US20070264430A1 - High-strength, low-cost, recyclable backing for fabrics and method for making same - Google Patents

High-strength, low-cost, recyclable backing for fabrics and method for making same Download PDF

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Publication number
US20070264430A1
US20070264430A1 US11/879,595 US87959507A US2007264430A1 US 20070264430 A1 US20070264430 A1 US 20070264430A1 US 87959507 A US87959507 A US 87959507A US 2007264430 A1 US2007264430 A1 US 2007264430A1
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Prior art keywords
composition
density polyethylene
blend
backing material
low density
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US11/879,595
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Larry Mullinax
Shannon VanScoy
Daniel Hoyt
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Individual
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Individual
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/18Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • DTEXTILES; PAPER
    • D05SEWING; EMBROIDERING; TUFTING
    • D05CEMBROIDERING; TUFTING
    • D05C17/00Embroidered or tufted products; Base fabrics specially adapted for embroidered work; Inserts for producing surface irregularities in embroidered products
    • D05C17/02Tufted products
    • D05C17/023Tufted products characterised by the base fabric
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0063Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf
    • D06N7/0071Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf characterised by their backing, e.g. pre-coat, back coating, secondary backing, cushion backing
    • D06N7/0076Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf characterised by their backing, e.g. pre-coat, back coating, secondary backing, cushion backing the back coating or pre-coat being a thermoplastic material applied by, e.g. extrusion coating, powder coating or laminating a thermoplastic film
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00Polyalkenes
    • B32B2323/04Polyethylene
    • B32B2323/043HDPE, i.e. high density polyethylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00Polyalkenes
    • B32B2323/04Polyethylene
    • B32B2323/046LDPE, i.e. low density polyethylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00Polyalkenes
    • B32B2323/10Polypropylene
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00Macromolecular materials of the coating layers
    • D06N2203/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/042Polyolefin (co)polymers
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/06Properties of the materials having thermal properties
    • D06N2209/067Flame resistant, fire resistant
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/16Properties of the materials having other properties
    • D06N2209/165Odour absorbing, deodorizing ability
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/16Properties of the materials having other properties
    • D06N2209/1671Resistance to bacteria, mildew, mould, fungi
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/18Longitudinally sectional layer of three or more sections
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/23907Pile or nap type surface or component
    • Y10T428/23957Particular shape or structure of pile
    • Y10T428/23964U-, V-, or W-shaped or continuous strand, filamentary material
    • Y10T428/23971Continuous strand with adhesive bond to backing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/23907Pile or nap type surface or component
    • Y10T428/23979Particular backing structure or composition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/23907Pile or nap type surface or component
    • Y10T428/23986With coating, impregnation, or bond
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/23907Pile or nap type surface or component
    • Y10T428/23993Composition of pile or adhesive
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24355Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
    • Y10T428/24372Particulate matter
    • Y10T428/24405Polymer or resin [e.g., natural or synthetic rubber, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • Y10T428/24496Foamed or cellular component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24479Structurally defined web or sheet [e.g., overall dimension, etc.] including variation in thickness
    • Y10T428/24496Foamed or cellular component
    • Y10T428/24504Component comprises a polymer [e.g., rubber, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/10Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
    • Y10T442/102Woven scrim
    • Y10T442/15Including a foam layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/10Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
    • Y10T442/102Woven scrim
    • Y10T442/162Including a natural or synthetic rubber layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/10Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
    • Y10T442/184Nonwoven scrim
    • Y10T442/198Coated or impregnated
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2369Coating or impregnation improves elasticity, bendability, resiliency, flexibility, or shape retention of the fabric
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2762Coated or impregnated natural fiber fabric [e.g., cotton, wool, silk, linen, etc.]
    • Y10T442/277Coated or impregnated cellulosic fiber fabric
    • Y10T442/2779Coating or impregnation contains an acrylic polymer or copolymer [e.g., polyacrylonitrile, polyacrylic acid, etc.]

Definitions

  • This invention is generally directed to a backing material for fabrics and a method for making that backing. More specifically, the invention is directed to a backing for fabrics, such as carpets, rugs, mats, and any other textiles or products where it is necessary or desirable to bind any fibers or material to itself, each other, a backing, and/or a substrate.
  • fabrics that are tufted, non-tufted, woven, non-woven, knitted, pile knitted, or needlepoint.
  • weaving two strands of filament usually called the weft and the warp, generally makes woven textiles.
  • a third strand, the pile is included to make woven carpet.
  • the pile can be formed of free ends or of loops. Sometimes the loops of the pile are cut to form tufts. Tufts are also sometimes inserted individually rather than as part of the continuous weave, such as by stitching the tufts to a previously woven or non-woven fabric, or by needle-punching fibers into a woven or non-woven substrate.
  • Backings are applied to carpets, carpet tiles, moldable carpets, liners, covers, mats, moldable mats, rugs, moldable rugs, and other applications. Backings can be used to obtain fiber-lock performance and tuft-lock performance, give stability and structural integrity to the fabric, afford non-skid characteristics, and provide various levels of flame retardancy.
  • a structural layer, such as fiberglass, can be incorporated into the backing layer for further strength and dimensional stability.
  • hot melt requires the use of special compounding equipment, which increases operating costs.
  • hot melt requires the use of additives such as tackifiers and heat stabilizers which increase product cost and also degrade and impair product performance over time.
  • polyvinyl chloride Another material often used for backing for carpets is polyvinyl chloride. This material, however, as is well known, creates smoke and extremely toxic fumes upon combustion and is therefore undesirable for indoor use.
  • Some of these fabrics include swimming pool covers and primary backing for the tufting of carpet.
  • Some of these fabrics include mattress covers, non-woven primary backing for carpet tufting, and fabric for cured-in-place piping.
  • fabrics include tufted, non-tufted, woven, non-woven, knitted, pile knitted, or needlepoint fabrics.
  • the present invention provides a backing material made through the use of extrusion compounding, whereby the raw materials are compounded in-line rather than in a separate compounding operation.
  • extrusion compounding of high melt index, low-density polyethylene(s), polypropylene(s), high-density polyethylene(s), flexibilizer(s), and/or other additives, a backing material is created that offers more desirable strength, penetration, and flexibility combinations than backings made with other materials or methods.
  • the backing material of the present invention has superior bundle penetration/fiber-lock, tuft bind/stitch-lock, wet tuft bind, lamination strength, dimensional stability, flame and smoke test results, and moisture barrier test results, as compared to the backing materials known in the prior art.
  • the backing material is not aqueous based, which eliminates the need for drying ovens.
  • the backing material is insoluble; therefore it retains its strength when exposed to water and/or steam.
  • the backing material is nonabrasive and durable and provides lamination strength, flame retardancy, and smoke performance.
  • the backing material is of lower weight than comparable backing materials and requires less energy to produce.
  • extrusion compounding method allows for the efficient introduction of ingredients such as flame-retardants, anti-microbials, odor minimizers/eliminators, structural fillers, scent additives, and sun, salt, oil, gasoline, diesel, and petroleum protectants or inhibitors.
  • FIG. 1 is a diagram of the components in a method for applying a backing material that incorporates the features of the present invention to a fabric;
  • FIG. 2 is a cross-sectional view of a product produced using the method depicted in FIG. 1 ;
  • FIG. 3 is a flow chart of the method diagrammed in FIG. 1 ;
  • FIG. 4 is a diagram of the components of a method for applying a backing material that incorporates the features of the present invention to a fabric and a structural substrate;
  • FIG. 5 is a cross-sectional view of a product produced using the method depicted in FIG. 4 ;
  • FIG. 6 is a flow chart of the method diagrammed in FIG. 4 ;
  • FIG. 7 is a flow chart of another embodiment of the method diagrammed in FIG. 3 .
  • a backing material is a material applied to a fabric, such as carpets, carpet tiles, moldable carpets, liners, covers, mats, moldable mats, rugs, and other applications to obtain fiber-lock performance, tuft-lock performance, increased stability and structural integrity, non-skid characteristics, and/or flame retardancy.
  • the backing material of the preferred embodiment of the present invention has basic ingredients of high melt index low-density polyethylene (“LDPE”) and flexibilizers.
  • LDPE or high-density polyethylene (“HDPE”) can be used for increased strength and as a polymeric cost-reducing replacement for high melt index LDPE and/or flexibilizers.
  • HDPE although more expensive than LDPE, is stronger, more scratch resistant, more abrasion resistant, and more dimensionally stable than LDPE. The choice of which of these two materials to use depends on the requirements of the application and the cost of the available commodities.
  • composition of the backing material of the present invention is some combination of the following ingredients having the following properties:
  • LDPE having:
  • HDPE having a specific gravity greater than 0.92.
  • High melt index (MI greater than about 1,000) polypropylene (as needed to cross-link for higher strength);
  • Flexibilizers used to provide flexibility to the backing material, such as contained-geometry catalyzed low density polyethylene (specific gravity less than about 0.92), ethylene methyl acrylate, ethylene vinyl acetate, ethylene butyl modified polyethylenes, KRATON® rubber, and other thermoplastic elastomers or thermoplastic rubbers;
  • Fillers such as magnesium hydroxide (sometimes called brucite), Portland cement, and calcium oxide, to provide strength, flame retardancy, and aquasetting, or post-consumer and/or production recycled thermoplastics;
  • Stearic acid to create dispersants such as magnesium stearate or calcium stearate, to increase the ability of the flexibilizer to mix with the LDPE, HDPE, and polyethylene;
  • Additives such as flame retardants, anti-microbials, odor eliminators, odor minimizers, scents, and inhibitors to protect from sun, salt, oil, gasoline, diesel fuel, or other petroleum derivatives (as needed, depending on the specific application and requirements of the customer).
  • ingredients of the backing materials known in the prior art are comparatively inexpensive as compared to the ingredients of the backing materials known in the prior art.
  • These ingredients produce a backing material that is insoluble in water, and therefore one that will retain its strength when exposed to water or steam, providing an advantage over prior art backing materials that weaken when exposed to water or that contain thermally-degradable additives.
  • the backing material made of these materials is nonabrasive and durable and of lower weight than the backing materials known in the prior art, all criteria important to consumers.
  • the proportions of the ingredients to be used to create the backing material depend on the end use of the fabric to which the backing material will be applied.
  • a backing material for loop pile carpet is a compound of low molecular weight, high melt index LDPE, low specific gravity, average melt index LDPE or HDPE, high melt index polypropylene, flexibilizers, and anti-microbials.
  • the following table sets forth the preferred formulation and the range of concentrations of these ingredients: TABLE 1A Loop Pile Carpet Percentage Preferred Element Used Formulation 1. Low Mol.Wt., High MI LDPE 22-53% 40% 2. Low Specific Gravity, Avg. MI LDPE or 22-53% 8% HDPE 3. High MI Polypropylene 0-10% As needed 4. Flexibilizers 0-25% 12% 5. Anti-Microbials or other additives 0-2% As needed 6. Fillers 25-60% 40%
  • a backing material for cut pile carpet is a compound of low molecular weight, high melt index LDPE, low specific gravity, average melt index LDPE or HDPE, high melt index polypropylene, flexibilizers, anti-microbials, and fillers.
  • the following table sets forth the preferred formulation and the range of concentrations of these ingredients: TABLE 1B Cut Pile Carpet Percentage Preferred Element Used Formulation 1. Low Mol.Wt., High MI LDPE 15-38% 20% 2. Low Specific Gravity, Avg. MI LDPE or 15-60% 15% HDPE 3. High MI Polypropylene 0-10% As needed 4. Flexibilizers 0-25% 15% 5. Anti-Microbials or other additives 0-2% As needed 6. Fillers 25-60% 50%
  • a backing material for automotive or marine carpet is a compound of low molecular weight, high melt index LDPE, low specific gravity, average melt index LDPE or HDPE, high melt index polypropylene, flexibilizers, anti-microbials, and fillers.
  • the following table sets forth the preferred formulation and the range of concentrations of these ingredients: TABLE 1C Automotive or Marine Carpet Percentage Preferred Element Used Formulation 1. Low Mol.Wt., High MI LDPE 15-38% 20% 2. Low Specific Gravity, Avg. MI LDPE or 15-60% 15% HDPE 3. High MI Polypropylene 0-10% As needed 4. Flexibilizers 0-15% 15% 5. Anti-Microbials or other additives 0-2% As needed 6. Fillers 25-60% 50%
  • a backing material for washable rugs and mats, such as bathroom mats is a compound of low molecular weight, high melt index LDPE, low specific gravity, average molecular weight LDPE or HDPE, flexibilizers, antimicrobials, and fillers.
  • the following table sets forth the preferred formulation and the range of concentrations of these ingredients: TABLE 1D Washable Rugs and Mats Percentage Preferred Element Used Formulation 1. Low Mol. Wt., High MI LDPE 0-38% 20% 2. Low Specific Gravity, Avg. MI LDPE or 0-50% As Needed HDPE 3. High MI Polypropylene 0 0 4. Flexibilizers 0-100% 40% 5. Anti-Microbials or other additives 0-2% As Needed 6. Fillers 0-60% 40%
  • a backing material for non-skid absorbent mats which are generally made of an absorbent non-woven material, is a compound of LDPE or HDPE, flexibilizers, anti-microbials, and fillers.
  • the following table sets forth the preferred formulation and the range of concentrations of these ingredients: TABLE 1E Non-skid Absorbent Mats Percentage Preferred Element Used Formulation 1. Low Mol. Wt., High MI LDPE 0 0 2. Low Specific Gravity, Avg. MI LDPE or 0-50% 15% HDPE 3. High MI Polypropylene 0 0 4. Flexibilizers 0-100% 35% 5. Anti-Microbials or other additives 0-2% As Needed 6. Fillers 0-70% 50%
  • the backing material for woven polypropylene fabrics is a compound of LDPE or HDPE, high melt index, low-density and/or high-density polyethylene, flexibilizers, antimicrobials, and fillers.
  • the following table sets forth the preferred formulation and the range of concentrations of these ingredients: TABLE 1F Woven Polypropylene Fabrics Percentage Preferred Element Used Formulation 1. Low Mol. Wt., High MI LDPE 0-25% As Needed 2. Low Specific Gravity, Avg. MI LDPE or 0-75% 50% HDPE 3. High MI Polypropylene 0 0 4. Flexibilizers 0-50% 25% 5. Anti-Microbials or other additives 0-2% As Needed 6. Fillers 0-50% 25%
  • a backing material for non-woven fabrics is a compound of LDPE or HPDE, high melt index polypropylene, flexibilizers, antimicrobials, and fillers.
  • the following table sets forth the preferred formulation and the range of concentrations of these ingredients: TABLE 1G Non-Woven Fabrics Percentage Preferred Element Used Formulation 1. Low Mol. Wt., High MI LDPE 0 0 2. Low Specific Gravity, Avg. MI LDPE or 0-100% 30% HDPE 3. High MI Polypropylene 0-25% As Needed 4. Flexibilizers 0-100% 70% 5. Anti-Microbials or other additives 0-2% As Needed 6. Fillers 0-50% As Needed
  • low molecular weight, high melt index LDPE provides superior bundle penetration when used with fabrics having a pile, such as carpet.
  • Low molecular weight, high melt index LDPE has not been used conventionally in extruders, and is difficult to extrude.
  • the novel combination of low molecular weight, high melt index LDPE and a flexibilizer has been found to extrudable in a co-rotating twin-screw extruder.
  • the preferred flexibilizer is contained-geometry, catalyzed LDPE. This material is available in wide spec and accordingly can be obtained for lower cost than other flexibilizers, although more expensive, virgin material can be used also. Other flexibilizers, as described above, are available but are generally more expensive.
  • the backing material of the present invention is preferably made by metering the ingredients to a starve-fed co-rotating twin-screw extruder.
  • Co-rotating twin screw extruders can operate at higher processing rotational speeds than counter-rotating twin screw extruders or single screw extruders and accordingly are more efficient and versatile. Additionally, the use of co-rotating screws causes higher shear at the mixing point, allowing for processing at lower pressure and temperature, which is easier and more energy efficient than the methods known in the prior art.
  • in-line, extrusion compounding produces a backing material that has more desirable strength, penetration, and flexibility than backing materials known in the prior art. Additionally, in-line, extrusion compounding of the ingredients described above creates a backing material with superior bundle penetration/fiber-lock, tuft bind/stitch-lock, wet tuft bind, lamination strength, dimensional stability, flame and smoke test results, and moisture barrier test results as compared to the backing materials known in the prior art.
  • Mixing in the extruder also allows for the incorporation of ingredients such as fillers, flexibilizers, and performance enhancers such as anti-microbials.
  • ingredients such as fillers, flexibilizers, and performance enhancers such as anti-microbials.
  • flame retardants including but not limited to magnesium hydroxide
  • Numerous antimicrobial agents as are well known in the art can be added to the extruder mixture.
  • Scent of any desired type can be added to the extruder mixture.
  • Portland cement or other inorganic material can be added to the extruder mixture to maintain or improve strength of the backing material.
  • Stearic acid if added to the extruder mixture, will react and create dispersants such as magnesium stearate or calcium stearate.
  • Photoresistant chemicals are well known in the art and can be added to the extruder mixture. Odor minimizers and odor eliminators are well known in the art and can be added to the extruder mixture. Additives to protect against sun, salt or against petroleum-derived materials such as gasoline, oil, diesel fuel, or other petrofuels or petrochemicals are well known in the art and can be added to the extruder mixture.
  • in-line extrusion compounding of the ingredients described above eliminates the need for tackifiers, heat stabilizers, or other impurities required by the methods known in the prior art.
  • Preferred processing temperatures for the step of mixing the ingredients in the extruder are dependent upon the range of temperatures at which the polymers stay stable and the range of temperatures that provide the best performance of the final product.
  • the following table lists these processing temperature ranges along with the preferred processing temperature for the present invention: TABLE 4 Processing Temperature Ranges (Degrees F.) Polymer Preferred Method Stability Product Performance Operating 1. Mixing 200-600 250-500 325-425 2. Pumping 200-600 325-500 375-450 3. Coating 200-600 325-500 375-450 4. Fabric Pre-Heat 75-300 120-240 150-200 5. Cooling 32-175 70-150 75-110
  • formulations can be changed while running, saving processing time by reducing or eliminating set up time.
  • FIG. 1 shows the components of the method for applying the backing material 2 , which incorporates the features of the present invention, to the fabric 4 such as a carpet.
  • FIG. 2 shows a product produced using the method depicted in FIG. 1 .
  • the composite 22 shown in FIG. 2 is made up of fabric 4 and backing material 2 .
  • FIG. 3 is a flow chart of the method.
  • a roll 6 of fabric 4 is mounted on a let off 8 (step 201 ).
  • the fabric 4 is fed to the in-running nip point 10 of a pair of pressurized rollers 12 , 14 (step 203 ).
  • Roller 14 is chilled.
  • the backing material 2 having been mixed in a twin-screw extruder 16 and heated above its melting point (step 205 ), is pushed through a die 18 and into the nip point 10 formed by the rollers 12 , 14 (step 207 ).
  • the pressure at nip point 10 is preferably sufficient to cause the backing material 2 to adhere to the fabric 4 .
  • the pressure at nip point 10 is preferably sufficient to cause the backing material to penetrate the bundles of the pile and provide fiberlock in the fabric-backing-material composite 22 .
  • this pressure is above 100 pounds per linear inch and is adjusted for different types of fabrics.
  • Directional roller 20 pulls the fabric 4 around roller 14 , keeping the fabric 4 and backing material 2 in contact with the chilled roller 14 for as long as feasible, in order to harden the backing material 2 (step 209 ).
  • the now married fabric-and-backing-material composite 22 then feeds through directional rollers 24 , 26 , 28 , for final inspection (step 211 ) before shipping, to roll up 30 , where it is rolled into shipping roll 32 (step 213 ).
  • FIG. 4 shows the components of the method for applying a backing material that incorporates the features of the present invention, along with a structural substrate, to a fabric such as a carpet.
  • the structural substrate imparts greater strength and dimensional stability to the fabric.
  • the structural substrate can be woven or non-woven and can be made of fiberglass, basalt, polypropylenes, polyolefins, polymerized non-olefins, polyamides, polyesters, nylon, or any other threads, yarns, fibers, filaments, or meshes, or combinations of any of these materials.
  • the structural substrate can also be a preformed foam, such as a thermoplastic material or a thermoset material, and can be a chemically-blown foam or a mechanically-blown foam, either stabilized or unstabilized.
  • FIG. 5 is a cross-sectional view of a product made by the method in FIG. 4 .
  • the composite 124 is made up of fabric 104 , such as cut pile carpet, backing material 118 , and a structural substrate 110 .
  • FIG. 6 is a flow chart of the method.
  • a roll 102 of fabric 104 is mounted on a first let off 106 (step 301 ).
  • a roll 108 of structural substrate 110 is mounted on a second let off 112 (step 303 ).
  • a compensator 138 is used to keep a constant tension on the structural substrate 110 .
  • a compensator or “dancer” is conventional and accordingly will not be further described. Both the fabric 104 and the substrate 110 are fed to the in-running nip point 112 of a pair of rollers 114 , 116 (step 305 ).
  • the backing material 118 having been mixed in a twin-screw extruder 120 and heated above its melting point (step 307 ), is pushed through a die 122 (step 309 ) and into the nip point 112 formed by the rollers 114 , 116 , between fabric 104 and substrate 110 .
  • the pressure of pressurized rollers 114 , 116 marries the fabric 104 to the substrate 110 , as backing material 118 penetrates into both fabric 104 and substrate 110 .
  • Roller 116 is chilled.
  • Directional roller 123 pulls the now-married fabric-backing-material-substrate composite 124 around roller 116 , keeping the fabric-backing-material-substrate composite 124 in contact with chilled roller 116 for as long as feasible, in order to harden the backing material 118 (step 311 ).
  • the composite 124 feeds via directional rollers 130 , 132 , 134 for inspection (step 313 ) then to a roll up 126 for formation into a shipping roll 128 (step 315 ).
  • chilled roller 14 or 116 can have patterns projecting from its surface. As the fabric and backing material is pressed between roller 12 and chilled roller 14 or between roller 114 and chilled roller 116 , the pattern is pressed into the surface of the backing material.
  • the pattern can be a knurl, design, texture, or other pattern.
  • the pattern can provide reduced-skid or non-skid properties to the fabric, or enhanced adhesion, useful in the case of carpets and some other applications.
  • the pattern can also be an aesthetic design, texture, or pattern, or can display a logo, trademark, or other identifying matter.
  • the fabric is preheated at preheat station 136 before being fed to the in-running nip point 10 or 112 .
  • the preheat temperature is chosen based on the weight, construction, and type of fabric, but is preferably between 120° F. and 275° F.
  • the preheat step can be accomplished by contact, such as rolling the fabric over a contact roll or a contact plate heated by steam, oil, or electricity, or by a noncontact method such as infrared radiative heat or forced air.
  • the backing material of the present invention can be made, solidified, stored in bulk, and later re-melted and applied to a fabric. This process is diagrammed in FIG. 7 . Steps 201 through 205 and 209 through 213 are identical to the steps described in connection with FIG. 3 .
  • the backing material is again preferably made by mixing the ingredients described above in a co-rotating twin-screw extruder and heating those ingredients above the melting point of the mixture. The backing material is then forced through a die and cooled until it solidifies (step 401 ). The backing material can then be stored in bulk until needed.
  • the backing material can be cooled and stored in a drum.
  • a conventional drum melter is used to re-melt the backing material (step 403 ) and to pump the backing material either directly to a die or to a standard extruder for delivery to a die (step 405 ), for application to a fabric as described above.
  • the more expensive twin-screw extruder described above is not needed for the application step, since the backing material has already been made and only needs to be re-melted and applied.
  • the backing material of the present invention can be made, solidified into blocks, billets, or pellets, stored, and later re-melted and applied to a fabric.
  • the backing material is again preferably made by mixing the ingredients described above in a co-rotating twin-screw extruder and heating those ingredients above the melting point of the mixture. The backing material is then forced through a die, cooled until it solidifies, and then processed into blocks, billets or pellets (step 401 ). Equipment associated with processing into blocks, billets, and pellets is conventional and accordingly need not be further described. The backing material can then be stored until needed.
  • the pellets can be introduced into a standard, single-screw extruder for re-melting (step 403 ) and extrusion through a die to a fabric (step 404 ).
  • Blocks, billets, or pellets can be liquefied in a heated mixer or other suitable melting device (step 403 ) and pumped either directly to a die or to a standard single screw extruder for delivery to a die (step 404 ), for application to a fabric.

Abstract

A backing material is made of low-density and/or high-density polyethylene(s) and/or a flexibilizer to provide high-strength, low-cost, and recyclable backing material for fabrics. The backing material can incorporate polypropylene(s), additional flexibilizers, fillers, flame-retardants, anti-microbials, odor minimizers/eliminators, scent, and protectants for further desired properties.

Description

    CROSS-REFERENCE TO RELATED APPLICATION
  • This application claims the benefit of States provisional patent application Ser. No. 60/481,318, filed on Sep. 1, 2003.
  • FIELD OF THE INVENTION
  • This invention is generally directed to a backing material for fabrics and a method for making that backing. More specifically, the invention is directed to a backing for fabrics, such as carpets, rugs, mats, and any other textiles or products where it is necessary or desirable to bind any fibers or material to itself, each other, a backing, and/or a substrate. This includes fabrics that are tufted, non-tufted, woven, non-woven, knitted, pile knitted, or needlepoint.
  • BACKGROUND OF THE INVENTION
  • Weaving two strands of filament, usually called the weft and the warp, generally makes woven textiles. A third strand, the pile, is included to make woven carpet. The pile can be formed of free ends or of loops. Sometimes the loops of the pile are cut to form tufts. Tufts are also sometimes inserted individually rather than as part of the continuous weave, such as by stitching the tufts to a previously woven or non-woven fabric, or by needle-punching fibers into a woven or non-woven substrate.
  • For many woven and non-woven fabrics, it is desirable to apply a backing to the fabric. Backings are applied to carpets, carpet tiles, moldable carpets, liners, covers, mats, moldable mats, rugs, moldable rugs, and other applications. Backings can be used to obtain fiber-lock performance and tuft-lock performance, give stability and structural integrity to the fabric, afford non-skid characteristics, and provide various levels of flame retardancy. A structural layer, such as fiberglass, can be incorporated into the backing layer for further strength and dimensional stability.
  • Traditionally, latex or hot melt adhesives have been used for backing of fabrics and especially for backing of carpets, mats, and rugs. Both adhesives provide strength, penetration, and flexibility; key criteria in the selection of a backing material. Both adhesives, however, have drawbacks.
  • Conventionally-used latex requires the use of high-energy drying ovens, which increases operating costs. In addition, latex-based products lose strength when subjected to water and regain only a portion of their strength when dry. In addition to these drawbacks generally associated with latex, there can be further product-specific drawbacks. For example, the existing products on the market for the washable mat and rug business use a latex backing, but sacrifice fiber-lock and tuft-lock performance in order to achieve the desired non-skid and machine-wash properties.
  • Conventionally-used hot melt applications require the use of special compounding equipment, which increases operating costs. In addition, hot melt requires the use of additives such as tackifiers and heat stabilizers which increase product cost and also degrade and impair product performance over time.
  • Another material often used for backing for carpets is polyvinyl chloride. This material, however, as is well known, creates smoke and extremely toxic fumes upon combustion and is therefore undesirable for indoor use.
  • Accordingly, a need exists for a backing material that is strong, durable, inexpensive, recyclable, able to be applied to fabrics without the use of drying ovens, able to eliminate the need for undesirable processing additives, and able to incorporate custom additives without product degradation or impairing performance as needed for specific product enhancements. The present invention meets this need. Other features and advantages of the present invention will become clear upon a reading of the attached specification.
  • SUMMARY OF THE INVENTION
  • It is a general object of the present invention to present a backing material for use on fabrics that is strong, inexpensive, and easy and energy efficient to produce and apply.
  • It is a further object of the present invention to present a backing material for woven fabrics that is strong, inexpensive, flame retardant, and easy and energy efficient to produce and apply. Some of these fabrics include swimming pool covers and primary backing for the tufting of carpet.
  • It is a further object of the present invention to present a backing material for non-woven fabrics that is strong, inexpensive, flame retardant, and easy and energy efficient to produce and apply. Some of these fabrics include mattress covers, non-woven primary backing for carpet tufting, and fabric for cured-in-place piping.
  • It is yet a further object of the present invention to present a backing material for fabrics where it is necessary or desirable to bind any fibers or material to itself, each other, another backing, and/or a substrate. These fabrics include tufted, non-tufted, woven, non-woven, knitted, pile knitted, or needlepoint fabrics.
  • It is yet a further object of the present invention to present a backing material that is readily recyclable.
  • It is yet a further object of the present invention to present a backing material that can incorporate performance additives and fillers.
  • It is yet a further object of the present invention to present a method for making such a backing material.
  • Briefly, and in accordance with the foregoing, the present invention provides a backing material made through the use of extrusion compounding, whereby the raw materials are compounded in-line rather than in a separate compounding operation. Through the use of extrusion compounding of high melt index, low-density polyethylene(s), polypropylene(s), high-density polyethylene(s), flexibilizer(s), and/or other additives, a backing material is created that offers more desirable strength, penetration, and flexibility combinations than backings made with other materials or methods.
  • The backing material of the present invention has superior bundle penetration/fiber-lock, tuft bind/stitch-lock, wet tuft bind, lamination strength, dimensional stability, flame and smoke test results, and moisture barrier test results, as compared to the backing materials known in the prior art.
  • Additionally, because extrusion compounding is utilized rather than a method requiring tackifiers, heat stabilizers, or the addition of other impurities, unused material and post-consumer waste is easily recyclable by grinding and reintroduction of the unused material into the extrusion compounding method. The backing material is not aqueous based, which eliminates the need for drying ovens. The backing material is insoluble; therefore it retains its strength when exposed to water and/or steam. The backing material is nonabrasive and durable and provides lamination strength, flame retardancy, and smoke performance. The backing material is of lower weight than comparable backing materials and requires less energy to produce. The combination of this method and the ingredients used as set forth herein eliminates the incorporation of thermally degradable ingredients as well as those ingredients that weaken when subjected to moisture or water. In addition, the extrusion compounding method allows for the efficient introduction of ingredients such as flame-retardants, anti-microbials, odor minimizers/eliminators, structural fillers, scent additives, and sun, salt, oil, gasoline, diesel, and petroleum protectants or inhibitors.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • The organization and manner of the structure and operation of the invention, together with further objects and advantages thereof, may best be understood by reference to the following description, taken in connection with the accompanying drawings, wherein like reference numerals identify like elements in which:
  • FIG. 1 is a diagram of the components in a method for applying a backing material that incorporates the features of the present invention to a fabric;
  • FIG. 2 is a cross-sectional view of a product produced using the method depicted in FIG. 1;
  • FIG. 3 is a flow chart of the method diagrammed in FIG. 1;
  • FIG. 4 is a diagram of the components of a method for applying a backing material that incorporates the features of the present invention to a fabric and a structural substrate;
  • FIG. 5 is a cross-sectional view of a product produced using the method depicted in FIG. 4;
  • FIG. 6 is a flow chart of the method diagrammed in FIG. 4; and
  • FIG. 7 is a flow chart of another embodiment of the method diagrammed in FIG. 3.
  • DETAILED DESCRIPTION
  • While the invention may be susceptible to embodiment in different forms, there is shown in the drawings, and herein will be described in detail, specific embodiments with the understanding that the present disclosure is to be considered an exemplification of the principles of the invention, and is not intended to limit the invention to that as illustrated and described herein.
  • A backing material is a material applied to a fabric, such as carpets, carpet tiles, moldable carpets, liners, covers, mats, moldable mats, rugs, and other applications to obtain fiber-lock performance, tuft-lock performance, increased stability and structural integrity, non-skid characteristics, and/or flame retardancy. The backing material of the preferred embodiment of the present invention has basic ingredients of high melt index low-density polyethylene (“LDPE”) and flexibilizers. Other LDPE or high-density polyethylene (“HDPE”) can be used for increased strength and as a polymeric cost-reducing replacement for high melt index LDPE and/or flexibilizers. HDPE, although more expensive than LDPE, is stronger, more scratch resistant, more abrasion resistant, and more dimensionally stable than LDPE. The choice of which of these two materials to use depends on the requirements of the application and the cost of the available commodities.
  • The general composition of the backing material of the present invention is some combination of the following ingredients having the following properties:
  • 1. LDPE having:
      • i. A low molecular weight, i.e. number average molecular weight, Mn, less than about 10,000, or weight average molecular weight, Mw, less than about 35,000, and/or
      • ii. High melt indices (MI greater than about 1,000); and/or
      • iii. Specific gravity less than or equal to 0.92.
  • 2. HDPE having a specific gravity greater than 0.92.
  • 3. High melt index (MI greater than about 1,000) polypropylene (as needed to cross-link for higher strength);
  • 4. Flexibilizers, used to provide flexibility to the backing material, such as contained-geometry catalyzed low density polyethylene (specific gravity less than about 0.92), ethylene methyl acrylate, ethylene vinyl acetate, ethylene butyl modified polyethylenes, KRATON® rubber, and other thermoplastic elastomers or thermoplastic rubbers;
  • 5. Fillers, such as magnesium hydroxide (sometimes called brucite), Portland cement, and calcium oxide, to provide strength, flame retardancy, and aquasetting, or post-consumer and/or production recycled thermoplastics;
  • 6. Stearic acid to create dispersants, such as magnesium stearate or calcium stearate, to increase the ability of the flexibilizer to mix with the LDPE, HDPE, and polyethylene;
  • 7. Additives such as flame retardants, anti-microbials, odor eliminators, odor minimizers, scents, and inhibitors to protect from sun, salt, oil, gasoline, diesel fuel, or other petroleum derivatives (as needed, depending on the specific application and requirements of the customer).
  • The use of these ingredients is comparatively inexpensive as compared to the ingredients of the backing materials known in the prior art. These ingredients produce a backing material that is insoluble in water, and therefore one that will retain its strength when exposed to water or steam, providing an advantage over prior art backing materials that weaken when exposed to water or that contain thermally-degradable additives. The backing material made of these materials is nonabrasive and durable and of lower weight than the backing materials known in the prior art, all criteria important to consumers.
  • The proportions of the ingredients to be used to create the backing material depend on the end use of the fabric to which the backing material will be applied.
  • A backing material for loop pile carpet is a compound of low molecular weight, high melt index LDPE, low specific gravity, average melt index LDPE or HDPE, high melt index polypropylene, flexibilizers, and anti-microbials. The following table sets forth the preferred formulation and the range of concentrations of these ingredients:
    TABLE 1A
    Loop Pile Carpet
    Percentage Preferred
    Element Used Formulation
    1. Low Mol.Wt., High MI LDPE 22-53% 40%
    2. Low Specific Gravity, Avg. MI LDPE or 22-53%  8%
       HDPE
    3. High MI Polypropylene  0-10% As needed
    4. Flexibilizers  0-25% 12%
    5. Anti-Microbials or other additives 0-2% As needed
    6. Fillers 25-60% 40%
  • A backing material for cut pile carpet is a compound of low molecular weight, high melt index LDPE, low specific gravity, average melt index LDPE or HDPE, high melt index polypropylene, flexibilizers, anti-microbials, and fillers. The following table sets forth the preferred formulation and the range of concentrations of these ingredients:
    TABLE 1B
    Cut Pile Carpet
    Percentage Preferred
    Element Used Formulation
    1. Low Mol.Wt., High MI LDPE 15-38% 20%
    2. Low Specific Gravity, Avg. MI LDPE or 15-60% 15%
       HDPE
    3. High MI Polypropylene  0-10% As needed
    4. Flexibilizers  0-25% 15%
    5. Anti-Microbials or other additives 0-2% As needed
    6. Fillers 25-60% 50%
  • A backing material for automotive or marine carpet is a compound of low molecular weight, high melt index LDPE, low specific gravity, average melt index LDPE or HDPE, high melt index polypropylene, flexibilizers, anti-microbials, and fillers. The following table sets forth the preferred formulation and the range of concentrations of these ingredients:
    TABLE 1C
    Automotive or Marine Carpet
    Percentage Preferred
    Element Used Formulation
    1. Low Mol.Wt., High MI LDPE 15-38% 20%
    2. Low Specific Gravity, Avg. MI LDPE or 15-60% 15%
       HDPE
    3. High MI Polypropylene  0-10% As needed
    4. Flexibilizers  0-15% 15%
    5. Anti-Microbials or other additives 0-2% As needed
    6. Fillers 25-60% 50%
  • A backing material for washable rugs and mats, such as bathroom mats, is a compound of low molecular weight, high melt index LDPE, low specific gravity, average molecular weight LDPE or HDPE, flexibilizers, antimicrobials, and fillers. The following table sets forth the preferred formulation and the range of concentrations of these ingredients:
    TABLE 1D
    Washable Rugs and Mats
    Percentage Preferred
    Element Used Formulation
    1. Low Mol. Wt., High MI LDPE 0-38% 20%
    2. Low Specific Gravity, Avg. MI LDPE or 0-50% As Needed
       HDPE
    3. High MI Polypropylene 0 0
    4. Flexibilizers 0-100% 40%
    5. Anti-Microbials or other additives 0-2% As Needed
    6. Fillers 0-60% 40%
  • A backing material for non-skid absorbent mats, which are generally made of an absorbent non-woven material, is a compound of LDPE or HDPE, flexibilizers, anti-microbials, and fillers. The following table sets forth the preferred formulation and the range of concentrations of these ingredients:
    TABLE 1E
    Non-skid Absorbent Mats
    Percentage Preferred
    Element Used Formulation
    1. Low Mol. Wt., High MI LDPE 0 0
    2. Low Specific Gravity, Avg. MI LDPE or 0-50% 15%
       HDPE
    3. High MI Polypropylene 0 0
    4. Flexibilizers 0-100% 35%
    5. Anti-Microbials or other additives 0-2% As Needed
    6. Fillers 0-70% 50%
  • The backing material for woven polypropylene fabrics is a compound of LDPE or HDPE, high melt index, low-density and/or high-density polyethylene, flexibilizers, antimicrobials, and fillers. The following table sets forth the preferred formulation and the range of concentrations of these ingredients:
    TABLE 1F
    Woven Polypropylene Fabrics
    Percentage Preferred
    Element Used Formulation
    1. Low Mol. Wt., High MI LDPE 0-25% As Needed
    2. Low Specific Gravity, Avg. MI LDPE or 0-75% 50%
       HDPE
    3. High MI Polypropylene 0 0
    4. Flexibilizers 0-50% 25%
    5. Anti-Microbials or other additives 0-2% As Needed
    6. Fillers 0-50% 25%
  • A backing material for non-woven fabrics is a compound of LDPE or HPDE, high melt index polypropylene, flexibilizers, antimicrobials, and fillers. The following table sets forth the preferred formulation and the range of concentrations of these ingredients:
    TABLE 1G
    Non-Woven Fabrics
    Percentage Preferred
    Element Used Formulation
    1. Low Mol. Wt., High MI LDPE 0 0
    2. Low Specific Gravity, Avg. MI LDPE or 0-100% 30%
       HDPE
    3. High MI Polypropylene 0-25% As Needed
    4. Flexibilizers 0-100% 70%
    5. Anti-Microbials or other additives 0-2% As Needed
    6. Fillers 0-50% As Needed
  • We have discovered that low molecular weight, high melt index LDPE provides superior bundle penetration when used with fabrics having a pile, such as carpet. Low molecular weight, high melt index LDPE has not been used conventionally in extruders, and is difficult to extrude. However, the novel combination of low molecular weight, high melt index LDPE and a flexibilizer has been found to extrudable in a co-rotating twin-screw extruder.
  • The preferred flexibilizer is contained-geometry, catalyzed LDPE. This material is available in wide spec and accordingly can be obtained for lower cost than other flexibilizers, although more expensive, virgin material can be used also. Other flexibilizers, as described above, are available but are generally more expensive.
  • Accordingly, the backing material of the present invention is preferably made by metering the ingredients to a starve-fed co-rotating twin-screw extruder. Co-rotating twin screw extruders can operate at higher processing rotational speeds than counter-rotating twin screw extruders or single screw extruders and accordingly are more efficient and versatile. Additionally, the use of co-rotating screws causes higher shear at the mixing point, allowing for processing at lower pressure and temperature, which is easier and more energy efficient than the methods known in the prior art.
  • The use of in-line, extrusion compounding produces a backing material that has more desirable strength, penetration, and flexibility than backing materials known in the prior art. Additionally, in-line, extrusion compounding of the ingredients described above creates a backing material with superior bundle penetration/fiber-lock, tuft bind/stitch-lock, wet tuft bind, lamination strength, dimensional stability, flame and smoke test results, and moisture barrier test results as compared to the backing materials known in the prior art.
  • Mixing in the extruder, instead of in a separate operation, also allows for the incorporation of ingredients such as fillers, flexibilizers, and performance enhancers such as anti-microbials. For example, flame retardants, including but not limited to magnesium hydroxide, can be added to the extruder mixture. Numerous antimicrobial agents as are well known in the art can be added to the extruder mixture. Scent of any desired type can be added to the extruder mixture. Portland cement or other inorganic material can be added to the extruder mixture to maintain or improve strength of the backing material. Stearic acid, if added to the extruder mixture, will react and create dispersants such as magnesium stearate or calcium stearate. Photoresistant chemicals are well known in the art and can be added to the extruder mixture. Odor minimizers and odor eliminators are well known in the art and can be added to the extruder mixture. Additives to protect against sun, salt or against petroleum-derived materials such as gasoline, oil, diesel fuel, or other petrofuels or petrochemicals are well known in the art and can be added to the extruder mixture.
  • Moreover, in-line extrusion compounding of the ingredients described above eliminates the need for tackifiers, heat stabilizers, or other impurities required by the methods known in the prior art. Unused backing material, whether industrial surplus or post-consumer waste is easily recyclable by grinding the unused backing material and reintroducing it into the extruder.
  • Preferred processing temperatures for the step of mixing the ingredients in the extruder are dependent upon the range of temperatures at which the polymers stay stable and the range of temperatures that provide the best performance of the final product. The following table lists these processing temperature ranges along with the preferred processing temperature for the present invention:
    TABLE 4
    Processing Temperature Ranges (Degrees F.)
    Polymer Preferred
    Method Stability Product Performance Operating
    1. Mixing 200-600 250-500 325-425
    2. Pumping 200-600 325-500 375-450
    3. Coating 200-600 325-500 375-450
    4. Fabric Pre-Heat  75-300 120-240 150-200
    5. Cooling  32-175  70-150  75-110
  • By using extrusion, formulations can be changed while running, saving processing time by reducing or eliminating set up time.
  • FIG. 1 shows the components of the method for applying the backing material 2, which incorporates the features of the present invention, to the fabric 4 such as a carpet. FIG. 2 shows a product produced using the method depicted in FIG. 1. The composite 22 shown in FIG. 2 is made up of fabric 4 and backing material 2. FIG. 3 is a flow chart of the method.
  • A roll 6 of fabric 4 is mounted on a let off 8 (step 201). The fabric 4 is fed to the in-running nip point 10 of a pair of pressurized rollers 12, 14 (step 203). Roller 14 is chilled. The backing material 2, having been mixed in a twin-screw extruder 16 and heated above its melting point (step 205), is pushed through a die 18 and into the nip point 10 formed by the rollers 12, 14 (step 207). The pressure at nip point 10 is preferably sufficient to cause the backing material 2 to adhere to the fabric 4. Additionally, if the fabric has a pile, the pressure at nip point 10 is preferably sufficient to cause the backing material to penetrate the bundles of the pile and provide fiberlock in the fabric-backing-material composite 22. In the preferred embodiment, this pressure is above 100 pounds per linear inch and is adjusted for different types of fabrics.
  • Directional roller 20 pulls the fabric 4 around roller 14, keeping the fabric 4 and backing material 2 in contact with the chilled roller 14 for as long as feasible, in order to harden the backing material 2 (step 209). The now married fabric-and-backing-material composite 22 then feeds through directional rollers 24, 26, 28, for final inspection (step 211) before shipping, to roll up 30, where it is rolled into shipping roll 32 (step 213).
  • FIG. 4 shows the components of the method for applying a backing material that incorporates the features of the present invention, along with a structural substrate, to a fabric such as a carpet. The structural substrate imparts greater strength and dimensional stability to the fabric. The structural substrate can be woven or non-woven and can be made of fiberglass, basalt, polypropylenes, polyolefins, polymerized non-olefins, polyamides, polyesters, nylon, or any other threads, yarns, fibers, filaments, or meshes, or combinations of any of these materials. The structural substrate can also be a preformed foam, such as a thermoplastic material or a thermoset material, and can be a chemically-blown foam or a mechanically-blown foam, either stabilized or unstabilized. FIG. 5 is a cross-sectional view of a product made by the method in FIG. 4. The composite 124 is made up of fabric 104, such as cut pile carpet, backing material 118, and a structural substrate 110. FIG. 6 is a flow chart of the method.
  • To apply the backing material 118 of the present invention to the fabric 104, along with the structural substrate 110, a roll 102 of fabric 104 is mounted on a first let off 106 (step 301). A roll 108 of structural substrate 110 is mounted on a second let off 112 (step 303). A compensator 138 is used to keep a constant tension on the structural substrate 110. A compensator or “dancer” is conventional and accordingly will not be further described. Both the fabric 104 and the substrate 110 are fed to the in-running nip point 112 of a pair of rollers 114, 116 (step 305).
  • The backing material 118, having been mixed in a twin-screw extruder 120 and heated above its melting point (step 307), is pushed through a die 122 (step 309) and into the nip point 112 formed by the rollers 114, 116, between fabric 104 and substrate 110. The pressure of pressurized rollers 114, 116 marries the fabric 104 to the substrate 110, as backing material 118 penetrates into both fabric 104 and substrate 110. Roller 116 is chilled. Directional roller 123 pulls the now-married fabric-backing-material-substrate composite 124 around roller 116, keeping the fabric-backing-material-substrate composite 124 in contact with chilled roller 116 for as long as feasible, in order to harden the backing material 118 (step 311). The composite 124 feeds via directional rollers 130, 132, 134 for inspection (step 313) then to a roll up 126 for formation into a shipping roll 128 (step 315).
  • In a further embodiment of the method diagrammed in FIGS. 1 and 4, chilled roller 14 or 116 can have patterns projecting from its surface. As the fabric and backing material is pressed between roller 12 and chilled roller 14 or between roller 114 and chilled roller 116, the pattern is pressed into the surface of the backing material. The pattern can be a knurl, design, texture, or other pattern. The pattern can provide reduced-skid or non-skid properties to the fabric, or enhanced adhesion, useful in the case of carpets and some other applications. The pattern can also be an aesthetic design, texture, or pattern, or can display a logo, trademark, or other identifying matter.
  • In another embodiment of the method diagrammed in FIGS. 1 and 2, the fabric is preheated at preheat station 136 before being fed to the in-running nip point 10 or 112. The preheat temperature is chosen based on the weight, construction, and type of fabric, but is preferably between 120° F. and 275° F. The preheat step can be accomplished by contact, such as rolling the fabric over a contact roll or a contact plate heated by steam, oil, or electricity, or by a noncontact method such as infrared radiative heat or forced air.
  • Alternatively, the backing material of the present invention can be made, solidified, stored in bulk, and later re-melted and applied to a fabric. This process is diagrammed in FIG. 7. Steps 201 through 205 and 209 through 213 are identical to the steps described in connection with FIG. 3. In this alternative, the backing material is again preferably made by mixing the ingredients described above in a co-rotating twin-screw extruder and heating those ingredients above the melting point of the mixture. The backing material is then forced through a die and cooled until it solidifies (step 401). The backing material can then be stored in bulk until needed.
  • For example, the backing material can be cooled and stored in a drum. When it is needed, a conventional drum melter is used to re-melt the backing material (step 403) and to pump the backing material either directly to a die or to a standard extruder for delivery to a die (step 405), for application to a fabric as described above. The more expensive twin-screw extruder described above is not needed for the application step, since the backing material has already been made and only needs to be re-melted and applied.
  • Alternatively, the backing material of the present invention can be made, solidified into blocks, billets, or pellets, stored, and later re-melted and applied to a fabric. In this alternative, the backing material is again preferably made by mixing the ingredients described above in a co-rotating twin-screw extruder and heating those ingredients above the melting point of the mixture. The backing material is then forced through a die, cooled until it solidifies, and then processed into blocks, billets or pellets (step 401). Equipment associated with processing into blocks, billets, and pellets is conventional and accordingly need not be further described. The backing material can then be stored until needed. In this alternative, the pellets can be introduced into a standard, single-screw extruder for re-melting (step 403) and extrusion through a die to a fabric (step 404). Blocks, billets, or pellets can be liquefied in a heated mixer or other suitable melting device (step 403) and pumped either directly to a die or to a standard single screw extruder for delivery to a die (step 404), for application to a fabric.
  • While preferred embodiments of the present invention are shown and described, it is envisioned that those skilled in the art may devise various modifications of the present invention without departing from the spirit and scope of the appended claims.

Claims (28)

1-44. (canceled)
45. A composition comprising a blend of:
a flexibilizer; and
a low density polyethylene having a melt index greater than about 1,000.
46. The composition claim 45, wherein said blend is a melt blend.
47. The composition of claim 45, wherein said low density polyethylene has at least one of the properties of a number average molecular weight less than about 10,000, a weight average molecular weight less than about 35,000, or a specific gravity less than or equal to 0.92.
48. The composition of claim 45, wherein said low density polyethylene has a specific gravity less than or equal to 0.92.
49. The composition of claim 45, wherein said flexibilizer comprises at least one of a thermoplastic elastomer, a thermoplastic rubber, a contained geometry catalyzed low-density polyethylene, ethylene methylacrylate, ethylene vinyl acetate and ethylene butyl modified polyethylene.
50. The composition of claim 45 further comprising at least one filler.
51. The composition of claim 50, wherein said at least one filler comprises at least one of magnesium hydroxide, Portland cement, calcium carbonate and calcium oxide.
52. The composition of claim 45 further comprising a dispersant.
53. The composition of claim 52, wherein said dispersant is magnesium stearate or calcium stearate.
54. The composition of claim 45, wherein said composition is in the form of blocks, billets or pellets.
55. A method comprising forming a blend of a flexibilizer and a low density polyethylene having a melt index greater than about 1,000.
56. The method of claim 55, wherein said blend is formed by melting said flexibilizer and said low density polyethylene.
57. The method claim 56, wherein said melting is performed by extruding said flexibilizer and said low density polyethylene.
58. The method of claim 55, wherein said low density polyethylene has at least one of the properties of a number average molecular weight less than about 10,000, a weight average molecular weight less than about 35,000, or a specific gravity less than 0.92.
59. The method of claim 55, wherein said low density polyethylene has a specific gravity less than 0.92.
60. The method of claim 55, wherein said flexibilizer comprises at least one of a thermoplastic elastomer, a thermoplastic rubber, a contained geometry catalyzed low-density polyethylene, ethylene methylacrylate, ethylene vinyl acetate and ethylene butyl modified polyethylene.
61. The method of claim 55, wherein said blend further comprises at least one filler.
62. The method of claim 61, wherein said at least one filler comprises at least one of magnesium hydroxide, Portland cement, calcium carbonate and calcium oxide.
63. The method of claim 55, wherein said blend further comprises a dispersant.
64. The method of claim 63, wherein said dispersant is magnesium stearate or calcium stearate.
65. The method of claim 55 further comprising forming said blend into blocks, billets or pellets.
66. The method of claim 65 further comprising extruding said blocks, billets or pellets of said blend to form a layer.
67. A method comprising:
melting blocks, billets or pellets of a composition comprising a flexibilizer and a low density polyethylene having a melt index greater than about 1,000 to form a blend;
preheating a substrate; and
applying said blend to said preheated substrate.
68. The method of claim 67, wherein said substrate is a textile material.
69. The method of claim 67, wherein said substrate is a carpet.
70. The method of claim 67, wherein said substrate is a carpet tile.
71. The method of claim 67, wherein said composition is melted and blended in an extruder.
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CA2537428A1 (en) 2005-03-17
CA2537428C (en) 2013-02-19
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WO2005024108A2 (en) 2005-03-17
WO2005024108A3 (en) 2005-11-03
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EP1660315A4 (en) 2009-10-21
CN1860020A (en) 2006-11-08

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