US3647305A - Packet technology - Google Patents

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US3647305A
US3647305A US3647305DA US3647305A US 3647305 A US3647305 A US 3647305A US 3647305D A US3647305D A US 3647305DA US 3647305 A US3647305 A US 3647305A
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Prior art keywords
article
pocket
sheet material
edge
temporary seal
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Mary Joan H Baker
Robert C Baker
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • AHUMAN NECESSITIES
    • A45HAND OR TRAVELLING ARTICLES
    • A45DHAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D40/00Casings or accessories specially adapted for storing or handling solid or pasty toiletry or cosmetic substances, e.g. shaving soaps or lipsticks
    • A45D40/26Appliances specially adapted for applying pasty paint, e.g. using roller, using a ball
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47LDOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L13/00Implements for cleaning floors, carpets, furniture, walls, or wall coverings
    • A47L13/10Scrubbing; Scouring; Cleaning; Polishing
    • A47L13/16Cloths; Pads; Sponges
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47LDOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L23/00Cleaning footwear
    • A47L23/04Hand implements for shoe-cleaning, with or without applicators for shoe polish
    • A47L23/10Cloth or collapsible cleaning pads; Glove-like cleaning cloths
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • B32B2307/31Heat sealable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2367/00Polyesters, e.g. PET, i.e. polyethylene terephthalate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S383/00Flexible bags
    • Y10S383/902Flexible bags having nonbag use
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/913Material designed to be responsive to temperature, light, moisture
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/13Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1334Nonself-supporting tubular film or bag [e.g., pouch, envelope, packet, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/23907Pile or nap type surface or component
    • Y10T428/23943Flock surface
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/23907Pile or nap type surface or component
    • Y10T428/23993Composition of pile or adhesive
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24843Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] with heat sealable or heat releasable adhesive layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/28Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2813Heat or solvent activated or sealable
    • Y10T428/2817Heat sealable
    • Y10T428/2826Synthetic resin or polymer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31786Of polyester [e.g., alkyd, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31786Of polyester [e.g., alkyd, etc.]
    • Y10T428/31797Next to addition polymer from unsaturated monomers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/674Nonwoven fabric with a preformed polymeric film or sheet
    • Y10T442/675Ester condensation polymer sheet or film [e.g., polyethylene terephthalate, etc.]

Definitions

  • Appl 806983 The envelopelike container is easily manufactured by automated techniques. lt has opposing walls formed of flexible 52 us. c1. ..401/7, 206/56 AA, 401/132 Sheet material
  • the sheet material Preferably p y has a 51 Int. Cl. ..A46b 5/04 flexible pp rting organic polymeric film and an exposed [58] Field 61 Search ..401/7, 132; 206/56 A; 15/104, recess-wmaining layer Over one surface of that P Y 15/94 film. Seals unite peripheral portions of the opposing walls of the envelope together. One edge is only temporarily sealed; 56] Re'erences Cited and the others are permanently united. Earflaps extend beyond the temporary seal.
  • This invention relates to a new sheet material, a new package structure in the form of a discardable flexible envelopelike container convertible to a pocket applicator, and methods for making the new package structure as well as methods for using it.
  • the invention provides easily used discardable applicator packages for messy spreadable compositions such as shoe polishes, metal polishes, or other polishes, various cleaners, cleansers, cosmetic preparations, germicidal mixtures, medicinal compounds, toiletry items, polish removers, pastes, creams, lotions, oils, paints, waxes etc.
  • Van Boytham U.S. Pat. No. 2,621,784 An illustrative teaching is set forth in van Boytham U.S. Pat. No. 2,621,784.
  • Van Boythams structure is that of a sealed envelope which is fully opened and flattened in the palm of ones hand to expose an interior special flannelette applicator pad occupying the central portion of the open envelope layer and suitably cemented to it.
  • a special finger-receiving pocket is created on the under side of van Boythams open envelope by an extra fold of material.
  • a further illustrative approach is that in Wanzenberg US. Pat. No. 3,280,420, where a multifolded packet is set forth having special areas and limited treated surfaces for the application of shoe polish and the polishing thereof.
  • the applicator packet of the invention is economical to manufacture, uncomplicated in structure, easy and fast to use in a neat manner, and fully effective to permit application of packaged ingredients neatly upon a surface without contaminating or staining ones fingers or hands. Still further benefits of the invention will be evident as this description proceeds.
  • This new applicator package is preferably formed using especially prepared flexible sheet material of the invention.
  • This preferred sheet material has a flexible self-supporting organic polymeric film, and an exposed recess-containing layer over one surface of the polymeric film.
  • the side of the sheet material having that recess-containing layer (that is, recess-containing structure) is hermetically heat sealable to itself over all portions thereof.
  • the recess-containing layer side capable of serving as an applicator for polishing or coating a surface with messy material, it is also capable, in the preferred embodiment, of being sealed hermetically to itself by heat. Even when not hermetically heat scalable to itself, seals of permanent as well as temporary character are possible between face-to-face oriented areas of the recess-containing side of a sheet material in an envelope structure of the invention, as will be explained.
  • the new disposable flexible envclopelike applicator and container is extraordinarly simple to make. Continuous automated manufacturing techniques are possible. Multitudinous folding is avoided, which reduces raw material and manufacturing expenses. Yet the resulting new package structure is fully effective as a container for the marketing of single-use quantities of messy ingredients and is easily converted into an applicator pocket which permits controlled application of those ingredients to other surfaces without need for messy finger contact with the ingredients.
  • This new package structure is in the nature of an envelope having opposing walls formed of a flexible sheet material.
  • a spreadable messy composition is enclosed within the envelope cavity between the opposing walls of the container.
  • Recesscontaining layer means is fixed within the envelope cavity (e.g., the recess-containing layer side of the flexible sheet material) and provides a carrier structure or surface for the messy composition in the envelope cavity.
  • the sheet material forming the opposing walls is united along all portions thereof immediately adjacent the peripheral limits of the envelope cavity, with all of the portions which are in face-to-face relationship adjacent those peripheral limits being united by seal structures.
  • the expanse of the sheet material forming each of the opposing walls of the container is sufficient in size to extend beyond the seal structure along one edge or peripheral limit of the cavity to form outwardly projecting earflaps.
  • the seal structure along that one edge is temporary and rupturable, whereas the other seal structures ad- .jacent the peripheral limits of the envelope cavity are permanent in nature.
  • the edge seal which is temporary is at least 5 centimeters and no greater than about l5 (or possibly but rarely 20) centimeters in total length; and the depthdimension of the envelope cavity downwardly from that temporary seal edge is no greater than about 10 centimeters, and in any event, is less than the length of the temporary seal.
  • the earflaps are gripped by a thumb and forefinger and drawn apart to rupture the temporary seal of that one edge and simultaneously form the container into a pocket.
  • the pocket is then turned inside out to place the recess-containing layer means holding or carrying the spreadable composition on or in it exterior to the inverted pocket.
  • a person inserts his fingers into the inverted pocket, where they are protected against contamination during hand application of the composition.
  • the earflaps serve as a shield against unwanted contact between the composition and the person applying the composition even when an earflap is gripped between ones thumb and palm of hand to guide movement of the pocket applicator over a surface.
  • FIG. I is a side view of a package structure according to the invention.
  • FIG. 2 is a cross section taken on line 2-2 of FIG. 1, with a persons fingers shown in phantom;
  • FIG. 3 is a further cross-sectional view along the same plane as FIG. 2, including a persons fingers in phantom, showing the character of the package structure after it has been converted into a pocket;
  • FIG. 4 is likewise a cross-sectional view along the same plane as FIG. 2, including a persons fingers in phantom, showing the character of the package structure after it has been turned inside out and thereby converted into a pocket applicator;
  • FIGS. 5 and 6 are side plan views of alternate package structures according to the invention.
  • FIGS. 7 and 8 are cross-sectional views of illustrative flexible sheet material of the invention.
  • FIG. 9 is a top plan view illustrating a coating pattern for a method of manufacture.
  • FIG. 10 is a side plan view illustrating a further method of manufacture
  • FIG. 11 is a top plan view ofthe showing in FIG. and
  • FIG. 12 is an enlarged fragment of a package illustrating a temporary heat seal structure.
  • the new package structure is in the form of an envelopelike container 10 having opposing walls 1 l and 12 of flexible sheet material.
  • a small quantity of a spreadable composition 13 is within the envelope cavity of the container. This envelope cavity is between the opposing walls 11 and 12 of the flexible sheet material and is defined by those walls.
  • an illustrative preferred unitary sheet material useful in the practice of the invention is one having a flexible self-supporting, preferably nonfibrous, nonabsorbent, substantially nonporous organic polymeric film 14 (such as Mylar"), and an exposed recess-containing layer 15 (preferably a layer of random fibrous elements such as polyethylene fibers) scattered over and united to essentially all portions of one surface of the polymeric film, so that the recess-containing layer is essentially coextensive with the base.
  • the recess-containing layer side 15 forms the interior surface of walls 11 and 12 of the package.
  • That recess-containing side is preferably somewhat absorbent in character; and unless otherwise indicated by the context, absorbent, as used herein in connection with the recess-containing layer includes either or both absorbent and adsorbent phenomenon.
  • absorbent as used herein in connection with the recess-containing layer includes either or both absorbent and adsorbent phenomenon.
  • nonabsorbent which is sometimes used in connection with the polymeric base film, is not, however, to be construed as excluding the possibility of a surface of that film exhibiting some surface adsorbent phenomenon.
  • the character of the recess-containing layer serves to hold the messy composition more or less in position or partially within limited recesses or openings between elements (such as fibers) forming the structure of that layer.
  • Recess-containing refers to recess openings such as irregular spaces of minute or small character between fibrous elements of a layer (e.g., deposited as a layer by flocking), or to a uniform pattern of embossed in dents or recesses in a base film, or even to openings or passages in relatively thin spongelike or porous sheet material.
  • the recess means of the structure comprises a plurality of mini-recesses.
  • Sheet material of opposing walls 11 and 12 is united (preferably hermetically, but not necessarily so where nonfluid constituents are packaged) along all portions thereof immediately adjacent the peripheral limits of the envelope cavity itself.
  • the bottom edge 16 simply consists of a fold of the sheet material; and this fold permanently unites opposing walls 11 and 12 along that bottom or peripheral lower edge 16.
  • Portions of the recess-containing layer side of the sheet immediately adjacent the lateral peripheral limits of the envelope cavity are united together by permanent seal structures; and this is illustrated by permanent seals '17 and 18 at each lateral extremity or end of the cavity.
  • Temporary seal 19 extends across the top of the cavity uniting the face-to-face oriented sides of each wall at the upper peripheral limits of the cavity.
  • each opposing wall 11 and 12 of the envelope cavity is sufficient in size to extend outwardly beyond the temporary seal structure 19 which is along the upper peripheral edge or one edge of the envelope cavity.
  • the extension beyond temporary seal 19 is in the form of outwardly or upwardly projecting earflaps 20 and 21; and this extension must be at least a half-centimeter beyond the temporary seal 19.
  • the extension normally should be at least about I centimeter beyond seal 19, or even at least 1.5 centimeters (up to possible 3 or 5 or even 8 centimeters beyond seal 19).
  • the greater extensions provide a surface which sometimes may be useful for finish shining after application of messy ingredients.
  • the earflaps may be of unequal size so as to facilitate separation for hand gripping.
  • earflaps 20 and 21 may be shaped in the form illustrated by the dash line 22 in FIG. 1.
  • earflaps 20 and 21 extend outwardly at least about I centimeter along the entire length of temporary seal 19 and suitably terminate more or less in a straight edge 23, even though seal 19 may be arced or elevated at its central portion.
  • the earflaps preferably are not united along lateral edges 24 and 25.
  • the permanent seals 17 and 18 defining the lateral peripheral limits of the envelope cavity usually will not extend out or upwardly any great amount beyond their juncture with the temporary seal 19 (with the possible exception that, when an auxiliary seal structure 26 as illustrated in FIG. 5 is used, the permanent seals 17 and 18 as illustrated in FIG. 1 suitably merge with such an auxiliary seal).
  • the temporary seal along the one edge 19 of the envelope cavity is relatively easily rupturable by pulling apart earflaps 20 and 21.
  • Seal 19 is at least about 5 centimeters and no greater than about 15 (or rarely 20) centimeters in total length. Usually it is at least about 7 centimeters long but not longer than about 10 or 12 centimeters. It is always at least about as long as the longest dimension of the envelope cavity (e.g., between end seals 17 and 18).
  • the depth dimension of the envelope cavity itself is never greater than the length of the temporary seal 19 and generally not in excess of about 10 centimeters. Envelope cavities of greater depth have been usually found impractical for convenient reversal. Usually, the depth dimension (taken at the greatest distance between seal 19 and the bottom edge 16 of the cavity) is not in excess of about 8 centimeters, with a depth dimension between about 2 and 4 (or sometimes as high as 6) centimeters being most preferred.
  • the limited depth (preferably no greater than two-thirds or even one-half the length of the temporary seal) for the cavity serves not only to contribute to ease of reversal, in the manner hereinafter described, but also contributes to concentration of the messy spreadable composition to fingertip areas for application purposes, as will be evident from the teaching to follow.
  • an individual desiring to apply a spreadable composition within the cavity of the package structure first grips each earflap 20 and 21 between a thumb and forefinger and pulls those earflaps 20 and 21 apart, thereby rupturing the long temporary seal 19 along the top of the envelope cavity.
  • the fingers shown in phantom in FIG. 2 illustrate how this is done.
  • the resulting pocket is inverted or turned inside out. This can be done in almost a continuous motion from the rupturing of the temporary seal 19.
  • the structure is converted to an applicator which has the appearance, in cross section, as illustrated in FIG. 4.
  • the inverted pocket which now has become an applicator, may be firmly gripped during the step of using one's protected fingers to apply the spreadable composition to a surface.
  • the limited depth of the envelope cavity of the package structure as marketed in commerce serves to concentrate the messy ingredients on the exterior of the pocket applicator to an area where fingertip application of them is conveniently accomplished.
  • the earflaps of the inverted pocket further serve as a shield against unwanted contactbetween the spreadable messy composition and the person applying that composition. This is so even when an earflap is gripped, as just noted, between thumb and palm of hand to guide movement of the pocket applicator over a surface.
  • seals 17 and 18 at the lateral terminal ends of the elongated envelope cavity are preferably such as to taper inwardly (or toward each other) from their widest point at their juncture with the ends of temporary seal edge 19 to the bottom edge 16 of the envelope cavity.
  • these end seals 17 and 18 may be essentially straight in character; but tapering, as just noted, greatly facilitates convenient reversal of the package in the manner illustrated in FIGS. 2-4 inclusive.
  • the inverted pocket is less apt to have nonreversed small corner sections between the bottom edge 16 and end seals 17 or 18. While such small sections can be inverted by spreading ones fingers into those areas after inverting or reversing the main body of the pocket, the taper or slope of seals 17 and 18 contributes to the ease of inverting and reduces the likelihood that a small portion of the messy ingredients will be unavailable for application because of a nonreversed corner section. Much greater tapering than that illustrated may sometimes be desirable.
  • a further and most significant feature of the structure illustrated in FIG. I is in the design or shape of the temporary seal 19. That temporary seal 19 (both in FIG. 1 and in FIG. 6) is arced or tapered upwardly (i.e., outwardly from the envelope cavity), suitably in curved or straight lines, to a peak or elevation 26, suitably centrally located. This limited section or peak provides a starting point for convenient rupture of seal 19.
  • FIG. 5 illustrates a package formed using a cylinder of polymeric film, which results in lateral ends numbered 17 and 18 of the envelope cavity being inherently united (e.g., folds).
  • Temporary seal 19 is shown as a straight seal, which is less preferred, but is extremely simple and economical.
  • outer portions or peripheral extremities of the earflaps may be continuously united by a contoured strong heat seal 26; but when this is done, some separation means, such as a tear strip 27 with a projecting part as a grip-tab, should be located between the united earflaps. Tear strip 27 preferably extends partially into the area of seal 26 (which assists in holding tear strip 27 in position).
  • An extra or auxiliary seal such as seal 26 provides a further fully sealed chamber beyond temporary seal 19 to protect against loss of cavity contents in the event of accidental rupture of temporary seal 19 during shipment.
  • Tear strip 27 permits convenient separation of the earflaps; and where the temporary seal 19 is not damaged, the flaps are clean to serve the opening and protective functions as aforediscussed.
  • the bottom edge of the envelope cavity in FIG. 5 is united by a permanent heat seal 28, which in this figure also serves to bond and permanently hold one edge of a separate recess-containing layer means as a free tongue in the cavity (said tongue suitably being a sheet of fibers or spongelike material having the approximate shape within the envelope cavity of FIG. 5 as shown by the dash lines upwardly from seal 28 in FIG. 5).
  • FIG. 6 illustrates an envelope cavity of essentially elliptical shape, formed by providing contoured permanent seals 17 and 18 for approximately the lower half of each end of the ellipse and a continuous stretch of permanent seal 28 along the bottom, with an arced temporary seal 19 across the top of the ellipse and partially into the end curved portions thereof to meet the permanent end seals.
  • Sheet material useful to form packet structures of the invention must have a self-supporting base layer or film 14 of flexi ble organic polymeric character.
  • the base polymeric film is preferably very thin (e.g., preferably not over about 80-100 microns thick). Where it is extremely flexible, thicker films (200 or 300 or even possibly as thick as 500 microns) may be used without interferring with pocket inversion.
  • the film structure is strong and tear resistant in use; and therefore it is tough. It may be as thin as about 5 microns, but usually will lie within the range of thickness of about l0 microns up to about 40 or 60 microns.
  • An illustrative base polymeric film structure is quarter mil or about 6-micron Mylar coated with a lO-micron heat seal polymeric resin layer or film).
  • the film is not fibrous matt in character, although it may contain embedded fibrous or filament reinforcing. It does not serve per se as an absorbent material; and thus is nonabsorbent. It should not react with packaged ingredients. It is substantially nonporous or substantially fluid impervious in the sense that, in the packet form, it will substantially prevent migration or leakage of the particular composition packaged.
  • Appropriate fluid imperviousness to a particular fluid-containing composition to be packaged may be imparted or enhanced, as by employing more than one type of material (either as a laminate or in admixture) in the structure of the base polymeric film.
  • the base film serves as a substantially impervious barrier to escape of the particular composition which is packaged.
  • the flexible base film structure may be essentially clear and transparent or tinted or dyed and transparent. It may be pigmented to obscure packaged contents. Inorganic coloring pigments may be concentrated in a single strata of the base structure.
  • a film of vapor-deposited metal e.g., aluminum
  • An embedded vapordeposited metal film (which has the appearance of being substantially continuous) may serve as a good background for printed instructions on sheet material.
  • a desirable base film structure is one having a substantially nonthermoplastic essentially non-heat-sealable polymeric film (such as, for example, a polyethylene terephalate type film) to which a thermoplastic and readily heat-sealable polymeric film or coating (such as, for example, a polyethylene or polyvinylidene chloride) is permanently adhered by any known suitable technique (e.g., primers, chemical reaction, etc.).
  • the films of Scothpak which is a trademark of Minnesota Mining and Manufacturing Company, are of such composite unitary character.
  • a polymeric film 14 (e.g., 15-20 microns thick) which is not heat sealable or only difficulty heat sealable, but which is coated with a thin film 29 (e.g., 5-10 microns thick) which is readily heat sealable.
  • the heat sealable resin layer in such a structure may be relatively thicker, such as 60 or microns; or additional layers of heat-sealable resin may be added, e.g., a coating of acrylic resin solids such as WN-80 of Rohm & I-Iaas Chemical Company.
  • Plasticizers may be incorporated in a heat-sealable layer. They generally serve to lower the temperature at which heat sealing may be effected.
  • plasticizers which is a well-known art, will be effected to avoid those which migrate and contaminate packaged ingredients.
  • the thickness of a heat-sealable resin coating will not exceed about 30 microns; and the preferred total thickness of the base film as a structure including any resin film coating will not be over about 60 microns.
  • Base structures as thin as possible form the more easily handled packages.
  • the base polymeric film may itself be formed wholly of heat-sealable material.
  • thermoplastic materials or compositions based upon polymeric resins such as polyethylene, polyvinyl chloride, polyamide-type resins (such as formed by reacting a polybasic acid with a polyamine; nylon), nylon-reinforced vinyls, and a variety of others.
  • a recess-containing layer 15 which preferably is soft but need not necessarily be napped or piled. It may be porous or foam resin material of spongy character, with or without fibrous elements (e.g., U.S. Pat. No. 2,671,743), or it may be formed as an irregular layer of nonthermoplastic or thermoplastic fibrous elements, or both.
  • the overall thickness of the layer structure characterized as the recess-containing layer as united to the base desirably is maintained as thin as possible (e.g., up to 50 microns) and is preferably not greater than about 200 or possibly 300 microns. It may be and usually is irregular in thickness.
  • Thicker recess containing layers united to a base film e.g., 500 microns or even 1,000 microns (a millimeter) are sometimes useful; but such thicker layers (preferably formed of shiftable fibers on a back film to facilitate pocket inversion) generally are unnecessary and add expense.
  • nonthermoplastic fibrous elements such as cellulosic fibers, e.g., paper, rayon or like fibers; or even glass fibers where mild abrasive-type action is needed or is not a disadvantage
  • Flocking of nonthermoplastic fibrous elements on a softened thermoplastic layer is a suitable technique to bond fibrous elements in place; and heat sealing of the fibrous side of the structure to itself may still be accomplished where the thickness of the heat sealable coating is sufficient to swallow up or penetrate through the fibrous elements during the step of applying modest pressure and the necessary softening heat during heat sealing (e.g., varying normally from about 40 C. up to about 150 C. or 200 C, or even possibly 300 C., depending upon the softening temperature of the heat-scalable material employed).
  • a preponderance e.g., over 50 percent by volume
  • the fibrous elements employed are nonthermoplastic-even though they may be bonded to the base film by thermoplastic material-it is suitable to employ very thin base materials and to form seals by adding adhesive material between the portions of the sheet material to be sealed. This may be accomplished in mass production as illustrated in FIG, 9.
  • Adhesive material 30 preferably heat activatable or thermoplastic
  • droplets or pellets 32 of the ingredients to be packaged are droplets or pellets 32 of the ingredients to be packaged.
  • it is suitable to cool or even freeze liquid-type spreadable compositions in, for example, rod form. Small pellets may be cut from the rod and automatically positioned as illustrated in FIG. 9; or small quantities of a cooled mass may be dispensedby extrusion as a relatively nonflowable droplet 32 into the proper locations for packaging, as illustrated in FIG. 9.
  • Another suitable technique is that of temporarily encapsulating measured quantities of the ingredients to be packaged.
  • Still another, where only minute quantities are required, is that of a rotogravure or even a lithographic transfer approach.
  • the lower half of the sheet stock 31 is folded over the upper half and the folded structure is passed between a lower pressure drum and an upper drum having a projecting peripheral pattern of heat elements which mates with the coating pattern 30 as the folded sheet stock is passed through.
  • a further suitable approach is that of coating upon a flat stock formed with heat-scalable fibers a relatively wide strip (e.g., the entire edge portion of the flattened stock), from about 1 centimeter up to about onefourth the width of the stock, with a relatively non-heat-sealable resin (or one softened only above the temperature at which the heat sealable fibers are softened). This contributes to the formation of excellent temporary heat seals which are neatly separable, as will be discussed in connection with FIG. 12.
  • the quantity of adhesive in the pattern for seal 19 may be reduced in comparison to the quantity or width of coating for the areas to form permanent seals 17 and 18.
  • a different type of adhesive e.g., one of relatively low molecular weight, lower softening temperature and low internal strength
  • Even' possible is the use of room temperature pressure-sensitive adhesive for temporary seal 19; but seals of such material generally are not as reliable as heat seals in terms of handling the packet in commerce.
  • the packaged composition does not contain ingredients capable of attaching or separating the seal prematurely.
  • the insertion of a strip in the nature of a tear strip for use to aid separation of a temporary seal is also possible.
  • thermoplastic fibrous elements 15 are employed in the fabrication of a recess-containing layer on base polymeric films.
  • Fibers of thermoplastic cellulose acetate, polyvinyl acetate, polyethylene or other thermoplastic material may be flocked upon a base polymeric film and bonded thereto either by partial melting or softening of flocked thermoplastic fibers to gain a bond to base film of nonther moplastic character, (preferably suitably primed). or by heat softening a thin thermoplastic base film or coating.
  • the thermoplastic fibers employed should preferably soften at a temperature no higher than about that for the softening of the thermoplastic resin coating.
  • Soft fibrous layers of heat scalable character may suitably be prepared by the Rando-Web technique, or by carding fibers into a porous mat (preferably of overall thickness not above microns).
  • a soft fibrous layer of randomly oriented thermoplastic cellulose acetate fibers e.g., fibers of about 3- denier size and one-half to 2 inches in length
  • a base film e.g., a cellulose acetate film united to a polyethylene terephthalate base
  • thermoplastic fibrous layer without obstructing the heat seal properties of such a thermoplastic fibrous layer; and in that sense, the layer still is characterizable as consisting essentially of thermoplastic fibers or fibrous elements.
  • thermoplastic heat scalable fibers e.g., thermoplastic at a temperature between about 40 C. and about 300 C.
  • thermoplastic heat-sealable polymeric film or coating on the fiber-carrying side of a nonthermoplastic base film
  • FIGS. 10 and 11 An automatic heat-sealing manufacturing technique is illustrated schematically in FIGS. 10 and 11, where a flattened longitudinal strip of sheet stock 33 is shown as being folded upwardly upon itself in face-to-face relationship (along a' line approximately at the center of the longitudinal strip) by suitable lateral guide rollers 34 as the flat sheet stock is indexed through apparatus. Then heat seal elements 35 and 36 move together to form a relatively wide permanent heat.seal 37 at longitudinally spaced intervals along the folded stock. These permanent seals 37 extend transversely from and intersect the fold line so as to form a series of pockets along the longitudinal folded length of the sheet material. The distance out from the fold line to which these permanent seals extend is limited by the size relationships aforediscussed for the envelope cavity of the packages.
  • the line of pockets, separated by seals 37, are then forced open by guide discs 38 and 39; and simultaneously the line of pockets is lowered in its travel as compared to the line of travel at seal elements 35 and 36. This action serves to bulge the sides of the pockets outwardly for reception of a measured quantity of the spreadable composition to be packaged.
  • the measured quantity is dispensed in a shot manner by a plunger-type extruder 40.
  • the line of pockets is passed between heat sealing coacting rolls 41 and 42, which add the narrow line of temporary or light heat seal 19 in a longitudinal direction across the top of the envelope cavity of the package.
  • the line of temporary light heat seal connects terminal portions of the permanent seals opposite the fold line or edge.
  • Cutter knives are used to sever the envelope packages transversely through the permanent seals 37 along illustrated dash line 43.
  • the cut along dash line 43 may be discontinuous, in the form of a line of dots or dash cuts, thereby maintaining the packages, for marketing purposes, in a continuous strip from which the consumer can easily sever a package at the time of use.
  • Temporary seals such as illustrated at numeral 19 in the various figures of the drawing are conveniently formed by employing relatively thin or narrow lines (e.g., 2 millimeters width) of heat seal as compared to the practice of employing relatively wider lines of heat seal (on the order of 4 or 5 millimeters or even I centimeter or more in width) for permanent heat seals, Since the fibrous character of heat-sealable fibrous layers is largely destroyed by fusion in the heat seal area, the ease of rupture of temporary heat seals 19 is sometimes desirably improved by incorporating additional structure in that area. Without additional structure in that area, the rupture of temporary heat seals is sometimes accompanied by the formation of strings of tear or rninute hairy protections along the joined surfaces of temporary seal.
  • relatively thin or narrow lines e.g., 2 millimeters width
  • relatively wider lines of heat seal on the order of 4 or 5 millimeters or even I centimeter or more in width
  • the base film consists of material which is thermoplastic at the temperature of heat sealing for the fibers (as distinguished from structures where the fibers are heat sealed at temperatures below the softening temperature for the base film or where the base film structure includes an essentially nonthermoplastic film).
  • FIG. 12 which is an enlarged fragment of a package, a special temporary heat seal structure 19 is illustrated.
  • fibrous surface of each sheet material 44 and 45 is joined to an intermediate striplike layer 46.
  • Strip or layer 46 is thermoplastic and extends as a narrow strip down the length of the temporary seal 19. lllustratively, its structure may be such that it is of gradually varying composition from one surface to the other.
  • the surface of strip 46 to which fibers 15 of one sheet 44 are bonded may be relatively high melting, whereas the surface to which fibers 15 of the other sheet 45 is bonded may have an adhesive activation temperature comparable to the heat seal activation temperature of the fibers 15 of the sheet material.
  • a suitable strip for a package formed of sheet material carrying thermoplastic cellulose acetate fibers is one having cellulose acetate as the material exposed on one side and a higher melting but possibly still a thermoplastic nylon as the material exposed on its opposite surface.
  • a variety of resin combinations are possible, with the composition intermediate the surface portions being a blend or admixture.
  • Manufacture of a strip 46 is easily accomplished by coating the lower softening or melting thermoplastic, (after elevating it to the softening temperature of the higher melting thermoplastic) as a hot melt upon a thin film of the higher melting thermoplastic.
  • the sheet material employed in forming the packets may itself be free of a recess-containing layer unified therewith and a separate recess-containing layer means bonded in position, as by heat sealing, at the time of forming the packets.
  • additional recess-containing layer means may be incorporated in the packets.
  • a nonwoven (or even woven) mat of fibers or a porous spongy sheet material may be employed as a separate recess-containing sheet.
  • Such a sheet may even be as thick as about 5 millimeters, but generally will be as thin as possible (e.g., or 200 microns) consistent with therecess volume required. Thickness generally should not exceed I or 2 millimeters, and usually not even a half-millimeter or 500 microns.
  • the separate recess-containing sheet may be handled as a continuous strip of material and feed with a base polymeric film through manufacturing steps such as discussed in connection with FIGS. 9, 10 and 11.
  • a relatively narrow band of a recess-containing separate sheet or layer material e.g., of a width up to about three-fourths or even the entire depth of the envelope cavity contemplated
  • a relatively narrow band of a recess-containing separate sheet or layer material may be inserted as an intermediate layer between the walls of a polymeric base film chosen for a string of packets (such as described in connection with FIGS. 10 and 11).
  • the recess-containing separate sheet is, for example, a heat-scalable mat of thermoplastic cellulose acetate fibers, the formation of heat seals 37 between a string of packets, as illustrated in FIGS.
  • envelope packets are formed with a recesscontaining layer extending between end seals (e.g., 17 and 18 as illustrated in FIG, 1), and united with those end seals, but not united continuously over the inner surfaces of either base polymeric film structure forming the walls of the packets.
  • end seals e.g., 17 and 18 as illustrated in FIG, 1
  • the band or width of recess-containing sheet material in such packets is exposed upon one or the other side of the inverted envelope pocket, ready for use in applying the packaged messy composition.
  • the earflaps 20 and.2l may conveniently be free of a recess-containing coating. But if a recess-containing layer free of messy ingredients is desired for finish shining or the like after application of messy ingredients, it is conveniently made available by employing a band or width of separate recess-containing sheet material so wide as to extend through the temporary seal 19 and outwardly as an extra flap intermediate earflaps 20 and 21.
  • metal polishes e.g., polishes containing, for example, finely divided pigment size abrasivelike particles of precipitated chalk, plus a film-forming organic compound such as an alkyl thiol, and a volatile solvent, suitably organic in nature, for the film-forming organic compound).
  • An illustrative shoe polish may comprise a wax emulsion (e.g., camauba wax in water), a binder or strength-imparting tack-free film-forming organic material (e.g., a polymeric acrylic resin emulsion), leveler-type ingredients which reduce surface tension of an applied film (e.g., butoxyethyl phosphate, alcohols, etc.), pigment sized particles such as carbon black, and a diluent such as water.
  • Cleansing compositions of spreadable character may include such ingredients as a detergent, a humectant, an astringent (e.g., particles of aluminum sulfate), and drying agent such as alcohol.
  • Sterile or nonsterile composition may be packaged according to this teaching. Insect repellants, soaps, abrasive materials,
  • the quantity of composition in each envelope will not exceed about 2 or possibly 3 cubic centimeters in volume; although a volume s high as 5 (or even possibly cubic centimeters may be so packaged. Sometimes a volume as low as 0.001 cubic centimeter is all that may be needed (as, for example, in packaging a sample for a potential user to test to determine suitability in a particular application before purchasing bulk quantities).
  • a label flap or sheet carrying such data may be attached to an envelope, preferably to a sealed area of the sheet material or to an earflap. Where the package is to be hung on a hook for display purposes, a small hole may be punched through a relatively wide seal area or through an earflap.
  • a disposable flexible envelopelike container convertible to a pocket applicator, said container having opposing walls formed of flexible sheet material, a spreadable composition within the envelope cavity between said opposing walls of said container, said flexible sheet material comprising a flexible organic polymeric film substantially impervious to said composition, recess-contain ing layer means fixed within said envelope cavity and carrying at least a portion of said spreadable composition within recesses thereof, the sheet material forming said opposing walls being united along all portions thereof immediately adjacent the peripheral limits of said envelope cavity, with all portions in face-to-face relationship adjacent said peripheral limits being united by seal structures, the expanse of said sheet material forming each said opposing wall being sufficient in size to extend beyond a seal structure along one edge of said envelope cavity to form a pair of outwardly projecting earflaps for finger gripping, said seal structure along said one edge being temporary and rupturable and all other seal structures adjacent the peripheral limits of said envelope cavity being permanent, and said earflaps being each adapted to be gripped between
  • said temporary seal structure of said one edge is at least 5 centimeters and no greater than centimeters in total length, with the maximum depth dimension of said envelope cavity downwardly from said one edge being no greater than l0 centimeters and being less than the length of said one edge.
  • seal structures comprise heat-unified thermoplastic material.
  • thermoplastic polymeric resin 6.
  • polymeric film comprises a laminate having a substantially nonthermoplastic polymeric resin film and a thermoplastic readily heatsealable polymeric coating permanently adhered thereto.
  • said recess-containing layer means consists essentially of an exposed recess-containing)la1yer united to one surface of said polymeric film.
  • said exposed recess-containing layer comprises fibrous elements.
  • the temporary seal structure of said one edge is a heat seal structure and comprises an interposed layer of organic resin material within the temporarily heat-sealed portion of the fibrous layer surfaces of the sheet material, said interposed resin layer being characterized by having at least one surface of a composition not activated to adhesiveness at the temperature at which the fibrous layers of said sheet material are activated during heat sealing, the temperature of formation of said temporary seal being insufficient to activate said composition of said one surface of said layer, whereby said fibrous layer of said sheet material temporarily united to said one surface of said layer is separable therefrom by a hand pulling force without forming strings of torn material at said temporary heat seal structure.
  • the method of preparing a pocket applicator for applying a limited quantity of spreadable composition to a surface comprising gripping each earflap of the article of claim 1 between a thumb and forefinger, pulling said earflaps apart by hand a distancejust sufficient to cause rupture and opening of said temporary seal of said one edge of said article, to thereby convert said article into an open pocket, inverting said pocket to place the recess-containing layer means thereof carrying said spreadable composition exterior to said inverted pocket, and inserting fingers of one hand into said inverted pocket.
  • said flexible organic polymeric film comprises a polymer of polyethylene terephthalate.
  • the temporary seal structure of said one edge comprises an interposed layer structure between the opposing walls of sheet material in said temporary seal structure, one surface of said interposed layer structure being permanently united to one of said opposing walls in said temporary seal structure, and the other surface of said interposed layer structure being rupturally united to the other of said opposing walls in said temporary seal structure.

Abstract

A disposable flexible envelopelike container and a new sheet material are taught. The container is convertible to a pocket applicator for applying packaged messy spreadable compositions such as various polishes, cleaners, pastes, oils, paints, stains, waxes, and many other compositions. The envelopelike container is easily manufactured by automated techniques. It has opposing walls formed of flexible sheet material. The sheet material preferably employed has a flexible self-supporting organic polymeric film and an exposed recesscontaining layer over one surface of that polymeric film. Seals unite peripheral portions of the opposing walls of the envelope together. One edge is only temporarily sealed; and the others are permanently united. Earflaps extend beyond the temporary seal. In use, a person grips the earflaps and pulls them apart to rupture the temporary seal and thereby convert the envelopelike container into a pocket. This pocket is then reversed or inverted to place the spreadable composition exterior to the inverted pocket. One then inserts one''s fingers in the inverted pocket, which now becomes an applicator, and then applies the spreadable composition. The earflaps serve as a shield against unwanted contact with the spreadable composition during application of it to a surface. The length of the temporary seal and its relationship to the depth of the envelope cavity is critical to permit convenient reversal or inversion of the pocket during the step of converting the container into an applicator.

Description

United States Patent Primary Examiner-Lawrence Charles Attomey-Robert C. Baker Baker et al. Mar. 7, 1972 [54] PACKET TECHNOLOGY ABSTRACT [72] Inventors: Mary Joan H. Baker; Robert C. Baker, A disposable flexible envelopelike container and a new sheet both of 1831 Summit Avenue, St. Paul, material are taught. The container is convertible to a pocket Minn. 55105 applicator for applying packaged messy spreadable compositions such as various olishes, cleaners, pastes, oils, aints, [22] Flled: 1969 stains, waxes, and man other compositions. p
[21] Appl 806983 The envelopelike container is easily manufactured by automated techniques. lt has opposing walls formed of flexible 52 us. c1. ..401/7, 206/56 AA, 401/132 Sheet material The sheet material Preferably p y has a 51 Int. Cl. ..A46b 5/04 flexible pp rting organic polymeric film and an exposed [58] Field 61 Search ..401/7, 132; 206/56 A; 15/104, recess-wmaining layer Over one surface of that P Y 15/94 film. Seals unite peripheral portions of the opposing walls of the envelope together. One edge is only temporarily sealed; 56] Re'erences Cited and the others are permanently united. Earflaps extend beyond the temporary seal. UNITED STATES PATENTS In use, a person grips the earflaps and pulls them apart to rup- 2,232,783 2/1941 Hausheer ..206/56 AA ture the temporary seal and thereby eenvert the envelepelike 2,954,116 9/1960 M et L 206/56 AA container into a pocket. This pocket is then reversed or in- 2,997,166 8/1961 Pratt 206/56 AA verted to place the spreadable composition exterior to the in- 3,l76,338 4/1965 Homburger... 401/7 verted pocket. One then inserts ones fingers in the inverted 3,190,436 6/1965 Diamant 206/165 P whieh new becomes an applicator, and then pp 3 230 420 10/19 w 15 104 94 the spreadable composition. The earflaps serve as a shield 3,369,267 2/1968 Friedland et al ..401/132 x against unwanted eenteet with the spreadable composition during application of it to a surface. The length of the temporary seal and its relationship to the depth of the envelope cavity is critical to permit convenient reversal or inversion of the pocket during the step of converting the container into an applicator.
19 Claims, 12 Drawing Figures PACKET TECHNOLOGY This invention relates to a new sheet material, a new package structure in the form of a discardable flexible envelopelike container convertible to a pocket applicator, and methods for making the new package structure as well as methods for using it.
The invention provides easily used discardable applicator packages for messy spreadable compositions such as shoe polishes, metal polishes, or other polishes, various cleaners, cleansers, cosmetic preparations, germicidal mixtures, medicinal compounds, toiletry items, polish removers, pastes, creams, lotions, oils, paints, waxes etc.
Convenience-type packaging of various ingredients in small single use or discardable applicator packets has been proposed heretofore. An illustrative teaching is set forth in van Boytham U.S. Pat. No. 2,621,784. Van Boythams structure is that of a sealed envelope which is fully opened and flattened in the palm of ones hand to expose an interior special flannelette applicator pad occupying the central portion of the open envelope layer and suitably cemented to it. A special finger-receiving pocket is created on the under side of van Boythams open envelope by an extra fold of material. A further illustrative approach is that in Wanzenberg US. Pat. No. 3,280,420, where a multifolded packet is set forth having special areas and limited treated surfaces for the application of shoe polish and the polishing thereof.
One objection to prior art single-use applicator packages or packets is the complexity and therefore the expense of manufacturing them. Another objection is that their arrangement of elements militates against careful and neat application of their contents. For example, the van Boytham flannelette applicator pad occupies most of the open area of his envelope layer, and extends into the palm area of ones hand, which tends to increase the risk of spreading ingredients from the treated pad to undesired areas. Controlled and neat application of ingredients is normally only accomplished with the tips of ones fingers. The Wanzenberg package structure is so complex as to invite almost a professional approach to shoe shining instead of a simple quick and neat job. Still further, known applicator package structures of the prior art are less than effective to save one from messy contact with the packaged ingredients during application of those ingredients to a surface. These and other disadvantages have militated against practical adoption of prior art applicator packets for messy compositions. In short, despite the long standing need for effective single-use applicator packets, and the desire for them by consumers, a truely practical and economical and simple convenience-type single-use package-applicator for messy ingredients, effective to save one from messy contact with those ingredients, has not heretofore, insofar as is known, been available.
This invention provides a novel solution to this problem. The applicator packet of the invention is economical to manufacture, uncomplicated in structure, easy and fast to use in a neat manner, and fully effective to permit application of packaged ingredients neatly upon a surface without contaminating or staining ones fingers or hands. Still further benefits of the invention will be evident as this description proceeds.
This new applicator package is preferably formed using especially prepared flexible sheet material of the invention. This preferred sheet material has a flexible self-supporting organic polymeric film, and an exposed recess-containing layer over one surface of the polymeric film. Preferably, the side of the sheet material having that recess-containing layer (that is, recess-containing structure) is hermetically heat sealable to itself over all portions thereof. Thus, not only is the recess-containing layer side capable of serving as an applicator for polishing or coating a surface with messy material, it is also capable, in the preferred embodiment, of being sealed hermetically to itself by heat. Even when not hermetically heat scalable to itself, seals of permanent as well as temporary character are possible between face-to-face oriented areas of the recess-containing side of a sheet material in an envelope structure of the invention, as will be explained.
The new disposable flexible envclopelike applicator and container is extraordinarly simple to make. Continuous automated manufacturing techniques are possible. Multitudinous folding is avoided, which reduces raw material and manufacturing expenses. Yet the resulting new package structure is fully effective as a container for the marketing of single-use quantities of messy ingredients and is easily converted into an applicator pocket which permits controlled application of those ingredients to other surfaces without need for messy finger contact with the ingredients.
This new package structure is in the nature of an envelope having opposing walls formed of a flexible sheet material. A spreadable messy composition is enclosed within the envelope cavity between the opposing walls of the container. Recesscontaining layer means is fixed within the envelope cavity (e.g., the recess-containing layer side of the flexible sheet material) and provides a carrier structure or surface for the messy composition in the envelope cavity.
The sheet material forming the opposing walls is united along all portions thereof immediately adjacent the peripheral limits of the envelope cavity, with all of the portions which are in face-to-face relationship adjacent those peripheral limits being united by seal structures. The expanse of the sheet material forming each of the opposing walls of the container is sufficient in size to extend beyond the seal structure along one edge or peripheral limit of the cavity to form outwardly projecting earflaps. The seal structure along that one edge is temporary and rupturable, whereas the other seal structures ad- .jacent the peripheral limits of the envelope cavity are permanent in nature. The edge seal which is temporary is at least 5 centimeters and no greater than about l5 (or possibly but rarely 20) centimeters in total length; and the depthdimension of the envelope cavity downwardly from that temporary seal edge is no greater than about 10 centimeters, and in any event, is less than the length of the temporary seal.
In use, the earflaps are gripped by a thumb and forefinger and drawn apart to rupture the temporary seal of that one edge and simultaneously form the container into a pocket. The pocket is then turned inside out to place the recess-containing layer means holding or carrying the spreadable composition on or in it exterior to the inverted pocket. Then a person inserts his fingers into the inverted pocket, where they are protected against contamination during hand application of the composition. The earflaps serve as a shield against unwanted contact between the composition and the person applying the composition even when an earflap is gripped between ones thumb and palm of hand to guide movement of the pocket applicator over a surface.
The invention will further be described by reference to a drawing, made a part hereof, wherein the several figures are each schematic sketches or illustrations as follows:
FIG. I is a side view of a package structure according to the invention;
FIG. 2 is a cross section taken on line 2-2 of FIG. 1, with a persons fingers shown in phantom;
FIG. 3 is a further cross-sectional view along the same plane as FIG. 2, including a persons fingers in phantom, showing the character of the package structure after it has been converted into a pocket;
FIG. 4 is likewise a cross-sectional view along the same plane as FIG. 2, including a persons fingers in phantom, showing the character of the package structure after it has been turned inside out and thereby converted into a pocket applicator; I
FIGS. 5 and 6 are side plan views of alternate package structures according to the invention;
FIGS. 7 and 8 are cross-sectional views of illustrative flexible sheet material of the invention;
FIG. 9 is a top plan view illustrating a coating pattern for a method of manufacture;
FIG. 10 is a side plan view illustrating a further method of manufacture;
FIG. 11 is a top plan view ofthe showing in FIG. and
FIG. 12 is an enlarged fragment of a package illustrating a temporary heat seal structure.
Referring to the drawing, and particularly FIGS. 1 and 2, the new package structure is in the form of an envelopelike container 10 having opposing walls 1 l and 12 of flexible sheet material. A small quantity of a spreadable composition 13 is within the envelope cavity of the container. This envelope cavity is between the opposing walls 11 and 12 of the flexible sheet material and is defined by those walls.
Referring to FIGS. 2 and 7, an illustrative preferred unitary sheet material useful in the practice of the invention is one having a flexible self-supporting, preferably nonfibrous, nonabsorbent, substantially nonporous organic polymeric film 14 (such as Mylar"), and an exposed recess-containing layer 15 (preferably a layer of random fibrous elements such as polyethylene fibers) scattered over and united to essentially all portions of one surface of the polymeric film, so that the recess-containing layer is essentially coextensive with the base. The recess-containing layer side 15 forms the interior surface of walls 11 and 12 of the package. That recess-containing side is preferably somewhat absorbent in character; and unless otherwise indicated by the context, absorbent, as used herein in connection with the recess-containing layer includes either or both absorbent and adsorbent phenomenon. (The term nonabsorbent, which is sometimes used in connection with the polymeric base film, is not, however, to be construed as excluding the possibility of a surface of that film exhibiting some surface adsorbent phenomenon). The character of the recess-containing layer serves to hold the messy composition more or less in position or partially within limited recesses or openings between elements (such as fibers) forming the structure of that layer. Recess-containing refers to recess openings such as irregular spaces of minute or small character between fibrous elements of a layer (e.g., deposited as a layer by flocking), or to a uniform pattern of embossed in dents or recesses in a base film, or even to openings or passages in relatively thin spongelike or porous sheet material. In effect the recess means of the structure comprises a plurality of mini-recesses.
Sheet material of opposing walls 11 and 12 is united (preferably hermetically, but not necessarily so where nonfluid constituents are packaged) along all portions thereof immediately adjacent the peripheral limits of the envelope cavity itself. Illustratively, the bottom edge 16 simply consists of a fold of the sheet material; and this fold permanently unites opposing walls 11 and 12 along that bottom or peripheral lower edge 16. Portions of the recess-containing layer side of the sheet immediately adjacent the lateral peripheral limits of the envelope cavity are united together by permanent seal structures; and this is illustrated by permanent seals '17 and 18 at each lateral extremity or end of the cavity. Temporary seal 19 extends across the top of the cavity uniting the face-to-face oriented sides of each wall at the upper peripheral limits of the cavity.
To be especially observed is that the expanse of the sheet material forming each opposing wall 11 and 12 of the envelope cavity is sufficient in size to extend outwardly beyond the temporary seal structure 19 which is along the upper peripheral edge or one edge of the envelope cavity. The extension beyond temporary seal 19 is in the form of outwardly or upwardly projecting earflaps 20 and 21; and this extension must be at least a half-centimeter beyond the temporary seal 19. The extension normally should be at least about I centimeter beyond seal 19, or even at least 1.5 centimeters (up to possible 3 or 5 or even 8 centimeters beyond seal 19). The greater extensions provide a surface which sometimes may be useful for finish shining after application of messy ingredients. If desired, the earflaps may be of unequal size so as to facilitate separation for hand gripping. They may be shaped in the form illustrated by the dash line 22 in FIG. 1. Preferably, however, earflaps 20 and 21 extend outwardly at least about I centimeter along the entire length of temporary seal 19 and suitably terminate more or less in a straight edge 23, even though seal 19 may be arced or elevated at its central portion. Further, the earflaps preferably are not united along lateral edges 24 and 25. Thus, the permanent seals 17 and 18 defining the lateral peripheral limits of the envelope cavity usually will not extend out or upwardly any great amount beyond their juncture with the temporary seal 19 (with the possible exception that, when an auxiliary seal structure 26 as illustrated in FIG. 5 is used, the permanent seals 17 and 18 as illustrated in FIG. 1 suitably merge with such an auxiliary seal).
The temporary seal along the one edge 19 of the envelope cavity is relatively easily rupturable by pulling apart earflaps 20 and 21. Seal 19 is at least about 5 centimeters and no greater than about 15 (or rarely 20) centimeters in total length. Usually it is at least about 7 centimeters long but not longer than about 10 or 12 centimeters. It is always at least about as long as the longest dimension of the envelope cavity (e.g., between end seals 17 and 18).
The depth dimension of the envelope cavity itself, measured downwardly from the temporary seal 19, is never greater than the length of the temporary seal 19 and generally not in excess of about 10 centimeters. Envelope cavities of greater depth have been usually found impractical for convenient reversal. Usually, the depth dimension (taken at the greatest distance between seal 19 and the bottom edge 16 of the cavity) is not in excess of about 8 centimeters, with a depth dimension between about 2 and 4 (or sometimes as high as 6) centimeters being most preferred. The limited depth (preferably no greater than two-thirds or even one-half the length of the temporary seal) for the cavity serves not only to contribute to ease of reversal, in the manner hereinafter described, but also contributes to concentration of the messy spreadable composition to fingertip areas for application purposes, as will be evident from the teaching to follow.
In use, an individual desiring to apply a spreadable composition within the cavity of the package structure first grips each earflap 20 and 21 between a thumb and forefinger and pulls those earflaps 20 and 21 apart, thereby rupturing the long temporary seal 19 along the top of the envelope cavity. The fingers shown in phantom in FIG. 2 illustrate how this is done. The result'is that seal 19 is opened to convert the package structure into a pocket, which is illustrated in FIG. 3. Then the resulting pocket is inverted or turned inside out. This can be done in almost a continuous motion from the rupturing of the temporary seal 19. It is accomplished by continued gripping of the earflaps 20 and 21 between thumb and forefinger and holding them apart while simultaneously using the other fingers of one or both hands to press the walls 11 and 12 and the bottom edge 16 of the open pocket upwardly to turn the pocket of FIG. 3 inside out. After being turned inside out, the structure is converted to an applicator which has the appearance, in cross section, as illustrated in FIG. 4. One then inserts two or three or all fingers of one hand (depending upon the size selected for the package structure) in the inverted pocket applicator and grips an earflap by pressing ones thumb against it and against the palm of one s hand. This is shown in phantom in FIG. 4. Thus the inverted pocket, which now has become an applicator, may be firmly gripped during the step of using one's protected fingers to apply the spreadable composition to a surface. The limited depth of the envelope cavity of the package structure as marketed in commerce serves to concentrate the messy ingredients on the exterior of the pocket applicator to an area where fingertip application of them is conveniently accomplished. The earflaps of the inverted pocket further serve as a shield against unwanted contactbetween the spreadable messy composition and the person applying that composition. This is so even when an earflap is gripped, as just noted, between thumb and palm of hand to guide movement of the pocket applicator over a surface.
To be noted is the fact that seals 17 and 18 at the lateral terminal ends of the elongated envelope cavity are preferably such as to taper inwardly (or toward each other) from their widest point at their juncture with the ends of temporary seal edge 19 to the bottom edge 16 of the envelope cavity. Al-
ternately these end seals 17 and 18 may be essentially straight in character; but tapering, as just noted, greatly facilitates convenient reversal of the package in the manner illustrated in FIGS. 2-4 inclusive. Also, the inverted pocket is less apt to have nonreversed small corner sections between the bottom edge 16 and end seals 17 or 18. While such small sections can be inverted by spreading ones fingers into those areas after inverting or reversing the main body of the pocket, the taper or slope of seals 17 and 18 contributes to the ease of inverting and reduces the likelihood that a small portion of the messy ingredients will be unavailable for application because of a nonreversed corner section. Much greater tapering than that illustrated may sometimes be desirable.
A further and most significant feature of the structure illustrated in FIG. I is in the design or shape of the temporary seal 19. That temporary seal 19 (both in FIG. 1 and in FIG. 6) is arced or tapered upwardly (i.e., outwardly from the envelope cavity), suitably in curved or straight lines, to a peak or elevation 26, suitably centrally located. This limited section or peak provides a starting point for convenient rupture of seal 19.
FIG. 5 illustrates a package formed using a cylinder of polymeric film, which results in lateral ends numbered 17 and 18 of the envelope cavity being inherently united (e.g., folds). Temporary seal 19 is shown as a straight seal, which is less preferred, but is extremely simple and economical. Illustratively, outer portions or peripheral extremities of the earflaps (only flap 21 being visible for the view of FIG. 5) may be continuously united by a contoured strong heat seal 26; but when this is done, some separation means, such as a tear strip 27 with a projecting part as a grip-tab, should be located between the united earflaps. Tear strip 27 preferably extends partially into the area of seal 26 (which assists in holding tear strip 27 in position). An extra or auxiliary seal such as seal 26 provides a further fully sealed chamber beyond temporary seal 19 to protect against loss of cavity contents in the event of accidental rupture of temporary seal 19 during shipment. Tear strip 27 permits convenient separation of the earflaps; and where the temporary seal 19 is not damaged, the flaps are clean to serve the opening and protective functions as aforediscussed. The bottom edge of the envelope cavity in FIG. 5 is united by a permanent heat seal 28, which in this figure also serves to bond and permanently hold one edge of a separate recess-containing layer means as a free tongue in the cavity (said tongue suitably being a sheet of fibers or spongelike material having the approximate shape within the envelope cavity of FIG. 5 as shown by the dash lines upwardly from seal 28 in FIG. 5).
FIG. 6 illustrates an envelope cavity of essentially elliptical shape, formed by providing contoured permanent seals 17 and 18 for approximately the lower half of each end of the ellipse and a continuous stretch of permanent seal 28 along the bottom, with an arced temporary seal 19 across the top of the ellipse and partially into the end curved portions thereof to meet the permanent end seals.
Sheet material useful to form packet structures of the invention must have a self-supporting base layer or film 14 of flexi ble organic polymeric character. The base polymeric film is preferably very thin (e.g., preferably not over about 80-100 microns thick). Where it is extremely flexible, thicker films (200 or 300 or even possibly as thick as 500 microns) may be used without interferring with pocket inversion. The film structure is strong and tear resistant in use; and therefore it is tough. It may be as thin as about 5 microns, but usually will lie within the range of thickness of about l0 microns up to about 40 or 60 microns. (An illustrative base polymeric film structure is quarter mil or about 6-micron Mylar coated with a lO-micron heat seal polymeric resin layer or film). The film is not fibrous matt in character, although it may contain embedded fibrous or filament reinforcing. It does not serve per se as an absorbent material; and thus is nonabsorbent. It should not react with packaged ingredients. It is substantially nonporous or substantially fluid impervious in the sense that, in the packet form, it will substantially prevent migration or leakage of the particular composition packaged. Appropriate fluid imperviousness to a particular fluid-containing composition to be packaged may be imparted or enhanced, as by employing more than one type of material (either as a laminate or in admixture) in the structure of the base polymeric film. In essence, the base film serves as a substantially impervious barrier to escape of the particular composition which is packaged.
The flexible base film structure may be essentially clear and transparent or tinted or dyed and transparent. It may be pigmented to obscure packaged contents. Inorganic coloring pigments may be concentrated in a single strata of the base structure. A film of vapor-deposited metal (e.g., aluminum) may be placed on the base polymeric film, or embedded between layers. Metal foils, however, are too stiff. An embedded vapordeposited metal film (which has the appearance of being substantially continuous) may serve as a good background for printed instructions on sheet material.
A desirable base film structure is one having a substantially nonthermoplastic essentially non-heat-sealable polymeric film (such as, for example, a polyethylene terephalate type film) to which a thermoplastic and readily heat-sealable polymeric film or coating (such as, for example, a polyethylene or polyvinylidene chloride) is permanently adhered by any known suitable technique (e.g., primers, chemical reaction, etc.). The films of Scothpak," which is a trademark of Minnesota Mining and Manufacturing Company, are of such composite unitary character. FIG. 8 illustrates a polymeric film 14 (e.g., 15-20 microns thick) which is not heat sealable or only difficulty heat sealable, but which is coated with a thin film 29 (e.g., 5-10 microns thick) which is readily heat sealable. (Where desired, the heat sealable resin layer in such a structure may be relatively thicker, such as 60 or microns; or additional layers of heat-sealable resin may be added, e.g., a coating of acrylic resin solids such as WN-80 of Rohm & I-Iaas Chemical Company.) Plasticizers may be incorporated in a heat-sealable layer. They generally serve to lower the temperature at which heat sealing may be effected. However, the selection of plasticizers, which is a well-known art, will be effected to avoid those which migrate and contaminate packaged ingredients. Usually, the thickness of a heat-sealable resin coating will not exceed about 30 microns; and the preferred total thickness of the base film as a structure including any resin film coating will not be over about 60 microns. Base structures as thin as possible form the more easily handled packages.
The base polymeric film may itself be formed wholly of heat-sealable material. Useful to this end are thermoplastic materials or compositions based upon polymeric resins such as polyethylene, polyvinyl chloride, polyamide-type resins (such as formed by reacting a polybasic acid with a polyamine; nylon), nylon-reinforced vinyls, and a variety of others.
Upon one side of the base film 14 (or a composite base film such as illustrated in FIG. 8) is preferably united a recess-containing layer 15, which preferably is soft but need not necessarily be napped or piled. It may be porous or foam resin material of spongy character, with or without fibrous elements (e.g., U.S. Pat. No. 2,671,743), or it may be formed as an irregular layer of nonthermoplastic or thermoplastic fibrous elements, or both. The overall thickness of the layer structure characterized as the recess-containing layer as united to the base desirably is maintained as thin as possible (e.g., up to 50 microns) and is preferably not greater than about 200 or possibly 300 microns. It may be and usually is irregular in thickness. It may be even as thin as only a few microns (especially when formed by flocking fibrous elements or embossing recesses in a base polymeric film). Thicker recess containing layers united to a base film, e.g., 500 microns or even 1,000 microns (a millimeter) are sometimes useful; but such thicker layers (preferably formed of shiftable fibers on a back film to facilitate pocket inversion) generally are unnecessary and add expense.
The material of the recess-containing layer, and the character of the base film itself, determines or may limit the useful type of seal structures. But where the base film itself or a coating on it is thermoplastic and heat scalable, and where that heat-scalable film is of sufficient thickness (e.g., about 60 microns), nonthermoplastic fibrous elements (such as cellulosic fibers, e.g., paper, rayon or like fibers; or even glass fibers where mild abrasive-type action is needed or is not a disadvantage) may be employed in limited quantities while retaining heat scalability for the structure. Flocking of nonthermoplastic fibrous elements on a softened thermoplastic layer is a suitable technique to bond fibrous elements in place; and heat sealing of the fibrous side of the structure to itself may still be accomplished where the thickness of the heat sealable coating is sufficient to swallow up or penetrate through the fibrous elements during the step of applying modest pressure and the necessary softening heat during heat sealing (e.g., varying normally from about 40 C. up to about 150 C. or 200 C, or even possibly 300 C., depending upon the softening temperature of the heat-scalable material employed).
Where a preponderance (e.g., over 50 percent by volume) of the fibrous elements employed are nonthermoplastic-even though they may be bonded to the base film by thermoplastic material-it is suitable to employ very thin base materials and to form seals by adding adhesive material between the portions of the sheet material to be sealed. This may be accomplished in mass production as illustrated in FIG, 9. Adhesive material 30 (preferably heat activatable or thermoplastic) is solvent coated on the fibrous side of the sheet material 31 in a repetitive pattern while the sheet material is in flattened stock form prior to the step of forming any seals. Volatiles are removed from the coated pattern (which will be noted from FIG. 9 to be in the shape of the seals l7, l8 and 19 illustrated in FIG. 1),
Also illustrated in FIG, 9 are droplets or pellets 32 of the ingredients to be packaged. To reduce mess during manufactun ing steps, it is suitable to cool or even freeze liquid-type spreadable compositions in, for example, rod form. Small pellets may be cut from the rod and automatically positioned as illustrated in FIG. 9; or small quantities of a cooled mass may be dispensedby extrusion as a relatively nonflowable droplet 32 into the proper locations for packaging, as illustrated in FIG. 9. Another suitable technique is that of temporarily encapsulating measured quantities of the ingredients to be packaged. Still another, where only minute quantities are required, is that of a rotogravure or even a lithographic transfer approach.
After volatiles are removed from the coated pattern 30 and the pellets or droplets 32 in position, the lower half of the sheet stock 31 is folded over the upper half and the folded structure is passed between a lower pressure drum and an upper drum having a projecting peripheral pattern of heat elements which mates with the coating pattern 30 as the folded sheet stock is passed through.
In connection with FIG. 9, a further suitable approach is that of coating upon a flat stock formed with heat-scalable fibers a relatively wide strip (e.g., the entire edge portion of the flattened stock), from about 1 centimeter up to about onefourth the width of the stock, with a relatively non-heat-sealable resin (or one softened only above the temperature at which the heat sealable fibers are softened). This contributes to the formation of excellent temporary heat seals which are neatly separable, as will be discussed in connection with FIG. 12.
Alternately, the quantity of adhesive in the pattern for seal 19 (as illustrated in FIG. 9) may be reduced in comparison to the quantity or width of coating for the areas to form permanent seals 17 and 18. Further, a different type of adhesive (e.g., one of relatively low molecular weight, lower softening temperature and low internal strength) may be coated in the pattern for the temporary seal 19. Even' possible is the use of room temperature pressure-sensitive adhesive for temporary seal 19; but seals of such material generally are not as reliable as heat seals in terms of handling the packet in commerce.
They may be used, however, where the packaged composition does not contain ingredients capable of attaching or separating the seal prematurely. Also possible is the insertion of a strip in the nature of a tear strip for use to aid separation of a temporary seal.
Preferably, thermoplastic fibrous elements 15 are employed in the fabrication of a recess-containing layer on base polymeric films. Fibers of thermoplastic cellulose acetate, polyvinyl acetate, polyethylene or other thermoplastic material may be flocked upon a base polymeric film and bonded thereto either by partial melting or softening of flocked thermoplastic fibers to gain a bond to base film of nonther moplastic character, (preferably suitably primed). or by heat softening a thin thermoplastic base film or coating. While not always necessary, the thermoplastic fibers employed should preferably soften at a temperature no higher than about that for the softening of the thermoplastic resin coating. This relationship is important where the fibers are per se heat sealed (e.g., fused) in the formation of seals for a packet. An interesting sheet structure is that carefully formed by lightly calendering a mat of polyethylene fibers at room temperature and then passing the compacted layer over a heated drum at a temperature sufficient to flow the contacting surface of the mat into a continuous film while at the same time causing the opposite surface of the matted fibers to relax or even expand somewhat outwardly from their compacted calendered condition.
Soft fibrous layers of heat scalable character may suitably be prepared by the Rando-Web technique, or by carding fibers into a porous mat (preferably of overall thickness not above microns). A soft fibrous layer of randomly oriented thermoplastic cellulose acetate fibers (e.g., fibers of about 3- denier size and one-half to 2 inches in length) may be laminated to a base film (e.g., a cellulose acetate film united to a polyethylene terephthalate base) by passing the base film over a heated drum while feeding the layer of fibers to it, preferably under slight bonding pressures. To reduce costs, a small quantity of nonthermoplastic fibers (up to or approaching about 30 percent or so of the total fiber volume) may be incorporated in a thermoplastic fibrous layer without obstructing the heat seal properties of such a thermoplastic fibrous layer; and in that sense, the layer still is characterizable as consisting essentially of thermoplastic fibers or fibrous elements.
The most economical and practical sheet structures of the invention are those wherein the recess-containing fibrous layer, instead of being woven, is simply a randomly oriented layer of nonwoven fibers or fibrous elements. Sheet material formed using thermoplastic heat scalable fibers (e,g., thermoplastic at a temperature between about 40 C. and about 300 C.) and preferably a thermoplastic heat-sealable polymeric film (or coating on the fiber-carrying side of a nonthermoplastic base film) is especially adapted for movement through automatic heat sealing and package forming apparatus.
An automatic heat-sealing manufacturing technique is illustrated schematically in FIGS. 10 and 11, where a flattened longitudinal strip of sheet stock 33 is shown as being folded upwardly upon itself in face-to-face relationship (along a' line approximately at the center of the longitudinal strip) by suitable lateral guide rollers 34 as the flat sheet stock is indexed through apparatus. Then heat seal elements 35 and 36 move together to form a relatively wide permanent heat.seal 37 at longitudinally spaced intervals along the folded stock. These permanent seals 37 extend transversely from and intersect the fold line so as to form a series of pockets along the longitudinal folded length of the sheet material. The distance out from the fold line to which these permanent seals extend is limited by the size relationships aforediscussed for the envelope cavity of the packages. The line of pockets, separated by seals 37, are then forced open by guide discs 38 and 39; and simultaneously the line of pockets is lowered in its travel as compared to the line of travel at seal elements 35 and 36. This action serves to bulge the sides of the pockets outwardly for reception of a measured quantity of the spreadable composition to be packaged. The measured quantity is dispensed in a shot manner by a plunger-type extruder 40. Thereafter, the line of pockets is passed between heat sealing coacting rolls 41 and 42, which add the narrow line of temporary or light heat seal 19 in a longitudinal direction across the top of the envelope cavity of the package. The line of temporary light heat seal connects terminal portions of the permanent seals opposite the fold line or edge. Cutter knives, not illustrated, are used to sever the envelope packages transversely through the permanent seals 37 along illustrated dash line 43. If desired, the cut along dash line 43 may be discontinuous, in the form of a line of dots or dash cuts, thereby maintaining the packages, for marketing purposes, in a continuous strip from which the consumer can easily sever a package at the time of use.
Temporary seals such as illustrated at numeral 19 in the various figures of the drawing are conveniently formed by employing relatively thin or narrow lines (e.g., 2 millimeters width) of heat seal as compared to the practice of employing relatively wider lines of heat seal (on the order of 4 or 5 millimeters or even I centimeter or more in width) for permanent heat seals, Since the fibrous character of heat-sealable fibrous layers is largely destroyed by fusion in the heat seal area, the ease of rupture of temporary heat seals 19 is sometimes desirably improved by incorporating additional structure in that area. Without additional structure in that area, the rupture of temporary heat seals is sometimes accompanied by the formation of strings of tear or rninute hairy protections along the joined surfaces of temporary seal. Also, additional structure is preferably employed where the base film consists of material which is thermoplastic at the temperature of heat sealing for the fibers (as distinguished from structures where the fibers are heat sealed at temperatures below the softening temperature for the base film or where the base film structure includes an essentially nonthermoplastic film).
In FIG. 12, which is an enlarged fragment of a package, a special temporary heat seal structure 19 is illustrated. In that structure, fibrous surface of each sheet material 44 and 45 is joined to an intermediate striplike layer 46. Strip or layer 46 is thermoplastic and extends as a narrow strip down the length of the temporary seal 19. lllustratively, its structure may be such that it is of gradually varying composition from one surface to the other. The surface of strip 46 to which fibers 15 of one sheet 44 are bonded may be relatively high melting, whereas the surface to which fibers 15 of the other sheet 45 is bonded may have an adhesive activation temperature comparable to the heat seal activation temperature of the fibers 15 of the sheet material. Thus, during the heat sealing of temporary seal 19 (which in this structural relationship may be accomplished in a relatively wide width up to the width of strip 46), the fibers of sheet 45 fuse into and permanently unite with the surface of strip 46 adjacent thereto; but the fibers of sheet 44 merely fuse together and into contact with the surface of strip 46 adjacent thereto, without merging or blending with the material of that surface. The interface between fused fibers of sheet 44 and the adjacent surface of strip 46 therefore is relatively easily ruptured, but is a hermetic seal prior to being ruptured. lllustratively, a suitable strip for a package formed of sheet material carrying thermoplastic cellulose acetate fibers is one having cellulose acetate as the material exposed on one side and a higher melting but possibly still a thermoplastic nylon as the material exposed on its opposite surface. A variety of resin combinations are possible, with the composition intermediate the surface portions being a blend or admixture. Manufacture ofa strip 46 is easily accomplished by coating the lower softening or melting thermoplastic, (after elevating it to the softening temperature of the higher melting thermoplastic) as a hot melt upon a thin film of the higher melting thermoplastic. Instead of employing a separate strip 46, similar structural results are made possible by coating a striplike layer of resin (having a higher softening temperature than the softening temperature of the thermoplastic fibers of the sheet stock) in a pattern such as illustrated for the temporary seal 19in FIG. 9. One way of accomplishing this is by solvent coating.
If desired, the sheet material employed in forming the packets may itself be free of a recess-containing layer unified therewith and a separate recess-containing layer means bonded in position, as by heat sealing, at the time of forming the packets. (Also, even when the sheet material employed is one having fibers or the like unified as a layer thereto, additional recess-containing layer means may be incorporated in the packets.) This has been illustrated in connection with FIG. 5, where the recess-containing layer means is in the nature of a tongue-flap of a recess-containing sheet formed either of heatsealable or non-heat-sealable material. A nonwoven (or even woven) mat of fibers or a porous spongy sheet material may be employed as a separate recess-containing sheet. Such a sheet may even be as thick as about 5 millimeters, but generally will be as thin as possible (e.g., or 200 microns) consistent with therecess volume required. Thickness generally should not exceed I or 2 millimeters, and usually not even a half-millimeter or 500 microns.
The separate recess-containing sheet may be handled as a continuous strip of material and feed with a base polymeric film through manufacturing steps such as discussed in connection with FIGS. 9, 10 and 11. Suitably, a relatively narrow band of a recess-containing separate sheet or layer material (e.g., of a width up to about three-fourths or even the entire depth of the envelope cavity contemplated) may be inserted as an intermediate layer between the walls of a polymeric base film chosen for a string of packets (such as described in connection with FIGS. 10 and 11). If the recess-containing separate sheet is, for example, a heat-scalable mat of thermoplastic cellulose acetate fibers, the formation of heat seals 37 between a string of packets, as illustrated in FIGS. 10 and 11, can also effectively fuse the fibers of the band or width of cellulose acetate in the area of heat seals 37. Other processing steps can be as discussed in connection with FIGS. 10 and 11. The result is that envelope packets are formed with a recesscontaining layer extending between end seals (e.g., 17 and 18 as illustrated in FIG, 1), and united with those end seals, but not united continuously over the inner surfaces of either base polymeric film structure forming the walls of the packets. Upon inversion, as illustrated in FIGS. 2-4 inclusive, the band or width of recess-containing sheet material in such packets is exposed upon one or the other side of the inverted envelope pocket, ready for use in applying the packaged messy composition. In this type of structure, there need be no recess-containing material in the portion of the envelope package where the temporary seal 19 is formed. Also, the earflaps 20 and.2l may conveniently be free of a recess-containing coating. But if a recess-containing layer free of messy ingredients is desired for finish shining or the like after application of messy ingredients, it is conveniently made available by employing a band or width of separate recess-containing sheet material so wide as to extend through the temporary seal 19 and outwardly as an extra flap intermediate earflaps 20 and 21.
Illustrative messy spreadable compositions desirably packaged as taught herein are metal polishes (e.g., polishes containing, for example, finely divided pigment size abrasivelike particles of precipitated chalk, plus a film-forming organic compound such as an alkyl thiol, and a volatile solvent, suitably organic in nature, for the film-forming organic compound). An illustrative shoe polish may comprise a wax emulsion (e.g., camauba wax in water), a binder or strength-imparting tack-free film-forming organic material (e.g., a polymeric acrylic resin emulsion), leveler-type ingredients which reduce surface tension of an applied film (e.g., butoxyethyl phosphate, alcohols, etc.), pigment sized particles such as carbon black, and a diluent such as water. Cleansing compositions of spreadable character may include such ingredients as a detergent, a humectant, an astringent (e.g., particles of aluminum sulfate), and drying agent such as alcohol. Sterile or nonsterile composition may be packaged according to this teaching. Insect repellants, soaps, abrasive materials,
even powdery compounds are but further illustrations of the almost limitless variety of compositions which may be packaged in the relatively flat-type envelopes using the principles hereof.
Generally, the quantity of composition in each envelope will not exceed about 2 or possibly 3 cubic centimeters in volume; although a volume s high as 5 (or even possibly cubic centimeters may be so packaged. Sometimes a volume as low as 0.001 cubic centimeter is all that may be needed (as, for example, in packaging a sample for a potential user to test to determine suitability in a particular application before purchasing bulk quantities).
As an alternate to printing identifying indicia or instructions upon sheet material of an envelope of the invention, or in addition to so doing, a label flap or sheet carrying such data may be attached to an envelope, preferably to a sealed area of the sheet material or to an earflap. Where the package is to be hung on a hook for display purposes, a small hole may be punched through a relatively wide seal area or through an earflap.
That which is claimed is:
I. As a new package article: a disposable flexible envelopelike container convertible to a pocket applicator, said container having opposing walls formed of flexible sheet material, a spreadable composition within the envelope cavity between said opposing walls of said container, said flexible sheet material comprising a flexible organic polymeric film substantially impervious to said composition, recess-contain ing layer means fixed within said envelope cavity and carrying at least a portion of said spreadable composition within recesses thereof, the sheet material forming said opposing walls being united along all portions thereof immediately adjacent the peripheral limits of said envelope cavity, with all portions in face-to-face relationship adjacent said peripheral limits being united by seal structures, the expanse of said sheet material forming each said opposing wall being sufficient in size to extend beyond a seal structure along one edge of said envelope cavity to form a pair of outwardly projecting earflaps for finger gripping, said seal structure along said one edge being temporary and rupturable and all other seal structures adjacent the peripheral limits of said envelope cavity being permanent, and said earflaps being each adapted to be gripped between a thumb and forefinger and drawn apart to rupture the temporary seal of said one edge and simultaneously form said container into a pocket capable of being turned inside out to place said recess-containing layer means carrying said spreadable composition exterior to said inverted pocket, whereby fingers inserted into said inverted pocket are protected against contamination during hand application of said composition.
2. The article of claim 1 herein said temporary seal structure of said one edge is at least 5 centimeters and no greater than centimeters in total length, with the maximum depth dimension of said envelope cavity downwardly from said one edge being no greater than l0 centimeters and being less than the length of said one edge.
3. The article of claim 1 wherein said temporary seal structure of said one edge is no longer than l0 centimeters and the depth dimension of said cavity downwardly from said one edge is no greater than 6 centimeters.
4. The article of claim 1 wherein said outwardly projecting earflaps are of substantially equal size.
5. The article of claim 1 wherein the seal structures comprise heat-unified thermoplastic material.
6. The article of claim 1 wherein the polymeric film of the sheet material comprises thermoplastic polymeric resin.
7. The article of claim 1 wherein the polymeric film comprises a laminate having a substantially nonthermoplastic polymeric resin film and a thermoplastic readily heatsealable polymeric coating permanently adhered thereto.
8. The article of claim 1 wherein said recess-containing layer means consists essentially of an exposed recess-containing)la1yer united to one surface of said polymeric film.
. he article of claim 8 wherein said exposed recess-containing layer comprises fibrous elements.
10. The article of claim 8 wherein said exposed recess-containing layer consists essentially of thermoplastic fibrous elements.
U. The article of claim 8 wherein the temporary seal structure of said one edge is a heat seal structure and comprises an interposed layer of organic resin material within the temporarily heat-sealed portion of the fibrous layer surfaces of the sheet material, said interposed resin layer being characterized by having at least one surface of a composition not activated to adhesiveness at the temperature at which the fibrous layers of said sheet material are activated during heat sealing, the temperature of formation of said temporary seal being insufficient to activate said composition of said one surface of said layer, whereby said fibrous layer of said sheet material temporarily united to said one surface of said layer is separable therefrom by a hand pulling force without forming strings of torn material at said temporary heat seal structure.
12. The article of claim 1 wherein said recess-containing layer means is affixed within the cavity of said envelopelike container by a permanent heat seal.
13. The article of claim 1 wherein said outwardly projecting earflaps are sealed together at the outer peripheral limits thereof and a tear strip extends along said seal at said outer peripheral limits for rapid separation of said peripherally sealed earflaps.
14. The method of preparing a pocket applicator for applying a limited quantity of spreadable composition to a surface, comprising gripping each earflap of the article of claim 1 between a thumb and forefinger, pulling said earflaps apart by hand a distancejust sufficient to cause rupture and opening of said temporary seal of said one edge of said article, to thereby convert said article into an open pocket, inverting said pocket to place the recess-containing layer means thereof carrying said spreadable composition exterior to said inverted pocket, and inserting fingers of one hand into said inverted pocket.
15. The article of claim 1 wherein the maximum depth dimension of said envelope cavity downwardly from said temporary seal structure along said one edge is less than the length of said temporary seal structure.
16. The article of claim 15 wherein said maximum depth dimension is no greater than one-half the length of said temporary seal.
17. The article of claim 15 wherein the configuration of said temporary seal structure along said one edge presents a peak portion which provides a starting point for said rupture of said temporary seal.
18. The article of claim 1 wherein said flexible organic polymeric film comprises a polymer of polyethylene terephthalate.
19. The article of claim 1 wherein the temporary seal structure of said one edge comprises an interposed layer structure between the opposing walls of sheet material in said temporary seal structure, one surface of said interposed layer structure being permanently united to one of said opposing walls in said temporary seal structure, and the other surface of said interposed layer structure being rupturally united to the other of said opposing walls in said temporary seal structure.

Claims (19)

1. As a new package article: a disposable flexible envelopelike container convertible to a pocket applicator, said container having opposing walls formed of flexible sheet material, a spreadable composition within the envelope cavity between said opposing walls of said container, said flexible sheet material comprising a flexible organic polymeric film substantially impervious to said composition, recess-containing layer means fixed within said envelope cavity and carrying at least a portion of said spreadable composition within recesses thereof, the sheet material forming said opposing walls being united along all portions thereof immediately adjacent the peripheral limits of said envelope cavity, with all portions in face-to-face relationship adjacent said peripheral limits being uniteD by seal structures, the expanse of said sheet material forming each said opposing wall being sufficient in size to extend beyond a seal structure along one edge of said envelope cavity to form a pair of outwardly projecting earflaps for finger gripping, said seal structure along said one edge being temporary and rupturable and all other seal structures adjacent the peripheral limits of said envelope cavity being permanent, and said earflaps being each adapted to be gripped between a thumb and forefinger and drawn apart to rupture the temporary seal of said one edge and simultaneously form said container into a pocket capable of being turned inside out to place said recess-containing layer means carrying said spreadable composition exterior to said inverted pocket, whereby fingers inserted into said inverted pocket are protected against contamination during hand application of said composition.
2. The article of claim 1 herein said temporary seal structure of said one edge is at least 5 centimeters and no greater than 15 centimeters in total length, with the maximum depth dimension of said envelope cavity downwardly from said one edge being no greater than 10 centimeters and being less than the length of said one edge.
3. The article of claim 1 wherein said temporary seal structure of said one edge is no longer than 10 centimeters and the depth dimension of said cavity downwardly from said one edge is no greater than 6 centimeters.
4. The article of claim 1 wherein said outwardly projecting earflaps are of substantially equal size.
5. The article of claim 1 wherein the seal structures comprise heat-unified thermoplastic material.
6. The article of claim 1 wherein the polymeric film of the sheet material comprises thermoplastic polymeric resin.
7. The article of claim 1 wherein the polymeric film comprises a laminate having a substantially nonthermoplastic polymeric resin film and a thermoplastic readily heat-sealable polymeric coating permanently adhered thereto.
8. The article of claim 1 wherein said recess-containing layer means consists essentially of an exposed recess-containing layer united to one surface of said polymeric film.
9. The article of claim 8 wherein said exposed recess-containing layer comprises fibrous elements.
10. The article of claim 8 wherein said exposed recess-containing layer consists essentially of thermoplastic fibrous elements.
11. The article of claim 8 wherein the temporary seal structure of said one edge is a heat seal structure and comprises an interposed layer of organic resin material within the temporarily heat-sealed portion of the fibrous layer surfaces of the sheet material, said interposed resin layer being characterized by having at least one surface of a composition not activated to adhesiveness at the temperature at which the fibrous layers of said sheet material are activated during heat sealing, the temperature of formation of said temporary seal being insufficient to activate said composition of said one surface of said layer, whereby said fibrous layer of said sheet material temporarily united to said one surface of said layer is separable therefrom by a hand pulling force without forming strings of torn material at said temporary heat seal structure.
12. The article of claim 1 wherein said recess-containing layer means is affixed within the cavity of said envelopelike container by a permanent heat seal.
13. The article of claim 1 wherein said outwardly projecting earflaps are sealed together at the outer peripheral limits thereof and a tear strip extends along said seal at said outer peripheral limits for rapid separation of said peripherally sealed earflaps.
14. The method of preparing a pocket applicator for applying a limited quantity of spreadable composition to a surface, comprising gripping each earflap of the article of claim 1 between a thumb and forefinger, pulling said earflaps apart by hand a distance just sufficient to cause rupture and opeNing of said temporary seal of said one edge of said article, to thereby convert said article into an open pocket, inverting said pocket to place the recess-containing layer means thereof carrying said spreadable composition exterior to said inverted pocket, and inserting fingers of one hand into said inverted pocket.
15. The article of claim 1 wherein the maximum depth dimension of said envelope cavity downwardly from said temporary seal structure along said one edge is less than the length of said temporary seal structure.
16. The article of claim 15 wherein said maximum depth dimension is no greater than one-half the length of said temporary seal.
17. The article of claim 15 wherein the configuration of said temporary seal structure along said one edge presents a peak portion which provides a starting point for said rupture of said temporary seal.
18. The article of claim 1 wherein said flexible organic polymeric film comprises a polymer of polyethylene terephthalate.
19. The article of claim 1 wherein the temporary seal structure of said one edge comprises an interposed layer structure between the opposing walls of sheet material in said temporary seal structure, one surface of said interposed layer structure being permanently united to one of said opposing walls in said temporary seal structure, and the other surface of said interposed layer structure being rupturally united to the other of said opposing walls in said temporary seal structure.
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Cited By (48)

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US3806260A (en) * 1971-12-14 1974-04-23 Banknote Corp Mitt
US3776644A (en) * 1972-10-25 1973-12-04 R Baker Packet
US4065826A (en) * 1974-12-06 1978-01-03 Imperial Chemical Industries Limited Gloves
US4140409A (en) * 1977-09-02 1979-02-20 Baxter Travenol Laboratories, Inc. Disposable liquid applicator
EP0546426A1 (en) * 1991-12-07 1993-06-16 Margarete Burkhardt Surfaces cleaning and polishing article
US5316400A (en) * 1991-12-19 1994-05-31 Creative Products Resource, Inc. Package systsem for flowable or solid substances
US5460620A (en) * 1992-07-31 1995-10-24 Creative Products Resource, Inc. Method of applying in-tandem applicator pads for transdermal delivery of a therapeutic agent
US5242433A (en) * 1992-12-07 1993-09-07 Creative Products Resource Associates, Ltd. Packaging system with in-tandem applicator pads for topical drug delivery
US5254109A (en) * 1992-12-07 1993-10-19 Creative Products Resource Associates, Ltd. Separately packaged applicator pads for topical delivery of incompatable drugs
US5368581A (en) * 1992-12-07 1994-11-29 Creative Products Resource Associates, Ltd. Method of using a packaging system with folded applicator pads for topical drug delivery
US5562642A (en) * 1992-12-07 1996-10-08 Creative Products Resource, Inc. Separately packaged applicator pads for topical delivery of incompatible drugs
US5320531A (en) * 1993-01-22 1994-06-14 Delizo Madamba Peggy A Absorbent finger sleeve for use in dentistry or medicine
EP0753280A2 (en) * 1995-07-13 1997-01-15 MELITTA HAUSHALTSPRODUKTE GmbH & Co. Kommanditgesellschaft Cleaning glove
EP0753280A3 (en) * 1995-07-13 1998-05-20 MELITTA HAUSHALTSPRODUKTE GmbH & Co. Kommanditgesellschaft Cleaning glove
US5980960A (en) * 1997-04-25 1999-11-09 Arcade, Inc. Sampler applicator having a stretchy layer
US6862759B2 (en) 1998-06-26 2005-03-08 Hill-Rom Services, Inc. Hospital bed
US6325565B1 (en) 1998-06-30 2001-12-04 The Procter & Gamble Company Anti-perspirant/deodorant applicator
US6315482B1 (en) 1998-11-04 2001-11-13 The Procter & Gamble Company Applicator for applying and distributing substances to target surfaces
US6322271B1 (en) 1998-11-04 2001-11-27 The Procter & Gamble Company Applicator for applying and distributing substances to target surfaces
US6406206B1 (en) 1998-11-04 2002-06-18 The Procter & Gamble Company Applicator for applying and distributing substances to target surfaces
US6007264A (en) * 1998-12-02 1999-12-28 Felix Investments, Llc Integral package applicator
WO2000032321A1 (en) * 1998-12-02 2000-06-08 Felix Investments, Llc Integral package applicator
USD427371S (en) * 1999-01-06 2000-06-27 The Procter & Gamble Company Applicator
US6250829B1 (en) * 1999-05-19 2001-06-26 Maureen Brower Lotion applicator and enclosure
US6702733B1 (en) 1999-07-01 2004-03-09 40 J's Llc Expanded clitoral sensitizing compounds with methods and apparatus for the delivery of these compounds
US6547614B2 (en) * 2000-10-06 2003-04-15 Salus Marine Wear Inc. Personal flotation device construction method
WO2002049477A1 (en) * 2000-12-18 2002-06-27 The Procter & Gamble Company Disposable tooth cleaning article
US20040047953A1 (en) * 2002-09-05 2004-03-11 Jacqueline Lauby Baking wipes
US6902335B2 (en) 2003-05-08 2005-06-07 R.P. Scherer Technologies, Inc. Hand held dispensing and application apparatus
US20050207821A1 (en) * 2003-05-08 2005-09-22 Bergey Michael S Hand held dispensing and application apparatus
US7484261B2 (en) 2004-09-30 2009-02-03 Kimberly-Clark Worldwide, Inc. Spot cleaner
US20060067964A1 (en) * 2004-09-30 2006-03-30 Kimberly-Clark Worldwide, Inc. Decal that includes synergistic antimicrobials for treating surfaces
US20060068199A1 (en) * 2004-09-30 2006-03-30 Koenig David W Decal and method for treating surfaces
US20060064830A1 (en) * 2004-09-30 2006-03-30 Sigl Wayne C Spot cleaner
US8911771B2 (en) 2004-11-17 2014-12-16 Otsuka America Pharmaceutical, Inc. Fluid application device and method
US20060115520A1 (en) * 2004-11-17 2006-06-01 Vanek Patrick P Fluid application device and method
US20060194041A1 (en) * 2005-02-28 2006-08-31 Mullally Kevin J Device for releasing an agent to be detected through olfaction
US20070134045A1 (en) * 2005-12-13 2007-06-14 Holt Mary R Two-sided applicator with reactive or complementary chemistries
US20100162948A1 (en) * 2007-06-19 2010-07-01 Azarian Donna J Cooking wipes and dispensers for same
US20110033221A1 (en) * 2008-04-22 2011-02-10 Kurt Koptis Leak resistant applicator pod and method
US8591130B2 (en) 2008-04-22 2013-11-26 Kurt Koptis Leak resistant applicator pod and method
US20100168638A1 (en) * 2008-12-30 2010-07-01 Otsuka America Pharmaceutical, Inc. Fluid application device and method
US20100168637A1 (en) * 2008-12-30 2010-07-01 Otsuka America Pharmaceutical, Inc. Fluid application device and method
US8858484B2 (en) 2008-12-30 2014-10-14 Otsuka America Pharmaceutical, Inc. Fluid application device and method
US8979785B2 (en) 2008-12-30 2015-03-17 Otsuka Pharmaceutical Factory, Inc. Fluid application device and method
US9566421B2 (en) 2008-12-30 2017-02-14 Otsuka America Pharmaceutical, Inc. Fluid application device and method
WO2018020341A1 (en) * 2016-07-25 2018-02-01 Pennelli Faro S.R.L. Brush for the application of fluid products, particularly for powdery, creamy, liquid products or the like
US11406173B2 (en) 2016-07-25 2022-08-09 Pennelli Faro S.R.L. Brush for the application of fluid products, particularly for powdery, creamy, liquid products or the like

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