|Número de publicación||US3379811 A|
|Tipo de publicación||Concesión|
|Fecha de publicación||23 Abr 1968|
|Fecha de presentación||3 Feb 1965|
|Fecha de prioridad||22 Feb 1964|
|También publicado como||DE1435461A1, DE1435461C3|
|Número de publicación||US 3379811 A, US 3379811A, US-A-3379811, US3379811 A, US3379811A|
|Inventores||Hartmann Ludwig, Riedmuller Walter, Muller Gerhard|
|Cesionario original||Freudenberg Carl|
|Exportar cita||BiBTeX, EndNote, RefMan|
|Citas de patentes (9), Citada por (93), Clasificaciones (21)|
|Enlaces externos: USPTO, Cesión de USPTO, Espacenet|
April 23, 1968 L. HARTMANN ET AL 3,379,811
APPARATUS AND PROCESS FOR PRODUCTION OF FILAMENTS Filed Feb. 3, 1965 I lll :Iluplllnll I, .Il Y
I FIG. B.
INVENTORS LUDWIG HARTMANN WALTER RIEQMULLER GERHARD MULLER ATTORNEYS.
3,379,811 APPARATUS AND PRGCESS FR PRODUCTIQN F FlLAP/IENTS Ludwig Hartmann, berilockenbach, Walter Riedmiiller,
Heppenheim, and Gerhard Mller, Morlenhach, Germany, assignors to Carl Freudenberg, Weinheim an der Bergstrasse, Germany, a corporation of Germany Filed Feb. 3, 1965, Ser. No. 430,092 Claims priority, application Germany, Feb. 22, 1964, F 42,095 9 Claims. till. 26d- 210) ABSTRACT 0F THE DSCLOSURE Filament-spinninf7 apparatus and process including a substantially coplanar row of spinning orifices adapted to spin a substantially coplanar row of filaments therethrough and means on each side of the row of orifices and filaments for impinging a fluid, preferably air, onto the filaments as spun, whereby to draw the filaments wherein the impinging air emerges from slits. Means are provided for rendering the air emerging from the slits, both non-turbulent and substantially uniform in velocity from one end of the slit to the other. These means include two successive channels connected to each other through conduit means with one of the channels being connected to each slit with the air being introduced into the channel furthest from the slit in order to permit the air to pass through both channels, the conduit means therebetween and the conduit means between one channel and the slit disn charge opening in such manner as to emerge substantially non-turbulent and with substantially uniform velocity.
The present invention relates to the production of filaments. More particularly, the invention is concerned with the production of filaments direct from a melt of the material composing the filaments.
In the usual manner of producing textile products, the filaments are formed in for example, a spinning process and are collected on spools. Then the textile product is formed by the working of filaments withdrawn from the spools. Several attempts have been made to provide a procedure wherein the textile products are formed concurrently with the production of the filaments, so that the step of collecting the fibers on spools is eliminated. in particular, attempts have been made to produce non-woven fabrics in this manner. Thus, polymer melts have been sprayed from a spray gun onto a form provided. for the r production of a fabric. The resulting products are in general not satisfactory since the filaments are of low strength. Such filaments do not have a molecular orientation as is desired for the fibers. It has also been proposed to subject filament forms issuing from various discharge devices to the influence of electrical forces so that the filaments are changed to cobweb-like structures- The cobweb is then collected on a suitable form. These products do not have as high a strength as is desired.
in the previous attempts to form fabrics direct from a melt, described above, the melt outlet openings have been of l mm. diameter, which is customary for melt spinning processes. It has also been proposed to utilize smaller outet openings and to direct air currents along the path of the melt streams issuing from the outlet openings. Electrical forces can also be utilized. The filaments are then col- 6 lected on a suitable form for the desired fabric. In these prior art attempts, diftlc lty is encountered in the respect that as the width 0f the fabric is increased, the distribution and structure of the fabric tend to become non-uniform. The number of discharge devices is increased in order to increase the width and the various forces existing during production of the fieeces inter-act so that ted States Patent O 3,379,3ll Patented Apr'. 23, 1968 ICC non-uniformity results in the product. These fabrics have the further disadvantage that the filaments thereof do not have desired molecular orientation.
Still another procedure for the `production of nonwoven fabrics direct from a melt is the subject of US. application Ser. No. 341,489, filed Ian. 27, 1964 and assigned to the assignee of the present application. ln the process of that application, a spinning head is used which has a plurality of melt outlet openings disposed at spaced intervals along a straight line of any suitable length, for eX- arnple a length equal to the desired width of the fabric being produced. Melt is discharged from the melt outlet openings, and simultaneously air streams generally parallel to the plane along which the melt streams move, are directed into impinging relation with the melt streams. The air streams and the melt streams enter a guide passageway which is a channel open at both ends and serves to define the path of travel of the laments as they move from the spinneret head to the form on which they are collected. The gas stream also passes through the guide passageway.
The melt streams re drawn by the gas stream into filaments and the gas stream then serves to cool the filaments to the desired extent, prior to collection thereof as a fleece. This procedure provides the desired molecular orientation, and, further, is suitable for production of iieeccs of substantial width. This procedure, however, as practiced heretofore involves difficulty due to turbulence of the gas streams which results in a measure of non-uniformity. This is particularly significant in respect to the production of thin fieeces. The turbulence is due, at least in part, to the structure of the spinning devices used. The conditions of temperature and pressure require supporting members for the spinning devices which are in the path of the gas streams, and thus cause turbulence.
It is the principal object of the instant invention to obviate the disadvantages mentioned for the spinning devices just described.
The manner in which this and other objects are attained, will be best understood by reference to the following description, taken in reference to the accompanying drawings, wherein:
FlG. l is a cross-sectional view of the back member of the spinneret head shown in FIG. 2;
FIG. 2 is a cross-sectional View of a spinneret head according to the invention;
FiG. 2a is an enlarged view of a portion of the spinneret head shown in FIG. 2; and
FlG. 3 is a perspective view of a spinneret head according to the invention and a guide passageway, and also indicates the path of melt streams from the spinneret head.
According to the invention, the spinning device is suitable lfor spinning a plurality of filaments from a melt by discharging a like number of Streams of the melt and drawing the streams into the filaments with a fluid, preferably a gas and commonly air or stream or air and steam. The head includes means dening a plurality of melt outlet openings for discharging the streams from the melt, and includes two slot discharge openings disposed opposite each other across the melt outlets for delivery of the gas to impinging relation with the melt streams to draw the streams into the filaments. The invention is characterized in that the gas is delivered to the melt streams in a manner that low turbulence exists. The spinneret head is provided with means for delivering the gas to the slot discharge openings, and reducing turbulence of the gas. Thus, the head can include an elongated distribution chamber ttor each slot discharge, which extends over the length of the slot discharge and is adapted for receiving the air for delivery to the slot discharge openings, and a passageway which communicates each o-f the distribution chambers with its slot discharge opening. The passageways have means for reducing turbulence of the fluid passed therethrough -to the slot discharge openings. Desirably, the passageways include directional changes and changes in cross-section. In one construction for the spinneret head, found `well suited for the purposes of the invention, each of the passageways includes a length adjacent its discharge opening and terminating thereat, which diverges towards its slot discharge opening, and each of the passageways has a restriction therein on the distribution chamber side of the diverging length thereof, ifor reducing pressure of the iiuid flowing through the passageway. The head is constructed lsuch that the flow paths through the two distribution chambers and the passageways is the same. Further, the device of the invention includes an elongated filament guide passageway for receiving the filament material issuing from the melt outlet openings and guiding it on to the form on which the textile product is produced. The guide passageway is open at both ends and is disposed in spaced relation with respect to the melt outlet openings. It receives the melt streams and also the gas brought into impinging relation with the melt streams.
Referring to the drawings, as is shown in FIG. 2, a spinneret head includes a back member a, and a iront member a. The back member is shown disassembled `from the spinneret head in FiG. 1.
The back member a can be milled from a steel plate and includes a cone-shaped nozzle b which extends over the length of the head (see FIG. 3), and is provided along the apex thereof, at spaced intervals, with melt outlet openings m. The angle of the cone-shaped nozzle can be about l-45, and the apex of the cone can be cut away about 1.0-3 mm. from the apex, to provide a nozzle discharge edge p of about 1.4-2 mm, height. The melt outlet openings m can be spaced 1.0- mm., center to center, and preferably they are spaced about 2 mm. The diameter of the melt outlet openings m can be 0.1-0.6 mm., and the melt openings are disposed along a straight line. The openings are -disposed at mid-points along the height of the edge p. The back member has a bore q leading to the melt discharge openings m. Further, the back member is milled to provide the channels e and d, as to which more will be said shortly.
The -txront member a is rformed of two like elements r and s, positioned one on either side of the cone-shaped nozzle b. The rear side of element r and element s of the front member a' is each milled to provide a channel z, which, when the front member and the back member are assembled, opens into one of the channels e of the back member so that together there is yformed a distribution channel for the gas, for receiving the gas and distributing it over the length of the slot discharge opening shortly to be described. Further, the front members r and s are provided with recesses t which, when, the members are assembled, communicate the distribution chambers e, z with the channels d in the back plate, and the end portions j of the front member elements r and s are positioned and formed so that the ends f define with the cone-shaped nozzle b of the back plate two passageways disposed one on either side of the cone-shaped nozzle b, each terminating in an elongated slot g which extends over the length of the line of melt outlet openings in the cone-shaped nozzle b. Thus, a passageway is provided -from each of the distribution chambers e, z to the slot discharge openings g. Also, the ends f of the front member elements form with the cone-shaped nozzle b a length of passageway adjacent each of the slot discharge openings, terminating at the slot discharge openings, which lengths diverge towards the slot discharge openings.
The inserts j are xedly secure in the 'front member elements r and s and serve as baflies to direct gas flow from the distribution chambers e, z into the channels d.
Thus, the spinning head is constructed so that there are directional changes along the flow path from the distribution chambers to the slot discharge openings. Furi ther, the cross-section, i.e. the cross-sectional flow area, of the path from the distribution chambers e, z to the slot discharge openings g, chan-ges. These construction features serve to reduce the turbulence of the gas stream issuing from the Slots g.
Also, on the distribution chamber side of the diverging lengths u, restrictions are disposed in the path of the gas. Thus, `the lip h in each of the lfront member elements provides a restriction or oriiice in the flow path of the gas, and, further, the insert j is positioned in a manner such that restriction k is provided. This construction causes the turbulence of gas issued from the melt outlet openings g to be low.
The number of melt outlet openings can be -300; more or less can also be used. The distribution channels can extend into the front and back members a distance of about 7-35 mm., and the width of the channel e can be about l0 mm. The distribution chambers are disposed parallel to the slot discharge openings g, and the flow path from one distribution chamber e, z to its slot discharge opening g is the same as the flow path from the other distribution chamber e, z to its discharge slot g, so that flow conditions along the two paths from the distribution chambers will be substantially the same. The width of the slot discharge openings g can be 0.3 mm.
As is indicated in FIG. 3, the distribution chambers have connected to the ends thereof gas inlet conduits o. A gas inlet conduit is connected to each end of each of the distribution chambers. Desirably these inlet conduits are connected to a common source of gas.
Due to the manner in which the spinning head is constructed, gas is discharged from the slot discharge openings g which is of low turbulence to the extent that improved results are realized in respect to the production of iieeces. In the passage of the gas from the distribution chambers to the slot discharge openings, a continuous change in ow velocity occurs, and a pressure drop occurs, for example a pressure drop of from 0.14 atmospheres gauge to 0.11 atmospheres gauge. This is a pressure drop of about 20% and a pressure drop in the amount of about 15-3 0% is desirable. In the lengths u of the passageways, the conditions of the gas are substantially the same, and, accordingly, the gases are delivered from the slot discharge openings in about the same conditions so that improved operation is realized.
As the melt streams issue from the melt outlet openings m, they are engaged by the gas streams, and over a distance of about 5 mm. from the outlet openings for the melt, the gas streams greatly extend the filaments. For exam-ple, for an outlet opening size of 400 microns, the melt streams can be drawn into filaments of 1 micron diameter and this extension takes place substantially within the distance of 5 mm. This great elongation effects a desired molecular orientation for the filaments, and is done without substantial breakage of the filaments.
The invention further provides a guide passageway s (see FIG. 3) for the filaments. The guide passageway is open at both ends and is disposed in spaced relation with respect to the melt outlet openings m. It receives the filaments from the outlet openings and also receives the gas from the slot discharge openings g, and the guide passageway guides the filaments on their way to the form (not shown) on which they are collected for the making of the fabric. The guide passageway can be spaced 3-8 cm., preferably about 5 cm.from the melt outlet openings m. For a length of 320V mm. for the cone-shaped nozzle b, the length of the slot discharge openings g can be about 340 mm., and the length of the inlet opening of the guide passageway s can be about 360 mm. Preferably these elements are related in this manner, i.e. the length of the cone-shaped nozzle b is less than the length of the gas slot discharge openings, and the corresponding dimension of the guide passageway is greater than the length of the slots. The width of the inlet opening to the guide channel s' can be about 3 cm. The length of the guide channel is such that the elongation of the filaments is complete before the filaments leave the guide passageway. As indicated previously, by far the greater part of the expansion occurs immediately following issuance of the melt streams from the melt outlet openings m, but some further elongation occurs. The filaments become set during the course of travel through the guide passageway. For example, for polycaprolactam, the 4length of the guide passageway can be 40 om.
As is indicated by the arrows r (FIG. 3) some gas is aspirated from the vicinity of the spinning head into the guide passageway, by reason of the movement of the gas streams from the slot discharge openings g. Due to the fact that these gas streams are at the same conditions, uniform aspiration occurs, so that the aspiration effect does not cause harmful turbulence.
The amount of gas which is aspirated into the inlet opening p of the guide passageway s will depend on the conditions, and particularly on the condition of the gas streams issuing from the slot discharge openings g. The aspirated air, which can be called second-ary air, can exceed in amount the gas streams from the slot discharge openings g. For example, the secondary air can be ten times the amount of gas from the slot discharge openings. This is an important aspect of the operation of the spinning head. The secondary gas stream may contribute to the cooling of the melt streams and/or may serve to facilitate evaporation of solvent from the melt streams, whereby the solidification of the threads is effected. Further, the secondary gas streams may facilitate the obtaining of a desired water 'content for the fibers. Thus, the secondary stream may assist the adiabatic cooling of the gas streams from the slot discharge openings so that the desired take-up of water by the fibers is obtained. On the other hand, the secondary gas stream may be used to remove excess moisture from the fibers. Also, of course, the secondary gas streams aid in the setting of the filaments at the desired molecular orientation, and aid in the guiding of the filaments on their course through the guide passageway.
It will be appreciated that the guide passageway s performs the important function of maintaining the individual filaments substantially out of contact with each other during the setting thereof. After leaving the guide passageway s the filaments are collected as a non-woven fieece on suitable forms. Substantial contacting of the different filaments does not occur until just shortly before the filaments are collected on the form. This is an important characteristic of the device of the invention, since, by reason of such operation, it is possible to obtain fieeces of good uniformity.
A plurality of spinning heads according to the invention can be used together, and in such operation each spinning head is provided with its own guide channel. Further, the guide channel or channels can be rocked to provide a desired shifting of the fibers so that good intermixing of the fibers in the non-woven fleece is obtained. Where several spinning heads are used, different melt compositions can be discharged from the various heads to produce fieeces of mixed composition.
The spinning head of the invention is Well suited for the spinning of polymer compositions in general. It can be used for spinning of filaments of polyamides, polyesters, polyolefins, polyurethanes, etc. The melt can be a solution, and the melt can contain softeners and other modifying agents. The device can also be used for production of rayon fabrics, particularly when using a collecting form suitable for rayon, such as, for example, that illustrated in FIG. 14 or FIG. 13 of the above-mentioned co-pending application, Serial No. 341,489, filed January 27, 1964.
The spinning head is well suited for use of steam as the gas utilized to draw the filaments. Water vapor-air mixtures can mso be used. 'The use of water vapor or steam offers the possibility of controlling the moisture content of the filaments. As is indicated above, the use of steam or water vapor-air mixture as the gas stream can be correlated with the secondary air stream which is aspirated into the guide passageway s in a manner as will permit close and accurate control of the moisture content of the filaments.
The spinning head of the invention provides the further advantage that the air streams supplied are at substantially uniform conditions across the entire cross-sectional flow area. Thus, the gas on each side of the filaments is at the same condition, while at the same time the conditions of the gas along the width of the filaments is the same.
EXAMPLE Polycaprolactam (nylon 6) was spun with a spinning nozzle according to the invention, under the followlng conditions:
Melt outlet openings, number Melt outlet diameter microns 400 Melt outlet spacing, center to center mm 2 Slot discharge opening, length mm 340 Slot discharge opening, width mm 0.3 Nozzle temperature C-.. 225 Gas mixture, air:watervapor 10:1 Gas temperature in slots C 225 Gas quantity Nm3/min-- 1.5 Guide passageway inlet opening, length mm 380 Guide passageway inlet, width mm 30 Guide passageway length mm-- 600 Fiber titer den-- 1 While the invention has been described with respect to particular embodiments thereof, it will be understood that these embodiments are merely representative of the invention and do not serve to provide the limits thereof.
What is claimed is:
1. In an apparatus for spinning a plurality of filaments which apparatus comprises at least one elongated spinneret having a plurality of substantially coplanar spinning orifices therein; a pair of fiuid outlet slit means on either side of said spinning orifices; means to feed polymer to said spinning orifices; and means to feed a fluid to each of said slit means; the improvement which comprises said fiuid feeding means comprising a first channel means operatively connected to said slit means via conduit means; a second channel means operatively connected to said first channel means via conduit means; and means for feeding said fiuid to said second channel means whereby fiuid emitted from said slit means is at substantially the same velocity at substantially all points therealong.
2. The improved apparatus claimed in claim l wherein said channels are substantially parallel.
3. The improved apparatus claimed in claim 2 wherein said slit means is substantially parallel to said first channel.
4. The improved apparatus claimed in claim 1l, including a multiplicity of conduit means between said first and second channels.
5. The improved apparatus claimed in claim 1, including at least one turbulence-reducing insert in said conduit means.
6. The improved apparatus claimed in claim 1, including means, at both ends of said second channel, for introducing said fiuid thereinto.
7. In the process of producing drawn filaments which comprises issuing polymer in filament form from a row of substantially coplanar spinning orifices, impinging a fiuid onto both sides of said row of filaments at a velocity higher than the filament velocity, and drawing said filaments with said fiuid; the improvement which comprises passing said fluid through multiple successive channel means connected to each other through conduit means prior to impingement thereof onto said filaments which passage substantially reduces the turbulence of said fiuid and makes the velocity of said fiuid substantially uniform upon impingement.
References Cited UNITED STATES PATENTS 2,411,660 11/1946 Manning 264-176 10/1951 Ladisch 264-176 Anderson et al 264-168 Detzsch et a1. 264-168 Stevens 264-167 Buschmann et a1. 264-176 Vinicki 264-176 Oberly 264-210 Bauer 264-207 DONALD I. ARNOLD, Primary Examiner.
|Patente citada||Fecha de presentación||Fecha de publicación||Solicitante||Título|
|US2411660 *||22 May 1943||26 Nov 1946||Fred W Manning||Method of making filter cartridges, abrasive sheets, scouring pads, and the like|
|US2571457 *||23 Oct 1950||16 Oct 1951||Ladisch Rolf Karl||Method of spinning filaments|
|US2584043 *||20 Jun 1945||29 Ene 1952||American Viscose Corp||Method and apparatus for processing filamentary materials|
|US2697251 *||7 Feb 1951||21 Dic 1954||American Viscose Corp||Method and apparatus for manufacturing artificial filaments|
|US3163691 *||25 Nov 1960||29 Dic 1964||Du Pont||Process and apparatus for three layer net extrusion|
|US3197812 *||30 Abr 1962||3 Ago 1965||Dietzsch Hans-Joachim||Spinning head with plural nozzles|
|US3312766 *||5 May 1964||4 Abr 1967||Stevens Alexander Michael||Extrusion of plastic tubes of varying diameter|
|US3320343 *||9 Sep 1963||16 May 1967||Schwarza Chemiefaser||Process for melt-spinning of synthetic linear high polymers|
|US3335210 *||29 Oct 1963||8 Ago 1967||Monsanto Co||Filament yarn spinning apparatus and method|
|Patente citante||Fecha de presentación||Fecha de publicación||Solicitante||Título|
|US3497586 *||4 Ene 1968||24 Feb 1970||Fmc Corp||Process and apparatus for melt spinning thermoplastic yarn|
|US3528129 *||7 Nov 1966||15 Sep 1970||Freudenberg Carl Kg||Apparatus for producing nonwoven fleeces|
|US3543332 *||28 Jun 1968||1 Dic 1970||Celanese Corp||Apparatus for producing fibrous structures|
|US3865535 *||4 Jun 1973||11 Feb 1975||Beloit Corp||Two piece die assembly for extruding micro-filaments|
|US3890184 *||12 Oct 1973||17 Jun 1975||Exxon Research Engineering Co||Method of making extruded rib battery separators|
|US3942723 *||24 Abr 1974||9 Mar 1976||Beloit Corporation||Twin chambered gas distribution system for melt blown microfiber production|
|US3954361 *||23 May 1974||4 May 1976||Beloit Corporation||Melt blowing apparatus with parallel air stream fiber attenuation|
|US3970417 *||24 Abr 1974||20 Jul 1976||Beloit Corporation||Twin triple chambered gas distribution system for melt blown microfiber production|
|US3985481 *||24 Sep 1975||12 Oct 1976||Rothmans Of Pall Mall Canada Limited||Extrusion head for producing polymeric material fibres|
|US4073850 *||9 Dic 1974||14 Feb 1978||Rothmans Of Pall Mall Canada Limited||Method of producing polymeric material|
|US4241002 *||24 May 1978||23 Dic 1980||Standard Oil Company (Indiana)||Process for producing homogeneous curly synthetic polymer fibers|
|US4295809 *||14 Sep 1979||20 Oct 1981||Toa Nenryo Kogyo Kabushiki Kaisha||Die for a melt blowing process|
|US4380570 *||8 Abr 1980||19 Abr 1983||Schwarz Eckhard C A||Apparatus and process for melt-blowing a fiberforming thermoplastic polymer and product produced thereby|
|US4660228 *||3 Jul 1985||28 Abr 1987||Kanebo, Ltd.||Glove|
|US4668566 *||7 Oct 1985||26 May 1987||Kimberly-Clark Corporation||Multilayer nonwoven fabric made with poly-propylene and polyethylene|
|US4724109 *||2 Ene 1986||9 Feb 1988||Denki Kagaku Kogyo Kabushiki Kaisha||Process for production of continuous inorganic fibers and apparatus therefor|
|US4753834 *||2 Abr 1987||28 Jun 1988||Kimberly-Clark Corporation||Nonwoven web with improved softness|
|US4778460 *||7 Oct 1985||18 Oct 1988||Kimberly-Clark Corporation||Multilayer nonwoven fabric|
|US4818463 *||20 Nov 1987||4 Abr 1989||Buehning Peter G||Process for preparing non-woven webs|
|US4874659 *||23 Oct 1985||17 Oct 1989||Toray Industries||Electret fiber sheet and method of producing same|
|US4889476 *||10 Ene 1986||26 Dic 1989||Accurate Products Co.||Melt blowing die and air manifold frame assembly for manufacture of carbon fibers|
|US4999080 *||26 May 1989||12 Mar 1991||Corovin Gmbh||Apparatus for producing a nonwoven fabric from continuous filaments|
|US5046225 *||23 Feb 1990||10 Sep 1991||Rieter Machine Works, Ltd.||Drawing bath|
|US5080569 *||29 Ago 1990||14 Ene 1992||Chicopee||Primary air system for a melt blown die apparatus|
|US5087186 *||3 Abr 1989||11 Feb 1992||Accurate Products Co.||Meltblowing apparatus|
|US5196207 *||27 Ene 1992||23 Mar 1993||Kimberly-Clark Corporation||Meltblown die head|
|US5269670 *||24 Ago 1992||14 Dic 1993||Exxon Chemical Patents Inc.||Meltblowing die|
|US5286182 *||6 Ene 1992||15 Feb 1994||Mitsubishi Kasei Corporation||Spinning nozzle for preparing a fiber precursor|
|US5292068 *||17 Ago 1992||8 Mar 1994||Nordson Corporation||One-piece, zero cavity nozzle for swirl spray of adhesive|
|US5292239 *||1 Jun 1992||8 Mar 1994||Fiberweb North America, Inc.||Apparatus for producing nonwoven fabric|
|US5307547 *||25 Jul 1991||3 May 1994||Rieter Machine Works, Ltd.||Process and device for hydrodynamic drawing of a polymer thread|
|US5336071 *||19 May 1993||9 Ago 1994||Mitsui Petrochemical Industries, Ltd.||Air gun for the production of non-woven fabric and non-woven fabric producing apparatus|
|US5342335 *||22 Dic 1993||30 Ago 1994||Kimberly-Clark Corporation||Nonwoven web of poly(vinyl alcohol) fibers|
|US5350624 *||5 Oct 1992||27 Sep 1994||Kimberly-Clark Corporation||Abrasion resistant fibrous nonwoven composite structure|
|US5407619 *||6 Oct 1993||18 Abr 1995||Mitsubishi Kasei Corporation||Process for preparing a fiber precursor of metal compound, and a process for preparing a fiber of metal|
|US5445509 *||14 Feb 1994||29 Ago 1995||J & M Laboratories, Inc.||Meltblowing die|
|US5445785 *||22 Dic 1993||29 Ago 1995||Kimberly-Clark Corporation||Method of preparing a nonwoven web of poly(vinyl alcohol) fibers|
|US5508102 *||20 Jun 1994||16 Abr 1996||Kimberly-Clark Corporation||Abrasion resistant fibrous nonwoven composite structure|
|US5700254 *||22 May 1995||23 Dic 1997||Kimberly-Clark Worldwide, Inc.||Liquid distribution layer for absorbent articles|
|US5876388 *||16 Feb 1996||2 Mar 1999||Kimberly-Clark Worldwide, Inc.||Liquid distribution layer for absorbent articles|
|US5935512 *||18 Dic 1997||10 Ago 1999||Kimberly-Clark Worldwide, Inc.||Nonwoven process and apparatus|
|US6022818 *||2 Abr 1996||8 Feb 2000||Kimberly-Clark Worldwide, Inc.||Hydroentangled nonwoven composites|
|US6136245 *||23 Jul 1997||24 Oct 2000||Ason Engineering, Inc.||Method for producing non-woven webs|
|US6183670||23 Sep 1997||6 Feb 2001||Leonard Torobin||Method and apparatus for producing high efficiency fibrous media incorporating discontinuous sub-micron diameter fibers, and web media formed thereby|
|US6315806||1 Jun 2000||13 Nov 2001||Leonard Torobin||Method and apparatus for producing high efficiency fibrous media incorporating discontinuous sub-micron diameter fibers, and web media formed thereby|
|US6364647||8 Oct 1998||2 Abr 2002||David M. Sanborn||Thermostatic melt blowing apparatus|
|US6709526||7 Mar 2000||23 Mar 2004||The Procter & Gamble Company||Melt processable starch compositions|
|US6723160||1 Feb 2002||20 Abr 2004||The Procter & Gamble Company||Non-thermoplastic starch fibers and starch composition for making same|
|US6799957||7 Feb 2002||5 Oct 2004||Nordson Corporation||Forming system for the manufacture of thermoplastic nonwoven webs and laminates|
|US6802895||19 Dic 2003||12 Oct 2004||The Procter & Gamble Company||Non-thermoplastic starch fibers and starch composition for making same|
|US6811740||1 Feb 2002||2 Nov 2004||The Procter & Gamble Company||Process for making non-thermoplastic starch fibers|
|US6955850||29 Abr 2004||18 Oct 2005||The Procter & Gamble Company||Polymeric structures and method for making same|
|US6977116||29 Abr 2004||20 Dic 2005||The Procter & Gamble Company||Polymeric structures and method for making same|
|US7018188||8 Abr 2003||28 Mar 2006||The Procter & Gamble Company||Apparatus for forming fibers|
|US7025821||7 Oct 2004||11 Abr 2006||The Procter & Gamble Company||Non-thermoplastic starch fibers and starch composition for making same|
|US7029620||13 Mar 2003||18 Abr 2006||The Procter & Gamble Company||Electro-spinning process for making starch filaments for flexible structure|
|US7041369||27 Nov 2000||9 May 2006||The Procter & Gamble Company||Melt processable starch composition|
|US7276201||18 Mar 2004||2 Oct 2007||The Procter & Gamble Company||Process for making non-thermoplastic starch fibers|
|US7476350||31 Ago 2004||13 Ene 2009||Aktiengesellschaft Adolph Saurer||Method for manufacturing thermoplastic nonwoven webs and laminates|
|US7524379||17 Dic 2003||28 Abr 2009||The Procter + Gamble Company||Melt processable starch compositions|
|US7662534||10 Sep 2007||16 Feb 2010||Ricoh Company Ltd.||Apparatus for producing toner precursor, and method for the same, fibrous toner precursor, apparatus for producing toner, and method for producing electrophotographic toner and fine resin particles|
|US7666261||6 Nov 2008||23 Feb 2010||The Procter & Gamble Company||Melt processable starch compositions|
|US7704328||6 Nov 2008||27 Abr 2010||The Procter & Gamble Company||Starch fiber|
|US7744791||27 Jun 2005||29 Jun 2010||The Procter & Gamble Company||Method for making polymeric structures|
|US7754119||27 Jun 2005||13 Jul 2010||The Procter & Gamble Company||Method for making polymeric structures|
|US7798434||13 Dic 2006||21 Sep 2010||Nordson Corporation||Multi-plate nozzle and method for dispensing random pattern of adhesive filaments|
|US7938908||5 Ene 2010||10 May 2011||The Procter & Gamble Company||Fiber comprising unmodified and/or modified starch and a crosslinking agent|
|US7939010||17 Nov 2005||10 May 2011||The Procter & Gamble Company||Method for forming fibers|
|US8074902||14 Abr 2008||13 Dic 2011||Nordson Corporation||Nozzle and method for dispensing random pattern of adhesive filaments|
|US8168003||31 Mar 2011||1 May 2012||The Procter & Gamble Company||Fiber comprising starch and a surfactant|
|US8236213 *||15 May 2008||7 Ago 2012||Asahi Glass Company, Limited||Process for producing perfluoropolymer, production apparatus and process for producing electrolyte membrane for polymer electrolyte fuel cells|
|US8435600||3 Nov 2011||7 May 2013||Nordson Corporation||Method for dispensing random pattern of adhesive filaments|
|US8623246||21 May 2010||7 Ene 2014||The Procter & Gamble Company||Process of making a fibrous structure|
|US8764904||23 Mar 2012||1 Jul 2014||The Procter & Gamble Company||Fiber comprising starch and a high polymer|
|US9017586||21 May 2010||28 Abr 2015||The Procter & Gamble Company||Polymeric structures and method for making same|
|US20040132873 *||17 Dic 2003||8 Jul 2004||The Procter & Gamble Company||Melt processable starch compositions|
|US20040149165 *||19 Dic 2003||5 Ago 2004||The Procter & Gamble Company||Non-thermoplastic starch fibers and starch composition for making same|
|US20040183238 *||18 Mar 2004||23 Sep 2004||James Michael David||Process for making non-thermoplastic starch fibers|
|US20040201127 *||8 Abr 2003||14 Oct 2004||The Procter & Gamble Company||Apparatus and method for forming fibers|
|US20050023711 *||31 Ago 2004||3 Feb 2005||Nordson Corporation||Method for manufacturing thermoplastic nonwoven webs and laminates|
|US20050076809 *||7 Oct 2004||14 Abr 2005||Mackey Larry Neil||Non-thermoplastic starch fibers and starch composition for making same|
|US20050106970 *||2 Mar 2001||19 May 2005||Stanitis Gary E.||Melt processable perfluoropolymer forms|
|US20050244634 *||29 Abr 2004||3 Nov 2005||The Procter & Gamble Company||Polymeric structures and method for making same|
|US20050244635 *||29 Abr 2004||3 Nov 2005||The Procter & Gamble Company||Polymeric structures and method for making same|
|US20050263938 *||27 Jun 2005||1 Dic 2005||Cabell David W||Polymeric structures and method for making same|
|US20050275133 *||27 Jun 2005||15 Dic 2005||Cabell David W||Polymeric structures and method for making same|
|US20140342027 *||5 Ago 2014||20 Nov 2014||Panasonic Corporation||Nanofiber manufacturing apparatus and method of manufacturing nanofibers|
|DE2334741A1 *||9 Jul 1973||24 Ene 1974||Exxon Research Engineering Co||Werkzeug fuer die herstellung von vliesbahnen im schmelzblasverfahren|
|EP0474423A2 *||28 Ago 1991||11 Mar 1992||CHICOPEE (a New Jersey corp.)||Primary air system for a melt blown die apparatus|
|EP0541960A1 *||9 Oct 1992||19 May 1993||Nordson Corporation||Loop producing apparatus|
|EP0701010A1 *||11 Oct 1991||13 Mar 1996||Exxon Chemical Patents Inc.||Meltblowing Die|
|EP1898265A2 *||10 Sep 2007||12 Mar 2008||Ricoh Company, Ltd.||Apparatus for producing toner precursor, and method for the same, fibrous toner precursor, apparatus for producing toner, and method for producing electrophotographic toner and fine resin particles|
|WO2011009997A2||20 Jul 2010||27 Ene 2011||Ahlstrom Corporation||High cellulose content, laminiferous nonwoven fabric|
|Clasificación de EE.UU.||264/555, 264/210.2, 264/DIG.750, 264/290.5, 425/72.2, 425/382.4, 425/464, 264/211.14|
|Clasificación internacional||D01D4/02, D01D5/098, D01D5/04, D04H3/16|
|Clasificación cooperativa||D01D4/025, D01D5/0985, D01D5/04, Y10S264/75, D04H3/16|
|Clasificación europea||D04H3/16, D01D5/098B, D01D4/02C, D01D5/04|