US2491225A - Method of protecting subterranean metallic structures - Google Patents

Method of protecting subterranean metallic structures Download PDF

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US2491225A
US2491225A US558924A US55892444A US2491225A US 2491225 A US2491225 A US 2491225A US 558924 A US558924 A US 558924A US 55892444 A US55892444 A US 55892444A US 2491225 A US2491225 A US 2491225A
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protecting
pipe line
buried
structures
protected
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US558924A
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Dick E Stearns
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00Apparatus or processes specially adapted for manufacturing conductors or cables
    • H01B13/22Sheathing; Armouring; Screening; Applying other protective layers
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F13/00Inhibiting corrosion of metals by anodic or cathodic protection
    • C23F13/02Inhibiting corrosion of metals by anodic or cathodic protection cathodic; Selection of conditions, parameters or procedures for cathodic protection, e.g. of electrical conditions
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L58/00Protection of pipes or pipe fittings against corrosion or incrustation
    • F16L58/02Protection of pipes or pipe fittings against corrosion or incrustation by means of internal or external coatings
    • F16L58/16Protection of pipes or pipe fittings against corrosion or incrustation by means of internal or external coatings the coating being in the form of a bandage

Definitions

  • This invention .relatesto ⁇ method and. means, of protecting subterranean or. buried metallic. structures from electrolysis and corrosiondue. to local action.
  • theA present custom is, to.. install an anode yat a substantialdistance.away fromv the pipe line .so .thatdirect .current .induced tolow from.. the anode Yto ythepipe line willbe spread over asubstantial length of. the pipeline. Because of the relative nearness of the conventional anode-tothe pipeline-as compared to the extent of the pipe line over which protection from corrosion is desired,v there isV substantial wastage of electrical energy between the two extremities (of 0 the pipe linesectionunder Iprotection) receiving i the critical amount of potential required for protection.
  • interferencei occurs where two structures, one. of whichisprotected by the usual method,... approachA onerosa-each other.
  • Someoffthe current from..v the buried anode williowto anadacent. portion o the other structure, thence along that structure to the point ci nearest approach of the two structures, and then across to the structure being protected. This does not hurt the structure being protected, but will quickly eat away or cori-ode the other structure and destroy it.
  • the present. invention has for .its principal and general objectthe provision of fully adequate and reliable protection for a pipeline or similar struct ture buried in the earth or .otherwise made subject to corrosiondue to electrolysisand local electro? chemical action..
  • Another object Voftheloresent invention isV to provide a means for more adequatelycontrolling the current flow by which the protection is' secured, as ⁇ compared with. inadequate current control of the methods heretofore used..
  • Another object is to avoid the interference above described.
  • Fig. 1 is a view partly in. elevation Yand partly in longitudinal cross section through a pipe line, illustratingY the apparatus employed and the method of carrying jout'the present invention.
  • Fig. 2 is atransverse crosssection'taken along the line '2"-2'of Fig; l. Y
  • Fig. 3 isa diagrammatic illustration showing the. applicationof the protective voltage to a pipe or similar object 'to be protected in. accordance with this invention.
  • the numeral l illustrates. a pipeline which in this particular instance is' the structure to be. protected.' This pipeline .isprovidedwith an insulating coating 2 'which' may generallyv speaking be of the type presently.4 employed on suchlstruc'- tures such asy enamels or coatings having a coaltar base oranyother suitablecoating material.
  • a sheathing or wrapping of sheet metal or metal foil 4 may be of any suitable material but is preferably of some very light and thin material such as aluminum foil and is preferably of such a nature as to cover the entire or substantially the entire surface of the exterior of the insulated structure.
  • a pipe line or other structure coated or wrapped as just described it is put in place in the ground or in such other position as would subject it to electrolysis and local action, and the negative pole of a direct current Voltage is applied to the structure to be protected the same as in the present system of protecting such structures.
  • the other pole is connected directly to the sheathing 4 which covers substantially the entire surface of the insulation over the structure to be protected.
  • the sheathing 4 is made of metal, and preferably of a metal which has a very low electrical resistance, it will assume substantially the same potential throughout its extent, because unless there are holes in the insulating coating underneath this sheathing, there will be substantially no flow of current. Even if there is a considerable iiow of current, the extent of the metal sheathing provides a substantial path for the flow of current and hence would tend to minimize any voltage drop due to such ow.
  • the protection afforded Will be uniform and the voltage for providing such protection may be substantially lower than that which has heretofore been employed. Furthermore, due to the excellent path provided for current flow and the fact that the anode extends along, substantially parallel to and in close proximity to the structure to be protected,
  • the method of protecting buried metallic structures from corrosion due to electrolysis and local action which comprises coating the same the positive and negative poles of a source of di- 4 rect current electric voltage to said sheath and metallic structure respectively.
  • the method of protecting buried metallic structures from corrosion due to electrolysis and local action which comprises coating the same with an electrical insulator, sheathing the insulated coating of such structure with an electrically conductive sheath of sheet metal of foil thickness in close relation thereto, and applying the positive and negative poles of a source of direct current electric voltage to said sheath and metallic structure respectively.
  • the method of protecting buried metallic structures from corrosion due to electrolysis and local action which comprises coating the same with an electrical insulator, wrapping the coated structure with a thin metallic sheathing of foil thickness applied spirally over substantially the entire exterior surface of the structure in close relation thereto, and applying the positive and negative poles of a source of direct current electric voltage to said wrapping and said metallic structure respectively.
  • the method of protecting a pipe line of electrically conducting material to be buried in the ground from corrosion due to electrolysis and local action comprising the steps of coating the pipe line exteriorally with insulating material, applying a thin sheet of metal surrounding the insulating material in close relation thereto and applying the positive and negative poles of a source of direct current electric voltage to the sheet and pipe line, respectively.
  • the method of protecting a pipe line of electrlcally conducting material to be buried in the ground from corrosion due to electrolysis and local action comprising the steps of coating the pipe line exteriorally with insulating plastic material, then wrapping the coated pipe line spirally with a fibrous wrapper, then wrapping the thus coated pipe line with a metal wrapper of foil thickness in close relation with the fibrous wrapper and then applying the positive and negative poles of a source of direct current electric voltage to the metallic wrapping and pipe line, respectively.

Description

Patented Dec. 13, 1949 UNIT ED STATES v. PA-T-El`1'l`f OFFICE METHODmOFgPROSIECTING SUBTERR'ANEAN- i METALLIC STRUCTURES' Y Dick E.V Stearns; Shreveport, La.v
Application Octoberxl, 1944,- Serial hlm-558,924
5 Claims.' (Cl. 204-147) This invention .relatesto `method and. means, of protecting subterranean or. buried metallic. structures from electrolysis and corrosiondue. to local action.
It is common.practicettoprevent such electrolysis andv corrosion-.oisubsurface structures such as pipe lines or thelike vby .applyingto .the structure adirectcur-rent `volt'age'oi suchpolarity as to'causev the currenttolowin a direction to make deposit on the pipeline rather than to take material` from thepipe lineY or, other. structure. Such structuresV are usually:Ak coated. .with an insulating material but suchinsulationeither has or develops weakA spots .at which, .accelerated corrosion or electrolysistakes place `andthe electrical protection justy referred to tends .tcstopor atleast eife'ctively inhibit.thedeterioration otthe pipe line or other ,structureat such defective spotsin the insulation.
In applying. sucha voltage to a subterranean structure, theA present custom is, to.. install an anode yat a substantialdistance.away fromv the pipe line .so .thatdirect .current .induced tolow from.. the anode Yto ythepipe line willbe spread over asubstantial length of. the pipeline. Because of the relative nearness of the conventional anode-tothe pipeline-as compared to the extent of the pipe line over which protection from corrosion is desired,v there isV substantial wastage of electrical energy between the two extremities (of 0 the pipe linesectionunder Iprotection) receiving i the critical amount of potential required for protection. Efforts haveabeen-pmade'with a degree of success towards increasing over-all efficiency byV using several smaller units'over a given extent of pipe line rather thanr'having only one lunit therefor. At best, howeverythefprotection units with the present system-must ine-placed every-few miles along apipe-line lor similar structurein order to give the'necessary prOtection and even then the protection afforded is not uniform and is unreliable.
lAs 'an example 'of `one ofthe vproblems encountered'with the Apresently used system, there is a result known as interferenceiwhich occurs where two structures, one. of whichisprotected by the usual method,... approachA onerosa-each other. Someoffthe current from..v the buried anode williowto anadacent. portion o the other structure, thence along that structure to the point ci nearest approach of the two structures, and then across to the structure being protected. This does not hurt the structure being protected, but will quickly eat away or cori-ode the other structure and destroy it.
The present. invention. has for .its principal and general objectthe provision of fully adequate and reliable protection for a pipeline or similar struct ture buried in the earth or .otherwise made subject to corrosiondue to electrolysisand local electro? chemical action..
More specically itis an object of the present invention to provide more yadequate .protection for such a structure with a smaller number oi units than now necessaryandto make it. possible to place such units at the most convenient points on the structure., Another object Voftheloresent invention isV to provide a means for more adequatelycontrolling the current flow by which the protection is' secured, as` compared with. inadequate current control of the methods heretofore used..
Another object is to avoid the interference above described...
Other objects and advantages of this invention 'willbecome apparent from the followingdescription taken in connection with" the accompanying drawing wherein is set forth b'y way of illustration and example Vone embodiment of this invention.
In the drawing;
Fig. 1 is a view partly in. elevation Yand partly in longitudinal cross section through a pipe line, illustratingY the apparatus employed and the method of carrying jout'the present invention.
Fig. 2is atransverse crosssection'taken along the line '2"-2'of Fig; l. Y
Fig. 3 isa diagrammatic illustration showing the. applicationof the protective voltage to a pipe or similar object 'to be protected in. accordance with this invention.
Referring more in detail to the drawing, the numeral l illustrates. a pipeline which in this particular instance is' the structure to be. protected.' This pipeline .isprovidedwith an insulating coating 2 'which' may generallyv speaking be of the type presently.4 employed on suchlstruc'- tures such asy enamels or coatings having a coaltar base oranyother suitablecoating material.
V,Such acoating k2 manif. desired,.be wrapped'inV a manner .suchlas now employed with a suitable brous insulating wrapper such. as indicated at 3. It. willbe .understood that `upto this point. the 'practice described is thesame. as that.. employed in connection vwith `the. present protection of buried pipe lines'.
In accordance with the present invention, there is added to the coatings on the structure to be protected, a sheathing or wrapping of sheet metal or metal foil 4. This sheet metal or metal foil may be of any suitable material but is preferably of some very light and thin material such as aluminum foil and is preferably of such a nature as to cover the entire or substantially the entire surface of the exterior of the insulated structure. With a pipe line or other structure coated or wrapped as just described, it is put in place in the ground or in such other position as would subject it to electrolysis and local action, and the negative pole of a direct current Voltage is applied to the structure to be protected the same as in the present system of protecting such structures. However, instead of connecting the other pole to an electrode buried at a substantial distance from the structure to be protected, the other pole is connected directly to the sheathing 4 which covers substantially the entire surface of the insulation over the structure to be protected.
Inasmuch as the sheathing 4 is made of metal, and preferably of a metal which has a very low electrical resistance, it will assume substantially the same potential throughout its extent, because unless there are holes in the insulating coating underneath this sheathing, there will be substantially no flow of current. Even if there is a considerable iiow of current, the extent of the metal sheathing provides a substantial path for the flow of current and hence would tend to minimize any voltage drop due to such ow.
Inasmuch as the protective voltage is applied substantially uniformly over the entire surface of the structure to be protected, and at a position closely adjacent such structure, the protection afforded Will be uniform and the voltage for providing such protection may be substantially lower than that which has heretofore been employed. Furthermore, due to the excellent path provided for current flow and the fact that the anode extends along, substantially parallel to and in close proximity to the structure to be protected,
only a relatively few points of application of the voltage will be necessary and these may be located more nearly where they may be conveniently tended. Also since the sheath which forms the anode is close to the structure protected at all points and is between that structure and any adjacent structure, there will be no possibility of interference such as above described.
Although the method and means for protecting subterranean structures has been described as applied to buried pipe lines or the like, it will be appreciated that it may also be applied to other structures such as buried tanks, cables and in fact any structure which is in such a location that it is subjected to corrosion due to electrolysis and local action.
It will also be appreciated that by the apparatus and method just described there has been provided a means for carrying out and accomplishing all of the objects and advantages sought by this invention.
Having described my invention, I claim:
1. The method of protecting buried metallic structures from corrosion due to electrolysis and local action, which comprises coating the same the positive and negative poles of a source of di- 4 rect current electric voltage to said sheath and metallic structure respectively.
2. The method of protecting buried metallic structures from corrosion due to electrolysis and local action, which comprises coating the same with an electrical insulator, sheathing the insulated coating of such structure with an electrically conductive sheath of sheet metal of foil thickness in close relation thereto, and applying the positive and negative poles of a source of direct current electric voltage to said sheath and metallic structure respectively.
3. The method of protecting buried metallic structures from corrosion due to electrolysis and local action, which comprises coating the same with an electrical insulator, wrapping the coated structure with a thin metallic sheathing of foil thickness applied spirally over substantially the entire exterior surface of the structure in close relation thereto, and applying the positive and negative poles of a source of direct current electric voltage to said wrapping and said metallic structure respectively. v
4. The method of protecting a pipe line of electrically conducting material to be buried in the ground from corrosion due to electrolysis and local action comprising the steps of coating the pipe line exteriorally with insulating material, applying a thin sheet of metal surrounding the insulating material in close relation thereto and applying the positive and negative poles of a source of direct current electric voltage to the sheet and pipe line, respectively.
5. The method of protecting a pipe line of electrlcally conducting material to be buried in the ground from corrosion due to electrolysis and local action comprising the steps of coating the pipe line exteriorally with insulating plastic material, then wrapping the coated pipe line spirally with a fibrous wrapper, then wrapping the thus coated pipe line with a metal wrapper of foil thickness in close relation with the fibrous wrapper and then applying the positive and negative poles of a source of direct current electric voltage to the metallic wrapping and pipe line, respectively.
DICK E. STEARNS.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Number Name Date 843,357 Partee et al. Feb. 5, 1907 1,096,177 Marino May 12, 1914 1,867,984 Pistor July 19, 1932 1,871,125 McGary et al Aug. 9, 1932 FOREIGN PATENTS Number Country Date 249,714 vItaly Aug. 7, 1926 408,799 Germany Jan. 30, 1925 OTHER REFERENCES Transactions of the Electrochemical Society, vol. 64 (1933), pages 115 to 123.
Technologic Papers of the Bureau of Stand ards, No. 52, Dec. 27, 1915, pages 33 to A37.
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Cited By (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2744863A (en) * 1951-10-25 1956-05-08 Smith Corp A O Cathodic protection of metal in vapor space
US2847375A (en) * 1953-07-13 1958-08-12 Texas Co Apparatus for corrosion prevention
US2903405A (en) * 1956-05-24 1959-09-08 Sabins Dohrmann Inc Corrosion prevention system
US3151050A (en) * 1963-02-15 1964-09-29 David K Wilburn Laminated anti-corrosive paint system
US3254012A (en) * 1962-07-20 1966-05-31 Concrete Thermal Casings Inc Method of cathodically protecting heat-insulated pipes
US3260661A (en) * 1965-04-01 1966-07-12 Koppers Co Inc Sacrificial metal pipe coverings
US3265601A (en) * 1961-05-26 1966-08-09 Inst Francais Du Petrole Process for protecting metals against corrosion at elevated temperatures
US3303118A (en) * 1963-04-08 1967-02-07 Engelhard Ind Inc Cathodic protection and anti-marine fouling electrode system
US3313721A (en) * 1958-12-31 1967-04-11 Englehard Ind Inc Dish-shaped anode
US3349017A (en) * 1966-05-02 1967-10-24 Concrete Thermal Casings Inc Method and structure of cathodically protecting metallic casings of heat distribution systems
US3409525A (en) * 1965-05-24 1968-11-05 Goodyear Tire & Rubber Process for reducing corrosion
US3484350A (en) * 1965-04-28 1969-12-16 Allegheny Ludlum Steel Method of producing trim members
US3623968A (en) * 1968-01-02 1971-11-30 Tapecoat Co Inc The Sacrificial anode and pipe protected thereby
US3868313A (en) * 1972-02-25 1975-02-25 Philip James Gay Cathodic protection
US3990478A (en) * 1974-11-20 1976-11-09 Inland Steel Company Combined strengthening and corrosion protection of pipelines
US4091291A (en) * 1975-05-22 1978-05-23 Reynolds Metals Company System for underground distribution of electrical power and electrical cable construction for use therein
US4502929A (en) * 1981-06-12 1985-03-05 Raychem Corporation Corrosion protection method
FR2602800A1 (en) * 1986-04-30 1988-02-19 Trest Juzhvodoprovod METHOD OF PROTECTING CORROSION OF THE INNER SURFACE OF A CONDUCT
US4812212A (en) * 1987-09-08 1989-03-14 Harco Technologies Corporation Apparatus for cathodically protecting reinforcing members and method for installing same
US4957612A (en) * 1987-02-09 1990-09-18 Raychem Corporation Electrodes for use in electrochemical processes
US4990231A (en) * 1981-06-12 1991-02-05 Raychem Corporation Corrosion protection system
US5378336A (en) * 1991-06-25 1995-01-03 Ecoline Anticorrosion S.R.L. Inert anode for dissipation of continuous current
US5411646A (en) * 1993-05-03 1995-05-02 Corrpro Companies, Inc. Cathodic protection anode and systems
US6238545B1 (en) 1999-08-02 2001-05-29 Carl I. Allebach Composite anode, electrolyte pipe section, and method of making and forming a pipeline, and applying cathodic protection to the pipeline
US6554992B1 (en) * 1995-06-07 2003-04-29 Mcwane, Inc. Aluminum alloy exterior coating for underground ductile iron pipe

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US843357A (en) * 1906-01-24 1907-02-05 William Arky Partee Hull-cleaning and friction-reducing apparatus.
US1096177A (en) * 1912-08-27 1914-05-12 Pascal Marino Process of superficially metallizing the surface of cast-iron, wood, gypsum, paper, and other porous substances or articles.
DE408799C (en) * 1923-09-09 1925-01-30 Siemens Bauunion G M B H Komm Device to protect iron filter tubes covered with copper braid against electrolytic destruction and incrustation
US1867984A (en) * 1931-02-27 1932-07-19 Adolph F Pistor Pipe-line covering
US1871125A (en) * 1929-10-11 1932-08-09 Gulf Production Company Protective means for buried metallic surfaces

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US843357A (en) * 1906-01-24 1907-02-05 William Arky Partee Hull-cleaning and friction-reducing apparatus.
US1096177A (en) * 1912-08-27 1914-05-12 Pascal Marino Process of superficially metallizing the surface of cast-iron, wood, gypsum, paper, and other porous substances or articles.
DE408799C (en) * 1923-09-09 1925-01-30 Siemens Bauunion G M B H Komm Device to protect iron filter tubes covered with copper braid against electrolytic destruction and incrustation
US1871125A (en) * 1929-10-11 1932-08-09 Gulf Production Company Protective means for buried metallic surfaces
US1867984A (en) * 1931-02-27 1932-07-19 Adolph F Pistor Pipe-line covering

Cited By (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2744863A (en) * 1951-10-25 1956-05-08 Smith Corp A O Cathodic protection of metal in vapor space
US2847375A (en) * 1953-07-13 1958-08-12 Texas Co Apparatus for corrosion prevention
US2903405A (en) * 1956-05-24 1959-09-08 Sabins Dohrmann Inc Corrosion prevention system
US3313721A (en) * 1958-12-31 1967-04-11 Englehard Ind Inc Dish-shaped anode
US3265601A (en) * 1961-05-26 1966-08-09 Inst Francais Du Petrole Process for protecting metals against corrosion at elevated temperatures
US3254012A (en) * 1962-07-20 1966-05-31 Concrete Thermal Casings Inc Method of cathodically protecting heat-insulated pipes
US3151050A (en) * 1963-02-15 1964-09-29 David K Wilburn Laminated anti-corrosive paint system
US3303118A (en) * 1963-04-08 1967-02-07 Engelhard Ind Inc Cathodic protection and anti-marine fouling electrode system
US3260661A (en) * 1965-04-01 1966-07-12 Koppers Co Inc Sacrificial metal pipe coverings
US3484350A (en) * 1965-04-28 1969-12-16 Allegheny Ludlum Steel Method of producing trim members
US3409525A (en) * 1965-05-24 1968-11-05 Goodyear Tire & Rubber Process for reducing corrosion
US3349017A (en) * 1966-05-02 1967-10-24 Concrete Thermal Casings Inc Method and structure of cathodically protecting metallic casings of heat distribution systems
US3623968A (en) * 1968-01-02 1971-11-30 Tapecoat Co Inc The Sacrificial anode and pipe protected thereby
US3868313A (en) * 1972-02-25 1975-02-25 Philip James Gay Cathodic protection
US3990478A (en) * 1974-11-20 1976-11-09 Inland Steel Company Combined strengthening and corrosion protection of pipelines
US4091291A (en) * 1975-05-22 1978-05-23 Reynolds Metals Company System for underground distribution of electrical power and electrical cable construction for use therein
US4502929A (en) * 1981-06-12 1985-03-05 Raychem Corporation Corrosion protection method
US4990231A (en) * 1981-06-12 1991-02-05 Raychem Corporation Corrosion protection system
FR2602800A1 (en) * 1986-04-30 1988-02-19 Trest Juzhvodoprovod METHOD OF PROTECTING CORROSION OF THE INNER SURFACE OF A CONDUCT
US4957612A (en) * 1987-02-09 1990-09-18 Raychem Corporation Electrodes for use in electrochemical processes
US4812212A (en) * 1987-09-08 1989-03-14 Harco Technologies Corporation Apparatus for cathodically protecting reinforcing members and method for installing same
US5378336A (en) * 1991-06-25 1995-01-03 Ecoline Anticorrosion S.R.L. Inert anode for dissipation of continuous current
US5411646A (en) * 1993-05-03 1995-05-02 Corrpro Companies, Inc. Cathodic protection anode and systems
US6554992B1 (en) * 1995-06-07 2003-04-29 Mcwane, Inc. Aluminum alloy exterior coating for underground ductile iron pipe
US6238545B1 (en) 1999-08-02 2001-05-29 Carl I. Allebach Composite anode, electrolyte pipe section, and method of making and forming a pipeline, and applying cathodic protection to the pipeline

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