US3548543A - Devices for power washing,surface reforming and the like - Google Patents

Devices for power washing,surface reforming and the like Download PDF

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US3548543A
US3548543A US703492A US3548543DA US3548543A US 3548543 A US3548543 A US 3548543A US 703492 A US703492 A US 703492A US 3548543D A US3548543D A US 3548543DA US 3548543 A US3548543 A US 3548543A
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liquid
jet
valve
jets
blast
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US703492A
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Dewey M Evans
Frederick W Koepke
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Ajem Laboratories Inc
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Ajem Laboratories Inc
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24CABRASIVE OR RELATED BLASTING WITH PARTICULATE MATERIAL
    • B24C5/00Devices or accessories for generating abrasive blasts

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  • This invention relates to an improved device for power washing, surface re-forming and the like, e.g., for deburring, abrading, or peening device. More particularly the invention relates to a device in which intermittent high velocity liquid jets are used without the waterhammer and other disadvantageous effects of sudden stoppage and difiiculties of rapid build-up of the required high velocity.
  • the present invention supplements or replaces such expedients by intermittent jets which strike with sudden high velocity and then allow the liquid to drain away and strike again with the high velocity jet when enough of the liquid hasdrained back along the surface so that the jet can be fully effective once more and repeating as often as required.
  • the present invention provides improved apparatus for intermittent jet action.
  • the jets pick up and accelerate surface-reforming particles by ejector action; and, when an object to be treated is placed in the path of the jets, very effective surface-reforming results.
  • the present invention facilitates cleaning out small cavities by intermittent blasts of liquid, with or without suspended grit, which strike the cavity opening at a suitable angle.
  • the present invention has an additional unexpected advantage that it improves the overall surface reforming effect even on level surfaces. This is a very advantageous and rather uncommon phenomenon. Usually when a special problem is solved by a modified process there has to be some compromise, and it is rare that the overall operation of the general process is actually improved.
  • the jet pulsation and interruption can be effected, to some extent, by a simple on and off valve, but it is much better to divert a continuously flowing high velocity stream successively to different jet orifices. In this way a constant load on the pump is maintained and the inertia of the flowing stream is utilized to get sudden bursts of the liquid, rather than gradual acceleration at each set of orifices, thus attaining much greater effectiveness than if the flow were actually stopped altogether.
  • the high pressure water is periodically and successively diverted to the several orifices in turn; but, where that is not feasible, the flow can be diverted back to a reservoir in order to avoid interruption of fiow in the high pressure stream.
  • FIG. 1 is a section, in semi-diagrammatic form, of a piston type valve; connected to two blasting jets shown digrammatically;
  • FIG. 2 is an end view of a different type of valve
  • FIG. 3 is a side view of the same type of valve as FIG. 2.
  • each tank 1 is illustrated as formed with a conical settling chamber in which is a jet nozzle 2 and a coaxial blast tube 3.
  • the water is supplied under relatively high pressure through nozzles 2 from the conduit 4.
  • the clear liquid supply conduits 4 communicate with a valve chamber 9 in which a slide valve 10 moves periodically.
  • High pressure water linet 11 is at a central posi tion in valve 9.
  • conduit 4 In the position illustrated in the drawing with the piston at the left, the conduit 4 is closed and conduit 4 provides open passage for the high pressure liquid from 11. Hence a high velocity jet will flow from the orifice 2' and a blast from 3 will be established in the right-hand tank 1'. Pcriodically, for example every other second, the piston valve rapidly moves to the position shown in dashed lines, diverting flow from the right-hand tank to and through the orifice 2 of the left-hand tank. The sequence is repeated continually; and articles 6 which are positioned in the blast are thus treated, first being struck by the blast and then allowed to drain, and then, when the surface is once more freed of liquid, again being subjected to the blast. Because the flow of liquid is successively and alternately directed to the jets 2 and 2, without stopping the fiow of liquid, the blast is of greatest possible velocity and impact force at all times, and deterioration of apparatus by water hammer and other intertial effects is substantially avoided.
  • the intermittent or pulsed jet formation is effected in the clear liquid supply, but the liquid may nevertheless carry some fine abrasive particles.
  • the diversion is controlled by operation of the motor 12, which is sealed from the liquid by a gland 8.
  • the fluid pressure motor 12 and the means for supplying 4 fluid pressure and suction alternately to its connections 13 and 14 may be of types already known in the art.
  • each tank 1 is shown in transverse vertical section, it appears as if each tank had only a single orifice. This may often be so, but in many cases a plurality of orifices and blast tubes or a slot orifice and elongated blast tube, e.g., as set forth in the said prior applications, are used, so that a ribbon-like jet is produced, which is advantageous in the treatment of some articles. Where there are multiple jets, it is by no means necessary that the diverted flow go to a different machine or a different tank. On the contrary, it is often more advantageous to divert the fiow from one jet to another in the same blast tank.
  • each blast tank For some operations it is desirable to have multiple sets of orifices in each blast tank. These orifices and blast tubes advantageously are at different angles each best suited to treating a particular part of the article to which it is directed..
  • the present invention is well suited to the pulsing of such multiple jet sets.
  • FIGS. 2 and 3 Another type of interrupting valve, which acts also as a distributor, is shown in FIGS. 2 and 3.
  • a valve body 9a is provided with a plurality of outlets 4a in its face.
  • a rotatable distributor 10a having a hollow arm or slot 15.
  • the axial inlet, or liquid feed pipe 11A communicates with the hollow passage of the slot or arm; and the passage extends outward so as to communicate also with the outlets 4a.
  • the shaft 17 turns the distributor 10a, the slot 15 successively communicates with one outlet 4a after another, as is best seen in FIG. 2; and therefore in a single revolution the high pressure liquid will successively have been directed to each of four outlet tubes in turn.
  • the slot 15 communicates with each outlet 4a before it is cut off from the previous one, the high velocity flow of liquid is never shut ff, and the inertia of the liquid is used to rapidly build up the velocity in each jet as a previously connected jet is cut off.
  • the periodicity of the jet pulses will vary With the nature of the machines used, and nature and orientation of the surface being treated.
  • the pulse rate is determined by the rate at which the valves are driven, and this obviously can be controlled by use of a variable speed electric motor 19 on shaft 17 or by control of the fluid pressure supply to the fiuid pressure motor 12, which drives valve 10.
  • Various types of motors may be used to drive the valve 10. Besides the reciprocating fluid pressure motor indicated diagrammatically at 12 or a simple rotary electric motor mentioned above, we may use a solenoid or a rotary cam or crank device for the slide valve and a rack and pinion with ratchet to convert the action of a reciprocating motor for drive of a slide valve.
  • An apparatus for surface treatment of a manufactured article comprising a jet nozzle, supply means as a source of a substantially constant volume flow of liquid at high pressures, valve means for repeatedly and rapidly diverting said flow to and from said jet nozzle to create high impact intermittent liquid blasts, drive means for actuating said valve means, and control means for regulating the rate of actuating said valve means such that the intermittent jet blasts issuing from said nozzle impinge on the same area of treatment at a rate timed to permit at least partial drainage of the spent liquid blocking the area of treatment on said article during the periods between said blast to permit said blast more effectively to wash said article.
  • valve means comprises a valve body having achamber of substantially uniform cross section With inlet and outlet ports thereinto, a piston fitted therein and shaped to pass across said inlet port progressively to open a passage to one side thereof and correspondingly close the passage at the other side of the piston.
  • valve means comprises a cylindrical housing having an axial inlet opening at one end of the housing and a plurality of outlet openings at points spaced around the periphery of said housing, said nozzles ultimately connected to said respective outlet openings for directing jets of liquid at the articles to be treated, a rotatable distributor within said housing, said distributor having an axial inlet aligned with said inlet opening and further having a curved passage extending from said axial inlet to an outlet at the periphery of said distributor, said drive means connected to said distributor for rotating said distributor sequentially to deliver the high pressure liquid to the respective nozzles for providing intermittent liquid jets therefrom.

Description

'D e c. 22; 1970' D, EVANS ET AL 3,548,543
DEVICES FOR POWER WASHING, SURFACE RE-FORMING AND THE LIKE Original Filed June 7, 1961 'mvsu EY M. NS FRE K'W.KEOPKE United States Patent Int. Cl. B24c 3/04 US. Cl. 51-8 6 Claims ABSTRACT OF THE DISCLOSURE Apparatus for cleaning and/or abrasive deburring or shot peening by means of intermittent series of high impact liquid blasts timed to treat a given surface with high efficiency by the apparatus being timed to permit drainage. of blocking liquid between the intermittent blasts.
This is a division of application Ser. No. 115,407, filed June 7, 1961, now Pat. No. 3,360,400, dated Dec. 26, 1967.
This invention relates to an improved device for power washing, surface re-forming and the like, e.g., for deburring, abrading, or peening device. More particularly the invention relates to a device in which intermittent high velocity liquid jets are used without the waterhammer and other disadvantageous effects of sudden stoppage and difiiculties of rapid build-up of the required high velocity.
Such problems are presented especially in the surface treatment of manufactured metal parts, e.g,. for cleaning, removal of scale, deburring etc., and in some cases, for alteration of the surface microcrystalline structure by methods such as shot peening. All such procedures will be referred to generally in this specification and claims as surface re-forming. There have heretofore been known in this art power washers, using sprays and jets in various ways for loosening and Washing away soil of various kinds. These have included mechanical devices for moving the parts being treated into various orientations to the jets, and for moving jets into suitable orientations, even for pushing jet carrying mandrels into small openings. The present invention supplements or replaces such expedients by intermittent jets which strike with sudden high velocity and then allow the liquid to drain away and strike again with the high velocity jet when enough of the liquid hasdrained back along the surface so that the jet can be fully effective once more and repeating as often as required.
The result of this is to make a given amount of water or other treating liquid do more useful work and likewise to increase eificiency of use of energy imparted to the liquid in the high velocity stream.
In a prior application of our co-workers Nicholas J. Panzica, Robert C. Nillhiser, and Warren W. Wool, Jr., Ser. No. 67,396, filed Nov. 6, 1960, now Pat. No. 3,233,- 865, there was set forth a diversion-type valve useful in washing and surface reforming methods. We have adapted the use of such diversion equipment to give intermittent or pulsating jet action.
The present invention provides improved apparatus for intermittent jet action.
In the copending application of Umbricht and Johnson, Ser. No. 9,910 filed Feb. 19, 1960, now issued as Pat. No. 3,150,467, a new method of surface re-forming by blasting with solid particles suspended in a suitable liquid is described and claimed. A clear liquid such as water is forced at high velocity from orifices to form jets of a Patented Dec. 22, 1970 Ice.
suspension of solid particles for the surface re-forming operation. These particles may be various grits, for abrasive scouring, deburring, etc. or, in the case of peening, steel shot and the like. The jets pick up and accelerate surface-reforming particles by ejector action; and, when an object to be treated is placed in the path of the jets, very effective surface-reforming results.
These processes have revolutionized the surface treatment of many parts, particularly metal castings in the automotive industry. The outer surfaces of such castings can readily be treated by the process and apparatus previously disclosed in applications of myself and my coworkers; but difiicult problems are encountered with parts having scale or adhering flakes, etc., to be removed or small cavities, for example tapped holes to be smoothed, deburred, cleansed of oils, chips, abrasives, etc. Once such surface is covered with the liquid, and especially when small holes are filled with the liquid, the surfaces are insulated thereby from the intended action of the jets, and then there is no longer any strong blast of suspended solids actually striking the surfaces to be treated.
The present invention facilitates cleaning out small cavities by intermittent blasts of liquid, with or without suspended grit, which strike the cavity opening at a suitable angle. The present invention has an additional unexpected advantage that it improves the overall surface reforming effect even on level surfaces. This is a very advantageous and rather uncommon phenomenon. Usually when a special problem is solved by a modified process there has to be some compromise, and it is rare that the overall operation of the general process is actually improved.
In operations using the present invention, we frequently interrupt the flow of the cleaning solution or surface re-forming liquid, and repeatedly subject the surfaces to. bursts, or sudden blasts, of the treating liquid. If the jets are pulsed, for example operating on and off for only a fraction of a minute, even as briefly as a second each, the suspension drains back from its condition of dynamic balance during the jet flow so that, even in the smallcavities from which the liquid cannot fully drain out, it no longer prevents the next pulse of the jet from producing an effective scouring, etc. of the inner surfaces of cavities, and the other surfaces over which the liquid drains. Advantageously, the part is held or turned so that liquid will drain out from such cavities while the jet is interrupted. As a result, thorough cleaning and/ or surface re-forming of the surfaces is effected in one machine and without need for hand labor.
Surprisingly, even on large surfaces which do not pre sent the problem of small cavities the effectiveness of the blasting operation is actually improved by such intermittent bursts and interruptions. Apparently the sudden onset, as a jet starts, improves the cleaning and removal of surface scale and the like, probably because sudden impact stresses before any reaction effects have occurred to obstruct or counter balance them. In any event the removal of the undesirable material is actually improved by pulsing the jets, and the present invention is not limited to any theory of why this is so.
The jet pulsation and interruption can be effected, to some extent, by a simple on and off valve, but it is much better to divert a continuously flowing high velocity stream successively to different jet orifices. In this way a constant load on the pump is maintained and the inertia of the flowing stream is utilized to get sudden bursts of the liquid, rather than gradual acceleration at each set of orifices, thus attaining much greater effectiveness than if the flow were actually stopped altogether. Where there is a plurality of jet orifices, the high pressure water is periodically and successively diverted to the several orifices in turn; but, where that is not feasible, the flow can be diverted back to a reservoir in order to avoid interruption of fiow in the high pressure stream. The shift from one path to another should be as rapid as possible so as to provide a sudden burst of liquid from the jet to which the flow is diverted. In the specific description, to follow, two types of valves embodying this invention are illustrated. It should be understood that these are typical, and representative of others which can be used.
The invention will be described in more detail in conjunction with the accompanying drawings in which the invention is applied as an improvement with the Umbricht and Johnson apparatus referred to above. In these drawings:
FIG. 1 is a section, in semi-diagrammatic form, of a piston type valve; connected to two blasting jets shown digrammatically;
FIG. 2 is an end view of a different type of valve, and
FIG. 3 is a side view of the same type of valve as FIG. 2.
In FIG 1. the bottom portions of two blasting tanks are shown diagrammatically and broken away. Each tank 1 is illustrated as formed with a conical settling chamber in which is a jet nozzle 2 and a coaxial blast tube 3. The water is supplied under relatively high pressure through nozzles 2 from the conduit 4.
In operation a blast of water through each of the nozzles 2 in turn, entrains some of a slurry of surface reforming solids which settles in the bottoms of tanks 1 around the gaps between the orifices 2 and blast tubes 3. This slurry, entrained with the high velocity liquid jets, is then accelerated in the blast tubes 3 so that it strikes with high velocity on articles 6 which are positioned or moved into the blast from tube 3. The positioning and movement of such articles is now known, and examples are disclosed in prior patent specifications, e.g., those Umbricht and Johnson applications identified above and D. M. Evans Pat. No. 2,832,461, April 29, 1958, O. M. Arnold No. 2,900,991, Aug. 25, 1959, E. Umbricht and D. M. Evans No. 2,918,071, Dec. 22, 1959, Umbricht, Evans and W. Johnson No. 2,925,614, Feb. 23, 1960, Umbricht and Evans No. 2,926,674, Mar. 1, 1960, and No. 2,926,675, Mar. 1, 1960, and the continuation-impart application Ser. No. 371,175, filed May 26, 1964, now Pat. No. 3,187,883.
The clear liquid supply conduits 4 communicate with a valve chamber 9 in which a slide valve 10 moves periodically. High pressure water linet 11 is at a central posi tion in valve 9.
In the position illustrated in the drawing with the piston at the left, the conduit 4 is closed and conduit 4 provides open passage for the high pressure liquid from 11. Hence a high velocity jet will flow from the orifice 2' and a blast from 3 will be established in the right-hand tank 1'. Pcriodically, for example every other second, the piston valve rapidly moves to the position shown in dashed lines, diverting flow from the right-hand tank to and through the orifice 2 of the left-hand tank. The sequence is repeated continually; and articles 6 which are positioned in the blast are thus treated, first being struck by the blast and then allowed to drain, and then, when the surface is once more freed of liquid, again being subjected to the blast. Because the flow of liquid is successively and alternately directed to the jets 2 and 2, without stopping the fiow of liquid, the blast is of greatest possible velocity and impact force at all times, and deterioration of apparatus by water hammer and other intertial effects is substantially avoided.
It will be noted that the intermittent or pulsed jet formation is effected in the clear liquid supply, but the liquid may nevertheless carry some fine abrasive particles. The diversion is controlled by operation of the motor 12, which is sealed from the liquid by a gland 8. The fluid pressure motor 12 and the means for supplying 4 fluid pressure and suction alternately to its connections 13 and 14 may be of types already known in the art.
Because the tanks 1 are shown in transverse vertical section, it appears as if each tank had only a single orifice. This may often be so, but in many cases a plurality of orifices and blast tubes or a slot orifice and elongated blast tube, e.g., as set forth in the said prior applications, are used, so that a ribbon-like jet is produced, which is advantageous in the treatment of some articles. Where there are multiple jets, it is by no means necessary that the diverted flow go to a different machine or a different tank. On the contrary, it is often more advantageous to divert the fiow from one jet to another in the same blast tank.
For some operations it is desirable to have multiple sets of orifices in each blast tank. These orifices and blast tubes advantageously are at different angles each best suited to treating a particular part of the article to which it is directed.. The present invention is well suited to the pulsing of such multiple jet sets.
Another type of interrupting valve, which acts also as a distributor, is shown in FIGS. 2 and 3. Here a valve body 9a is provided with a plurality of outlets 4a in its face. Within the body 9a is a rotatable distributor 10a having a hollow arm or slot 15. The axial inlet, or liquid feed pipe 11A communicates with the hollow passage of the slot or arm; and the passage extends outward so as to communicate also with the outlets 4a. As the shaft 17 turns the distributor 10a, the slot 15 successively communicates with one outlet 4a after another, as is best seen in FIG. 2; and therefore in a single revolution the high pressure liquid will successively have been directed to each of four outlet tubes in turn. Because the slot 15 communicates with each outlet 4a before it is cut off from the previous one, the high velocity flow of liquid is never shut ff, and the inertia of the liquid is used to rapidly build up the velocity in each jet as a previously connected jet is cut off.
The operation is described in connection with FIG. 1, but the design of the distributor lends itself to installations where there are more than two sets of jet orifices. There are many other types of liquid distributors, which can be used to serve the functions described.
The periodicity of the jet pulses will vary With the nature of the machines used, and nature and orientation of the surface being treated. The pulse rate is determined by the rate at which the valves are driven, and this obviously can be controlled by use of a variable speed electric motor 19 on shaft 17 or by control of the fluid pressure supply to the fiuid pressure motor 12, which drives valve 10.
Various types of motors may be used to drive the valve 10. Besides the reciprocating fluid pressure motor indicated diagrammatically at 12 or a simple rotary electric motor mentioned above, we may use a solenoid or a rotary cam or crank device for the slide valve and a rack and pinion with ratchet to convert the action of a reciprocating motor for drive of a slide valve.
We claim:
1. An apparatus for surface treatment of a manufactured article, comprising a jet nozzle, supply means as a source of a substantially constant volume flow of liquid at high pressures, valve means for repeatedly and rapidly diverting said flow to and from said jet nozzle to create high impact intermittent liquid blasts, drive means for actuating said valve means, and control means for regulating the rate of actuating said valve means such that the intermittent jet blasts issuing from said nozzle impinge on the same area of treatment at a rate timed to permit at least partial drainage of the spent liquid blocking the area of treatment on said article during the periods between said blast to permit said blast more effectively to wash said article.
2. An apparatus according to claim 1 in which the diverting means is a power actuated piston valve.
3. An apparatus according to claim 1 in which the diverting means is a rotating liquid distributor.
4. An apparatus as described in claim 1 for altering the surface microstructure of articles by abrasive blasting, shot peening, andthe like, which further comprises surface-altering particles, said supply means supplying a fiow of liquid at high pressures for creating a jet from said jet nozzle which entrains surface-altering particles and imparts thereto a surface-altering energy, and means for maintaining a replenishable supply of said surfacealtering particles in a zone from which said impeller jet can entrain said particles.
5. An apparatus as described in claim 1 having a plurality of jet nozzles wherein said valve means comprises a valve body having achamber of substantially uniform cross section With inlet and outlet ports thereinto, a piston fitted therein and shaped to pass across said inlet port progressively to open a passage to one side thereof and correspondingly close the passage at the other side of the piston.
6. An apparatus as described in claim 1 having a plurality of nozzles wherein said valve means comprises a cylindrical housing having an axial inlet opening at one end of the housing and a plurality of outlet openings at points spaced around the periphery of said housing, said nozzles ultimately connected to said respective outlet openings for directing jets of liquid at the articles to be treated, a rotatable distributor within said housing, said distributor having an axial inlet aligned with said inlet opening and further having a curved passage extending from said axial inlet to an outlet at the periphery of said distributor, said drive means connected to said distributor for rotating said distributor sequentially to deliver the high pressure liquid to the respective nozzles for providing intermittent liquid jets therefrom.
References Cited UNITED STATES PATENTS 390,688 10/ 1 888 Masson. 825,370 7/ 1906 Zurbuch. 1,655,941 1/1928 Dawson et al. 134129 1,672,286 6/1928 Stringham et al. 13434X 3,150,467 9/1964 Umbricht et a1. 51-8 3,233,865 2/1966 Panzica et al. 251--309 LESTER M. SWINGLE, Primary Examiner US. Cl. X.R. 134191
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5248343A (en) * 1990-12-07 1993-09-28 Golden Technologies Company, Inc. Method for finishing metal containers
US5271773A (en) * 1990-12-07 1993-12-21 Golden Technologies Company, Inc. Process for cleaning articles with an aqueous solution of terpene and recycle water after separation
US5328518A (en) * 1991-12-06 1994-07-12 Golden Technologies Company, Inc. Method for separating components of liquids in industrial process
US5415584A (en) * 1993-09-21 1995-05-16 Tomco2 Equipment Company Particle blast cleaning apparatus
US5421899A (en) * 1990-12-07 1995-06-06 Golden Technologies Company, Inc. Method for cleaning manufacturing lubricants and coolants from metal containers
US5445680A (en) * 1990-12-07 1995-08-29 Golden Technologies Company, Inc. Method of decorating metal surfaces
US5525371A (en) * 1992-06-10 1996-06-11 Biochem Systems Division, A Division Of Golden Technologies Company, Inc. Method for cleaning parts soiled with oil components and separating terpenes from oil compositions with a ceramic filter
US5542983A (en) * 1990-12-07 1996-08-06 Biochem Systems Process for cleaning metal surfaces with physical emulsion of terpene and water
US20020121559A1 (en) * 1999-01-12 2002-09-05 Shin Narui Method and device for recovering permeability of porous pavement surface layer

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US390688A (en) * 1888-10-09 John masson
US825370A (en) * 1905-04-22 1906-07-10 Henry A Zurbuch Valve.
US1655941A (en) * 1928-01-10 A corpoba
US1672286A (en) * 1924-07-05 1928-06-05 Swenarton Method of and apparatus for dishwashing
US3150467A (en) * 1960-02-19 1964-09-29 Ajem Lab Inc Hydraulic surface treating process and equipment
US3233865A (en) * 1960-11-04 1966-02-08 Ajem Lab Inc Rotary plug valve

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US390688A (en) * 1888-10-09 John masson
US1655941A (en) * 1928-01-10 A corpoba
US825370A (en) * 1905-04-22 1906-07-10 Henry A Zurbuch Valve.
US1672286A (en) * 1924-07-05 1928-06-05 Swenarton Method of and apparatus for dishwashing
US3150467A (en) * 1960-02-19 1964-09-29 Ajem Lab Inc Hydraulic surface treating process and equipment
US3233865A (en) * 1960-11-04 1966-02-08 Ajem Lab Inc Rotary plug valve

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5248343A (en) * 1990-12-07 1993-09-28 Golden Technologies Company, Inc. Method for finishing metal containers
US5271773A (en) * 1990-12-07 1993-12-21 Golden Technologies Company, Inc. Process for cleaning articles with an aqueous solution of terpene and recycle water after separation
US5421899A (en) * 1990-12-07 1995-06-06 Golden Technologies Company, Inc. Method for cleaning manufacturing lubricants and coolants from metal containers
US5445680A (en) * 1990-12-07 1995-08-29 Golden Technologies Company, Inc. Method of decorating metal surfaces
US5542983A (en) * 1990-12-07 1996-08-06 Biochem Systems Process for cleaning metal surfaces with physical emulsion of terpene and water
US5328518A (en) * 1991-12-06 1994-07-12 Golden Technologies Company, Inc. Method for separating components of liquids in industrial process
US5525371A (en) * 1992-06-10 1996-06-11 Biochem Systems Division, A Division Of Golden Technologies Company, Inc. Method for cleaning parts soiled with oil components and separating terpenes from oil compositions with a ceramic filter
US5415584A (en) * 1993-09-21 1995-05-16 Tomco2 Equipment Company Particle blast cleaning apparatus
US20020121559A1 (en) * 1999-01-12 2002-09-05 Shin Narui Method and device for recovering permeability of porous pavement surface layer

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