|Número de publicación||US2549935 A|
|Tipo de publicación||Concesión|
|Fecha de publicación||24 Abr 1951|
|Fecha de presentación||18 Jun 1946|
|Fecha de prioridad||18 Jun 1946|
|Número de publicación||US 2549935 A, US 2549935A, US-A-2549935, US2549935 A, US2549935A|
|Inventores||Sauer John C|
|Cesionario original||Du Pont|
|Exportar cita||BiBTeX, EndNote, RefMan|
|Citas de patentes (1), Citada por (57), Clasificaciones (10)|
|Enlaces externos: USPTO, Cesión de USPTO, Espacenet|
Patented Apr. 24, 1951 POLYMERS OF HEXAFLUOROPROPENE John C. Sauer, Wilmington, Del., assignor to E. I. du Pont de Nemours & Company, Wilmington, Del., a corporation of Delaware No Drawing. Application June 18, 1946, Serial No. 677,529
8 Claims. 1 This invention relates to new polymeric materials and more particularly to copolymers comprising hexafiuoropropene.
where X and Y are hydrogen or fluorine, can be used. More specifically hexafiuoropropene can be copolymerized with polymerizable unsaturated compounds selected from the group consisting of vinyl compounds, vinylidene compounds, and
compound having the formula orpo where X is halogen.
Still more specifically these objects can be realized by subjecting to polymerization conditions a mixture comprising hexafiuoropropene and tetrafiuoroethylene, ethylene or vinyl chloride and the like.
The following examples, wherein parts and per cents are by weight, unless otherwise specified, illustrate specific embodiments of this invention:
Example 1 A stainless steel, high pressure reactor is flushed with oxygen-free nitrogen and then is charged with 200 parts of deoxygenated water, 0.15 part of ammonium persulfate and 1.0 part of sodium pyrophosphate. The Water occupies about one-half of the total internal volume of the reactor. The reactor is closed, evacuated, cooled in a solid carbon dioxide-methanol mixture, and is then further charged with 20 parts of hexafiuoropropene and 60 parts of tetrafiuoroethylene. The reactor is agitated and heated to 2 55 C.-64 C. for 9.8 hours; a pressure of 250-650 atmospheres is maintained by water injection.
The reactor is then cooled to room temperature and the unreacted gases collected by water displacement. The molecular weight of the gaseous mixture is measured and from these data it is calculated that the gaseous mixture contains 58.5% of hexafiuoropropene.
The copolymer is discharged from the reactor, washed with distilled water, suspended for 3 hours in a refluxing solution containing 200 cc. of concentrated hydrochloric acid and 50 cc. of acetic acid, filtered, and again washed with water, and air-dried at a pressure of about 200 mm. at C. for 48 hours. The amount of copolymer thus obtained is 37.2 parts. Based on the weight of the copolymer and the composition of the unreacted monomer mixture, a materials balance calculation indicates that the copolymer contains of tetrafluoroethylene and 20% of hexafluoropropene.
The copolymer is pressed into clear, tough films at 350 C. in a laboratory Carver press. These films have a tensile strength of 2000 p. s. i. at 300% elongation, and soften at about 310 C. The films are totally resistant to the action of concentrated sulfuric acid at 100 C. or to a sodium hydroxide-potassium hydroxide eutectic at 280 C. The films have a dielectric constant of 2.17 and a power factor of 0.00014 at 1000 cycles. Filaments are formed by extruding the polymer through a die at 370 C. under a load of 200 p. s. 1.
Example 2 A high pressure reactor is charged as described in Example 1 except that 15 parts of hexafiuoropropene and parts of tetrafiuoroethylene are used. The reactor is agitated and heated at a temperature of 60 C.-6 l C. for 9.2 hours. The pressure is maintained at 460-500 atmospheres by water injection. The reactor is then cooled to room temperature. Based on a materials balance determination, the copolymer contains 86.6% of tetrafiuoroethylene and 13.4% of hexafiuoropropene. The amount of copolymer obtained is 18 parts.
Clear tough films, which can be pressed at 340 C.-350 C. in a laboratory Carver press, have a tensile strength of 1750 p. s. i. at 230% elongation and soften in the range of 325 C.-330 C. These films are likewise completely resistant to the action of sulfuric acid at C. or to a sodium hydroxide-potassium hydroxide eutectic at 280 C. The power factor of the pressed films is 0.00015 at 1000 cycles and the dielectric constant is 2.18. The copolymer can be extruded into filaments by forcing it through a die at 400 C. under a load of 200 p. s. i.
Example 3 A high pressure reactor is charged as described in Example 1 with 50 parts of deoxygenated water, 0.2 part of ammonium persulfate, 7.5 parts of hexafluoropropene and 20 parts of tetrafiuoroethylene. The reactor is agitated and heated at a temperature of 57 C.-80 C. for 14.5 hours. A pressure of 50-100 atmospheres is maintained in the reactor by Water injection. After cooling the reactor to room temperature, the copolymer is discharged, Washed with distilled water and airdried at 150 C. for 2 hours. The amount of copolymer thus obtained is 24 parts.
The copolymer is pressed into clear, tough films at 350 C. in a laboratory Carver press. These films have a tensile strength of 1750 p. s. i. at 84% elongation and a zero tenacity temperature of 320 C.
Example 4 A stainless steel high pressure reactor is flushed with oxygen-free nitrogen and is then charged with 200 parts of oxygen-free water and 0.2 part of lauroyl peroxide. The Water occupies about one-half of the total internal volume of the reactor. The reactor is closed, evacuated, cooled in a solid carbon dioxide-methanol mixture, and is then further charged with 15 parts of heXafiuropropene and 70 parts of ethylene. The reactor is agitated and heated to 70 C. and the pressure in the reactor is maintained at 575-600 atmospheres by the injection of oxygen-free water. After 9.5 hours, the reactor is cooled to room ten1- perature, the unreacted portion of the gaseous monomers is bled ofl, and the contents of the reactor are discharged. After filtering, the lumpy copolymer is washed with distilled water and the copolymer subsequently dried in an oven at 100 C. for '24 hours. The amount of copolymer thus obtained is 7 parts. This copolymer contains 285% fluorine which corresponds to 37.5% of hexafluoropropene and 62.5% of ethylene. The copolymer is soluble in refluxing xylene, from Whicha clear film is prepared by casting the solution on a glass plate and allowing the solvent to evaporate.
Example A stainless steel high pressure reactor is charged, as described in Example 4, with the following:
200 parts of deoxygenated water 0.15 part of ammonium persulfate 1.0 part of sodium pyrophosphate parts of hexafiuoropropene 75 parts of vinyl chloride The reactor is agitated, heated to 60 C. and the pressure in the reactor is maintained at 850-950 atmospheres by the injection of oxygen-free water.
After 9.5 hours the reactor is cooled to room temperature, the unreacted portion of the monomers is bled off and the contents of the reactor are discharged. After drying, 29 parts of a 'hexafluoropropene/vinyl chloride copolymer are "obtained. This copolymer contains 1.2% of fluobetween steel plates covered with aluminum foil are capable of being permanently elongated and 4 have tensile strengths of 6850 p. s. i. at 12% elongation.
It Will be understood that the above examples are merely illustrative and that the invention broadly comprises the process (and products obtained thereby) of preparing new copolymerization products comprising subjecting to polymerization conditions a mixture including'hexafluoropropene and another ethylenically unsaturated polymerizable compound.
The hexafluoropropene is generally present in the polymerization mixture in an amount varying from 5 to the prefered monomer charge contains 535% hexafiuoropropene. In order that the properties of the hexafluoropropene copolymer differ appreciably from the the product obtained by the polymerization of the comonomer alone, it is essential that the copolymer contain at least 1% and preferably at least 5% of hexafiuoropropene. The most attractive copolym-ers are those containing from 5 to 50 of hexafiuoropropene.
The polymerizable unsaturated organic compounds useful in forming the present copolymers with hexafluoropropene are characterized by their ability to undergo polymerization with hexafluoropropene to form macromolecular polymers. Examples of such compounds are mono-ethylenic hydrocarbons e. g. ethylene, propylene, isobutylene and styrene; halogenated compounds e. g. 1,1-difluoro-2-chloroethylene, trifluoroethylene, chlorotrifluoroethylene and particularly the vinyl halides e. g. vinyl fluoride, vinyl chloride and vinyl bromide; vinyl carboxylates e. g. vinyl formats, vinyl acetate, vinyl propionate, vinyl benzoate; alpha-methylene .monocarboxylic acids and their esters, nitriles, amides, anhydrides, and acid halides e. g. methyl inethacrylate, methacrylic acid, methyl alpha-chloroacrylate, acrylonitrile, methacrylic amides, methacrylic acid anhydride and methacrylic acid chloride; vinyl ethers e. g. vinyl methyl ether and vinyl butyl ether; vinyl ketones e. g. vinyl methyl ketone and vinyl phenyl ketone; N-vinyl compounds e. g. N-vinylsuccinimide, N- vinylphthalimide and N-vinylcarbazole; compounds having more than one ethylenic double bond e. g. butadiene, isoprene, 2-fiuoro-'1,3- butadiene, 2chlor0 "l,'3'butadiene, "2-cyano-'1,'3- butadiene; vinylidene compounds e. g. vinylidene chloride; and compounds containing acetylenic unsaturation in addition to the ethylenic double bond e. g. monovinylacetylene, divinylacetylene and vinyl-(ethinyDcarbinols. Of the class of .polymerizable unsaturated compounds disclosed --above, those having the group wherein X and Y are hydrogen or fluorine, are preferred because they copolymerize most readily with. hexafiuoropropene. Particularly desirable hexafiuoropropene copolymers are obtained when the comonomer is 'tetrafiuoroethylene, vinyl chloride, or ethylene. Hexafluoropro'pene can be efle'ctively copolymerized with one or more of the above polymerizable compounds to obtain two, three or multicompon'ent copolymers.
As will be appreciated, it is usually desirable to carry out the reactions of this invention in the presence of a polymerization initiator. Compounds most suitable for this are 'those"containing the'p'ero'xy linkage O-O and certain aliphatic azo compounds. Examples of these compounds are acyl peroxides e. g. dibenzoyl peroxide, benzoylacetyl peroxide, dilauroyl peroxide, diacetyl peroxide; dialkyl peroxides e. g. diethyl peroxide, ditertiarybutyl peroxide or dipropyl peroxide; hydrogen peroxide; salts of true non-metallic peracids e. g. ammonium persulfate, potassium persulfate, and sodium persulfate and oxygen; and certain aliphatic' azo compounds, preferably those having an alpha-tertiary carbon atom, e. g. alpha, alpha-azodiisobutyronitrile and the like. The preferred amount of initiator used is in excess of 0.001% but not more than about 5% based on the total weight of monomers. A quantity of initiator above 0.001% through 1% is specif cally preferred.
The conditions described herein, for example pressure, under which this invention is carried out, in general, will depend somewhat on the comonomer employed. In some cases pressures as low as 3 atmospheres can be employed, while in other cases pressures as high as 5000 atmospheres are more desirable to achieve the high molecular Weight copolymers. Thus with normally liquid comonomers, e. g. vinyl carboxylates or esters of alpha-beta-unsaturated monocarboxylic acids, desirable comonomer concentrations are obtained at relatively low pressures and accordingly the polymerization may be carried out at pressures of 3-100 atmospheres. With normally gaseous comonomers, e. g. olefinic hydrocarbons and halogenated ethylenes (e. g. vinyl fluoride or trifluoroethylene), pressures of 100-1000 atmospheres are preferable. fiuoroethylene copolymers have been prepared at pressures as low as 100 atmospheres, although the preferred range is 500-1000 atmospheres. The ethylene copolymers are best prepared in a pressure range of 300-1000 atmospheres.
Although the above preferred pressures fall within the range of 3-1000 atmospheres, and generall this invention will be practiced within this pressure range, those skilled in the art will appreciate that applicable pressures are not so limited. The lower pressure employed will depend somewhat on such factors as the particular characteristics desired in the copolymer. There is no upper pressure limit whatsoever which may be employed above the preferred pressure insofar as substantial differences in results are concerned. Of course, available apparatus and, more usually, convenience and economy will be influencing factors.
The reaction may be carried out in a closed system if desired. However, it is advantageous to inject (either batch-wise or continuously) a mixture of hexafluoropropene and comonomer in desired proportions as the reaction progresses, or to maintain a desired pressure in the reactor by injecting deoxygenated water. The course of reaction may be followed by the drop in pressure in the reactor. Cessation of the reaction is indicated by cessation of the pressure drop.
As with pressure, the temperature at which this invention may be carried out will depend to some extent on the comonomer employed as well as on the initiator used for inducing the copolymerization reaction. In some instances temperatures of about C. are suitable, while in other instances temperatures of about 300 C. are more desirable. With acyl peroxides as initiators the preferred temperatures are 50 C.-1'75 C.; with persulfate initiators, 30 C.-100 C.; with azo nitriles as initiators, 10 C.-200 C.;
Tertra- 6 and with oxygen as an initiator, C.-200 C.- In general, the preferred temperatures fall with in the range of 35 C.- C.
While the preferred conditions as to temperature and pressure for practicing this invention consist in maintaining a pressure substantially above atmospheric, and usually within the range of 3-100() atmospheres, and a temperature of 35 C.-160 0., those skilled in the art will appreciate that, as with pressure, temperatures outside this range and even temperatures outside the range of 10 C.-300 C. set out hereinbefore are applicable. However, temperatures outside this broader range are less practical because of relatively low rate of reaction when substantially lower temperatures are employed and because of the tendency of less desirable qualities to appear in the copolymers when excessively high temperatures are used.
While it is preferable to carry out the reaction in an aqueous medium, organic solvents, instead of or in addition to water, may be employed. Examples of organic solvents include hexane, octane, isooctane, methylcyclohexane, benzene, acetone, methanol, tertiary butanol, and tertiary amyl alcohol.
Finely divided solids which serve as fillers can be included in the polymerization mixture and the polymerization can be carried out in their presence. Examples of such fillers include pigments 6. g. titanium dioxide; metals e. g. copper, aluminum, and iron powder; and other finely divided materials e. g. mica, glass and asbestos. These, and similar materials, can also be added to the preformed copolymers.
The hexafluoropropene employed in the practice of this invention should be reasonably pure and should be substantially free of acidic substances such as hydrogen chloride or hydrogen fluoride, and should also be reasonably free of oxygen. Although oxygen is an initiator in the small amounts indicated previously, substantially larger proportions (i. e. above approximately 5 of oxygen tend to have an undesirable effect upon the reaction.
- The equipment employed in carrying out this invention should be of sufficient strength to withstand the pressure and temperatures employed. That portion-of the equipment which comes in actual contact with polymerizing systems should be fabricated of or lined with a material which will not rapidly catalyze the decomposition of the initiator, or which will not be rapidly corroded or otherwise affected by any of the components in the polymerizing system. Suitable materials include silver, enamel, glass, stainless steel, monel metal, and nickel. It is preferable that the reacting system be equipped with some means of providing agitation.
The products of this invention are adapted to a variety of uses. They can be molded into films, foils, tapes, and massive articles. Fibers and films of the copolymers of this invention can be used as insulating material by wrapping the article to be insulated or by extruding the hot copolymers around the object to be insulated. Solutions of the soluble copolymers can be used for coating wires, fiberglass, ceramics and the like. For some uses the copolymers can be combined with plasticizers, stabilizers, fillers, pigments, natural resins or other synthetic resins. Hexafiuoropropene/tetrafiuoroethylene copolymers are particularly outstanding in that they can be readily molded above the softening temperature and therefore are adapted to many ace-9,935
7 uses to-which the ftetrafluoroethylene :polymer;itself is 1 unsuited.
As many apparently widely different embodiments of this invention maybe made without departing fromthe spirit and scope thereof, it is tobe understood that the invention is not limited to the specific embodiments thereof except as defined in the appended claims.
1. The polymerization product of a mixture comprising .hexafiuoropropene and another ethylenically unsaturated polymerizable compound; the hexafluoropropene being present in the said mixture in an amount of approximately 25% by weight of the combined weight of the polymerizabl-ecompounds contained in the said mixture.
2. A new rcopolymerization product resulting from subjecting toapressure of at least 3 atmospheres and a temperature of 10 C.-,3fl- C. a mixture comprising hexafiuoropropene and a polymerizable fluoroethylene compound, in the presence rofia polymerization initiator; the hexafiuoropropene being present in the said mixture in an amount of approximately 25% by weight of the combined weight of the hexafiuoropropene and the said fluoroethylene compound.
3. The polymerization product of a mixture comprising hexafluoropropene-and a polymerizable halogen substituted ethylene compound; the hexafluoropropene being present in the said mixture in an amount of approximately 25% weight of the combined weight of the hexafluoropropene and the said halogen substituted ethylene compound.
4. A new copolymeriza-tion product resulting from subjecting to a pressure of at least 3 atmospheres and ,a temperature of C.-300 C. a mixture comprising hexafluoropropene and tetrafluoroethylene, in the, presence of a polymerization initiator; the hexafluoropropene being present .inthe said mixture in an amount of approximately,25% by weight of the combined weight of the hexafiuoropropene and the tetrafluoroethylene.
5. A new copolymerization product resulting from subjecting to a pressure of at least 3 atmospheres-anda temperature of 10 C.-300 C. a mix- 5 Number 8 ture:compnsing:hexafluoroprcpeneandethylene, in the presence of a polymerization initiator; the hexafiuoropropene-being present in the said mixture in .anvamount of approximately :by weightof'the combined weightof the hexafiuoropropene and the ethylene.
6. :A new copolymerization product resulting from subjectingito a pressure of at least 3 atmospheres and a temperatureof 10 C.-300 C. acmixture comprising hexafiuoropropene "and vinyl chloride, in the presence of 4a polymerization initiator; the hexafluoropropene being present in the saidmixture inan amount of approximately 25% by weight of the combined weight of the hexafluoropropene and. the vinyl chloride.
7. A new polymerization product resulting from subjecting to a pressure of at least ,3 atmos- -pheresand a temperature-M10QCeBOO" CY. amixture comprising hexazfluoropropene and another ethylenically unsaturated polymerizable compound,in the presence of a polymerization initiator; the hexafluoropropenebeing present in the said mixture in an amount of approximately 25% by weight of the combined weight of the :poly merizable compounds contained in the polymerization mixture.
8. A new copolymerization product resulting from subjecting to a pressureof at least 3 atmospheres and a temperature of 10'C.-.300 C.,a mixture comprising hexafluoropropene and a polymerizable halogen substituted ethylene compound, in the presence of a polymerization initiator; the hexafluoropropene vbeing present in the said mixturein an amount of approximately 25% by weight of the combined weight of the hexafluoropropene'and the said halogen substituted ethylene compound.
JOHN C. SAUER.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Name Date 2,468,664 Hanford et a1 Apr. 26, 1949
|Patente citada||Fecha de presentación||Fecha de publicación||Solicitante||Título|
|US2468664 *||28 Ago 1945||26 Abr 1949||Du Pont||Tetrafluoroethylene copolymers|
|Patente citante||Fecha de presentación||Fecha de publicación||Solicitante||Título|
|US2598283 *||23 Oct 1947||27 May 1952||Atomic Energy Commission||Copolymers of perfluoropropene and tetrafluoroethylene and method of making same|
|US2738343 *||28 Feb 1951||13 Mar 1956||Kellogg M W Co||Copolymer of trifluorochloroethylene and vinylidene fluoride|
|US2919263 *||9 Jun 1955||29 Dic 1959||Hoechst Ag||Process for the preparation of high molecular weight fluorine compounds|
|US2938889 *||12 Jun 1957||31 May 1960||Du Pont||Polymerization of tetrafluoroethylene with selected metal fluorides|
|US2946763 *||29 Mar 1957||26 Jul 1960||Du Pont||Novel perfluorocarbon polymers|
|US2951065 *||28 Oct 1955||30 Ago 1960||Minnesota Mining & Mfg||2-trifluoromethyl-butadiene copolymers and preparation thereof|
|US2951783 *||25 Oct 1956||6 Sep 1960||Minnesota Mining & Mfg||Polymer of trifluorochloroethylene and preparation thereof|
|US2955099 *||29 Mar 1957||4 Oct 1960||Du Pont||Viscosity stabilized melt extrudable perfluorocarbon polymers|
|US2983624 *||16 Jul 1956||9 May 1961||Du Pont||Glass fabric gasket and diaphragm material coated with a cured elastomeric copolymerof vinylidene fluoride and hexafluoropropene and method of making same|
|US2989433 *||18 Jun 1957||20 Jun 1961||Du Pont||Process of preparing laminated structures|
|US2998332 *||23 Jun 1959||29 Ago 1961||Du Pont||Method for marking a perfluorocarbon resin surface and composition therefor|
|US2999854 *||31 Jul 1958||12 Sep 1961||Minnesota Mining & Mfg||Fluorinated elastomers and cross linking thereof|
|US3011916 *||21 Nov 1958||5 Dic 1961||Du Pont||Method of marking perfluorocarbon resin surfaces|
|US3018188 *||10 Abr 1958||23 Ene 1962||Du Pont||Process for printing on fluorocarbon resin surfaces|
|US3025183 *||22 Jun 1956||13 Mar 1962||Du Pont||Cured elastomer and process of making same|
|US3025185 *||21 Ago 1957||13 Mar 1962||Du Pont||Heat stable coated fabric comprising wholly aromatic polyamide fabric coated with copolymer of vinylidene fluoride and hexafluoropropene|
|US3051677 *||29 Abr 1957||28 Ago 1962||Du Pont||Copolymer elastomer of vinylidenefluoride and hexafluoropropene|
|US3051683 *||10 Nov 1959||28 Ago 1962||Du Pont||Polytetrafluoroethylene-hexafluoro-propylene-tetrafluoroethylene copolymer colloidalblend and article thereof|
|US3053818 *||31 Jul 1956||11 Sep 1962||Minnesota Mining & Mfg||Trifluorochloroethylene interpolymers|
|US3062793 *||29 Dic 1958||6 Nov 1962||Du Pont||Amorphous copolymers of hexafluoropropylene and tetrafluoroethylene and their preparation|
|US3108086 *||28 Jun 1960||22 Oct 1963||Connecticut Hard Rubber Co||Fuel-resistant pressure-sensitive composition|
|US3142665 *||26 Jul 1960||28 Jul 1964||Du Pont||Novel tetrafluoroethylene resins and their preparation|
|US3189802 *||29 Nov 1960||15 Jun 1965||Zisman William A||Vibrating capacitor with a coated reference electrode|
|US3194428 *||29 Ene 1962||13 Jul 1965||Neville Chemical Co||Coated black plate containers|
|US3240757 *||26 Abr 1961||15 Mar 1966||Dow Chemical Co||Copolymers of 3, 3, 3-trifluoro-2-trifluoromethyl propene and vinyl monomers|
|US3404127 *||17 Sep 1964||1 Oct 1968||Gaf Corp||Simultaneous polymerization and alkylation of acrylate esters|
|US3940359 *||8 May 1974||24 Feb 1976||E. I. Du Pont De Nemours And Company||Soil-repellent coating compositions|
|US3966660 *||30 Oct 1974||29 Jun 1976||Teijin Limited||Method for preparing vinyl fluoride-hexafluoro-propylene resin and method for producing a coating therefrom|
|US3982983 *||22 Abr 1975||28 Sep 1976||Caterpillar Tractor Co.||Controlled bonding of fluoroelastomers to metal substrates|
|US4002810 *||2 Ene 1975||11 Ene 1977||Pennwalt Corporation||Process for insertion of hexafluoropropene at the aliphatic carbon-hydrogen bond of a polyolefin|
|US4039595 *||16 Jun 1975||2 Ago 1977||Pennwalt Corporation||Copolymers of ethylene and hexafluoropropene|
|US4105716 *||11 Feb 1977||8 Ago 1978||Daikin Kogyo Co., Ltd.||Process for producing tetrafluoroethylene/hexafluoropropylene copolymer blends|
|US4183837 *||12 May 1975||15 Ene 1980||Teijin Limited||Liquid coating composition containing vinyl fluoride-hexafluoropropylene resin|
|US4256856 *||15 Ago 1977||17 Mar 1981||Japan Atomic Energy Research Institute||Components of uranium enrichment plant|
|US4362162 *||23 Mar 1981||7 Dic 1982||Daikin Kogyo Co., Ltd.||Surgical sutures|
|US4552925 *||7 Mar 1983||12 Nov 1985||Daikin Kogyo Co., Ltd.||Tetrafluoroethylene/hexafluoropropylene copolymer having improved extrudability|
|US5266639 *||28 Ago 1992||30 Nov 1993||E. I. Du Pont De Nemours And Company||Low-melting tetrafluorethylene copolymer and its uses|
|US5374683 *||23 Nov 1993||20 Dic 1994||E. I. Du Pont De Nemours And Company||Low-melting tetrafluoroethylene copolymer and its uses|
|US5397829 *||23 Nov 1993||14 Mar 1995||E. I. Du Pont De Nemours And Company||Low-melting tetrafluoroethylene copolymer and its uses|
|US5547761 *||1 Jun 1995||20 Ago 1996||E. I. Du Pont De Nemours And Company||Low melting tetrafluoroethylene copolymer and its uses|
|US6037399 *||28 Jun 1996||14 Mar 2000||W. L. Gore & Associates, Inc.||Microemulsion polymerization systems for the production of small melt-processible fluoropolymer particles|
|US7156755||26 Ene 2005||2 Ene 2007||Callaway Golf Company||Golf ball with thermoplastic material|
|US7175543||17 Feb 2006||13 Feb 2007||Callaway Golf Company||Golf ball and thermoplastic material|
|US7312267||23 Feb 2005||25 Dic 2007||Callaway Golf Company||Golf ball and thermoplastic material|
|US7361101||20 Dic 2006||22 Abr 2008||Callaway Golf Company||Golf ball and thermoplastic material|
|US7438650||15 Oct 2007||21 Oct 2008||Callaway Golf Company||Golf ball and thermoplastic material|
|US7612134||17 Feb 2006||3 Nov 2009||Callaway Golf Company||Golf ball and thermoplastic material|
|US7612135||30 Oct 2007||3 Nov 2009||Callaway Golf Company||Golf ball and thermoplastic material|
|US20060166759 *||26 Ene 2005||27 Jul 2006||Callaway Golf Company||Golf Ball with Thermoplastic Material|
|US20060189733 *||23 Feb 2005||24 Ago 2006||Kennedy Thomas J Iii||Golf ball and thermoplastic material|
|US20070087864 *||20 Dic 2006||19 Abr 2007||Kennedy Iii Thomas J||Golf Ball and Thermoplastic Material|
|US20080032821 *||15 Oct 2007||7 Feb 2008||Kennedy Thomas J Iii||Golf Ball And Thermoplastic Material|
|US20100048786 *||25 Feb 2010||Callaway Golf Company||Golf ball and thermoplastic material|
|USRE32199 *||27 Feb 1985||8 Jul 1986||E. I. Du Pont De Nemours And Company||Tough, stable tetrafluoroethylene-fluoroalkyl perfluorovinyl ether copolymers|
|DE1465571B1 *||4 Mar 1963||20 Ago 1970||Thomas & Betts Corp||Verfahren zur Herstellung gedruckter Schaltungen|
|DE2019150A1 *||21 Abr 1970||12 Nov 1970||Du Pont||Mischpolymerisate aus Tetrafluoraethylen und Fluoralkyl-perfluorvinylaethern sowie Verfahren zur Herstellung derselben|
|DE2706783A1 *||17 Feb 1977||18 Ago 1977||Daikin Ind Ltd||Verfahren zur herstellung von tetrafluoraethylen/hexafluorpropylen-copolymeren|
|Clasificación de EE.UU.||526/254, 526/235, 526/249, 528/401, 526/229, 526/229.5|
|Clasificación internacional||C08F214/00, C08F214/28|