US20090178800A1 - Multi-Layer Water Swelling Packer - Google Patents

Multi-Layer Water Swelling Packer Download PDF

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Publication number
US20090178800A1
US20090178800A1 US12/013,519 US1351908A US2009178800A1 US 20090178800 A1 US20090178800 A1 US 20090178800A1 US 1351908 A US1351908 A US 1351908A US 2009178800 A1 US2009178800 A1 US 2009178800A1
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United States
Prior art keywords
component
packer
water containing
core
containing fluids
Prior art date
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Abandoned
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US12/013,519
Inventor
James R. Korte
Edward T. Wood
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Baker Hughes Holdings LLC
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Individual
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Filing date
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Application filed by Individual filed Critical Individual
Priority to US12/013,519 priority Critical patent/US20090178800A1/en
Assigned to BAKER HUGHES INCORPORATED reassignment BAKER HUGHES INCORPORATED ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KORTE, JAMES R., WOOD, EDWARD T.
Publication of US20090178800A1 publication Critical patent/US20090178800A1/en
Abandoned legal-status Critical Current

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    • EFIXED CONSTRUCTIONS
    • E21EARTH DRILLING; MINING
    • E21BEARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B33/00Sealing or packing boreholes or wells
    • E21B33/10Sealing or packing boreholes or wells in the borehole
    • E21B33/12Packers; Plugs
    • E21B33/1208Packers; Plugs characterised by the construction of the sealing or packing means

Definitions

  • the field of the invention is a packer for downhole use and more particularly a swelling packer responsive to water containing fluids where the swelling rate is regulated to allow proper placement before a full set.
  • Packers are used to isolate zones in a wellbore. Many different types of packers have been used over the years. Some of these designs involve mechanical compression that comes from a setting tool that uses relative movement. Other designs use pressure that is converted with a piston to a mechanical force to set the packer.
  • Another packer style is an inflatable where the fluid is pumped through a series of check valves into a sealed annular space between a mandrel and an element. One end of the element is generally fixed to the mandrel with the opposite end riding toward it as the element radially expands from the pumped fluid into the annular space.
  • packers have used materials that swell.
  • a structure similar to an inflatable was used and the annular space contained swelling clay such as bentonite.
  • Annular well fluids were admitted into this annular space and distributed with a wick.
  • the swelling clay then enlarged the annular space defined by the sealing element until the assembly closed off the wellbore.
  • Another design used an elastic polymer sensitive to hydrocarbons in the well.
  • the outer layer had a greater resistance and a lower diffusion rate to hydrocarbons than the core.
  • the outer layer was optionally reinforced. This design is described in U.S. Pat. No. 7,143,832.
  • a packer that employs swelling and sensitivity to water containing fluids and that has a mechanism to control the swelling of a core until the packer is delivered in its intended location.
  • An outer covering layer is fitted over the core where preferably the outer layer allows water containing fluids to diffuse but that has a substantially lower swelling rate than the core in response to water containing fluids.
  • the core is protected and its swelling is inhibited long enough to allow it to be properly placed.
  • the outer covering can be made to dissolve in water containing fluids as opposed to diffusing water containing fluids and swelling at a lower rate than the core.
  • a packer for downhole use responds to water containing fluids by swelling from its core.
  • the core is preferably covered with an outer layer that preferably has a lower rate of diffusion and swelling than the core that it surrounds. Because of this arrangement, the packer can be delivered to the desired location before it is set by swelling of the core.
  • the outer layer can also be responsive to water containing fluids by dissolving slowly to allow time to properly position the packer before the core swells to a sealing relationship with the surrounding tubular or the wellbore wall.
  • FIG. 1 is a half section view of the packer in the run in configuration before the core swells.
  • the packer of the present invention is illustrated in FIG. 1 .
  • the mandrel 10 is surrounded by a core material 12 which in turn is covered by an outer layer 14 .
  • the core material and the outer layer material are preferably responsive to water containing fluids which are defined as having at least 2% water and the preferred responses to exposure to such fluids is diffusion and swelling.
  • Swelling in water or saline brines is illustrated by a super absorbent polymer, sodium polyacrylate.
  • Sodium polyacrylate is a polyelectrolyte and swells due to osmotic pressure effects.
  • the fixed anionic charge on the pendent group of the polymer chain or on the swelling agent needs to be balanced by cationic counter ions to maintain electro neutrality.
  • the counter ions will not diffuse out of the polymer matrix although they are mobile.
  • the chemical potential of the counter ions in the polymer matrix is higher than that of the counter ions in the water outside the polymer.
  • water migrates into the polymer matrix, leading to swelling of the polymer matrix.
  • the extent of swelling of the polymer matrix is derived from the balance between the elasticity of the polymer network and the osmotic pressure effects of the counter ions.
  • the water swellable rubber can be obtained by either copolymerization or compounding of a polyelectrolyte polymer with rubber.
  • the core 12 swells more extensively than the outer layer 14 .
  • the outer layer 14 delays the swelling of the core in the presence of water containing fluids so that the packer P of the present invention can be delivered to the desired location.
  • the balance between the elasticity of the outer polymer network and the osmotic pressure forces is in favor of limiting the swell reaction rate while the balance between the elasticity and the osmotic pressure forces of the inner layer are in favor of swelling (expansion).
  • the net result is the inner layer expands the outer layer, or the outer layer retards the swell (expansion) rate of the inner layer.
  • the outer layer 14 protects the core from abrasion and other mechanical impacts and regulates the rate that the water containing fluids reach the core 12 .
  • the core 12 can preferably be made from acrylate, acetate or formate salts or one of the following elastomeric polymer materials or combinations thereof: acrylonitrile, nitrile, hydrogenated nitrile, chloroprene, ethylene vinyl acetate, ethylene propylene diene monomer, ethylene propylene, or polynorbornen and acrylic copolymer, super absorbent polymers (SAP), carboxy methyl cellulose or/and a partially modified or fully cross-linked acrylic polymer added.
  • SAP super absorbent polymers
  • the outer layer 14 can be made from acrylate, acetate or formate salts or one or more of the following elastomeric polymer materials or combinations thereof: acrylonitrile, nitrile, hydrogenated nitrile, chloroprene, ethylene vinyl acetate, ethylene propylene diene monomer, ethylene propylene, or polynorbornen with an acrylic copolymer added.
  • the outer layer 14 can be continuous in its coverage of the core 12 or there can be openings or gaps in the outer layer through which water containing fluids can reach the core 12 .
  • the outer layer 14 can be in a single or multiple layers. If it is continuous the water containing fluid can diffuse through it to reach the core 12 .
  • the outer layer can be made of a material that will dissolve in a water containing fluid such as water containing drilling mud, sea water or saline brines.
  • the core 12 and the outer layer 14 should preferably have different swelling or diffusion rates with the core 12 swelling substantially more than the outer layer 14 and preferably having a higher diffusion rate for water containing fluids than the outer layer 14 .
  • the packer P components can take the shape of an irregular wellbore. In the preferred embodiment the packer P responds only to the presence of water containing fluids.
  • the core need not be uniform as far as the material. It can be designed to swell more toward the center of the element initially so that well fluids are displaced to opposed ends that have not yet swelled into contact with the surrounding wellbore.

Abstract

A packer for downhole use responds to water containing fluids by swelling from its core. The core is preferably covered with an outer layer that preferably has a lower rate of diffusion and swelling than the core that it surrounds. Because of this arrangement, the packer can be delivered to the desired location before it is set by swelling of the core. The outer layer can also be responsive to water containing fluids by dissolving slowly to allow time to properly position the packer before the core swells to a sealing relationship with the surrounding tubular or the wellbore wall.

Description

    FIELD OF THE INVENTION
  • The field of the invention is a packer for downhole use and more particularly a swelling packer responsive to water containing fluids where the swelling rate is regulated to allow proper placement before a full set.
  • BACKGROUND OF THE INVENTION
  • Packers are used to isolate zones in a wellbore. Many different types of packers have been used over the years. Some of these designs involve mechanical compression that comes from a setting tool that uses relative movement. Other designs use pressure that is converted with a piston to a mechanical force to set the packer. Another packer style is an inflatable where the fluid is pumped through a series of check valves into a sealed annular space between a mandrel and an element. One end of the element is generally fixed to the mandrel with the opposite end riding toward it as the element radially expands from the pumped fluid into the annular space.
  • More recently, packers have used materials that swell. In one design a structure similar to an inflatable was used and the annular space contained swelling clay such as bentonite. Annular well fluids were admitted into this annular space and distributed with a wick. The swelling clay then enlarged the annular space defined by the sealing element until the assembly closed off the wellbore. Another design used an elastic polymer sensitive to hydrocarbons in the well. There was an inner and an outer layer that was rubber and allowed the hydrocarbons to get through to the inner core. The outer layer had a greater resistance and a lower diffusion rate to hydrocarbons than the core. The outer layer was optionally reinforced. This design is described in U.S. Pat. No. 7,143,832. Also of interest but working in the opposite direction are plugs that can be used downhole and then removed by exposure to well fluids such as is illustrated in U.S. Pat. No. 5,607,017. Packers that use water expandable materials are shown in U.S. Pat. No. 5,048,605 and Japan application 07-334115 filed Nov. 29, 1995 and entitled Borehole Packing Method
  • What is needed and is the focus of the present invention is a packer that employs swelling and sensitivity to water containing fluids and that has a mechanism to control the swelling of a core until the packer is delivered in its intended location. An outer covering layer is fitted over the core where preferably the outer layer allows water containing fluids to diffuse but that has a substantially lower swelling rate than the core in response to water containing fluids. As a result, the core is protected and its swelling is inhibited long enough to allow it to be properly placed. Alternatively the outer covering can be made to dissolve in water containing fluids as opposed to diffusing water containing fluids and swelling at a lower rate than the core. These and other aspects of the present invention will be more readily understood by those skilled in the art from a review of the description of the preferred embodiment and the associated drawing, which appear below while understanding that the claims determine the full scope of the invention.
  • SUMMARY OF THE INVENTION
  • A packer for downhole use responds to water containing fluids by swelling from its core. The core is preferably covered with an outer layer that preferably has a lower rate of diffusion and swelling than the core that it surrounds. Because of this arrangement, the packer can be delivered to the desired location before it is set by swelling of the core. The outer layer can also be responsive to water containing fluids by dissolving slowly to allow time to properly position the packer before the core swells to a sealing relationship with the surrounding tubular or the wellbore wall.
  • BRIEF DESCRIPTION OF THE DRAWING
  • FIG. 1 is a half section view of the packer in the run in configuration before the core swells.
  • DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
  • The packer of the present invention is illustrated in FIG. 1. In the preferred embodiment, the mandrel 10 is surrounded by a core material 12 which in turn is covered by an outer layer 14. The core material and the outer layer material are preferably responsive to water containing fluids which are defined as having at least 2% water and the preferred responses to exposure to such fluids is diffusion and swelling. Swelling in water or saline brines is illustrated by a super absorbent polymer, sodium polyacrylate. Sodium polyacrylate is a polyelectrolyte and swells due to osmotic pressure effects. The fixed anionic charge on the pendent group of the polymer chain or on the swelling agent needs to be balanced by cationic counter ions to maintain electro neutrality. Thus, the counter ions will not diffuse out of the polymer matrix although they are mobile. As a consequence, the chemical potential of the counter ions in the polymer matrix is higher than that of the counter ions in the water outside the polymer. To equalize the chemical potential of the counter ions (or to maintain thermodynamic equilibrium), water migrates into the polymer matrix, leading to swelling of the polymer matrix. The extent of swelling of the polymer matrix is derived from the balance between the elasticity of the polymer network and the osmotic pressure effects of the counter ions. The water swellable rubber can be obtained by either copolymerization or compounding of a polyelectrolyte polymer with rubber.
  • Preferably the core 12 swells more extensively than the outer layer 14. In that manner, the outer layer 14 delays the swelling of the core in the presence of water containing fluids so that the packer P of the present invention can be delivered to the desired location. Stated differently, the balance between the elasticity of the outer polymer network and the osmotic pressure forces is in favor of limiting the swell reaction rate while the balance between the elasticity and the osmotic pressure forces of the inner layer are in favor of swelling (expansion). The net result is the inner layer expands the outer layer, or the outer layer retards the swell (expansion) rate of the inner layer.
  • The outer layer 14 protects the core from abrasion and other mechanical impacts and regulates the rate that the water containing fluids reach the core 12.
  • The core 12 can preferably be made from acrylate, acetate or formate salts or one of the following elastomeric polymer materials or combinations thereof: acrylonitrile, nitrile, hydrogenated nitrile, chloroprene, ethylene vinyl acetate, ethylene propylene diene monomer, ethylene propylene, or polynorbornen and acrylic copolymer, super absorbent polymers (SAP), carboxy methyl cellulose or/and a partially modified or fully cross-linked acrylic polymer added.
  • The outer layer 14 can be made from acrylate, acetate or formate salts or one or more of the following elastomeric polymer materials or combinations thereof: acrylonitrile, nitrile, hydrogenated nitrile, chloroprene, ethylene vinyl acetate, ethylene propylene diene monomer, ethylene propylene, or polynorbornen with an acrylic copolymer added.
  • The outer layer 14 can be continuous in its coverage of the core 12 or there can be openings or gaps in the outer layer through which water containing fluids can reach the core 12. The outer layer 14 can be in a single or multiple layers. If it is continuous the water containing fluid can diffuse through it to reach the core 12. Alternatively, the outer layer can be made of a material that will dissolve in a water containing fluid such as water containing drilling mud, sea water or saline brines.
  • The core 12 and the outer layer 14 should preferably have different swelling or diffusion rates with the core 12 swelling substantially more than the outer layer 14 and preferably having a higher diffusion rate for water containing fluids than the outer layer 14. Together the packer P components can take the shape of an irregular wellbore. In the preferred embodiment the packer P responds only to the presence of water containing fluids.
  • When the outer layer is designed to dissolve in water containing fluids, it simply slowly goes away as the core 12 swells.
  • The core need not be uniform as far as the material. It can be designed to swell more toward the center of the element initially so that well fluids are displaced to opposed ends that have not yet swelled into contact with the surrounding wellbore.
  • The above description is illustrative of the preferred embodiment and various alternatives and is not intended to embody the broadest scope of the invention, which is determined from the claims appended below, and properly given their full scope literally and equivalently.

Claims (16)

1. A packer for downhole use, comprising:
a mandrel;
a multi-component element wherein a first component, having a cohesive shape supported by said mandrel, swells responsive to water containing fluid and a second component controls access of water containing fluids to said first component.
2. The packer of claim 1, wherein:
said second component is mounted over said first component.
3. The packer of claim 2, wherein:
said second component allows water containing fluid to diffuse through it.
4. The packer of claim 3, wherein:
said second component has openings.
5. The packer of claim 1, wherein:
said second component dissolves in the presence of water containing fluids.
6. The packer of claim 1, wherein:
said first component is made of an elastomeric polymer material or acrylate, acetate or formate salts.
7. The packer of claim 6, wherein:
said material further comprises acrylonitrile, nitrile, hydrogenated nitrile, chloroprene, ethylene vinyl acetate, ethylene propylene diene monomer, ethylene propylene, or polynorbornen and acrylic copolymer, super absorbent polymers (SAP), carboxy methyl cellulose or/and a partially modified or fully cross-linked acrylic polymer added.
8. The packer of claim 1, wherein:
said second component is made of an elastomeric polymer material or acrylate, acetate or formate salts.
9. The packer of claim 8, wherein:
said material further comprises acrylonitrile, nitrile, hydrogenated nitrile, chloroprene, ethylene vinyl acetate, ethylene propylene diene monomer, ethylene propylene, or polynorbornen with an acrylic copolymer added.
10. The packer of claim 1, wherein:
said second component swells less than said first component.
11. The packer of claim 1, wherein:
said second component diffuses water containing fluids at a slower rate than said first component.
12. The packer of claim 10, wherein:
said first component comprises an annular cylindrical shape disposed around said mandrel.
13. The packer of claim 12, wherein:
said second component covers substantially the entire outer surface of said first component.
14. The packer of claim 11, wherein:
said first component comprises an annular cylindrical shape disposed around said mandrel.
15. The packer of claim 14, wherein:
said second component covers substantially the entire outer surface of said first component.
16. The packer of claim 10, wherein:
said second component diffuses water containing fluids at a slower rate than said first component.
US12/013,519 2008-01-14 2008-01-14 Multi-Layer Water Swelling Packer Abandoned US20090178800A1 (en)

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100025035A1 (en) * 2008-08-04 2010-02-04 Baker Hughes Incorporated Swelling Delay Cover for a Packer
US20110209760A1 (en) * 2007-10-04 2011-09-01 Antonio Bonucci Method for manufacturing photovoltaic panels by the use of a polymeric tri-layer comprising a composite getter system
WO2012005874A2 (en) * 2010-06-30 2012-01-12 Halliburton Energy Services, Inc. Mitigating leaks in production tubulars
WO2012005926A2 (en) * 2010-07-09 2012-01-12 Halliburton Energy Services, Inc. Drill string/annulus sealing with swellable materials
US8439082B2 (en) 2010-06-25 2013-05-14 Baker Hughes Incorporated Retention mechanism for subterranean seals experiencing differential pressure
WO2014039604A1 (en) * 2012-09-05 2014-03-13 Schlumberger Canada Limited Functionally gradient elastomer material for downhole sealing element
WO2014062391A1 (en) 2012-10-16 2014-04-24 Halliburton Energy Services, Inc. Controlled swell-rate swellable packer and method
CN104704193A (en) * 2012-10-05 2015-06-10 贝克休斯公司 System for increasing swelling efficiency
US20180156006A1 (en) * 2015-05-05 2018-06-07 Risun Oilflow Solutions Inc. Swellable choke packer
WO2018147833A1 (en) * 2017-02-07 2018-08-16 Halliburton Energy Services, Inc. Packer sealing element with non-swelling layer
US10087703B2 (en) 2012-09-17 2018-10-02 Halliburton Energy Services, Inc. Well tools with semi-permeable barrier for water-swellable material
US20240117702A1 (en) * 2022-10-07 2024-04-11 Halliburton Energy Services, Inc. Sealing element of isolation device with inner core and outer shell

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040020662A1 (en) * 2000-09-08 2004-02-05 Jan Freyer Well packing
US20050199401A1 (en) * 2004-03-12 2005-09-15 Schlumberger Technology Corporation System and Method to Seal Using a Swellable Material
US7066259B2 (en) * 2001-12-27 2006-06-27 Weatherford/Lamb, Inc. Bore isolation
US7070001B2 (en) * 2002-12-23 2006-07-04 Weatherford/Lamb, Inc. Expandable sealing apparatus
US20080185158A1 (en) * 2007-02-06 2008-08-07 Halliburton Energy Services, Inc. Swellable packer with enhanced sealing capability

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040020662A1 (en) * 2000-09-08 2004-02-05 Jan Freyer Well packing
US7066259B2 (en) * 2001-12-27 2006-06-27 Weatherford/Lamb, Inc. Bore isolation
US7070001B2 (en) * 2002-12-23 2006-07-04 Weatherford/Lamb, Inc. Expandable sealing apparatus
US20050199401A1 (en) * 2004-03-12 2005-09-15 Schlumberger Technology Corporation System and Method to Seal Using a Swellable Material
US20080185158A1 (en) * 2007-02-06 2008-08-07 Halliburton Energy Services, Inc. Swellable packer with enhanced sealing capability

Cited By (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110209760A1 (en) * 2007-10-04 2011-09-01 Antonio Bonucci Method for manufacturing photovoltaic panels by the use of a polymeric tri-layer comprising a composite getter system
US9595626B2 (en) * 2007-10-04 2017-03-14 Saes Getters S.P.A. Method for manufacturing photovoltaic panels by the use of a polymeric tri-layer comprising a composite getter system
US20100025035A1 (en) * 2008-08-04 2010-02-04 Baker Hughes Incorporated Swelling Delay Cover for a Packer
US8118092B2 (en) * 2008-08-04 2012-02-21 Baker Hughes Incorporated Swelling delay cover for a packer
US8439082B2 (en) 2010-06-25 2013-05-14 Baker Hughes Incorporated Retention mechanism for subterranean seals experiencing differential pressure
US10184321B2 (en) 2010-06-30 2019-01-22 Halliburton Energy Services, Inc. Mitigating leaks in production tubulars
WO2012005874A2 (en) * 2010-06-30 2012-01-12 Halliburton Energy Services, Inc. Mitigating leaks in production tubulars
WO2012005874A3 (en) * 2010-06-30 2012-03-29 Halliburton Energy Services, Inc. Mitigating leaks in production tubulars
US8960312B2 (en) 2010-06-30 2015-02-24 Halliburton Energy Services, Inc. Mitigating leaks in production tubulars
WO2012005926A3 (en) * 2010-07-09 2012-04-05 Halliburton Energy Services, Inc. Drill string/annulus sealing with swellable materials
US8353355B2 (en) 2010-07-09 2013-01-15 Halliburton Energy Services, Inc. Drill string/annulus sealing with swellable materials
WO2012005926A2 (en) * 2010-07-09 2012-01-12 Halliburton Energy Services, Inc. Drill string/annulus sealing with swellable materials
WO2014039604A1 (en) * 2012-09-05 2014-03-13 Schlumberger Canada Limited Functionally gradient elastomer material for downhole sealing element
US10087703B2 (en) 2012-09-17 2018-10-02 Halliburton Energy Services, Inc. Well tools with semi-permeable barrier for water-swellable material
CN104704193A (en) * 2012-10-05 2015-06-10 贝克休斯公司 System for increasing swelling efficiency
US10443340B2 (en) 2012-10-16 2019-10-15 Halliburton Energy Services, Inc. Method for making controlled swell-rate swellable packer
AU2013331694B2 (en) * 2012-10-16 2016-11-10 Halliburton Energy Services, Inc. Controlled swell-rate swellable packer and method
CN104755698A (en) * 2012-10-16 2015-07-01 哈里伯顿能源服务公司 Controlled swell-rate swellable packer and method
US9869152B2 (en) 2012-10-16 2018-01-16 Halliburton Energy Services, Inc. Controlled swell-rate swellable packer and method
US10012051B2 (en) 2012-10-16 2018-07-03 Halliburton Energy Services, Inc. Controlled swell-rate swellable packer and method
EP2909433A4 (en) * 2012-10-16 2016-06-22 Halliburton Energy Services Inc Controlled swell-rate swellable packer and method
WO2014062391A1 (en) 2012-10-16 2014-04-24 Halliburton Energy Services, Inc. Controlled swell-rate swellable packer and method
US20180156006A1 (en) * 2015-05-05 2018-06-07 Risun Oilflow Solutions Inc. Swellable choke packer
WO2018147833A1 (en) * 2017-02-07 2018-08-16 Halliburton Energy Services, Inc. Packer sealing element with non-swelling layer
GB2572086A (en) * 2017-02-07 2019-09-18 Halliburton Energy Services Inc Packer sealing element with non-swelling layer
GB2572086B (en) * 2017-02-07 2022-04-06 Halliburton Energy Services Inc Packer sealing element with non-swelling layer
US11473391B2 (en) 2017-02-07 2022-10-18 Halliburton Energy Services, Inc. Packer sealing element with non-swelling layer
US20240117702A1 (en) * 2022-10-07 2024-04-11 Halliburton Energy Services, Inc. Sealing element of isolation device with inner core and outer shell

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Owner name: BAKER HUGHES INCORPORATED, TEXAS

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:KORTE, JAMES R.;WOOD, EDWARD T.;REEL/FRAME:020646/0112;SIGNING DATES FROM 20080114 TO 20080115

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION