US2424034A - Tin-plate brightening apparatus - Google Patents

Tin-plate brightening apparatus Download PDF

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US2424034A
US2424034A US474649A US47464943A US2424034A US 2424034 A US2424034 A US 2424034A US 474649 A US474649 A US 474649A US 47464943 A US47464943 A US 47464943A US 2424034 A US2424034 A US 2424034A
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chamber
strip
liquid
compartment
oil
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US474649A
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Hopper Edward William
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Crucible Steel Company of America
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Crucible Steel Company of America
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/48After-treatment of electroplated surfaces
    • C25D5/50After-treatment of electroplated surfaces by heat-treatment

Definitions

  • the pump 50 will likewise produce a pressure in chamber 46 which is somewhat above the hydrostatic pressure at passageways 45 and 41 when the circulating system is not in operation, and substantial equilibrium will be attained when the circulating system is in operation with very little interchange of oil between the compartments 44 and 48.
  • the oil streams in chamber 46 likewise counteract kinetically the tendencyof hot oil to flow along with strip 43 through the passageway 45.

Description

July 15, 1947. E, w, HOPPER 2,424,034
TINPLA TE BRIGHTENI NG APPARATUS Filed Feb. 4, 1943 5 Sheets-Sheet 1 IN VEN TOR.
EBDYWARD WffJPPE/P.
ATTORNEYS July 15, 1947. w HQPPER 2,424,034
- TINPLATE BRIGHTENING APPARATUS Filed Feb. 4, 1943 3' Sheets-Sheet 2 IN V EN TOR.
EgiA/AAD WffoPPEe. (W1 44, PM
ATTORNEYS,
July 15, 1947. E, w HOPPER 2,424,034
TINPLATE BRIGHTENING APPARATUS Filed Feb. 4; 1943 s Sheets-Sheet s INVENTOR. EDI/I44 RD WDPPEE'.
A TTO R/VEYS' Patented July 15, 1947 TIN-PLATE BRIGHTENING APPARATUS Edward William Hopper, Midland, Pa., assignor to Crucible Steel Company of America, New York, N. Y., a corporation of New Jersey Application February 4, 1943, Serial No. 474,649
2 Claims.
The invention relates to tinplate brightening apparatus of the type wherein the tin-containing coating is melted while immersed in a relatively hot bath, and is thereupon passed into a cooler bath to solidify the coating in brightened condition. In the use of such apparatus it is important that the tinplated strip be kept out of contact with solid surfaces during the above mentioned steps of treatment, and it has been customary to provide a passageway communicating between the baths below their liquid level, through which passageway a strip under treatment is passed, as in the patents to J. F. Ferm No. 2,141,382, dated December 27, 1938, and No. 2,192,303, dated March 5, 1940. The use of such a passageway creates a problem of preventing or minimizing intermingling of the two baths and consequent temperature equalization as caused by flow of the liquid through the passageway, due both to convection currents set up by the difference in density between the hotter and cooler liquids, and to the tendency of a certain amount of the hotter liquid to be entrained along with the moving tinplated strip and thus pass from the hotter to the cooler bath.
The primary object of the present invention is to provide a simple and effective method of minimizing temperature equalization of the above character, with consequent conservation of heat. The invention also contemplates effective control of rate of cooling and crystallization of the tin coating, thereby promoting the production of a uniform high quality product having a bright finish.
In accordance with the present invention I interpose between the hotter and cooler baths above mentioned a chamber which is constructed to constrict as far as possible the flow of liquid be tween the two baths, i. e., the passageways connecting the chamber with the baths afford only such clearance as is necessary to permit the tinplated strip to travel through without touching the walls of the passageways, and liquid under pressure is circulated through such chamber in such manner that the pressure within the chamber, and also the streams of liquid circulating therethrough, oppose the flow of the liquid from the hotter bath into the cooler bath. In the drawings- Fig. 1 is a vertical longitudinal sectional view somewhat schematic, of one form of apparatus constructed to operate in accordance with the invention and involving the use of hot and cool oil tanks which are located side by side.
Fig. 2 is a view in general similar to Fig. 1 I
but involving a modified form of apparatus, and
certain parts being cut away, which may be assumed to be similar to those shown in Fig. 1.
Fig. 3 is a view similar to Fig. 1 but involving the use of successive treating chambers which are located one above the other. i
Fig. 4 is also a view similar to Fig. 1 and involving the use of tanks located side by side, and with the apparatus also modified as compared to Fig. 1.
Fig. 5 is a section on line 5-5 of Fig. 4 looking in the direction of the arrows.
Fig. 6 is also a view similar to Fig. 1 and showing a further modification of the invention.
In Fig. 1 the invention is shown as applied to a tinplate brightening apparatus having a compartment I containing a bath of appropriate liquid, for example as described in the patent to Fink No. 2,303,035, November 24, 1942, in which bath the continuously moving tinplate strip 2 is immersed during the stage that its tin containing coating is melted as above described. As shown in Fig. 1 the strip 2, before passing into chamber I, first passes over guide rolls 3 and 4, the latter of which is located in a preliminary liquid containing chamber Ia. From this chamber la the plated strip passes through a passageway 5 and then through chamber I in a, substantially horizontal direction as hown, being led out of chamber I through a narrow passageway 6. From the standpoint of the present invention in its broader aspects, the particular method of melting the tin containing coating is not essential, i. e., the bath itself may supply all the heat needed to melt the coating, as may be considered to be the case in the apparatus of Fig. 1, or as hereinafter described appropriate additional heating means such as a high frequency electrical induction unit or heating by electrical resistance currents, may be used.
From the compartment I the strip 2 passes into a chamber 1 which is interposed between the hotter oil of compartment I and a cooler oil bath contained in a compartment 8, the strip 2 passing from chamber I through a passageway 9 in the side wall of compartment 8. The clearance between the walls of the passageways 6 and 9 is made as small as possible consistent with keeping the strip 2 out of contact with these walls, thus constricting as far as possible, the flow of liquid between the chamber I and compartments I and 8, and also enabling a higher liquid pressure to be maintained in chamber 1 as hereinafter described.
Liquid under pressure is then caused to circulate through chamber I so as to build up a higher liquid pressure therein. In the form of the invention shown in Fig. 1 a pump I0 Supplies cooler liquid from compartment 8 through a pipe II to a header I2, from whence the liquid passes into chamber I through inlet ports I3 which are disposed on opposite sides of strip 2. Streams of liquid thus flow along the opposite surfaces of the strip as indicated by the arrows in Fig. 1, in general countercurrent direction with respect to the direction of travel of the strip 2 and of the liquid which tends to be entrained along therewith. The streams of liquid thus oppose the flow f liquid from compartment I through passageway into chamber I, and also the pressure produced by the pump II] in chamber 1 is somewhat higher than the normal hydrostatic pressure at passageway 6 when the pump is not in action. Thus when the system is put into operation a certain amount of liquid may flow initially from chamber 1 into the compartment I to raise the level of the liquid therein to some extent, until operating conditions substantially reach an equilibrium such that there is a very little flow of hot liquid into chamber I from compartment I.
The conditions of operation will be such that the tin containing coating of strip 2 as it leaves compartment I will be in molten condition, and the temperature of the liquid in chamber I may be regulated to control the rate of crystallization and cooling of the coating.
As shown in Fig. 1 the liquid stream passes out of chamber I through ports I4 located respectively above and below strip 2 near the passageway 6, and communicating with a header I5 from which the oil is returned to compartment 8 through a pipe I6. A heat interchanger is indicated diagrammatically at I! for cooling the circulating liquid if desired. Palm oil may be mentioned as a liquid suitable to be used in carrying out the invention, the temperature of the oil in compartment I being about 460 F. or slightly higher, and the relatively cooler oil circulating through chamber 1 and compartment 8 being at a' temperature say of 150 F. The tin coating should be relatively cool before coming into contact with the guide roll I8 in compartment 8, from whence the strip may pass up and out between the rolls I9 as shown in Fig. 1.
Due both to the streams of oil passing through chamber I and the increase in pressure which is made possible by the constricted passageways connecting this chambe with the compartments I and 8, the carry over of hot oil from compartment I along with the strip is minimized, the rate of cooling the strip is kept under control, and the various areas of the tin coated surfaces are subjected to substantially uniform treating conditions.
Fig. 2 shows a somewhat modified form of apparatus wherein an electrical high frequency induction heating unit 20 is used to melt the tin containing coating. As shown the strip passes from a compartment Ia containing a liquid bath similar to compartment I except that the liquid may be at somewhat lower temperature. From compartment Ia strip 2 passes through a constricted throat 2I which is surrounded by the induction heating unit 20' above described, it-' being understood that the latter may be constructed as known in the art or in appropriate manner, its specific design not being a part of the present invention.
From the throat 2I the strip 2 preferably passes in this instance through a heat trap chamber 22, it being understood that the tin coating is in melted condition as the strip leaves throat 2|. The temperature in chamber 22 may range say from 300-400 F. thus causing the coating to solidify in chamber 22, and "further causinga substantial amount of residual heat in strip 2 to be absorbed by the oil in chamber 22, from whence the hot liquid is pumped back through outlet ports 23 in chamber 22 and a header 24, through pump 25 and a pipe line 26 leading back into compartment la. The temperature of the liquid in compartment Ia may range say from to 300 F., thus imparting a certain amount of preheat to strip 2 while passing through compartment Ia, and circulating liquid passes through throat 2| along with the strip.
From the chamber 22 the partially cooled strip may pass through a constricted passageway 6a similar to the passageway 6 above described in connection with Fig. 1, and into a cooler liquid containing chamber Ia. similar in construction and function to the chamber above described in connection with Fig. 1 and having outlet ports I4a, a header I5a and a pipe I6 similar respectively to the parts I4, l5, etc., of Fig. 1. In fact the parts which are cut away at the right of Fig. 2 may all be understood as similar to the parts appearing at the right of Fig. 1.
Fig. 3 shows a form of the invention adapted for use in connection with tinplate brightening apparatus wherein an initial liquid bath is located in a compartment 21, from whence the strip 2 passes downwardly through a throat 2Ia surrounded by an electrical induction heating unit 20a, to a subjacent heat trap chamber 22a. The last mentioned parts may be understood as comparable respectively to the elements 20, 2| and 22 above described in connection with Fig. 2, and the heat trap chamber 220, will also have outlet ports 23a, a header 24a, pump 25a. and pipe 26a leading back to the compartment 21, and respectively comparable to the parts 23 to 26 above described in connection with Fig. 2.
In the apparatus of Fig. 3, residual heat from strip 2 as the tin containing coating solidifies in chamber 22a, will be absorbed by the liquid contained in such chamber, and the heated liquid circulated back into compartment 2'! s as to serve for preheating the strip 2 as it passes through the'latter. In the apparatus of Fig. 3
the oil will also circulate downwardly through throat 2 la in opposition to the rising convective currents of liquid which otherwise would tend to be formed in such throat.
From the chamber 22a above described the strip passes through a constricted passageway 61) into a chamber 1b which may be understood as similar in construction and function to the chambers I and la already described, and having a pump I01), a, pipe IIb, aheader I2b, inlet ports I3b, outlet ports Mb, a header I5b, pipe I61: and heat exchanger IIb respectively similar to the parts I 0 to I! already described in connection with Fig. 1. In this instance however the relatively cool oil in chamber 'Ib, being at all points heneath the level of the hotter liquid in chamber 22a, will not tend to admix with the latter. Both the circulating oil streams passing through chamber 1b and the pressure produced therein by pump I0b will minimize the downward entrainment of hot oil through passageway 6b. From the chamber Ib the strip passes downwardly through a narrow passageway 9b to a final compartment 81) containing cooler liquid, such compartment being in this instance U- shaped and having guide rolls I8b which lead the strip to pass upwardly to rolls I9b, respectively similar to the parts I8 and I9 of Fig, 1. In this vertical form of apparatus there is very little tendency of the strip 2 to vibrate or sag in passing through the throat 2Ia and the passageways 6b and 9b, and thus the latter may be made exceedingly narrow, as is advantageous in promoting the efiiciency of the apparatus.
In the apparatus of Figs. 4 and 5 a tin coated strip 33 is fed from a hot oil bath 34 through a passageway 35 comparable to the passageway 6 previously described, then through a chamber 36 comparable to the chamber 1 previously described, then through a passageway 31 comparable to the passageway 9 previously described, and then into a cooler oil compartment 38 comparable to the bath 8 previously described. In this form of the invention however the oil is pumped through the chamber 36 under pressure in streams which pass substantially parallel to the strip 33 and transverse to its direction of travel. As shown in Fig. the incoming oil streams may pass from a header 39 through inlet ports 46 disposed respectively above and below the level of strip 33, and the oil stream may pass out of chamber 36 through exit ports 4| also disposed respectively above and below the level of strip 33 and communicating with an offtake header 42, The headers 39 and 42 may be regarded as comparable in function respectively to the headers 12 and 15 of Fig. 1 and having similar circulating connections (not shown in Figs. 4 and 5). In this instance the oil pressure obtaining in chamber 36 will also be slightly above the normal hydrostatic pressure at the passageways 35 and 31 when the oil circulating system is out of operation. Then when the system goes into operation it will reach a condition of substantial pressure equilibrium at the passageways 35 and 31, under which condition there will be very little interchange of oil between the compartments 34 and 38.
Fig. 6 illustrates a further modification wherein the tin coated strip 43 is led through a relatively hot oil compartment 44 comparable to the bath 34 of Fig. 4, then through passageway 45 comparable to the passageway 35 of Fig. 4, and then through a chamber 46 comparable to the chamber 36 of Fig. 4, then through passageway 41 comparable to the passageway 31 of Fig. 4, and then through a cooler oil containing compartment 48 comparable to the compartment 36 of Fig. 4. In the case of Fig. 6 circulating oil for chamber 46 is drawn from a separate reservoir 49 by a pump 59 and supplied under pressure to a header 5| located at an intermediate point along the length of chamber 46, From the header 5! the oil under pressure passes through upper and lower ports 52 into contact with the upper and lower surfaces of strip 43, from whence the oil streams divide as indicated by the arrows in Fig. 5 and pass respectively toward the opposite ends of chamber 46, from whence they are exhausted through ofitake ports 53 and 54 at the opposite ends of chamber 46. These offtake ports communicate respectively with headers 55 and 56 from whence oil circulates back into reservoir 49 through the pipes 51 and 58 respectively.
In the operation of the apparatus of Fig. 6 the pump 50 will likewise produce a pressure in chamber 46 which is somewhat above the hydrostatic pressure at passageways 45 and 41 when the circulating system is not in operation, and substantial equilibrium will be attained when the circulating system is in operation with very little interchange of oil between the compartments 44 and 48. The oil streams in chamber 46 likewise counteract kinetically the tendencyof hot oil to flow along with strip 43 through the passageway 45.
Alternatively, in respect to the form of the invention above described in connection with Fig. 3, the direction of flow of the liquid through the pipe 26a may be reversed so as to cause the oil to circulate through throat 2la in counterflow fashion, i. e., in a direction opposite to the direction of travel of the strip. In this case the liquid passing up from chamber 22a and through the throat Zla, will absorb heat from the strip and then pass upwardly into compartment 21, giving up heat to the downwardly moving strip 2 so as to preheat the latter.
While the invention has been disclosed as carried out by the above described specific forms of apparatus, it should be understood that many changes may be made therein without departing from the invention in its broader aspects, within the scope of the appended claims.
I claim:
1. Tinplate brightening apparatus of the class described having an upper relatively hot liquid containing compartment having associated therewith a throated portion affording downward travel of a plated strip or the like through said compartment and throat, a heating unit enclosing said throat and constructed to melt the coating of the strip as it passes such throated portion, a heat trap chamber disposed beneath said throat and in the path of travel of said strip, means being provided to circulate liquid between said chamber and said compartment, said apparatus including a relatively cooler liquid containing compartment disposed beneath said chamber.
2. Tinplate brightening apparatus of the class described having an upper relatively hot liquid containing compartment having associated therewith a throated portion affording downward travel of a plated strip or the like through said compartment and throat, a heating unit enclosing said throat and constructed to melt the coating of the strip as it passes such throated portion, a heat trap chamber disposed beneath said throat and in the path of travel of said strip, means being provided to circulate liquid between said chamber and said compartment, said apparatus including a relatively cooler liquid contain ing compartment disposed beneath said chamber and also including a second chamber interposed between said first mentioned chamber and said relatively cooler liquid containing compartment, means being provided to pass relatively cool liquid through said last mentioned chamber.
EDWARD WILLIAM HOPPER.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Number Name Date 2,171,437 Tannehill Aug. 29, 1939 1,864,490 Harrison June 21, 1932 1,991,81'1 Nachtman Feb. 19, 1935 2,141,382 Ferm Dec. 27, 1938 2,192,303 Ferm Mar. 5, 1940 1,068,411 Chubb July 29, 1913 2,162,692 Bailey June 20, 1939 2,274,963 Hopper Mar. 3, 1942 7 2,357,126 Nachtman Aug. 29, 1944 Re. 20,673 Meyers Mar. 15, 1938
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2536186A (en) * 1946-05-02 1951-01-02 John D Keller Method of wiping liquid metal coatings
US2839437A (en) * 1955-04-21 1958-06-17 Jones & Laughlin Steel Corp Method of producing a dull finished fused tin coating
US2904321A (en) * 1953-03-13 1959-09-15 Bostroem Theodore Liquid bath furnace and methods for continuous heat treatment of articles of manufacture
US3021236A (en) * 1958-05-28 1962-02-13 Midland Ross Corp Convective heat transfer furnace and method
US3287158A (en) * 1962-08-09 1966-11-22 Whitfield Lab Inc Coating of metal with other metals
US3358980A (en) * 1965-01-21 1967-12-19 Inland Steel Co Apparatus for quenching web material
US3832973A (en) * 1969-01-29 1974-09-03 Kalle Ag Apparatus for the production of a multi-layer sheet material of microporous structure
US3845540A (en) * 1972-04-28 1974-11-05 Maneely Illinois Hot galvanizing process and apparatus
US4709716A (en) * 1986-09-16 1987-12-01 Rca Corporation Rinse tank
US4982686A (en) * 1986-07-09 1991-01-08 Miply Equipment, Inc. Converging chamber saturator with removable insert

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1068411A (en) * 1910-01-26 1913-07-29 Westinghouse Electric & Mfg Co Method of and apparatus for coating wires.
US1864490A (en) * 1926-08-23 1932-06-21 Florence M Harrison Electrolytic apparatus
US1991817A (en) * 1930-02-04 1935-02-19 John S Nachtman Method of plating steel
USRE20673E (en) * 1938-03-15 Wire ob strip tinning machine
US2141382A (en) * 1938-08-10 1938-12-27 Pittsburgh Crucible Steel Comp Apparatus for treating plated strip metal
US2162692A (en) * 1935-11-11 1939-06-20 Thaddeus F Baily Continuous strip furnace
US2171437A (en) * 1937-03-05 1939-08-29 Walter W Lepper Apparatus for the electrolytic production of metallic shapes
US2192303A (en) * 1938-12-27 1940-03-05 Pittsburgh Crucible Steel Comp Apparatus for treating plated strip metal
US2274963A (en) * 1938-08-10 1942-03-03 Crucible Steel Company Process for plating tin and tin alloys
US2357126A (en) * 1938-05-05 1944-08-29 John S Nachtman Alloying and fusing process

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE20673E (en) * 1938-03-15 Wire ob strip tinning machine
US1068411A (en) * 1910-01-26 1913-07-29 Westinghouse Electric & Mfg Co Method of and apparatus for coating wires.
US1864490A (en) * 1926-08-23 1932-06-21 Florence M Harrison Electrolytic apparatus
US1991817A (en) * 1930-02-04 1935-02-19 John S Nachtman Method of plating steel
US2162692A (en) * 1935-11-11 1939-06-20 Thaddeus F Baily Continuous strip furnace
US2171437A (en) * 1937-03-05 1939-08-29 Walter W Lepper Apparatus for the electrolytic production of metallic shapes
US2357126A (en) * 1938-05-05 1944-08-29 John S Nachtman Alloying and fusing process
US2141382A (en) * 1938-08-10 1938-12-27 Pittsburgh Crucible Steel Comp Apparatus for treating plated strip metal
US2274963A (en) * 1938-08-10 1942-03-03 Crucible Steel Company Process for plating tin and tin alloys
US2192303A (en) * 1938-12-27 1940-03-05 Pittsburgh Crucible Steel Comp Apparatus for treating plated strip metal

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2536186A (en) * 1946-05-02 1951-01-02 John D Keller Method of wiping liquid metal coatings
US2904321A (en) * 1953-03-13 1959-09-15 Bostroem Theodore Liquid bath furnace and methods for continuous heat treatment of articles of manufacture
US2839437A (en) * 1955-04-21 1958-06-17 Jones & Laughlin Steel Corp Method of producing a dull finished fused tin coating
US3021236A (en) * 1958-05-28 1962-02-13 Midland Ross Corp Convective heat transfer furnace and method
US3287158A (en) * 1962-08-09 1966-11-22 Whitfield Lab Inc Coating of metal with other metals
US3358980A (en) * 1965-01-21 1967-12-19 Inland Steel Co Apparatus for quenching web material
US3832973A (en) * 1969-01-29 1974-09-03 Kalle Ag Apparatus for the production of a multi-layer sheet material of microporous structure
US3845540A (en) * 1972-04-28 1974-11-05 Maneely Illinois Hot galvanizing process and apparatus
US4982686A (en) * 1986-07-09 1991-01-08 Miply Equipment, Inc. Converging chamber saturator with removable insert
US4709716A (en) * 1986-09-16 1987-12-01 Rca Corporation Rinse tank

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