US2811457A - Inorganic bonded thermal insulating bodies and method of manufacture - Google Patents
Inorganic bonded thermal insulating bodies and method of manufacture Download PDFInfo
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- US2811457A US2811457A US326778A US32677852A US2811457A US 2811457 A US2811457 A US 2811457A US 326778 A US326778 A US 326778A US 32677852 A US32677852 A US 32677852A US 2811457 A US2811457 A US 2811457A
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- 238000000034 method Methods 0.000 title description 18
- 238000004519 manufacturing process Methods 0.000 title description 5
- 239000002245 particle Substances 0.000 claims description 41
- 239000004964 aerogel Substances 0.000 claims description 34
- 239000011230 binding agent Substances 0.000 claims description 23
- 239000003605 opacifier Substances 0.000 claims description 16
- 239000000919 ceramic Substances 0.000 claims description 14
- 239000004615 ingredient Substances 0.000 claims description 9
- 230000003014 reinforcing effect Effects 0.000 claims description 9
- 239000012783 reinforcing fiber Substances 0.000 claims description 8
- 239000007795 chemical reaction product Substances 0.000 claims description 7
- 239000011800 void material Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 description 27
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 23
- 239000000835 fiber Substances 0.000 description 14
- 239000004965 Silica aerogel Substances 0.000 description 12
- 239000000463 material Substances 0.000 description 12
- 238000009413 insulation Methods 0.000 description 9
- 239000000945 filler Substances 0.000 description 7
- 239000000499 gel Substances 0.000 description 7
- 229910052845 zircon Inorganic materials 0.000 description 7
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 7
- 230000005855 radiation Effects 0.000 description 6
- 238000000465 moulding Methods 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- XYCWOLUUHSNDRX-UHFFFAOYSA-L [dioxido-[oxo(trioxidosilyloxy)silyl]oxysilyl]oxy-[[dioxido-[oxo(trioxidosilyloxy)silyl]oxysilyl]oxy-oxosilyl]oxy-dioxidosilane iron(2+) dihydroxide Chemical compound [OH-].[OH-].[Fe++].[Fe++].[Fe++].[Fe++].[Fe++].[Fe++].[Fe++].[O-][Si]([O-])([O-])O[Si](=O)O[Si]([O-])([O-])O[Si](=O)O[Si]([O-])([O-])O[Si]([O-])([O-])O[Si](=O)O[Si]([O-])([O-])[O-] XYCWOLUUHSNDRX-UHFFFAOYSA-L 0.000 description 4
- 230000001419 dependent effect Effects 0.000 description 4
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000010425 asbestos Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 229910052895 riebeckite Inorganic materials 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 2
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- 238000012935 Averaging Methods 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009950 felting Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 238000007429 general method Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 239000002557 mineral fiber Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000012255 powdered metal Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000011863 silicon-based powder Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B30/00—Compositions for artificial stone, not containing binders
- C04B30/02—Compositions for artificial stone, not containing binders containing fibrous materials
Definitions
- This invention relates to handlcable, ceramic-bonded heat insulation shapes which have low thermal conductivity comparable to that of free still air, and methods of manufacturing such insulating bodies.
- a primary object of the invention is to provide a high temperature heat insulation shape which is handleable and is retained in its bonded form by a ceramic bonding material, and which contains a maximum number of minute pore spacings between the finest structural units, such spacings averaging effectively below the approximate mean free path of air.
- An additional and more specific object is to provide a high temperature ceramic-bonded, handlcable heat insulation shape having a thermal conductivity factor k of approximately 0.4 B. t. u./sq. ft./hour/inch/ F. at 1000 F. mean.
- Another object of the invention is to provide a ceramic-bonded, handleable heat insulation shape having a chiefly inorganic composition adapted for insulating service at temperatures ranging as high as 1500 F.
- the invention consists in the improved thermal insulation material and method of manufacture which defined by the accompanying claims.
- thermal insulating shapes An important novel feature of the herein-disclosed thermal insulating shapes is that, in general, the preferred shapes having densities in the range between approxinrately 8 and 30 lbs/cu. ft. exhibit thermal insulating characteristics comparable to a correspondingly dimenstoned volume of free still air which has a thermal conductivity of 0.404 at 1000 F. mean; that is, have a thermal conductivity factor k of less than 0.55 at 1000 F. nie'an.
- ceramic-bonded, handleable shapes of this invention in the density range indicated have thermal conductivity factors less than corresponding thermal conductivity factors of unb'ondeulocse mass mixtures of essentially the same composition as the bonded shapes, even after such mixtures have been consolidated by vibration to densities equallag-the density of the bonded, handleable shapes.
- Such a phenomenon is entirely unexpected since, in normal instances of bonding together loose insulating particles, the finally formed body has a higher k than a correspondingly dense mass of loose particles. This is usually clue, of course, to an increase of the solids conductivity of the mass.
- the handleable insulating shapes made according to this invention exhibit the converse of this general consideration.
- a bulk mixture of the same proportions of the silica aerogel and Zircon of the type used in molding the ceramicbonded shape was vibrated to a density of 9.2 lbs/cu.
- the asbestos fiber of the block would also increas the solids conductivity, and would thus be expected to increase the k of the consolidated loose mass. It will be appreciated that a loose mass including fiber could probably not be vibrated to such a density, and retain homogeneity.
- thermal insulating shapes of comparable densities and thermal conductivity factors k to the ceramic-bonded insulating shapes of this invention.
- the preferred insulating shapes disclosed and claimed in our copending application essentially comprise a reinforcing skeleton or network of fine staple reinforcing fibers which may be either organic or inorganic, a substantial amount of particulate filler material having an ultimate structural unit with a diameter finer than millimicrons, such as aerogel or finely divided channel grade carbon black, and an inorganic or organic binder distributed throughout and holding the body in shape-retaining form.
- a suitable, disclosed binder for such blocks is a thcrmosetting phenolic-aldehyde resin.
- the preferred insulating shapes according to this in-- vention are composed essentially of a reinforcing skeleton or network of fine staple reinforcing fibers which may be either organic or inorganic; a substantial amount, and preferably at least 40% by weight of a particulate filler material having a porous or fibrillate structure, such as aerogels of, for example, silica, chromic oxide, thoria, magnesium hydrate, alumina, and mixtures thereof; and a ceramic binder having a composition comprising the heat reaction product of the ingredients initially present in the aerogel particles.
- a particulate filler material having a porous or fibrillate structure
- aerogels of, for example, silica, chromic oxide, thoria, magnesium hydrate, alumina, and mixtures thereof
- a ceramic binder having a composition comprising the heat reaction product of the ingredients initially present in the aerogel particles.
- the aerogel particles utilized to form the ceramicbonded insulating shapes of this invention are formed by a procedure generally similar to that outlined in the patent to Kistler, No. 2,093,454.
- the method generally comprises forming a gel, confining the resulting prodnot in a pressure vessel, applying heat thereto until the liquid in the gel has reached a temperature at which the surface dimension of the liquid is so small as to produce no substantial shrinkage of the gel when the liquid is allowed to evaporate, maintaining such a temperature, and then releasing the vapor from the pressure vessel at a rate insufficient to injure the gel. Dry, porous, fibrillate aerogel particles are thus obtained.
- the composition of these aerogels is substantially that of the materials forming the gel.
- the composition is almost entirely silica when a silica gel is used as the starting material.
- the particles also evidently contain, however, impurities comparable to those found in the gel.
- aerogel particles such as silica aerogel, contain residual impurities in the form of soluble salts such as sodium sulphate and the like formed as reaction products during the formation of the gel.
- Staple reinforcing fibers suitable for use in the insulating shapes of this invention may comprise such materials as various types of asbestos fibers of reinforcing grade, cleaned mineral fibers, fine diameter glass fibers, preferably pretreated, as with acid, to roughen the surface or otherwise to improve the surface adhesion characteristics, heat-stable organic fibers such as acrylic fibers which have been treated to render them heat-stable, or mixtures thereof.
- the preferred inorganic fiber is a well-opened fine staple amosite asbestos classifying as to length not less than at least 25% longer than A". All of such fibers should preferably classify finer than 20 microns diameter and further finer than microns.
- the amount of fiber present in the bonded insulation shape is usually small but may vary over a considerable range, depending upon the strength requirements for the particular insulation service.
- the fiber content preferably comprises up to by weight, and normally approximately 5% by weight of the insulating shape is used.
- the low conductivity insulating shapes of this invention must contain a substantial amount of a particulate filler material having the structural and chemical characteristics which are necessary to this invention.
- the particulate filler material is exemplified by aerogels such as those of silica, chromic oxide, thoria, magnesium hydrate, alumina, etc., and mixtures thereof.
- aerogels in particle form have a straw stack agglomerate fibril structure, with the fibrils composing the ultimate or finest structural unit of diameter finer than 100 millimicrons.
- the average aerogel particles should embrace a total void or dead air space of 75-99% by volume, and may be treated to render them hydrophobic in nature.
- particulate filler material of the above defined nature which must be utilized is dependent upon the nature of the insulating shape formed and its desired use.
- the insulating bodies may contain from 4095% by weight of such filler particles.
- the preferred proportion is approximately 40-75% by weight, and a substantial amount of opacitying material is used.
- the opacity of an aerogel is usually adequate for insulating against heat transfer by radiation.
- the insulating shape should be composed in part of finely divided opacifiers, preferably of inorganic composition.
- These opacifiers may be of the radiation reflective type, such as metallic aluminum or silicon powder; of the radiation absorbing type, such as powdered metals or finely divided pigments, as for example, chromium oxide; or of the radiation scattering type, such as zircon, titanium dioxide, or other materials of high index of rel to a density sufficient to form particles, fiber, opacifier,
- opacifiers may advantageously be used as an opacifier for the aerogel fillers in amounts up to 125% by weight of the total aerogel particle content of the shape. It will be appreciated that the amount of opacifier required is usually determined by the severity of the radiation problem, which increases with the increase in temperature. Since the blocks of this invention are particularly adapted for high temperature use, the radiation problem will be serious and relatively large amounts of opacifier should be used.
- the ceramic binder utilized in the low conductivity insulating shapes of this inven tion does not require the addition of other than the aforesaid ingredients to the composition; that is, no binder materials are required in the finally fabricated insulating shape which are not present as part of the composition of the aerogel particles.
- the ceramic bond of the herein disclosed-insulating shapes may be formed by either of two methods. In both methods the various components used to form the insulating shape are intimately mixed by any suitable mixing procedure to obtain a thorough dispersion and intermixing of all ingredients.
- aerogel particles, the fiber, and opacifier are intimately mixed to develop a particle-filled fibrous mass.
- This mass is then moisturized by treatment in a humidifying chamber.
- the mass is exposed to a gas with a relatively high humidity and an elevated temperature, for example, air with a relative humidity of 95% and a temperature of F.
- the mass is exposed to the humidified gas for a sufiicient time to enable it to adsorb some moisture, and preferably approximately 2-35% by weight of said particles.
- the amount of moisture required to be adsorbed is dependent upon that required to give the shape its green strength, that is, to enable the formation of an initial handleable green body upon molding, which in turn is dependent upon the density of the molded body.
- green bodies having densities of approximately 13 lbs/cu ft. have been fabricated employing only approximately two percent moisture.
- the maximum amount of moisture which may be employed is dependent upon the consideration that the insulating characteristics of the final product must be obtained, and thus the aerogel structure may not be destroyed.
- the resultant humidified or wetted mixture may then be pressed, with or without heat, to the desired shape and a handleable, self-sustaining green body.
- the final ceramic-bonded, handleable low conductivity insulating shape is then obtained by heating the thus formed shape for a time and at an elevated temperature sufiicient to develop the ceramic bond, apparently by a partial sintering and/or a reaction between the impurities present in the aerogel, as, for example, between the sodium sulphate and the silica itself, in a silica aerogel.
- This temperature should preferably be approximately 1000 F., and temperatures from approximately 600 to 1600 F. have been utilized successfully with silica aerogel compositions.
- the second method for forming the ceramic-bonded insulating shapes of this invention is generally similar to the foregoing.
- a mixture of aerogel and a thermally decomposable temporary binder is intimately mixed to obtain a particleloaded, fibrous network mass.
- Any suitable temporary binder may be utilized which has the characteristics of rendering to the mass a handleable shape upon the intial forming and the capability of being burned out of the shape at the sintering temperature.
- Most organic binders such as common thermosetting resins, as, for example, phenolor urea-formaldehyde, and common thermoplastic resins such as vinyl chloride, vinyl chloride-acetate copolymers, or silicons, have these desired characteristics.
- the temporary binder is utilized in an amount sufficient to render the initially formed shape handleable for all future manufacturing procedures, and should be capable of obtaining its shape-retaining form under the conditions utilized to obtain the initially formed shape.
- a light, fluffy mass is formed by intimately mixing the aerogel particles, fiber, and binder, preferably in dry particulate form.
- the mass is then subjected to sufficient heat and pressure to obtain the desired density and to set or cure the binder to its shape-retaining form.
- the thus formed temporarily bonded, handleable shape is then heated to a sufliciently high temperature to burn out the temporary binder and develop the ceramic bond as heretofore disclosed.
- a substantially lower thermal conductivity is obtained in a burned out body formed in accordance with this procedure and containing a relatively large amount of thermally conductive opacifier particles than that found for the temporarily bonded body use in its formation. This is apparently due to the destruction of thermally conductive bridges of temporary binder between opacifier particles.
- the intimately mixed light and bulky mass can be molded and set to a shape of any desired conformation and density.
- Suitable green bodies may be obtained by molding the mass in a conventional press mold, utilizing suitable pressures and/or temperatures to either activate and develop a set for the temporary binder, or to develop a set in the moisturized shape.
- Such bodies may also be obtained by uniformly distributing, i. e. felting, and consolidating the fluffy mass in known manner and then heating the thus consolidated mass to obtain a handleable ape.
- Excellent thermal insulating shapes have been produced according to this invention having densities in the range of 8 to 30 lbs/cu. ft. with thermal conductivities, or k factors, approximating 0.35 to 0.55 at 1000 F. mean.
- the preferred insulating shapes have a thermal conductivity factor k of approximately 0.4 at 1000 F. mean; that is, the preferred shapes formed according to this invention have insulating characteristics comparable to free still air.
- Opacified shapes having the essentially inorganic compositions which are set forth above are adapted for insulating service for temperatures up to 1500 F.
- the ceramic-bonded insulating shapes have ample strength characteristics and handleability for subsequent insulating service.
- a ceramicbonded insulating shape formed from a composition approximately comprising by weight of amosite fibers, 75% by weight of silica aerogel, by weight of zircon, and 5% by weight of thermosetting resin temporary binder, and having a density of 13 lbs./ cu. it. was found on test to develop a transverse modulus of rupture of approximately lbs./ sq. in.
- Example I A strong, ceramic-bonded thermal insulating shape was formed by molding with sufficient heat and pressure to set the resin, an intimately dispersed mixture of:
- the thus formed green" shape was heated for approximately one hour at 1200 F. to develop the desired ceramic bond.
- the ceramic-bonded shape obtained had a density of approximately 17 lbs./cu. ft. and a thermal conductivity factor k of 0.22 at 350 F. mean, and 0.4 at 1000 F.
- a series of insulating bodies having a density of approximately 20 lbs./ cu. ft. were molded from a humidilied mixture containing 85 parts of silica aerogel and 10 parts of zircon opacitier.
- Half of the blocks fabricated were fired at 1400 F. as herein disclosed, while the remainder were tested in an unfired condition.
- Standard test conditions indicated a modulus of rupture of approximately 13.4 lbs/cu. ft. for the unfired blocks, while the fired blocks were found to have a modulus of rupture of 24.0 lbs./cu. ft.
- a comparison of these moduli of rupture immediately indicates substantially greater strength in the fired blocks fabricated in accordance with this invention, which must be due to the bonding medium formed during the firing procedure.
- a ceramic-bonded. handleable insulating body having a density of less than approximately 30 lbs/cu. ft. and a thermal conductivity factor k of less than approximately 0.55 at l000 F. mean, comprising heat-stable, staple reinforcing fibers in amount sufficient to form a reinforcing skeleton up to approximately 15% by weight, approximately 40 to 95% by weight of inorganic aerogel particles containing a total void space of approximately 75 to 99% by volume, finely divided opacifier particles, and a ceramic binder distributed throughout said body essentially comprising the heat reaction product of the ingredients initially present in said aerogel particles.
- a ceramic-bonded, light weight, handleable insulating body having a low thermal conductivity which comprises hcat-stable, staple reinforcing fibers in amount sufficient to form a reinforcing skeleton up to approximately 15% by weight, approximately 40 to 95% by weight of inorganic aerogel particles. and a ceramic binder distributed throughout said body essentially comprising the heat reaction product of the ingredients initially present in said aerogel particles.
- a ceramic-bonded, light weight, handleable insulating body having a low thermal conductivity which comprises heat-stable, staple reinforcing fibers in amount sufficicnt to form a reinforcing skeleton up to approximately 15% by weight, approximately 40 to 95% by weight of inorganic aerogel particles, finely divided opacifier particles in amount up to approximately by weight of said aerogel particles, and a ceramic binder distributed throughout said body essentially comprising the heat reaction product of the ingredients initially present in said aerogel particles.
- a ceramic-bonded, handleable insulating body having a form a reinforcing skeleton up to approximately 15% approximately 40 to 95% by weight of inorganic aerogei particles, finely divided opacifier particles in amount up to approximately 125% by weight of said aerogel particles, and a ceramic binder distributed weight of silica aerogel particles,
Description
are hereinafter described and more particularly United States Patent INORGANIC BONDED THERMAL INSULATING BODIES AND METHOD OF MANUFACTURE Application December 18, 1952, Serial No. 326,778
7 Claims. (Cl. 106-69) No Drawing.
This invention relates to handlcable, ceramic-bonded heat insulation shapes which have low thermal conductivity comparable to that of free still air, and methods of manufacturing such insulating bodies.
This application is related to copending U. S. patent applications Serial No. 326,791, filed December 18, 1952, and Serial No. 270,748, filed February 8, 1952, the latter of which is a continuation-in-part of our U. S. patent application Serial No. 226,548, filed May 15, 1951, now abandoned.
A primary object of the invention is to provide a high temperature heat insulation shape which is handleable and is retained in its bonded form by a ceramic bonding material, and which contains a maximum number of minute pore spacings between the finest structural units, such spacings averaging effectively below the approximate mean free path of air.
An additional and more specific object is to provide a high temperature ceramic-bonded, handlcable heat insulation shape having a thermal conductivity factor k of approximately 0.4 B. t. u./sq. ft./hour/inch/ F. at 1000 F. mean.
Another object of the invention is to provide a ceramic-bonded, handleable heat insulation shape having a chiefly inorganic composition adapted for insulating service at temperatures ranging as high as 1500 F.
With the above and other objects and features in view, the invention consists in the improved thermal insulation material and method of manufacture which defined by the accompanying claims.
An important novel feature of the herein-disclosed thermal insulating shapes is that, in general, the preferred shapes having densities in the range between approxinrately 8 and 30 lbs/cu. ft. exhibit thermal insulating characteristics comparable to a correspondingly dimenstoned volume of free still air which has a thermal conductivity of 0.404 at 1000 F. mean; that is, have a thermal conductivity factor k of less than 0.55 at 1000 F. nie'an.
It is additionally of particular note that ceramic-bonded, handleable shapes of this invention in the density range indicated have thermal conductivity factors less than corresponding thermal conductivity factors of unb'ondeulocse mass mixtures of essentially the same composition as the bonded shapes, even after such mixtures have been consolidated by vibration to densities equallag-the density of the bonded, handleable shapes. Such a phenomenon is entirely unexpected since, in normal instances of bonding together loose insulating particles, the finally formed body has a higher k than a correspondingly dense mass of loose particles. This is usually clue, of course, to an increase of the solids conductivity of the mass.
The handleable insulating shapes made according to this invention exhibit the converse of this general consideration. For example, a ceramic-bonded, h-andleable rigid block of 9.2 lbs/cu. ft. density formed according ice to a hereinafter-disclosed procedure from a mixture comprising 5% by weight of amosite asbestos fibers, 60% by weigh of silica acrogel of approximately voids by volume, 30% by weight of zircon particles, and 5% of a temporary phenolic resin binder, was tested to have a k factor of 0.24 at 350 F. mean. A bulk mixture of the same proportions of the silica aerogel and Zircon of the type used in molding the ceramicbonded shape, was vibrated to a density of 9.2 lbs/cu. ft. and tested to have a k factor of 0.26 at 350 F. mean. The asbestos fiber of the block would also increas the solids conductivity, and would thus be expected to increase the k of the consolidated loose mass. It will be appreciated that a loose mass including fiber could probably not be vibrated to such a density, and retain homogeneity.
While this comparison of the thermal conductivities of a loose mass and a block formed in accordance with this invention clearly indicates better insulating characteristics in the block, it is of particular note that even lower thermal conductivities are obtained when the blocks are fabricated to higher densities than that indicated above. It has been found that blocks in the higher density range as, for example, of approximately 15 lbs/cu. ft, exhibit a lower thermal conductivity than blocks of the same composition molded to a density comparable to that set forth above, that is, approximately 9 or 10 lbs/cu. ft.
in our copending application Serial No. 270,748, there are disclosed and claimed thermal insulating shapes of comparable densities and thermal conductivity factors k to the ceramic-bonded insulating shapes of this invention. The preferred insulating shapes disclosed and claimed in our copending application essentially comprise a reinforcing skeleton or network of fine staple reinforcing fibers which may be either organic or inorganic, a substantial amount of particulate filler material having an ultimate structural unit with a diameter finer than millimicrons, such as aerogel or finely divided channel grade carbon black, and an inorganic or organic binder distributed throughout and holding the body in shape-retaining form. A suitable, disclosed binder for such blocks is a thcrmosetting phenolic-aldehyde resin. We have now found that insulating bodies having the heretofore-mentioned low densities and very low thermal conductivities may be fabricated without such an added binder, and are paricularly suitable for high temperature insulating service.
The preferred insulating shapes according to this in-- vention are composed essentially of a reinforcing skeleton or network of fine staple reinforcing fibers which may be either organic or inorganic; a substantial amount, and preferably at least 40% by weight of a particulate filler material having a porous or fibrillate structure, such as aerogels of, for example, silica, chromic oxide, thoria, magnesium hydrate, alumina, and mixtures thereof; and a ceramic binder having a composition comprising the heat reaction product of the ingredients initially present in the aerogel particles. For most kinds of insulation service, it is desirable to include in the composition finely divided opacifier materials.
The aerogel particles utilized to form the ceramicbonded insulating shapes of this invention are formed by a procedure generally similar to that outlined in the patent to Kistler, No. 2,093,454. The method generally comprises forming a gel, confining the resulting prodnot in a pressure vessel, applying heat thereto until the liquid in the gel has reached a temperature at which the surface dimension of the liquid is so small as to produce no substantial shrinkage of the gel when the liquid is allowed to evaporate, maintaining such a temperature, and then releasing the vapor from the pressure vessel at a rate insufficient to injure the gel. Dry, porous, fibrillate aerogel particles are thus obtained. The composition of these aerogels is substantially that of the materials forming the gel. For example, the composition is almost entirely silica when a silica gel is used as the starting material. The particles also evidently contain, however, impurities comparable to those found in the gel. While not limiting ourselves to any particular theory, it is considered that aerogel particles, such as silica aerogel, contain residual impurities in the form of soluble salts such as sodium sulphate and the like formed as reaction products during the formation of the gel. When the molded blocks of this invention formed by the processes as hereinafter disclosed are heated to a sufficient degree, a ceramic bond is formed in the block, probably due to a sintering of the aerogel or an incipient ceramic reaction between the aerogel and the salts present therein, or possibly both. This phenomenon is utilized to obtain the ceramic-bonded low conductivity insulating shapes of this invention.
Staple reinforcing fibers suitable for use in the insulating shapes of this invention may comprise such materials as various types of asbestos fibers of reinforcing grade, cleaned mineral fibers, fine diameter glass fibers, preferably pretreated, as with acid, to roughen the surface or otherwise to improve the surface adhesion characteristics, heat-stable organic fibers such as acrylic fibers which have been treated to render them heat-stable, or mixtures thereof.
The preferred inorganic fiber is a well-opened fine staple amosite asbestos classifying as to length not less than at least 25% longer than A". All of such fibers should preferably classify finer than 20 microns diameter and further finer than microns. The amount of fiber present in the bonded insulation shape is usually small but may vary over a considerable range, depending upon the strength requirements for the particular insulation service. The fiber content preferably comprises up to by weight, and normally approximately 5% by weight of the insulating shape is used.
As heretofore indicated, the low conductivity insulating shapes of this invention must contain a substantial amount of a particulate filler material having the structural and chemical characteristics which are necessary to this invention. The particulate filler material is exemplified by aerogels such as those of silica, chromic oxide, thoria, magnesium hydrate, alumina, etc., and mixtures thereof. Such aerogels in particle form have a straw stack agglomerate fibril structure, with the fibrils composing the ultimate or finest structural unit of diameter finer than 100 millimicrons. The average aerogel particles should embrace a total void or dead air space of 75-99% by volume, and may be treated to render them hydrophobic in nature.
The amount of particulate filler material of the above defined nature which must be utilized is dependent upon the nature of the insulating shape formed and its desired use. For many purposes, the insulating bodies may contain from 4095% by weight of such filler particles. When the shapes are to be utilized for high temperature insulation, the preferred proportion is approximately 40-75% by weight, and a substantial amount of opacitying material is used.
Below 150 F., the opacity of an aerogel, such as silica aerogel, is usually adequate for insulating against heat transfer by radiation. However, above this temperature, the insulating shape should be composed in part of finely divided opacifiers, preferably of inorganic composition. These opacifiers may be of the radiation reflective type, such as metallic aluminum or silicon powder; of the radiation absorbing type, such as powdered metals or finely divided pigments, as for example, chromium oxide; or of the radiation scattering type, such as zircon, titanium dioxide, or other materials of high index of rel to a density sufficient to form particles, fiber, opacifier,
fraction in the infrared. These opacifiers may advantageously be used as an opacifier for the aerogel fillers in amounts up to 125% by weight of the total aerogel particle content of the shape. It will be appreciated that the amount of opacifier required is usually determined by the severity of the radiation problem, which increases with the increase in temperature. Since the blocks of this invention are particularly adapted for high temperature use, the radiation problem will be serious and relatively large amounts of opacifier should be used.
As heretofore indicated, the ceramic binder utilized in the low conductivity insulating shapes of this inven tion does not require the addition of other than the aforesaid ingredients to the composition; that is, no binder materials are required in the finally fabricated insulating shape which are not present as part of the composition of the aerogel particles.
The ceramic bond of the herein disclosed-insulating shapes may be formed by either of two methods. In both methods the various components used to form the insulating shape are intimately mixed by any suitable mixing procedure to obtain a thorough dispersion and intermixing of all ingredients.
In the first method, aerogel particles, the fiber, and opacifier, if used, are intimately mixed to develop a particle-filled fibrous mass. This mass is then moisturized by treatment in a humidifying chamber. In the chamher, the mass is exposed to a gas with a relatively high humidity and an elevated temperature, for example, air with a relative humidity of 95% and a temperature of F. The mass is exposed to the humidified gas for a sufiicient time to enable it to adsorb some moisture, and preferably approximately 2-35% by weight of said particles. It will be appreciated that the amount of moisture required to be adsorbed is dependent upon that required to give the shape its green strength, that is, to enable the formation of an initial handleable green body upon molding, which in turn is dependent upon the density of the molded body. For example, green bodies having densities of approximately 13 lbs/cu ft., have been fabricated employing only approximately two percent moisture. The maximum amount of moisture which may be employed is dependent upon the consideration that the insulating characteristics of the final product must be obtained, and thus the aerogel structure may not be destroyed.
The resultant humidified or wetted mixture may then be pressed, with or without heat, to the desired shape and a handleable, self-sustaining green body. The final ceramic-bonded, handleable low conductivity insulating shape is then obtained by heating the thus formed shape for a time and at an elevated temperature sufiicient to develop the ceramic bond, apparently by a partial sintering and/or a reaction between the impurities present in the aerogel, as, for example, between the sodium sulphate and the silica itself, in a silica aerogel. This temperature should preferably be approximately 1000 F., and temperatures from approximately 600 to 1600 F. have been utilized successfully with silica aerogel compositions.
The second method for forming the ceramic-bonded insulating shapes of this invention is generally similar to the foregoing. In this procedure a mixture of aerogel and a thermally decomposable temporary binder is intimately mixed to obtain a particleloaded, fibrous network mass.
Any suitable temporary binder may be utilized which has the characteristics of rendering to the mass a handleable shape upon the intial forming and the capability of being burned out of the shape at the sintering temperature. Most organic binders, such as common thermosetting resins, as, for example, phenolor urea-formaldehyde, and common thermoplastic resins such as vinyl chloride, vinyl chloride-acetate copolymers, or silicons, have these desired characteristics. The temporary binder is utilized in an amount sufficient to render the initially formed shape handleable for all future manufacturing procedures, and should be capable of obtaining its shape-retaining form under the conditions utilized to obtain the initially formed shape.
When the temporary binder is utilized a light, fluffy mass is formed by intimately mixing the aerogel particles, fiber, and binder, preferably in dry particulate form. The mass is then subjected to sufficient heat and pressure to obtain the desired density and to set or cure the binder to its shape-retaining form. The thus formed temporarily bonded, handleable shape is then heated to a sufliciently high temperature to burn out the temporary binder and develop the ceramic bond as heretofore disclosed. It is of particular note that a substantially lower thermal conductivity is obtained in a burned out body formed in accordance with this procedure and containing a relatively large amount of thermally conductive opacifier particles than that found for the temporarily bonded body use in its formation. This is apparently due to the destruction of thermally conductive bridges of temporary binder between opacifier particles.
In either or both of the aforementioned procedures, the intimately mixed light and bulky mass can be molded and set to a shape of any desired conformation and density. Suitable green bodies may be obtained by molding the mass in a conventional press mold, utilizing suitable pressures and/or temperatures to either activate and develop a set for the temporary binder, or to develop a set in the moisturized shape. Such bodies may also be obtained by uniformly distributing, i. e. felting, and consolidating the fluffy mass in known manner and then heating the thus consolidated mass to obtain a handleable ape.
Excellent thermal insulating shapes have been produced according to this invention having densities in the range of 8 to 30 lbs/cu. ft. with thermal conductivities, or k factors, approximating 0.35 to 0.55 at 1000 F. mean. As heretofore indicated, the preferred insulating shapes have a thermal conductivity factor k of approximately 0.4 at 1000 F. mean; that is, the preferred shapes formed according to this invention have insulating characteristics comparable to free still air. Opacified shapes having the essentially inorganic compositions which are set forth above are adapted for insulating service for temperatures up to 1500 F. The ceramic-bonded insulating shapes have ample strength characteristics and handleability for subsequent insulating service. For example, a ceramicbonded insulating shape formed from a composition approximately comprising by weight of amosite fibers, 75% by weight of silica aerogel, by weight of zircon, and 5% by weight of thermosetting resin temporary binder, and having a density of 13 lbs./ cu. it. was found on test to develop a transverse modulus of rupture of approximately lbs./ sq. in.
The following are examples of various ceramic-bonded insulating shapes of low thermal conductivity, and their general method of preparation. It is understood, of course, that the compostion of, and methods for producing, these blocks are exemplary and are not to be considered to limit the invention to the particular compositions and operating conditions outlined. In all examples the indicated proportions of ingredients are in parts by weight.
Example I A strong, ceramic-bonded thermal insulating shape was formed by molding with sufficient heat and pressure to set the resin, an intimately dispersed mixture of:
Silica aerogel 55 Zircon 40 Amosite asbestos fiber 5 Phenol-formaldehyde resin 5 Example II was then heated for ap- A strong, ceramic-bonded thermal insulation shape was formed by humidifying, with air at F. and relative humidity, to a 10% moisture content an intimately dispersed mixture of:
Silica aerogel Zircon 40 Amosite asbestos fiber andthen molding a green body of this composition with suflicient pressure to obtain a handleable shape. The thus formed green" shape was heated for approximately one hour at 1200 F. to develop the desired ceramic bond. The ceramic-bonded shape obtained had a density of approximately 17 lbs./cu. ft. and a thermal conductivity factor k of 0.22 at 350 F. mean, and 0.4 at 1000 F.
mean.
In order to determine the characteristics of the bonding medium utilized in accordance with this invention, a series of insulating bodies having a density of approximately 20 lbs./ cu. ft. were molded from a humidilied mixture containing 85 parts of silica aerogel and 10 parts of zircon opacitier. Half of the blocks fabricated were fired at 1400 F. as herein disclosed, while the remainder were tested in an unfired condition. Standard test conditions indicated a modulus of rupture of approximately 13.4 lbs/cu. ft. for the unfired blocks, while the fired blocks were found to have a modulus of rupture of 24.0 lbs./cu. ft. A comparison of these moduli of rupture immediately indicates substantially greater strength in the fired blocks fabricated in accordance with this invention, which must be due to the bonding medium formed during the firing procedure.
it will be understood that the details given herein are for the purpose of illustration, not restriction, and that variations within the spirit of the invention are intended to be included in the scope of the appended claims.
What we claim is:
1. A ceramic-bonded. handleable insulating body having a density of less than approximately 30 lbs/cu. ft. and a thermal conductivity factor k of less than approximately 0.55 at l000 F. mean, comprising heat-stable, staple reinforcing fibers in amount sufficient to form a reinforcing skeleton up to approximately 15% by weight, approximately 40 to 95% by weight of inorganic aerogel particles containing a total void space of approximately 75 to 99% by volume, finely divided opacifier particles, and a ceramic binder distributed throughout said body essentially comprising the heat reaction product of the ingredients initially present in said aerogel particles.
2. A ceramic-bonded, light weight, handleable insulating body having a low thermal conductivity, which comprises hcat-stable, staple reinforcing fibers in amount sufficient to form a reinforcing skeleton up to approximately 15% by weight, approximately 40 to 95% by weight of inorganic aerogel particles. and a ceramic binder distributed throughout said body essentially comprising the heat reaction product of the ingredients initially present in said aerogel particles.
3. A ceramic-bonded, light weight, handleable insulating body having a low thermal conductivity, which comprises heat-stable, staple reinforcing fibers in amount sufficicnt to form a reinforcing skeleton up to approximately 15% by weight, approximately 40 to 95% by weight of inorganic aerogel particles, finely divided opacifier particles in amount up to approximately by weight of said aerogel particles, and a ceramic binder distributed throughout said body essentially comprising the heat reaction product of the ingredients initially present in said aerogel particles.
4. A ceramic-bonded, handleable insulating body having a density of less of less than approximately 0.55 at 1000" F. mean, which comprises heatstable, staple reinforcing fibers in amount sufficient to form a reinforcing skeleton up to approximately by weight, approximately 40 to 95% by weight of inorganic aerogel throughout said body essentially said aerogel particles.
5. A ceramic-bonded, handleable insulating body having a form a reinforcing skeleton up to approximately 15% approximately 40 to 95% by weight of inorganic aerogei particles, finely divided opacifier particles in amount up to approximately 125% by weight of said aerogel particles, and a ceramic binder distributed weight of silica aerogel particles,
6. A ceramic-bonded, light weight, handleable insulating body having a low thermal conductivity, which ent in said silica aerogel particles.
7. A ceramiebondcd, light weight, handleable insu- Iating body having a low thermal conductivity,
mately 15% by weight, approximately to by finely divided opacifier particles in amount up to approximately by weight of said aerogel particles, and
tributed throughout said body essentially comprising the heat reaction product of the ingredients initially present in said silica aerogel particles.
References Cited in the file of this patent UNITED STATES PATENTS
Claims (1)
1. A CERAMIC-BONDED, HANDLEABLE INSULATING BODY HAVING A DENSITY OF LESS THAN APPROXIMATELY 30 LBS./CU. FT AND A THERMAL CONDUCTIVITY FACTOR K OF LESS THAN APPROXIMATELY 0.55 AT 1000*F. MEAN, COMPRISING HEAT-STABLE STAPLE REINFORCING FIBERS IN AMOUNT SUFFICIENT TO FORM A REINFORCING SKELETON UP TO APPROXIMATELY 15% BY WEIGHT, APPROXIMATELY 40 TO 95% BY WEIGHT OF INORGANIC AEROGEL PARTICLES CONTAINING A TOTAL VOID SPACE OF APPROXIMATELY 75 TO 99% BY VOLUME, FINELY DIVIDED OPACIFIER PARTICLES, AND A CERAMIC BINDER DISTRIBUTED THROUGHOUT SAID BODY ESSENTIALLY COMPRISING THE HEAT REACTION PRODUCT OF THE INGREDIENTS INITIALLY PRESENT IN SAID AEROGEL PARTICLES.
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US326778A US2811457A (en) | 1952-12-18 | 1952-12-18 | Inorganic bonded thermal insulating bodies and method of manufacture |
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US3001362A (en) * | 1957-07-26 | 1961-09-26 | Russell Mfg Co | Insulator for rocket motor |
US3014872A (en) * | 1959-10-26 | 1961-12-26 | Gen Electric | Fibrous insulation |
US3041205A (en) * | 1959-04-01 | 1962-06-26 | Du Pont | Composition comprising colloidal silica and a water-soluble phosphorus compound and articles prepared therefrom and process of preparing such articles |
US3055831A (en) * | 1961-09-25 | 1962-09-25 | Johns Manville | Handleable heat insulation shapes |
US3176354A (en) * | 1960-03-25 | 1965-04-06 | Johns Manville | Method of applying a free flowing insulating fill material |
US3231401A (en) * | 1964-06-22 | 1966-01-25 | Carborundum Co | Refractory composition |
US3233697A (en) * | 1960-06-07 | 1966-02-08 | Owens Corning Fiberglass Corp | Muffler internally coated with highly refractory fibers |
US3766000A (en) * | 1970-03-02 | 1973-10-16 | Mc Donnell Douglas Corp | Low thermal expansion composites |
US3870595A (en) * | 1969-10-06 | 1975-03-11 | Foseco Int | Protection of turbine casings |
US3904427A (en) * | 1969-10-06 | 1975-09-09 | Foseco Int | Protection of turbine casings |
JPS5140088B1 (en) * | 1970-06-10 | 1976-11-01 | ||
US3989533A (en) * | 1972-04-10 | 1976-11-02 | Foseco International Limited | Composition for use in forming heat insulating hot top liners and method of making same |
US4041199A (en) * | 1974-01-02 | 1977-08-09 | Foseco International Limited | Refractory heat-insulating materials |
JPS5486853A (en) * | 1977-12-07 | 1979-07-10 | Wacker Chemie Gmbh | Method of improving heat retainer made from silicon dioxide by dry process |
US4264660A (en) * | 1975-11-04 | 1981-04-28 | Volkswagenwerk Aktiengesellschaft | Thermally insulated composite article |
DE3020326A1 (en) * | 1980-05-29 | 1981-12-03 | Grünzweig + Hartmann und Glasfaser AG, 6700 Ludwigshafen | DEVICE FOR THE HEAT-INSULATING STORAGE OF AN ELECTRIC HEATER, IN PARTICULAR FOR A RADIATION-HEATED COOKING PLATE, AND A HEAT-INSULATING PLATE THEREFOR, AND METHOD FOR THE PRODUCTION THEREOF |
USH200H (en) | 1984-06-27 | 1987-01-06 | The United States Of America As Represented By The United States Department Of Energy | High temperature structural insulating material |
EP0290791A1 (en) * | 1987-05-12 | 1988-11-17 | Ruhrkohle Aktiengesellschaft | Hollow ceramic plug for coke oven doors |
US4943465A (en) * | 1988-10-24 | 1990-07-24 | The Carborundum Company | Thermal insulating, high temperature resistant composite |
US5804294A (en) * | 1995-08-02 | 1998-09-08 | The Morgan Crucible Company Plc | Microporous insulation for data recorders and the like |
US5948314A (en) * | 1994-10-20 | 1999-09-07 | Hoechst Aktiengesellschaft | Composition containing an aerogel, method of producing said composition and the use thereof |
US6045718A (en) * | 1995-08-02 | 2000-04-04 | The Morgan Crucible Company Plc | Microporous insulation for data recorders and the like |
US20050155371A1 (en) * | 2004-01-15 | 2005-07-21 | Electronic Controls Design, Inc. | Thermal insulation for electronic devices |
WO2012000585A1 (en) * | 2010-07-02 | 2012-01-05 | Rockwool International A/S | Insulating construction element, use of an insulating construction element and method for manufacturing an insulating construction element |
US20140361209A1 (en) * | 2011-05-26 | 2014-12-11 | Electricite De France | Aerogel-based material that is super-insulating at atmospheric pressure |
WO2023148082A1 (en) | 2022-02-03 | 2023-08-10 | Empa Eidgenössische Materialprüfungs- Und Forschungsanstalt | Binder-free bulk silica aerogel material, method of producing the same and uses thereof |
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Cited By (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3001362A (en) * | 1957-07-26 | 1961-09-26 | Russell Mfg Co | Insulator for rocket motor |
US3041205A (en) * | 1959-04-01 | 1962-06-26 | Du Pont | Composition comprising colloidal silica and a water-soluble phosphorus compound and articles prepared therefrom and process of preparing such articles |
US3014872A (en) * | 1959-10-26 | 1961-12-26 | Gen Electric | Fibrous insulation |
US3176354A (en) * | 1960-03-25 | 1965-04-06 | Johns Manville | Method of applying a free flowing insulating fill material |
US3233697A (en) * | 1960-06-07 | 1966-02-08 | Owens Corning Fiberglass Corp | Muffler internally coated with highly refractory fibers |
US3055831A (en) * | 1961-09-25 | 1962-09-25 | Johns Manville | Handleable heat insulation shapes |
US3231401A (en) * | 1964-06-22 | 1966-01-25 | Carborundum Co | Refractory composition |
US3870595A (en) * | 1969-10-06 | 1975-03-11 | Foseco Int | Protection of turbine casings |
US3904427A (en) * | 1969-10-06 | 1975-09-09 | Foseco Int | Protection of turbine casings |
US3766000A (en) * | 1970-03-02 | 1973-10-16 | Mc Donnell Douglas Corp | Low thermal expansion composites |
JPS5140088B1 (en) * | 1970-06-10 | 1976-11-01 | ||
US3989533A (en) * | 1972-04-10 | 1976-11-02 | Foseco International Limited | Composition for use in forming heat insulating hot top liners and method of making same |
US4041199A (en) * | 1974-01-02 | 1977-08-09 | Foseco International Limited | Refractory heat-insulating materials |
US4264660A (en) * | 1975-11-04 | 1981-04-28 | Volkswagenwerk Aktiengesellschaft | Thermally insulated composite article |
JPS5830271B2 (en) * | 1977-12-07 | 1983-06-28 | ワツカ−・ヒエミ−・ゲゼルシヤフト・ミツト・ベシユレンクテル・ハフツング | Improvement method for heat insulator manufactured from silicon dioxide by dry method |
JPS5486853A (en) * | 1977-12-07 | 1979-07-10 | Wacker Chemie Gmbh | Method of improving heat retainer made from silicon dioxide by dry process |
DE3020326A1 (en) * | 1980-05-29 | 1981-12-03 | Grünzweig + Hartmann und Glasfaser AG, 6700 Ludwigshafen | DEVICE FOR THE HEAT-INSULATING STORAGE OF AN ELECTRIC HEATER, IN PARTICULAR FOR A RADIATION-HEATED COOKING PLATE, AND A HEAT-INSULATING PLATE THEREFOR, AND METHOD FOR THE PRODUCTION THEREOF |
USH200H (en) | 1984-06-27 | 1987-01-06 | The United States Of America As Represented By The United States Department Of Energy | High temperature structural insulating material |
EP0290791A1 (en) * | 1987-05-12 | 1988-11-17 | Ruhrkohle Aktiengesellschaft | Hollow ceramic plug for coke oven doors |
US4943465A (en) * | 1988-10-24 | 1990-07-24 | The Carborundum Company | Thermal insulating, high temperature resistant composite |
US5948314A (en) * | 1994-10-20 | 1999-09-07 | Hoechst Aktiengesellschaft | Composition containing an aerogel, method of producing said composition and the use thereof |
US5804294A (en) * | 1995-08-02 | 1998-09-08 | The Morgan Crucible Company Plc | Microporous insulation for data recorders and the like |
US6045718A (en) * | 1995-08-02 | 2000-04-04 | The Morgan Crucible Company Plc | Microporous insulation for data recorders and the like |
US20050155371A1 (en) * | 2004-01-15 | 2005-07-21 | Electronic Controls Design, Inc. | Thermal insulation for electronic devices |
US6993927B2 (en) | 2004-01-15 | 2006-02-07 | Electronic Controls Design, Inc. | Thermal insulation for electronic devices |
WO2012000585A1 (en) * | 2010-07-02 | 2012-01-05 | Rockwool International A/S | Insulating construction element, use of an insulating construction element and method for manufacturing an insulating construction element |
US20140361209A1 (en) * | 2011-05-26 | 2014-12-11 | Electricite De France | Aerogel-based material that is super-insulating at atmospheric pressure |
US10604642B2 (en) * | 2011-05-26 | 2020-03-31 | Electricite De France | Aerogel-based material that is super-insulating at atmospheric pressure |
WO2023148082A1 (en) | 2022-02-03 | 2023-08-10 | Empa Eidgenössische Materialprüfungs- Und Forschungsanstalt | Binder-free bulk silica aerogel material, method of producing the same and uses thereof |
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