US3324500A - Scouring pad - Google Patents
Scouring pad Download PDFInfo
- Publication number
- US3324500A US3324500A US413619A US41361964A US3324500A US 3324500 A US3324500 A US 3324500A US 413619 A US413619 A US 413619A US 41361964 A US41361964 A US 41361964A US 3324500 A US3324500 A US 3324500A
- Authority
- US
- United States
- Prior art keywords
- scouring
- water
- ammonium salt
- particles
- coated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000009991 scouring Methods 0.000 title claims description 67
- 239000002245 particle Substances 0.000 claims description 107
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 89
- 150000003863 ammonium salts Chemical class 0.000 claims description 71
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 54
- 229910021529 ammonia Inorganic materials 0.000 claims description 44
- 238000000576 coating method Methods 0.000 claims description 38
- 239000011248 coating agent Substances 0.000 claims description 37
- 239000000463 material Substances 0.000 claims description 29
- 238000010521 absorption reaction Methods 0.000 claims description 8
- 208000035155 Mitochondrial DNA-associated Leigh syndrome Diseases 0.000 claims 2
- 208000003531 maternally-inherited Leigh syndrome Diseases 0.000 claims 2
- 239000003599 detergent Substances 0.000 description 39
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical group [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 17
- 239000000344 soap Substances 0.000 description 17
- 239000001099 ammonium carbonate Substances 0.000 description 16
- 239000000203 mixture Substances 0.000 description 15
- 239000000243 solution Substances 0.000 description 15
- 235000012501 ammonium carbonate Nutrition 0.000 description 13
- 210000002268 wool Anatomy 0.000 description 11
- 229910000831 Steel Inorganic materials 0.000 description 10
- 239000010959 steel Substances 0.000 description 10
- 239000002253 acid Substances 0.000 description 9
- 239000000853 adhesive Substances 0.000 description 9
- 230000001070 adhesive effect Effects 0.000 description 9
- 239000000337 buffer salt Substances 0.000 description 9
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- 239000000835 fiber Substances 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 7
- 239000000839 emulsion Substances 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 5
- 239000005695 Ammonium acetate Substances 0.000 description 5
- VAYOSLLFUXYJDT-RDTXWAMCSA-N Lysergic acid diethylamide Chemical compound C1=CC(C=2[C@H](N(C)C[C@@H](C=2)C(=O)N(CC)CC)C2)=C3C2=CNC3=C1 VAYOSLLFUXYJDT-RDTXWAMCSA-N 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 5
- -1 ammonium acetate Chemical class 0.000 description 5
- 229940043376 ammonium acetate Drugs 0.000 description 5
- 235000019257 ammonium acetate Nutrition 0.000 description 5
- 210000003298 dental enamel Anatomy 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- 229910052700 potassium Inorganic materials 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- 229960003975 potassium Drugs 0.000 description 5
- 238000013268 sustained release Methods 0.000 description 5
- 239000012730 sustained-release form Substances 0.000 description 5
- 229920006385 Geon Polymers 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 235000019270 ammonium chloride Nutrition 0.000 description 4
- 238000010411 cooking Methods 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 238000007654 immersion Methods 0.000 description 4
- 239000002609 medium Substances 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 3
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 3
- 239000003240 coconut oil Substances 0.000 description 3
- 235000019864 coconut oil Nutrition 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000004519 grease Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000010935 stainless steel Substances 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 239000003760 tallow Substances 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910000881 Cu alloy Inorganic materials 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229920000914 Metallic fiber Polymers 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 239000000020 Nitrocellulose Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 229920001986 Vinylidene chloride-vinyl chloride copolymer Polymers 0.000 description 2
- 229920006387 Vinylite Polymers 0.000 description 2
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 2
- 239000002671 adjuvant Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical group O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 235000013824 polyphenols Nutrition 0.000 description 2
- 229920002689 polyvinyl acetate Polymers 0.000 description 2
- 239000011118 polyvinyl acetate Substances 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000003871 sulfonates Chemical class 0.000 description 2
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 2
- ICLYJLBTOGPLMC-KVVVOXFISA-N (z)-octadec-9-enoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCC\C=C/CCCCCCCC(O)=O ICLYJLBTOGPLMC-KVVVOXFISA-N 0.000 description 1
- YAKZAWBQNVBQSE-UHFFFAOYSA-N 1-ethenylpyrrolidin-2-one;ethyl prop-2-enoate Chemical compound CCOC(=O)C=C.C=CN1CCCC1=O YAKZAWBQNVBQSE-UHFFFAOYSA-N 0.000 description 1
- GXJQMKFJQFGQKV-KHPPLWFESA-N 2-[methyl-[(z)-octadec-9-enoyl]amino]ethanesulfonic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N(C)CCS(O)(=O)=O GXJQMKFJQFGQKV-KHPPLWFESA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- 229910000906 Bronze Inorganic materials 0.000 description 1
- 241001398967 Colonia Species 0.000 description 1
- 229920004934 Dacron® Polymers 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 241000982822 Ficus obtusifolia Species 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- 241000618809 Vitales Species 0.000 description 1
- FVFJGQJXAWCHIE-UHFFFAOYSA-N [4-(bromomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CBr)C=C1 FVFJGQJXAWCHIE-UHFFFAOYSA-N 0.000 description 1
- CXDBXTHJTZQPOJ-UHFFFAOYSA-M [Na+].CC=C.CC=C.CC=C.CC=C.[O-]S(=O)(=O)C1=CC=CC=C1 Chemical compound [Na+].CC=C.CC=C.CC=C.CC=C.[O-]S(=O)(=O)C1=CC=CC=C1 CXDBXTHJTZQPOJ-UHFFFAOYSA-M 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- 229940056585 ammonium laurate Drugs 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- VJCJAQSLASCYAW-UHFFFAOYSA-N azane;dodecanoic acid Chemical compound [NH4+].CCCCCCCCCCCC([O-])=O VJCJAQSLASCYAW-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- HCDIREGKVCNEFC-UHFFFAOYSA-N formaldehyde;2-phenylphenol Chemical compound O=C.OC1=CC=CC=C1C1=CC=CC=C1 HCDIREGKVCNEFC-UHFFFAOYSA-N 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- ZHALDANPYXAMJF-UHFFFAOYSA-N octadecanoate;tris(2-hydroxyethyl)azanium Chemical compound OCC[NH+](CCO)CCO.CCCCCCCCCCCCCCCCCC([O-])=O ZHALDANPYXAMJF-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 150000002889 oleic acids Chemical class 0.000 description 1
- 150000004028 organic sulfates Chemical class 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- 239000001508 potassium citrate Substances 0.000 description 1
- 229960002635 potassium citrate Drugs 0.000 description 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
- 235000011082 potassium citrates Nutrition 0.000 description 1
- ONQDVAFWWYYXHM-UHFFFAOYSA-M potassium lauryl sulfate Chemical compound [K+].CCCCCCCCCCCCOS([O-])(=O)=O ONQDVAFWWYYXHM-UHFFFAOYSA-M 0.000 description 1
- 229940116985 potassium lauryl sulfate Drugs 0.000 description 1
- 229940096992 potassium oleate Drugs 0.000 description 1
- 229940114930 potassium stearate Drugs 0.000 description 1
- MLICVSDCCDDWMD-KVVVOXFISA-M potassium;(z)-octadec-9-enoate Chemical compound [K+].CCCCCCCC\C=C/CCCCCCCC([O-])=O MLICVSDCCDDWMD-KVVVOXFISA-M 0.000 description 1
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- DCBSHORRWZKAKO-UHFFFAOYSA-N rac-1-monomyristoylglycerol Chemical class CCCCCCCCCCCCCC(=O)OCC(O)CO DCBSHORRWZKAKO-UHFFFAOYSA-N 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 230000011664 signaling Effects 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 235000011083 sodium citrates Nutrition 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229940074404 sodium succinate Drugs 0.000 description 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- IZWPGJFSBABFGL-GMFCBQQYSA-M sodium;2-[methyl-[(z)-octadec-9-enoyl]amino]ethanesulfonate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC(=O)N(C)CCS([O-])(=O)=O IZWPGJFSBABFGL-GMFCBQQYSA-M 0.000 description 1
- VPNZAQYBGUPBSV-UHFFFAOYSA-M sodium;2-pentadecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O VPNZAQYBGUPBSV-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 229940117013 triethanolamine oleate Drugs 0.000 description 1
- 229940029614 triethanolamine stearate Drugs 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L17/00—Apparatus or implements used in manual washing or cleaning of crockery, table-ware, cooking-ware or the like
- A47L17/04—Pan or pot cleaning utensils
- A47L17/08—Pads; Balls of steel wool, wire, or plastic meshes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/049—Cleaning or scouring pads; Wipes
Definitions
- the present invention relates to an improved scouring pad capable of releasing ammonia upon use. More particularly, it relates to a scouring pad which retains its capability of releasing ammonia upon re-use.
- Scouting articles such as steel wool pads are widely used as household scouring agents for the cleansing of soiled cooking utensils and the like.
- this scouring it has :been found desirable to have an ammonia containing product present to provide an ammoniacal odor when the scouring pad is contacted with water and to aid in the removal of grease.
- ammonia-containing detergent compositions have been available for use with scouring pads. Unfortunately, when such compositions are used in an aqueous solution, the water rapidly dissolves the ammonium salt to release the ammonia prior to the end of the useful life of the product.
- a scouring pad having water-soluble ammonium salt particles coated with a water-insoluble rupturable film provides an ammoniacal odor when the film is abraded or ruptured by using the pad in a scouring operation and thereafter provides a sustained release of ammonia vapor. Accordingly, the ammoniacal odor is available during substantially all of the time that the product is in use and, additionally, ammonia is available to aid in the removal of oily types of soil and grime from many surfaces.
- the scouring pad of the present invention comprises a body of fibrous scouring material containing a plurality of water-soluble ammonium salt particles having a water insoluble rupturable outer coating.
- coated ammonium salt particles can be combined with an aqueous-containing detergent medium which normally tends to decompose the ammonium salts and release ammonia.
- coated ammonium salt particles can be combined with an aqueous-containing detergent medium and used as an integral part of a scouring pad without any release of ammonia vapor until the film on the ammonium salt particles has been ruptured or abraded by the scouring action.
- the coated ammonia salt particles and aqueous-containing detergent medium are intimately mixed in the scouring pad. Since the ammonia is gradually released, it serves as a signaling device to indicate loss of detergent power.
- the fibrous scouring materials useful in the present invention are any of those commonly used for scouring pads such as the metallic fibers and synthetic organic fibers well known in the art.
- Typical metallic fibers are steel wool, stainless steel fibers, copper fibers and copper alloy fibers, e.g. bronze and brass.
- steel Wool and stainless steel fibers are employed since the ammonia released could possibly cause corrosion by reaction with copper or copper alloys.
- Typical synthetic organic fibers that may be used include nylon, polyester fibers such as Dacron, acrylic fibers such as Acrilanj rayon and other well known materials of similar types.
- the water-soluble ammonium salts to be employed in the present invention for producing a sustained release of ammonia vapor are the crystalline ammonium compounds which are characterized by their solubility in water and the release of ammonia in an alkaline solution.
- a particularly suitable water-soluble ammonium salt is ammonium carbonate since in the presence of water, ammonia vapor is readily released.
- ammonium carbonate refers to the ammonium carbonate of commerce which is a mixture of ammonium bicarbonate and ammonium carb'amate (e.g. see Merck Index, Seventh Edition).
- ammonium salts which may be employed are the ammonium salts of strong acids such as ammonium chloride, ammonium sulfate, ammonium phosphate and the ammonium salts of weak acids such as ammonium acetate and ammonium bicarbonate. Since the ammonia vapor is released in an alkaline solution, the ammonium salts which are acid in solution such as the ammonium salts of strong acids and some ammonium salts of weak acids, e.g. ammonium acetate, require the presence of an alkaline buffer salt to provide sufficient alkalinity for the release of the ammonia. Of course, an alkaline buffer salt is not necessary where ammonium salts which are alkaline in solution, e.g.
- alkaline buffer salts such as sodium carbonate, potassium carbonate, sodium acetate, potassium acetate, sodium citrate and potassium citrate, and organic alkaline buffer salts such as sodium succinate.
- the particle size of the crystalline ammonium salts is not critical by itself, it can influence the rate of release of ammonia, the sustained release of ammonia and the arrangement of the particles in scouring pads.
- the particle size of the ammonium salts Will range from about 20 to 30 mils in diameter to about to mls, although coarser or finer material may be used. The finer particles will release ammonia quickly whereas the larger particles will provide a more sustained release of ammonia.
- the water-soluble ammonium salt component of the present invention provides ammonia to aid in the removal of grease and grime during each scouring operation.
- the Water insoluble coating materials used to coat all surfaces of the ammonium salt particles are water insoluble substances which form a film over the ammonium salt particles.
- the film is characterized in that it is readily ruptured or abraded by scouring and is impermeable or substantially impermeable to water and prevents transmission of moisture to the ammonium salt particles prior to rupture, thus preventing or inhibiting the premature release of ammonia by any moisture in the scouring pad prior to usage.
- the water insoluble films that have been found to be most useful are those provided by film forming solutions of plastics. Since the ammonium salts will release ammonia in the presence of water as well as at elevated temperatures, the plastic solutions should not contain water nor should heat be required for drying to form the water-insoluble films. After the ammonium salt particles are coated with the plastic solution, room temperature curing should be sufficient for the film formation;
- Suitable Water-insoluble coating materials for use in coating the water-soluble ammonium salt particles of the present invention are vinyls such as polyvinyl chlorides (Geon 151, Geon 251,, Geon 351, Pliovic Latex 300. and Exon 700 XR59), vinylidene chloride-vinyl chloride copolymers (Saran), and vinyl chloride-vinyl acetate copolymers (Vinylite VMCH, Vinylite VYHH and Geon 200 X These materials provide films which have chemical resistance to alkalies and have negligible water absorption, i.e. the films are substantially impermeable to Water.
- vinyls such as polyvinyl chlorides (Geon 151, Geon 251,, Geon 351, Pliovic Latex 300. and Exon 700 XR59), vinylidene chloride-vinyl chloride copolymers (Saran), and vinyl chloride-vinyl acetate copolymers (Vinylite VMCH, Vinylite
- alkyd resins having alkali resistance and water absorption of less than 0.5% after 24 hour immersion at 25 C.
- suitable materials are alkyd resins having alkali resistance and water absorption of less than 0.5% after 24 hour immersion at 25 C. such as made from anhydrides and a polybasic alcohol (Glyptal 2468); polystyrene having alkali resistance and Water absorption of from about 0.04 to 0.06% after 24 hour immersion at 25 C.; and polymethyl methacrylates having alkali resistance and water absorption of from about 0.3 to 0.4% after 24 hour immersion at 25 C.
- the films of these materials are considered to be substantially impermeable to water.
- Cellulosic plastics such as cellulose acetate and cellulose nitrate have rather high moisture absorption capacities but are useful in certain applications.
- paints containing Cellulosic plastics provide a very satisfactory film for the ammonium salt particles, e..g. Krylon Royal Blue No. 1901 Spray Enamel, Krylon, Inc., Philadelphia, Pa. according to the following composition:
- Non-volatile Cellulose nitrate 11.80 Coconut oil modified alkyd. Dioctyl phthalate. Volatile Ketones, esters, alcohols, aromatic hydrocarbons, aliphatic hydrocarbons 45.60 Propellant Halogenated hydrocarbon 40.00
- Phenolics such as phenol formaldehyde form a film having a low moisture absorption, i.e. about 0.1 to 0.2% after 24 hour immersion at 25 C. and are particularly useful in detergent-free systems since some types of detergent may weaken the coating.
- a suitable phenolic coating is the following phenol formaldehyde base for paints:
- a water insoluble adhesive may be employed to hold the coated ammonium salt particles to the fibrous scouring material.
- Any suitable adhesive composition which does not react with the water insoluble coating material or the ammonium salt and can withstand repeated wettings can be used.
- Typical suitable cements are synthetic polymer based emulsion binders such as polyvinyl acetate emulsions (Elvacet, Vinac) which form Water insoluble bonds after water has evaporated from the emulsion.
- Other suitable emulsion binders are ethyl acrylate emulsions (Rhoplex B-15) and vinyl pyrrolidone-ethyl acrylate emulsions ('Pelectron 130).
- Non-solvent containing adhesives which are set by specific catalysts, e.g., epoxy resins cured with polyamines are also useful.
- specific catalysts e.g., epoxy resins cured with polyamines
- the choice of adhesive will be somewhat dependent on the nature of the fibrous scouring material and the water insoluble coating material used and should usually be selected for the greatest degree of adhesion under the conditions of use.
- the detergents which may be used are selected from the group consisting of anionic and non-ionic detergents.
- Suitable anionic detergents are well known and include alkali metal and alkaline earth salts of various organic sulfates and sulfonates such as the higher alkyl aryl sulfonates, e.g., the sulfonates of alkylated benzene, toluene, cresol, naphthalene and the like in which the alkyl group contains from about 10 to 18 carbon atoms, typified by sodium pentadecyl benzene sulfonate and sodium tetrapropylene benzene sulfonate; higher fatty alcohol sulfates such as potassium lauryl sulfate and the lithium salt of sulfated alcohols derived from coconut oil by reduction; sulfated higher fatty acid mono
- Suitable non-ionic detergents include the water-soluble ethyl oxide condensates of water insoluble (molecular weight 900 to 3,400) polypropylene glycols (Pluronics); higher fatty acid alkanolamides such as lauric monoand diethanolamide; and the ethylene oxide condensates of alkyl phenols such as nonyl phenol condensed with from 6 to 16 mols of ethylene oxide.
- inorganic builder salts such as pentasodium tripolyphosphate, tetrasodium pyrophosphate and the like may be employed to supplement or replace the anionic or non-ionic detergents but it is preferred to utilize some detergent too.
- the detergent composition can serve as an alkaninity adjusting agent for those ammonium salt particles which are acid in solution.
- ammonium acid salts are employed in conjunction with anionic detergent salts or non-ionic detergents and inorgaic builder salts it is not necessary to employ alkaline buffer salts if the detergent system is characterized by a pH of from about 8 to about 12.
- adjuvants which are known in the detergent art. Perfumes, coloring agents, fluorescent brighteners, bleaches, foam enhancing additives, antibacterial and fungicidal compounds and rust preventing materials may be employed. If stable they may be formulated with the detergent or may be separately added, as desired. It is to be understood that the adjuvants employed will not materially affect the water insoluble coating on the ammonium salts.
- the water insoluble coating material solutions may be applied to the ammonium salt particles in any manner suitable for coating particles.
- One method by which the water-soluble ammonium salt particles may be cated with the water insoluble coating material solutions is by first placing the ammonium salt particles on a vibrating feeder. While the particles are bouncing on the feeder they are coated with the plasticized solution at room temperature. If desired, the plasticized solution may contain some pigment so that one can visually determine when the particles have been completely coated. The resulting coated particles are dried at ambient temperature and a water insoluble film encapsulates the water-soluble ammonium salt particles. Additionally, the water-soluble ammonium salt particles may be coated with the water-insoluble coating material by dipping the particles into a plastic film forming solution.
- the water-soluble ammonium salt particles are immersed or dipped in the film forming solution and then placed on a vibrating screen to drain, dry and set the coating.
- the coating material may be applied by various other methods useful for coating particles such as a fluidized coating bed where the ammonium salt particles are placed in a coating unit chamber and coated with steams of coating solution while suspended in the chamber by air currents.
- the water insoluble film encapsulating the ammonium salt particles should be thin enough to be ruptured by scouring action but not so thick that normal scouring would not abrade or rupture the film.
- the coated ammonium salt particles may have a water insoluble film in thickness of from about 0.5 to mils and preferably about 4 to 6 mils.
- the individual ammonium salt particles may have film coatings of different thicknesses.
- both the particle size of the ammonium salts and the film thickness can vary and influence the sustained release of ammonia.
- the alkaline buffer salt-s are preferably separately coated with the same water insoluble coating materials.
- the scouring pads of the present invention can have any desired shape and form. It will be apparent to those skilled in the art that these articles may be prepared by any typical method such as by coating one face of a fibrous scouring material strip with a water insoluble adhesive and coated ammonium salt particles or coating one face with a detergent paste containing the coated ammonium salt particles and rolling up the strip with the coated face on the inside and compressing to impart a desired shape and form. Additionally, the strip may be loaded with the adhesive and coated ammonium salt particles, rolled and pressed to form a pad and coat one or both faces of the pad with the detergent paste and coated ammonium salt particles.
- the scouring articles have a slight ammonia odor after formation of the pads, and when used in conjunction with dishwater in the course of scouring, the desired ammoniacal odor is released during each use as the water insoluble film is abraded or ruptured by the fibrous material such as steel wool.
- FIG. 1 shows a pad which has been compressed to make a form-retaining pad of pillow-shape in which a narrow strip along each edge is permanently crimped While the center portion remains relatively fluffy;
- FIG. 2 is a frag mentary sectional view drawn to a larger scale along the line 2--2 of FIG. 1; and
- FIG. 3 shows an end view of the pad coated on a face.
- the pad 11 has a narrow crimped border 12 around its edges, thus enabling the pad to maintain its shape.
- the pad 11 is formed with a water insoluble adhesive coating 13 containing coated ammonium salt particles 14 inside the pad.
- the pad 11 may have one or both faces of the pad coated with a detergent paste 15 containing coated ammonium salt particles 14.
- the instant coated ammonium salt particles are employed in a small but effective amount sufiicient to provide an ammoniacal odor during scouring in the presence of an aqueous medium.
- the exact minimum amount necessary to such action, as well as the aid in grease cutting action, is dependent upon the fibrous scouring material employed, the size of the particles, the thickness of the coating film, arrangement of the particles and the types and amount of other constituents in the pad.
- very small amounts may suflice, e.g. as little as 0.01% by weight of the steel Wool, whereas in the case of scouring pads containing a detergent system increased proportions may be required.
- the coated ammonium salt particles in a scouring pad will vary in particle size and film thickness and be distributed through out the pad with the majority of the larger particles or thicker coated particles being in the core of the pad. Suitable proportions will be illustrated by the examples hereinafter set forth.
- Example I Commercial ammonium carbonate lumps are reduced to particles which passed through a No. 10 US. standard mesh sieve but remained on a No. sieve. The particles are then placed on a vibrating feeder. While bouncing on the vibrating feeder, the ammonium carbonate particles are sprayed and thoroughly coated with Krylon Royal Blue No. 190 1 Spray Enamel. An aqeuous solution (32% solids) of a mixture of potassium and sodium soaps is partially dried to provide a soap paste containing about 40% moisture. The soap is a 50:50 coco:tallow soap in which the saponifying alkali metal is a 9:1 mixture of potassium and sodium.
- the pads When used to scour solid cooking utensils, the pads release ammonia vapor during use in the wash water. After drying-out, the pads provide the same results in subsequent usages.
- the coated ammonium carbonate particles In storage, prior to use and between each use, the coated ammonium carbonate particles do not release ammonia although they are carried in a soap system containing moisture which would normally tend to cause the ammonia vapor to be released.
- Example 11 Spherical commercial ammonium carbonate particles having a particle size from about to 50 mils in diameter are placed on a vibrating feeder. The ammonium carbonate particles are thoroughly coated by spraying with Krylon Royal Blue No. 1901 Spray Enamel to provide coated ammonium carbonate particles encapsulated in a film having a thickness of about 4 to 6 mils after drying at room temperature. An aqueous solution solids) of a blend of 69% sodium soap (20% coconut oil:80% tallow) and 31% sodium. N-methyl N-oleoyl taurate is partially dried to provide a detergent paste containing about 2 5% moisture.
- the pads When used to scour cooking vessels and kitchen utensils, the pads release ammonia vapor during use in the wash water. The pads also release ammonia during subsequent usage.
- Example III Spherical commercial ammonium carbonate particles having a particle size of about 50 mils in diameter are separated into two batches. Each batch is separately placed on a vibrating feeder and thoroughly coated by spraying with Krylon Royal Blue No. 1901 Spray Enamel. One batch of ammonium salt particles are coated until they are encapsulated in a film having a thickness of about 2 to 3 mils and the other batch of ammonium salt particles are coated until they are encapsulated in a film having a thickness of about 5 to 7 mils.
- Example I 8 gramsof the soap paste of Example I and 4 grams of each batch of coated ammonium salt particles are intimately mixed and spread along one face of a steel Wool strip of designated weight (e.g. 25 or 27 grams) and rolled as set forth in Example I. These scouring pads exhibit the same ammonia releasing ability as those of Examples I and II.
- Example IV Ammonium chloride particles having a particle size of about 50 milsin diameter are immersed in a vinylidene chloridevinyl chloride copolymer (Saran) coating solution and then placed on a vibrating screen to drain and dry at room temperature.
- the film on the dry particles has a thickness of about 5 or 6 mils.
- Sodium carbonate particles of about 50 mils in diameter are coated as set forth above to provide them with a film having a thickness of about 3 or 4 mils.
- Example V Ammonium acetate particles having a particle size from about 30 to 50 mils in diameter are spray coated with Krylon Royal Blue No. 1901 Spray Enamel as set forth in Example I. Twenty-five parts of coated ammonium acetate particles are intimately mixed in a detergent paste consisting of 25 parts of sodium dodecyl benzene sulfonate, 25 parts of the diethanolamide of coconut oil fatty acids, 43 parts of pentasodium tripolyphosphate and 7 parts of sodium meta silicate.
- a scouring pad which during successive scouring operations in the presence of water is adapted to controllably release ammonia comprising a body of fibrous scouring material containing a plurality of water-soluble ammonium salt particles, the particle sizes of which are distributed throughout the range from about mils to about 130 mils, said water-soluble ammonium salt particles having a water insoluble rupturable outer coating providing a film substantially impermeable to water absorption, said film being from about 0.5 mil to about 10 mils thick, the coated ammonium salt particles being at least about 0.01
- coated ammonium salt particles being adapted to release ammonia in the presence of water when the outer coating is ruptured during a scouring operation, and said coated ammonium salt particles being present in variant particle sizes and coating thicknesses so that ammonia is controllably released during sucessive scouring operations.
- a scouring pad according to claim 1 including a plurality of water-soluble alkaline buffer salt particles having a water insoluble rupturable outer coating, and a water insoluble adhesive composition adherent to a surface of the fibrous scouring material and the water insoluble outer coating, thereby holding the coated watersoluble ammonium salt particles and the coated alkaline buffer salt particles to the fibrous scouring material until the outer coatings of said particles are ruptured during a scouring operation whereby ammonia is released in the presence of water.
- a scouring pad according to claim 1 wherein the water-soluble ammonium salt particles are commercial ammonium carbonate particles having a particle size from about 30 mils to about 50 mils, encapsulated in a water insoluble rupturable outer coating providing a film from about 4 mils to about 6 mils thick, and including a watersoluble aqueous soap paste, said soap paste being a mixture of potassium and sodium soaps in which the soap is a 50 coconutzSO tallow soap and the saponifying alkali metal is a 9:1 mixture of potassium to sodium, the ratio of said soap paste to the encapsulated ammonia carbonate particles being about 5:1 by weight.
- the water-soluble ammonium salt particles are commercial ammonium carbonate particles having a particle size from about 30 mils to about 50 mils, encapsulated in a water insoluble rupturable outer coating providing a film from about 4 mils to about 6 mils thick, and including a watersoluble aqueous soap paste, said soap paste being a mixture of potassium and
- a scouring pad which during successive scouring operations in the presence of water is adapted to controllably release ammonia
- a body of fibrous scouring material containing a water soluble aqueous detergent paste and a plurality of water soluble ammonium salt particles, the particles size of which are distributed throughout the range from about 30 mils to about 50 mils, said water-soluble ammonium salt particles having a water insoluble rupturable outer coating providing a film being from about 2 mils to about 8 mils thick, the coated ammonium salt particles being at least about 0.01% by weight of the fibrous scouring material and distributed throughout the scouring pad, said coated ammonium salt particles being adapted to release ammonia in the presence of water only when the outer coating is ruptured during a scouring operation and said coated ammonium salt particles being present in variant particle sizes and coating thicknesses so that ammonia is controllably released during successive scouring operations.
Description
SCOURING PAD Filed NOV. 24, 1964 I N V EN TORS m as' HERBERT @445? 3,324,500 SCOURHNG PAD George Herbert Fuller and Werner Otto Tundermann, Colonia, N.J., assignors to Colgate-Palmolive Company, New York, N.Y., a corporation of Delaware Filed Nov. 24, 1964, Ser. No. 413,619 4 Claims. (Cl. -639) The present invention relates to an improved scouring pad capable of releasing ammonia upon use. More particularly, it relates to a scouring pad which retains its capability of releasing ammonia upon re-use.
Scouting articles such as steel wool pads are widely used as household scouring agents for the cleansing of soiled cooking utensils and the like. In conjunction with this scouring, it has :been found desirable to have an ammonia containing product present to provide an ammoniacal odor when the scouring pad is contacted with water and to aid in the removal of grease. Heretofore, ammonia-containing detergent compositions have been available for use with scouring pads. Unfortunately, when such compositions are used in an aqueous solution, the water rapidly dissolves the ammonium salt to release the ammonia prior to the end of the useful life of the product.
It has now been discovered that a scouring pad having water-soluble ammonium salt particles coated with a water-insoluble rupturable film provides an ammoniacal odor when the film is abraded or ruptured by using the pad in a scouring operation and thereafter provides a sustained release of ammonia vapor. Accordingly, the ammoniacal odor is available during substantially all of the time that the product is in use and, additionally, ammonia is available to aid in the removal of oily types of soil and grime from many surfaces. The scouring pad of the present invention comprises a body of fibrous scouring material containing a plurality of water-soluble ammonium salt particles having a water insoluble rupturable outer coating.
It has also been found that the coated ammonium salt particles can be combined with an aqueous-containing detergent medium which normally tends to decompose the ammonium salts and release ammonia. In accordance with the present invention coated ammonium salt particles can be combined with an aqueous-containing detergent medium and used as an integral part of a scouring pad without any release of ammonia vapor until the film on the ammonium salt particles has been ruptured or abraded by the scouring action. Additionally, in this embodiment of the invention the coated ammonia salt particles and aqueous-containing detergent medium are intimately mixed in the scouring pad. Since the ammonia is gradually released, it serves as a signaling device to indicate loss of detergent power. As the aqueous-containing detergent medium Will not cause release of ammonia and the two are concurrently depleted during use, it is apparent that when ammonia is no longer being released, both the detergent and ammonium salts have been completely used and the pad should be discarded.
The fibrous scouring materials useful in the present invention are any of those commonly used for scouring pads such as the metallic fibers and synthetic organic fibers well known in the art. Typical metallic fibers are steel wool, stainless steel fibers, copper fibers and copper alloy fibers, e.g. bronze and brass. Preferably, steel Wool and stainless steel fibers are employed since the ammonia released could possibly cause corrosion by reaction with copper or copper alloys. Typical synthetic organic fibers that may be used include nylon, polyester fibers such as Dacron, acrylic fibers such as Acrilanj rayon and other well known materials of similar types.
3,324,5W Patented June 13, 1%67 The water-soluble ammonium salts to be employed in the present invention for producing a sustained release of ammonia vapor are the crystalline ammonium compounds which are characterized by their solubility in water and the release of ammonia in an alkaline solution. A particularly suitable water-soluble ammonium salt is ammonium carbonate since in the presence of water, ammonia vapor is readily released. As used herein the term ammonium carbonate refers to the ammonium carbonate of commerce which is a mixture of ammonium bicarbonate and ammonium carb'amate (e.g. see Merck Index, Seventh Edition). Other ammonium salts which may be employed are the ammonium salts of strong acids such as ammonium chloride, ammonium sulfate, ammonium phosphate and the ammonium salts of weak acids such as ammonium acetate and ammonium bicarbonate. Since the ammonia vapor is released in an alkaline solution, the ammonium salts which are acid in solution such as the ammonium salts of strong acids and some ammonium salts of weak acids, e.g. ammonium acetate, require the presence of an alkaline buffer salt to provide sufficient alkalinity for the release of the ammonia. Of course, an alkaline buffer salt is not necessary where ammonium salts which are alkaline in solution, e.g. commercial ammonium carbonate and ammonium bicarbonate, are employed nor where an ammonium acid salt is used in conjunction with an alkaline system such as in combination with some detergent systems as described hereinafter. Examples of typical alkaline buffer salts are inorganic alkaline buffer salts such as sodium carbonate, potassium carbonate, sodium acetate, potassium acetate, sodium citrate and potassium citrate, and organic alkaline buffer salts such as sodium succinate.
While the particle size of the crystalline ammonium salts is not critical by itself, it can influence the rate of release of ammonia, the sustained release of ammonia and the arrangement of the particles in scouring pads. Generally the particle size of the ammonium salts Will range from about 20 to 30 mils in diameter to about to mls, although coarser or finer material may be used. The finer particles will release ammonia quickly whereas the larger particles will provide a more sustained release of ammonia.
In addition to the provision of an ammoniacal odor during use, the water-soluble ammonium salt component of the present invention provides ammonia to aid in the removal of grease and grime during each scouring operation.
The Water insoluble coating materials used to coat all surfaces of the ammonium salt particles are water insoluble substances which form a film over the ammonium salt particles. The film is characterized in that it is readily ruptured or abraded by scouring and is impermeable or substantially impermeable to water and prevents transmission of moisture to the ammonium salt particles prior to rupture, thus preventing or inhibiting the premature release of ammonia by any moisture in the scouring pad prior to usage. The water insoluble films that have been found to be most useful are those provided by film forming solutions of plastics. Since the ammonium salts will release ammonia in the presence of water as well as at elevated temperatures, the plastic solutions should not contain water nor should heat be required for drying to form the water-insoluble films. After the ammonium salt particles are coated with the plastic solution, room temperature curing should be sufficient for the film formation;
Suitable Water-insoluble coating materials for use in coating the water-soluble ammonium salt particles of the present invention are vinyls such as polyvinyl chlorides (Geon 151, Geon 251,, Geon 351, Pliovic Latex 300. and Exon 700 XR59), vinylidene chloride-vinyl chloride copolymers (Saran), and vinyl chloride-vinyl acetate copolymers (Vinylite VMCH, Vinylite VYHH and Geon 200 X These materials provide films which have chemical resistance to alkalies and have negligible water absorption, i.e. the films are substantially impermeable to Water. Other suitable materials are alkyd resins having alkali resistance and water absorption of less than 0.5% after 24 hour immersion at 25 C. such as made from anhydrides and a polybasic alcohol (Glyptal 2468); polystyrene having alkali resistance and Water absorption of from about 0.04 to 0.06% after 24 hour immersion at 25 C.; and polymethyl methacrylates having alkali resistance and water absorption of from about 0.3 to 0.4% after 24 hour immersion at 25 C. The films of these materials are considered to be substantially impermeable to water. Cellulosic plastics such as cellulose acetate and cellulose nitrate have rather high moisture absorption capacities but are useful in certain applications. It has been unexpectedly found that paints containing Cellulosic plastics provide a very satisfactory film for the ammonium salt particles, e..g. Krylon Royal Blue No. 1901 Spray Enamel, Krylon, Inc., Philadelphia, Pa. according to the following composition:
Percent Pigment 2.60
Titanium dioxide percent 58.70 Iron Blue do 40.30 Lithol Maroon do 1.00 Non-volatile Cellulose nitrate 11.80 Coconut oil modified alkyd. Dioctyl phthalate. Volatile Ketones, esters, alcohols, aromatic hydrocarbons, aliphatic hydrocarbons 45.60 Propellant Halogenated hydrocarbon 40.00
Phenolics, such as phenol formaldehyde form a film having a low moisture absorption, i.e. about 0.1 to 0.2% after 24 hour immersion at 25 C. and are particularly useful in detergent-free systems since some types of detergent may weaken the coating. A suitable phenolic coating is the following phenol formaldehyde base for paints:
Parts Mineral spirit 28.12 Varnish oil 17.15 Para phenyl phenol-formaldehyde resin 16.65 China-wood oil 25.98 Dipentene 4.67 Ethylene glycol monoethyl ether 3.84 Toluol 2.38 High flash naphtha 1.21
A water insoluble adhesive may be employed to hold the coated ammonium salt particles to the fibrous scouring material. Any suitable adhesive composition which does not react with the water insoluble coating material or the ammonium salt and can withstand repeated wettings can be used. Typical suitable cements are synthetic polymer based emulsion binders such as polyvinyl acetate emulsions (Elvacet, Vinac) which form Water insoluble bonds after water has evaporated from the emulsion. Other suitable emulsion binders are ethyl acrylate emulsions (Rhoplex B-15) and vinyl pyrrolidone-ethyl acrylate emulsions ('Pelectron 130). Non-solvent containing adhesives which are set by specific catalysts, e.g., epoxy resins cured with polyamines are also useful. Of course, the choice of adhesive will be somewhat dependent on the nature of the fibrous scouring material and the water insoluble coating material used and should usually be selected for the greatest degree of adhesion under the conditions of use.
It is preferred to employ a detergent or detergent composition in the present invention in order to provide cleansing and polishing properties. The detergents which may be used are selected from the group consisting of anionic and non-ionic detergents. Suitable anionic detergents are well known and include alkali metal and alkaline earth salts of various organic sulfates and sulfonates such as the higher alkyl aryl sulfonates, e.g., the sulfonates of alkylated benzene, toluene, cresol, naphthalene and the like in which the alkyl group contains from about 10 to 18 carbon atoms, typified by sodium pentadecyl benzene sulfonate and sodium tetrapropylene benzene sulfonate; higher fatty alcohol sulfates such as potassium lauryl sulfate and the lithium salt of sulfated alcohols derived from coconut oil by reduction; sulfated higher fatty acid monoglycerides such as the sodium or magnesium salts of monosulfated glyceryl monomyristate; higher fatty acid N-substituted taurates such as sodium N-methyl N-oleoyl taurate; and alkali metal, ammonium and triethanolamine soaps of higher fatty acids having about 12 to 18 carbon atoms such as sodium oleate, sodium stea'rate, potassium oleate, potassium stearate, potassium soap of mixed oleic and coconut oil fatty acids, ammonium sterate, ammonium oleate, ammonium laurate, triethanolamine oleate, and triethanolamine stearate. Suitable non-ionic detergents include the water-soluble ethyl oxide condensates of water insoluble (molecular weight 900 to 3,400) polypropylene glycols (Pluronics); higher fatty acid alkanolamides such as lauric monoand diethanolamide; and the ethylene oxide condensates of alkyl phenols such as nonyl phenol condensed with from 6 to 16 mols of ethylene oxide. If desired, inorganic builder salts such as pentasodium tripolyphosphate, tetrasodium pyrophosphate and the like may be employed to supplement or replace the anionic or non-ionic detergents but it is preferred to utilize some detergent too.
In addition to its customary foaming and detergent action to provide cleansing and polishing during use of the scouring pad, the detergent composition can serve as an alkaninity adjusting agent for those ammonium salt particles which are acid in solution. Thus, when ammonium acid salts are employed in conjunction with anionic detergent salts or non-ionic detergents and inorgaic builder salts it is not necessary to employ alkaline buffer salts if the detergent system is characterized by a pH of from about 8 to about 12.
In addition to the components of the improved article described above, one may employ adjuvants which are known in the detergent art. Perfumes, coloring agents, fluorescent brighteners, bleaches, foam enhancing additives, antibacterial and fungicidal compounds and rust preventing materials may be employed. If stable they may be formulated with the detergent or may be separately added, as desired. It is to be understood that the adjuvants employed will not materially affect the water insoluble coating on the ammonium salts.
The water insoluble coating material solutions may be applied to the ammonium salt particles in any manner suitable for coating particles. One method by which the water-soluble ammonium salt particles may be cated with the water insoluble coating material solutions is by first placing the ammonium salt particles on a vibrating feeder. While the particles are bouncing on the feeder they are coated with the plasticized solution at room temperature. If desired, the plasticized solution may contain some pigment so that one can visually determine when the particles have been completely coated. The resulting coated particles are dried at ambient temperature and a water insoluble film encapsulates the water-soluble ammonium salt particles. Additionally, the water-soluble ammonium salt particles may be coated with the water-insoluble coating material by dipping the particles into a plastic film forming solution. For example, the water-soluble ammonium salt particles are immersed or dipped in the film forming solution and then placed on a vibrating screen to drain, dry and set the coating. Also, the coating material may be applied by various other methods useful for coating particles such as a fluidized coating bed where the ammonium salt particles are placed in a coating unit chamber and coated with steams of coating solution while suspended in the chamber by air currents. The water insoluble film encapsulating the ammonium salt particles should be thin enough to be ruptured by scouring action but not so thick that normal scouring would not abrade or rupture the film. In general, the coated ammonium salt particles may have a water insoluble film in thickness of from about 0.5 to mils and preferably about 4 to 6 mils. Additionally, the individual ammonium salt particles may have film coatings of different thicknesses. Thus, both the particle size of the ammonium salts and the film thickness can vary and influence the sustained release of ammonia. Where the ammonium acid salts are used in combination with alkaline buffer salts, the alkaline buffer salt-s are preferably separately coated with the same water insoluble coating materials.
The scouring pads of the present invention can have any desired shape and form. It will be apparent to those skilled in the art that these articles may be prepared by any typical method such as by coating one face of a fibrous scouring material strip with a water insoluble adhesive and coated ammonium salt particles or coating one face with a detergent paste containing the coated ammonium salt particles and rolling up the strip with the coated face on the inside and compressing to impart a desired shape and form. Additionally, the strip may be loaded with the adhesive and coated ammonium salt particles, rolled and pressed to form a pad and coat one or both faces of the pad with the detergent paste and coated ammonium salt particles. It has been found that the scouring articles have a slight ammonia odor after formation of the pads, and when used in conjunction with dishwater in the course of scouring, the desired ammoniacal odor is released during each use as the water insoluble film is abraded or ruptured by the fibrous material such as steel wool.
Suitable scouring pads of the present invention are illustrated in the accompanying drawings in which: FIG. 1 shows a pad which has been compressed to make a form-retaining pad of pillow-shape in which a narrow strip along each edge is permanently crimped While the center portion remains relatively fluffy; FIG. 2 is a frag mentary sectional view drawn to a larger scale along the line 2--2 of FIG. 1; and FIG. 3 shows an end view of the pad coated on a face.
Referring to the drawings, the pad 11 has a narrow crimped border 12 around its edges, thus enabling the pad to maintain its shape.
As shown in FIG. 2, the pad 11 is formed with a water insoluble adhesive coating 13 containing coated ammonium salt particles 14 inside the pad. As shown in FIG. 3, the pad 11 may have one or both faces of the pad coated with a detergent paste 15 containing coated ammonium salt particles 14.
The instant coated ammonium salt particles are employed in a small but effective amount sufiicient to provide an ammoniacal odor during scouring in the presence of an aqueous medium. The exact minimum amount necessary to such action, as well as the aid in grease cutting action, is dependent upon the fibrous scouring material employed, the size of the particles, the thickness of the coating film, arrangement of the particles and the types and amount of other constituents in the pad. Thus in the case of steel wool per se, very small amounts may suflice, e.g. as little as 0.01% by weight of the steel Wool, whereas in the case of scouring pads containing a detergent system increased proportions may be required. Preferably, the coated ammonium salt particles in a scouring pad will vary in particle size and film thickness and be distributed through out the pad with the majority of the larger particles or thicker coated particles being in the core of the pad. Suitable proportions will be illustrated by the examples hereinafter set forth.
The following examples are given to illustrate the nature of the invention and it will be understood that the invention is not limited thereto. All parts and percentages are by weight unless otherwise specified.
Example I Commercial ammonium carbonate lumps are reduced to particles which passed through a No. 10 US. standard mesh sieve but remained on a No. sieve. The particles are then placed on a vibrating feeder. While bouncing on the vibrating feeder, the ammonium carbonate particles are sprayed and thoroughly coated with Krylon Royal Blue No. 190 1 Spray Enamel. An aqeuous solution (32% solids) of a mixture of potassium and sodium soaps is partially dried to provide a soap paste containing about 40% moisture. The soap is a 50:50 coco:tallow soap in which the saponifying alkali metal is a 9:1 mixture of potassium and sodium.
In preparing a soap charged scouring pad, 2.5 grams of the above soap paste and 0.5 gram of coated ammonium carbonate particles are intimately mixed and the mixture is spread along one face of a strip of 0 gauge steep wool weighing 27 grams. The strip is rolled up with the paste-carrying face on the inside, and the pad is then compressed to impart a desired shape and form.
When used to scour solid cooking utensils, the pads release ammonia vapor during use in the wash water. After drying-out, the pads provide the same results in subsequent usages.
In storage, prior to use and between each use, the coated ammonium carbonate particles do not release ammonia although they are carried in a soap system containing moisture which would normally tend to cause the ammonia vapor to be released.
Example 11 Spherical commercial ammonium carbonate particles having a particle size from about to 50 mils in diameter are placed on a vibrating feeder. The ammonium carbonate particles are thoroughly coated by spraying with Krylon Royal Blue No. 1901 Spray Enamel to provide coated ammonium carbonate particles encapsulated in a film having a thickness of about 4 to 6 mils after drying at room temperature. An aqueous solution solids) of a blend of 69% sodium soap (20% coconut oil:80% tallow) and 31% sodium. N-methyl N-oleoyl taurate is partially dried to provide a detergent paste containing about 2 5% moisture.
In preparing detergent charged scouring pads, 10 grams of the detergent paste is spread along one face of a strip of stainless steel fibers weighing 30 grams. The detergent coated strip is passed under a hopper containing the coated ammonium salt particles. The nozzle of the hopper is adapted so that the opening of the nozzle can be varied and as the strip passes beneath the nozzles the opening is varied and 5 grams of particles ranging from 30 to mils in diameter are spread along the surface of the detergent paste. The strip is rolled up with the paste carrying face on the inside, and the pad is pressed to impart a desired shape and form.
When used to scour cooking vessels and kitchen utensils, the pads release ammonia vapor during use in the wash water. The pads also release ammonia during subsequent usage.
Example III Spherical commercial ammonium carbonate particles having a particle size of about 50 mils in diameter are separated into two batches. Each batch is separately placed on a vibrating feeder and thoroughly coated by spraying with Krylon Royal Blue No. 1901 Spray Enamel. One batch of ammonium salt particles are coated until they are encapsulated in a film having a thickness of about 2 to 3 mils and the other batch of ammonium salt particles are coated until they are encapsulated in a film having a thickness of about 5 to 7 mils.
In preparing loaded scouring pads 8 gramsof the soap paste of Example I and 4 grams of each batch of coated ammonium salt particles are intimately mixed and spread along one face of a steel Wool strip of designated weight (e.g. 25 or 27 grams) and rolled as set forth in Example I. These scouring pads exhibit the same ammonia releasing ability as those of Examples I and II.
Example IV Ammonium chloride particles having a particle size of about 50 milsin diameter are immersed in a vinylidene chloridevinyl chloride copolymer (Saran) coating solution and then placed on a vibrating screen to drain and dry at room temperature. The film on the dry particles has a thickness of about 5 or 6 mils. Sodium carbonate particles of about 50 mils in diameter are coated as set forth above to provide them with a film having a thickness of about 3 or 4 mils.
In preparing scouring pads, 1 gram of coated ammonium chloride particles and 1 gram of coated sodium carbonate particles are distributed along one face of a steel wool strip weighing grams. One gram of a polyvinyl acetate emulsion (Elvacet) is spread along this face of the steel wool strip over the particles and an additional 1 gram of coated ammonium chloride particles and 1 gram of coated sodium carbonate particles are distributed over the adhesive. The coated strip is rolled and pressed as set forth in Example I.
When these pads are used to scour cooking vessels, a detectable ammoniacal odor is present during each use.
Example V Ammonium acetate particles having a particle size from about 30 to 50 mils in diameter are spray coated with Krylon Royal Blue No. 1901 Spray Enamel as set forth in Example I. Twenty-five parts of coated ammonium acetate particles are intimately mixed in a detergent paste consisting of 25 parts of sodium dodecyl benzene sulfonate, 25 parts of the diethanolamide of coconut oil fatty acids, 43 parts of pentasodium tripolyphosphate and 7 parts of sodium meta silicate.
In preparing detergent charged scouring pads, about 10 grams of the mixture of detergent paste and coated ammonium acetate particles are spread over one entire face of a steel wool strip 2% inches wide and of suflicient length to weigh about 5 to 7 grams and the strip folded to form a pad 2% inches by 2% inches.
These pads also release ammonia vapor when used with water to scour articles.
Although the present invention has been described with reference to particular embodiments and examples, it will be apparent to those skilled in the art that variation and modification of this invention can be made and that equivalents can be substituted therefor without departing from the principles and true spirit of the invention as defined in the appended claims.
What is claimed is:
' 1. A scouring pad which during successive scouring operations in the presence of water is adapted to controllably release ammonia comprising a body of fibrous scouring material containing a plurality of water-soluble ammonium salt particles, the particle sizes of which are distributed throughout the range from about mils to about 130 mils, said water-soluble ammonium salt particles having a water insoluble rupturable outer coating providing a film substantially impermeable to water absorption, said film being from about 0.5 mil to about 10 mils thick, the coated ammonium salt particles being at least about 0.01
by weight of the fibrous scouring material and distributed throughout the scouring pad, said coated ammonium salt particles being adapted to release ammonia in the presence of water when the outer coating is ruptured during a scouring operation, and said coated ammonium salt particles being present in variant particle sizes and coating thicknesses so that ammonia is controllably released during sucessive scouring operations.
2. A scouring pad according to claim 1 including a plurality of water-soluble alkaline buffer salt particles having a water insoluble rupturable outer coating, and a water insoluble adhesive composition adherent to a surface of the fibrous scouring material and the water insoluble outer coating, thereby holding the coated watersoluble ammonium salt particles and the coated alkaline buffer salt particles to the fibrous scouring material until the outer coatings of said particles are ruptured during a scouring operation whereby ammonia is released in the presence of water.
3. A scouring pad according to claim 1 wherein the water-soluble ammonium salt particles are commercial ammonium carbonate particles having a particle size from about 30 mils to about 50 mils, encapsulated in a water insoluble rupturable outer coating providing a film from about 4 mils to about 6 mils thick, and including a watersoluble aqueous soap paste, said soap paste being a mixture of potassium and sodium soaps in which the soap is a 50 coconutzSO tallow soap and the saponifying alkali metal is a 9:1 mixture of potassium to sodium, the ratio of said soap paste to the encapsulated ammonia carbonate particles being about 5:1 by weight.
4. A scouring pad which during successive scouring operations in the presence of water is adapted to controllably release ammonia comprising a body of fibrous scouring material containing a water soluble aqueous detergent paste and a plurality of water soluble ammonium salt particles, the particles size of which are distributed throughout the range from about 30 mils to about 50 mils, said water-soluble ammonium salt particles having a water insoluble rupturable outer coating providing a film being from about 2 mils to about 8 mils thick, the coated ammonium salt particles being at least about 0.01% by weight of the fibrous scouring material and distributed throughout the scouring pad, said coated ammonium salt particles being adapted to release ammonia in the presence of water only when the outer coating is ruptured during a scouring operation and said coated ammonium salt particles being present in variant particle sizes and coating thicknesses so that ammonia is controllably released during successive scouring operations.
References Cited UNITED STATES PATENTS Re. 16,350 5/1926 Bird 252- 709,846 9/1902 Young 252-176 2,051,435 8/1936 Colleran 252-91 2,542,058 2/1951 Riedesel 15-506 X 2,980,941 4/1961 Miller 15-506 3,034,169 5/1962 Vitale et al 252-91 X 3,175,331 3/1965 Klein 15-506 X FOREIGN PATENTS 563,255 9/1958 Canada.
CHARLES A. WILLMUTH, Primary Examiner.
R. L. BLEUTGE, Assistant Examiner.
Claims (1)
1. A SCOURING PAD WHICH DURING SUCCESSIVE SCOURING OPERATIONS IN THE PRESENCE OF WATER IS ADPATED TO CONTROLLABLY RELEASE AMMONIA COMPRISING A BODY OF FIBROUS SCOURING MATERIAL CONTAINING A PLURALITY OF WATER-SOLUBLE AMMONIUM SALT PARTICLES, THE PARTICLE SIZES OF WHICH ARE DISTRIBUTED THROUGHOUT THE RANGE FROM ABOUT 20 MILS TO ABOUT 130 MILS, SAID WATER-SOLUBLE AMMONIUM SALT PARTICLE HAVING A WATER INSOLUBLE REPUTURABLE OUTER COATING PROVIDING A FILM SUBSTANTIALLY IMPERMEABLE TO WATER ABSORPTION, SAID FILM BEING FROM ABOUT 0.5 MIL TO ABOUT 10 MILS THICK, THE COATED AMMONIUM SALT PARTICLES BEING AT LEAST ABOUT 0.01% BY WEIGHT OF THE FIBROUS SCOURING MATERIAL AND DISTRUBTED THROUGHOUT THE SCOURING PAD, SAID COATED AMMONIUM SALT PARTICLES BEING ADAPTED TO RELASE AMMONIA IN THE PRESENCE OF WATER WHEN THE OUTER COATING IS RUPTURED DURING A SCOURING OPERATION, AND SAID COATED AMMONIUM SALT PARTICLES BEING PRESENT IN VARIANT PARTICLE SIZES AND COATING THICKNESSES SO THAT AMMONIA IS CONTROLLABLY RELEASED DURING SUCCESSIVE SCOURING OPERATIONS.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US413619A US3324500A (en) | 1964-11-24 | 1964-11-24 | Scouring pad |
BE672788D BE672788A (en) | 1964-11-24 | 1965-11-24 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US413619A US3324500A (en) | 1964-11-24 | 1964-11-24 | Scouring pad |
Publications (1)
Publication Number | Publication Date |
---|---|
US3324500A true US3324500A (en) | 1967-06-13 |
Family
ID=23637957
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US413619A Expired - Lifetime US3324500A (en) | 1964-11-24 | 1964-11-24 | Scouring pad |
Country Status (2)
Country | Link |
---|---|
US (1) | US3324500A (en) |
BE (1) | BE672788A (en) |
Cited By (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3396419A (en) * | 1966-06-02 | 1968-08-13 | American Cyanamid Co | Disposable surgical scrub sponge and dispenser |
US4188447A (en) * | 1976-07-20 | 1980-02-12 | Collo Gmbh | Polymeric foam cleaning product |
US4216104A (en) * | 1976-12-03 | 1980-08-05 | Gerhard Gergely | Process of manufacturing a gas-generating cleaning material |
US4546515A (en) * | 1983-09-08 | 1985-10-15 | Mobil Oil Corporation | Scouring pad and method for producing same |
US4987632A (en) * | 1984-05-11 | 1991-01-29 | Lever Brothers Company | Wiping article |
US5090832A (en) * | 1986-05-12 | 1992-02-25 | Colgate-Palmolive Company | Disposable cleaning pad and method |
US5187830A (en) * | 1991-11-25 | 1993-02-23 | Sponge Fishing Co., Inc. | Washing, drying and scrubbing pad |
US5361445A (en) * | 1993-02-26 | 1994-11-08 | Sponge Fishing Co., Inc. | Scrubber washer apparatus |
US5421898A (en) * | 1992-02-21 | 1995-06-06 | Reckitt & Colman Inc. | Method and element for controlling release of a disinfectant from a substrate |
WO1998055043A1 (en) | 1997-06-03 | 1998-12-10 | Gillette Canada Inc. | Dental hygiene article |
US6547468B2 (en) | 2001-06-22 | 2003-04-15 | The Procter & Gamble Company | Dosing reservoir |
WO2003043480A1 (en) * | 2001-11-16 | 2003-05-30 | The Procter & Gamble Company | Disposable dish care and hard surface cleaning wipe |
US6607739B1 (en) | 2000-02-14 | 2003-08-19 | Johnson & Johnson Consumer Companies, Inc. | Dispensing article |
US6726386B1 (en) | 1999-10-08 | 2004-04-27 | The Procter & Gamble Company | Semi-enclosed applicator and a cleaning composition contained therein |
US6783294B2 (en) * | 2000-02-14 | 2004-08-31 | Johnson & Johnson Consumer Companies, Inc. | Solid cleanser holder |
US6811338B1 (en) | 1999-10-08 | 2004-11-02 | The Procter & Gamble Company | Disposable semi-enclosed applicator for distributing a substance onto a target surface |
AU781324B2 (en) * | 2000-02-14 | 2005-05-19 | Johnson & Johnson Consumer Companies, Inc. | Textured film devices |
US7021848B1 (en) | 1999-10-08 | 2006-04-04 | The Procter & Gamble Company | Semi-enclosed applicator having a temperature changing element |
US7108440B1 (en) | 1999-10-08 | 2006-09-19 | The Procter & Gamble Company | Applicator for distributing a substance onto a target surface |
US20090075547A1 (en) * | 2007-09-19 | 2009-03-19 | Rotter Matin J | Cleaning pads with abrasive loaded filaments and anti-microbial agent |
US20110131742A1 (en) * | 2006-01-23 | 2011-06-09 | Manfred Cheung | Golf Ball Cleaning Pad |
US20150335222A1 (en) * | 2014-05-21 | 2015-11-26 | Madison Mark Jones | Rag Stack System and Method |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1200526B (en) * | 1986-11-03 | 1989-01-18 | Larac Spa | FLEXIBLE COATINGS FOR THE DESULPHATING CLEANING OF FRESCOED SURFACES |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US709846A (en) * | 1901-06-03 | 1902-09-23 | Conrad Doersch | Ammonia-generator. |
US2051435A (en) * | 1933-03-25 | 1936-08-18 | Benjamin Michaelson | Cleaning cloth and method of producing same |
US2542058A (en) * | 1949-12-05 | 1951-02-20 | Minnesota Mining & Mfg | Polishing sheet |
CA563255A (en) * | 1958-09-16 | L. Perlman Jacob | Powdered ammonia detergent composition | |
US2980941A (en) * | 1958-12-08 | 1961-04-25 | Ncr Co | Cleaning sheet |
US3034169A (en) * | 1956-12-10 | 1962-05-15 | Colgate Palmolive Co | Durable scouring pads and composition therefor |
US3175331A (en) * | 1964-07-13 | 1965-03-30 | Union Carbide Corp | Cleaning and scouring pad |
-
1964
- 1964-11-24 US US413619A patent/US3324500A/en not_active Expired - Lifetime
-
1965
- 1965-11-24 BE BE672788D patent/BE672788A/xx unknown
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA563255A (en) * | 1958-09-16 | L. Perlman Jacob | Powdered ammonia detergent composition | |
US709846A (en) * | 1901-06-03 | 1902-09-23 | Conrad Doersch | Ammonia-generator. |
US2051435A (en) * | 1933-03-25 | 1936-08-18 | Benjamin Michaelson | Cleaning cloth and method of producing same |
US2542058A (en) * | 1949-12-05 | 1951-02-20 | Minnesota Mining & Mfg | Polishing sheet |
US3034169A (en) * | 1956-12-10 | 1962-05-15 | Colgate Palmolive Co | Durable scouring pads and composition therefor |
US2980941A (en) * | 1958-12-08 | 1961-04-25 | Ncr Co | Cleaning sheet |
US3175331A (en) * | 1964-07-13 | 1965-03-30 | Union Carbide Corp | Cleaning and scouring pad |
Cited By (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3396419A (en) * | 1966-06-02 | 1968-08-13 | American Cyanamid Co | Disposable surgical scrub sponge and dispenser |
US4188447A (en) * | 1976-07-20 | 1980-02-12 | Collo Gmbh | Polymeric foam cleaning product |
US4216104A (en) * | 1976-12-03 | 1980-08-05 | Gerhard Gergely | Process of manufacturing a gas-generating cleaning material |
US4272393A (en) * | 1976-12-03 | 1981-06-09 | Gerhard Gergely | Gas generating cleaning article |
US4546515A (en) * | 1983-09-08 | 1985-10-15 | Mobil Oil Corporation | Scouring pad and method for producing same |
US4987632A (en) * | 1984-05-11 | 1991-01-29 | Lever Brothers Company | Wiping article |
US5090832A (en) * | 1986-05-12 | 1992-02-25 | Colgate-Palmolive Company | Disposable cleaning pad and method |
US5187830A (en) * | 1991-11-25 | 1993-02-23 | Sponge Fishing Co., Inc. | Washing, drying and scrubbing pad |
US5421898A (en) * | 1992-02-21 | 1995-06-06 | Reckitt & Colman Inc. | Method and element for controlling release of a disinfectant from a substrate |
US5361445A (en) * | 1993-02-26 | 1994-11-08 | Sponge Fishing Co., Inc. | Scrubber washer apparatus |
WO1998055043A1 (en) | 1997-06-03 | 1998-12-10 | Gillette Canada Inc. | Dental hygiene article |
US7021848B1 (en) | 1999-10-08 | 2006-04-04 | The Procter & Gamble Company | Semi-enclosed applicator having a temperature changing element |
US6726386B1 (en) | 1999-10-08 | 2004-04-27 | The Procter & Gamble Company | Semi-enclosed applicator and a cleaning composition contained therein |
US7108440B1 (en) | 1999-10-08 | 2006-09-19 | The Procter & Gamble Company | Applicator for distributing a substance onto a target surface |
US6811338B1 (en) | 1999-10-08 | 2004-11-02 | The Procter & Gamble Company | Disposable semi-enclosed applicator for distributing a substance onto a target surface |
US6957924B1 (en) | 2000-02-14 | 2005-10-25 | Johnson & Johnson Consumer Companies, Inc. | Textured film devices |
US20030203010A1 (en) * | 2000-02-14 | 2003-10-30 | Warren Wallo | Dispensing article |
US6783294B2 (en) * | 2000-02-14 | 2004-08-31 | Johnson & Johnson Consumer Companies, Inc. | Solid cleanser holder |
US6607739B1 (en) | 2000-02-14 | 2003-08-19 | Johnson & Johnson Consumer Companies, Inc. | Dispensing article |
AU781324B2 (en) * | 2000-02-14 | 2005-05-19 | Johnson & Johnson Consumer Companies, Inc. | Textured film devices |
AU785186B2 (en) * | 2001-06-13 | 2006-10-19 | Johnson & Johnson Consumer Companies, Inc. | Solid cleanser holder |
US6547468B2 (en) | 2001-06-22 | 2003-04-15 | The Procter & Gamble Company | Dosing reservoir |
US20030121530A1 (en) * | 2001-11-16 | 2003-07-03 | The Procter & Gamble Company | Disposable dish care and hard surface cleaning wipe |
WO2003043480A1 (en) * | 2001-11-16 | 2003-05-30 | The Procter & Gamble Company | Disposable dish care and hard surface cleaning wipe |
US7132377B2 (en) | 2001-11-16 | 2006-11-07 | The Procter & Gamble Company | Disposable dish care and hard surface cleaning wipe |
US20110131742A1 (en) * | 2006-01-23 | 2011-06-09 | Manfred Cheung | Golf Ball Cleaning Pad |
US20090075547A1 (en) * | 2007-09-19 | 2009-03-19 | Rotter Matin J | Cleaning pads with abrasive loaded filaments and anti-microbial agent |
US20150335222A1 (en) * | 2014-05-21 | 2015-11-26 | Madison Mark Jones | Rag Stack System and Method |
US9706894B2 (en) * | 2014-05-21 | 2017-07-18 | Madison Mark Jones | Rag stack system and method |
Also Published As
Publication number | Publication date |
---|---|
BE672788A (en) | 1966-03-16 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3324500A (en) | Scouring pad | |
EP0118313B1 (en) | Method and device for conditioning fabrics in a tumble-dryer | |
US3042621A (en) | Detergent composition | |
US3896033A (en) | Encapsulated fabric softener | |
US4740326A (en) | Soil release polymer coated substrate containing a laundry detergent for improved cleaning performance | |
US3945936A (en) | Bleaching article | |
US2875155A (en) | Detergent briquette and process for the production thereof | |
EP3580320B1 (en) | Particulate fragrance enhancers | |
JPS58209397A (en) | Tool for conditioning property of knitted fabric in tumble dryer | |
JPS63199296A (en) | Detergent composition containing peroxide bleaching agent and stain release agent | |
JPS5865798A (en) | Controlled release laundry bleaching agent products | |
US3318817A (en) | Process for preparing detergent tablets | |
US4057673A (en) | Fabric conditioning with improved composition containing a plasticizer | |
NO157902B (en) | SCRUBBING / CLEANING PRODUCTS. | |
JP7414839B2 (en) | Method of manufacturing fibrous water-soluble unit dose articles | |
JP2006516153A (en) | Method for producing solid aromatic substance concentrate | |
US3042622A (en) | Abrasive cleaning composition | |
US2896242A (en) | Cleaning and scouring pads | |
US3516937A (en) | Sustained action detergent product containing encapsulated sodium tripolyphosphate | |
US2555285A (en) | Detergent composition | |
WO1991017238A1 (en) | Extended-release plaque preventing and dissolving compositions and their method of use | |
US3034169A (en) | Durable scouring pads and composition therefor | |
EP4118173A1 (en) | Solid granules used for cleaning agents | |
US3329616A (en) | Process for preparing detergents | |
CA2030370C (en) | Delayed action drain cleaner compositions |