US2637893A - Artificial filament - Google Patents

Artificial filament Download PDF

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Publication number
US2637893A
US2637893A US81126A US8112649A US2637893A US 2637893 A US2637893 A US 2637893A US 81126 A US81126 A US 81126A US 8112649 A US8112649 A US 8112649A US 2637893 A US2637893 A US 2637893A
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filament
filaments
web portions
artificial filament
artificial
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US81126A
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Shaw Gilbert
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    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • A46D1/02Bristles details
    • A46D1/0238Bristles with non-round cross-section
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/253Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S273/00Amusement devices: games
    • Y10S273/06Nylon
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2973Particular cross section

Definitions

  • the present invention relates to improved fila- I ments utilizable, for instance, as bristles in the manufacture of push brooms, Whisks, brushes, and related articles.
  • the invention relates more particularly to a filament which is artificially prepared, as contrasted with naturally occurring filaments such as vegetable fibres or animal hairs and bristles, said filaments of the invention being made of long chain, linear thermoplastic polymers the molecules of which have been oriented,
  • the invention has for an object the provision of an artificial filament having high qualities of stiffness, resiliency and durability making it particularly useful for use as bristles in brooms, brushes, and the like.
  • the invention further provides a filament having increased surface area over conventional filaments of either natural or synthetic origin making it particularly useful for paint brushes and similar uses, for instance.
  • Another object is the provision of a filament wherein the strength characteristics are retained but a substantially smaller mass of material is utilized than in conventional filaments, giving rise to savings in materials and a lighter weight in objects fabricated from the filaments.
  • Figs. 1 and 2 of the drawings illustrate two preferred cross sectional shapes which may be adapted for the synthetic filaments of the invention.
  • the filament of the invention is made of a long chain linear polymer or copolymer such as, for instance, vinyl chloride-acetate or nylon, the molecules of which have been oriented, that is, made to lie generally in the direction of the length of the filament, in order to provide a filament of high modulus of elasticity and tensile strength.
  • the filament is extruded from a suitable die so that the finished form of the filament provides a central filament portion and a plurality of filament web portions extending radially outwardly from the central portion.
  • the web portions so provided are preferably of considerable radial extent, extending for at least several times the thickness of the central filament portion, sothat the construction of the filament is essentially that of several intersecting continuous web portions, the central portion of thefilament being merely the intersection of the several webs and having a cross sectional dimension of about the order of the width of such webs.
  • all of the angles formed between adjacent surfaces of the webs by their intersection are equal, that is, the web portions are regularly positioned as radii in the body of the filament, and such web portions are preferably of substantially equal thickness and said thickness for each web portion is continuous.
  • Figs. 1 and 2 illustrate preferred cross sectional forms to be imparted to filaments in accordance with the invention, although such forms are given by way of example only, and other forms may be used.
  • a cruciform cross sectional shape may be adopted for the filament wherein a central filament portion ii] is formed by the intersection of the radially extending web portions M, l2, l3 and M.
  • the Web portions extend radially for distances which are several times the greatest thickness of the central portion [8, thus providing high strength in the filament with a minimum of material, and likewise providing a large total external surface.
  • the angles a internally of the filament formed between the adjacent faces of the several web portions are preferably, though not necessarily, equal, and the several web portions are also preferably of the same thickness and of substantially uniform thickness throughout their lengths, providing uniformity in the construction and functioning of the filament.
  • the filament may within the scope of the invention take a form having a Y cross section, wherein the central portion I5 is formed by the intersection of the three 3 web portions I6, I! and i8, and the arrangement and proportion of the elements is similar in principle to the embodiment of Fig. 1 just described.
  • any long chain linear thermoplastic polymer capable of being subsequently oriented may be used as the material for the filament depending upon the various properties which are desired in the finished pro uc't, and such pol'y'mer is extruded in accordance with known practices through spinnerets having shapes to impart the desired final form to the filament.
  • the bores or apertures of the spirinerets would have the forms of the cross sectional shapes of the finished filaments there shown.
  • the filament is extrudedand solfdifiedit is then stretched in accordance with the method best suited to the partichlar material being used in l me mi n; fill ,I 1.
  • the Po me scam-unwell lie .1. th .qi ectin q lt el n t .of...the filamentk giving a high m odulus of elasand..tensi a rene h. tgilaee I l d ..t'ions..
  • a filament of substantially uniform cross-section throughoutdts length whichis particularly adapted for use as a brush bristle, 'saidfilament being formed from a long chain linear oriented stable thermoplastic polymer, said cross-section cornprising at least three fiat, thin, erect webs radiating at about equal angles from each other from a small center portion having a cross-sectionaldimension of about the order of the thicknessdf such web's,'whereby a high degree of stiffness and a great amount of surface is obtained with a minimum of polymer.

Description

May 12, 1953 W 2,637,893
ARTIFICIAL FILAMENT Filed March 12, 1949 INVENTOR. G /1. BER T 5 HA w ,4 TTORNE Y5 Patented May 12, 1 953 UNITED STATES PATENT OFFICE ARTIFICIAL FILAMENT Gilbert Shaw, Middlebury, Vt.
Application March 12, 1949, Serial No. 81,126
1 Claim. (01. 2882) The present invention relates to improved fila- I ments utilizable, for instance, as bristles in the manufacture of push brooms, Whisks, brushes, and related articles. The invention relates more particularly to a filament which is artificially prepared, as contrasted with naturally occurring filaments such as vegetable fibres or animal hairs and bristles, said filaments of the invention being made of long chain, linear thermoplastic polymers the molecules of which have been oriented,
or made to lie generally in the direction of the with the invention, the same being realized and attained by means of the instrumentalities and combinations pointed out in the appended claim.
lhe invention consists in the novel parts, constructions, arrangements, combinations and improvements herein shown and described.
The accompanying drawings, referred to herein and constituting a part hereof, illustrate an embodiment of the invention, and together with the description, serve to explain the principles of the invention.
The invention has for an object the provision of an artificial filament having high qualities of stiffness, resiliency and durability making it particularly useful for use as bristles in brooms, brushes, and the like. The invention further provides a filament having increased surface area over conventional filaments of either natural or synthetic origin making it particularly useful for paint brushes and similar uses, for instance. Another object is the provision of a filament wherein the strength characteristics are retained but a substantially smaller mass of material is utilized than in conventional filaments, giving rise to savings in materials and a lighter weight in objects fabricated from the filaments.
Figs. 1 and 2 of the drawings illustrate two preferred cross sectional shapes which may be adapted for the synthetic filaments of the invention.
With the above stated and other objects in view the filament of the invention is made of a long chain linear polymer or copolymer such as, for instance, vinyl chloride-acetate or nylon, the molecules of which have been oriented, that is, made to lie generally in the direction of the length of the filament, in order to provide a filament of high modulus of elasticity and tensile strength. The filament is extruded from a suitable die so that the finished form of the filament provides a central filament portion and a plurality of filament web portions extending radially outwardly from the central portion. The web portions so provided are preferably of considerable radial extent, extending for at least several times the thickness of the central filament portion, sothat the construction of the filament is essentially that of several intersecting continuous web portions, the central portion of thefilament being merely the intersection of the several webs and having a cross sectional dimension of about the order of the width of such webs. In preferred forms of the filament all of the angles formed between adjacent surfaces of the webs by their intersection are equal, that is, the web portions are regularly positioned as radii in the body of the filament, and such web portions are preferably of substantially equal thickness and said thickness for each web portion is continuous. It will be apparent that filaments so fabricated will have maximum strength, stiffness and area characteristics for a minimum mass of material, and their use in brushes and brooms will provide maximum possible material economy.
It will be understood that the foregoing general description and the following detailed description as well are exemplary and explanatory of the invention but are not restrictive thereof.
Referring now in detail to the invention, Figs. 1 and 2 illustrate preferred cross sectional forms to be imparted to filaments in accordance with the invention, although such forms are given by way of example only, and other forms may be used. As shown in Fig. l, a cruciform cross sectional shape may be adopted for the filament wherein a central filament portion ii] is formed by the intersection of the radially extending web portions M, l2, l3 and M. The Web portions extend radially for distances which are several times the greatest thickness of the central portion [8, thus providing high strength in the filament with a minimum of material, and likewise providing a large total external surface. The angles a internally of the filament formed between the adjacent faces of the several web portions are preferably, though not necessarily, equal, and the several web portions are also preferably of the same thickness and of substantially uniform thickness throughout their lengths, providing uniformity in the construction and functioning of the filament.
As shown in Fig. 2 of the drawings, the filament may within the scope of the invention take a form having a Y cross section, wherein the central portion I5 is formed by the intersection of the three 3 web portions I6, I! and i8, and the arrangement and proportion of the elements is similar in principle to the embodiment of Fig. 1 just described.
In the formation of filaments of the invention any long chain linear thermoplastic polymer capable of being subsequently oriented may be used as the material for the filament depending upon the various properties which are desired in the finished pro uc't, and such pol'y'mer is extruded in accordance with known practices through spinnerets having shapes to impart the desired final form to the filament. In the case of filaments of the forms shown in Figs l and Z, for example, the bores or apertures of the spirinerets would have the forms of the cross sectional shapes of the finished filaments there shown.
After the filament is extrudedand solfdifiedit is then stretched in accordance with the method best suited to the partichlar material being used in l me mi n; fill ,I 1. the Po me scam-unwell lie .1. th .qi ectin q lt el n t .of...the filamentk giving a high m odulus of elasand..tensi a rene h. tgilaee I l d ..t'ions.. under which such stretching place -ivi11.-.hary in a,, cQrd& i=.Wit- ,t,h i t;iiria l.beine.use,d.afor inst ce lniylonlfil'am ts wil s re ch filw tens. to se e i ih f Y .inal n th. at .cpn t llgd t m ra re w i h L .Qm..ins a Q.m iY.- b $5. .fil men sc elrv nylg ar tre che l,ata tim r. 11'
.Zcr in anc n y mi s iihm ehf ni tmpsph .-f?m.. %h..we??? After e fil m t r riented the may in; accordance "withjk' I ract c h he is j .i lxii s nsebyr e smegma.. steam. befihiP or'dr meal s winkfi ifim. to a s aple er fijhe finished fila warrant "to 0.005 of 4 limited to the specific embodiments shown and described but departures may be made therefrom, within the scope of the accompanying claims, without departing from the principles of the invention and without sacrificing its chief advantages.
What I claim is:
A filament of substantially uniform cross-section throughoutdts length whichis particularly adapted for use as a brush bristle, 'saidfilament being formed from a long chain linear oriented stable thermoplastic polymer, said cross-section cornprising at least three fiat, thin, erect webs radiating at about equal angles from each other from a small center portion having a cross-sectionaldimension of about the order of the thicknessdf such web's,'whereby a high degree of stiffness and a great amount of surface is obtained with a minimum of polymer.
GILBERT SHAW.
rtf'iehc'es Cited in the file of this patent UN'I'TED 's'rA'rEs PATENTS @1 number "Name Date '1,7'73;969 Dreyfus et "a1. Aug-26,1930 @1002 ,1'53 Mendel May 21,1935 2,071,251 'Cai'others Feb. 16,1937 2,152j826 Spencer 1 -Ap'r. 4,4.939 "2,161,766 Rug'eleyet a1. June "6, L939 "2294;394 -Dra'emann Sept. 8,1942 2,433,325 Slaughter "Dec. 23,1947 255081799 Reis, "Jr -May-23, 0 EQREIGN A'PENTS mber... ic ilm i i Y mac gv phnandn Malawi-923 zsa so Italy l navjjaj'ifis 430,741 Germany "Jiixi-26;i926
"O HER REFERENCES r hlyvvbiir fsyhfihcic r ibr Thins"- 1931 revision. copy in' Div; 21.
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Cited By (64)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2743511A (en) * 1952-11-05 1956-05-01 Nat Plastic Products Company Scouring pad and filament
US2803087A (en) * 1955-02-24 1957-08-20 Albert M Zalkind Toy fencing foil
US2828752A (en) * 1954-08-16 1958-04-01 Eastman Kodak Co Fibrous tobacco smoke filters
US2834093A (en) * 1954-05-21 1958-05-13 Du Pont Regenerated cellulose filaments and products therefrom
DE1052357B (en) * 1957-01-07 1959-03-12 Zellwolle Und Kunstseide Ring Process for producing a split-end plastic bristle
US2939201A (en) * 1959-06-24 1960-06-07 Du Pont Trilobal textile filament
US2945739A (en) * 1955-06-23 1960-07-19 Du Pont Process of melt spinning
US2948584A (en) * 1958-05-20 1960-08-09 Du Pont Acrylonitrile fibers and process for producing same
US2959839A (en) * 1955-05-18 1960-11-15 Du Pont Linear condensation polymer fiber
US3017686A (en) * 1957-08-01 1962-01-23 Du Pont Two component convoluted filaments
US3041915A (en) * 1957-07-27 1962-07-03 Inventa A G Fur Forschung & Pa Process for the manufacture of net-like structures from synthetic fibers
DE1140901B (en) * 1961-09-16 1962-12-13 Walter Herdling Brush bristle
US3069747A (en) * 1958-03-04 1962-12-25 Du Pont Shaped products
US3091015A (en) * 1955-06-30 1963-05-28 Du Pont Drawing of nylon
US3097416A (en) * 1960-09-26 1963-07-16 Du Pont Textile filaments
US3109220A (en) * 1960-08-19 1963-11-05 Du Pont Tetralobal cross-sectioned filaments
US3116197A (en) * 1956-08-31 1963-12-31 Du Pont Nubbed filament and dyed fabric of same
US3121040A (en) * 1962-10-19 1964-02-11 Polymers Inc Unoriented polyolefin filaments
US3122960A (en) * 1964-03-03 stohlen
US3142147A (en) * 1959-03-09 1964-07-28 Monsanto Co Voluminous yarn from synthetic continuous thermoplastic filaments
US3184822A (en) * 1962-08-15 1965-05-25 Shaw Gilbert Method for manufacture of spatulated fibre
US3194002A (en) * 1962-07-25 1965-07-13 Eastman Kodak Co Multifilament yarn of non-regular cross section
DE1205051B (en) * 1961-10-23 1965-11-18 Gilbert Shaw Plastic bristles for brushes or the like and a method for their production
US3239865A (en) * 1965-03-24 1966-03-15 E B & A C Whiting Company Brush containing polypropylene bristles
US3239867A (en) * 1963-11-04 1966-03-15 Osborn Mfg Co Brush and brush material
US3249669A (en) * 1964-03-16 1966-05-03 Du Pont Process for making composite polyester filaments
US3295308A (en) * 1965-04-05 1967-01-03 Eastman Kodak Co Multifilament polyolefin carpets of non-regular cross-section and method of manufacture
US3312994A (en) * 1965-03-01 1967-04-11 Fassio Julius Brush device for cleaning, scouring and polishing
DE1253229B (en) * 1965-08-13 1967-11-02 Rhodiaceta brush
US3382305A (en) * 1954-10-29 1968-05-07 Du Pont Process for preparing oriented microfibers
US3425893A (en) * 1965-08-03 1969-02-04 James G Sims Textile filaments
US3508390A (en) * 1968-09-30 1970-04-28 Allied Chem Modified filament and fabrics produced therefrom
JPS5117327A (en) * 1974-07-31 1976-02-12 Kuraray Co Jujigatadanmenseni oyobi sonoseizoho
US4311761A (en) * 1980-09-04 1982-01-19 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Filament for wig
US4713289A (en) * 1985-04-09 1987-12-15 E. I. Du Pont De Nemours And Company Water-dispersible synthetic fiber
US4733425A (en) * 1986-06-16 1988-03-29 Sanderson-Macleod, Inc. Mascara brush
US5567072A (en) * 1995-06-07 1996-10-22 Risdon Corporation Mascara applicator having slotted bristles
US5595198A (en) * 1995-06-07 1997-01-21 Risdon Corporation Mascara applicator and method of making the same
WO1997003589A1 (en) 1995-07-19 1997-02-06 Specialty Filaments, Inc. Hollow brush bristle with radiating spokes
US5677059A (en) * 1995-05-10 1997-10-14 Kanegafuchi Kagaku Kogyo Kabushiki Kaisha Fiber for artificial hair having excellent bulkiness
US5723159A (en) * 1989-04-04 1998-03-03 Eastman Chemical Company Spinnerets for making fibers capable of spontaneously transporting fluids
US5762432A (en) * 1995-06-07 1998-06-09 Risdon Corporation Mascara applicator having slotted bristles
US5786087A (en) * 1995-02-22 1998-07-28 Specialty Filaments, Inc. Honeycomb brush bristles and brush made therefrom
WO1999045820A1 (en) * 1998-03-09 1999-09-16 Gillette Canada Company A notched dental hygiene article
US5993784A (en) * 1997-07-24 1999-11-30 Whitehill Oral Technologies Low foaming therapeutic toothpastes with improved cleaning and abrasion performance
US6086373A (en) * 1996-07-25 2000-07-11 Schiff; Thomas Method of cleaning teeth with a toothbrush with improved cleaning and abrasion efficiency
US6450177B1 (en) 1999-03-12 2002-09-17 Avon Products, Inc. Applicator brush
US6790797B1 (en) 1999-04-15 2004-09-14 Invista North America S.A.R.L. Insulating and footwear system
US20060080799A1 (en) * 2004-10-18 2006-04-20 Frank Lucente Toothbrush featuring bristles with raised annular portions
US20100306944A1 (en) * 2009-03-04 2010-12-09 Braun Gmbh Toothbrush bristle and method for manufacturing such a bristle
US20140325780A1 (en) * 2011-12-22 2014-11-06 Carl Freudenberg Kg Broom head with bristle structure
EP1846618B2 (en) 2005-02-08 2018-05-30 Ten Cate Thiolon B.V. Artificial fibre for use in an artificial grass sport field
CN109310201A (en) * 2016-06-03 2019-02-05 宝洁公司 Long filament and oral care implement for oral care implement
USD840159S1 (en) 2017-11-17 2019-02-12 Lilly Brush Company, Llc Brush
USD846216S1 (en) 2017-11-17 2019-04-16 Lilly Brush Company, Llc Handheld detailer
USD853126S1 (en) 2017-11-17 2019-07-09 Lilly Brush Company, Llc Brush
US10869545B2 (en) 2017-10-10 2020-12-22 The Procter & Gamble Company Filament for an oral care implement and oral care implement
US10869546B2 (en) 2017-10-10 2020-12-22 The Procter & Gamble Company Tuft and head for an oral care implement and oral care implement
US10874205B2 (en) 2016-06-03 2020-12-29 The Procter & Gamble Company Head for an oral care implement and oral care implement
USD917891S1 (en) 2019-07-26 2021-05-04 Lilly Brush Co., LLC Detailing tool
US11219302B2 (en) 2017-10-10 2022-01-11 The Procter & Gamble Company Head for an oral care implement and oral care implement
US11259623B2 (en) 2017-05-31 2022-03-01 The Procter & Gamble Company Head for an oral care implement and oral care implement
US11425991B2 (en) 2014-03-11 2022-08-30 The Procter & Gamble Company Head for an oral care implement
US11517171B2 (en) 2019-07-26 2022-12-06 Lilly Brush Co., LLC Detailing tool

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US1773969A (en) * 1928-09-08 1930-08-26 Celanese Corp Process of and apparatus for making artificial filaments
US2002153A (en) * 1933-04-13 1935-05-21 Sylvania Ind Corp Artificial filament and method for its production
US2071251A (en) * 1931-07-03 1937-02-16 Du Pont Fiber and method of producing it
US2152826A (en) * 1936-09-04 1939-04-04 Filatex Corp Article and process for producing the same
US2161766A (en) * 1937-09-15 1939-06-06 Carbide & Carbon Chem Corp Synthetic fiber
US2294894A (en) * 1938-07-09 1942-09-08 Draemann Max Process and apparatus for making sharp-edged thereads, cords, ribbons or bands, profiled stripe, and so forth from plastic masses, artificial and natural dispersions and emulsions
US2433325A (en) * 1942-08-19 1947-12-23 Extruded Plastics Inc Extruded resinous bristles
US2508799A (en) * 1944-12-28 1950-05-23 Pittsburgh Plate Glass Co Paintbrush and synthetic bristles for the same

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NL8490C (en) *
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US1773969A (en) * 1928-09-08 1930-08-26 Celanese Corp Process of and apparatus for making artificial filaments
US2071251A (en) * 1931-07-03 1937-02-16 Du Pont Fiber and method of producing it
US2002153A (en) * 1933-04-13 1935-05-21 Sylvania Ind Corp Artificial filament and method for its production
US2152826A (en) * 1936-09-04 1939-04-04 Filatex Corp Article and process for producing the same
US2161766A (en) * 1937-09-15 1939-06-06 Carbide & Carbon Chem Corp Synthetic fiber
US2294894A (en) * 1938-07-09 1942-09-08 Draemann Max Process and apparatus for making sharp-edged thereads, cords, ribbons or bands, profiled stripe, and so forth from plastic masses, artificial and natural dispersions and emulsions
US2433325A (en) * 1942-08-19 1947-12-23 Extruded Plastics Inc Extruded resinous bristles
US2508799A (en) * 1944-12-28 1950-05-23 Pittsburgh Plate Glass Co Paintbrush and synthetic bristles for the same

Cited By (76)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3122960A (en) * 1964-03-03 stohlen
US2743511A (en) * 1952-11-05 1956-05-01 Nat Plastic Products Company Scouring pad and filament
US2834093A (en) * 1954-05-21 1958-05-13 Du Pont Regenerated cellulose filaments and products therefrom
US2828752A (en) * 1954-08-16 1958-04-01 Eastman Kodak Co Fibrous tobacco smoke filters
US3382305A (en) * 1954-10-29 1968-05-07 Du Pont Process for preparing oriented microfibers
US3546063A (en) * 1954-10-29 1970-12-08 Du Pont Microfibers and shaped structures containing microfibers
US2803087A (en) * 1955-02-24 1957-08-20 Albert M Zalkind Toy fencing foil
US2959839A (en) * 1955-05-18 1960-11-15 Du Pont Linear condensation polymer fiber
US2945739A (en) * 1955-06-23 1960-07-19 Du Pont Process of melt spinning
US3091015A (en) * 1955-06-30 1963-05-28 Du Pont Drawing of nylon
US3116197A (en) * 1956-08-31 1963-12-31 Du Pont Nubbed filament and dyed fabric of same
DE1052357B (en) * 1957-01-07 1959-03-12 Zellwolle Und Kunstseide Ring Process for producing a split-end plastic bristle
US3041915A (en) * 1957-07-27 1962-07-03 Inventa A G Fur Forschung & Pa Process for the manufacture of net-like structures from synthetic fibers
US3017686A (en) * 1957-08-01 1962-01-23 Du Pont Two component convoluted filaments
US3069747A (en) * 1958-03-04 1962-12-25 Du Pont Shaped products
US2948584A (en) * 1958-05-20 1960-08-09 Du Pont Acrylonitrile fibers and process for producing same
US3142147A (en) * 1959-03-09 1964-07-28 Monsanto Co Voluminous yarn from synthetic continuous thermoplastic filaments
US2939201A (en) * 1959-06-24 1960-06-07 Du Pont Trilobal textile filament
US3109220A (en) * 1960-08-19 1963-11-05 Du Pont Tetralobal cross-sectioned filaments
US3097416A (en) * 1960-09-26 1963-07-16 Du Pont Textile filaments
DE1140901B (en) * 1961-09-16 1962-12-13 Walter Herdling Brush bristle
DE1205051B (en) * 1961-10-23 1965-11-18 Gilbert Shaw Plastic bristles for brushes or the like and a method for their production
US3194002A (en) * 1962-07-25 1965-07-13 Eastman Kodak Co Multifilament yarn of non-regular cross section
US3184822A (en) * 1962-08-15 1965-05-25 Shaw Gilbert Method for manufacture of spatulated fibre
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