US3650327A - Thermal insulation of wells - Google Patents
Thermal insulation of wells Download PDFInfo
- Publication number
- US3650327A US3650327A US54720A US3650327DA US3650327A US 3650327 A US3650327 A US 3650327A US 54720 A US54720 A US 54720A US 3650327D A US3650327D A US 3650327DA US 3650327 A US3650327 A US 3650327A
- Authority
- US
- United States
- Prior art keywords
- casing
- borehole
- slurry
- formation
- vermiculite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH DRILLING; MINING
- E21B—EARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B36/00—Heating, cooling, insulating arrangements for boreholes or wells, e.g. for use in permafrost zones
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH DRILLING; MINING
- E21B—EARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B33/00—Sealing or packing boreholes or wells
- E21B33/10—Sealing or packing boreholes or wells in the borehole
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH DRILLING; MINING
- E21B—EARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B36/00—Heating, cooling, insulating arrangements for boreholes or wells, e.g. for use in permafrost zones
- E21B36/003—Insulating arrangements
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S166/00—Wells
- Y10S166/901—Wells in frozen terrain
Definitions
- This invention relates to the field of completing wells. More particularly, this invention relates to a method for thermally insulating a well.
- a thermal injection well is drilled to near the top of a zone of interest and a relatively large diameter casing is set in the wellbore in a conventional manner.
- the wellbore is then extended through the zone, and a smaller diameter casing is run from the surface to bottom of the well.
- This smaller diameter casing is cemented across the zone of interest and the annular space between the casings is filled with a slurry of vermiculite.
- Hot fluid injection may then be commenced; however, controlled application of heat may be necessary initially to dry the vermiculite without causing excessive steam pressure in the slurry as it is dehydrated.
- FIGURE shows a cross-sectional view of a sub-surface earth formation traversed by a well completed in accordance with the method ofthis invention.
- FIG. 1 DESCRIPTION OF A PREFERRED EMBODIMENT Referring to the FIGURE, we see a sub-surface earth formation into which it is desired to inject a heated fluid.
- a borehole 12 from the surface to a point adjacent the formation 10 into which hot fluid is to be injected.
- This borehole 12 may then be cased with a first casing 13 of relatively large diameter.
- This first casing 13 may be run into the hole and set in a conventional manner as by fixing the casing 13 in place with a cement 14.
- the well 11 is then extended into the formation 10 by drilling a borehole 15 with equipment capable of passing through the casing 13.
- a second casing 16 of smaller diameter than the first casing 13 is then extended into the well 11 from the surface to a point adjacent the bottom 17 of the extended borehole 15.
- the smaller casing 16 may then be cemented adjacent the formation of interest 10 with a cement l8, and a slurry 19 of expanded vermiculite may be placed in the annular space 23 between the larger casing 13 and the smaller casing 16.
- the vermiculite slurry 19 may comprise a mixture of vermiculite and any liquid capable of forming a suspension therewith.
- a preferred liquid is water.
- the slurry is preferably mixed to have the maximum vermiculite to liquid ratio consistent with the requirement that the slurry be capable of being pumped into place as hereinafter described.
- the vermiculite slurry may be installed in any suitable manner.
- the smaller diameter casing 16 may be provided with a means (not shown), such as a stage cementing collar, adjacent the lowermost portion of the annular space 23 in which it is desired to install the vermiculite which means will allow the annular space to be opened into fluid communication with the interior of this smaller casing 16.
- the smaller casing 16 may be cemented across the formation 10 and vermiculite slurry 19 may then be circulated down the smaller casing 16 and up the annular space 23 displacing any fluid in the annular space 23 through this means.
- a preferred method for placing the vermiculite slurry 19 in the annular space 23 is to pump the vermiculite slurry down the smaller casing 16 before the cement 18 is in place.
- an amount of slurry sufficient to fill the annular space 23 may be pumped down the casing 16 and then displaced into the annular space 23 by cement 18.
- the cement 18 is preferably positioned around the casing 16 in an amount substantially equivalent to the minimum amount required to assure the creation of a fluidtight seal around the smaller casing 16 sufficient to prevent the flow of steam into the annular space 23 between the larger casing 13 and the smaller casing 16 above the formation 10.
- the annular space 23 may be sealed off with a slip type packoff means 20 of a conventional type which is capable of maintaining a fluidtight seal while allowing the smaller casing 16 to move upwardly or downwardly relative to the larger casing 13.
- a slip type packoff means 20 of a conventional type which is capable of maintaining a fluidtight seal while allowing the smaller casing 16 to move upwardly or downwardly relative to the larger casing 13.
- the well 11 is provided with a substantially free standing casing 16 which may thermally expand without incurring any substantial additional axial stresses.
- the well is also provided with a conventional cemented casing 13 which protects zones above the formation 10 to be treated from invasion by a foreign fluid.
- the casing 16 is insulated by the vermiculite slurry from the surrounding formations thus reducing heat losses to these formations as heated fluids pass through the casing 16, or tubing 22.
- the well 11 is preferably opened into fluid communication with the formation 10 as by perforating the smaller casing 16 and the cement 18 with a number of perforations 21 in a conventional manner.
- Steam or other heated fluid may then be injected into the formation 10 through the well 11. This steam injection may be carried out directly through the casing 16 or the well may be provided with an injection tubing string 22.
- the heated fluid is preferably initially injected into the formation 10 at a controlled rate to gradually dehydrate the vermiculite slurry without causing excessive steam pressure in the slurry.
- the temperature and quantity of heated fluid injected are regulated so that the vermiculite slurry 19 is maintained at a predetermined temperature near the boiling point of water to effectually dehydrate the vermiculite at a rate low enough to avoid the formation of pockets of steam or gas within the annular space 23 between the casings l3 and 16.
- this invention provides a method for insulating a well wherein'an annular space between two strings of tubular pipe is filled'with a vermiculite. slurry after the pipe is positioned within the well. More particularly the invention comprises the steps of drilling a borehole from the surface at least to a point adjacent the bottom of a zone in which heat loss is desired to be minimized, extending into the borehole and substantiaily through the zone a first tubular casing of relatively large diameter, extending into the borehole and substantially through .the zone a second tubular casing of smaller diameter, pumping a slurry comprising vermiculite suspended in a carriplies'to the insulation of hot fluid injectionwells, it should be.
- a method for insulating a well through which a fluid passes between a sub-surface earth formation and the surface of the earth comprising the steps of:
- a method for insulating a well through which hot fluid is injected into a sub-surface formation of interest comprising the steps of: q
- the method of c an 3 including the step of fixing the top of said smaller diameter casing with a slip type packoff means capable of providing a substantially fluidtight seal off of the annular space between said larger and smaller diameter casing strings while simultaneously allowing said smaller diameter casing to move upwardly or downwardly relative to said larger diameter casing.
Abstract
A method for thermally insulating a well, such as a steam injection well or a well which produces oil through perma-frost formations, by filling an annular space between two strings of casing in the wells with heat insulating vermiculite slurry.
Description
United States Patent Burnside [4 1 Mar. 21, 1972 [54} THERMAL INSULATION 0F WELLS 3,502,148 3/1970 Slagle et a1 ..166/303 x 3 511 282 5/1970 Willhite et a1.
72 t Z 1 1 F D 3,561,531 2 1971 Miller ..l66/DlG. 1 [73] Assignee: Shell Oil Company, New York, N.Y.
' FOREIGN PATENTS OR APPLICATIONS 22 F1 1; 1 14 1970 I 1 c y 166,733 1/1956 Australia ..252/62 21 Appl. No.2 54,720
, OTHER PUBLICATIONS [52] U.S. Cl ..166/303, 166/57, 166/292, Willhite, el Design C ite for Completion of Steam 166/1316 1 Injection Wells, in J. Petr. Tech., Jan. 1967, pp. 15- 21. [5 1 I Inl. C1. ..E2lb 33/14, E2lb 43/24 Alaskan C mpletions Will Be Complicated, in o d [58] Fleld 01 Search ..166/285, 291, 292, 302, 303,- 1970, p.85. 166/57, 242, DIG. 1; 252/62 Primary Examiner-David H. Brown I 5 6] References Cited Attorney-Harold L. Denkler and Theodore E. Bieber UNlTED STATES PATENTS 57 I ABSTRACT Re.25,918 1 1/1965 Craig et al. ..166/303 A method for thermally insulating a well, such as a steam 3,360,046 12/1967 Johnson et jection well or a well which produces oil through perma-frost 8951612 8/1908 formations, by filling an annular space between two strings of 2'083'625 6/1937 whte casing in the wells with heat insulating vermiculite slurry. 2,607,422 8/1952 Parks et a1 3,451,479 6/1969 Parker 166/57 X 5 Chims, 1 Drawing Figure 3,456,735 7/1969 McDougall et a] ..166/57 UX Patented March 21,1972 I 3,650,327
'All
INVENTOR:
F. D. BURNSIDE BY:
HIS ATTORNEY THERMAL INSULATION OF WELLS BACKGROUND OF THE INVENTION l. Field of the Invention This invention relates to the field of completing wells. More particularly, this invention relates to a method for thermally insulating a well.
2. Description of the Prior Art A number of processes for the recovery of minerals from sub-surface deposits through wells involve the injection of a heated fluid into the deposit. For example, an often used technique for stimulating the production of a viscous crude oil from a sub-surface oil reservoir is to inject steam into that reservoir through a steam-injection well to heat the oil and reduce its viscosity.
As the heated fluid moves down an injection well it tends to lose heat to the surrounding earth formation and to the pipe which is usually present in such wells. This heat loss reduces the efficiency of the mineral recovery process. In addition, as the pipe is heated it tends to expand. If the linear expansion of the pipe is restricted, stresses are generated in the heated pipe which may cause the pipe to fail structurally. For example, pipe of the type commonly used in steam injection wells when free to expand grows longer by about 1 inch per hundred feet of length for every 100 Fahrenheit increase in temperature. If the heated pipe is bound to the earth formations through which it passes with a material, such as cement, which prevents the pipe from growing in length, stresses will develop which may lead to the failure ofthe pipe.
A number of techniques have been suggested for reducing the loss of heat in the wellbore from injected hot fluid. Among these is the use of heat insulating injection tubing string within a borehole cased with a larger diameter string of pipe which is cemented in place. It has been found that effective insulation may be obtained with an injection tubing string comprising a number of joints of double walled pipe having an insulating material disposed in the annular space between the double walls of the pipe. However, such double walled pipe is expensive to manufacture.
SUMMARY OF THE INVENTION It is an object of this invention to provide a method for completing a thermal injection well with conventional single welled tubular pipe in a manner which will reduce heat loss from injected hot fluid as it passes down the well and which will reduce casing failures due to stresses induced by the thermal expansion of well casings.
According to an embodiment of the invention a thermal injection well is drilled to near the top of a zone of interest and a relatively large diameter casing is set in the wellbore in a conventional manner. The wellbore is then extended through the zone, and a smaller diameter casing is run from the surface to bottom of the well. This smaller diameter casing is cemented across the zone of interest and the annular space between the casings is filled with a slurry of vermiculite. Hot fluid injection may then be commenced; however, controlled application of heat may be necessary initially to dry the vermiculite without causing excessive steam pressure in the slurry as it is dehydrated.
BRIEF DESCRIPTION OF THE DRAWING The FIGURE shows a cross-sectional view of a sub-surface earth formation traversed by a well completed in accordance with the method ofthis invention.
DESCRIPTION OF A PREFERRED EMBODIMENT Referring to the FIGURE, we see a sub-surface earth formation into which it is desired to inject a heated fluid. To provide an insulated injection well 11 according to the method of this invention, one may extend a borehole 12 from the surface to a point adjacent the formation 10 into which hot fluid is to be injected. This borehole 12 may then be cased with a first casing 13 of relatively large diameter. This first casing 13 may be run into the hole and set in a conventional manner as by fixing the casing 13 in place with a cement 14.
The well 11 is then extended into the formation 10 by drilling a borehole 15 with equipment capable of passing through the casing 13. A second casing 16 of smaller diameter than the first casing 13 is then extended into the well 11 from the surface to a point adjacent the bottom 17 of the extended borehole 15. The smaller casing 16 may then be cemented adjacent the formation of interest 10 with a cement l8, and a slurry 19 of expanded vermiculite may be placed in the annular space 23 between the larger casing 13 and the smaller casing 16.
The vermiculite slurry 19 may comprise a mixture of vermiculite and any liquid capable of forming a suspension therewith. A preferred liquid is water. The slurry is preferably mixed to have the maximum vermiculite to liquid ratio consistent with the requirement that the slurry be capable of being pumped into place as hereinafter described.
The vermiculite slurry may be installed in any suitable manner. For example, the smaller diameter casing 16 may be provided with a means (not shown), such as a stage cementing collar, adjacent the lowermost portion of the annular space 23 in which it is desired to install the vermiculite which means will allow the annular space to be opened into fluid communication with the interior of this smaller casing 16. In such a case the smaller casing 16 may be cemented across the formation 10 and vermiculite slurry 19 may then be circulated down the smaller casing 16 and up the annular space 23 displacing any fluid in the annular space 23 through this means.
A preferred method for placing the vermiculite slurry 19 in the annular space 23 is to pump the vermiculite slurry down the smaller casing 16 before the cement 18 is in place. Thus an amount of slurry sufficient to fill the annular space 23 may be pumped down the casing 16 and then displaced into the annular space 23 by cement 18. The cement 18 is preferably positioned around the casing 16 in an amount substantially equivalent to the minimum amount required to assure the creation of a fluidtight seal around the smaller casing 16 sufficient to prevent the flow of steam into the annular space 23 between the larger casing 13 and the smaller casing 16 above the formation 10.
At the surface, the annular space 23 may be sealed off with a slip type packoff means 20 of a conventional type which is capable of maintaining a fluidtight seal while allowing the smaller casing 16 to move upwardly or downwardly relative to the larger casing 13. Thus the well 11 is provided with a substantially free standing casing 16 which may thermally expand without incurring any substantial additional axial stresses. The well is also provided with a conventional cemented casing 13 which protects zones above the formation 10 to be treated from invasion by a foreign fluid. In addition, the casing 16 is insulated by the vermiculite slurry from the surrounding formations thus reducing heat losses to these formations as heated fluids pass through the casing 16, or tubing 22.
After placement of the cement l8 and the vermiculite slurry 19 the well 11 is preferably opened into fluid communication with the formation 10 as by perforating the smaller casing 16 and the cement 18 with a number of perforations 21 in a conventional manner. Steam or other heated fluid may then be injected into the formation 10 through the well 11. This steam injection may be carried out directly through the casing 16 or the well may be provided with an injection tubing string 22. The heated fluid is preferably initially injected into the formation 10 at a controlled rate to gradually dehydrate the vermiculite slurry without causing excessive steam pressure in the slurry. That is, the temperature and quantity of heated fluid injected are regulated so that the vermiculite slurry 19 is maintained at a predetermined temperature near the boiling point of water to effectually dehydrate the vermiculite at a rate low enough to avoid the formation of pockets of steam or gas within the annular space 23 between the casings l3 and 16.
reduce the rate of heattransfer from produced fluids to surrounding earth formations in situations where such heat loss is undesirable such as where th'e surrounding earth formation 4 I comprises a perma-frost zone which will melt if heated by such produced fluids. Of course, in such an application if the ternperature of .the produced fluids is less than the boiling tem peratureof water or other slurry forming liquid used, there is no danger that steam pockets may form as the vermiculite is dehydrated.
In summary, this invention provides a method for insulating a well wherein'an annular space between two strings of tubular pipe is filled'with a vermiculite. slurry after the pipe is positioned within the well. More particularly the invention comprises the steps of drilling a borehole from the surface at least to a point adjacent the bottom of a zone in which heat loss is desired to be minimized, extending into the borehole and substantiaily through the zone a first tubular casing of relatively large diameter, extending into the borehole and substantially through .the zone a second tubular casing of smaller diameter, pumping a slurry comprising vermiculite suspended in a carriplies'to the insulation of hot fluid injectionwells, it should be.
er liquid into the annular space between the first and second tubular casings, and closing the annular space adjacent the bottom of the zone with a seal off means such as cement or a packer.
I claim as my invention:
l. A method for insulating a well through which a fluid passes between a sub-surface earth formation and the surface of the earth comprising the steps of:
drilling a borehole from the surface at least to a point adjacent the bottom of a zone in which heat loss is desired to be minimized;
extending into the borehole and substantially through said zone a first tubular casing of relatively large diameter; extending into the borehole and substantially through said zone a second concentric tubular casing of smaller diameter;
pumping a nonsetting slurry. comprising vermiculite suspended "in a carrier liquid into the annular space between said first and second tubular casings;
closing the annular space adjacent the bottom of said zone with a seal-off means; and q drying the vermiculite by controlled application of heat to vaporize the carrier liquid.
2. The method of water. v I
3. A method for insulating a well through which hot fluid is injected into a sub-surface formation of interest comprising the steps of: q
extending a borehole to a point adjacent the top of said formation of interest;
running a string of relatively. large diameter casing into the borehole; i 7 extending the borehole into the formation of interest; running a second string of smaller diameter casing from the surface to a point adjacent the bottom of the borehole; mixing a nonsetting slurry comprising vermiculite and carrier liquid; I v I r placing said slurry in the annular space between the larger and smaller diameter casings; and cementing the smaller casing adjacent terest.
4. The method of claim 3 wherein the carrier liquid is water and wherein the method comprises the additional steps of:
opening the borehole into fluid communication with the formation of interest; and
injecting a hot fluid into the zone of interest at a controlled rate to dehydrate the vermiculite slurry without causing excessive steam ressure in the slurry. 5. The method of c an 3 including the step of fixing the top of said smaller diameter casing with a slip type packoff means capable of providing a substantially fluidtight seal off of the annular space between said larger and smaller diameter casing strings while simultaneously allowing said smaller diameter casing to move upwardly or downwardly relative to said larger diameter casing.
the formation of inclaim 1 whereinlsaid carrier liquid is
Claims (5)
1. A method for insulating a well through which a fluid passes between a sub-surface earth formation and the surface of the earth comprising the steps of: drilling a borehole from the surface at least to a point adjacent the bottom of a zone in which heat loss is desired to be minimized; extending into the borehole and substantially through said zone a first tubular casing of relatively large diameter; extending into the borehole and substantially through said zone a second concentric tubular casing of smaller diameter; pumping a nonsetting slurry comprising vermiculite suspended in a carrier liquid into the annular space between said first and second tubular casings; closing the annular space adjacent the bottom of said zone with a seal-off means; and drying the vermiculite by controlled application of heat to vaporize the carrier liquid.
2. The methoD of claim 1 wherein said carrier liquid is water.
3. A method for insulating a well through which hot fluid is injected into a sub-surface formation of interest comprising the steps of: extending a borehole to a point adjacent the top of said formation of interest; running a string of relatively large diameter casing into the borehole; extending the borehole into the formation of interest; running a second string of smaller diameter casing from the surface to a point adjacent the bottom of the borehole; mixing a nonsetting slurry comprising vermiculite and carrier liquid; placing said slurry in the annular space between the larger and smaller diameter casings; and cementing the smaller casing adjacent the formation of interest.
4. The method of claim 3 wherein the carrier liquid is water and wherein the method comprises the additional steps of: opening the borehole into fluid communication with the formation of interest; and injecting a hot fluid into the zone of interest at a controlled rate to dehydrate the vermiculite slurry without causing excessive steam pressure in the slurry.
5. The method of claim 3 including the step of fixing the top of said smaller diameter casing with a slip type packoff means capable of providing a substantially fluidtight seal off of the annular space between said larger and smaller diameter casing strings while simultaneously allowing said smaller diameter casing to move upwardly or downwardly relative to said larger diameter casing.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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US5472070A | 1970-07-14 | 1970-07-14 |
Publications (1)
Publication Number | Publication Date |
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US3650327A true US3650327A (en) | 1972-03-21 |
Family
ID=21993065
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Application Number | Title | Priority Date | Filing Date |
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US54720A Expired - Lifetime US3650327A (en) | 1970-07-14 | 1970-07-14 | Thermal insulation of wells |
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US (1) | US3650327A (en) |
CA (1) | CA929852A (en) |
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3720267A (en) * | 1970-10-02 | 1973-03-13 | Atlantic Richfield Co | Well production method for permafrost zones |
US3768547A (en) * | 1971-02-04 | 1973-10-30 | Dow Chemical Co | Arrangement to control heat flow between a member and its environment |
US3831678A (en) * | 1973-05-02 | 1974-08-27 | Nl Industries Inc | Method of producing and using a gelled oil base packer fluid |
US3840035A (en) * | 1971-03-15 | 1974-10-08 | K Lefever | Transmission of petroleum products through a frozen medium |
US3948313A (en) * | 1971-02-04 | 1976-04-06 | The Dow Chemical Company | Arrangement to control heat flow between a member and its environment |
US4258791A (en) * | 1980-01-29 | 1981-03-31 | Nl Industries, Inc. | Thermal insulation method |
US4276936A (en) * | 1979-10-01 | 1981-07-07 | Getty Oil Company, Inc. | Method of thermally insulating a wellbore |
US4463807A (en) * | 1981-06-15 | 1984-08-07 | In Situ Technology, Inc. | Minimizing subsidence effects during production of coal in situ |
US4528104A (en) * | 1982-08-19 | 1985-07-09 | Nl Industries, Inc. | Oil based packer fluids |
US4693313A (en) * | 1986-06-26 | 1987-09-15 | Kawasaki Thermal Systems, Inc. | Insulated wellbore casing |
US5297627A (en) * | 1989-10-11 | 1994-03-29 | Mobil Oil Corporation | Method for reduced water coning in a horizontal well during heavy oil production |
US20080224087A1 (en) * | 2007-03-14 | 2008-09-18 | Ezell Ryan G | Aqueous-Based Insulating Fluids and Related Methods |
US20080227665A1 (en) * | 2007-03-14 | 2008-09-18 | Ryan Ezell | Aqueous-Based Insulating Fluids and Related Methods |
US8322423B2 (en) | 2010-06-14 | 2012-12-04 | Halliburton Energy Services, Inc. | Oil-based grouting composition with an insulating material |
WO2014160644A1 (en) * | 2013-03-29 | 2014-10-02 | Halliburton Energy Services, Inc. | Aqueous-based insulating fluids and related methods |
US9062240B2 (en) | 2010-06-14 | 2015-06-23 | Halliburton Energy Services, Inc. | Water-based grouting composition with an insulating material |
US20180362827A1 (en) * | 2017-06-19 | 2018-12-20 | Saudi Arabian Oil Company | In-situ generation of glass-like materials inside subterranean formation |
CN115182710A (en) * | 2021-11-17 | 2022-10-14 | 中国石油大学(华东) | Method for improving thick oil thermal recovery development effect by using aerogel nano fluid |
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Cited By (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3720267A (en) * | 1970-10-02 | 1973-03-13 | Atlantic Richfield Co | Well production method for permafrost zones |
US3768547A (en) * | 1971-02-04 | 1973-10-30 | Dow Chemical Co | Arrangement to control heat flow between a member and its environment |
US3948313A (en) * | 1971-02-04 | 1976-04-06 | The Dow Chemical Company | Arrangement to control heat flow between a member and its environment |
US3840035A (en) * | 1971-03-15 | 1974-10-08 | K Lefever | Transmission of petroleum products through a frozen medium |
US3831678A (en) * | 1973-05-02 | 1974-08-27 | Nl Industries Inc | Method of producing and using a gelled oil base packer fluid |
US4276936A (en) * | 1979-10-01 | 1981-07-07 | Getty Oil Company, Inc. | Method of thermally insulating a wellbore |
US4258791A (en) * | 1980-01-29 | 1981-03-31 | Nl Industries, Inc. | Thermal insulation method |
US4463807A (en) * | 1981-06-15 | 1984-08-07 | In Situ Technology, Inc. | Minimizing subsidence effects during production of coal in situ |
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