US2516058A - Apparatus for plating of metals - Google Patents
Apparatus for plating of metals Download PDFInfo
- Publication number
- US2516058A US2516058A US504418A US50441843A US2516058A US 2516058 A US2516058 A US 2516058A US 504418 A US504418 A US 504418A US 50441843 A US50441843 A US 50441843A US 2516058 A US2516058 A US 2516058A
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- US
- United States
- Prior art keywords
- tube
- plating
- carbonyl
- plated
- hydrogen
- Prior art date
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- Expired - Lifetime
Links
- 229910052751 metal Inorganic materials 0.000 title description 22
- 239000002184 metal Substances 0.000 title description 21
- 238000007747 plating Methods 0.000 title description 15
- 150000002739 metals Chemical class 0.000 title description 10
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 20
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 17
- 239000001257 hydrogen Substances 0.000 description 16
- 229910052739 hydrogen Inorganic materials 0.000 description 16
- 239000007789 gas Substances 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 5
- 229910052750 molybdenum Inorganic materials 0.000 description 5
- 239000011733 molybdenum Substances 0.000 description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 5
- 229910052721 tungsten Inorganic materials 0.000 description 5
- 239000010937 tungsten Substances 0.000 description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 4
- 239000011651 chromium Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000007789 sealing Methods 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- MPMSMUBQXQALQI-UHFFFAOYSA-N cobalt phthalocyanine Chemical compound [Co+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 MPMSMUBQXQALQI-UHFFFAOYSA-N 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 239000012809 cooling fluid Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- LVIYYTJTOKJJOC-UHFFFAOYSA-N nickel phthalocyanine Chemical compound [Ni+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 LVIYYTJTOKJJOC-UHFFFAOYSA-N 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/04—Coating on selected surface areas, e.g. using masks
- C23C16/045—Coating cavities or hollow spaces, e.g. interior of tubes; Infiltration of porous substrates
Description
JERRY 195w J. J. LANDER 25%,058
APPARATUS FOR PLATING OF METALS Filed Sept. 50, 1943 WATER INLET lNl/EN TOR J. J LANDER Patented July 18, 1950 APPARATUS FOR PLATI'NG OF METALS James J. Lander, Murray Hill, N. J., assignor to Bell Telephone Laboratories, Incorporated, New York, N. Y., a corporation of New York Application September 30, 1943, Serial No. 504,418
1 Claim. 1
This invention relates to apparatus for coating metals, such as iron, steel, nickel or other metals, including those hereinafter mentioned, with chromium, tungsten or molybdenum.
Plating of objects which have internal surfaces, under-cut surfaces, depressions or grooves is often diflicult because of the difficulty of depositing the plated metal upon the internal surfaces, the recesses, or in the bottom of grooves.
An object of the present invention is to provide apparatus for coating metal surfaces with tungsten, chromium or molybdenum more especially internal surfaces of hollow cylinders and similar objects.
Another object is to provide apparatus for supplying uniform and adherent coatings of tungsten, chromium or molybdenum or alloys of any two or all three of these metals to any desired portion of or to the whole of the interior or internal surfaces of metallic objects such as hollow cylinders.
A special feature of the invention consists in the use of a low pressure in the plating chamber.
Another special feature of the invention is the provision of means for varying the hardness of the applied metallic plating.
The invention may be practiced by causing the coating of metal to be applied by decomposition of tungsten, chromium and molybdenum carbonyls at the surface of the metal to be coated, the surface being maintained in suitable cbnditionto cause the decomposition of the carbonyl and deposition of the metal upon the surface. The plating process is accomplished in an enclosed space under a reduced pressure maintained by a vacuum pump.
The surface to be plated may be treated preliminarily to the introduction of the carbonyl gas by heating it to relatively high temperatures such as 600 C. in a vacuum which is maintained by operating a vacuum pump. This tends to clean the surface.
However, hydrogen may be admitted to the plating vessel prior to, or during the platingoperation, or both, and such uses of hydrogen may result in one or more of several kinds of beneficial effects; for best results the hydrogen should be purified and for this purpose known methods may be employed.
In the first place, the surface to be plated may be further or more effectively cleaned, with the result of a more perfectly adhering plate, by admitting hydrogen to come into contact with the surface to be plated either immediately or after the object has been subjected to vacuum 2 for a period of time. The hydrogen is admitted from a suitable inlet and removed by a vacuum pump from a suitable outlet and during the time the surface to be plated is exposed to the hydrogen the temperature of the object having the surface to be plated may be raised as high as 600 C. or upward with the result that oxides and other substances upon the surface are removed.
The admission of hydrogen during the plating operation along with the carbonyl vapor may be through either the same inlet which supplies the carbonyl vapor or through a separate inlet. In either case an effect of the hydrogen is to produce an effect analogous to that which in electrolytic plating is sometimes styled throwing power which signifies that plating in crevices, grooves or depressions is more effectively accomplished and the metal plate is ap-- plied more uniformly over the surface to be plated.
Pressures of from to millimeter of mercury may be maintained in the plating vessel during plating; but the specification of these values is illustrative rather than limiting and with diflerent metals or under different conditions with the same metal best results may be secured with some particular pressure. A suitable device to continuously indicate the pressure is not illustrated in the drawings described hereinafter but the method of application of such a device is considered obvious.
Apparatus illustrative of the apparatus used in practicing the invention and the method or mode of its employment is further described in connection with the accompa g drawing in which: Fig. 1 illustrates the inlet end of an arrangement for delivering carbonyl gas more uniformly along the bore of a hollow tube to be plated and also removing CO gas, hydrogen and impurities from along the entire length thereof; and
Fig. 2 illustrates the outlet end of the apparatus of Fig. l;
The hollow cylinder 26 may consist of iron, nickel, any type of steel or ferrous, cobaltous or nickelous alloy known to the art as well as metals or alloys of the metals tungsten, vanadium, titanium, molybdenum, tantalum, copper, or stainless steel, gun metal, cutlery steel, brass, bronze or any other metal of properties similar to these It may be plated to produce a hard surface resistant to abrasion or a surface resistant to chemicals in gaseous or liquid form.
In connection with Figs. 1 and 2 it is contemplated that the member 32 should be sealed to the end of the gun barrel or other hollow tube to be plated. Before and after sealing as. aforesaid carbonyl powder is placed in one of the U- shaped tubes, for example, the tube l5. At this time the tube l may be maintained cold by being immersed in brine, ice water, solid CO2, or in any other suitable manner. If valves l1 and 40 are closed the tube l6 need not be cooled at this time. Permanently or separably mounted and sealed in the member 32 is a glass, vitreous, or metallic tube structure which includes Or is connected to an inlet pipe 36 and other pipes and valves 31, 38. 36 and 40 in the same manner as in Fig. 3. Gaskets 34 and screws 33 provide a gas-tight seal. After the sealing operation is performed the tube i6 is connected to a vacuum pump and the valve It opened to thoroughly exhaust air from the interior of the sealed-in space enclosed by the hollow cylinder 26 and the end pieces 32.
As a preliminary operation after sealing the end pieces to the member 26, the carbonyl may be purified by placing it either in the tube l5 or ii, exhausting the vessel, warming the tube in which the carbonyl is placed, chilling the other tube, and distilling the metallic carbonyl from one tube I5 or l6 to the other, the valves 39, I1 and I6 being closed and valve 40 being open. This operation may be repeated one or more times or its equivalent may be performed in a separate vessel before placing the powdered carbonyl in the apparatus illustrated. The advantage of doing it in the same apparatus lies in the certainty with which recontamination of the mate- 'rial is prevented. For this purpose the media 24 and 25 may be alternately chilled or heated or replaced by media of suitable temperatures. We may assume that this step has been performed, if necessary, and the metallic carbonyl powder is in the tube I! for th beginning of the plating operation and that the interior of the member 26 to be plated has been thoroughly exhausted of air. After the exhaustion or during the exhaustion hydrogen may be admitted through tube 31 in a slow stream until substantially the entire gas content of the tube consists Of hydrogen and at any stage after the exhaustion, upon the admission of hydrogen or afterward, heat is applied by means of the furnace 4| or other suitable means to the cylinder 26. The plates 32, their sealing gaskets, and the entire structure 42, 43, 44, 46, 46 is kept cool by circulation of water through the water jacket 42 from the water inlet to the water outlet. The interior surface of the element 26 thus becomes heated and all oxides and other reducible foreign substances are removed from its internal surface by the combined effect of the heat and hydrogen gas. The element 26 is then adjusted in temperature, if necessary, to a suitable plating temperature and the valve 40 opened to admit vaporized metallic carbonyl. At this time the tube l5 may be heated by heating the medium 24 in which it is immersed, or otherwise, to a suitable temperature. The valve I8 is open and the operation of the vacuum pump connected to the tube I6 is continuedto maintain a suitable degree of vacuum in the enclosed space in the interior of the tube 26. Hydrogen may be admitted through the valve 39 from a suitable source. The amount of hydrogen used may vary from none to several hundred or even several thousand molecules of H2 per molecule of carbonyl; hydrogen equal to 100 molecules of H2 per molecule of carbonyl produces good results. Suitable temperatures, depending upon the nature of the plate to be deposited, in the case of the carbonyls mentioned, may be in the range of 350 C. to 600 C.
,ing operation and prevent waste thereof.
Medium 26 may be of low temperature to chill and condense metallic carbonyl during the plat- The tube structure is provided with a water jacket 42 through which water is circulated to keep it cool. The carbonyl and hydrogen gases are supplied to an annular pipe 43 and pass out through any number of tubes 44 where they are exposed to the surface of the tubular member 26 to be plated. These outlets 44 may be Of any desired size and any desired number and may be distributed uniformly or otherwise, both circumferentially and axially over the whole length of the structure. The outlet gases pass through other openings 46 to an interior tube 46 which is connected at the outlet end through a structure similar to the inlet end and to a vacuum pump. At the outlet end the member 32 may be screwed into place upon a flange 32a and further screwed down upon the gasket by screws 33, if necessary; the water inlet pipe and the tube l6 may be detachable and screwed or otherwise fastened into place for each operation. As stated above, the structure 42, 43, 44, 45, 46 may consist of glass, plastic, or vitreous material but it may equally well and preferably consist of metal. This metallic structure may be mounted to have the tube to be plated placed over it and fastened into position for the P ating operation or the metallic structure may be thrust in the tube to be plated, which in such case would be preliminarily mounted in an oven 4i (diagrammatically indicated) or otherwise prepared to be heated to the desired degree. Owing to the fact that the carbonyl gas is supplied in a distributed manner over the entire inner surface, the plating may be made as uniform as desired by providing a suitable number and distribution of openings 44 and 46. The method and equipment may be adapted to tubes of very small diameter or large diameter or small length or great length by making the apparatus in a suitable size proportionate to the dimensions of the element to be platedupon its inner surface.
What is claimed is:
Apparatus for plating the interior of a hollow tube with metal comprising an elongated structure introducible into the hollow tube and extending substantially the entire length thereof, means for circulating a cooling fluid through the structure, means for supplying gas including gas of a metallic carbonyl into the structure, said structure comprising a plurality of outlet means distributed over substantially the entire length thereof for supplying the gas supplied thereto to the interior surface of the metallic tube to be plated, and a plurality of outlet means distributed over substantially the entire length thereof and leading to an outlet passage for removing said gas from the interior surface of the tube to be plated,
a vacuum pump attached to said outlet passage, said structure when introduced into the hollow tube to be plated being sealed thereto to exclude all gases except those introduced intentionally along with the metallic carbonyl vapor.
. JAMES J. LANDER.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Number Name Date Re. 16,556 Fahrenwald Feb. 22, 1927 986,558 Farkas Mar. 4, 1911 (Other references on following page) UNITED s'm m'mms Number Name Date Thowiess Aug. 10, 1915 Liebmann Oct. 5, 1915 Fahrenwald July 13, 1920 Coles Feb. 19, 1929 Fink July 28, 1931 Noddack Nov. 3, 1931 Olin Nov. 1, 1932 Iredeil Jan. 3, 1933 Seibt July 3, 1934 Moers Jan. 8, 1935 Bailey et ai. Apr. 16, 1935 Feiler Dec. 8, 1936 Schlecht May 23, 1939 Schlecht May 23, 1939 Borofski Aug. 22, 1939 Brauer Dec. 12,1939
Widell June 29,1943
Number Name Date Drummond Oct. 19, 1943 Drummond Mar. 14, 1944 Gorton --Feb. 19,1946
FOREIGN PATENTS Country Date Great Britain June 20. 1930 Great Britain Feb. 8, 1935 Great Britain Sept. 22, 1936 Great Britain Nov. 6, 1939 QTHER REFERENCES Sachs et ai.: Practical Metallurgy," second 16 printing, 1941, published by Amer. Soc. for Metals,
Cleveland. Ohio, pages 62-66 and 524 (page 62 relied upon).
Journal of the Institute of Metals, vol. XLVII,
Paragraph bridging pages 534, 535.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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US504418A US2516058A (en) | 1943-09-30 | 1943-09-30 | Apparatus for plating of metals |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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US504418A US2516058A (en) | 1943-09-30 | 1943-09-30 | Apparatus for plating of metals |
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US2516058A true US2516058A (en) | 1950-07-18 |
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US504418A Expired - Lifetime US2516058A (en) | 1943-09-30 | 1943-09-30 | Apparatus for plating of metals |
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Cited By (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2650564A (en) * | 1949-12-02 | 1953-09-01 | Ohio Commw Eng Co | Dynamic pyrolytic plating apparatus |
US2685124A (en) * | 1951-04-30 | 1954-08-03 | Ohio Commw Eng Co | Method for hi-vac alloying and coated product |
US2690980A (en) * | 1951-03-14 | 1954-10-05 | Bell Telephone Labor Inc | Carbonyl process |
US2700365A (en) * | 1951-10-08 | 1955-01-25 | Ohio Commw Eng Co | Apparatus for plating surfaces with carbonyls and other volatile metal bearing compounds |
US2719094A (en) * | 1951-06-16 | 1955-09-27 | Nat Res Corp | Coating device and method |
US2729190A (en) * | 1951-10-08 | 1956-01-03 | Pawlyk Peter | Apparatus for plating the interior of hollow objects |
US2731361A (en) * | 1952-12-09 | 1956-01-17 | Ohio Commw Eng Co | Catalyzed deposition of metals from the gaseous state |
US2743700A (en) * | 1949-09-10 | 1956-05-01 | Ohio Commw Eng Co | Continuous metal production and continuous gas plating |
US2767464A (en) * | 1952-10-24 | 1956-10-23 | Ohio Commw Eng Co | Composite metallic bodies and method of producing the same |
US2783164A (en) * | 1953-09-17 | 1957-02-26 | Nat Res Corp | Method of coating a metal substrate with molybdenum |
US2789064A (en) * | 1953-03-02 | 1957-04-16 | Schladitz Hermann | Process and apparatus for the metallisation of continuously travelling organic and inorganic foils by thermal decomposition of metal compounds |
US2790731A (en) * | 1953-12-14 | 1957-04-30 | Ohio Commw Eng Co | Method and apparatus for the production of electrically resistant films |
US2817141A (en) * | 1953-04-14 | 1957-12-24 | Ohio Commw Eng Co | Composite metal structure |
US2859130A (en) * | 1954-06-16 | 1958-11-04 | Ohio Commw Eng Co | Method for gas plating synthetic fibers |
US2872342A (en) * | 1952-12-09 | 1959-02-03 | Ohio Commw Eng Co | Catalytic nickel plating |
US2886469A (en) * | 1954-05-31 | 1959-05-12 | Siemens Planiawerke Ag | Method of coating metallic bodies with aluminum utilizing vaporous sub-chlorides |
US2887089A (en) * | 1955-06-22 | 1959-05-19 | Ohio Commw Eng Co | Gas plating apparatus |
US2887984A (en) * | 1954-06-24 | 1959-05-26 | Ohio Commw Eng Co | Apparatus for gas plating continuous length of metal strip |
US2921868A (en) * | 1956-06-07 | 1960-01-19 | Union Carbide Corp | Aluminum gas plating of various substrates |
US2933415A (en) * | 1954-12-23 | 1960-04-19 | Ohio Commw Eng Co | Nickel coated iron particles |
US2985509A (en) * | 1958-02-24 | 1961-05-23 | Union Carbide Corp | Method of recovering metal carbonyls from gases |
US3050417A (en) * | 1954-03-18 | 1962-08-21 | Union Carbide Corp | Chromium nickel alloy gas plating |
US3126902A (en) * | 1964-03-31 | Method and apparatus for producing high vacuum | ||
US3211583A (en) * | 1961-09-19 | 1965-10-12 | Melpar Inc | Pyrolytic deposition of germanium |
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US2159604A (en) * | 1928-03-26 | 1939-05-23 | Ig Farbenindustrie Ag | Metallic article |
US1893286A (en) * | 1928-05-25 | 1933-01-03 | Westinghouse Lamp Co | Method of carbonizing metals and alloys |
US1965059A (en) * | 1930-04-03 | 1934-07-03 | Seibt Georg | Apparatus for producing high ohmic resistances or the like |
US1997761A (en) * | 1931-01-23 | 1935-04-16 | Chrysler Corp | Method of internally coating hollow articles |
US1987577A (en) * | 1931-11-25 | 1935-01-08 | Gen Electric | Apparatus for the thermic treatment of metal wires, filaments, bands, or the like |
US2063596A (en) * | 1932-02-19 | 1936-12-08 | Ig Farbenindustrie Ag | Thermal treatment of carbon compounds |
GB423823A (en) * | 1933-01-24 | 1935-02-08 | Ig Farbenindustrie Ag | Improvements in the manufacture of pulverulent metal alloys |
US2159231A (en) * | 1934-10-25 | 1939-05-23 | Ig Farbenindustrie Ag | Producing nickel alloy articles |
GB487854A (en) * | 1935-10-11 | 1938-06-24 | Carl Trenzen | Improvements in and relating to the production of metal coatings on objects |
US2170259A (en) * | 1936-01-09 | 1939-08-22 | Firm Mettmanner Britannia Ware | Process for the introduction of graphitic carbon into light metals or light metal alloys |
US2183302A (en) * | 1936-01-22 | 1939-12-12 | Fernseh Ag | Method for producing coatings of high ohmic resistance in the interior of vacuum tubes |
GB514333A (en) * | 1938-05-03 | 1939-11-06 | Paul Alexander | Improved method of depositing metallic films from metal vaporized in vacuo |
US2332309A (en) * | 1940-05-20 | 1943-10-19 | Ohio Commw Eng Co | Gaseous metal deposition |
US2344138A (en) * | 1940-05-20 | 1944-03-14 | Chemical Developments Corp | Coating method |
US2323173A (en) * | 1941-05-10 | 1943-06-29 | Rca Corp | Electrode wire |
US2395044A (en) * | 1942-04-02 | 1946-02-19 | Walter T Gorton | Gun |
Cited By (24)
Publication number | Priority date | Publication date | Assignee | Title |
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US3126902A (en) * | 1964-03-31 | Method and apparatus for producing high vacuum | ||
US2743700A (en) * | 1949-09-10 | 1956-05-01 | Ohio Commw Eng Co | Continuous metal production and continuous gas plating |
US2650564A (en) * | 1949-12-02 | 1953-09-01 | Ohio Commw Eng Co | Dynamic pyrolytic plating apparatus |
US2690980A (en) * | 1951-03-14 | 1954-10-05 | Bell Telephone Labor Inc | Carbonyl process |
US2685124A (en) * | 1951-04-30 | 1954-08-03 | Ohio Commw Eng Co | Method for hi-vac alloying and coated product |
US2719094A (en) * | 1951-06-16 | 1955-09-27 | Nat Res Corp | Coating device and method |
US2700365A (en) * | 1951-10-08 | 1955-01-25 | Ohio Commw Eng Co | Apparatus for plating surfaces with carbonyls and other volatile metal bearing compounds |
US2729190A (en) * | 1951-10-08 | 1956-01-03 | Pawlyk Peter | Apparatus for plating the interior of hollow objects |
US2767464A (en) * | 1952-10-24 | 1956-10-23 | Ohio Commw Eng Co | Composite metallic bodies and method of producing the same |
US2731361A (en) * | 1952-12-09 | 1956-01-17 | Ohio Commw Eng Co | Catalyzed deposition of metals from the gaseous state |
US2872342A (en) * | 1952-12-09 | 1959-02-03 | Ohio Commw Eng Co | Catalytic nickel plating |
US2789064A (en) * | 1953-03-02 | 1957-04-16 | Schladitz Hermann | Process and apparatus for the metallisation of continuously travelling organic and inorganic foils by thermal decomposition of metal compounds |
US2817141A (en) * | 1953-04-14 | 1957-12-24 | Ohio Commw Eng Co | Composite metal structure |
US2783164A (en) * | 1953-09-17 | 1957-02-26 | Nat Res Corp | Method of coating a metal substrate with molybdenum |
US2790731A (en) * | 1953-12-14 | 1957-04-30 | Ohio Commw Eng Co | Method and apparatus for the production of electrically resistant films |
US3050417A (en) * | 1954-03-18 | 1962-08-21 | Union Carbide Corp | Chromium nickel alloy gas plating |
US2886469A (en) * | 1954-05-31 | 1959-05-12 | Siemens Planiawerke Ag | Method of coating metallic bodies with aluminum utilizing vaporous sub-chlorides |
US2859130A (en) * | 1954-06-16 | 1958-11-04 | Ohio Commw Eng Co | Method for gas plating synthetic fibers |
US2887984A (en) * | 1954-06-24 | 1959-05-26 | Ohio Commw Eng Co | Apparatus for gas plating continuous length of metal strip |
US2933415A (en) * | 1954-12-23 | 1960-04-19 | Ohio Commw Eng Co | Nickel coated iron particles |
US2887089A (en) * | 1955-06-22 | 1959-05-19 | Ohio Commw Eng Co | Gas plating apparatus |
US2921868A (en) * | 1956-06-07 | 1960-01-19 | Union Carbide Corp | Aluminum gas plating of various substrates |
US2985509A (en) * | 1958-02-24 | 1961-05-23 | Union Carbide Corp | Method of recovering metal carbonyls from gases |
US3211583A (en) * | 1961-09-19 | 1965-10-12 | Melpar Inc | Pyrolytic deposition of germanium |
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