US3340281A - Method for producing lubricating oil additives - Google Patents
Method for producing lubricating oil additives Download PDFInfo
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- US3340281A US3340281A US463924A US46392465A US3340281A US 3340281 A US3340281 A US 3340281A US 463924 A US463924 A US 463924A US 46392465 A US46392465 A US 46392465A US 3340281 A US3340281 A US 3340281A
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- 239000000654 additive Substances 0.000 title description 15
- 239000010687 lubricating oil Substances 0.000 title description 9
- 238000004519 manufacturing process Methods 0.000 title description 2
- 150000001412 amines Chemical class 0.000 claims description 13
- 239000000314 lubricant Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 7
- 230000008569 process Effects 0.000 claims description 7
- 229920001281 polyalkylene Polymers 0.000 claims description 6
- 239000003921 oil Substances 0.000 description 41
- 239000000047 product Substances 0.000 description 22
- 239000000203 mixture Substances 0.000 description 20
- 229920000642 polymer Polymers 0.000 description 19
- 239000003999 initiator Substances 0.000 description 18
- 238000007792 addition Methods 0.000 description 14
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 14
- 239000002270 dispersing agent Substances 0.000 description 14
- 239000007795 chemical reaction product Substances 0.000 description 13
- -1 haloacetyl halide compound Chemical class 0.000 description 13
- 239000010802 sludge Substances 0.000 description 13
- 238000012360 testing method Methods 0.000 description 13
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 12
- 150000003254 radicals Chemical class 0.000 description 12
- VGCXGMAHQTYDJK-UHFFFAOYSA-N Chloroacetyl chloride Chemical compound ClCC(Cl)=O VGCXGMAHQTYDJK-UHFFFAOYSA-N 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 10
- 229920001083 polybutene Polymers 0.000 description 10
- 238000010992 reflux Methods 0.000 description 10
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 10
- 229920001577 copolymer Polymers 0.000 description 9
- 230000006872 improvement Effects 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 7
- 239000002966 varnish Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 6
- 239000004480 active ingredient Substances 0.000 description 6
- 150000001336 alkenes Chemical class 0.000 description 6
- 239000002199 base oil Substances 0.000 description 6
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical group CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 6
- 150000002430 hydrocarbons Chemical group 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 5
- 238000000502 dialysis Methods 0.000 description 5
- 238000004821 distillation Methods 0.000 description 5
- 150000004820 halides Chemical class 0.000 description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 5
- 229920000768 polyamine Polymers 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- 229920005549 butyl rubber Polymers 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 238000007348 radical reaction Methods 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 150000001266 acyl halides Chemical class 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- IUFXKTIZXZVLJC-UHFFFAOYSA-N buta-1,3-diene;2-methylprop-1-ene Chemical compound CC(C)=C.C=CC=C IUFXKTIZXZVLJC-UHFFFAOYSA-N 0.000 description 3
- 239000012433 hydrogen halide Substances 0.000 description 3
- 229910000039 hydrogen halide Inorganic materials 0.000 description 3
- 238000005461 lubrication Methods 0.000 description 3
- GBMDVOWEEQVZKZ-UHFFFAOYSA-N methanol;hydrate Chemical compound O.OC GBMDVOWEEQVZKZ-UHFFFAOYSA-N 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000012044 organic layer Substances 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000003776 cleavage reaction Methods 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- NIQQIJXGUZVEBB-UHFFFAOYSA-N methanol;propan-2-one Chemical compound OC.CC(C)=O NIQQIJXGUZVEBB-UHFFFAOYSA-N 0.000 description 2
- 239000010705 motor oil Substances 0.000 description 2
- LSHROXHEILXKHM-UHFFFAOYSA-N n'-[2-[2-[2-(2-aminoethylamino)ethylamino]ethylamino]ethyl]ethane-1,2-diamine Chemical compound NCCNCCNCCNCCNCCN LSHROXHEILXKHM-UHFFFAOYSA-N 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 238000007342 radical addition reaction Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 230000007017 scission Effects 0.000 description 2
- 229960001124 trientine Drugs 0.000 description 2
- 239000010913 used oil Substances 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VVNCNSJFMMFHPL-VKHMYHEASA-N D-penicillamine Chemical group CC(C)(S)[C@@H](N)C(O)=O VVNCNSJFMMFHPL-VKHMYHEASA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- VHOQXEIFYTTXJU-UHFFFAOYSA-N Isobutylene-isoprene copolymer Chemical compound CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 description 1
- 230000035508 accumulation Effects 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- VDDMKJPUJHRUMM-UHFFFAOYSA-N cyclopenta-1,3-diene;2-methylprop-1-ene Chemical group CC(C)=C.C1C=CC=C1 VDDMKJPUJHRUMM-UHFFFAOYSA-N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000005474 detonation Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 229910021385 hard carbon Inorganic materials 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 150000002431 hydrogen Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 150000002432 hydroperoxides Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000005673 monoalkenes Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000012713 reactive precursor Substances 0.000 description 1
- 239000011369 resultant mixture Substances 0.000 description 1
- 238000007363 ring formation reaction Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- AGGKEGLBGGJEBZ-UHFFFAOYSA-N tetramethylenedisulfotetramine Chemical compound C1N(S2(=O)=O)CN3S(=O)(=O)N1CN2C3 AGGKEGLBGGJEBZ-UHFFFAOYSA-N 0.000 description 1
- 238000010626 work up procedure Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
- C10M133/52—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of 30 or more atoms
- C10M133/56—Amides; Imides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
- C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/26—Amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/046—Polyamines, i.e. macromoleculars obtained by condensation of more than eleven amine monomers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
Definitions
- This invention relates to 'new compositions of matter useful as lubricating oil additives. More particularly, it relates to a new class of ashless dispersants and viscosity index improver additives, the process of preparing the same, and lubricating oil compositions containing such ashless dispersants.
- sludge deposits the chief source of engine operating difliculties as related to lubricants and lubrication.
- the term sludge is used broadly to identify all types of engine deposits ranging from varnish or lacquer-like films to packed or hard carbon accumulations, as Well as to the softer types of pasty or granular sludges. These deposits endanger the engine by causing disruption of oil circulation, by plugging of screens and passages, and by causing valve sticking and ring sticking. They also may lower the en-gines efficiency by causing piston sticking in the cylinders, high oil consumption, loss of power and excessive detonation.
- additives useful in cont-rolling engine deposits are known.
- these compounds are metal salts of organic compounds. Oil solubility is attained by linking the metal salt su'bstituent to a hydrocarbon group of suificient size to render the compound oil solube. While these compounds have exhibited some dispersaucy properties, they have for the most part, created a new problem.
- Such additive-treated motor oils usually have quite appreciable ash contents, and When such oils work up into the combustion chamber they leave inorganic residues upon ignition. These ash deposits are undesirable because they lower the efiiciency of the engine by fouling spark plugs and valves and contribute to pre-ignition.
- the compound is effective in both the form of a low molecular weight dispersant and in the form of a combination dispersant-VI improver for a multi-graded oil.
- polymeric acylhalide formed in the free radical reaction gives a reactive precursor which is then treated with a polyamine such as a polyalkylene amine, e.g. triethylene tetramine (TETA), tetraethylene pentamine (TEPA), ethylene diamine, pentaethylene hexamine (PEHA) or with a monoamine such as ammonia, mono-alkylamines, and di-alkylamines as well as compounds containing mercaptyl groups.
- polyalkylene amine is meant those polyamines having the formula wherein x is an integer of from 2 to about 10, R is hydro gen or a lower alkyl hydrocarbon substituent and alkylone is a lower alkylene, i.e. divalent, open chain, hydrocarbon group having from 1 to 8 carbon atoms. Triethylene tetramine and tetraethylene pentamine are preferred.
- the double bond-containing polymers useful in this free radical reaction may be mono-olefins, di-olefins and polyolefins and include poly'butenes, polypropyleens, or copolymers such as isobutylene-isoprene, isobutylene-butadiene, cyclopentadiene-isobutylene.
- the suitable molecular Weight range is approximately 300 to approximately 550,000.
- a suitable polymeric olefin is one having an average molecular Weight of between approximately 300 and approximately 9,000, and advantageously between 300 and 2500.
- the polybutenes ranging in average molecular weight from about 450 to about 2000 are most advantageously utilized in the free radical reaction.
- a preferred polybutene is one with an average molecular Weight of 1100 and a viscosity at F. of 140,000 SSU and at 210 F. of 3000 SSU (hereinafter referred to as Polybutene A).
- Another preferred polybutene is one with an average molecular weight of 1800 and viscosity at 210 F. of 15,000 SSU (hereinafter referred to as Polybutene B).
- Polybutene B For the high molecular weight dispersont-VI improver it is advantageous to use a polymeric olefin having a molecular weight of between approximately 9000 and approximately 550,000. It is most advantageous to use a copolymer of isobutylene-butadiene with an average molecular weight of between approximately 30,000 to approximately 100,000.
- R is a hydrocarbon polymer or copolymer having a molecular weight of between 300 and 550,000
- X is a halide.
- This reaction is extremely versatile as shown by the fact that a very wide range of polymers of varying molecular weights and double bond contents may be successfully used in forming a precursor for the incorporation of polyamines or monoamines.
- Suitable polymers or copolymers have a molecular weight of between 300 and more than 80,000 (after the degradation efiect described above).
- the addition of the haloacetyl halide is strongly dependent on the amount of initiator used. It is desirable to use between 0.2 and 1 mole of initiator for every double bond per molecule of polymer. (Hereinafter the words double bond, as used in mole ratios, are to he understood as meaning the double bond content per mole cule of polymer. This method of expressing the mole ratios is used since the double bond content of the polymer, and not merely the number of moles of polymer, will influence the number of moles of reactants utilized.)
- the amount of haloacetyl halide reactant necessary in the reaction depends upon the amount of the initiator used. Therefore, for a lower amount of initiator a higher quantity of haloacetyl halide is necessary. It is advantageous to use 2 to 20 moles of haloacetyl halide per mole of double bond. In addition, as the molecular weight of the polymer increases, it is desirable that the molar percent of the haloacetyl halide increase.
- the reaction may proceed in a mole ratio of double bondzhaloacetyl halide: free radical initiator of from about 1:20:02 to about 1:2:1. It is preferable to use 1 mole of initiator per mole of double bond. For a higher molecular weight polymer it is preferable to use 10 to 20 moles of haloacetyl halide per mole double bond, and for the lower molecular weight polymer it is preferred to use between 2 and moles.
- the free radical addition of the haloacetyl halide takes place over a temperature range of 50 C. to 225 C.
- the exact temperature of the reaction is dependent upon the initiator and is chosen in such a manner as to provide the most efl'icient usage of the initiator over a reasonable length of time and which would allow for approximately 90% of the initiator to decompose.
- a suitable temperature range for the initiator, di-t-butyl peroxide is 125 C. to 170 C.
- the temperature range of 140-155 C. and total reaction time of about 3 to 20 hours is preferred for this initiator. It is desirable that a portion-wise addition of initiator be made.
- From 5 to portions may be added over a 2 to 5 hour period for the high molecular weight product and the total reaction time allowed for the adduct formation be between 3 and 6 hours.
- the total reaction time allowed for the adduct formation be between 3 and 6 hours.
- 2 additions of the initiator and a 20 hour total reflux period is advantageous with the above initiator.
- the reaction temperature can vary from 25 C. to 175 C. It is preferred that the pot temperature be held between approximately C. to approximately 175 C. so as to drive the reaction to irnidazoline ring formation leaving only minor amounts of monoand di-substituted amides in the finished product.
- the amine In the displacement reaction, it is desirable to use an excess of the amine (from 1 to 20 moles of amine to each double bond per molecule of polymeric olefin, preferably 2 to 10 moles) in order to take up the hydrogen halide given off during the reaction as well as to give a high yield of the one-ended product and prevent cross-linking. In most cases a major proportion of the unreacted amine and the amine-hydrogen halide salt settles out upon cooling leaving only small amounts of same dispersed throughout the reaction mixture. The dispersed amine and the salt may be removed by 20 percent methanol water wash followed by centrifugation.
- Another method of removing the hydrogen halide is to treat the haloacetyl halide adduct with alcohol in order to form the ester. Treatment of this product with an amine at temperatures of from about 150 C. to about 175 C. would then afford the same type of active site giving the alcohol back as a reaction product.
- the resulting solution was then added slowly with rapid stirring to 361 grams (1.9 moles) of dried tetraethylene pentamine in 100 milliliters of refluxing decane. Upon completion of the addition, the mixture was refluxed another hour, cooled and added to approximately 5-8 liters of hexane. The resuliting mixture was washedwith 20 percentmethanolwater solution (1 part wash to 3 parts final reaction mixture) and centrifuged. The organic layer was removed, 200 grams of SW oil added and the hexane and decane solvents stripped under a vacuum (pot temperature 160 C. at 20 mm.). The final product weighed 1,088 grams and contained 811 percent polymer, representing 33 percent of the active ingredient. The basic nitrogen content by dialysis was 1.3 percent.
- the solution was refluxed an additional 4 hours and then added to 86 grams (0.45 mole) of dry tetraethylene pentamine. Upon completion of this addition, the solution was again refluxed another hour and then allowed to cool. The upper layer was decanted from the excess tetraethylene pentamine and added to 200 grams of SW oil. The entire solution was then stripped yielding a bright product weighing 575 grams, containing 35 percent active ingredient with a basic nitrogen content by dialysis of 0.95 percent.
- the reaction product of this invention when incorporated in a hydrocarbon oil of lubricating viscosity, exhibits exceptional dispersant qualities without leaving an ash residue in the engine.
- synthetic or other natural hydrocarbon oils may be used to provide the base oil.
- the reaction product above described will normally constitute from about 1 to 20 Weight percent of the lubricant, but this percentage may be higher or lower. The percentage will usually depend upon the nature of the dispersant product, e.g. high molecular weight or low molecular weight; the use to which the lubricant will be put; and the use to which the additive will be put, e.g. no VI improvement, some VI improvement or total VI improvement.
- the preferable range of the lower molecular weight product in lubricating oil is from 3 to 5 weight percent, and for the higher molecular weight product, exhibiting total VI improvement, from 1 to 15 weight percent.
- reaction products can be suitably employed alone in the base oil, they are usually used in combination with other lubricant addition agents which impart various desirable characteristics to the base oil.
- lubricant addition agents which impart various desirable characteristics to the base oil.
- these reaction products exhibit a marked effectiveness in VI improvement and dispersancy, it may be necessary, depending upon the use of the lubricant, to incorporate other additives in the base oil, e.g. corrosion and rust inhibitors, pour point depressants, foam inhibitors, etc.
- Other lubricant addition agents can be used in combination with the additive of this invention.
- a number of performance tests for evaluating the characteristics of lubricating oils were conducted.
- a test, made to determine the anti-sludge properties of the oil is known as the Lincoln MS Test, Sequence V, developed by the Ford Motor Company. Briefly, the test consists of using the oil to be tested as a lubricating oil in a V-8 Lincoln engine under prescribed test conditions Accordingly 5 quarts of oil are placed in the crankcase and the engine is started and run in accordance with the 4 hour cycle:
- Example I do l. do 48 43 0 l 9. 0 do 1. 5 Extended drain oil 45 35 0 0 8. 0 A current commercial 1. 6 Multi-graded premium oil 35 35 0 8. 0
- Example 3. 7 A current commercial 1. 0 .do 2O 32 98 50 6. 0
- Example 5 A current commercial 1. 0 do 32 98 50 6.0
- a further illustration of the usefulness of this invention is provided by an examination of the results of sludge spot dispersancy test.
- oil formulations already tested under control tests at various levels of dispersancy in a standard engine detergency-dispersancy test are employed as source of in engine produced sludge.
- a composite of these used formulations is made and thoroughly mixed.
- a weighed amount of used oil composite and a weighed amount of the detergency candidate are combined and heated to 300 F. Thereafter this mixture is added to an equal volume of fresh unused, unformulated SAE 20 oil also at 300 F. The resultant mixture is held at 300 F. for two hours.
Description
United States Patent M 3,340,281 METHOD FOR PRODUCING LUBRICATING OIL ADDITIVES William T. Brannen, In, Chicago Heights, Ill., assignor to Standard Oil Company, Chicago, 111., a corporation of Indiana No Drawing. Filed June 14, 1965, Ser. No. 463,924 2 Claims. (Cl. 260-4045) This invention relates to 'new compositions of matter useful as lubricating oil additives. More particularly, it relates to a new class of ashless dispersants and viscosity index improver additives, the process of preparing the same, and lubricating oil compositions containing such ashless dispersants.
It is generally considered that the chief source of engine operating difliculties as related to lubricants and lubrication is sludge deposits. The term sludge is used broadly to identify all types of engine deposits ranging from varnish or lacquer-like films to packed or hard carbon accumulations, as Well as to the softer types of pasty or granular sludges. These deposits endanger the engine by causing disruption of oil circulation, by plugging of screens and passages, and by causing valve sticking and ring sticking. They also may lower the en-gines efficiency by causing piston sticking in the cylinders, high oil consumption, loss of power and excessive detonation.
Operating conditions most conducive to sludge formation are the short haul, stop-start urban type. Engine idling, cold starting, engine warm-up, accelerating, coasting to a stop, or using the engine as a brake all increase sludge.
A large number of additives useful in cont-rolling engine deposits are known. In the main, these compounds are metal salts of organic compounds. Oil solubility is attained by linking the metal salt su'bstituent to a hydrocarbon group of suificient size to render the compound oil solube. While these compounds have exhibited some dispersaucy properties, they have for the most part, created a new problem. Such additive-treated motor oils usually have quite appreciable ash contents, and When such oils work up into the combustion chamber they leave inorganic residues upon ignition. These ash deposits are undesirable because they lower the efiiciency of the engine by fouling spark plugs and valves and contribute to pre-ignition.
Good engine lubrication also requires an oil which will not thicken excessively at low temperatures nor thin out excessively at elevated temperatures, which means that oils of high viscosity index (VI) are to be preferred as engine lubricants. Such oils develop a minimum of friction and viscous drag at low temperatures, and accordingly allow easier engine starting in cold weather and more rapid flow and circulation during the warm-up period. At the elevated temperatures developed in running engines, high VI oils retain higher viscosities and thus provide better lubrication of hot engine parts and better sealing of PlS'. ton rings to insure low oil consumption.
It is an object of this invention to provide a new class of compositions of matter. It is also an object of this invention to provide compositions which may be used as multifunctional additives in hydrocarbon oils. It is a further object to provide low molecular Weight compositions useful as effective ashless dispersant additives in lubricating oils. It is another object to provide high molecular Weight compositions useful as total VI irnprovers-dispersant combinations in lubricants. It is another object to provide intermediate molecular Weight compositions useful as partial VI improver-dispersant combinations in lubricants. It is another object to provide a unique lubricating oil composition effective in low temperature automobile op eration. It is another object to provide a process for the Patented Sept. 5, 1967 preparation of new additives useful as dispersants and VI improver-dispersants, Other objects and advantages will be apparent as the discussion of the invention proceeds.
I have now discovered a process for the preparation of an ashless formulation that will leave no residue in the combustion chamber and will provide outstanding engine cleanliness at low operating temperatures. The compound is effective in both the form of a low molecular weight dispersant and in the form of a combination dispersant-VI improver for a multi-graded oil.
The preparation of the product of the process of the invention is accomplished by the reaction of a polymeric acylhalide and a polyamine or monoamine. The polymeric acylhalide is the reaction product of a polymeric olefin wtih an whaloacetyl halide, preferably ohloroacetyl chloride, under free radical conditions. Free radical condi tions herein described can be either light catalyzed or catalyzed by use of the common free radical initiators such as peroxides, hydroperoxides, and 2120 compounds; a preferred initiator is di-tert-butyl peroxide. The polymeric acylhalide formed in the free radical reaction gives a reactive precursor which is then treated with a polyamine such as a polyalkylene amine, e.g. triethylene tetramine (TETA), tetraethylene pentamine (TEPA), ethylene diamine, pentaethylene hexamine (PEHA) or with a monoamine such as ammonia, mono-alkylamines, and di-alkylamines as well as compounds containing mercaptyl groups. By polyalkylene amine is meant those polyamines having the formula wherein x is an integer of from 2 to about 10, R is hydro gen or a lower alkyl hydrocarbon substituent and alkylone is a lower alkylene, i.e. divalent, open chain, hydrocarbon group having from 1 to 8 carbon atoms. Triethylene tetramine and tetraethylene pentamine are preferred.
The double bond-containing polymers useful in this free radical reaction may be mono-olefins, di-olefins and polyolefins and include poly'butenes, polypropyleens, or copolymers such as isobutylene-isoprene, isobutylene-butadiene, cyclopentadiene-isobutylene. The suitable molecular Weight range is approximately 300 to approximately 550,000. For the lower molecular weight dispersant, a suitable polymeric olefin is one having an average molecular Weight of between approximately 300 and approximately 9,000, and advantageously between 300 and 2500. The polybutenes ranging in average molecular weight from about 450 to about 2000 are most advantageously utilized in the free radical reaction. A preferred polybutene is one with an average molecular Weight of 1100 and a viscosity at F. of 140,000 SSU and at 210 F. of 3000 SSU (hereinafter referred to as Polybutene A). Another preferred polybutene is one with an average molecular weight of 1800 and viscosity at 210 F. of 15,000 SSU (hereinafter referred to as Polybutene B). For the high molecular weight dispersont-VI improver it is advantageous to use a polymeric olefin having a molecular weight of between approximately 9000 and approximately 550,000. It is most advantageous to use a copolymer of isobutylene-butadiene with an average molecular weight of between approximately 30,000 to approximately 100,000. A preferred copolymer of isobutylene-butadiene is one with an average molecular weight of between 60,000 to 80,000 and a weight percent of butadiene of about 0.4 to about 2.0. Another preferable source of high molecular weight poly- :mer is butyl rubber of average molecular weight of 450,- 000 and an average mole percent unsaturation of l.52.0. Two commercially available butyl rubbers marketed as Butyl Rubber and 218 are suitable.
In most respects the reactions using the high molecular weight copolymers are similar to those found with the low molecular weight olefins. One important difference which does occur, however, is the oxidative degradation of the very high molecular weight copolymers by the free radical initiator. This involves a cleavage of the internal double bonds. By such cleavage a polymer of molecular weight of approximately 450,000 may be degraded to a polymer of molecular weight of between 60,000 to 80,000. This is highly desirable.
There is evidence that the free radicalreaction proceeds by way of addition of the haloacetyl halide compound to the double bonds of the polymer. The following mechanism conforms to this evidence:
wherein R is a hydrocarbon polymer or copolymer having a molecular weight of between 300 and 550,000, and X is a halide. This reaction is extremely versatile as shown by the fact that a very wide range of polymers of varying molecular weights and double bond contents may be successfully used in forming a precursor for the incorporation of polyamines or monoamines. Suitable polymers or copolymers have a molecular weight of between 300 and more than 80,000 (after the degradation efiect described above).
Since the free radical addition step is an extremely short-chain reaction, the addition of the haloacetyl halide is strongly dependent on the amount of initiator used. It is desirable to use between 0.2 and 1 mole of initiator for every double bond per molecule of polymer. (Hereinafter the words double bond, as used in mole ratios, are to he understood as meaning the double bond content per mole cule of polymer. This method of expressing the mole ratios is used since the double bond content of the polymer, and not merely the number of moles of polymer, will influence the number of moles of reactants utilized.)
The amount of haloacetyl halide reactant necessary in the reaction depends upon the amount of the initiator used. Therefore, for a lower amount of initiator a higher quantity of haloacetyl halide is necessary. It is advantageous to use 2 to 20 moles of haloacetyl halide per mole of double bond. In addition, as the molecular weight of the polymer increases, it is desirable that the molar percent of the haloacetyl halide increase. The reaction, then, may proceed in a mole ratio of double bondzhaloacetyl halide: free radical initiator of from about 1:20:02 to about 1:2:1. It is preferable to use 1 mole of initiator per mole of double bond. For a higher molecular weight polymer it is preferable to use 10 to 20 moles of haloacetyl halide per mole double bond, and for the lower molecular weight polymer it is preferred to use between 2 and moles.
The free radical addition of the haloacetyl halide takes place over a temperature range of 50 C. to 225 C. The exact temperature of the reaction is dependent upon the initiator and is chosen in such a manner as to provide the most efl'icient usage of the initiator over a reasonable length of time and which would allow for approximately 90% of the initiator to decompose. A suitable temperature range for the initiator, di-t-butyl peroxide is 125 C. to 170 C. The temperature range of 140-155 C. and total reaction time of about 3 to 20 hours is preferred for this initiator. It is desirable that a portion-wise addition of initiator be made. From 5 to portions may be added over a 2 to 5 hour period for the high molecular weight product and the total reaction time allowed for the adduct formation be between 3 and 6 hours. For the low molecular weight product, 2 additions of the initiator and a 20 hour total reflux period is advantageous with the above initiator.
In the polyamine addition step it is desirable, when reacting an amine with the haloacetyl halide-treated polymers, that the inverse addition of the reactants be followed. Thus, the haloacetyl halide adducts are added quite slowly to the amine. This technique prevents cross-linking, which leads to gels in high molecular weight polymers and affords mostly a one-ended type of product. The reaction temperature can vary from 25 C. to 175 C. It is preferred that the pot temperature be held between approximately C. to approximately 175 C. so as to drive the reaction to irnidazoline ring formation leaving only minor amounts of monoand di-substituted amides in the finished product.
In the displacement reaction, it is desirable to use an excess of the amine (from 1 to 20 moles of amine to each double bond per molecule of polymeric olefin, preferably 2 to 10 moles) in order to take up the hydrogen halide given off during the reaction as well as to give a high yield of the one-ended product and prevent cross-linking. In most cases a major proportion of the unreacted amine and the amine-hydrogen halide salt settles out upon cooling leaving only small amounts of same dispersed throughout the reaction mixture. The dispersed amine and the salt may be removed by 20 percent methanol water wash followed by centrifugation.
Another method of removing the hydrogen halide is to treat the haloacetyl halide adduct with alcohol in order to form the ester. Treatment of this product with an amine at temperatures of from about 150 C. to about 175 C. would then afford the same type of active site giving the alcohol back as a reaction product.
The preparation of the reaction product of this invention is illustrated in the following examples:
EXAMPLE I Preparation of low molecular weight dispersant In a three-necked 5 liter flask was placed 900 grams (0.75 mole) of Polybutene A and 254 grams (2.25 moles) of chloroacetyl chloride in 2 litersof decane. The resulting solution was then refluxed (pot temperature 150 C.) and 90 grams (1-00 mole percent) of di-t butyl peroxide added in 2 equal portions, 4 hours apart, with rapid stirring. The reflux period was extended an additional 16 hours, after which the excess chloroacetyl chloride was removed by atmospheric distillation. The resulting solution was then added slowly with rapid stirring to 361 grams (1.9 moles) of dried tetraethylene pentamine in 100 milliliters of refluxing decane. Upon completion of the addition, the mixture was refluxed another hour, cooled and added to approximately 5-8 liters of hexane. The resuliting mixture was washedwith 20 percentmethanolwater solution (1 part wash to 3 parts final reaction mixture) and centrifuged. The organic layer was removed, 200 grams of SW oil added and the hexane and decane solvents stripped under a vacuum (pot temperature 160 C. at 20 mm.). The final product weighed 1,088 grams and contained 811 percent polymer, representing 33 percent of the active ingredient. The basic nitrogen content by dialysis was 1.3 percent.
EXAMPLE II To a refluxing solution of 300 grams (0.15 mole) of Polybutene B and 100 grams (0.89 mole) of chloroacetyl chloride in 2 liters of decane (pot temperature -155" C.) was added 70 grams (400 mole percent) of di-t-butyl peroxide (divided into 7-10 gram portions and added over half hour intervals). After the last addition, the solution was refluxed for 16 hours. Upon completion of the reflux period, the excess chloroacetyl chloride was removed by atmospheric distillation and 60 grams (0.45 mole) of oxo-octyl alcohol added. The solution was refluxed an additional 4 hours and then added to 86 grams (0.45 mole) of dry tetraethylene pentamine. Upon completion of this addition, the solution was again refluxed another hour and then allowed to cool. The upper layer was decanted from the excess tetraethylene pentamine and added to 200 grams of SW oil. The entire solution was then stripped yielding a bright product weighing 575 grams, containing 35 percent active ingredient with a basic nitrogen content by dialysis of 0.95 percent.
EXAMPLE III To 400 grams of isobutylene-butadiene copolymer (intrinsic viscosity of 0.51, weight percent butadiene of 0.5) and 81 grams (0.7 mole) of chloroacetyl chloride and 1.5 liters of refluxing decane was added 12 grams (230 mole percent, 2 gram portions every half hour) of di-tbutyl peroxide. Upon completion of the addition, the solution was refluxed another hour after which the excess chloroacetyl chloride was removed by atmospheric distillation. The resulting solution was then added to 133 grams (0.7 mole) of dry tetraethylene pentamine, refluxed for an hour, cooled, decanted, and 3 liters of hexane added, along with 2000 grams of silica gel and 1000 grams of Celite. The entire mixture was rapidly stirred for 15 minutes, filtered, and a filtrate added to 300 grams of SW oil. The solvent was removed by vacuum stripping giving 390 grams of a product containing 23 percent active ingredient and having a basic dialysis nitrogen content of 0.48 percent.
EXAMPLE IV To refluxing solution of 400 grams of isobutylenebutadiene copolymer (intrinsic viscosity 0.67, weight percent butadiene 0.8) and 100 grams (0.89 mole) of chloroacetyl chloride in two liters of decane was added with rapid stirring. 12.5 grams (160 mole percent) of di-t-butyl peroxide was divided into 6 equal parts and added /2 hour apart. Upon completion of the addition, the solution was refluxed another hour after which the excess chloroacetyl chloride was removed by atmospheric distillation. The solution was then added slowly with rapid stirring to 151 grams (0.8 mole) of dry TEPA, refluxed for 2 hours, cooled, washed with 20 percent methanol-water, and centrifuged. The organic layer was removed and the polymer precipitated with methanolacetone twice, added to 300 grams of SW oil and the solvents removed on a steam plate. A bright, viscous product was obtained weighing 450 grams, containing 33 percent active ingredient with a percent basic N of 0.51 by dialysis.
EXAMPLE V A 400 grams sample of Butyl Rubber 218 (mole percent unsaturation 1.5-2.0) was dissolved and 3 liters of decane by use of heat and a high speed mixer. To this viscous solution was then added 150 grams (1.32 moles) of chloroacetyl chloride, the solution rapidly stirred and brought to reflux (pot temperature 155 C.) A total of 24.5 grams (130 mole percent) of di-t-butyl peroxide was added in 7 equal portions /2 hour apart. At the end of the addition period, the solution was refluxed another hour after which the excess chloroacetyl chloride was removed by atmospheric distillation. The resulting solution was then added slowly with stirring to 151 grams (0.8 mole) of dry TEPA followed by another hour reflux period. At the end of this reflux period the solution was cooled and 3 liters of hexane added. The entire mixture was then washed with 30 percent methanol-water and centrifuged. The organic layer was removed and the polymer was precipitated twice with methanol-acetone. The polymer was then redissolved in 1350 grams of SW oil yielding 1700 grams of a dark, clear, viscous product, containing 0.29 percent basic N by dialysis and 20 percent active ingredient.
The reaction product of this invention, when incorporated in a hydrocarbon oil of lubricating viscosity, exhibits exceptional dispersant qualities without leaving an ash residue in the engine. In addition to petroleum hydrocarbon sources, synthetic or other natural hydrocarbon oils may be used to provide the base oil. The reaction product above described will normally constitute from about 1 to 20 Weight percent of the lubricant, but this percentage may be higher or lower. The percentage will usually depend upon the nature of the dispersant product, e.g. high molecular weight or low molecular weight; the use to which the lubricant will be put; and the use to which the additive will be put, e.g. no VI improvement, some VI improvement or total VI improvement. The preferable range of the lower molecular weight product in lubricating oil is from 3 to 5 weight percent, and for the higher molecular weight product, exhibiting total VI improvement, from 1 to 15 weight percent.
While the above described reaction products can be suitably employed alone in the base oil, they are usually used in combination with other lubricant addition agents which impart various desirable characteristics to the base oil. Thus, although these reaction products exhibit a marked effectiveness in VI improvement and dispersancy, it may be necessary, depending upon the use of the lubricant, to incorporate other additives in the base oil, e.g. corrosion and rust inhibitors, pour point depressants, foam inhibitors, etc. Other lubricant addition agents can be used in combination with the additive of this invention.
A number of performance tests for evaluating the characteristics of lubricating oils were conducted. A test, made to determine the anti-sludge properties of the oil, is known as the Lincoln MS Test, Sequence V, developed by the Ford Motor Company. Briefly, the test consists of using the oil to be tested as a lubricating oil in a V-8 Lincoln engine under prescribed test conditions Accordingly 5 quarts of oil are placed in the crankcase and the engine is started and run in accordance with the 4 hour cycle:
l Phasel Pl1ase2 I Phase3 The four-hour cycle is reset a total of 48 times 192 hours running time. After each 16 hours of operation the engine is shut down for 8 hours. Twoounce samples of oil are taken every 30 hours and the oil level is adjusted with fresh oil to a level of five quarts. Addedoil is weighed. At the end of the test, the hot oil is drained, weighed and recorded. The engine is then disassembled and inspected for deposits of varnish and sludge among other observable results as set out in the table below.
Engine components are examined visually and rated. All
of the following ratings are considered perfect: 50 for total sludge and for total varnish; 0 percent for oil ring groove filling (ORGF) and oil screen clogging; and 10.0
for piston varnish. The following ratings are considered passing: 60 percent or lower for screen clogging; 50 percent or lower for ring plugging; 26 or higher for total sludge; and 7 or higher for piston varnish. v
The following results may be considered under 3 headings:
Class I.Low molecular weight (under 2500) dispersantno VI improvement;
Class II.Intermediate molecular weight (between 2500 and 30,000) dispersantsome VI improvement (supplemented with small amounts of VI improver); and
Class III.I-Iigh molecular weight (above 30,000) dispersantt0tal VI improver combination.
CLASS I Formulation Rating Sample Wt. Base Oil Percent Total Total Percent Percent Piston Additive active Sludge Varnish ORGF Oil Screen Varnish ingredient in base oil Reaction product of l. O Multi-graded premium oil--. 37 43 0 9. 0
Example I. do l. do 48 43 0 l 9. 0 do 1. 5 Extended drain oil 45 35 0 0 8. 0 A current commercial 1. 6 Multi-graded premium oil 35 35 0 8. 0
dispersant. do 2. 4 do 45 40 0 8i 0 CLASS II Reaction product of 2. O Multi-graded oll.- 47 39 19 2 8. 5
Example 3. 7 A current commercial 1. 0 .do 2O 32 98 50 6. 0
product.*
CLASS III 8 Reaction product of 2.0 Premium oil 45 45 9. 4 10 10.0
Example 4. 9 Reaction product of 2. 0 do 45 44 13 1 8. 6
Example 5. 10 A current commercial 1. 0 do 32 98 50 6.0
product.*
*The additive used in Samples 7 and 10 is the most comparable commercial dispersant-VI improver combination available. However, due to difierenc es in structure of these products with the products of this invention, a true weight percentage comparison is impossible. To use more than 1.0 percent active ingredient would be detrimental to the VI improvement properties necessary for a properly multi-graded oil composition. Therefore, a 2.0 weight percent act1v1ty of this commercial product would cause the oil to fall outside the acceptable viscosity range for multi-graded oils andwould not appreciably change the ratings.
It is significant to note that in most cases a considerably smaller quantity of the reaction product of this invention was used to obtain results comparable to or better than a typical commercially available product now being used. While the commercially available dispersants are somewhat effective, as regards to 'dispersancy, it is necessary to incorporate with them an additional VI improver for multi-graded oils. This is not necessary when using my high molecular weight composition inasmuch as it exhibits excellent VI improvement. Furthermore, only a small amount of VI improver is necessary when using an intermediate molecular weight product of this invention. The following indicates the effectiveness of the high molecular product of Example V as a viscosity index improver:
A further illustration of the usefulness of this invention is provided by an examination of the results of sludge spot dispersancy test. In this test oil formulations already tested under control tests at various levels of dispersancy in a standard engine detergency-dispersancy test are employed as source of in engine produced sludge. A composite of these used formulations is made and thoroughly mixed. A weighed amount of used oil composite and a weighed amount of the detergency candidate are combined and heated to 300 F. Thereafter this mixture is added to an equal volume of fresh unused, unformulated SAE 20 oil also at 300 F. The resultant mixture is held at 300 F. for two hours. Thereafter, while thoroughly stirring the hot mixture of fresh oil, used oil and detergency candidate, duplicate drop (from capillary pipette) portions are placed on blotting paper. The blotting paper so treated is permitted to stand for 12 to 16 hours. There are two concentric circles where each three drop deposit is made. The inner circle is black and the outer annulus is somewhat clear. For each of the duplicate spot tests the diameters measurements are made by measuring the spot rating which will be obtained in a Lincoln Sequency V" engine test but when used with a control spot test (no fresh detergent) and compared with known high detergency additives tested at the same time the relative order of the SDT numbers are indicative of performance 7 to be expected from actual Lincoln SequenceV tests. SDI
number values of 60 to for detergency' candidates areindicative of likely success in attaining a passing total sludge value rating and not that a particular total sludge value rating will be achieved for any particular SDT number value in the 60 to 80 range.
Compound: SDT rating Sample X.Polybutene A-chloroacetyl' chlorideTETA 73 Sample Y.Polybutene Ac-hloroacetyl chloridePEHA 83" Sample Z.Polybutene Bchloroacetyl chloride-TEPA 81 Unless otherwise stated, the percentages statedher'ein and in the claims are weight percentages.
While I have described my invention by reference to specific embodiments thereof, the same are given by way of illustration. Modifications and variations will be ap-* parent from my description of those skilled in the art.
I claim:
1. A process for the preparation of a lubricant oil soluble product from a polyalkylene' amine havingthe formula wherein x is an integer from 2 to about 10, R is hydrogen 9 10 or lower alkyl and alkylene is lower alkylene of from 1 References Cited to 8 carbon atoms, a polyolefin and an u-haloacetyl halide UNITED STATES PATENTS which comprises first reacting at 50 to 225 C. an ochaloacetyl halide with a polymeric olefin having a molec- 3,219,666 11/1965 Norman et 252-5L5 X ular Weight in the range of from about 300 to 550,000 in 5 3,272,746 9/1966 Le Suer et X the presence of a free radical initiator and then adding said free radical initiated reaction product slowly to said FOREIGN PATEFITS polyalkylene amine at 25 to 175 0. 983,040 2/1965 Great i 2. The process of claim 1 wherein the whaloacetyl halide is a-chloroacetyl chloride and the polyalkylene 10 DANIEL WYMANPHmary Emmmer amine is tetraethylene pentamine. P. P. GARVIN, Assistant Examinr.
Claims (1)
1. A PROCESS FOR THE PREPARATION OF A LUBRICANT OIL SOLUBLE PRODUCT FROM A POLYALKYLENE AMINE HAVING THE FORMULA
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB983040A (en) * | 1962-10-08 | 1965-02-10 | Shell Int Research | Ashless lubricant additives, their preparation and lubricants containing them |
US3219666A (en) * | 1959-03-30 | 1965-11-23 | Derivatives of succinic acids and nitrogen compounds | |
US3272746A (en) * | 1965-11-22 | 1966-09-13 | Lubrizol Corp | Lubricating composition containing an acylated nitrogen compound |
-
1965
- 1965-06-14 US US463924A patent/US3340281A/en not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3219666A (en) * | 1959-03-30 | 1965-11-23 | Derivatives of succinic acids and nitrogen compounds | |
GB983040A (en) * | 1962-10-08 | 1965-02-10 | Shell Int Research | Ashless lubricant additives, their preparation and lubricants containing them |
US3272746A (en) * | 1965-11-22 | 1966-09-13 | Lubrizol Corp | Lubricating composition containing an acylated nitrogen compound |
Cited By (172)
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