5824748A (en) * 1996-06-03 1998-10-20 Minnesota Mining And Manufacturing Company Composite pressure sensitive adhesive microspheres
US5851474A (en) * 1995-04-11 1998-12-22 Brunel University Of Uxbridge Injection molding with periodic forces to the material in the mold
US5858139A (en) * 1994-06-21 1999-01-12 Minnesota Mining And Manufacturing Company Composite used for light control or privacy
US6033516A (en) * 1993-07-17 2000-03-07 Emtec Magnetics Gmbh Process for the production of an anticopy film
US6151526A (en) * 1998-04-29 2000-11-21 Advanced Bionics Corporation Ribbed electrode for cochlear stimulation
US6189934B1 (en) * 1999-05-10 2001-02-20 Larry W. Scruggs Anti-copy layer utilizing spectral fragments
US6297906B1 (en) * 1996-02-29 2001-10-02 3M Innovative Properties Company Light fixture containing optical film
US6367128B1 (en) * 2000-02-10 2002-04-09 3M Innovative Properties Company Self-mating reclosable mechanical fastener
US6398370B1 (en) * 2000-11-15 2002-06-04 3M Innovative Properties Company Light control device
US6502935B1 (en) * 1999-04-30 2003-01-07 Felix Schoeller Jr. Foto-Und Spezialpapiere Gmbh & Co. Kg Ink-jet recording material comprising pigment layers
US6514589B1 (en) * 2000-01-10 2003-02-04 Kolon Industries, Inc. Solar control film
US20030038924A1 (en) * 2001-08-24 2003-02-27 Veligdan James T. Prismatic optical display
US20040130788A1 (en) * 2001-02-02 2004-07-08 Kazuhiko Minami Optical filter and filter for touch panel type display
US20040202822A1 (en) * 2002-10-24 2004-10-14 Eastman Kodak Company Light management film with colorant receiving layer
US6806310B2 (en) * 2002-05-22 2004-10-19 Isp Investments Inc. Coated substrates for computer printers
US6830798B2 (en) * 2001-07-10 2004-12-14 Raytech Composites, Inc. Continuous yarn laid wet friction material
US20050027068A1 (en) * 2002-05-22 2005-02-03 Isp Investments Inc. Terpolymer compositions for coating substrates used in computer printers
US20060012059A1 (en) * 2004-07-14 2006-01-19 Ya-Chuan Cheng Method for manufacturing an optical sheet

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE27617E (en) * 1970-10-30 1973-04-17 Louvered transparent sheeting made by skiving
GB1315138A (en) * 1970-12-08 1973-04-26 Byrn G F Byrn Co G Moulding of louvres
US5204160A (en) * 1988-08-08 1993-04-20 Minnesota Mining And Manufacturing Company Light-collimating film
EP0354672A3 (en) * 1988-08-08 1990-10-10 Minnesota Mining And Manufacturing Company Light-collimating film
JP3043069B2 (en) * 1990-12-21 2000-05-22 ミネソタ・マイニング・アンド・マニュファクチュアリング・カンパニー Light control film with few ghost images
JPH0515836A (en) * 1991-07-16 1993-01-26 Dainippon Printing Co Ltd Production of direction selective ray adjusting sheet
JP3328496B2 (en) * 1996-03-04 2002-09-24 シャープ株式会社 Liquid crystal display
JP4066463B2 (en) 1996-07-18 2008-03-26 凸版印刷株式会社 Method for manufacturing copy protection body and copy protection body
JP3585074B2 (en) * 1996-07-26 2004-11-04 株式会社冨士ネーム VEHICLE DISPLAY LIGHT PATH REGULATION MEMBER AND METHOD OF MANUFACTURING THE SAME
JPH10104406A (en) * 1996-09-26 1998-04-24 Sharp Corp Production of light shielding filer and optical display device formed by using the same
JPH10246805A (en) * 1997-03-06 1998-09-14 Dainippon Printing Co Ltd Optical sheet for diffused light control, back light device, and liquid crystal display device
US6106922A (en) 1997-10-03 2000-08-22 3M Innovative Company Coextruded mechanical fastener constructions
JP2001219681A (en) 2000-02-10 2001-08-14 Dainippon Printing Co Ltd Decorative body
JP4502445B2 (en) * 2000-03-16 2010-07-14 大日本印刷株式会社 Method for producing antireflection film
JP2002184719A (en) * 2000-12-19 2002-06-28 Matsushita Electric Ind Co Ltd Method of forming pattern
ITMI20012075A1 (en) * 2001-10-08 2003-04-08 Consiglio Nazionale Ricerche PROCEDURE FOR THE CONFERENCE AND CONTROL ON MICRO AND NANOMATRIC STAIRS OF THE STRUCTURAL ELECTRIC PROPERTY AND ANISOTROPY PROPERTIES AND
JP2003127494A (en) 2001-10-22 2003-05-08 Seiko Epson Corp Method and system for authenticating printed matter and print system
JP2003211475A (en) * 2002-01-24 2003-07-29 Nippon Zeon Co Ltd Method for manufacturing molded product for optics
US20030180563A1 (en) 2002-02-27 2003-09-25 Canon Kabushiki Kaisha Optical element and method of manufacturing the same, or laminated optical element and method of manufacturing the same
KR20050021016A (en) 2002-06-17 2005-03-04 메르크 파텐트 게엠베하 Composite material containing a core-covering-particle
EP1391973B1 (en) * 2002-08-05 2004-12-15 Alcatel Conduit glue bag, conduit glue strips and methods for installing cable in sewer pipe
JP2004295045A (en) * 2003-03-28 2004-10-21 Daicel Chem Ind Ltd Sheet for plasma display panel, and manufacturing method therefor
EP1727635A4 (en) * 2004-03-25 2011-10-05 Shehwa P & C Co Ltd Privacy securing film

Patent Citations (56)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3524789A (en) * 1967-08-15 1970-08-18 Minnesota Mining & Mfg Louvered transparent sheeting made by skiving
US3691140A (en) * 1970-03-09 1972-09-12 Spencer Ferguson Silver Acrylate copolymer microspheres
US3689346A (en) * 1970-09-29 1972-09-05 Rowland Dev Corp Method for producing retroreflective material
US3707416A (en) * 1970-10-30 1972-12-26 Minnesota Mining & Mfg Skewed billets for making louvered films
US4025673A (en) * 1972-04-13 1977-05-24 Reinnagel Richard E Method of forming copy resistant documents by forming an orderly array of fibers extending upward from a surface, coating the fibers and printing the coated fibers and the copy resistant document resulting from said method
US3857731A (en) * 1973-04-06 1974-12-31 Minnesota Mining & Mfg Acrylate microsphere-surfaced sheet material
US4097634A (en) * 1976-04-19 1978-06-27 Minnesota Mining And Manufacturing Company Thermoplastic resin molding of complex decorative relief
US4166152A (en) * 1977-08-17 1979-08-28 Minnesota Mining And Manufacturing Company Tacky polymeric microspheres
US4166152B1 (en) * 1977-08-17 1999-05-18 Minnesota Mining & Mfg Tacky polymeric microspheres
US4576850A (en) * 1978-07-20 1986-03-18 Minnesota Mining And Manufacturing Company Shaped plastic articles having replicated microstructure surfaces
US4244683A (en) * 1979-09-20 1981-01-13 Reflexite Corporation Apparatus for compression molding of retroreflective sheeting
US4601861A (en) * 1982-09-30 1986-07-22 Amerace Corporation Methods and apparatus for embossing a precision optical pattern in a resinous sheet or laminate
US4578298A (en) * 1983-07-25 1986-03-25 Kisokaseisangyou Co., Ltd. Composite films for protecting documents from being reproduced
US4536362A (en) * 1983-10-06 1985-08-20 Mobil Oil Corporation Method for producing longitudinally ribbed plastic film
US4495318A (en) * 1984-03-21 1985-01-22 International Cube Corporation Low tack microsphere glue
US4684593A (en) * 1984-05-08 1987-08-04 Secure Images Inc. Secure and self-verifiable image
US4788094A (en) * 1986-09-25 1988-11-29 Kabushiki Kaisha Tokai Rika Denki Seisakusho Light controlling sheet
US4984060A (en) * 1987-09-24 1991-01-08 Tadahiro Ohmi Semiconductor device wirings with hillocks
US5431644A (en) * 1987-12-23 1995-07-11 Minnesota Mining And Manufacturing Company Elastic strand construction
US4894060A (en) * 1988-01-11 1990-01-16 Minnesota Mining And Manufacturing Company Disposable diaper with improved hook fastener portion
US5045569A (en) * 1988-11-30 1991-09-03 Minnesota Mining And Manufacturing Company Hollow acrylate polymer microspheres
US5073457A (en) * 1988-12-01 1991-12-17 Minnesota Mining And Manufacturing Company Repositionable adhesive
US5175030A (en) * 1989-02-10 1992-12-29 Minnesota Mining And Manufacturing Company Microstructure-bearing composite plastic articles and method of making
US5183597A (en) * 1989-02-10 1993-02-02 Minnesota Mining And Manufacturing Company Method of molding microstructure bearing composite plastic articles
US5290068A (en) * 1989-07-05 1994-03-01 Nocopi International Ltd. Document security method and system
US5145544A (en) * 1989-08-01 1992-09-08 Minnesota Mining And Manufacturing Company Method for preparing tape having improved tear strength
US5389723A (en) * 1990-10-24 1995-02-14 Minnesota Mining And Manufacturing Company Transparent liquid absorbent materials for use as ink receptive layers
US5134198A (en) * 1990-10-24 1992-07-28 Minnesota Mining And Manufacturing Company Transparent liquid absorbent materials
US5254388A (en) * 1990-12-21 1993-10-19 Minnesota Mining And Manufacturing Company Light control film with reduced ghost images
US5301981A (en) * 1992-07-09 1994-04-12 Docusafe, Ltd. Copy preventing device and method
US5728449A (en) * 1992-08-14 1998-03-17 Emtec Magnetics Gmbh Anti-copy film layer for documents
US5795643A (en) * 1992-10-29 1998-08-18 Basf Magnetics Gmbh Anticopying film
US5571617A (en) * 1993-04-23 1996-11-05 Minnesota Mining And Manufacturing Company Pressure sensitive adhesive comprising tacky surface active microspheres
US6033516A (en) * 1993-07-17 2000-03-07 Emtec Magnetics Gmbh Process for the production of an anticopy film
US5993940A (en) * 1994-06-21 1999-11-30 3M Innovative Properties Company Composite used for light control of privacy
US5858139A (en) * 1994-06-21 1999-01-12 Minnesota Mining And Manufacturing Company Composite used for light control or privacy
US5663241A (en) * 1994-12-13 1997-09-02 Minnesota Mining And Manufacturing Company Removable pressure sensitive adhesive and article
US5851474A (en) * 1995-04-11 1998-12-22 Brunel University Of Uxbridge Injection molding with periodic forces to the material in the mold
US5714237A (en) * 1996-01-16 1998-02-03 Minnesota Mining Manufacturing Company Partially crosslinked microspheres
USRE37563E1 (en) * 1996-01-16 2002-02-26 3M Innovative Properties Company Partially crosslinked microspheres
US6297906B1 (en) * 1996-02-29 2001-10-02 3M Innovative Properties Company Light fixture containing optical film
US5824748A (en) * 1996-06-03 1998-10-20 Minnesota Mining And Manufacturing Company Composite pressure sensitive adhesive microspheres
US5756625A (en) * 1996-10-11 1998-05-26 Minnesota Mining And Manufacturing Company Stabilized adhesive microspheres
US6151526A (en) * 1998-04-29 2000-11-21 Advanced Bionics Corporation Ribbed electrode for cochlear stimulation
US6502935B1 (en) * 1999-04-30 2003-01-07 Felix Schoeller Jr. Foto-Und Spezialpapiere Gmbh & Co. Kg Ink-jet recording material comprising pigment layers
US6189934B1 (en) * 1999-05-10 2001-02-20 Larry W. Scruggs Anti-copy layer utilizing spectral fragments
US6514589B1 (en) * 2000-01-10 2003-02-04 Kolon Industries, Inc. Solar control film
US6367128B1 (en) * 2000-02-10 2002-04-09 3M Innovative Properties Company Self-mating reclosable mechanical fastener
US6398370B1 (en) * 2000-11-15 2002-06-04 3M Innovative Properties Company Light control device
US20040130788A1 (en) * 2001-02-02 2004-07-08 Kazuhiko Minami Optical filter and filter for touch panel type display
US6830798B2 (en) * 2001-07-10 2004-12-14 Raytech Composites, Inc. Continuous yarn laid wet friction material
US20030038924A1 (en) * 2001-08-24 2003-02-27 Veligdan James T. Prismatic optical display
US6806310B2 (en) * 2002-05-22 2004-10-19 Isp Investments Inc. Coated substrates for computer printers
US20050027068A1 (en) * 2002-05-22 2005-02-03 Isp Investments Inc. Terpolymer compositions for coating substrates used in computer printers
US20040202822A1 (en) * 2002-10-24 2004-10-14 Eastman Kodak Company Light management film with colorant receiving layer
US20060012059A1 (en) * 2004-07-14 2006-01-19 Ya-Chuan Cheng Method for manufacturing an optical sheet

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009096722A3 (en) * 2008-01-29 2009-11-05 Lg Chem, Ltd. Method for making privacy film
US20100295196A1 (en) * 2008-01-29 2010-11-25 Dong-Wook Lee Method for making privacy film
KR101091533B1 (en) 2008-01-29 2011-12-13 주식회사 엘지화학 Method for making privacy film
US8444885B2 (en) 2008-01-29 2013-05-21 Lg Chem, Ltd. Method for making privacy film
US20090237950A1 (en) * 2008-03-24 2009-09-24 I/O Controls Corporation Low glare lighting for a transit vehicle
US8210724B2 (en) 2008-03-24 2012-07-03 I/O Controls Corporation Low glare lighting for a transit vehicle
US8740425B2 (en) 2008-03-24 2014-06-03 I/O Controls Corporation Low glare lighting for a transit vehicle
WO2011035418A1 (en) * 2009-09-23 2011-03-31 Peter Dobrich Enhanced display
WO2018078493A3 (en) * 2016-10-28 2018-06-07 3M Innovative Properties Company Light control film with varied viewing angle
US10948734B2 (en) 2016-10-28 2021-03-16 3M Innovative Properties Company Light control film with varied viewing angle
DE102019006022B3 (en) 2019-08-21 2020-07-23 Sioptica Gmbh Optical element with variable transmission and screen with such an optical element

Also Published As

Publication number Publication date
WO2007047745A1 (en) 2007-04-26
US20070087186A1 (en) 2007-04-19
EP1948436A1 (en) 2008-07-30
KR20080050483A (en) 2008-06-05
JP2009511992A (en) 2009-03-19
CN101326042B (en) 2011-04-06
US7467873B2 (en) 2008-12-23
CN101287595B (en) 2011-12-21
JP2009511307A (en) 2009-03-19
EP1948436A4 (en) 2011-05-04
CN101287595A (en) 2008-10-15
EP1943075A1 (en) 2008-07-16
WO2007047544A1 (en) 2007-04-26
CN101326042A (en) 2008-12-17
KR20080058370A (en) 2008-06-25
EP1943075A4 (en) 2011-05-04

Similar Documents

Publication Publication Date Title
US20070084549A1 (en) Method of making a privacy film
DE60316196T2 (en) Manufacturing process for a film with a microstructured surface
EP2550146B1 (en) Extrusion die and method for making multiple stripe extrudate
US6521325B1 (en) Optically transmissive microembossed receptor media
KR101812822B1 (en) Composite layer
JP2013523485A (en) Composite layer
JP2004503404A (en) Polypropylene card structure
MXPA04001936A (en) Card sheet construction.
US7632566B2 (en) Paper for card, method for producing same and playing cards
JPH02251537A (en) Extrusion-cast film suitable for label surface material punchable to controlled depth
JP2011222513A (en) Laminated double-sided light guide plate
JP2011221532A (en) Double-sided light guide plate
CA2006007A1 (en) Waterproof recording material having ground patterns and its manufacturing method
JP2012098700A (en) Optical sheet with printed double-sided light guide plate
US20170123112A1 (en) Multilayered Press Stable Lens Array Film
JPH02890A (en) Label with sublimation transfer image
JP2021123031A (en) Recording medium, recording medium with separation member, decorative sheet, decorative sheet with separation member, decorative product and production method of decorative product

Legal Events

Date Code Title Description
AS Assignment

Owner name: 3M INNOVATIVE PROPERTIES COMPANY, MINNESOTA

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:GRAHAM, PAUL D.;CLARKE, GRAHAM M.;REEL/FRAME:018499/0006

Effective date: 20061013

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION