US2333443A - Method of preparing detergent - Google Patents

Method of preparing detergent Download PDF

Info

Publication number
US2333443A
US2333443A US2333443DA US2333443A US 2333443 A US2333443 A US 2333443A US 2333443D A US2333443D A US 2333443DA US 2333443 A US2333443 A US 2333443A
Authority
US
United States
Prior art keywords
composition
alkali metal
anhydrous
water
silicate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
Publication date
Application granted granted Critical
Publication of US2333443A publication Critical patent/US2333443A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/06—Phosphates, including polyphosphates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates

Definitions

  • This invention relates toalkali metal silicate compositions and to a method of preparing them..
  • the products of the invention are adapted particularly for detergent purposes such as in cleansing, washing, degreasing, and scouring operations.
  • One of the principal objects of the present invention has been to provide detergent compositions comprised of alkali metal silicates which are adapted to prevent the formation of lime and magnesium deposits and precipitates when they are used in unsoftened water. It has been understood in the past by those skilled in the art that the use of alkali metal phosphates is helpful in obtaining this result.
  • a composition comprised of anhydrous tetrasodium pyrophosphate and sodium metalsilicate mixed to gather in a dry state is adapted for the purpose, but such a mixture is slow to dissolve in water, because the pyrophosphate, in picking up water to form its decahydrate, cements the particles of metasilicate together; and of itself the anhydrous pyrophosphate is very slow to dissolve in water.
  • the components of dry mechanical mixes tend to separate, through sifting, especially if one of them is not of'the same particle size or degree of granulation or fineness as the other ingredients. It is the frequent experience that the composition at the top of the barrel .of the material will be difierent from the composition at the bottom of the barrel from this cause.
  • the objective of the present invention has been to provide a dry and granular detergent composition comprising an alkali metal silicate and an anhydrous alkali metal phosphate which, in addition to providing the desired water softening as well as detergent properties, is readily soluble in water and, therefore easy to use in the industrial operations for which it is intended. Otherwise expressed, the objective has been to obtain a material exhibiting all of the advantages which each component is capable of providing, but none of the disadvantages exhibited by a dry mixture of the same ingredients.
  • the present invention is predicated upon the discovery that, while adry mixture of an alkali metal silicate and an anhydrous alkali metal phosphate is a composition difiicult to dissolve in water, the addition of the phosphate component while the alkali metal silicate is in a liquid condition provides a product which is of greatly improved solubility.
  • the present invention contemplates a process for improving the water solubility of a silicate-anhydrous phosphate composition by incorporating the two with one another while the silicate is in a liquidstate, that is, before the silicate is crystallizedi In this process the two components are stirred together until a composition of uniform consistency is obtained, then the silicate is permitted to exert its crystallitic characteristic and harden.
  • the resultant composition is adapted to be granulated or reduced to a marketable form in the usual manner as readily as the ordinary forms of crystallized alkali metal silicates.
  • alkali metal phosphates other than the orthophosphates are their tendency to revert to orthophosphates in the presence of strong alkalies and water at elevated temperatures. This reversion greatly reduces their water softening power. It has been discovered that under the manufacturing conditions of the present process, anhydrous tetrasodium pyrophosphate does not revert to orthophosphate to any marked degree when added to hot liquid alkali metalmetasilicates or to more alkaline silicate materials. It has also been discovered that if at least 15% of sodium tripolyphosphate is used in the compositions, there is very little tendency for this compound to revert to pyrophosphate and orthophosphate.
  • the silicate be in a hydrated form, that is, with approximately 2 to approximately 9 molecules water of hydration. Water may be present in excess of this amount, provided it does not detract from the ability of the silicate subsequently to crystallize.
  • the amount of phosphate which it is desirable to use for the prevention of the deposition of calcium and magnesium compounds is usually quite small, for example, in the neighborhood of to 15%, sometimes less and sometimes considerably more, in instances where the composition is to be used for a special purpose.
  • the process of the present invention enables supplementary components besides phosphates to be incorporated, for example, sodium carbonate or caustic soda.
  • sodium carbonate when sodium carbonate is used it, like the phosphate, is preferably in the anhydrous condition.
  • Example A Per cent Sodium metasilicate pentahydrate 80.00 Tetrasodium pyrophosphate anhydrous 15.00 Sodium carbonate anhydrous 5.00
  • Example B Per cent Sodium metasilicate pentahydrate 55.00 Tetrasodium pyrophosphate anhydrous.-- 40.00 Sodium carbonate anhydrous 5.00
  • This composition represents about the maximum amount of phosphate which is desirable to use.
  • Example C Per cent Sodium silicate (1.6Na2O-SiOr5.5H2O) 76.90 Tetrasodium pyrophosphate anhydrous 12.60 Sodium carbonate anhydrous 10.50
  • Example D Per cent Sodium orthosilicate (2NazO-Si0r5AHzO) 85.00 Tetrasodium pyrophosphate anhydrous 10.00
  • composition represents about the maximum amount of phosphate which it is desirable to use. All percentages in the above examples are by weight.
  • the phosphate component and any supplementary ingredients. such as sodium carbonate or the like. are added to the silicate component while it is in the liquid state, in the proportions desired, and the components are then stirred together so that the mass becomes of uniform composition over a period oi time during which the temperature is maintained to prevent crystallization of the mass from taking place.
  • the temperature of the mass is lowered and it crystallizes to a hard, grindable condition.
  • a given batch of the material may be cast in pans and there permitted to cool, and the cakes so obtained can then be ground.
  • the final product is a flakedmaterial similar to the products made by the McDaniel process.
  • the silicates which are adapted to be used in the practice of the present invention are the metasilicate, in which the ratio of NaaO to 810: is 1 to 1; the orthosilicate, in which the ratio is 2 to l; (orthosilicates as disclosed in the McDaniel Patents Nos. 2,131,718 and 2,223,293 may be usefully employed); intermediate products in which the ratios may be 1.3 to 1: 1.5 to 1; 1.8 to 1 or thereabouts, and ratios up to 25Naz0 to 1310:. These products difler from one another as to the molecular quantity of sodium oxide which they contain and are therefore of differing alkaline activity.
  • alkali metal pyrophosphates and tripolyphosphates are preferred in the practice of the present invention because of their stability during the manufacturing process and their capacity to suppress the deposition or precipitation of calcium and magnesium compounds even at elevated temperatures for sub stantial periods of time in the presence of strong alkalies.
  • compositions of the present invention are advantageous because of their improved water softening and detergent value. They are therefore especially adapted to a large number of industrial cleaning operations.
  • a method of obtaining a dry. granular composition of an alkali metal silicate and an alkali metal phosphate which method comprises admixing an anhydrous alkali metal pyrophosphate with an alkali metal metasilicate containing from 2 to 9 molecules water of hydration while the said silicate is in a melted condition until a composition is obtained of uniform consistency and in such proportion that the alkali pyrophosphate constitutes about 5 to 40% by weight of said composition, then hardening said composition by permitting it to cool and then grinding said composition, said composition being characterized in that it is more readily soluble in water than a physical mixture of said components.
  • a method of making a d y. ranular composition of sodium metasilicate and anhydrous tetrasodium pyrophosphate comprises adding anhydrous tetrasodium pyrophosphate to sodium metasilicate pentahydrate while the sodium metasilicate is in a molten condition, admixing these components until a composition of uniform consistency is obtained, then permitting said composition to cool and harden, and then grinding the hardened material, the tetrasodium pyrophosphate component of said composition constituting from about 5 to 40% by weight of said'composition, and said composition being characterized in that it is more readily soluble in water than a physical mixture of said components.
  • a method of obtaining a water-soluble composition of an alkali metal silicate and an alkali metal phosphate comprises adding an anhydrous alkali metal pyrophosphate to a hydrated alkali metal metasilicate while said met'asilicate is in a molten condition, admixing said components to obtain a composition of uniform consistency, permitting said composition to cool and harden, and then comminuting said composition, the anhydrous phosphate component of said composition constituting from about 5 to 40% by weight of the whole and said com position being characterized in that it is more readily soluble in water than a physical mixture of the said components.
  • a method of obtaining a water-soluble composition of an alkali metal silicate and an alkali metal phosphate comprises adding an anhydrous alkali metal pyrophosphat to a hydrated alkali metal metasilicate while said metasilicate is in a molten condition, admixing said components to obtain a composition of uniform consistency and permitting said composition to cool and harden, then grinding said composition, the anhydrous phosphate component of said composition constituting from about 5 to 15% by weight of the whole and said composition being characterized in that it is more readily soluble in water than a physical mixture of the said components.
  • a method of obtaining a water-soluble composition of an alkali metal silicate and an alkali metal phosphate comprises admixing an alkali metal pyrophosphate with an alkali metal metasilicate pentahydrate while said metasilicate component is in a molten condition until a composition of uniform consistency is obtained and in such proportion that the anhydrous phosphate component constitutes about 5 to 15% by weight of said admixture, then permitting said composition to cool and harden and subsequently comminuting said composition, the said composition being characterized in that it is more readily soluble in water than a physical mixture of'said components.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Description

Patented Nov. 2, 1943 METHOD OF PREPARING DETERGENT COMPOSITIONS Edward A. Robinson, Mount Lebanon, Pa., assignor to Diamond Alkali Company, Pittsburgh, Pa., a corporation of Delaware No Drawing. Application December 23, 1940, Serial No. 371,406
Claims. (Cl. 252-135) This invention relates toalkali metal silicate compositions and to a method of preparing them..
The products of the invention are adapted particularly for detergent purposes such as in cleansing, washing, degreasing, and scouring operations.
One of the principal objects of the present invention has been to provide detergent compositions comprised of alkali metal silicates which are adapted to prevent the formation of lime and magnesium deposits and precipitates when they are used in unsoftened water. It has been understood in the past by those skilled in the art that the use of alkali metal phosphates is helpful in obtaining this result. For instance, a composition comprised of anhydrous tetrasodium pyrophosphate and sodium metalsilicate mixed to gather in a dry state is adapted for the purpose, but such a mixture is slow to dissolve in water, because the pyrophosphate, in picking up water to form its decahydrate, cements the particles of metasilicate together; and of itself the anhydrous pyrophosphate is very slow to dissolve in water. For that reason, as well as others, when an alkali metal phosphate of this type is to be used commercially to supplement a silicate in a detergent bath, the practice has been to dissolve the two components separately or use the more soluble decahydrate of tetrasodium pyrophosphate in mechanical mixes. The first procedure is obviously tedious and becomes a substantial nuisance when detergent baths are made up day after day, as in typical industrial operations, while the use of the decahydrate is' more expensive because of its higher cost per unit of P205. These difliculties are also encountered when mechanical mixes containing anhydrous sodium tripolyphosphate are made. Moreover, in addition to slow solubility, the components of dry mechanical mixes tend to separate, through sifting, especially if one of them is not of'the same particle size or degree of granulation or fineness as the other ingredients. It is the frequent experience that the composition at the top of the barrel .of the material will be difierent from the composition at the bottom of the barrel from this cause.
The objective of the present invention has been to provide a dry and granular detergent composition comprising an alkali metal silicate and an anhydrous alkali metal phosphate which, in addition to providing the desired water softening as well as detergent properties, is readily soluble in water and, therefore easy to use in the industrial operations for which it is intended. Otherwise expressed, the objective has been to obtain a material exhibiting all of the advantages which each component is capable of providing, but none of the disadvantages exhibited by a dry mixture of the same ingredients.
Briefly, the present invention is predicated upon the discovery that, while adry mixture of an alkali metal silicate and an anhydrous alkali metal phosphate is a composition difiicult to dissolve in water, the addition of the phosphate component while the alkali metal silicate is in a liquid condition provides a product which is of greatly improved solubility. The present invention contemplates a process for improving the water solubility of a silicate-anhydrous phosphate composition by incorporating the two with one another while the silicate is in a liquidstate, that is, before the silicate is crystallizedi In this process the two components are stirred together until a composition of uniform consistency is obtained, then the silicate is permitted to exert its crystallitic characteristic and harden. The resultant composition is adapted to be granulated or reduced to a marketable form in the usual manner as readily as the ordinary forms of crystallized alkali metal silicates.
The precise chemical explanations accounting for the fact that an admixture of the two components mechanically is not readily soluble in water while an admixture of the two components is freely soluble if made while one is in a liquid state, are not fully appreciated or explained by the present knowledge concerning the behavior of the chemicals. However, the fact is that the products made by the latter method dissolve in one-third to one-half the time required to dissolve dry-mix compositions, and are therefore especially suitable for industrial usage.
One of the characteristics of the alkali metal phosphates other than the orthophosphates is their tendency to revert to orthophosphates in the presence of strong alkalies and water at elevated temperatures. This reversion greatly reduces their water softening power. It has been discovered that under the manufacturing conditions of the present process, anhydrous tetrasodium pyrophosphate does not revert to orthophosphate to any marked degree when added to hot liquid alkali metalmetasilicates or to more alkaline silicate materials. It has also been discovered that if at least 15% of sodium tripolyphosphate is used in the compositions, there is very little tendency for this compound to revert to pyrophosphate and orthophosphate. As the quantity of tripolyphosphate is increased the reversion is still further lessened, and products containing about 30-40% sodium tripolyphosphate are stable and have the same water softening power as equivalent mechanical mixes. This stability remains undiminished for long periods after the compositions are prepared. The other complex phosphates of the kind heretofore available are much less stable under the conditions of this process and must ordinarily be dry mixed with alkali metal silicates to preserve their water softening power. Such mixes, of course, have the disadvantage of separation during shipment in barrels and other containers.
In the practice of the method of the present invention it is preferable that the silicate be in a hydrated form, that is, with approximately 2 to approximately 9 molecules water of hydration. Water may be present in excess of this amount, provided it does not detract from the ability of the silicate subsequently to crystallize.
The amount of phosphate which it is desirable to use for the prevention of the deposition of calcium and magnesium compounds is usually quite small, for example, in the neighborhood of to 15%, sometimes less and sometimes considerably more, in instances where the composition is to be used for a special purpose.
The process of the present invention enables supplementary components besides phosphates to be incorporated, for example, sodium carbonate or caustic soda. When sodium carbonate is used it, like the phosphate, is preferably in the anhydrous condition.
The following examples illustrate typical compositions of the present invention:
Example A Per cent Sodium metasilicate pentahydrate 80.00 Tetrasodium pyrophosphate anhydrous 15.00 Sodium carbonate anhydrous 5.00
Example B Per cent Sodium metasilicate pentahydrate 55.00 Tetrasodium pyrophosphate anhydrous.-- 40.00 Sodium carbonate anhydrous 5.00
This composition represents about the maximum amount of phosphate which is desirable to use.
Example C Per cent Sodium silicate (1.6Na2O-SiOr5.5H2O) 76.90 Tetrasodium pyrophosphate anhydrous 12.60 Sodium carbonate anhydrous 10.50
Example D Per cent Sodium orthosilicate (2NazO-Si0r5AHzO) 85.00 Tetrasodium pyrophosphate anhydrous 10.00
This composition represents about the maximum amount of phosphate which it is desirable to use. All percentages in the above examples are by weight.
All of these products exhibit pronounced ability to prevent the deposition of calcium and magnesium compounds. especially when they are used in conJunction with fatty acid soaps. This characteristic is displayed even after the materials have been maintained in aqueous solution at elevated temperatures for substantial periods of time. In operations where soap is not used they prevent the formation of calcium, magnesium, and iron phosphates and carbonates.
In the practice of the method, the phosphate component and any supplementary ingredients. such as sodium carbonate or the like. are added to the silicate component while it is in the liquid state, in the proportions desired, and the components are then stirred together so that the mass becomes of uniform composition over a period oi time during which the temperature is maintained to prevent crystallization of the mass from taking place. After the incorporating procedure the temperature of the mass is lowered and it crystallizes to a hard, grindable condition. For example, after the admixture, a given batch of the material, may be cast in pans and there permitted to cool, and the cakes so obtained can then be ground. In cases where the product is incorporated in the orthosilicates as disclosed in the McDaniel Patents Nos. 2,131,718 and 2,223,293, the final product is a flakedmaterial similar to the products made by the McDaniel process.
The silicates which are adapted to be used in the practice of the present invention are the metasilicate, in which the ratio of NaaO to 810: is 1 to 1; the orthosilicate, in which the ratio is 2 to l; (orthosilicates as disclosed in the McDaniel Patents Nos. 2,131,718 and 2,223,293 may be usefully employed); intermediate products in which the ratios may be 1.3 to 1: 1.5 to 1; 1.8 to 1 or thereabouts, and ratios up to 25Naz0 to 1310:. These products difler from one another as to the molecular quantity of sodium oxide which they contain and are therefore of differing alkaline activity. The alkali metal pyrophosphates and tripolyphosphates are preferred in the practice of the present invention because of their stability during the manufacturing process and their capacity to suppress the deposition or precipitation of calcium and magnesium compounds even at elevated temperatures for sub stantial periods of time in the presence of strong alkalies.
Besides the improved solubility exhibited by the compositions of the present invention, they are advantageous because of their improved water softening and detergent value. They are therefore especially adapted to a large number of industrial cleaning operations.
Having described my invention, I claim:
1. A method of obtaining a dry. granular composition of an alkali metal silicate and an alkali metal phosphate, which method comprises admixing an anhydrous alkali metal pyrophosphate with an alkali metal metasilicate containing from 2 to 9 molecules water of hydration while the said silicate is in a melted condition until a composition is obtained of uniform consistency and in such proportion that the alkali pyrophosphate constitutes about 5 to 40% by weight of said composition, then hardening said composition by permitting it to cool and then grinding said composition, said composition being characterized in that it is more readily soluble in water than a physical mixture of said components.
2. A method of making a d y. ranular composition of sodium metasilicate and anhydrous tetrasodium pyrophosphate, which method comprises adding anhydrous tetrasodium pyrophosphate to sodium metasilicate pentahydrate while the sodium metasilicate is in a molten condition, admixing these components until a composition of uniform consistency is obtained, then permitting said composition to cool and harden, and then grinding the hardened material, the tetrasodium pyrophosphate component of said composition constituting from about 5 to 40% by weight of said'composition, and said composition being characterized in that it is more readily soluble in water than a physical mixture of said components.
3. A method of obtaining a water-soluble composition of an alkali metal silicate and an alkali metal phosphate, which method comprises adding an anhydrous alkali metal pyrophosphate to a hydrated alkali metal metasilicate while said met'asilicate is in a molten condition, admixing said components to obtain a composition of uniform consistency, permitting said composition to cool and harden, and then comminuting said composition, the anhydrous phosphate component of said composition constituting from about 5 to 40% by weight of the whole and said com position being characterized in that it is more readily soluble in water than a physical mixture of the said components.
4. A method of obtaining a water-soluble composition of an alkali metal silicate and an alkali metal phosphate, which method comprises adding an anhydrous alkali metal pyrophosphat to a hydrated alkali metal metasilicate while said metasilicate is in a molten condition, admixing said components to obtain a composition of uniform consistency and permitting said composition to cool and harden, then grinding said composition, the anhydrous phosphate component of said composition constituting from about 5 to 15% by weight of the whole and said composition being characterized in that it is more readily soluble in water than a physical mixture of the said components.
5. A method of obtaining a water-soluble composition of an alkali metal silicate and an alkali metal phosphate, which method comprises admixing an alkali metal pyrophosphate with an alkali metal metasilicate pentahydrate while said metasilicate component is in a molten condition until a composition of uniform consistency is obtained and in such proportion that the anhydrous phosphate component constitutes about 5 to 15% by weight of said admixture, then permitting said composition to cool and harden and subsequently comminuting said composition, the said composition being characterized in that it is more readily soluble in water than a physical mixture of'said components.
EDWARD A. ROBINSON.
US2333443D Method of preparing detergent Expired - Lifetime US2333443A (en)

Publications (1)

Publication Number Publication Date
US2333443A true US2333443A (en) 1943-11-02

Family

ID=3433557

Family Applications (1)

Application Number Title Priority Date Filing Date
US2333443D Expired - Lifetime US2333443A (en) Method of preparing detergent

Country Status (1)

Country Link
US (1) US2333443A (en)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2439784A (en) * 1944-12-30 1948-04-13 Hall Lab Inc Process of boiling out steam boilers prior to placing them in operation and composition therefor
US2712529A (en) * 1948-10-21 1955-07-05 Procter & Gamble Detergent composition
US2909490A (en) * 1954-07-28 1959-10-20 Olin Mathieson Manufacture of duplex composition of sodium tripolyphosphate and sodium silicate solution
US2987483A (en) * 1956-07-02 1961-06-06 Pennsalt Chemicals Corp Cleaning composition
US3941723A (en) * 1971-05-14 1976-03-02 Philadelphia Quartz Company Crystallized alkali metal silicate with sequestering agents
US4556505A (en) * 1982-04-05 1985-12-03 Fenn & Company Material for drying cut plants and grains and methods of facilitating such drying
US4561995A (en) * 1982-04-05 1985-12-31 Fenn & Company Material for drying cut plants and methods of facilitating such drying
US4569780A (en) * 1978-02-07 1986-02-11 Economics Laboratory, Inc. Cast detergent-containing article and method of making and using
US4687121A (en) * 1986-01-09 1987-08-18 Ecolab Inc. Solid block chemical dispenser for cleaning systems
US4690305A (en) * 1985-11-06 1987-09-01 Ecolab Inc. Solid block chemical dispenser for cleaning systems
USRE32763E (en) * 1978-02-07 1988-10-11 Ecolab Inc. Cast detergent-containing article and method of making and using
US5209864A (en) * 1991-07-03 1993-05-11 Winbro Group, Ltd. Cake-like detergent and method of manufacture

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2439784A (en) * 1944-12-30 1948-04-13 Hall Lab Inc Process of boiling out steam boilers prior to placing them in operation and composition therefor
US2712529A (en) * 1948-10-21 1955-07-05 Procter & Gamble Detergent composition
US2909490A (en) * 1954-07-28 1959-10-20 Olin Mathieson Manufacture of duplex composition of sodium tripolyphosphate and sodium silicate solution
US2987483A (en) * 1956-07-02 1961-06-06 Pennsalt Chemicals Corp Cleaning composition
US3941723A (en) * 1971-05-14 1976-03-02 Philadelphia Quartz Company Crystallized alkali metal silicate with sequestering agents
US4569780A (en) * 1978-02-07 1986-02-11 Economics Laboratory, Inc. Cast detergent-containing article and method of making and using
USRE32763E (en) * 1978-02-07 1988-10-11 Ecolab Inc. Cast detergent-containing article and method of making and using
US4556505A (en) * 1982-04-05 1985-12-03 Fenn & Company Material for drying cut plants and grains and methods of facilitating such drying
US4561995A (en) * 1982-04-05 1985-12-31 Fenn & Company Material for drying cut plants and methods of facilitating such drying
US4690305A (en) * 1985-11-06 1987-09-01 Ecolab Inc. Solid block chemical dispenser for cleaning systems
US4687121A (en) * 1986-01-09 1987-08-18 Ecolab Inc. Solid block chemical dispenser for cleaning systems
US5209864A (en) * 1991-07-03 1993-05-11 Winbro Group, Ltd. Cake-like detergent and method of manufacture

Similar Documents

Publication Publication Date Title
US2412819A (en) Detergent briquette
US2333443A (en) Method of preparing detergent
US2382163A (en) Detergent briquette
US2382165A (en) Detergent briquette
US2382164A (en) Detergent briquette
JPH041800B2 (en)
US2374100A (en) Water treatment
US2365190A (en) Washing compositions
US3620979A (en) Process of forming free-flowing, particulate mixtures of phosphates and silicates
US2333444A (en) Method op preparing stable deter
US3174934A (en) Hydration of sodium tripolyphosphate
US2427642A (en) Rapidly soluble tetrasodium pyrophosphate
US3058917A (en) Liquid dishwashing detergent
US3630928A (en) Particles containing mixtures of polyphosphates and silicates
US2310475A (en) Soap
US3303134A (en) Detergent processes and compositions therefor
US2746930A (en) Process for making detergent compositions
US3285859A (en) Alkali metal silicates and method for producing the same
US2909490A (en) Manufacture of duplex composition of sodium tripolyphosphate and sodium silicate solution
JPS60262896A (en) Granular nonionic detergent composition containing builder
US2145015A (en) Dry disinfecting composition and method of making the same
US2897155A (en) Process for preparing a detergent composition containing anhydrous form 11 tripolyphosphate
US2175781A (en) Process for the manufacture of sodium silicate detergents
US3271317A (en) Silicated sodium hydroxide
US2153872A (en) Method of making alkali metal silicates