US2621392A - Novel yarn and method of making same - Google Patents

Novel yarn and method of making same Download PDF

Info

Publication number
US2621392A
US2621392A US25313A US2531348A US2621392A US 2621392 A US2621392 A US 2621392A US 25313 A US25313 A US 25313A US 2531348 A US2531348 A US 2531348A US 2621392 A US2621392 A US 2621392A
Authority
US
United States
Prior art keywords
cellulose
yarn
reconstituted
yarns
twist
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US25313A
Inventor
Orlando A Battista
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Akzo Nobel UK PLC
Original Assignee
American Viscose Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by American Viscose Corp filed Critical American Viscose Corp
Priority to US25313A priority Critical patent/US2621392A/en
Application granted granted Critical
Publication of US2621392A publication Critical patent/US2621392A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic System
    • D06M11/385—Saponification of cellulose-acetate

Definitions

  • This invention relates to novel composite yarns and to methods of making them.
  • the invention provides yarns which can be used in the construction of special effect fabrics of the ratin or boucl type by ordinary weaving procedures.
  • the yarns may have only the normal or conventional twist of from one to five turns of twist per inch, or they may have a higher twist if desired.
  • An object of this invention is to provide composite yarns which may be woven to produce boucl or similar fabrics by ordinary weaving methods and without requiring the application of difierent degrees of tension to the yarns as they are fed to the loom.
  • Another object of the invention is to provide yarns for making fabrics having surface characteristics which closely approximate or duplicate'those or" a boucl fabric.
  • a specific object of the invention is to provide novel composite yarns comprising at least two singles yarns, at least one of which comprises regenerated cellulose fibers from viscose, and at least another of which is a singles yarn consisting of fibers of cellulose reconstituted from an organic acid ester of cellulose in situ in the yarn.
  • a composite yarn is produced by plying, doubling or otherwise associating at least one singles yarn formed of fibers of a fiber-forming organic acid ester of cellulose with at least one singles yarn formed of fibers of a fiber-forming material which is not affected, as such,by aqueous solutions of ammonia or lower alkylene amines.
  • the yarns which are associated to form the composite yarn have a twist of from one to five turns of twist per inch.
  • the composite yarn is then immersed in an aqueous solution of ammonia or of an alkylene amine, such as methylenediamine or ethylene-cliamine, to effect com plete deesterificaticn of the cellulose organic acid ester component throughout its cross-section, the conditions of the deesterification being such that the final composite yarn does not have a measurable cellulose ester content.
  • the composite yarn is then dried in relaxed condition.
  • the component comprising the cellulose organic acid ester may comprise one or more singles yarns formed from fibers or filaments of cellulose acetate, propionate, butyrate, etc... or it may comprise one or more singles yarns formed from fibers or filaments of mixed cellulose esters, such as cellulose acetate-butyrate.
  • the expression singles yarn designates a continuous fibrous strand consisting of a multiplicity of fibers and/or filaments associated tomeasurements on the cellulose. Deesterification of the cellulose ester component without'degradation of the cellulose is essential to the produc tion of useful, stable composite yarns having the desired characteristics.
  • the reconstituted cellulose component expends its shrinkage capacity, and shrinks linearly causing the remaining component of the yarn which is not afiected as such by the deesterification treatment to wind itself about the reconstituted cellulose component.
  • the deesterification of the cellulose ester component of the composite yarn must be homogeneous andcomplete and, as has been stated, the composite yarn, after the deesterification treatment, must not have a measurable cellulose ester content.
  • ammonia and the lower alkylene amines having up to 3 carbons are specific agents for deesterifying the cellulose ester component homogeneously throughout its cross-section without appreciable. or noticeable degradation of the cellulose.
  • the conditions of the treatment that is the concentration of the nitrogeneous deesterifying agent, the temperature at which the composite yarn is treated with the solution, and the duration of the treatment, are interrelated. If lower concentrations.” of ammonia or alkylene amine are used, higher. temperatures and longer immersion times are necessary, and vice versa.
  • the deesterifying medium is maintained in the liquid phase throughout the entire treatment.
  • aqueous solutions of ammonia or the alkylene amines of from 6 to 28% concentration at room temperatures, that is at temperatures in the range of to 30 0. Under those conditions, the deesterification is complete in from 6 to 15 hours.
  • the treated composite yarn is dried in the relaxed state at from 90 to 95 C.
  • the singles yarn or yarns plied or otherwise associated with the singles yarn or yarns of the fiber-forming organic acid ester of cellulose may be formed from fibers or filaments of any fiberforming material which is not afiected, as such, to any appreciable extent when the composite yarn is dried in the relaxed condition after immersion in the solution of ammonia or alkylene amine used to convert the cellulose ester component to reconstituted cellulose.
  • the singles yarn associated with the cellulose ester yarn may comprise silk, cotton, flax, regenerated cellulose from viscose or cuprammonium, etc.
  • the composite yarn comprising a component of cellulose reconstituted from the ester may be woven to produce boucle' or ratin fabrics having efiects corresponding to those of fabrics made from the conventional houcl yarns comprising two ground threads and an effect thread. How ever, the usual special weaving procedures normally resorted to in the manufacture of boucl fabrics are not necessary in. the present case.
  • the boucl efiects are due solely to the presence of the novel composite yarns of the invention.
  • the fabrics may be made wholly of the new composite yarns comprising the component of cellulose reconstituted from an ester in situ in the yarn, or the composite yarns may alternate with plain yarns in the warp and filling, or in the filling only.
  • the new composite yarns may also be knitted to produce fabrics having very interesting surface characteristics.
  • Example I A plied yarn was formed from a 150 denier/ 90 filament dull viscose yarn having a twist of 3 8 turns of twist per inch, and a 150 denier/41 filament dull cellulose acetate yarn (commercial secondary acetate) having a twist of 3 8 turns of twist per inch.
  • the plied yarn had a Z twist of 8 turns per inch.
  • the plied yarn was immersed in skein form in a bath consisting of a 15% aqueous ammonia solution for 15 hours at room temperature. The yarn was then washed free of ammonia, given a soft soap finish, and dried in the relaxed condition.
  • the composite yarn was woven as a filling for a fabric, the warp yarns of which consisted of one end of 150 denier/90 filament dull viscose rayon yarn having 3 8 turns of twist per inch, alternating regularly with one end of 150 denier/41 filament dull cellulose acetate yarn having 3 8 turns of twist per inch.
  • Example II A composite yarn consisting of one end of 200 denier/52 filament dull acetate yarn having 3 turns of twist/inch and one end of 150 denier/ filament dull viscose yarn having 3 turns of twist/inch, plied to give a composite yarn having 14 8 turns per inch, and treated as in Example I to convert the cellulose acetate to reconstituted cellulose was used as filling for a woven fabric, the warp of which comprised one end of 75 denier/30 filament bright viscose rayon yarn having a twist of 3 8 turns of twist/inch alternating regularly with one end having three Z turns of twist/inch. A novel fabric having thick and thin surface characteristics was produced.
  • Example I II A composite yarn was obtained in the following manner: A denier/36 filament dull acetate yarn having 1 /2 8 turns of twist/inch was plied with a 75 denier/30 filament bright viscose rayon yarn having 3 S turns of twist/inch, to give a plied yarn having 14. 8 turns of twist/inch. Two of these plied yarns were plied to give a composite yarn having 8 2 turns of twist/inch. The composite yarn was treated as in Example I to convert the cellulose acetate yarn to reconstituted cellulose. The composite yarn was then used as the filling for a fabric having a warp as in Example II. A novel fabric having thick and thin surface characteristics was obtained.
  • a method of producing yarns each comprising at least one shrunk end consisting of cellulose reconstituted from an organic acid ester of cellulose and at least one unshrunl: end which is wound about the reconstituted cellulose end as a result of shrinkage of the last-mentioned end in the yarn, which yarns impart a boucl effect to fabrics woven therefrom solely by the condition of the ends resulting from shrinkage of the reconstituted cellulose end in the yarn, which comprises plying at least one end of an organic acid ester of cellulose with at least one end of a material which is not affected as such when the yarn is dried in relaxed condition after immersion in aqueous solutions of ammonia and aikylene diamines, immersing th yarn, pri r to weaving, in a 6 to 28 aqueous solution of a substance selected from the group consisting of ammonia and alkylene diamines having from 1 to 3 carbons, for from 6 to 15 hours, at 25 to 30 (3., to completely and homogeneously convert
  • the plied yarn comprises initially at least one end of cellulose acetate having a twist of from 1 to 5 turns per inch.
  • the plied yarn comprises initially at least one end of cellulose acetate and at least one end of cellulose rcgenerated from viscose.
  • the plied yarn comprises initially at least one end of cellulose acetate having a twist of 3 turns per inch, and at least one end of cellulose regenerated from ORLANDO A. BATTISTA.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Woven Fabrics (AREA)

Description

Patented Dec. 16, 1952 NB-VEL YARN AND METHOD OF R AKING SAIVIE Urlando A. Battista, Drexel Hill, Pa, assignor to American Viscose Corporation, Wilmington, Del, a. corporation of Delaware No Drawing. Application May 5, 1948, Serial No. 25,313
8 Claims. 1
This invention relates to novel composite yarns and to methods of making them. The invention provides yarns which can be used in the construction of special effect fabrics of the ratin or boucl type by ordinary weaving procedures. The yarns may have only the normal or conventional twist of from one to five turns of twist per inch, or they may have a higher twist if desired.
An object of this invention is to provide composite yarns which may be woven to produce boucl or similar fabrics by ordinary weaving methods and without requiring the application of difierent degrees of tension to the yarns as they are fed to the loom. Another object of the invention is to provide yarns for making fabrics having surface characteristics which closely approximate or duplicate'those or" a boucl fabric. A specific object of the invention is to provide novel composite yarns comprising at least two singles yarns, at least one of which comprises regenerated cellulose fibers from viscose, and at least another of which is a singles yarn consisting of fibers of cellulose reconstituted from an organic acid ester of cellulose in situ in the yarn.
The objects of the invention are accomplished in the following manner:
A composite yarn is produced by plying, doubling or otherwise associating at least one singles yarn formed of fibers of a fiber-forming organic acid ester of cellulose with at least one singles yarn formed of fibers of a fiber-forming material which is not affected, as such,by aqueous solutions of ammonia or lower alkylene amines. Preferably the yarns which are associated to form the composite yarn have a twist of from one to five turns of twist per inch. The composite yarn is then immersed in an aqueous solution of ammonia or of an alkylene amine, such as methylenediamine or ethylene-cliamine, to effect com plete deesterificaticn of the cellulose organic acid ester component throughout its cross-section, the conditions of the deesterification being such that the final composite yarn does not have a measurable cellulose ester content. The composite yarn is then dried in relaxed condition.
The component comprising the cellulose organic acid ester may comprise one or more singles yarns formed from fibers or filaments of cellulose acetate, propionate, butyrate, etc... or it may comprise one or more singles yarns formed from fibers or filaments of mixed cellulose esters, such as cellulose acetate-butyrate.
The expression singles yarn designates a continuous fibrous strand consisting of a multiplicity of fibers and/or filaments associated tomeasurements on the cellulose. Deesterification of the cellulose ester component without'degradation of the cellulose is essential to the produc tion of useful, stable composite yarns having the desired characteristics. The cellulose ester component present in the composite yarn in its initial condition, exists in the finished yarn as a component of cellulose reconstituted from the ester.
As a result of the removal of the ester groups:
from the cellulose chain, the reconstituted cellulose component undergoes linear shrinkage so:
that when the treated composite yarn is dried in the relaxed state, the reconstituted cellulose component expends its shrinkage capacity, and shrinks linearly causing the remaining component of the yarn which is not afiected as such by the deesterification treatment to wind itself about the reconstituted cellulose component. There is thus obtained a composite yarn in which the component other than the reconstituted cellulose component has been converted to a permanently crimped condition, thereby crimping the composite yarn as a whole.
The deesterification of the cellulose ester component of the composite yarn must be homogeneous andcomplete and, as has been stated, the composite yarn, after the deesterification treatment, must not have a measurable cellulose ester content. I find that ammonia and the lower alkylene amines having up to 3 carbons are specific agents for deesterifying the cellulose ester component homogeneously throughout its cross-section without appreciable. or noticeable degradation of the cellulose. The conditions of the treatment, that is the concentration of the nitrogeneous deesterifying agent, the temperature at which the composite yarn is treated with the solution, and the duration of the treatment, are interrelated. If lower concentrations." of ammonia or alkylene amine are used, higher. temperatures and longer immersion times are necessary, and vice versa. However, the deesterifying medium is maintained in the liquid phase throughout the entire treatment. I prefer to use aqueous solutions of ammonia or the alkylene amines of from 6 to 28% concentration at room temperatures, that is at temperatures in the range of to 30 0. Under those conditions, the deesterification is complete in from 6 to 15 hours. Preferably, the treated composite yarn is dried in the relaxed state at from 90 to 95 C.
The singles yarn or yarns plied or otherwise associated with the singles yarn or yarns of the fiber-forming organic acid ester of cellulose may be formed from fibers or filaments of any fiberforming material which is not afiected, as such, to any appreciable extent when the composite yarn is dried in the relaxed condition after immersion in the solution of ammonia or alkylene amine used to convert the cellulose ester component to reconstituted cellulose. For example, the singles yarn associated with the cellulose ester yarn may comprise silk, cotton, flax, regenerated cellulose from viscose or cuprammonium, etc.
The composite yarn comprising a component of cellulose reconstituted from the ester may be woven to produce boucle' or ratin fabrics having efiects corresponding to those of fabrics made from the conventional houcl yarns comprising two ground threads and an effect thread. How ever, the usual special weaving procedures normally resorted to in the manufacture of boucl fabrics are not necessary in. the present case. The boucl efiects are due solely to the presence of the novel composite yarns of the invention. The fabrics may be made wholly of the new composite yarns comprising the component of cellulose reconstituted from an ester in situ in the yarn, or the composite yarns may alternate with plain yarns in the warp and filling, or in the filling only. The new composite yarns may also be knitted to produce fabrics having very interesting surface characteristics.
The following examples will illustrate the method of the invention:
Example I A plied yarn was formed from a 150 denier/ 90 filament dull viscose yarn having a twist of 3 8 turns of twist per inch, and a 150 denier/41 filament dull cellulose acetate yarn (commercial secondary acetate) having a twist of 3 8 turns of twist per inch. The plied yarn had a Z twist of 8 turns per inch. The plied yarn was immersed in skein form in a bath consisting of a 15% aqueous ammonia solution for 15 hours at room temperature. The yarn was then washed free of ammonia, given a soft soap finish, and dried in the relaxed condition. Immersion of the yarn in the ammonia solution had the efiect of converting the cellulose acetate component to reconstituted cellulose at all portions of its crosssection, so that when the yarn was dried while relaxed the component which initially comprised cellulose acetate shrank about 40% in linear dimension, causing the component of regenerated cellulose from viscose to wind itself about the shrunken component.
The composite yarn was woven as a filling for a fabric, the warp yarns of which consisted of one end of 150 denier/90 filament dull viscose rayon yarn having 3 8 turns of twist per inch, alternating regularly with one end of 150 denier/41 filament dull cellulose acetate yarn having 3 8 turns of twist per inch.
Example II A composite yarn consisting of one end of 200 denier/52 filament dull acetate yarn having 3 turns of twist/inch and one end of 150 denier/ filament dull viscose yarn having 3 turns of twist/inch, plied to give a composite yarn having 14 8 turns per inch, and treated as in Example I to convert the cellulose acetate to reconstituted cellulose was used as filling for a woven fabric, the warp of which comprised one end of 75 denier/30 filament bright viscose rayon yarn having a twist of 3 8 turns of twist/inch alternating regularly with one end having three Z turns of twist/inch. A novel fabric having thick and thin surface characteristics was produced.
Example I II A composite yarn was obtained in the following manner: A denier/36 filament dull acetate yarn having 1 /2 8 turns of twist/inch was plied with a 75 denier/30 filament bright viscose rayon yarn having 3 S turns of twist/inch, to give a plied yarn having 14. 8 turns of twist/inch. Two of these plied yarns were plied to give a composite yarn having 8 2 turns of twist/inch. The composite yarn was treated as in Example I to convert the cellulose acetate yarn to reconstituted cellulose. The composite yarn was then used as the filling for a fabric having a warp as in Example II. A novel fabric having thick and thin surface characteristics was obtained.
Some variations maybe made in the conditions specifically stated in the examples without transcending the spirit and scope of the invention as defined in the appended claims.
I claim:
1. A method of producing yarns each comprising at least one shrunk end consisting of cellulose reconstituted from an organic acid ester of cellulose and at least one unshrunl: end which is wound about the reconstituted cellulose end as a result of shrinkage of the last-mentioned end in the yarn, which yarns impart a boucl effect to fabrics woven therefrom solely by the condition of the ends resulting from shrinkage of the reconstituted cellulose end in the yarn, which comprises plying at least one end of an organic acid ester of cellulose with at least one end of a material which is not affected as such when the yarn is dried in relaxed condition after immersion in aqueous solutions of ammonia and aikylene diamines, immersing th yarn, pri r to weaving, in a 6 to 28 aqueous solution of a substance selected from the group consisting of ammonia and alkylene diamines having from 1 to 3 carbons, for from 6 to 15 hours, at 25 to 30 (3., to completely and homogeneously convert the cellulose ester end throughout its cross-section to reconstituted cellulose without measurable degradation of the cellulose, washing the yarn, and thereafter drying the yarn under relaxed condition.
2. The method of claim 1 wherein the cellulose ester component initially present in the composite yarn consists of cellulose acetate.
3. The method of claim 1 wherein the plied yarn comprises initially at least one end of cellulose acetate having a twist of from 1 to 5 turns per inch.
4. The method of claim 1 wherein the plied yarn comprises initially at least one end of cellulose acetate and at least one end of cellulose rcgenerated from viscose.
5. The method of claim 1 wherein the plied yarn comprises initially at least one end of cellulose acetate having a twist of 3 turns per inch, and at least one end of cellulose regenerated from ORLANDO A. BATTISTA.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Number Number Name Date Dreyfus et a1: Feb. 14, 1933 Taylor Oct. 9, 1934 Sowter June 16, 1936 Dickie Feb. 16, 1937 Moncriefi et a1. Sept. 7, 1937 Platt Mar. 29, 1938 Bell et a1. Oct. 22, 1940 Wallach Aug. 19, 1941 Wallach Nov. 25, 1941 Bell et a1 June 27, 1944 FOREIGN PATENTS Country Date Great Britain Sept. 16, 1942 Great Britain Sept. 16, 1942

Claims (1)

1. A METHOD OF PRODUCING YARNS EACH COMPRISING AT LEAST ONE SHRUNK END CONSISTING OF CELLULOSE RECONSTITUTED FROM AN ORGANIC ACID ESTER OF CELLULOSE AND AT LEAST ONE UNSHRUNK END WHICH IS WOUND ABOUT THE RECONSTITUTED CELLULOSE END AS A RESULT OF SHRINKAGE OF THE LAST-MENTIONED END IN THE YARN, WHICH YARNS IMPART A BOUCLE EFFECT TO FABRICS WOVEN THEREFROM SOLELY BY THE CONDITION OF THE ENDS RESULTING FROM SHRINKAGE OF THE RECONSTITUTED CELLULOSE END THE YARN, WHICH COMPRISES PLYING AT LEAST ONE END OF AN ORGANIC ACID ESTER OF CELLULOSE WITH AT LEAST ONE END OF A MATERIAL WHICH IS NOT AFFECTED AS SUCH WHEN THE YARN IS DRIED IN RELAXED CONDITION AFTER IMMERSION IN AQUEOUS SOLUTIONS OF AMMONIA AND ALKYLENE DIAMINES, IMMERSING THE YARN, PRIOR TO WEAVING, IN A 6 TO 28% AQUEOUS SOLUTION OF A SUBSTANCE SELECTED FROM THE GROUP CONSISTING OF AMMONIA AND ALKYLENE DIAMINES HAVING FROM 1 TO 3 CARBONS, FOR FROM 6 TO 15 HOURS, AT 25 TO 30* C., TO COMPLETELY AND HAMOGENEOUSLY CONVERT THE CELLULOSE ESTER END THROUGHOUT ITS CROSS-SECTION TO RECONSTITUTED CELLULOSE WITHOUT MEASURABLE DEGRADATION OF THE CELLULOSE, WASHING THE YARN, AND THEREAFTER DRYING THE YARN UNDER RELAXED CONDITION.
US25313A 1948-05-05 1948-05-05 Novel yarn and method of making same Expired - Lifetime US2621392A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US25313A US2621392A (en) 1948-05-05 1948-05-05 Novel yarn and method of making same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US25313A US2621392A (en) 1948-05-05 1948-05-05 Novel yarn and method of making same

Publications (1)

Publication Number Publication Date
US2621392A true US2621392A (en) 1952-12-16

Family

ID=21825310

Family Applications (1)

Application Number Title Priority Date Filing Date
US25313A Expired - Lifetime US2621392A (en) 1948-05-05 1948-05-05 Novel yarn and method of making same

Country Status (1)

Country Link
US (1) US2621392A (en)

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1897691A (en) * 1928-01-21 1933-02-14 Celanese Corp Partial saponification of material containing organic esters of cellulose
US1976201A (en) * 1931-01-01 1934-10-09 Celanese Corp Textile material and the production thereof
US2044130A (en) * 1933-02-15 1936-06-16 Celancse Corp Textile yarn and the manufacture thereof
US2070583A (en) * 1931-06-18 1937-02-16 Celanese Corp Textiles containing cellulose derivatives
US2092004A (en) * 1933-11-22 1937-09-07 Celanese Corp Manufacture of artificial textile and other material
US2112303A (en) * 1935-07-30 1938-03-29 Celanese Corp Textile fabric of mixed fibers
US2218633A (en) * 1937-04-20 1940-10-22 Celanese Corp Textile material
US2252999A (en) * 1937-05-24 1941-08-19 Sylvania Ind Corp Article and process for the manufacture thereof
US2264229A (en) * 1937-11-02 1941-11-25 Sylvania Ind Corp Process for treating fibers and the products produced
GB547887A (en) * 1941-03-13 1942-09-16 Angus Smith Bell Improvements in or relating to the production of fabrics of a voluminous character
GB547886A (en) * 1941-03-13 1942-09-16 Angus Smith Bell Improvements in or relating to the production of voluminous yarns

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1897691A (en) * 1928-01-21 1933-02-14 Celanese Corp Partial saponification of material containing organic esters of cellulose
US1976201A (en) * 1931-01-01 1934-10-09 Celanese Corp Textile material and the production thereof
US2070583A (en) * 1931-06-18 1937-02-16 Celanese Corp Textiles containing cellulose derivatives
US2044130A (en) * 1933-02-15 1936-06-16 Celancse Corp Textile yarn and the manufacture thereof
US2092004A (en) * 1933-11-22 1937-09-07 Celanese Corp Manufacture of artificial textile and other material
US2112303A (en) * 1935-07-30 1938-03-29 Celanese Corp Textile fabric of mixed fibers
US2218633A (en) * 1937-04-20 1940-10-22 Celanese Corp Textile material
US2252999A (en) * 1937-05-24 1941-08-19 Sylvania Ind Corp Article and process for the manufacture thereof
US2264229A (en) * 1937-11-02 1941-11-25 Sylvania Ind Corp Process for treating fibers and the products produced
GB547887A (en) * 1941-03-13 1942-09-16 Angus Smith Bell Improvements in or relating to the production of fabrics of a voluminous character
GB547886A (en) * 1941-03-13 1942-09-16 Angus Smith Bell Improvements in or relating to the production of voluminous yarns
US2352245A (en) * 1941-03-13 1944-06-27 Celanese Corp Textile material and the production thereof

Similar Documents

Publication Publication Date Title
US2262861A (en) Composite article
US1989099A (en) Process of improving artificial threads
US2701406A (en) Fabric and method of making same
US3061998A (en) Bulked continuous filament yarns
US2287099A (en) Artificial wool
US2174878A (en) Yarn and method of producing same
US2414800A (en) Method of producing regenerated cellulose textile material
US2439813A (en) Artificial filament
US2780511A (en) Methiod of making cellulose acetate teixtile fibers by acetylization of relgenerated cellulose fibers
US2328074A (en) Manufacture of textile yarn
US3337671A (en) Method of making regenerated cellulose filaments
US2103218A (en) Heat-resistant yarn and heat-resistant cord and process for making same
US2621392A (en) Novel yarn and method of making same
US2846839A (en) Snag resistant bulky multi-ply superpolymidic yarn
US3120095A (en) Method of making high bulk yarns
US2602285A (en) Process of producing crepeable yarn
US3128147A (en) Process for treating polynosic fibers and products obtained thereby
US2507561A (en) Method of producing differential color effects in fabrics, and the fabric
US3046082A (en) Viscose process for the manufacture of low-shrink rayon
US2138950A (en) Method of producing yarn
US3084070A (en) Warp size comprising high molecular weight styrene/maleic anhydride copolymer
GB415055A (en) Improvements in yarn manufacture
US3340340A (en) Manufacture of crimped viscose rayon fibres
US2072250A (en) Treatment of filaments, films, and similar materials containing organic derivatives of cellulose
US3855775A (en) Process for producing ply yarn from threads of fibers