US2635056A - Finishing composition for textile materials - Google Patents
Finishing composition for textile materials Download PDFInfo
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- US2635056A US2635056A US720106A US72010647A US2635056A US 2635056 A US2635056 A US 2635056A US 720106 A US720106 A US 720106A US 72010647 A US72010647 A US 72010647A US 2635056 A US2635056 A US 2635056A
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- silica
- fabric
- fabrics
- solution
- sol
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
Definitions
- This invention relates to finishing agents for textile yarns or fabrics, and to methods of treating yarns or fabrics therewith.
- a silica aquasol containing from 1 to 20% by weight of a water-soluble polyhydric alcohol such as glycerine, diethylene glycol or sorbitol.
- a water-soluble polyhydric alcohol such as glycerine, diethylene glycol or sorbitol.
- These aquasols, or alcoaquasols may contain silica in amounts varying from about 0.5 to 30% by weight, and may be prepared in a wide variety of ways. It is important, however, for the sol to be applied in such amounts and concentrations as to supply from 0.1 to 5% silica on the fabric based on the dry weight of the fabric.
- the amount of polyhydric alcohol employed should preferably be not more than about twice as great as the amount of silica applied on the fabric.
- the sol or solution on the yarn or fabric is dried, which may or may not require special drying equipment, depending on whether subsequent treatment of the yarn or fabric involves subjecting the material to drying conditions.
- the yarn or fabric is passed over steam heated dry cans or infra red heated tenter frames maintained at a temperature of about 200 F. or higher, but not high enough to damage the fabric.
- an inorganic resinous film is applied, as indicated by the fact that the resulting material is substantially dust free, relatively wash fast, and appreciably firmer and fuller than prior to treatment.
- the treated fabrics of this invention differ decidedly from the gel treated fabrics of the prior art. In some cases, it is possible to dry the yarns or fabrics at lower temperatures, and even as low as room temperature.
- the silica aquasol used in accordance with the invention is preferably made by reacting an acid, such as a mineral acid or any other acid capable of forming salts by reaction with silicates, with a water-soluble silicate in the manner customarily employed to form silica gel, washing the resulting gel with water to remove the electrolytes formed during the reaction, covering the gel with a weak aqueous solution of a substance capable of forming hydroxyl ions and, after removing the gel from the solution, heating the gel, while avoiding evaporation of water, until substantially all of the gel is converted to a sol.
- an acid such as a mineral acid or any other acid capable of forming salts by reaction with silicates
- a water-soluble silicate in the manner customarily employed to form silica gel
- Solutions prepared in the above manner are preferred, since they are stable for an indefinite period of time.
- the silica contained therein has a larger particle size than the silica in other types of sols, and since they are usually prepared in a neutral or slightly alkaline state, they are admirably adapted for the purposes of this invention.
- Other types of colloidal solutions or sols of silica may also be used, however, including the sols prepared by reacting watersoluble silicates with an acid and subjecting the acidified silicate to treatment with alcohol and/ or to cooling to remove the electrolytes formed, as described in the U. S. patent to Morris D. Marshal, No.2,285,449 and in the U. S. patent to John F. White, No. 2,285,477. It is also possible to use sols prepared by treatment of an alkali silicate with ion-exchange material, as described in the U. S. patent to Paul G. Bird, No. 2,244,325.
- concentration of the colloidal solution or sol used is relatively unimportant, as it is possible to employ a wide variety of solution strengths depending upon the type of apparatus used or the degree of pick-up which is possible in the particular apparatus employed for applying the sol. Generally, however, it is preferable to employ solutions having an SiOz concentration between 0.1 and about 10%, although concentrations as high as 30% can be used.
- the alco-aquasols used in accordance with this invention may be readily prepared from the aquasols made by any of the above methods by merely mixing glycerine or other suitable polyhydric alcohol with the sol in appropriate proportions.
- suitable polyhydric alcohols include such water-soluble polyhydric alcohols as diethylene glycol and sorbitol.
- anhydrous glycero-sol or other polyhydric alcohol sol can be prepared in any desired manner, after which water is added in appropriate amounts to make an alco-aquasol.
- the fabric In applying the alco-aquasol to the fabric to be treated, the fabric is first immersed or otherwise coated or treated with the sol, after which the treated fabric is passed through squeeze rolls and dried in any suitable manner well known to the art.
- the resulting fabric not only possesses exceptional qualities of slip control, but displays a very desirable soft and full hand and is substantially free of dusting.
- Example I A colloidal solution of silica was prepared as:
- the solution so produced contained about 12.5 S102 and was diluted with water until it contained only 0.5% SiOz.
- Example II A silica aquasol containing about 12.5% SiOz was prepared as described in Example I. This was diluted with Water until it contained only 3% SiOz. To 98 pounds of the resulting aquasol was added 2 pounds of glycerine. Satin finished cotton lining was immersed in theresulting sol, and after passing through the sol was run through a padder. The fabric was then dried on a conventional tenter frame at a-temperature of 220 F., and upon completion of the drying was found to contain about 2.5% SiOz on the dry weight of the fabric. The treated fabric showed a reduction in slippage of 82% as compared with the slippagev displayed by the same fabric in the absence of treatment and had, in addition,- a marked delusten'ng effect. The fabric also possessed an exceedingly soft and full feel and was substantiallyfree of dusting.
- the sols described herein may be applied either by spraying or by immersion, either with or without the assistanceof padding or squeeze rolls or other types of extracting equipment. As a wide choice may bemade in the strength of the solution used, itis possible to use all types of apparatus in applying the sols. Thus, the desired amount of silica may be readily applied to the yarns or fabrics by adjusting the concentration of the solution in accordance with the amount of pick-up possible with the particular apparatus employed.
- the per cent pick-up referred to herein is a measure of the amount of solution by weight picked up or retained by the fibers. For example, pickup means that the fibersrhave picked up an amount by weight of the sol or solution equal to the weight of the fibers.
- the preferred sols for the purposes of this invention usually have, as initially prepared, apH ranging from about 7 to 10. It is possible, however, to employ the sols ata somewhat lowerpH, if desired. as for example where an acid reacting sol is desired.
- the sols may be applied to the fibers within the range of 4 to 10 pH, depending, on requirements and the most suitable pH for the particular fibers being treated.
- Yarns and fabricstreated with the sols of this invention possess a fullness'which is retained after washing, and when large enough amounts within thestated range are employed have a delustered appearance without added opaqueness.
- the sols also impart to yarns and fabrics a greater coefiicientof friction or slip resistance than similar untreated yarns possess. This, in turn, results in yarns or fabrics of greater tensile strength.
- Fine knit goods, such as hosiery show a. markedly increased wear, run and snag resistance, when treated with the sols madein accordance with the processes described herein.
- the treated fabrics possess an exceptionally soft hand, and are substantially free of dusting.
- the unusual advantages obtained as a result of the application of the sols described herein are believed to be due to the sub-microscopic roughness-imparted by the deposit of exceedingly small particles of silica-in the form of an inorganic resinous film.
- the silica films deposited have markedly different properties and effects on the yarn or fabric as compared with depositions of silica gel.
- the exceptional softness and freedom from dusting are, however, due primarily to the presenceof the glycerine-or other suitable-polyhydric-alcohol in the sol.
- A-fi'ni'shing agent for textile yarns or fabrics consisting of a colloidal solution of silica in water containing from 0.5 to 30% by Weight of silica and from 1 to 20% by weight of a water-soluble polyhydric alcohol selected from the group consisting of glycerine, diethylene glycol and sorbitol, said solution having a pH ranging from 7 to 10.
- a finishing agent for textile yarns or fabrics consisting of a colloidal solution of silica in Water containing from 0.5 to 30% by weight of silica and from 1 to 20% by weight of glycerine, said solution having a pH ranging from 7 to 10.
- a finishing agent for textile yarns or fabrics consisting of a colloidal solution of silica in water containing from 0.5 to 30% by Weight of silica and from 1 to 20% by weight of diethylene glycol, said solution having a pH ranging from 7 to 10.
- a finishing agent for textile yarns or fabrics consisting of a colloidal solution of silica in Water containing from 0.5 to 30% by weight of silica and from 1 to 20% by weight of sorbitol, said solution having a pH ranging from 7 to 10.
Description
Patented Apr. 14, 1953 FINISHING COMPOSITION FOR TEXTILE MATERIALS Donald H. Powers, Winchester, Mass., assignor to Monsanto Chemical Company, St. Louis, Mo., a corporation of Delaware No Drawing. Application January 3, 1947, Serial No. 720,106
4 Claims.
This invention relates to finishing agents for textile yarns or fabrics, and to methods of treating yarns or fabrics therewith.
It is a primary object of this invention to treat yarns or fabrics for the purpose of providing them with an improved finish and to provide an agent for this purpose which is not only capable of imparting exceptional slip resistance to fabrics, but is adapted to give to fabrics a soft, full hand and a substantially dust free finish.
The above and other purposes of the invention are obtained by applying on the yarn or fabric by any suitable means, such as spraying, immersion or padding, a silica aquasol containing from 1 to 20% by weight of a water-soluble polyhydric alcohol such as glycerine, diethylene glycol or sorbitol. These aquasols, or alcoaquasols, may contain silica in amounts varying from about 0.5 to 30% by weight, and may be prepared in a wide variety of ways. It is important, however, for the sol to be applied in such amounts and concentrations as to supply from 0.1 to 5% silica on the fabric based on the dry weight of the fabric. Moreover, the amount of polyhydric alcohol employed should preferably be not more than about twice as great as the amount of silica applied on the fabric.
After being applied, the sol or solution on the yarn or fabric is dried, which may or may not require special drying equipment, depending on whether subsequent treatment of the yarn or fabric involves subjecting the material to drying conditions. Preferably, the yarn or fabric is passed over steam heated dry cans or infra red heated tenter frames maintained at a temperature of about 200 F. or higher, but not high enough to damage the fabric. By treating the fabric in this manner, an inorganic resinous film is applied, as indicated by the fact that the resulting material is substantially dust free, relatively wash fast, and appreciably firmer and fuller than prior to treatment. In this respect, the treated fabrics of this invention differ decidedly from the gel treated fabrics of the prior art. In some cases, it is possible to dry the yarns or fabrics at lower temperatures, and even as low as room temperature.
The silica aquasol used in accordance with the invention is preferably made by reacting an acid, such as a mineral acid or any other acid capable of forming salts by reaction with silicates, with a water-soluble silicate in the manner customarily employed to form silica gel, washing the resulting gel with water to remove the electrolytes formed during the reaction, covering the gel with a weak aqueous solution of a substance capable of forming hydroxyl ions and, after removing the gel from the solution, heating the gel, while avoiding evaporation of water, until substantially all of the gel is converted to a sol. A more complete description of the manufacture of the above type of sol may be obtained in U. S. Patent No. 2,375,738 to John F. White.
Solutions prepared in the above manner are preferred, since they are stable for an indefinite period of time. Moreover, the silica contained therein has a larger particle size than the silica in other types of sols, and since they are usually prepared in a neutral or slightly alkaline state, they are admirably adapted for the purposes of this invention. Other types of colloidal solutions or sols of silica may also be used, however, including the sols prepared by reacting watersoluble silicates with an acid and subjecting the acidified silicate to treatment with alcohol and/ or to cooling to remove the electrolytes formed, as described in the U. S. patent to Morris D. Marshal, No.2,285,449 and in the U. S. patent to John F. White, No. 2,285,477. It is also possible to use sols prepared by treatment of an alkali silicate with ion-exchange material, as described in the U. S. patent to Paul G. Bird, No. 2,244,325.
The concentration of the colloidal solution or sol used is relatively unimportant, as it is possible to employ a wide variety of solution strengths depending upon the type of apparatus used or the degree of pick-up which is possible in the particular apparatus employed for applying the sol. Generally, however, it is preferable to employ solutions having an SiOz concentration between 0.1 and about 10%, although concentrations as high as 30% can be used.
The alco-aquasols used in accordance with this invention may be readily prepared from the aquasols made by any of the above methods by merely mixing glycerine or other suitable polyhydric alcohol with the sol in appropriate proportions. Other suitable polyhydric alcohols include such water-soluble polyhydric alcohols as diethylene glycol and sorbitol. Alternatively, and anhydrous glycero-sol or other polyhydric alcohol sol can be prepared in any desired manner, after which water is added in appropriate amounts to make an alco-aquasol.
In applying the alco-aquasol to the fabric to be treated, the fabric is first immersed or otherwise coated or treated with the sol, after which the treated fabric is passed through squeeze rolls and dried in any suitable manner well known to the art. The resulting fabric not only possesses exceptional qualities of slip control, but displays a very desirable soft and full hand and is substantially free of dusting.
Other featuresand advantages of the invention will be apparent-from the following examples:
Example I A colloidal solution of silica was prepared as:
follows:
Seventy-three pounds of 66 Be. H2804 were diluted with 358 pounds of water and charged to a mixing tank. Four hundred and seventy-two pounds of a sodium silicate solution analyzing 8.9% NazO and 29% SiOz were diluted with 377 pounds of water and added with stirring to the acid solution. The mixture set to a gel a few minutes after the mixing was completed. After 16'hours. agingthesyneresis liquor was siphoned off and the gel crushed to one inch lumps. These lumps. were washed with a continuous flow of water fo-r16 hours. The washed gel-was then covered with 750 poundsof: water containing. 0.9 poundof NaOH. After standing 6 hours the excesssolution was drained off and a portion of the gelwas charged to an autoclave. The gel was heated for 3 hours, using steam at 215 pounds per squareinch absolute pressurein the jacket of the autoclave. Thecontents of the autoclave were then blown out andthesmall amount of residual undispersedgel -was.removed by filtration. The solution so produced contained about 12.5 S102 and was diluted with water until it contained only 0.5% SiOz.
To the aquasol prepared as described above was added sufiicient-glycerine to provide a sol containing 1.0% glycerine by weight. Viscose flare chute cloth was immersed in the resulting sol, and after pas'singthrough the sol was. run through a padder adjusted for 100% pick-up. The fabric was then framed and dried on a conventional tenter frame at a temperature of 250 F. In comparison with 'the untreated cloth of the same type, the treated-fabric had more fullness of hand and greater slip resistance and tensile strength. Moreovenit had an exceedingly soft feel and was substantially free of dusting.
Example II A silica aquasol containing about 12.5% SiOz was prepared as described in Example I. This was diluted with Water until it contained only 3% SiOz. To 98 pounds of the resulting aquasol was added 2 pounds of glycerine. Satin finished cotton lining was immersed in theresulting sol, and after passing through the sol was run through a padder. The fabric was then dried on a conventional tenter frame at a-temperature of 220 F., and upon completion of the drying was found to contain about 2.5% SiOz on the dry weight of the fabric. The treated fabric showed a reduction in slippage of 82% as compared with the slippagev displayed by the same fabric in the absence of treatment and had, in addition,- a marked delusten'ng effect. The fabric also possessed an exceedingly soft and full feel and was substantiallyfree of dusting.
Equally effective results as those obtained in the above examples were'obtained by employing other water-solublepolyhydric alcohols including diethylene glycol or sorbitolv in the sols instead of glycerinein the proportions hereinbefore stated; I
In the examples, reference is made to the treatment of viscose and cotton fabrics. It should be understood, however, that equally good results can be obtained with all types of textile materials, including in addition to those named above, cellulosic materials, such as cellulose nitrate, cellulose acetate, cuprammonium rayon (Bernberg) and high tensile strength rayon (Fortisan) protein materials, such as natural silk and fibers made from the casein in milk (Aralac); synthetic materials, such as fibers made of the copolymer of vinyl chloride and vinylidine chloride (Saran), the copolymer of adipic acid and hexamethylene diamine (nylon), the copolymer of vinyl chlorideand vinyl acetate (Vinyon), and glass fibers; and yarns and fabrics containing mixtures or blends of any two or more of the above materials.
The sols described herein may be applied either by spraying or by immersion, either with or without the assistanceof padding or squeeze rolls or other types of extracting equipment. As a wide choice may bemade in the strength of the solution used, itis possible to use all types of apparatus in applying the sols. Thus, the desired amount of silica may be readily applied to the yarns or fabrics by adjusting the concentration of the solution in accordance with the amount of pick-up possible with the particular apparatus employed. The per cent pick-up referred to herein is a measure of the amount of solution by weight picked up or retained by the fibers. For example, pickup means that the fibersrhave picked up an amount by weight of the sol or solution equal to the weight of the fibers.
The preferred sols for the purposes of this invention usually have, as initially prepared, apH ranging from about 7 to 10. It is possible, however, to employ the sols ata somewhat lowerpH, if desired. as for example where an acid reacting sol is desired. Thus, the solsmay be applied to the fibers within the range of 4 to 10 pH, depending, on requirements and the most suitable pH for the particular fibers being treated.
Yarns and fabricstreated with the sols of this invention possess a fullness'which is retained after washing, and when large enough amounts within thestated range are employed have a delustered appearance without added opaqueness. The sols also impart to yarns and fabrics a greater coefiicientof friction or slip resistance than similar untreated yarns possess. This, in turn, results in yarns or fabrics of greater tensile strength. Fine knit goods, such as hosiery, show a. markedly increased wear, run and snag resistance, when treated with the sols madein accordance with the processes described herein. Moreover, the treated fabrics possess an exceptionally soft hand, and are substantially free of dusting.
The unusual advantages obtained as a result of the application of the sols described herein are believed to be due to the sub-microscopic roughness-imparted by the deposit of exceedingly small particles of silica-in the form of an inorganic resinous film. The silica films deposited have markedly different properties and effects on the yarn or fabric as compared with depositions of silica gel. The exceptional softness and freedom from dusting are, however, due primarily to the presenceof the glycerine-or other suitable-polyhydric-alcohol in the sol.
What I claim is:
1; A-fi'ni'shing agent for textile yarns or fabrics consisting of a colloidal solution of silica in water containing from 0.5 to 30% by Weight of silica and from 1 to 20% by weight of a water-soluble polyhydric alcohol selected from the group consisting of glycerine, diethylene glycol and sorbitol, said solution having a pH ranging from 7 to 10.
2. A finishing agent for textile yarns or fabrics consisting of a colloidal solution of silica in Water containing from 0.5 to 30% by weight of silica and from 1 to 20% by weight of glycerine, said solution having a pH ranging from 7 to 10.
3. A finishing agent for textile yarns or fabrics consisting of a colloidal solution of silica in water containing from 0.5 to 30% by Weight of silica and from 1 to 20% by weight of diethylene glycol, said solution having a pH ranging from 7 to 10.
4. A finishing agent for textile yarns or fabrics consisting of a colloidal solution of silica in Water containing from 0.5 to 30% by weight of silica and from 1 to 20% by weight of sorbitol, said solution having a pH ranging from 7 to 10.
DONALD H. POWERS.
References Cited in the file of this patent UNITED STATES PATENTS ame Date 6 Number Name Date 1,839,168 Stampe Dec. 29, 1931 2,027,931 Ray Jan. 14, 1936 2,042,702 Dreyfus June 2, 1936 5 2,071,419 Moss Feb. 23, 1937 2,285,449 Marshall June 9, 1942 2,285,477 White June 9, 1942 2,361,092 Gilbert Oct. 24, 1944 2,375,738 White May 8, 1945 1 2,383,653 Kirk Aug. 28, 1945 2,408,656 Kirk Oct. 1, 1946 2,432,484 Moulton Dec. 9, 1947 2,455,367 King Dec. 7, 1948 2,527,329 Powers et al Oct. 24, 1950 15 FOREIGN PATENTS Number Country Date 455,565 Great Britain Oct. 23, 1936 OTHER REFERENCES King: Journal Oil Colour Chemists Asso., vol. 13, No. 116 of 1930 (pages 28 to 55).
Qualitative Chemical Analyses, by Curtman, The MacMillan 00., 1933, pages 387-389.
Uses and Applications of Chemicals and Related Materials, Gregory, vol. 1, pages 239 and 302,
Reinhold Publishing Corp., New York, 1939.
Claims (1)
1. A FINISHING AGENT FOR TEXTILE YARNS OR FABRICS CONSISTING OF A COLLOIDAL SOLUTION OF SILICA IN WATER CONTAINING FROM 0.5 TO 30% BY WEIGHT OF SILICA AND FROM 1 TO 20% BY WEIGHT OF A WATER-SOLUBLE POLYHYDRIC ALCOHOL SELECTED FROM THE GROUP CONSISTING OF GLYCERINE, DIETHYLENE GLYCOL AND SORBITOL, SAID SOLUTION HAVING A PH RANGING FROM 7 TO 10.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US720106A US2635056A (en) | 1947-01-03 | 1947-01-03 | Finishing composition for textile materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US720106A US2635056A (en) | 1947-01-03 | 1947-01-03 | Finishing composition for textile materials |
Publications (1)
| Publication Number | Publication Date |
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| US2635056A true US2635056A (en) | 1953-04-14 |
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| US720106A Expired - Lifetime US2635056A (en) | 1947-01-03 | 1947-01-03 | Finishing composition for textile materials |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2780168A (en) * | 1951-11-16 | 1957-02-05 | John H Schneider | Composition for use in eliminating oil and grease smudges from offset printing mats and plates |
| US2823186A (en) * | 1955-09-14 | 1958-02-11 | Monsanto Chemicals | Silica aquasol containing a polyhydric alcohol |
| US2921913A (en) * | 1956-05-01 | 1960-01-19 | Du Pont | Silica organosols |
| US2928754A (en) * | 1956-12-31 | 1960-03-15 | American Viscose Corp | Production of soil-resistant material |
| US2941961A (en) * | 1955-10-13 | 1960-06-21 | Nalco Chemical Co | Silica-alumina compositions and method for the preparation thereof |
| US2941904A (en) * | 1955-08-31 | 1960-06-21 | Owens Corning Fiberglass Corp | High temperature glass fiber insulation product and method for manufacturing same |
| US2992124A (en) * | 1956-05-10 | 1961-07-11 | Port Oils Inc X | Resinous composition and method |
| US3004921A (en) * | 1958-06-11 | 1961-10-17 | Argus Chem | Preparation of colloidal dispersions of fine-particle size silica hydrogel in polyols |
| US3063128A (en) * | 1959-04-09 | 1962-11-13 | West Point Mfg Co | Process for controlling static properties of synthetic textile fibers |
| EP1746153A1 (en) | 2005-07-22 | 2007-01-24 | Unilever Plc | Improvements relating to domestic laundering |
| EP2184398A1 (en) * | 2008-11-11 | 2010-05-12 | Cognis IP Management GmbH | Use of silicone compounds for finishing fibers |
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| US1629241A (en) * | 1925-02-23 | 1927-05-17 | Ubbelohde Leo | Process of treating fibers for spinning purposes |
| US1839168A (en) * | 1928-12-20 | 1931-12-29 | Drager Otto H | Fabric for gas protection masks or the like and method for producing same |
| US2027931A (en) * | 1934-01-20 | 1936-01-14 | Carbide & Carbon Chem Corp | Method of depositing silica on material |
| US2042702A (en) * | 1929-05-04 | 1936-06-02 | Dreyfus Henry | Production or treatment of artificial materials |
| GB455565A (en) * | 1935-08-29 | 1936-10-23 | Bruno Kober | A method of producing bandaging material having a particularly high absorbing and adsorbing power |
| US2071419A (en) * | 1933-01-18 | 1937-02-23 | Celanese Corp | Treatment of textile material |
| US2285477A (en) * | 1942-06-09 | Method of producing sols | ||
| US2285449A (en) * | 1939-05-08 | 1942-06-09 | Monsanto Chemicals | Method of producing sols and aerogels |
| US2361092A (en) * | 1941-01-25 | 1944-10-24 | Gilbert Process Corp | Filter unit and process of making same |
| US2375738A (en) * | 1943-05-03 | 1945-05-08 | Monsanto Chemicals | Preparation of sols |
| US2383653A (en) * | 1941-06-04 | 1945-08-28 | Du Pont | Silicic acid sols |
| US2408656A (en) * | 1943-04-27 | 1946-10-01 | Du Pont | Process for producing silicic acid sols |
| US2432484A (en) * | 1943-03-12 | 1947-12-09 | American Optical Corp | Reflection reducing coating having a gradually increasing index of refraction |
| US2455367A (en) * | 1943-02-22 | 1948-12-07 | King Peter | Method for depositing nonreflective films and composition therefor |
| US2527329A (en) * | 1944-07-26 | 1950-10-24 | Monsanto Chemicals | Method for producing slip-resistant textile materials |
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1947
- 1947-01-03 US US720106A patent/US2635056A/en not_active Expired - Lifetime
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| US2285477A (en) * | 1942-06-09 | Method of producing sols | ||
| US1629241A (en) * | 1925-02-23 | 1927-05-17 | Ubbelohde Leo | Process of treating fibers for spinning purposes |
| US1839168A (en) * | 1928-12-20 | 1931-12-29 | Drager Otto H | Fabric for gas protection masks or the like and method for producing same |
| US2042702A (en) * | 1929-05-04 | 1936-06-02 | Dreyfus Henry | Production or treatment of artificial materials |
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| US2285449A (en) * | 1939-05-08 | 1942-06-09 | Monsanto Chemicals | Method of producing sols and aerogels |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2780168A (en) * | 1951-11-16 | 1957-02-05 | John H Schneider | Composition for use in eliminating oil and grease smudges from offset printing mats and plates |
| US2941904A (en) * | 1955-08-31 | 1960-06-21 | Owens Corning Fiberglass Corp | High temperature glass fiber insulation product and method for manufacturing same |
| US2823186A (en) * | 1955-09-14 | 1958-02-11 | Monsanto Chemicals | Silica aquasol containing a polyhydric alcohol |
| US2941961A (en) * | 1955-10-13 | 1960-06-21 | Nalco Chemical Co | Silica-alumina compositions and method for the preparation thereof |
| US2921913A (en) * | 1956-05-01 | 1960-01-19 | Du Pont | Silica organosols |
| US2992124A (en) * | 1956-05-10 | 1961-07-11 | Port Oils Inc X | Resinous composition and method |
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| US3063128A (en) * | 1959-04-09 | 1962-11-13 | West Point Mfg Co | Process for controlling static properties of synthetic textile fibers |
| EP1746153A1 (en) | 2005-07-22 | 2007-01-24 | Unilever Plc | Improvements relating to domestic laundering |
| EP2184398A1 (en) * | 2008-11-11 | 2010-05-12 | Cognis IP Management GmbH | Use of silicone compounds for finishing fibers |
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