US20100239807A1 - Flexible laminated hip and ridge shingle - Google Patents

Flexible laminated hip and ridge shingle Download PDF

Info

Publication number
US20100239807A1
US20100239807A1 US12/727,459 US72745910A US2010239807A1 US 20100239807 A1 US20100239807 A1 US 20100239807A1 US 72745910 A US72745910 A US 72745910A US 2010239807 A1 US2010239807 A1 US 2010239807A1
Authority
US
United States
Prior art keywords
decorative layer
shingle
hip
ridge
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US12/727,459
Inventor
Lawrence J. Grubka
Jennifer L. Frey
James E. Loftus
Donn R. Vermilion
Jason D. Guerra
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Owens Corning Intellectual Capital LLC
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to US12/727,459 priority Critical patent/US20100239807A1/en
Assigned to OWENS CORNING INTELLECTUAL CAPITAL, LLC reassignment OWENS CORNING INTELLECTUAL CAPITAL, LLC ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: GUERRA, JASON D., FREY, JENNIFER L., GRUBKA, LAWRENCE J., LOFTUS, JAMES E., VERMILION, DONN R.
Publication of US20100239807A1 publication Critical patent/US20100239807A1/en
Priority to US14/751,334 priority patent/US9482007B2/en
Abandoned legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J195/00Adhesives based on bituminous materials, e.g. asphalt, tar, pitch
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L95/00Compositions of bituminous materials, e.g. asphalt, tar, pitch
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04DROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D1/00Roof covering by making use of tiles, slates, shingles, or other small roofing elements
    • E04D1/12Roofing elements shaped as plain tiles or shingles, i.e. with flat outer surface
    • E04D1/20Roofing elements shaped as plain tiles or shingles, i.e. with flat outer surface of plastics; of asphalt; of fibrous materials
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04DROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D1/00Roof covering by making use of tiles, slates, shingles, or other small roofing elements
    • E04D1/26Strip-shaped roofing elements simulating a repetitive pattern, e.g. appearing as a row of shingles
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04DROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D1/00Roof covering by making use of tiles, slates, shingles, or other small roofing elements
    • E04D1/30Special roof-covering elements, e.g. ridge tiles, gutter tiles, gable tiles, ventilation tiles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B1/00Layered products having a general shape other than plane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/24Organic non-macromolecular coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/26Polymeric coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/546Flexural strength; Flexion stiffness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2419/00Buildings or parts thereof
    • B32B2419/06Roofs, roof membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form
    • B32B3/26Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar form; Layered products having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24025Superposed movable attached layers or components

Definitions

  • the present invention relates generally to roofing shingles, and more particularly, to a flexible laminating adhesive for use with a multi-layered shingled product that permits the shingle product to be bent, such as over an apex of a roof, without cracking or breaking.
  • flexible adhesive provides flexibility at temperatures lower than or equal to about 40° F.
  • Roofs are typically formed so as to present at least two non-parallel planes that meet at a peak, usually the uppermost point of the roof. This peak is typically referred to as the ridge. Roofs can also be formed to present other non-parallel planes that are often formed at the ends of the ridge to form other diagonally-extending plane intersections similar to the ridge, but are referred to as hips. Whereas, the covering of the planar portions of a roof typically involve the laying of shingles in overlapping, transversely parallel courses from the bottom roof edge to the ridge or hip, the ridges and hips require a different technique to cover the intersection of the two or more roof planes.
  • a conventional technique for covering the ridges and hips is to cut the shingles into appropriate width and to bend the cut shingle over the ridge or hip so as to overlap the shingles placed on the opposing roof planes, and then starting at one end of the ridge or hip and overlap the cut shingles along the length of the ridge or hip.
  • Asphalt composite shingles are one of the most commonly used roofing products. These asphalt composite shingles typically incorporate a base material made from a fiberglass mat, or other suitable reinforcement member, such as an organic felt material. This reinforcing base material serves as a matrix to support an asphalt coating and gives the shingle strength.
  • the asphalt coating is formulated for the particular service application and has a long-term ability to resist weathering and provide stability for the structure under extreme temperature conditions.
  • An outer layer of granules is applied to the asphalt coating to form an outer surface that the asphalt coating from direct sunlight. This outer layer of granules also offers resistance to fire. Utilizing differently colored granules provides a variety in the surface appearance of the shingle to establish color variations.
  • Conventional laminated shingles for example, as well as hip and ridge shingles, are generally multilayered and the separate, individual layers are held together with an adhesive material.
  • One problem associated with conventional adhesives is that the adhesive can be too strong for a particular application.
  • hip and ridge shingles are often formed of multiple layers or chips adhered to a base sheet in order to achieve a dimensional appearance when attached to a roof.
  • a problem may occur when bending the shingle over the ridge or hip.
  • the thickest areas of the shingle include two or three layers of material, bending the shingle to cover the ridge or hip often results in a crack along the outer layer of the dimensional composite shingle, which compromises the integrity of the ridge or hip covering. Furthermore, if the adhesive holding the various layers together is too aggressive, the layers providing the dimensional appearance of the shingle may tear apart or otherwise cause the shingle to fail.
  • an adhesive composition that includes a base asphalt, a linear copolymer, and an oil is provided.
  • the adhesive composition also contains a radial copolymer and/or one or more fillers.
  • the base asphalt used in the inventive adhesive composition may be a viscosity graded asphalt, such as AC-10 or AC-20, or a paving graded asphalt, such as PG58 or PG64.
  • the linear copolymer has an A-B di-block or A-B-A tri-block structure where blocks A and B may individually represent (1) styrene and butadiene or (2) styrene and isoprene.
  • the oil is a petroleum-based oil that both “softens” the asphalt in the composition and reduces the viscosity of the adhesive composition.
  • the adhesive composition also contains a radial copolymer having an (A-B) n radial structure, where n is an integer of at least 4, or a tri-block (A-B-A) radial structure having from 4-8 arms.
  • the inventive adhesive composition permits a multilayered shingle to have a degree of flexibility, such as to permit the shingle to be bent over the ridge line or hip of a roof.
  • shingles for use as a hip and ridge shingle that includes a base layer having a first length dimension and a first width dimension and a first decorative layer having a second length dimension and a second width dimension are provided.
  • the first decorative layer is affixed to the base layer by a flexible adhesive that allows the first decorative layer to move relative to the base layer without cracking or breaking the first decorative layer.
  • at least one of the second length dimension and second width dimension is the same as or smaller than the corresponding first length dimension and the first width dimension.
  • a second decorative layer is affixed to the first decorative layer by the flexible adhesive.
  • the adhesive permits the second decorative layer to move relative to said first decorative layer without cracking or breaking either the first or second decorative layer.
  • the second decorative layer may have a length and/or width dimension that is the same as or smaller than the corresponding length and width dimension of the first decorative layer.
  • the adhesive composition includes a base asphalt, a linear copolymer, an oil, and optionally, a radial copolymer and/or one or more fillers. Additionally, the adhesive possesses sufficient flexibility and shear to permit a multilayered hip and ridge shingle to be bent over the ridge or hip of a roof without cracking or breaking, even at temperatures lower than or equal to about 40° F.
  • hip and ridge shingles for covering a ridge line of a roof that includes (1) a base layer having a first length dimension and a first width dimension and (2) a first decorative layer having a second length dimension and a second width dimension where at least one of the second length and width dimensions is smaller than the corresponding first length and width dimensions are provided.
  • the first decorative layer is affixed to the base layer by a flexible adhesive that allows a limited movement of the first decorative layer relative to the base layer to permit the first decorative layer to bend about a different radius of curvature than the base member when the hip and ridge shingle is bent over a ridge line.
  • the hip and ridge shingle may also include a second decorative member affixed to the first decorative member by the flexible adhesive to allow a limited movement of the second decorative layer relative to the first decorative layer, thus allowing the second decorative layer to bend at a different radius of curvature than the first decorative layer.
  • each of the base layer, the first decorative layer, and the second decorative layer have opposing transverse edges that are offset when the hip and ridge shingle is installed on a ridge line or a hip of a roof.
  • the adhesive composition is flexible such that the layers of a multilayer shingle can be bent over the ridge or hip of a roof with out breaking or cracking.
  • the adhesive provides for more flexibility at lower temperatures, such as temperatures lower than or equal to about 40° F.
  • the decorative layers of a laminated asphalt composite shingle are secured by a flexible adhesive that permits the decorative layers to shift transversely to allow the respective decorative layers to bend at different radii of curvature when the shingle is placed over a roof ridge or hip.
  • the adhesive composition does not pose any safety or health issues to workers involved in their manufacture and/or application.
  • the asphaltic adhesive is useful in winter applications and in colder climates.
  • the exposed portion of the hip and ridge shingle is positioned on the decorative layers of a previously laid hip and ridge single when affixed to a ridge or hip of a roof, thereby providing a three dimensional, aesthetically pleasing appearance.
  • FIG. 1 is a schematic top plan view of an embodiment of a hip and ridge shingle formed according to the principles of the instant invention, the shingle being shown in a flat orientation with the decorative layers being representatively placed on a central portion of the shingle;
  • FIG. 2 is a schematic end elevational view of the hip and ridge shingle depicted in FIG. 1 ;
  • FIG. 3 is a schematic front elevational view of the hip and ridge shingle depicted in FIG. 1 ;
  • FIG. 4 is a schematic top plan view of an embodiment of a hip and ridge shingle formed according to the principles of the instant invention, the shingle being shown in a flat orientation with the decorative layers being representatively placed on a central portion of the shingle;
  • FIG. 5 is a schematic end elevational view of the hip and ridge shingle depicted in FIG. 4 ;
  • FIG. 6 is a schematic top plan view of a base shingle containing three separate hip and ridge shingles with perforations therebetween to facilitate separation of the hip and ridge shingles from the base shingle;
  • FIG. 7 is a schematic front elevational view of the hip and ridge shingle being bent to form a ridge or hip cover, the slippage of the individual layers being seen along the sides of the bent shingle.
  • the present inventions relate, at least in part, to a flexible adhesive composition for use with hip and ridge shingles (cap shingle) that includes a base asphalt, a linear copolymer, an oil, and, optionally, a radial copolymer and/or one or more fillers.
  • the adhesive possesses sufficient flexibility and shear to permit a multilayered hip and ridge shingle to be bent over the ridge or hip of a roof without cracking or breaking.
  • the adhesive provides for more flexibility at lower temperatures, such as temperatures lower than or equal to about 40° F.
  • the laminating adhesive composition contains, as one component, a base asphalt or other hydrocarbonaceous material.
  • a base asphalt or other hydrocarbonaceous material is meant to include any of a variety of materials that are solid or semi-solid materials at room temperature that gradually liquefy when heated and are formed predominantly of naturally occurring bitumens obtained as residue in petroleum refining.
  • the base asphalt used in the inventive adhesive composition is desirably a viscosity graded asphalt or an AC-10 paving grade asphalt such as PG58-22, which is commercially available British Petroleum and Conoco Philips and/or an AC-20 paving grade asphalt such as PG64-22, which is also commercially available from British Petroleum and Conoco Philips.
  • the base asphalt may be generally present in the adhesive composition in an amount from about 79.0% to about 90.5% by weight of the composition. In exemplary embodiments, the base asphalt may be present in the adhesive composition in an amount from about 81% to about 88% by weight of the composition. As used herein, and unless defined otherwise, the phrase “% by weight” is meant to denote % by weight of the total adhesive composition.
  • the adhesive composition contains a linear copolymer, and, optionally, a radial copolymer, each of which is described in detail below.
  • the copolymers are thermoplastic and are selected for their ability to impart strength to the adhesive at colder temperatures and to provide sufficient flexibility and/or shear.
  • the copolymers used in the inventive adhesive can be processed (i.e., melted and extruded) and can be repeatedly heated and cooled with no substantial loss in their properties, including elastomeric properties. Accordingly, the copolymers used herein substantially retain their properties when subjected to heating and cooling cycles.
  • One particular advantageous feature is the ability of the copolymers to retain strength upon cooling the copolymers, which gives both strength and flexibility to the adhesive at colder temperatures.
  • the adhesive composition contains a linear copolymer having an A-B di-block or A-B-A tri-block structure.
  • the linear copolymer has a di-block content greater than 50%.
  • Blocks A and B may individually represent (1) styrene and butadiene or (2) styrene and isoprene. Either block, A or B, may include more than one monomer. Additionally, each block segment may include 100 or more monomer units.
  • the linear copolymer may have a styrene content of less than 50%, from about 20% to about 40% styrene, or from about 20% to about 35% styrene.
  • the linear copolymer has a styrene/butadiene ratio of 33/67. In some examples the linear copolymer have styrene or polystyrene as the A block or end block units. Suitable copolymers include styrene-butadiene block copolymers and styrene-isoprene block copolymers.
  • non-limiting examples include D1118K, a styrene-butadiene-styrene di-block copolymer, and D1113K, and D1119K, styrene-isoprene-styrene linear polymers with a high-di-block content (all are commercially available from Kraton®).
  • the linear copolymer is a styrene-butadiene di-block copolymer, such as D1118K, commercially available from Kraton®.
  • the linear di-block copolymer may be present in the inventive adhesive composition in an amount from about 2.5% to about 11.0% by weight of the composition.
  • the linear copolymer is present in the adhesive composition in an amount from about 2.5% to about 6.5% by weight of the composition. In some exemplary embodiments, the linear copolymer may be present in the adhesive composition in a greater amount, such as, for example, from about 10.0-14.0% by weight of the composition, or from 11.0-12.0% by weight.
  • the adhesive composition may contain a radial copolymer.
  • the radial copolymer may have an (A-B) n radial structure, where n is an integer of at least 4, or from 4-20, or a tri-block (A-B-A) radial structure having from 4-8 arms.
  • Block copolymers are well known and are described in numerous patents, including, for example, U.S. Pat. No. 4,738,884 to Algrim, et al., U.S. Pat. No. 4,824,880 to Algrim, et al., and U.S. Pat. No. 6,759,454 to Stephens, et al., each of which is incorporated by reference in their entirety.
  • block A and/or B in the radial copolymer may include more than one monomer and each block segment may include 100 or more monomer units. Additionally, blocks A and B may individually represent (1) styrene and butadiene or (2) styrene and isoprene. It is desirable that the radial polymer have styrene or polystyrene as the A block or end block units.
  • the radial copolymer may have a styrene content of less than 50%, from about 20% to about 40% styrene, or from about 20% to about 35% styrene. In some examples, the styrene/butadiene ratio is 31/69.
  • Exemplary radial copolymers include D4158K (includes 33% oil), D1184K, D1116K, and D1144K, all of which are styrene-butadiene-styrene (SBS) radial copolymers (commercially available from Kraton®), and D1124K and D1126P, both of which are styrene-isoprene radial copolymers (commercially available from Kraton®).
  • the radial copolymer is a styrene-butadiene radial copolymer, such as D4158K or D1184K (commercially available from Kraton®).
  • the radial copolymer may be present in the adhesive composition in an amount from 0% to about 9.0% by weight of the composition. In exemplary embodiments, the radial copolymer may be present in the adhesive composition in an amount from about 3.5% to about 7.0% by weight of the composition.
  • the total amount of the radial copolymer and the linear copolymer present in the adhesive composition may range from about 6.5% to about 14.0%, or from about 8.0% to about 11.0% of the total composition.
  • the ratio of radial copolymer to linear copolymer present in the adhesive composition may range from 6:3 to 2:6 (radial copolymer:linear copolymer). In some examples, the ratio of radial copolymer to linear copolymer present in the adhesive composition is 5:4.
  • the oil can be any oil recognized in the art to enhance the “softness” of the asphalt in the adhesive composition.
  • the oil also aids in reducing the viscosity of the adhesive composition.
  • the oil is added in an amount necessary to achieve a desired viscosity for the adhesive composition, and to improve flexibility and low temperature bonding.
  • the viscosity of the adhesive composition desirably does not exceed approximately 1500 cps as measured by a Brookfield LVF Viscometer using spindle number 7 at 350° F.
  • the oil utilized in the adhesive composition may be a petroleum-based oil or other naphthenic or paraffinic oils identified by one of ordinary skill in the art.
  • Hydrolene SP-125 a severely solvent modified heavy petroleum oil commercially available from Sunoco, Inc. (CAS No. 63741-88-4).
  • the oil in combination with the selected copolymers, acts to give the flexibility and shear so that the adhesive can be used in conjunction with hip and ridge shingles, even at colder temperatures.
  • the oils and copolymer(s) permit the adhesive to flex and/or shear so that the layers of the hip and ridge shingle “slide” over each other upon bending and remain laminated together, without cracking or breaking the dimensional elements adhering to the base of the shingle.
  • the oil may be present in the adhesive composition in a total amount from about 2.0% to about 7.0% of the total adhesive composition, or from about 4.0% to about 6.0%. It is to be appreciated that a portion of the total oil content may be derived from another component of the adhesive composition, such as, for example, an oil-containing copolymer.
  • fillers may be added to any of the adhesive roofing sealant compositions.
  • a filler may be used.
  • Suitable fillers include, but are not limited to, limestone (calcium carbonate), dolomite (calcium magnesium carbonate), wollastonite, talc, silica, and others known to those skilled in the art.
  • the filler may have a median particle size from about 5 microns to about 50 microns, or from about 10 microns to about 30 microns.
  • a second adhesive composition is set forth in Table 2.
  • a third adhesive composition is set forth in Table 3.
  • the inventive adhesive compositions described herein can be reacted with elemental sulfur to vulcanize in situ.
  • Table 3 depicts an exemplary composition containing a mixture of two linear copolymers (i.e., di-block and tri-block styrene-butadiene copolymers). After dispersion in the base asphalt and oil, the copolymer blend may be crosslinked with sulfur. The addition of the sulfur to polymer modified asphalts enhances dispersion stability and improves mechanical properties.
  • the base asphalt is heated to a temperature of approximately 350° F. and the oil is blended into the molten asphalt.
  • the linear copolymer is added to the molten asphalt/oil to form a mixture. If a radial copolymer is included in the composition, it may be added along with the linear copolymer.
  • the mixture is then placed into a conventional milling apparatus where the polymers are sheared into smaller polymeric pieces.
  • the mixture is ground in the milling apparatus for a period of time sufficient to mill (grind) the polymers to a size that is no longer visible to the naked eye under UV light.
  • the adhesive composition is cooled for packaging and then melted for application to a shingle. It may be desirable to circulate and maintain the adhesive at an elevated temperature during processing and application to the shingles to aid in the prevention of phase separation.
  • the laminated hip and ridge shingle 10 may include a base layer 12 .
  • the base layer 12 may be formed in a conventional manner, and in some embodiments includes a reinforcement member, such as a fiberglass mat, on which asphalt and decorative granules are placed.
  • a reinforcement member such as a fiberglass mat
  • chopped glass fibers may be dispersed into a water slurry which may contain surfactants, viscosity modifiers, or other chemical agents. The slurry containing the dispersed fibers is then deposited onto a moving screen where a substantial portion of the water is removed.
  • a binder e.g., a urea formaldehyde binder or a polycarboxylic acid based binder
  • the mat formed of an assembly of randomly oriented, dispersed individual glass filaments, may be dried in any conventional manner, such as by passing the mat through an oven.
  • Asphalt may then be applied to the dried/cured mat in any known manner, such as by passing the mat through a bath containing an asphalt mix that may include molten asphalt, fillers, and optionally sulfur, to place a layer of asphalt on at least one side of the mat and fill in the interstices between the individual glass fibers.
  • the asphalt-coated mat is then cut to the appropriate shape and size to form the base layer 12 .
  • the hot, asphalt-coated mat may also be passed beneath one or more granule applicators that apply protective surface granules to portions of the asphalt-coated mat prior to cutting into the desired shape.
  • a similarly constructed first decorative or dimensional layer 14 is positioned on and adhered to the base layer 12 to provide a desired aesthetic appearance.
  • a second decorative (dimensional) layer 16 may be affixed on the first decorative layer 14 to provide greater depth to the composite shingle 10 and an enhanced three dimensional aesthetic appearance, particularly when viewed from a distance. It is to be appreciated that although the drawings reflect two decorative layers 14 , 16 that are positioned across the width of the base layer 12 , one skilled in the art will recognize that the decorative layers 14 , 16 can be placed in any appropriate arrangement or orientation on the base layer 12 to provide a desired aesthetic appearance.
  • the principles of the present invention are not limited to the specific location, size of the layers, or positioning of the decorative layers 14 , 16 , or the bending of the shingle to form a ridge or hip cap, as described in greater detail below, that requires the bending of all layers of the shingle irrespective of the location of the decorative layers 14 , 16 .
  • the first decorative layer 14 is positioned at a desired location on the base layer 12 and affixed thereto with the inventive adhesive composition.
  • the adhesive can be applied in a continuous or discontinuous fashion, such as in the form of beads or “dashes”.
  • the first decorative layer 14 may be the same size or substantially the same size as the base layer 12 .
  • the first decorative layer 14 may have a width that is smaller then the width of the base layer 12 , such as is shown in FIGS. 1-3 .
  • the first decorative layer 14 has a length and a width dimension and at least one of the length and width dimensions is smaller than the length and/or width dimension of the base layer 12 .
  • Subsequent layers, such as, for example, the second decorative layer 16 may have a length and/or a width dimension that is the same as or smaller that of the first decorative layer 14 .
  • the second decorative layer 16 may be affixed to the first decorative layer 14 such that the second layer 16 substantially covers the first decorative layer 14 .
  • the phrase “substantially covers” is intended to denote that the second layer 16 completely covers or nearly completely covers the first decorative layer 14 .
  • the first and second decorative layers have approximately the same length and width (i.e., are substantially the same size). Also, it is to be appreciated that the addition of the first and/or second decorative layer provides areas of greater thickness on the base layer, which provides a dimension to the shingle and an aesthetic appearance when viewed from a distance.
  • the second decorative layer 16 may have a length and/or a width dimension that is smaller than that of the first decorative layer 14 to offset the second decorative layer 14 from the first decorative layer 14 with only a partial overlap of the second decorative layer 16 on the first decorative layer.
  • the first decorative layer 14 is affixed to the base layer 12 with the adhesive composition.
  • the first decorative layer 14 has a size in a width dimension that is less than a size in the width dimension of the base layer 12 .
  • the second decorative layer 16 which has a size in the width dimension that is less than the width dimensions of both the first decorative layer 14 and the base layer 12 , is affixed to the top surface of the second decorative layer 14 to form a hip and ridge shingle 10 in accordance with at least one embodiment of the invention. It is to be appreciated that any number of configurations of the arrangements of the first and second decorative layers 14 , 16 on the base layer 12 and the sizes of the first and second decorative layers with respect to the base layer 12 are envisioned and are considered to be within the purview of the invention.
  • the shingle may be advantageously formed in-line using conventional roofing machines and existing roofing lines.
  • a base layer 12 is formed of a size large enough to accommodate several individual hip and ridge shingles.
  • a base shingle 40 formed of a base layer 12 including three separate hip and ridge shingles 10 can be seen.
  • a first decorative layer 14 and a second decorative layer 16 may be affixed to the base layer 12 in-line with the inventive adhesive being placed at each interface of the layers 12 , 14 , and 16 .
  • Perforations 15 separating the three separate shingles 10 may then be punched or otherwise formed into the base layer 12 .
  • the perforations 15 may be punched prior to the application of the first and second decorative layers.
  • the perforations 15 permit a worker to easily detach one hip and ridge shingle 10 from another at the jobsite without the need for any additional equipment.
  • the shingle 40 may not include perforations (not illustrated). If no perforations are present, the worker must cut or otherwise similarly detach the individual hip and ridge shingles 10 from the base shingle 40 .
  • the distance between the perforations and the resulting final size of the shingle 10 is dependent on the end use of the shingle 10 , and may include considerations such as the location where the shingle 10 will be used.
  • the perforations are about 12 inches or less from each other, thus forming shingles with a width of approximately 12 inches (or less).
  • the length of the shingle 10 may also be about 12 inches or less, and may or may not form a square shape.
  • FIG. 7 schematically illustrates the use of the hip and ridge single 10 .
  • the placement of shingles on the opposing planar portions 31 , 33 of the roof 30 which are overlapped by the hip and ridge shingle 10 have not been shown, one skilled in the art will understand that before the hip and ridge shingle 10 is folded over the ridge 35 of the roof 30 , the ridge 35 (which could also be a hip) being formed by the intersection of the two opposing planar surfaces 31 , 33 of the roof 30 , the shingles on the planar portions 31 , 33 are affixed to the roof 30 up to the ridge 35 .
  • the base shingle 40 starts in a flat orientation, such as is depicted in FIG.
  • one building may have a roof slope of 6:12, while another may have a 4:12 slope, thus resulting in the need for a ridge cap that can be mated to the roof.
  • the shingle 10 is detached from the base shingle 40 and is folded over the top of the ridge line 35 and secured in place, typically by nailing or otherwise mechanically affixing the hip and ridge shingle 10 to the roof.
  • Subsequent shingle pieces 10 are then placed in an overlapping arrangement, similar to the orientation of the courses of conventional shingles (e.g. three-tab shingles) on the planar portions of the roof 30 , beginning at one end of the ridge 35 and continuing to the opposing or distal end of the ridge 35 .
  • a first hip and ridge shingle may be mechanically affixed to the roof, such as by nailing through the first and second decorative layers and the base layer.
  • a subsequent hip and ridge shingle is then placed over the first shingle such that the exposed portion of the second hip and ridge shingle is positioned over the decorative layers of the first hip and ridge shingle. This process is repeated with additional hip and ridge shingles until the end of the ridge line or hip is reached. The exposed portion of each subsequent shingle is thus raised, thereby providing a three dimensional, aesthetically pleasing appearance to the ridge line or hip.
  • the cap 10 would be likely to crack or break because of the thickness of the shingle 10 and because of the use of rigid adhesives.
  • the respective layers can move relative to the adjacent layer to accommodate the increasing radius of curvature, as is reflected in the offset edges 27 along the transverse sides of the cap 10 .
  • the first decorative layer 14 is moved a distance of S 1 relative to the base member 12 and the second decorative layer 16 is moved a distance S 2 relative to the first decorative layer 14 .
  • the adhesive permits the relative movement and relaxes the stresses crated by folding the shingle 10 over the ridge.
  • An incidental benefit of this movement between the layers 12 , 14 , 16 is that the offset edges 27 along the transverse sides of the cap 10 provide an additional three dimensional depth to the cap 10 .
  • the adhesive composition of the present invention provides numerous advantages, such as, for example, flexibility at temperatures lower than or equal to about 40° F.
  • the hip and ridge shingle using the adhesive composition described herein can be manufactured in-line with conventional roofing machines on existing roofing lines. Incorporating the lamination of the decorative layers via the inventive adhesive in-line provides significant savings and an economic advantage.
  • the adhesive composition has little or no toxicity or safety issues, and, as a result, no additional safety precautions or equipment are needed to apply the adhesive to the layers forming the hip and ridge shingle.

Abstract

A laminated asphalt shingle including a base layer, a first decorative layer, and a second decorative layer is provided. The first decorative layer may be affixed to the base layer and to the second decorative layer by a flexible adhesive that permits the first decorative layer to move relative to both the base layer and the second decorative layer without de-bonding. The relative movement of the shingle layers permits the shingle to be folded over the ridge line of a roof without de-bonding or breaking the layers. Additionally, the relative movement of the layers when the shingle is installed over a ridge creates opposing transverse edges in which each layer is offset from the other layers as a result of the shingle bending about a different radius of curvature, thereby providing a dimensional appearance along the transverse edges.

Description

    CROSS-REFERENCE TO RELATED APPLICATIONS
  • This application is related to and claims domestic priority benefits from U.S. Provisional Patent Application Ser. No. 61/161,996 entitled “Low Temperature Shingle Sealant Composition” filed Mar. 20, 2009 and U.S. Provisional Patent Application Ser. No. 61/162,111 entitled “Low Temperature Shingle Sealant Composition” filed Mar. 20, 2009, the entire contents of which are expressly incorporated herein by reference in their entireties.
  • TECHNICAL FIELD AND INDUSTRIAL APPLICABILITY
  • The present invention relates generally to roofing shingles, and more particularly, to a flexible laminating adhesive for use with a multi-layered shingled product that permits the shingle product to be bent, such as over an apex of a roof, without cracking or breaking. In addition, flexible adhesive provides flexibility at temperatures lower than or equal to about 40° F.
  • BACKGROUND
  • Roofs are typically formed so as to present at least two non-parallel planes that meet at a peak, usually the uppermost point of the roof. This peak is typically referred to as the ridge. Roofs can also be formed to present other non-parallel planes that are often formed at the ends of the ridge to form other diagonally-extending plane intersections similar to the ridge, but are referred to as hips. Whereas, the covering of the planar portions of a roof typically involve the laying of shingles in overlapping, transversely parallel courses from the bottom roof edge to the ridge or hip, the ridges and hips require a different technique to cover the intersection of the two or more roof planes. A conventional technique for covering the ridges and hips is to cut the shingles into appropriate width and to bend the cut shingle over the ridge or hip so as to overlap the shingles placed on the opposing roof planes, and then starting at one end of the ridge or hip and overlap the cut shingles along the length of the ridge or hip.
  • Asphalt composite shingles are one of the most commonly used roofing products. These asphalt composite shingles typically incorporate a base material made from a fiberglass mat, or other suitable reinforcement member, such as an organic felt material. This reinforcing base material serves as a matrix to support an asphalt coating and gives the shingle strength. The asphalt coating is formulated for the particular service application and has a long-term ability to resist weathering and provide stability for the structure under extreme temperature conditions. An outer layer of granules is applied to the asphalt coating to form an outer surface that the asphalt coating from direct sunlight. This outer layer of granules also offers resistance to fire. Utilizing differently colored granules provides a variety in the surface appearance of the shingle to establish color variations.
  • Conventional laminated shingles, for example, as well as hip and ridge shingles, are generally multilayered and the separate, individual layers are held together with an adhesive material. One problem associated with conventional adhesives is that the adhesive can be too strong for a particular application. For instance, hip and ridge shingles are often formed of multiple layers or chips adhered to a base sheet in order to achieve a dimensional appearance when attached to a roof. However, when placing these multi-layered shingles along ridge or hip lines of a roof using conventional adhesives, a problem may occur when bending the shingle over the ridge or hip. In particular, because the thickest areas of the shingle include two or three layers of material, bending the shingle to cover the ridge or hip often results in a crack along the outer layer of the dimensional composite shingle, which compromises the integrity of the ridge or hip covering. Furthermore, if the adhesive holding the various layers together is too aggressive, the layers providing the dimensional appearance of the shingle may tear apart or otherwise cause the shingle to fail.
  • Thus, there exists a need in the art for an adhesive that will permit a multilayer shingle product to bend over the ridge or hip of a roof without failing, that does not pose any additional health or safety issues, is cost effective, and where the performance of the adhesive is sustainable over time
  • SUMMARY
  • In accordance with embodiments of the present invention, an adhesive composition that includes a base asphalt, a linear copolymer, and an oil is provided. In some exemplary embodiments, the adhesive composition also contains a radial copolymer and/or one or more fillers. The base asphalt used in the inventive adhesive composition may be a viscosity graded asphalt, such as AC-10 or AC-20, or a paving graded asphalt, such as PG58 or PG64. The linear copolymer has an A-B di-block or A-B-A tri-block structure where blocks A and B may individually represent (1) styrene and butadiene or (2) styrene and isoprene. The oil is a petroleum-based oil that both “softens” the asphalt in the composition and reduces the viscosity of the adhesive composition. In some exemplary embodiments, the adhesive composition also contains a radial copolymer having an (A-B)n radial structure, where n is an integer of at least 4, or a tri-block (A-B-A) radial structure having from 4-8 arms. The inventive adhesive composition permits a multilayered shingle to have a degree of flexibility, such as to permit the shingle to be bent over the ridge line or hip of a roof.
  • In other embodiments to shingles for use as a hip and ridge shingle that includes a base layer having a first length dimension and a first width dimension and a first decorative layer having a second length dimension and a second width dimension are provided. The first decorative layer is affixed to the base layer by a flexible adhesive that allows the first decorative layer to move relative to the base layer without cracking or breaking the first decorative layer. In the shingle, at least one of the second length dimension and second width dimension is the same as or smaller than the corresponding first length dimension and the first width dimension. In exemplary embodiments, a second decorative layer is affixed to the first decorative layer by the flexible adhesive. Similar to the first layer, the adhesive permits the second decorative layer to move relative to said first decorative layer without cracking or breaking either the first or second decorative layer. The second decorative layer may have a length and/or width dimension that is the same as or smaller than the corresponding length and width dimension of the first decorative layer. The adhesive composition includes a base asphalt, a linear copolymer, an oil, and optionally, a radial copolymer and/or one or more fillers. Additionally, the adhesive possesses sufficient flexibility and shear to permit a multilayered hip and ridge shingle to be bent over the ridge or hip of a roof without cracking or breaking, even at temperatures lower than or equal to about 40° F.
  • In yet other embodiments, hip and ridge shingles for covering a ridge line of a roof that includes (1) a base layer having a first length dimension and a first width dimension and (2) a first decorative layer having a second length dimension and a second width dimension where at least one of the second length and width dimensions is smaller than the corresponding first length and width dimensions are provided. The first decorative layer is affixed to the base layer by a flexible adhesive that allows a limited movement of the first decorative layer relative to the base layer to permit the first decorative layer to bend about a different radius of curvature than the base member when the hip and ridge shingle is bent over a ridge line. The hip and ridge shingle may also include a second decorative member affixed to the first decorative member by the flexible adhesive to allow a limited movement of the second decorative layer relative to the first decorative layer, thus allowing the second decorative layer to bend at a different radius of curvature than the first decorative layer. Additionally, each of the base layer, the first decorative layer, and the second decorative layer have opposing transverse edges that are offset when the hip and ridge shingle is installed on a ridge line or a hip of a roof.
  • It is an advantage of the present inventions that the adhesive composition is flexible such that the layers of a multilayer shingle can be bent over the ridge or hip of a roof with out breaking or cracking.
  • It is a further advantage of the present inventions that the adhesive provides for more flexibility at lower temperatures, such as temperatures lower than or equal to about 40° F.
  • It is also an advantage of the present inventions that the decorative layers of a laminated asphalt composite shingle are secured by a flexible adhesive that permits the decorative layers to shift transversely to allow the respective decorative layers to bend at different radii of curvature when the shingle is placed over a roof ridge or hip.
  • It is a further advantage of the present inventions that the respective decorative layers of a laminated asphalt composite shingle can bend at respective radii of curvature so that the decorative layers will not crack along the bend line.
  • It is yet another advantage of the present inventions that the adhesive composition does not pose any safety or health issues to workers involved in their manufacture and/or application.
  • It is also an advantage of the present inventions that the asphaltic adhesive is useful in winter applications and in colder climates.
  • It is an advantage of the present inventions that the individual layers of the shingle will bend at a radius of curvature that accommodates the thickness of the shingle being bent to cover the ridge or hip of a roof.
  • It is yet another advantage of the present inventions that the exposed portion of the hip and ridge shingle is positioned on the decorative layers of a previously laid hip and ridge single when affixed to a ridge or hip of a roof, thereby providing a three dimensional, aesthetically pleasing appearance.
  • It is a further advantage of the present inventions that the slipping of the individual decorative layers of a laminated composite shingle when bent to cover a ridge or hip of a roof results in an exposure of the underlying layer along the longitudinal length of the shingle.
  • The foregoing and other objects, features, and advantages of the inventions will appear more fully hereinafter from a consideration of the detailed description that follows.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • The advantages of this invention will be apparent upon consideration of the following detailed disclosure of the invention, especially when taken in conjunction with the accompanying drawings wherein:
  • FIG. 1 is a schematic top plan view of an embodiment of a hip and ridge shingle formed according to the principles of the instant invention, the shingle being shown in a flat orientation with the decorative layers being representatively placed on a central portion of the shingle;
  • FIG. 2 is a schematic end elevational view of the hip and ridge shingle depicted in FIG. 1;
  • FIG. 3 is a schematic front elevational view of the hip and ridge shingle depicted in FIG. 1; and
  • FIG. 4 is a schematic top plan view of an embodiment of a hip and ridge shingle formed according to the principles of the instant invention, the shingle being shown in a flat orientation with the decorative layers being representatively placed on a central portion of the shingle;
  • FIG. 5 is a schematic end elevational view of the hip and ridge shingle depicted in FIG. 4;
  • FIG. 6 is a schematic top plan view of a base shingle containing three separate hip and ridge shingles with perforations therebetween to facilitate separation of the hip and ridge shingles from the base shingle; and
  • FIG. 7 is a schematic front elevational view of the hip and ridge shingle being bent to form a ridge or hip cover, the slippage of the individual layers being seen along the sides of the bent shingle.
  • DETAILED DESCRIPTION
  • Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which the invention belongs. All references cited herein, including published or corresponding U.S. or foreign patent applications, issued U.S. or foreign patents, or any other references, are each incorporated by reference in their entireties, including all data, tables, figures, and text presented in the cited references. The terms “adhesive”, “inventive adhesive”, “adhesive composition”, “laminating adhesive”, and “laminating adhesive composition” may interchangeably be used herein. In addition, the terms “cap shingle”, “cap”, or “hip and ridge shingle” may be used interchangeably herein.
  • The present inventions relate, at least in part, to a flexible adhesive composition for use with hip and ridge shingles (cap shingle) that includes a base asphalt, a linear copolymer, an oil, and, optionally, a radial copolymer and/or one or more fillers. The adhesive possesses sufficient flexibility and shear to permit a multilayered hip and ridge shingle to be bent over the ridge or hip of a roof without cracking or breaking. In addition, the adhesive provides for more flexibility at lower temperatures, such as temperatures lower than or equal to about 40° F.
  • The laminating adhesive composition contains, as one component, a base asphalt or other hydrocarbonaceous material. As used herein, the term “asphalt” is meant to include any of a variety of materials that are solid or semi-solid materials at room temperature that gradually liquefy when heated and are formed predominantly of naturally occurring bitumens obtained as residue in petroleum refining. The base asphalt used in the inventive adhesive composition is desirably a viscosity graded asphalt or an AC-10 paving grade asphalt such as PG58-22, which is commercially available British Petroleum and Conoco Philips and/or an AC-20 paving grade asphalt such as PG64-22, which is also commercially available from British Petroleum and Conoco Philips. The base asphalt may be generally present in the adhesive composition in an amount from about 79.0% to about 90.5% by weight of the composition. In exemplary embodiments, the base asphalt may be present in the adhesive composition in an amount from about 81% to about 88% by weight of the composition. As used herein, and unless defined otherwise, the phrase “% by weight” is meant to denote % by weight of the total adhesive composition.
  • As discussed above, the adhesive composition contains a linear copolymer, and, optionally, a radial copolymer, each of which is described in detail below. The copolymers are thermoplastic and are selected for their ability to impart strength to the adhesive at colder temperatures and to provide sufficient flexibility and/or shear. As with conventional thermoplastic organic polymers, the copolymers used in the inventive adhesive can be processed (i.e., melted and extruded) and can be repeatedly heated and cooled with no substantial loss in their properties, including elastomeric properties. Accordingly, the copolymers used herein substantially retain their properties when subjected to heating and cooling cycles. One particular advantageous feature is the ability of the copolymers to retain strength upon cooling the copolymers, which gives both strength and flexibility to the adhesive at colder temperatures.
  • The adhesive composition contains a linear copolymer having an A-B di-block or A-B-A tri-block structure. In particular, the linear copolymer has a di-block content greater than 50%. Blocks A and B may individually represent (1) styrene and butadiene or (2) styrene and isoprene. Either block, A or B, may include more than one monomer. Additionally, each block segment may include 100 or more monomer units. The linear copolymer may have a styrene content of less than 50%, from about 20% to about 40% styrene, or from about 20% to about 35% styrene. In some embodiments, the linear copolymer has a styrene/butadiene ratio of 33/67. In some examples the linear copolymer have styrene or polystyrene as the A block or end block units. Suitable copolymers include styrene-butadiene block copolymers and styrene-isoprene block copolymers. Specific, non-limiting examples include D1118K, a styrene-butadiene-styrene di-block copolymer, and D1113K, and D1119K, styrene-isoprene-styrene linear polymers with a high-di-block content (all are commercially available from Kraton®). In some examples, the linear copolymer is a styrene-butadiene di-block copolymer, such as D1118K, commercially available from Kraton®. The linear di-block copolymer may be present in the inventive adhesive composition in an amount from about 2.5% to about 11.0% by weight of the composition. In some embodiments, the linear copolymer is present in the adhesive composition in an amount from about 2.5% to about 6.5% by weight of the composition. In some exemplary embodiments, the linear copolymer may be present in the adhesive composition in a greater amount, such as, for example, from about 10.0-14.0% by weight of the composition, or from 11.0-12.0% by weight.
  • Optionally, the adhesive composition may contain a radial copolymer. The radial copolymer may have an (A-B)n radial structure, where n is an integer of at least 4, or from 4-20, or a tri-block (A-B-A) radial structure having from 4-8 arms. Block copolymers are well known and are described in numerous patents, including, for example, U.S. Pat. No. 4,738,884 to Algrim, et al., U.S. Pat. No. 4,824,880 to Algrim, et al., and U.S. Pat. No. 6,759,454 to Stephens, et al., each of which is incorporated by reference in their entirety. Similar to the linear copolymer, block A and/or B in the radial copolymer may include more than one monomer and each block segment may include 100 or more monomer units. Additionally, blocks A and B may individually represent (1) styrene and butadiene or (2) styrene and isoprene. It is desirable that the radial polymer have styrene or polystyrene as the A block or end block units. The radial copolymer may have a styrene content of less than 50%, from about 20% to about 40% styrene, or from about 20% to about 35% styrene. In some examples, the styrene/butadiene ratio is 31/69.
  • Exemplary radial copolymers include D4158K (includes 33% oil), D1184K, D1116K, and D1144K, all of which are styrene-butadiene-styrene (SBS) radial copolymers (commercially available from Kraton®), and D1124K and D1126P, both of which are styrene-isoprene radial copolymers (commercially available from Kraton®). In some embodiments, the radial copolymer is a styrene-butadiene radial copolymer, such as D4158K or D1184K (commercially available from Kraton®). The radial copolymer may be present in the adhesive composition in an amount from 0% to about 9.0% by weight of the composition. In exemplary embodiments, the radial copolymer may be present in the adhesive composition in an amount from about 3.5% to about 7.0% by weight of the composition.
  • When both a linear and a radial copolymer are present in the inventive adhesive, the total amount of the radial copolymer and the linear copolymer present in the adhesive composition may range from about 6.5% to about 14.0%, or from about 8.0% to about 11.0% of the total composition. Additionally, the ratio of radial copolymer to linear copolymer present in the adhesive composition may range from 6:3 to 2:6 (radial copolymer:linear copolymer). In some examples, the ratio of radial copolymer to linear copolymer present in the adhesive composition is 5:4.
  • Another component present in the adhesive composition is an oil. The oil can be any oil recognized in the art to enhance the “softness” of the asphalt in the adhesive composition. The oil also aids in reducing the viscosity of the adhesive composition. In general, the oil is added in an amount necessary to achieve a desired viscosity for the adhesive composition, and to improve flexibility and low temperature bonding. The viscosity of the adhesive composition desirably does not exceed approximately 1500 cps as measured by a Brookfield LVF Viscometer using spindle number 7 at 350° F. The oil utilized in the adhesive composition may be a petroleum-based oil or other naphthenic or paraffinic oils identified by one of ordinary skill in the art. One particularly useful oil is Hydrolene SP-125, a severely solvent modified heavy petroleum oil commercially available from Sunoco, Inc. (CAS No. 63741-88-4). The oil, in combination with the selected copolymers, acts to give the flexibility and shear so that the adhesive can be used in conjunction with hip and ridge shingles, even at colder temperatures. The oils and copolymer(s) permit the adhesive to flex and/or shear so that the layers of the hip and ridge shingle “slide” over each other upon bending and remain laminated together, without cracking or breaking the dimensional elements adhering to the base of the shingle. The oil may be present in the adhesive composition in a total amount from about 2.0% to about 7.0% of the total adhesive composition, or from about 4.0% to about 6.0%. It is to be appreciated that a portion of the total oil content may be derived from another component of the adhesive composition, such as, for example, an oil-containing copolymer.
  • In some exemplary embodiments, fillers may be added to any of the adhesive roofing sealant compositions. For example, up to about 30% by weight of a filler may be used. Suitable fillers include, but are not limited to, limestone (calcium carbonate), dolomite (calcium magnesium carbonate), wollastonite, talc, silica, and others known to those skilled in the art. The filler may have a median particle size from about 5 microns to about 50 microns, or from about 10 microns to about 30 microns.
  • One adhesive composition is set forth in Table 1.
  • TABLE 1
    Components of Alternate % By
    Roofing Shingle % By Weight of Weight of
    Adhesive Composition Composition Composition
    PG64-22(1) 79.0-86.0 82.0-84.0
    Kraton 1111(2) 10.0-14.0 11.0-12.0
    Hydrolene SP-125(3) 4.0-7.0 5.0-6.0
    (1)performance grade asphalt (commercially available from British Petroleum and Conoco Philips)
    (2)styrene-isoprene-styrene tri-block copolymer (commercially available from Kraton ®)
    (4)petroleum-based oil (commercially available from Sunoco, Inc.)
  • A second adhesive composition is set forth in Table 2.
  • TABLE 2
    Components of Alternate % By
    Roofing Shingle % By Weight of Weight of
    Adhesive Composition Composition Composition
    PG58-22(1) 79.5-88.5 81.0-86.0
    Kraton 4158(2) 5.55-8.55 6.3-7.8
    Kraton 1118(3) 4.6-7.6 5.6-7.6
    Hydrolene SP-125(4) 1.35-4.35 2.1-3.6
    (1)performance grade asphalt (commercially available from British Petroleum and Conoco Philips)
    (2)styrene-butadiene radial copolymer containing oil (commercially available from Kraton ®)
    (3)styrene-butadiene di-block copolymer (commercially available from Kraton ®)
    (4)petroleum-based oil (commercially available from Sunoco, Inc.)
  • A third adhesive composition is set forth in Table 3. The inventive adhesive compositions described herein can be reacted with elemental sulfur to vulcanize in situ. Table 3 depicts an exemplary composition containing a mixture of two linear copolymers (i.e., di-block and tri-block styrene-butadiene copolymers). After dispersion in the base asphalt and oil, the copolymer blend may be crosslinked with sulfur. The addition of the sulfur to polymer modified asphalts enhances dispersion stability and improves mechanical properties.
  • TABLE 3
    Components of Alternate % By
    Roofing Shingle % By Weight of Weight of
    Adhesive Composition Composition Composition
    PG64-22(1) 79.7-89.4 82.3-86.4
    Kraton 1101(2) 4.0-8.0 6.0-7.0
    Kraton 1118(3) 2.5-5.0 2.5-3.5
    Hydrolene SP-125(4) 4.0-7.0 5.0-6.0
    Elemental sulfur 0.1-0.3 0.1-0.2
    (1)performance grade asphalt (commercially available from British Petroleum and Conoco Philips)
    (2)styrene-butadiene-styrene linear tri-block copolymer (commercially available from Kraton ®)
    (3)styrene-butadiene di-block copolymer (commercially available from Kraton ®)
    (4)petroleum-based oil (commercially available from Sunoco, Inc.)
  • Conventional mixing or blending techniques may be used to make the adhesive composition. In at least one exemplary embodiment, the base asphalt is heated to a temperature of approximately 350° F. and the oil is blended into the molten asphalt. The linear copolymer is added to the molten asphalt/oil to form a mixture. If a radial copolymer is included in the composition, it may be added along with the linear copolymer. The mixture is then placed into a conventional milling apparatus where the polymers are sheared into smaller polymeric pieces. The mixture is ground in the milling apparatus for a period of time sufficient to mill (grind) the polymers to a size that is no longer visible to the naked eye under UV light. The adhesive composition is cooled for packaging and then melted for application to a shingle. It may be desirable to circulate and maintain the adhesive at an elevated temperature during processing and application to the shingles to aid in the prevention of phase separation.
  • Turning to FIGS. 1-3, a hip and ridge shingle according to at least one exemplary embodiment of the invention can best be seen. The laminated hip and ridge shingle 10 may include a base layer 12. The base layer 12 may be formed in a conventional manner, and in some embodiments includes a reinforcement member, such as a fiberglass mat, on which asphalt and decorative granules are placed. As one example, chopped glass fibers may be dispersed into a water slurry which may contain surfactants, viscosity modifiers, or other chemical agents. The slurry containing the dispersed fibers is then deposited onto a moving screen where a substantial portion of the water is removed. Next, a binder (e.g., a urea formaldehyde binder or a polycarboxylic acid based binder) is applied, and the resulting mat is dried to remove the remaining water and cure the binder. The mat, formed of an assembly of randomly oriented, dispersed individual glass filaments, may be dried in any conventional manner, such as by passing the mat through an oven. Asphalt may then be applied to the dried/cured mat in any known manner, such as by passing the mat through a bath containing an asphalt mix that may include molten asphalt, fillers, and optionally sulfur, to place a layer of asphalt on at least one side of the mat and fill in the interstices between the individual glass fibers. The asphalt-coated mat is then cut to the appropriate shape and size to form the base layer 12. The hot, asphalt-coated mat may also be passed beneath one or more granule applicators that apply protective surface granules to portions of the asphalt-coated mat prior to cutting into the desired shape.
  • A similarly constructed first decorative or dimensional layer 14 is positioned on and adhered to the base layer 12 to provide a desired aesthetic appearance. Optionally, a second decorative (dimensional) layer 16 may be affixed on the first decorative layer 14 to provide greater depth to the composite shingle 10 and an enhanced three dimensional aesthetic appearance, particularly when viewed from a distance. It is to be appreciated that although the drawings reflect two decorative layers 14, 16 that are positioned across the width of the base layer 12, one skilled in the art will recognize that the decorative layers 14, 16 can be placed in any appropriate arrangement or orientation on the base layer 12 to provide a desired aesthetic appearance. Accordingly, the principles of the present invention are not limited to the specific location, size of the layers, or positioning of the decorative layers 14, 16, or the bending of the shingle to form a ridge or hip cap, as described in greater detail below, that requires the bending of all layers of the shingle irrespective of the location of the decorative layers 14, 16.
  • The respective layers 12, 14, 16 of the hip and ridge shingle 10 are adhered to one another via the flexible adhesive described in detail above. To form the hip and ridge shingle 10, the first decorative layer 14 is positioned at a desired location on the base layer 12 and affixed thereto with the inventive adhesive composition. The adhesive can be applied in a continuous or discontinuous fashion, such as in the form of beads or “dashes”. In at least one embodiment (not illustrated), the first decorative layer 14 may be the same size or substantially the same size as the base layer 12. In other embodiments, the first decorative layer 14 may have a width that is smaller then the width of the base layer 12, such as is shown in FIGS. 1-3. In general, the first decorative layer 14 has a length and a width dimension and at least one of the length and width dimensions is smaller than the length and/or width dimension of the base layer 12. Subsequent layers, such as, for example, the second decorative layer 16, may have a length and/or a width dimension that is the same as or smaller that of the first decorative layer 14. For instance, the second decorative layer 16 may be affixed to the first decorative layer 14 such that the second layer 16 substantially covers the first decorative layer 14. As used herein, the phrase “substantially covers” is intended to denote that the second layer 16 completely covers or nearly completely covers the first decorative layer 14. In FIGS. 1-3, the first and second decorative layers have approximately the same length and width (i.e., are substantially the same size). Also, it is to be appreciated that the addition of the first and/or second decorative layer provides areas of greater thickness on the base layer, which provides a dimension to the shingle and an aesthetic appearance when viewed from a distance.
  • In an alternate embodiment, the second decorative layer 16 may have a length and/or a width dimension that is smaller than that of the first decorative layer 14 to offset the second decorative layer 14 from the first decorative layer 14 with only a partial overlap of the second decorative layer 16 on the first decorative layer. As shown in FIGS. 4 and 5, the first decorative layer 14 is affixed to the base layer 12 with the adhesive composition. The first decorative layer 14 has a size in a width dimension that is less than a size in the width dimension of the base layer 12. The second decorative layer 16, which has a size in the width dimension that is less than the width dimensions of both the first decorative layer 14 and the base layer 12, is affixed to the top surface of the second decorative layer 14 to form a hip and ridge shingle 10 in accordance with at least one embodiment of the invention. It is to be appreciated that any number of configurations of the arrangements of the first and second decorative layers 14, 16 on the base layer 12 and the sizes of the first and second decorative layers with respect to the base layer 12 are envisioned and are considered to be within the purview of the invention.
  • The shingle may be advantageously formed in-line using conventional roofing machines and existing roofing lines. Initially, a base layer 12 is formed of a size large enough to accommodate several individual hip and ridge shingles. Turning to FIG. 6, a base shingle 40 formed of a base layer 12 including three separate hip and ridge shingles 10 can be seen. To form a hip and ridge shingle 10, a first decorative layer 14 and a second decorative layer 16 may be affixed to the base layer 12 in-line with the inventive adhesive being placed at each interface of the layers 12, 14, and 16. Perforations 15 separating the three separate shingles 10 may then be punched or otherwise formed into the base layer 12. In some embodiments, the perforations 15 may be punched prior to the application of the first and second decorative layers. The perforations 15 permit a worker to easily detach one hip and ridge shingle 10 from another at the jobsite without the need for any additional equipment. Alternatively, the shingle 40 may not include perforations (not illustrated). If no perforations are present, the worker must cut or otherwise similarly detach the individual hip and ridge shingles 10 from the base shingle 40. The distance between the perforations and the resulting final size of the shingle 10 is dependent on the end use of the shingle 10, and may include considerations such as the location where the shingle 10 will be used. For example, some regions of the United States use a smaller hip and ridge shingle than other regions. Generally, the perforations are about 12 inches or less from each other, thus forming shingles with a width of approximately 12 inches (or less). The length of the shingle 10 may also be about 12 inches or less, and may or may not form a square shape.
  • FIG. 7 schematically illustrates the use of the hip and ridge single 10. Although the placement of shingles on the opposing planar portions 31, 33 of the roof 30 which are overlapped by the hip and ridge shingle 10 have not been shown, one skilled in the art will understand that before the hip and ridge shingle 10 is folded over the ridge 35 of the roof 30, the ridge 35 (which could also be a hip) being formed by the intersection of the two opposing planar surfaces 31, 33 of the roof 30, the shingles on the planar portions 31, 33 are affixed to the roof 30 up to the ridge 35. The base shingle 40 starts in a flat orientation, such as is depicted in FIG. 7, for the ease of shipping and because the ridges and hips are formed at variable angles. For instance, one building may have a roof slope of 6:12, while another may have a 4:12 slope, thus resulting in the need for a ridge cap that can be mated to the roof.
  • In use, the shingle 10 is detached from the base shingle 40 and is folded over the top of the ridge line 35 and secured in place, typically by nailing or otherwise mechanically affixing the hip and ridge shingle 10 to the roof. Subsequent shingle pieces 10 are then placed in an overlapping arrangement, similar to the orientation of the courses of conventional shingles (e.g. three-tab shingles) on the planar portions of the roof 30, beginning at one end of the ridge 35 and continuing to the opposing or distal end of the ridge 35. In particular, a first hip and ridge shingle may be mechanically affixed to the roof, such as by nailing through the first and second decorative layers and the base layer. A subsequent hip and ridge shingle is then placed over the first shingle such that the exposed portion of the second hip and ridge shingle is positioned over the decorative layers of the first hip and ridge shingle. This process is repeated with additional hip and ridge shingles until the end of the ridge line or hip is reached. The exposed portion of each subsequent shingle is thus raised, thereby providing a three dimensional, aesthetically pleasing appearance to the ridge line or hip.
  • It is to be appreciated that if the topmost decorative layer 16 were required to bend at the radius of curvature corresponding to the base layer 12 in a conventional shingle, the cap 10 would be likely to crack or break because of the thickness of the shingle 10 and because of the use of rigid adhesives. However, due to the flexibility of the inventive adhesive, the respective layers can move relative to the adjacent layer to accommodate the increasing radius of curvature, as is reflected in the offset edges 27 along the transverse sides of the cap 10. In the three-layer shingle 10 depicted in FIG. 7, the first decorative layer 14 is moved a distance of S1 relative to the base member 12 and the second decorative layer 16 is moved a distance S2 relative to the first decorative layer 14. The adhesive permits the relative movement and relaxes the stresses crated by folding the shingle 10 over the ridge. An incidental benefit of this movement between the layers 12, 14, 16 is that the offset edges 27 along the transverse sides of the cap 10 provide an additional three dimensional depth to the cap 10.
  • The adhesive composition of the present invention provides numerous advantages, such as, for example, flexibility at temperatures lower than or equal to about 40° F. In addition, it is envisioned that the hip and ridge shingle using the adhesive composition described herein can be manufactured in-line with conventional roofing machines on existing roofing lines. Incorporating the lamination of the decorative layers via the inventive adhesive in-line provides significant savings and an economic advantage. Further, the adhesive composition has little or no toxicity or safety issues, and, as a result, no additional safety precautions or equipment are needed to apply the adhesive to the layers forming the hip and ridge shingle.
  • The invention of this application has been described above both generically and with regard to specific embodiments. Therefore, it is to be understood that a wide variety of alternatives known to those of skill in the art can be selected within the generic disclosure. The invention is not otherwise limited, except for the recitation of the claims set forth below.

Claims (22)

1. A shingle for use as a hip and ridge shingle:
a base layer having a first length dimension and a first width dimension; and
a first decorative layer having a second length dimension and a second width dimension,
wherein at least one of said second length dimension and said second width dimension is the same as or smaller than said first length dimension and said first width dimension, and
wherein said first decorative layer is affixed to said base layer by a flexible adhesive that allows a movement of said first decorative layer relative to said base layer without cracking or breaking said first decorative layer.
2. The shingle of claim 1, further comprising:
a second decorative layer affixed to said first decorative layer by said flexible adhesive, said flexible adhesive permitting said second decorative layer to move relative to said first decorative layer without cracking or breaking said first or second decorative layer.
3. The shingle of claim 1, wherein at least one of said second length and width dimensions is the same as or smaller than the corresponding first length and width dimension.
4. The shingle of claim 1, wherein said flexible adhesive comprises:
a hydrocarbonaceous material;
a linear copolymer having an A-B di-block or an A-B-A tri-block structure; and
an oil.
5. The shingle of claim 4, wherein said oil is selected from petroleum-based oils, naphthenic oils, paraffinic oils and combinations thereof.
6. The shingle of claim 4, further comprising a member selected from one or more fillers, a radial copolymer and combinations thereof, said radial copolymer being selected from a block copolymer having an (A-B)n radial structure where n is an integer of at least 4 and a block copolymer having a tri-block (A-B-A) radial structure having from 4-8 arms.
7. The shingle of claim 6, wherein said radial copolymer is selected from styrene-butadiene-styrene (SBS) radial copolymers and styrene-isoprene radial copolymers, and
wherein the copolymer forming said linear copolymer is selected from styrene-butadiene block copolymers and styrene-isoprene block copolymers.
8. The shingle of claim 4, wherein said adhesive provides flexibility at temperatures as less than or equal to about 40° F.
9. A hip and ridge shingle for covering a ridge line or hip of a roof comprising:
a base layer having a first length dimension and a first width dimension; and
a first decorative layer having a second length dimension and a second width dimension, at least one of said second length and width dimensions being smaller than the corresponding first length and width dimensions,
wherein said first decorative layer is affixed to said base layer by a flexible adhesive that allows a limited movement of said first decorative layer relative to said base layer to permits said first decorative layer to bend about a different radius of curvature than said base member when said hip and ridge is bent over said ridge line or said hip.
10. The hip and ridge shingle of claim 9, further comprising:
a second decorative member affixed to said first decorative member by said flexible adhesive to allow a limited movement of said second decorative layer relative to said first decorative layer, thus allowing said second decorative layer to bend at a different radius of curvature than said first decorative layer.
11. The hip and ridge shingle of claim 9, wherein each of said base layer, said first decorative layer, and said second decorative layer have opposing transverse edges, the corresponding said transverse edges of said first decorative layer being offset relative to said base layer and relative to said second decorative layer when said hip and ridge shingle is installed on said ridge line or said hip.
12. The hip and ridge shingle of claim 9, wherein said adhesive provides flexibility at temperatures less than or equal to about 40° F.
13. The hip and ridge shingle of claim 12, wherein said flexible adhesive comprises:
a hydrocarbonaceous material;
a linear copolymer having an A-B di-block or an A-B-A tri-block structure; and
an oil.
14. The hip and ridge shingle of claim 13, wherein said oil is selected from petroleum-based oils, naphthenic oils, paraffinic oils and combinations thereof.
15. The hip and ridge shingle of claim 13, further comprising a member selected from one or more fillers, a radial copolymer and combinations thereof, said radial copolymer being selected from a block copolymer having an (A-B)n radial structure where n is an integer of at least 4 and a block copolymer having a tri-block (A-B-A) radial structure having from 4-8 arms.
16. A hip and ridge shingle for mounting on a roof to cover a ridge line or hip of said roof, comprising:
a base layer having a first length dimension and a first width dimension;
a first decorative layer having a second length dimension and a second width dimension;
a second decorative layer affixed to said first decorative layer to provide areas of greater thickness on said base member; and
a flexible adhesive securing said first decorative layer to said base layer and said first decorative layer to said second decorative layer such that said first layer is operable to move relative to both said base layer and said second decorative layer to permit each of said base layer, said first decorative layer and said second decorative layer to bend with a different radius of curvature when said hip and ridge shingle is applied to said roof over said ridge line or said hip.
17. The hip and ridge shingle of claim 16, wherein said flexible adhesive permits said first and second decorative layers to move relative to each other and said base layer said without cracking or breaking said first or second decorative layer.
18. The hip and ridge shingle of claim 16, wherein at least one of said second length and width dimensions is smaller than the corresponding first length and width dimensions, said first decorative layer being affixed to said base layer.
19. The hip and ridge shingle of claim 18, wherein each of said base layer, said first decorative layer, and said second decorative layer have opposing transverse edges, the corresponding said transverse edges of said first decorative layer being offset relative to said base layer and relative to said second decorative layer when said hip and ridge shingle is installed on said ridge line or said hip.
20. The hip and ridge shingle of claim 16, wherein said flexible adhesive comprises:
a hydrocarbonaceous material;
a linear copolymer having an A-B di-block or an A-B-A tri-block structure; and
an oil.
21. The hip and ridge shingle of claim 14, wherein said oil is selected from petroleum-based oils, naphthenic oils, paraffinic oils and combinations thereof.
22. The hip and ridge shingle of claim 15, further comprising a member selected from one or more fillers, a radial copolymer and combinations thereof, said radial copolymer being selected from a block copolymer having an (A-B)n radial structure where n is an integer of at least 4 and a block copolymer having a tri-block (A-B-A) radial structure having from 4-8 arms.
US12/727,459 2009-03-20 2010-03-19 Flexible laminated hip and ridge shingle Abandoned US20100239807A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US12/727,459 US20100239807A1 (en) 2009-03-20 2010-03-19 Flexible laminated hip and ridge shingle
US14/751,334 US9482007B2 (en) 2009-03-20 2015-06-26 Flexible laminated hip and ridge shingle

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US16199609P 2009-03-20 2009-03-20
US16211109P 2009-03-20 2009-03-20
US12/727,459 US20100239807A1 (en) 2009-03-20 2010-03-19 Flexible laminated hip and ridge shingle

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US14/751,334 Continuation US9482007B2 (en) 2009-03-20 2015-06-26 Flexible laminated hip and ridge shingle
US14/751,334 Division US9482007B2 (en) 2009-03-20 2015-06-26 Flexible laminated hip and ridge shingle

Publications (1)

Publication Number Publication Date
US20100239807A1 true US20100239807A1 (en) 2010-09-23

Family

ID=42736284

Family Applications (4)

Application Number Title Priority Date Filing Date
US12/727,470 Active 2030-06-13 US9574350B2 (en) 2009-03-20 2010-03-19 Sealant composition for releasable shingle
US12/727,459 Abandoned US20100239807A1 (en) 2009-03-20 2010-03-19 Flexible laminated hip and ridge shingle
US14/751,334 Active US9482007B2 (en) 2009-03-20 2015-06-26 Flexible laminated hip and ridge shingle
US15/397,850 Active US10273392B2 (en) 2009-03-20 2017-01-04 Sealant composition for releasable shingle

Family Applications Before (1)

Application Number Title Priority Date Filing Date
US12/727,470 Active 2030-06-13 US9574350B2 (en) 2009-03-20 2010-03-19 Sealant composition for releasable shingle

Family Applications After (2)

Application Number Title Priority Date Filing Date
US14/751,334 Active US9482007B2 (en) 2009-03-20 2015-06-26 Flexible laminated hip and ridge shingle
US15/397,850 Active US10273392B2 (en) 2009-03-20 2017-01-04 Sealant composition for releasable shingle

Country Status (2)

Country Link
US (4) US9574350B2 (en)
CA (2) CA2697221C (en)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9017791B2 (en) 2008-05-13 2015-04-28 Owens Corning Intellectual Capital, Llc Shingle blank having formation of individual hip and ridge roofing shingles
US9074373B2 (en) 2013-03-04 2015-07-07 Certainteed Corporation System, method and apparatus for adding thickness to roofing products
US9097020B2 (en) 2010-03-04 2015-08-04 Owens Corning Intellectual Capital, Llc Hip and ridge roofing shingle
US9151055B2 (en) 2009-02-25 2015-10-06 Owens Corning Intellectual Capital, Llc Hip and ridge roofing material
US9290943B2 (en) 2012-01-05 2016-03-22 Owens Corning Intellectual Capital, Llc Hip and ridge roofing shingle
USD755997S1 (en) 2014-02-27 2016-05-10 Owens Corning Intellectual Capital, Llc Shingle
US9482007B2 (en) 2009-03-20 2016-11-01 Owens Corning Intellectual Capital, Llc Flexible laminated hip and ridge shingle
US9758970B2 (en) 2014-02-25 2017-09-12 Owens Corning Intellectual Capital, Llc Laminated hip and ridge shingle
US9834935B2 (en) 2011-09-13 2017-12-05 Owens Corning Intellectual Capital, Llc Granule coated waterproof roofing membrane
US20190186141A1 (en) * 2017-12-15 2019-06-20 Owens Corning Intellectual Capital, Llc Polymer modified asphalt roofing material
US10358824B2 (en) 2016-05-06 2019-07-23 Owens Corning Intellectual Capital, Llc Shingle sealing arrangements
US10370853B2 (en) * 2016-04-20 2019-08-06 Owens Corning Intellectual Capital, Llc Hip and ridge/starter shingle combination
US11313127B2 (en) 2009-02-25 2022-04-26 Owens Corning Intellectual Capital, Llc Hip and ridge roofing material
US11447953B2 (en) * 2017-07-20 2022-09-20 Zinniatek Limited Roof, siding, or cladding, or ridge or hip member for a roof

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20150099466A (en) 2014-02-21 2015-08-31 오웬스 코닝 인텔렉츄얼 캐피탈 엘엘씨 Shingles with increased hydrophobicity
US20160090512A1 (en) 2014-09-25 2016-03-31 Tamko Building Products, Inc. System and method for reducing viscosity variations in roofing asphalt
US10774535B2 (en) * 2016-11-14 2020-09-15 Owens Corning Intellectual Capital, Llc Asphalt shingles with a fire-retardant additive
US11927017B2 (en) 2017-06-05 2024-03-12 Millennuim Slate, LLC Roofing system and method
US11578494B2 (en) 2017-06-05 2023-02-14 Millennium Slate, Llc Roofing system and method
US10829937B2 (en) * 2017-06-05 2020-11-10 Millennium Slate, Llc Roofing system and method
US10865565B2 (en) 2018-07-11 2020-12-15 Owens Coming Intellectual Capital, LLC Shingles with increased hydrophobicity
USD923710S1 (en) * 2020-01-10 2021-06-29 Brilliant Graphics Group, LLC Roofing material display
US11346108B2 (en) 2020-01-10 2022-05-31 Bmic Llc Roofing shingles with registered self-seal strip patterns
USD940240S1 (en) * 2020-01-20 2022-01-04 Brilliant Graphics Group, LLC Roofing material display
USD923711S1 (en) * 2020-01-20 2021-06-29 Brilliant Graphics Group, LLC Roofing material display
USD939630S1 (en) * 2020-02-04 2021-12-28 Brilliant Graphics Group, LLC Bi-fold roofing material display
MX2021002565A (en) 2020-03-05 2021-09-06 Building Mat Investment Corp Systems and methods for applying dots of different adhesives to moving roofing shingle stock.
CN111349419A (en) * 2020-04-09 2020-06-30 山东普文特建材有限公司 High-elasticity building sealant
CA3128681A1 (en) 2020-08-21 2022-02-21 Building Materials Investment Corporation Roofing materials with improved low temperature sealant performance and methods of making thereof
CN112443081B (en) * 2020-10-23 2022-04-29 湖南省建新建材有限公司 Quick mounting structure of synthetic resin tile
USD972033S1 (en) * 2020-10-28 2022-12-06 Brilliant Graphics Group, LLC Roofing material display
MX2022002412A (en) * 2021-02-26 2023-01-18 Bmic Llc Roofing systems utilizing cap shingles with self-sealing adhesives.

Citations (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1495070A (en) * 1923-06-20 1924-05-20 Paraffine Co Inc Strip shingle
US1516243A (en) * 1920-11-23 1924-11-18 Barrett Co Roofing
US4194335A (en) * 1977-12-08 1980-03-25 Diamond John N Single sheathing roof panel
US4352837A (en) * 1977-06-20 1982-10-05 Certain-Teed Corporation Method of manufacturing roofing shingles having multiple ply appearance
US4637191A (en) * 1984-12-03 1987-01-20 Smith Robert L Starter shingle
US4789066A (en) * 1983-11-25 1988-12-06 Ex-Cell-O Corporation Container with protective seal and tear strip
US4856251A (en) * 1987-02-20 1989-08-15 Buck Donald A Self-gauging, anti-ice damming, double sealed shingle system
US5036119A (en) * 1989-10-16 1991-07-30 Shell Oil Company Process for preparing bituminous composition
US5271201A (en) * 1992-06-16 1993-12-21 Certainteed Corporation Hip or ridge shingle
USD347900S (en) * 1992-02-28 1994-06-14 Minnesota Mining And Manufacturing Company Laminated shingle
US5365711A (en) * 1993-04-28 1994-11-22 Pressutti Joseph E Low-cost highly aesthetic and durable shingle
US5419941A (en) * 1992-06-16 1995-05-30 Certainteed Corporation Hip or ridge shingle and method of making
US5676597A (en) * 1995-07-27 1997-10-14 Building Materials Corporation Of America Vented hip, ridge and rake composite shingle
US5799459A (en) * 1996-03-08 1998-09-01 Covert; Roger C. Roofing shingles and shingling method
US6112492A (en) * 1995-04-24 2000-09-05 Owens Corning Fiberglas Technology, Inc. Shingle having ribs and cavity on its underside
US6156289A (en) * 1991-06-27 2000-12-05 Minerals Research & Recovery, Inc. Iron based roofing granules and method of coloring same
US20020000068A1 (en) * 1999-03-05 2002-01-03 Mark Freiborg Folded ridge cover and method of fabrication
US20020038531A1 (en) * 1999-02-19 2002-04-04 Freshwater John G. Aesthetic, self-aligning shingle for hip, ridge, or rake portion of a roof
US6426309B1 (en) * 1998-12-30 2002-07-30 Owens Corning Fiberglas Technology, Inc. Storm proof roofing material
US6467235B2 (en) * 1998-11-13 2002-10-22 Certainteed Corporation Method and apparatus for making a thick-appearing shingle
US6494010B1 (en) * 2000-02-15 2002-12-17 Owens Corning Fiberglas Technology, Inc. Wind resistant roofing shingle
US6510664B2 (en) * 2001-06-14 2003-01-28 Stephen J. Kupczyk Multi-layered shingle
US6565431B1 (en) * 2002-04-25 2003-05-20 Building Materials Investment Corporation Fan fold vent
US6709760B2 (en) * 2000-09-29 2004-03-23 Owens Corning Fiberglas Technology, Inc. Crosslinked modified shingle adhesive
US20040083672A1 (en) * 2002-11-04 2004-05-06 Lawrence Penner Ridge cover and method of making
US6790307B2 (en) * 2002-01-22 2004-09-14 Owens Corning Fiberglas Technology, Inc. Shingles with multiple blend drops and method of depositing granules onto a moving substrate
US20040206012A1 (en) * 2003-04-17 2004-10-21 Joseph Pressutti Front fold ridge cover and method of making
US6813866B2 (en) * 2002-04-17 2004-11-09 Building Materials Investment Corporation Laminated hip and ridge asphalt shingle
US6933037B2 (en) * 1997-09-18 2005-08-23 Tamko Roofing Products Triple laminate roofing shingle
US20050204675A1 (en) * 2002-11-06 2005-09-22 Snyder Richard A Impact resistant shingle
US7021468B2 (en) * 2002-03-22 2006-04-04 Meadwestvaco Packaging Systems, Llc Shipping and display carton
US7048990B2 (en) * 2003-12-19 2006-05-23 Iko Industries Ltd. Dual layer shingle
US20060175386A1 (en) * 2005-02-09 2006-08-10 Holley John M Jr Carton with dispenser
US7165363B2 (en) * 2002-11-12 2007-01-23 Building Materials Investment Corp. Manually separable ridge vent
US20070144077A1 (en) * 2005-12-22 2007-06-28 Joseph Quaranta Hip, ridge or rake shingle
US7282536B2 (en) * 2002-02-07 2007-10-16 Kraton Polymers Llc Block copolymers and method for making same
US20090139175A1 (en) * 2007-11-30 2009-06-04 Atlas Roofing Corporation Roofing shingles and methods of making and affixing same
US7805905B2 (en) * 2004-02-12 2010-10-05 Building Materials Investment Corporation Roofing shingle
US20110126485A1 (en) * 2009-10-29 2011-06-02 Shane Bleil Multi-Configuration Hip and Ridge Shingle
US8006457B2 (en) * 2004-06-07 2011-08-30 Building Materials Investment Corporation Enhanced multi-layered shingle
US8266861B2 (en) * 2009-02-03 2012-09-18 Certainteed Corporation Process of producing hip, ridge or rake shingles, and high profile shingles produced thereby
US8281539B2 (en) * 2005-08-30 2012-10-09 Certainteed Corporation Shingle layer or shingle having thick appearance
US8323440B2 (en) * 2009-02-03 2012-12-04 Certainteed Corporation Process of producing hip, ridge or rake shingles, shingles produced thereby and stacks of the shingles
US8371085B2 (en) * 2009-02-03 2013-02-12 Certainteed Corporation Shingles with combined fastener target zone and water barrier and process for producing same
US8453408B2 (en) * 2007-03-22 2013-06-04 Certainteed Corporation Pre-assembled hip, ridge or rake shingle

Family Cites Families (226)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1701926A (en) * 1929-02-12 To-the plintkote
US400891A (en) * 1889-04-09 Buckle
US340294A (en) * 1886-04-20 Cotton-gin
US81579A (en) 1868-09-01 Improvement in marking weather-boarding
US379672A (en) * 1888-03-20 Art of making dry-sand cores
US383223A (en) * 1888-05-22 haselton
US466629A (en) * 1892-01-05 Burial apparatus
US313278A (en) * 1885-03-03 Geeaed beekman
US473326A (en) * 1892-04-19 Oil-purifier
US403087A (en) * 1889-05-14 Household sifter
US154334A (en) 1874-08-25 Improvement in furnaces for heating and annealing sheet metal
US400268A (en) * 1889-03-26 Charles a
US376660A (en) * 1888-01-17 Car-brake
US356161A (en) 1887-01-18 Metallic shingle
US1447750A (en) 1920-03-03 1923-03-06 Charles S Bird Shingle
US1583563A (en) * 1921-11-07 1926-05-04 Ruberoid Company Roof covering
US1601731A (en) 1921-11-16 1926-10-05 Flintkote Co Roof
US1698891A (en) 1922-11-09 1929-01-15 Flintkote Co Strip roofing unit and process of manufacture
US1565693A (en) 1923-04-23 1925-12-15 Way Edward John Cinematographic-film printer
US1666429A (en) * 1923-06-14 1928-04-17 Flintkote Co Roofing
US1549723A (en) 1923-06-15 1925-08-11 Asbestos Shingle Slate & Sheat Roofing shingle
US1597135A (en) 1923-07-12 1926-08-24 Barrett Co Roofing strip
US1665222A (en) * 1923-07-19 1928-04-10 Anaconda Sales Co Roofing element and process of making same
US1585693A (en) 1925-06-01 1926-05-25 Robinson Thomas Prepared roofing
US1676351A (en) 1926-04-14 1928-07-10 Lancaster Asphalt Inc Prepared roofing and method of making
US1897139A (en) 1926-05-27 1933-02-14 Patent & Licensing Corp Method of making roofing stock
US1843370A (en) * 1926-06-01 1932-02-02 Patent & Licensing Corp Irregular strip shingle
US1898989A (en) * 1928-05-11 1933-02-21 Bakelite Building Products Com Shingle
US1860899A (en) 1928-05-15 1932-05-31 Miller Thomas Denton Shingle
US1799500A (en) * 1928-12-29 1931-04-07 Anaconda Sales Co Prepared shingle
US1802868A (en) * 1929-05-02 1931-04-28 Black Systems Inc Building covering
US1885346A (en) 1930-09-24 1932-11-01 Norman P Harshberger Shingle element
US1984529A (en) 1931-06-05 1934-12-18 Barrett Co Reversible shingle
US2058167A (en) 1932-04-26 1936-10-20 Johns Manville Method of making a structural unit
US2161440A (en) 1936-02-21 1939-06-06 American Asphalt Roof Corp Shingle
US2490430A (en) 1943-08-07 1949-12-06 Carey Philip Mfg Co Composition roofing
US2630574A (en) 1949-03-12 1953-03-10 Germaine E Malarkey Neckwear
US2798006A (en) 1954-05-07 1957-07-02 Building Products Ltd Method of producing selvage roll roofing
US2847948A (en) 1955-05-06 1958-08-19 William G Truitt Composite roofing strip
US3054222A (en) 1958-04-23 1962-09-18 Malcolm W Buckner Roofing materials
US3138897A (en) 1959-11-06 1964-06-30 Johns Manville Self-sealing shingle
US3127701A (en) 1960-07-13 1964-04-07 Johns Manville Roof covering
US3252257A (en) * 1962-11-05 1966-05-24 Fibreboard Paper Products Corp Self-sealing shingle
US3332830A (en) * 1963-04-29 1967-07-25 Owens Corning Fiberglass Corp Asphaltic weathering sheet including continuous glass fibers
US3377762A (en) * 1965-08-26 1968-04-16 Brixite Mfg Company Composite shingle
US3468092A (en) 1967-12-05 1969-09-23 Alcan Aluminum Corp Composite strip shingle
US3468086A (en) 1968-04-09 1969-09-23 A C Hathorne Co The Prefabricated roofing construction and method
US3624975A (en) 1970-01-06 1971-12-07 Panacon Corp Strip shingle of improved aesthetic character
US3664081A (en) * 1970-07-15 1972-05-23 Ditz Crane Blowback seal and gauge for building exterior panels
US3813280A (en) * 1971-09-09 1974-05-28 Johns Manville Bituminous roofing products and process
US4091135A (en) 1972-02-19 1978-05-23 Tajima Roofing Co., Ltd. Laminated bituminous roofing membrane
US3833214A (en) 1973-04-11 1974-09-03 Addressograph Multigraph Sheet feeding apparatus for copy machine
JPS502937Y1 (en) 1973-07-31 1975-01-25
US3913294A (en) 1974-02-15 1975-10-21 Bennie Freiborg Asphalt composition hip and ridge cover
US4195461A (en) * 1978-04-06 1980-04-01 Isola Fabrikker A/S Roofing shingle
FR2438720A1 (en) 1978-10-13 1980-05-09 Votte Andre SYNTHETIC COVERING ELEMENTS OF THE SLATE TYPE AND THEIR PRODUCTION METHOD
US4274243A (en) 1978-12-18 1981-06-23 Johns-Manville Corporation Asphalt shingle for simulating a tiled roof
DE2917516A1 (en) 1979-04-30 1980-11-06 Isopag Ag Composite sheet and foam profiles for overlapping cladding boards
US4527374A (en) 1980-01-03 1985-07-09 Manville Service Corp. Three-tab shingle with staggered butt edge feature
US4333279A (en) 1980-01-03 1982-06-08 Manville Service Corporation Three-tab shingle with staggered butt edge feature
USD265510S (en) 1980-05-05 1982-07-20 Bedwell Jr Paul E Asphalt strip roofing shingle or similar article
US4366197A (en) 1980-07-28 1982-12-28 Masonite Corporation Building wall panels and method of making the same
US4439955A (en) * 1980-09-19 1984-04-03 Bennie Freiborg Asphalt composition hip and ridge cover
US4434589A (en) * 1980-09-19 1984-03-06 Bennie Freiborg Asphalt composition hip and ridge cover
US4404783A (en) 1980-11-17 1983-09-20 Bennie Freiborg Multi purpose roof piece
US4580389A (en) * 1980-11-17 1986-04-08 Bennie Freiborg Method of forming roofing piece
US4672790A (en) 1982-03-10 1987-06-16 Bennie Freiborg Multi-piece asphalt composition roofing system
US4459157A (en) 1982-07-19 1984-07-10 Tosco Corporation Asphalt composition
USD309027S (en) 1983-07-15 1990-07-03 Certainteed Corporation Tab portion of a shingle
US4817358A (en) * 1983-07-18 1989-04-04 Owens-Corning Fiberglas Corporation Asphalt shingle with foamed asphalt layer under tabs
CA1207975A (en) 1983-10-04 1986-07-22 Peter G. Macdonald Roofing shingles
US4680909A (en) 1984-09-11 1987-07-21 Industrial Research Development, Inc. Roofing system
USD300257S (en) 1985-10-22 1989-03-14 Certainteed Corporation Butt segment of a shingle
US4717614A (en) * 1986-02-14 1988-01-05 Gaf Corporation Asphalt shingle
US4824880A (en) * 1986-03-03 1989-04-25 Owens-Corning Fiberglas Corporation Asphalt adhesives
US4738884A (en) * 1986-03-03 1988-04-19 Owens-Corning Fiberglas Corporation Asphalt adhesives superimposed on asphalt-based roofing sheet
US4729814A (en) 1986-08-14 1988-03-08 The Celotex Corporation Apparatus for making an offset laminated roofing shingle
US4706435A (en) 1986-12-02 1987-11-17 Industrial Research Development, Inc. Prefabricated interlocking roofing system
US4755545A (en) 1987-04-06 1988-07-05 Gaf Corporation Roofing adhesive
US5181361A (en) * 1987-10-20 1993-01-26 Certainteed Corporation Multi-layer shingle
US5209802A (en) * 1987-10-20 1993-05-11 Certainteed Corporation Method of making a multi-layer shingle
US6305138B1 (en) * 1987-10-20 2001-10-23 Certainteed Corp. Composite shingle having shading zones in different planes
US5426902A (en) 1987-10-20 1995-06-27 Certainteed Corporation Composite shingle having shading zones in different planes
US5232530A (en) 1987-12-04 1993-08-03 Elk Corporation Of Dallas Method of making a thick shingle
US4835929A (en) 1988-01-25 1989-06-06 Gaf Corporation Laminated roofing hip
GB8811868D0 (en) * 1988-05-19 1988-06-22 Ici Plc Release film
USD313278S (en) 1989-02-09 1990-12-25 Certainteed Corporation Shingle
US5287669A (en) * 1990-04-27 1994-02-22 Certainteed Corporation Roofing shingle
USD340294S (en) 1990-04-27 1993-10-12 Certainteed Corporation Design for a tab portion of a shingle
US5065553A (en) 1990-05-11 1991-11-19 Magid Sanford J Roof flashing unit
US5039755A (en) 1990-05-29 1991-08-13 Shell Oil Company Selective hydrogenation of conjugated diolefin polymers
US5239802A (en) 1990-08-13 1993-08-31 Certainteed Corporation Adhesive arrangement for shingles and the like
US5319898A (en) 1991-01-08 1994-06-14 Bennie Freiborg Asphalt composition ridge cover
US5094042A (en) * 1991-01-08 1992-03-10 Ben Freborg Asphalt composition ridge cover and method of forming
US5369929A (en) 1991-09-18 1994-12-06 Elk Corporation Of Dallas Laminated roofing shingle
US5375387A (en) 1992-01-07 1994-12-27 Davenport; Ralph G. Roofing shingle providing simulated slate roof covering
US5247771A (en) 1992-03-23 1993-09-28 Poplin James E Ridge shingle unit
US5195290A (en) * 1992-06-03 1993-03-23 American Heartland Roofing Products, Inc. Laminar roofing product
US5347785A (en) * 1992-06-15 1994-09-20 Certainteed Corporation Two element shingle
USD366124S (en) 1992-10-19 1996-01-09 Certainteed Corporation Tab portion of a shingle
US5295340A (en) * 1993-04-05 1994-03-22 Pacific Coast Building Products, Inc. Dimensional shingle for hip, ridge and rake portions of a roof
CN2176391Y (en) 1993-09-13 1994-09-07 陈春男 Corrugated roof plate
CA2175382C (en) * 1993-11-02 2005-01-04 Charles A. Burton Pneumatic granule blender for asphalt shingles
US5571596A (en) 1993-12-23 1996-11-05 Johnson; Matthew E. Advanced composite roofing shingle
US5467568A (en) 1994-01-11 1995-11-21 Building Materials Corporation Of America Dimensional hip and ridge roofing panel
US5611186A (en) * 1994-02-01 1997-03-18 Elk Corporation Of Dallas Laminated roofing shingle
US5471801A (en) * 1994-09-01 1995-12-05 Gs Roofing Products Company, Inc. Hip and ridge asphalt roof covering
US5570556A (en) 1994-10-12 1996-11-05 Wagner; Thomas E. Shingles with connectors
USD379672S (en) 1994-12-28 1997-06-03 Owens Corning Fiberglass Technology, Inc. Tab portion of a roof shingle
CA2169598A1 (en) 1995-02-22 1996-08-23 Henry Koschitzky Method and apparatus for applying surfacing material to shingles
USD375563S (en) 1995-03-17 1996-11-12 Certainteed Corporation Shingle
USD369421S (en) 1995-03-17 1996-04-30 Elk Corporation Of Dallas Random cut laminated shingle
USD376660S (en) 1995-03-17 1996-12-17 Certainteed Corporation Shingle
US5615523A (en) * 1995-04-24 1997-04-01 Owens-Corning Fiberglas Technology, Inc. Roof having resinous shingles
US5664385A (en) 1995-04-27 1997-09-09 Iko Industries Ltd. Shingle with slots and method of making same
US5624522A (en) * 1995-06-07 1997-04-29 Owens-Corning Fiberglas Technology Inc. Method for applying granules to strip asphaltic roofing material to form variegated shingles
USD383223S (en) 1995-06-23 1997-09-02 Building Materials Corporation Of America Foldable hip and ridge roofing shingle
US6451409B1 (en) 1995-10-17 2002-09-17 Robert F. Lassiter Roofing material with integrally formed nail tabs
US5651734A (en) 1995-12-11 1997-07-29 Liberty Diversified Industries, Inc. Ridge cap roof ventilator applied in roll form and method of use
US5577361A (en) 1996-01-16 1996-11-26 Grabek, Jr.; Joseph F. Roofing shingle
US5860263A (en) * 1996-02-02 1999-01-19 Building Materials Corporation Of America Thickened reinforced roofing shingle
US5711126A (en) * 1996-05-13 1998-01-27 Owens-Corning Fiberglass Technology, Inc. Resinous angled shingles for roof ridge lines
US5822943A (en) 1996-07-10 1998-10-20 Tamko Roofing Products, Inc. Hurricane resistant shingle
US5853858A (en) 1997-01-22 1998-12-29 Building Materials Corporation Of America Multihued shingle sheet
US5939169A (en) 1997-01-23 1999-08-17 Building Materials Corporation Of America Composite roofing and siding shingle
USD406361S (en) 1997-01-23 1999-03-02 Building Materials Corporation Of America Shingle
CA2228639A1 (en) 1997-02-04 1998-08-04 Mark Freiborg Asphalt composition ridge covers with three dimensional effect
US6070384A (en) 1997-05-23 2000-06-06 Building Materials Corporation Of America Hip and ridge roofing shingle
USD400268S (en) 1997-10-14 1998-10-27 Building Materials Corporation Of America Folded hip and ridge roofing shingle
USD403087S (en) 1997-10-15 1998-12-22 Building Materials Corporation Of America Laminated roofing shingle
USD417513S (en) 1997-10-15 1999-12-07 Atlas Roofing Corporation Butt portion of a roofing shingle
ES2188028T3 (en) * 1997-10-21 2003-06-16 Saint Gobain Isover FAÇADE SYSTEM WITH AN INSULATING, POROUS AND TRANSLATED MATERIAL.
USD400981S (en) 1997-12-03 1998-11-10 Building Materials Corporation Of America Front of a roof shingle
US5916103A (en) 1997-12-17 1999-06-29 Roberts; Jimmie A. Interconnected roofing shingles
US6190754B1 (en) * 1997-12-24 2001-02-20 Building Materials Corporation Of America Variegated shingle and method of manufacture
US6220329B1 (en) * 1998-03-17 2001-04-24 Tamko Roofin Products Apparatus for making laminated roofing shingles
US5950387A (en) 1998-05-11 1999-09-14 Certainteed Corporation Wind-resistant shingle and method of applying
US6044608A (en) * 1998-05-29 2000-04-04 Certainteed Corporation Laminated shingle
US6010589A (en) * 1998-05-29 2000-01-04 Certainteed Corporation Method of making laminated shingles
US6038826A (en) * 1998-05-29 2000-03-21 Certainteed Corporation Stack and package of laminated shingles
US6148578A (en) 1998-06-17 2000-11-21 Nowacek; David C. Slate and interlayment roof and a method of preparing the same
USD417016S (en) 1998-08-03 1999-11-23 Atlas Roofing Corporation Butt portion of a roofing shingle
US6401425B1 (en) 1999-08-19 2002-06-11 Craig Frame Method of installing roofing shingles
US6014847A (en) * 1998-08-31 2000-01-18 Owens Corning Fiberglas Technology, Inc. Laminated roofing shingle having staggered shadow lines and method of making the same
USD435671S (en) 1998-08-31 2000-12-26 Owens Corning Fiberglas Technology, Inc. Tab portion of a strip shingle
US6083592A (en) 1998-09-03 2000-07-04 Building Materials Corporation Of America Self-sealing shingle adhesive load relief
US6670011B2 (en) 1998-10-07 2003-12-30 Johns Manville International, Inc. Pre-cut fibrous insulation blanket
US6105329A (en) 1998-10-15 2000-08-22 Building Materials Corporation Of America Trilaminate roofing shingle
US6361851B1 (en) * 1998-11-06 2002-03-26 Building Materials Investment Corporation Composite roofing shingle
US6185895B1 (en) * 1998-12-24 2001-02-13 Robert A. Rettew Ventilating radiant barrier
US6145265A (en) 1999-02-17 2000-11-14 Herbert Malarkey Roofing Company Laminated shingle
US6351913B1 (en) * 1999-03-05 2002-03-05 The Dorothy And Ben Freiborg 1980 Trust Folded ridge cover and method of fabrication
US6182400B1 (en) * 1999-03-05 2001-02-06 The Dorothy And Ben Freiborg 1980 Trust Folded ridge cover and method of fabrication
US6253512B1 (en) 1999-04-15 2001-07-03 Owens Corning Fiberglas Technology, Inc. Method of applying tiles to a roof
US6355132B1 (en) * 1999-05-03 2002-03-12 Certainteed Corporation Multi-layered shingle and method of making same
US6703120B1 (en) * 1999-05-05 2004-03-09 3M Innovative Properties Company Silicone adhesives, articles, and methods
US6199338B1 (en) * 1999-08-10 2001-03-13 Elk Corporation Of Dallas Universal starter shingle
US6310122B1 (en) * 1999-09-03 2001-10-30 Fina Technology, Inc. Stable bitumen polymer compositions
US6471812B1 (en) 1999-09-03 2002-10-29 Owens Corning Fiberglas Technology, Inc. Reducing humping of roofing shingles
US6247289B1 (en) 1999-10-26 2001-06-19 Walter R. Karpinia Roof shingle reinforcing strap
US6421976B1 (en) 1999-10-29 2002-07-23 Owens Corning Fiberglas Technology, Inc. Shingle for optically simulating a tile roof
US6936329B2 (en) * 1999-11-30 2005-08-30 Elkcorp. Fastener-free composite roofing product
US6990779B2 (en) * 1999-11-30 2006-01-31 Elk Premium Building Products, Inc. Roofing system and roofing shingles
US6579484B1 (en) * 1999-12-16 2003-06-17 Advanced Cardiovascular Systems, Inc. Co-extruded taper shaft
USD610720S1 (en) 2000-02-29 2010-02-23 Owens Corning Intellectual Capital, Llc Shingle
US7877949B1 (en) 2000-02-29 2011-02-01 Owens Corning Intellectual Capital, Llc Shingle for optically simulating a slate roof
AT409153B (en) 2000-03-03 2002-06-25 F Sis Ges M B H GASKET OR INSULATING RAIL FROM (POLYMER) BITUMEN
US6487828B1 (en) 2000-06-30 2002-12-03 Owens Corning Fiberglas Technology, Inc. Tabbed shingles length cut at mid-tab
US6468615B2 (en) 2001-02-16 2002-10-22 Johns Manville International, Inc. Pre-cut fibrous insulation blanket
US6610147B2 (en) 2001-08-31 2003-08-26 Owens-Corning Fiberglas Technology, Inc. Shingle granule valve and method of depositing granules onto a moving substrate
US20030070579A1 (en) * 2001-10-01 2003-04-17 Hong Le Hoa Preformed thermoplastic pavement marking construction
US7238408B2 (en) 2001-10-10 2007-07-03 Owens-Corning Fiberglas Technology Inc. Roofing materials having engineered coatings
US20040111996A1 (en) 2001-11-05 2004-06-17 Gary Heroneme Composite shingle and method of manufacture, method of packaging, and method of installation
US20030093958A1 (en) * 2001-11-19 2003-05-22 Freiborg Mark L. Asphalt composition ridge cover with improved ridge bend
CA2471734C (en) * 2001-12-26 2011-02-22 Arichell Technologies, Inc. Bathroom flushers with novel sensors and controllers
US6823637B2 (en) 2002-12-31 2004-11-30 Owens Corning Fiberglas Technology, Inc. Shingle with a rendered shadow design
US6804919B2 (en) * 2002-09-23 2004-10-19 Building Materials Investment Corporation Backer for tabbed composite shingles
US20040079042A1 (en) * 2002-10-29 2004-04-29 Elliott Bert W. Multi-layer laminated shingle
US7082724B2 (en) 2002-11-04 2006-08-01 Building Materials Investment Corporation Packaging of tabbed composite shingles having a backer strip containing uniform, identically spaced, vertical projections on its top edge
US6758019B2 (en) * 2002-11-06 2004-07-06 Certainteed Corporation Shingle with improved blow-off resistance
US7537820B2 (en) 2002-11-06 2009-05-26 Certainteed Corporation Shingle with reinforcement layer
US20040083674A1 (en) 2002-11-06 2004-05-06 Kalkanoglu Husnu M. Laminated shingle with wider nailing zone
US7267862B1 (en) * 2002-12-06 2007-09-11 Appleton Papers Inc. Controlled COF films
US20040123537A1 (en) 2002-12-31 2004-07-01 Elliott Bert W. Shingle with a rendered shadow design
US20040148874A1 (en) 2003-02-04 2004-08-05 Jolitz Randal J. Roofing products
US7146771B2 (en) 2003-03-04 2006-12-12 Johns Manville Cap sheet, roofing installation, and method
CA2425726A1 (en) 2003-04-17 2004-10-17 Jayant Kandy Wind resistant roofing shingle
US7201946B2 (en) 2003-05-29 2007-04-10 David Allan Collins Print methodology for applying polymer materials to roofing materials to form nail tabs or reinforcing strips
US20040258883A1 (en) 2003-06-17 2004-12-23 Elkcorp. Laminated roofing shingle
US7124548B2 (en) 2003-08-26 2006-10-24 Joseph Pressutti Folded high-profile ridge cover, and method of making
JP4776155B2 (en) * 2003-10-21 2011-09-21 旭化成ケミカルズ株式会社 Hydrogenated copolymer
US20050137295A1 (en) * 2003-12-17 2005-06-23 Kraton Polymers U.S. Llc Bituminous compositions modified by non-blocking elastomers
US20050235599A1 (en) 2004-03-23 2005-10-27 Kalkanoglu Husnu M Shingle with sharply defined tabs separated by slots and method of making
CA2559855C (en) 2004-03-23 2015-05-05 Building Materials Investment Corporation A building membrane
US7556849B2 (en) 2004-03-25 2009-07-07 Johns Manville Low odor faced insulation assembly
US7070051B2 (en) * 2004-03-26 2006-07-04 Atrion Medical Products, Inc. Needle counter device including troughs of cohesive material
US20050252136A1 (en) 2004-03-30 2005-11-17 George Hardin Metallic shingle construction
EP1737914B1 (en) * 2004-04-14 2007-09-19 Kraton Polymers Research B.V. A polymer modified bitumen composition to be used in asphalt binders or roofing compositions
US7281358B2 (en) * 2004-08-16 2007-10-16 Floyd Charles T Roofing shingle
US20060179767A1 (en) 2005-02-03 2006-08-17 Miller Carla A Laminated shingle with spacer bands for level stacking
US20070020436A1 (en) * 2005-02-25 2007-01-25 Teng Yihsien H Roofing shingle containing algae inhibiting metallic particles
US20060201094A1 (en) 2005-03-09 2006-09-14 Robert Lassiter Roofing shingle
US8557366B2 (en) * 2005-08-05 2013-10-15 Owens Corning Intellectual Capital, Llc Roofing shingle including sheet as headlap
US7836654B2 (en) 2005-08-05 2010-11-23 Owens Corning Intellectual Capital, Llc Shingle with reinforced nail zone and method of manufacturing
US7820237B2 (en) * 2005-10-06 2010-10-26 Owens Corning Intellectual Capital, Llc System for manufacturing a granule covered roofing shingle having a national shingle color
US8389103B2 (en) 2006-03-16 2013-03-05 Elk Premium Building Products, Inc. Roofing material
US20070266665A1 (en) 2006-04-17 2007-11-22 Atlas Roofing Corporation Hip and ridge shingle, method and apparatus for making, and method of using same
US8261505B2 (en) * 2006-10-25 2012-09-11 Certainteed Corporation Synthetic shingle or tile with stress relief nail zones
US20080134612A1 (en) 2006-11-09 2008-06-12 Henry Koschitzky Shingle with improved fastener pull-through resistance
US7765763B2 (en) 2006-12-30 2010-08-03 Owens Corning Intellectual Capital, Llc Pleated roofing membrane and roofing shingle system
FR2918066B1 (en) * 2007-06-26 2010-11-19 Total France NON-GELIFIABLE CONCENTRATE BINDER AND POMPABLE FOR BITUMEN / POLYMER
US20090282767A1 (en) 2008-05-13 2009-11-19 Grubka Lawrence J Hip And Ridge Roofing Material
US20100212240A1 (en) 2009-02-25 2010-08-26 Grubka Lawrence J Hip and ridge roofing material
US9017791B2 (en) 2008-05-13 2015-04-28 Owens Corning Intellectual Capital, Llc Shingle blank having formation of individual hip and ridge roofing shingles
US8371072B1 (en) 2008-09-23 2013-02-12 Certainteed Corporation Molded synthetic hip, ridge or rake shingle and process and apparatus for molding same
US9151055B2 (en) 2009-02-25 2015-10-06 Owens Corning Intellectual Capital, Llc Hip and ridge roofing material
US9574350B2 (en) 2009-03-20 2017-02-21 Owens Corning Intellectual Capital, Llc Sealant composition for releasable shingle
US20110005158A1 (en) * 2009-07-06 2011-01-13 Kailey R Jon Hip and ridge roofing material
CA2775064A1 (en) 2009-09-25 2011-03-31 Certainteed Corporation Pre-assembled hip, ridge or rake shingle
USD633222S1 (en) 2010-01-12 2011-02-22 Certainteed Corporation Shingle
USD633221S1 (en) 2010-01-12 2011-02-22 Certainteed Corporation Shingle strip
US9097020B2 (en) 2010-03-04 2015-08-04 Owens Corning Intellectual Capital, Llc Hip and ridge roofing shingle
US9290943B2 (en) 2012-01-05 2016-03-22 Owens Corning Intellectual Capital, Llc Hip and ridge roofing shingle
USD695925S1 (en) 2012-03-16 2013-12-17 Owens Corning Intellectual Capital, Llc Underlay portion of a shingle
USD711558S1 (en) 2012-12-14 2014-08-19 Boral Roofing LLC Roof tile
USD735545S1 (en) 2013-06-03 2015-08-04 Scott Cutters Limited Plastering tool

Patent Citations (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1516243A (en) * 1920-11-23 1924-11-18 Barrett Co Roofing
US1495070A (en) * 1923-06-20 1924-05-20 Paraffine Co Inc Strip shingle
US4352837A (en) * 1977-06-20 1982-10-05 Certain-Teed Corporation Method of manufacturing roofing shingles having multiple ply appearance
US4194335A (en) * 1977-12-08 1980-03-25 Diamond John N Single sheathing roof panel
US4789066A (en) * 1983-11-25 1988-12-06 Ex-Cell-O Corporation Container with protective seal and tear strip
US4637191A (en) * 1984-12-03 1987-01-20 Smith Robert L Starter shingle
US4856251A (en) * 1987-02-20 1989-08-15 Buck Donald A Self-gauging, anti-ice damming, double sealed shingle system
US5036119A (en) * 1989-10-16 1991-07-30 Shell Oil Company Process for preparing bituminous composition
US6156289A (en) * 1991-06-27 2000-12-05 Minerals Research & Recovery, Inc. Iron based roofing granules and method of coloring same
USD347900S (en) * 1992-02-28 1994-06-14 Minnesota Mining And Manufacturing Company Laminated shingle
US5575876A (en) * 1992-06-16 1996-11-19 Certainteed Corporation Method of making hip or ridge shingle
US5271201A (en) * 1992-06-16 1993-12-21 Certainteed Corporation Hip or ridge shingle
US5419941A (en) * 1992-06-16 1995-05-30 Certainteed Corporation Hip or ridge shingle and method of making
US5365711A (en) * 1993-04-28 1994-11-22 Pressutti Joseph E Low-cost highly aesthetic and durable shingle
USRE36858E (en) * 1993-04-28 2000-09-12 Pressutti; Joseph E. Low-cost highly aesthetic and durable shingle
US6112492A (en) * 1995-04-24 2000-09-05 Owens Corning Fiberglas Technology, Inc. Shingle having ribs and cavity on its underside
US5676597A (en) * 1995-07-27 1997-10-14 Building Materials Corporation Of America Vented hip, ridge and rake composite shingle
US5799459A (en) * 1996-03-08 1998-09-01 Covert; Roger C. Roofing shingles and shingling method
US6933037B2 (en) * 1997-09-18 2005-08-23 Tamko Roofing Products Triple laminate roofing shingle
US6467235B2 (en) * 1998-11-13 2002-10-22 Certainteed Corporation Method and apparatus for making a thick-appearing shingle
US6426309B1 (en) * 1998-12-30 2002-07-30 Owens Corning Fiberglas Technology, Inc. Storm proof roofing material
US20020038531A1 (en) * 1999-02-19 2002-04-04 Freshwater John G. Aesthetic, self-aligning shingle for hip, ridge, or rake portion of a roof
US20020000068A1 (en) * 1999-03-05 2002-01-03 Mark Freiborg Folded ridge cover and method of fabrication
US6494010B1 (en) * 2000-02-15 2002-12-17 Owens Corning Fiberglas Technology, Inc. Wind resistant roofing shingle
US6709760B2 (en) * 2000-09-29 2004-03-23 Owens Corning Fiberglas Technology, Inc. Crosslinked modified shingle adhesive
US6510664B2 (en) * 2001-06-14 2003-01-28 Stephen J. Kupczyk Multi-layered shingle
US6790307B2 (en) * 2002-01-22 2004-09-14 Owens Corning Fiberglas Technology, Inc. Shingles with multiple blend drops and method of depositing granules onto a moving substrate
US7282536B2 (en) * 2002-02-07 2007-10-16 Kraton Polymers Llc Block copolymers and method for making same
US7021468B2 (en) * 2002-03-22 2006-04-04 Meadwestvaco Packaging Systems, Llc Shipping and display carton
US6813866B2 (en) * 2002-04-17 2004-11-09 Building Materials Investment Corporation Laminated hip and ridge asphalt shingle
US6895724B2 (en) * 2002-04-17 2005-05-24 Building Materials Investment Corporation Laminated hip and ridge asphalt shingle
US6565431B1 (en) * 2002-04-25 2003-05-20 Building Materials Investment Corporation Fan fold vent
US20040083672A1 (en) * 2002-11-04 2004-05-06 Lawrence Penner Ridge cover and method of making
US20050204675A1 (en) * 2002-11-06 2005-09-22 Snyder Richard A Impact resistant shingle
US7165363B2 (en) * 2002-11-12 2007-01-23 Building Materials Investment Corp. Manually separable ridge vent
US20040206012A1 (en) * 2003-04-17 2004-10-21 Joseph Pressutti Front fold ridge cover and method of making
US7048990B2 (en) * 2003-12-19 2006-05-23 Iko Industries Ltd. Dual layer shingle
US7805905B2 (en) * 2004-02-12 2010-10-05 Building Materials Investment Corporation Roofing shingle
US8316608B2 (en) * 2004-06-07 2012-11-27 Building Materials Investment Corporation Enhanced multi-layered shingle
US8006457B2 (en) * 2004-06-07 2011-08-30 Building Materials Investment Corporation Enhanced multi-layered shingle
US8127514B2 (en) * 2004-06-07 2012-03-06 Elk Premium Building Products, Inc. Enhanced multi-layered shingle
US20060175386A1 (en) * 2005-02-09 2006-08-10 Holley John M Jr Carton with dispenser
US7909235B2 (en) * 2005-02-09 2011-03-22 Mead Westvaco Packaging Systems, Llc Carton with dispenser
US8302358B2 (en) * 2005-08-30 2012-11-06 Certainteed Corporation Shingle layer or shingle having thick appearance
US8281539B2 (en) * 2005-08-30 2012-10-09 Certainteed Corporation Shingle layer or shingle having thick appearance
US20070144077A1 (en) * 2005-12-22 2007-06-28 Joseph Quaranta Hip, ridge or rake shingle
US8281520B2 (en) * 2005-12-22 2012-10-09 Certainteed Corporation Hip, ridge or rake shingle
US8453408B2 (en) * 2007-03-22 2013-06-04 Certainteed Corporation Pre-assembled hip, ridge or rake shingle
US20090139175A1 (en) * 2007-11-30 2009-06-04 Atlas Roofing Corporation Roofing shingles and methods of making and affixing same
US8266861B2 (en) * 2009-02-03 2012-09-18 Certainteed Corporation Process of producing hip, ridge or rake shingles, and high profile shingles produced thereby
US8323440B2 (en) * 2009-02-03 2012-12-04 Certainteed Corporation Process of producing hip, ridge or rake shingles, shingles produced thereby and stacks of the shingles
US8371085B2 (en) * 2009-02-03 2013-02-12 Certainteed Corporation Shingles with combined fastener target zone and water barrier and process for producing same
US20110126485A1 (en) * 2009-10-29 2011-06-02 Shane Bleil Multi-Configuration Hip and Ridge Shingle

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Karen G Haynes, January 4, 1999, Shellflex 3681 MSDS, Page 1, Section 1. *

Cited By (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9017791B2 (en) 2008-05-13 2015-04-28 Owens Corning Intellectual Capital, Llc Shingle blank having formation of individual hip and ridge roofing shingles
US11313127B2 (en) 2009-02-25 2022-04-26 Owens Corning Intellectual Capital, Llc Hip and ridge roofing material
US9890534B2 (en) 2009-02-25 2018-02-13 Owens Corning Intellectual Capital, Llc Hip and ridge roofing material
US9151055B2 (en) 2009-02-25 2015-10-06 Owens Corning Intellectual Capital, Llc Hip and ridge roofing material
US9482007B2 (en) 2009-03-20 2016-11-01 Owens Corning Intellectual Capital, Llc Flexible laminated hip and ridge shingle
US9574350B2 (en) 2009-03-20 2017-02-21 Owens Corning Intellectual Capital, Llc Sealant composition for releasable shingle
US10273392B2 (en) 2009-03-20 2019-04-30 Owens Corning Intellectual Capital, Llc Sealant composition for releasable shingle
US9097020B2 (en) 2010-03-04 2015-08-04 Owens Corning Intellectual Capital, Llc Hip and ridge roofing shingle
US9834935B2 (en) 2011-09-13 2017-12-05 Owens Corning Intellectual Capital, Llc Granule coated waterproof roofing membrane
US9290943B2 (en) 2012-01-05 2016-03-22 Owens Corning Intellectual Capital, Llc Hip and ridge roofing shingle
US9074373B2 (en) 2013-03-04 2015-07-07 Certainteed Corporation System, method and apparatus for adding thickness to roofing products
US9758970B2 (en) 2014-02-25 2017-09-12 Owens Corning Intellectual Capital, Llc Laminated hip and ridge shingle
USD755997S1 (en) 2014-02-27 2016-05-10 Owens Corning Intellectual Capital, Llc Shingle
US10370853B2 (en) * 2016-04-20 2019-08-06 Owens Corning Intellectual Capital, Llc Hip and ridge/starter shingle combination
US11391046B2 (en) 2016-05-06 2022-07-19 Owens Corning Intellectual Capital, Llc Shingle sealing arrangements
US10538918B2 (en) 2016-05-06 2020-01-21 Owens Corning Intellectual Capital, Llc Shingle sealing arrangements
US10907352B2 (en) 2016-05-06 2021-02-02 Owens Corning Intellectual Capital, Llc Shingle sealing arrangements
US11795692B2 (en) 2016-05-06 2023-10-24 Owens Corning Intellectual Capital, Llc Shingle sealing arrangements
US10358824B2 (en) 2016-05-06 2019-07-23 Owens Corning Intellectual Capital, Llc Shingle sealing arrangements
US11447953B2 (en) * 2017-07-20 2022-09-20 Zinniatek Limited Roof, siding, or cladding, or ridge or hip member for a roof
US10907354B2 (en) 2017-12-15 2021-02-02 Owens Corning Intellectual Capital, Llc Polymer modified asphalt roofing material
US11028591B2 (en) 2017-12-15 2021-06-08 Owens Corning Intellectual Capital, Llc Polymer modified asphalt roofing material
US11028592B2 (en) 2017-12-15 2021-06-08 Owens Corning Intellectual Capital, Llc Polymer modified asphalt roofing material
US11035123B2 (en) 2017-12-15 2021-06-15 Owens Corning Intellectual Capital, Llc Polymer modified asphalt roofing material
US20190186141A1 (en) * 2017-12-15 2019-06-20 Owens Corning Intellectual Capital, Llc Polymer modified asphalt roofing material
US10961713B2 (en) 2017-12-15 2021-03-30 Owens Coming Intellectual Capital, LLC Polymer modified asphalt roofing material
US10934715B2 (en) * 2017-12-15 2021-03-02 Owens Corning Intellectual Capital, Llc Polymer modified asphalt roofing material
US11473305B2 (en) 2017-12-15 2022-10-18 Owens Corning Intellectual Capital, Llc Polymer modified asphalt roofing material
US11746527B2 (en) 2017-12-15 2023-09-05 Owens Corning Intellectual Capital, Llc Polymer modified asphalt roofing material
US10907353B2 (en) 2017-12-15 2021-02-02 Owens Coming Intellectual Capital, LLC Polymer modified asphalt roofing material
US11851889B2 (en) 2017-12-15 2023-12-26 Owens Corning Intellectual Capital, Llc Polymer modified asphalt roofing material

Also Published As

Publication number Publication date
US9574350B2 (en) 2017-02-21
US9482007B2 (en) 2016-11-01
CA2697223A1 (en) 2010-09-20
US20170145271A1 (en) 2017-05-25
CA2697221A1 (en) 2010-09-20
US20160024792A1 (en) 2016-01-28
CA2697221C (en) 2017-06-13
US10273392B2 (en) 2019-04-30
US20100236178A1 (en) 2010-09-23
CA2697223C (en) 2017-10-24

Similar Documents

Publication Publication Date Title
US9482007B2 (en) Flexible laminated hip and ridge shingle
US7475519B2 (en) Self-adhered roof system and components
US7977259B2 (en) Roofing underlayment and method of producing same
US20100098912A1 (en) Impact Resistant Shingle
US20110281094A1 (en) Multilayer modified bituminous roofing product
CA2879036C (en) Roofing material
US10059016B2 (en) Roofing shingle system
WO2009021046A3 (en) Reinforcement for asphaltic paving, method of paving, and process for making a grid with the coating for asphaltic paving
US20040014385A1 (en) Storm resistant roofing material
MXPA05009451A (en) Composition and method for roofing material installation.
US10774535B2 (en) Asphalt shingles with a fire-retardant additive
CA2245649C (en) Rollable asphaltic protection course
KR102411289B1 (en) Waterproof member including self-healing asphalt composition and non-woven fabric glass fiber and waterproofing method using the same
KR101352857B1 (en) Heat reduction-layer formed self-adhesive asphalt waterproof sheet, and manufacturing method thereof
US7906204B2 (en) Waterproofing UV-resistant bituminous membrane, system incorporating such a membrane, and manufacturing process
US20190270272A1 (en) Composite construction material
US20110165377A1 (en) Pressure-sensitive adhesive and products
EP1412591B1 (en) Roofing composite
MXPA98006946A (en) Lamina asphalt protection section
CA2438964A1 (en) Storm resistant roofing material
AU2002321875A1 (en) Roofing composite
CA2147339A1 (en) Modified overlay shingle
AU2002321876A1 (en) Roofing system and roofing shingles

Legal Events

Date Code Title Description
AS Assignment

Owner name: OWENS CORNING INTELLECTUAL CAPITAL, LLC, OHIO

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:GRUBKA, LAWRENCE J.;FREY, JENNIFER L.;LOFTUS, JAMES E.;AND OTHERS;SIGNING DATES FROM 20100526 TO 20100527;REEL/FRAME:024451/0939

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION