US3655569A - Detergent compositions containing a sequestrant and optionally a bleaching agent having a reduced tendency to attack copper, zinc and aluminum - Google Patents
Detergent compositions containing a sequestrant and optionally a bleaching agent having a reduced tendency to attack copper, zinc and aluminum Download PDFInfo
- Publication number
- US3655569A US3655569A US848084A US3655569DA US3655569A US 3655569 A US3655569 A US 3655569A US 848084 A US848084 A US 848084A US 3655569D A US3655569D A US 3655569DA US 3655569 A US3655569 A US 3655569A
- Authority
- US
- United States
- Prior art keywords
- detergent composition
- composition according
- acid ester
- phosphoric acid
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 87
- 239000003599 detergent Substances 0.000 title claims abstract description 73
- 239000007844 bleaching agent Substances 0.000 title claims abstract description 28
- 239000003352 sequestering agent Substances 0.000 title claims abstract description 17
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title abstract description 27
- 229910052802 copper Inorganic materials 0.000 title abstract description 25
- 239000010949 copper Substances 0.000 title abstract description 25
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title abstract description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title abstract description 12
- 239000011701 zinc Substances 0.000 title abstract description 12
- 229910052725 zinc Inorganic materials 0.000 title abstract description 12
- 229910052782 aluminium Inorganic materials 0.000 title abstract description 11
- -1 peroxide salt Chemical class 0.000 claims description 80
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 24
- 125000004432 carbon atom Chemical group C* 0.000 claims description 22
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 19
- 239000001257 hydrogen Substances 0.000 claims description 16
- 229910052739 hydrogen Inorganic materials 0.000 claims description 16
- 239000004094 surface-active agent Substances 0.000 claims description 14
- 229910052783 alkali metal Inorganic materials 0.000 claims description 13
- 150000001340 alkali metals Chemical class 0.000 claims description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 11
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 11
- 239000002736 nonionic surfactant Substances 0.000 claims description 10
- 150000003839 salts Chemical class 0.000 claims description 9
- 239000007787 solid Substances 0.000 claims description 9
- 238000004061 bleaching Methods 0.000 claims description 8
- 239000007800 oxidant agent Substances 0.000 claims description 8
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 239000003945 anionic surfactant Substances 0.000 claims description 5
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 239000004711 α-olefin Substances 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 125000003368 amide group Chemical group 0.000 claims description 3
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- 239000005864 Sulphur Substances 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 125000003262 carboxylic acid ester group Chemical class [H]C([H])([*:2])OC(=O)C([H])([H])[*:1] 0.000 claims 1
- 125000000963 oxybis(methylene) group Chemical group [H]C([H])(*)OC([H])([H])* 0.000 claims 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims 1
- 238000005260 corrosion Methods 0.000 abstract description 19
- 230000007797 corrosion Effects 0.000 abstract description 19
- 239000008233 hard water Substances 0.000 abstract description 11
- 239000003112 inhibitor Substances 0.000 abstract description 6
- 239000000243 solution Substances 0.000 description 31
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 22
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 18
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 13
- 239000002253 acid Substances 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- 238000009472 formulation Methods 0.000 description 11
- 235000011007 phosphoric acid Nutrition 0.000 description 11
- 150000002978 peroxides Chemical class 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 9
- 230000002401 inhibitory effect Effects 0.000 description 9
- 229960004838 phosphoric acid Drugs 0.000 description 9
- 238000005406 washing Methods 0.000 description 9
- 150000002148 esters Chemical class 0.000 description 8
- 235000019441 ethanol Nutrition 0.000 description 8
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 239000011575 calcium Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 6
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 239000007859 condensation product Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 235000021317 phosphate Nutrition 0.000 description 5
- ZLSXZNMFNRQDAZ-UHFFFAOYSA-N phosphoric acid 1-prop-1-en-2-yloxyhexadecane Chemical compound P(O)(O)(O)=O.C(CCCCCCCCCCCCCCC)OC(=C)C ZLSXZNMFNRQDAZ-UHFFFAOYSA-N 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229960001922 sodium perborate Drugs 0.000 description 5
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 229910001424 calcium ion Inorganic materials 0.000 description 4
- 239000012141 concentrate Substances 0.000 description 4
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 150000002191 fatty alcohols Chemical class 0.000 description 4
- 229910001425 magnesium ion Inorganic materials 0.000 description 4
- 239000010452 phosphate Substances 0.000 description 4
- 239000000523 sample Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 235000019832 sodium triphosphate Nutrition 0.000 description 4
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 150000003871 sulfonates Chemical class 0.000 description 4
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 229960000541 cetyl alcohol Drugs 0.000 description 3
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 3
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 229930195734 saturated hydrocarbon Natural products 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000271 synthetic detergent Substances 0.000 description 3
- 239000003760 tallow Substances 0.000 description 3
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 3
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical class CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 2
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 2
- 150000008052 alkyl sulfonates Chemical class 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 150000001733 carboxylic acid esters Chemical class 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 125000005702 oxyalkylene group Chemical group 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 239000008234 soft water Substances 0.000 description 2
- 238000006277 sulfonation reaction Methods 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- KHJWSKNOMFJTDN-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetic acid;sodium Chemical compound [Na].OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KHJWSKNOMFJTDN-UHFFFAOYSA-N 0.000 description 1
- XNCSCQSQSGDGES-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]propyl-(carboxymethyl)amino]acetic acid Chemical compound OC(=O)CN(CC(O)=O)C(C)CN(CC(O)=O)CC(O)=O XNCSCQSQSGDGES-UHFFFAOYSA-N 0.000 description 1
- UTSNPBIUNTZWNX-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;3-dodecyl-2-methylphenol;1,2,4,3-trioxathiane 3,3-dioxide Chemical compound O=S1(=O)OCCOO1.OCCN(CCO)CCO.CCCCCCCCCCCCC1=CC=CC(O)=C1C UTSNPBIUNTZWNX-UHFFFAOYSA-N 0.000 description 1
- JQFVHWURJXFMRP-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;tetradecane-1-sulfonic acid Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCCCS(O)(=O)=O JQFVHWURJXFMRP-UHFFFAOYSA-N 0.000 description 1
- ZJCZFAAXZODMQT-UHFFFAOYSA-N 2-methylpentadecane-2-thiol Chemical compound CCCCCCCCCCCCCC(C)(C)S ZJCZFAAXZODMQT-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- BDDLHHRCDSJVKV-UHFFFAOYSA-N 7028-40-2 Chemical compound CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O BDDLHHRCDSJVKV-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- GCPHQVMETKBFQM-UHFFFAOYSA-N CCCCCCCCCCCCCCCCCOCC(C)OP(=O)(O)O Chemical compound CCCCCCCCCCCCCCCCCOCC(C)OP(=O)(O)O GCPHQVMETKBFQM-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- KUKYTVIZJQMWAV-UHFFFAOYSA-N N.O=S1(=O)OCCOO1.CCCCC1=CC=CC(O)=C1CCCC Chemical compound N.O=S1(=O)OCCOO1.CCCCC1=CC=CC(O)=C1CCCC KUKYTVIZJQMWAV-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000004435 Oxo alcohol Substances 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000004111 Potassium silicate Substances 0.000 description 1
- FIVBZCZGKYWXIV-UHFFFAOYSA-N S1(=O)(=O)OOCCO1.C(CCCCCCCC)C1=C(C=CC=C1)O.[Na] Chemical compound S1(=O)(=O)OOCCO1.C(CCCCCCCC)C1=C(C=CC=C1)O.[Na] FIVBZCZGKYWXIV-UHFFFAOYSA-N 0.000 description 1
- RVGIOJROIFSMOY-UHFFFAOYSA-N S1(=O)(=O)OOCCO1.C(CCCCCCCC)C=1C(=C(C=CC1)O)CCCCCCCCC.[K] Chemical compound S1(=O)(=O)OOCCO1.C(CCCCCCCC)C=1C(=C(C=CC1)O)CCCCCCCCC.[K] RVGIOJROIFSMOY-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- SLINHMUFWFWBMU-UHFFFAOYSA-N Triisopropanolamine Chemical compound CC(O)CN(CC(C)O)CC(C)O SLINHMUFWFWBMU-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical group NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 description 1
- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 1
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- HJMZMZRCABDKKV-UHFFFAOYSA-N carbonocyanidic acid Chemical compound OC(=O)C#N HJMZMZRCABDKKV-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 229920003090 carboxymethyl hydroxyethyl cellulose Polymers 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- BHDAXLOEFWJKTL-UHFFFAOYSA-L dipotassium;carboxylatooxy carbonate Chemical compound [K+].[K+].[O-]C(=O)OOC([O-])=O BHDAXLOEFWJKTL-UHFFFAOYSA-L 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- 238000002036 drum drying Methods 0.000 description 1
- 229960001484 edetic acid Drugs 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 description 1
- 125000003916 ethylene diamine group Chemical group 0.000 description 1
- 229920003089 ethylhydroxy ethyl cellulose Polymers 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- ZUVCYFMOHFTGDM-UHFFFAOYSA-N hexadecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCOP(O)(O)=O ZUVCYFMOHFTGDM-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000003165 hydrotropic effect Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 125000001196 nonadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- UHGIMQLJWRAPLT-UHFFFAOYSA-N octadecyl dihydrogen phosphate Chemical class CCCCCCCCCCCCCCCCCCOP(O)(O)=O UHGIMQLJWRAPLT-UHFFFAOYSA-N 0.000 description 1
- 150000002888 oleic acid derivatives Chemical class 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- LNIAEVLCVIKUGU-UHFFFAOYSA-M potassium;octadecane-1-sulfonate Chemical compound [K+].CCCCCCCCCCCCCCCCCCS([O-])(=O)=O LNIAEVLCVIKUGU-UHFFFAOYSA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 108010080511 serum sodium transport inhibitor Proteins 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 229940048842 sodium xylenesulfonate Drugs 0.000 description 1
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 1
- PNGBYKXZVCIZRN-UHFFFAOYSA-M sodium;hexadecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCCCCCS([O-])(=O)=O PNGBYKXZVCIZRN-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- NVBFHJWHLNUMCV-UHFFFAOYSA-N sulfamide Chemical group NS(N)(=O)=O NVBFHJWHLNUMCV-UHFFFAOYSA-N 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontan-1-ol Chemical class CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical group NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/34—Derivatives of acids of phosphorus
- C11D1/345—Phosphates or phosphites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0073—Anticorrosion compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
- C23F11/167—Phosphorus-containing compounds
- C23F11/1673—Esters of phosphoric or thiophosphoric acids
Definitions
- compositions are provided that are especially formulated with a sequestrant for use in hard water, and optionally, a bleaching agent, and that contain a corrosion in- [52] US. Cl ..252/99, 252/89, 252/95, hibitor lessening the tendency of the composition to attack 252/135 252/389 252/DIG' 1 copper, zinc and aluminum. [51] Int. Cl. ..Clld 7/54 [58] Field of Search ..282/99, 89, 135, 389, DIG.
- Sequestrants of the aminocarboxylic acid type such as ethylene diamine tetraacetic acid and nitriloacetic acid, and their alkali metal and amine salts, are capable of reducing the calcium and magnesium ion concentration in hard water to the desired low level, but they strongly increase the corrosive attack of detergent solutions containing them on copper, zinc and aluminum, as well as metal alloys containing these metals. Such corrosive attack is accentuated if the detergent composition also includes bleaching agents of the peroxide type.
- Phosphoric acid esters of alkyl glyceryl ethers, and phosphoric acid esters of ethylene oxide adducts of fatty alcohols have been proposed as inhibitors of the corrosive effect of detergent compositions containing aminocarboxylic acid chelating agents.
- the effectiveness of these phosphoric acid esters is greatly reduced in the presence of bleaching or oxidizing agents, so that these esters are not capable of imparting a sufficient corrosion inhibiting effect to detergent formulations containing or to be used with a bleaching agent.
- the salts of monocetyl and monostearyl phosphates are good metal corrosion inhibitors in detergent compositions based on nonionic and/or anionic surfactants, but these alkyl phosphates form difficultly soluble calcium and magnesium salts. Consequently, they cannot be employed in detergent formulations intended for use in hard water, unless sequestrants are also present. However, these alkyl phosphates are relatively ineffective in inhibiting the corrosive effect of aminocarboxylic acid sequestrants, such as ethylene diamine 'tetraacetic acid and propylene diamine tetraacetic acid.
- monoalkyl oxypropylene phosphoric acid esters display excellent corrosion-inhibiting properties in synthetic surfactant detergent or washing compositions containing aminocarboxylic acid sequestrants and bleaching or oxidizing agents, such as'peroxides, and demonstrate this effect in both soft and hard water.
- the monoalkyl oxypropylene phosphoric acid esters can be used either in acid form or in salt form. If the acid form is used, the salt form may be formed in situ in the aqueous detergent or washing solution.
- the monoalkyl oxypropylene phosphoric acid ester corrosion inhibitors in accordance with the invention are defined by the following general formula:
- R is a straight or branched chain alkyl radical having from 5 about to about b and preferably from 16 to 18 carbon atoms.
- M is hydrogen, an alkali metal, such as sodium or potassium, ammonium or a strongly basic organic amine, such as tributylamine, monoethanolamine, diethanolamine, or triethanolamine.
- n is a number representing the average number of propylene oxide ether units, and is within the range from about I to about 4, and preferably 1 or 2. It will be understood that when n is greater than 1, mixtures can be present, and probably will be, when propylene oxide is condensed with the alcohol. In such cases, It represents an average number, and can be any fractional number within the range from 1 to 4, for instance, 1.2, 2.5 or 3.3.
- R can be, for example, pentadecyl, palmityl (cetyl), margaryl, stearyl, nonadecyl, and arachidyl.
- Exemplary monoalkyl oxypropylene phosphoric acid esters monopalmityltri(oxypropylene) phosphoric acid, monostearyldi(oxy-propylene)phosphoric acid, monomargaryldi(oxypropylene)phosphoric acid, monononadecyl 0xypropylene phosphoric acid, monoarachidyl oxypropylene phosphoric acid, monostearyltetra(oxypropylene) phosphoric acid, monostearyl tri(oxypropylene) phosphoric acid, monopalmityl(cetyl)tetra(oxypropylene) phosphoric acid,
- the essential ingredients of the detergent compositions of the invention are a synthetic detergent or surfactant, which can be of the anionic and/or nonionic type, and an aminocarboxylic acid chelating agent.
- the monoaklyloxypropylene phosphoric acid ester is intended to be used in the presence of a bleaching or oxidizing agent, such as a peroxide bleaching agent, and this is an optional ingredient, but it can be added later, when the washing solution is prepared.
- a bleaching or oxidizing agent such as a peroxide bleaching agent
- this is an optional ingredient, but it can be added later, when the washing solution is prepared.
- these components which with the monoalkyloxpropylene phosphoric acid ester are the only essential components, there can be included as optional components builders, fillers, optical whitening agents, coloring agents, perfumes, and other conventional detergent formulation components.
- the detergent formulations of the invention have a reduced tendency to corrode copper, zinc and aluminum, and alloys containing such metals.
- the weight ratio of monoalkyl oxypropylene phosphoric acid ester to surfactant should be within the range from about 10:1 to about 1:10.
- the detergent compositions of the invention have the following formulation, based on the solids content:
- the composition is in the form of particles produced by drying an aqueous mixture or slurry of the componcnt.
- Spray-drying is a preferred drying method, since it produces friable light particles which dissolve rapidly and completely in water.
- Other drying methods include suspension-drying and drum drying, the latter procedure being particularly useful in the production of particulate detergent mixtures in flake or large particle form.
- the detergent composition can also be formulated as an aqueous concentrate which forms a washing solution upon dilution with water.
- the concentrate has as high a composition solids content as possible, within the range from 20 to 75 percent, preferably from 30 to 60 percent by weight.
- the upper limit of solids content is normally determined by the solubility of the components in water or other solvent or suspending medium, such as ethyl alcohol, or methyl alcohol.
- solubility in water or other solvent can be increased in the concentrate by the addition of solubilizing agents.
- the monoalkyloxypropylene phosphoric acid esters display a solubilizing effect on the other ingredients. This effect can be increased by the addition of other hydrotropic substances, such as sodium xylene sulfonate and sodium toluene sulfonate.
- Organic solvents can be used, such as ethyl alcohol or methyl alcohol.
- the synthetic detergent or surfactant employed in the compositions of the invention can be of the anionic type, of the nonionic type, or the mixed nonionic-anionic type. Mixtures of anionic and nonionic surfactants can also be employed.
- anionic surfactants which can be employed are the alkyl aryl sulfonates, the alkyl sulfonates, the alpha-olefin sulfonates, the alkyl ether polyglycol sulfates, and the alkyl phenol ether sulfates. These are all known compounds.
- alkyl aryl sulfonates are the alkyl benzene sulfonates, which have the general formula:
- R is a straight or branched chain alkyl radical having from about four to about 18 carbon atoms.
- R is hydrogen or a straight or branched chain alkyl radical having from one to about 12 carbon atoms. The total of the number of carbon atoms in R and R is within the range from about and to about 24.
- M is hydrogen, or an alkali metal, ammonium or organic amine cation.
- alkyl benzene sulfonates examples include sodium dodecylbenzene sulfonate, sodium polypropylene benzene sulfonate (Lewis Pat. No. 2,477,383), sodium tridecylbenzene sulfonate, sodium cetylbenzene sulfonate, potassium dodecyl toluene sulfonate, triethanolamine dodecylbenzene sulfonate, potassium dinonylbenzene sulfonate, sodium didodecylbenzene sulfonate, and ammonium polypropylene benzene sulfonate.
- alkyl sulfonates have the general formula:
- R is a straight or branched chain alkyl group having from about ten to about twenty carbon atoms
- M is hydrogen, or an alkali metal, ammonium or organic amine cation.
- sulfonates are obtained by sulfonating paraffmic hydrocarbons with a mixture of sulfur dioxide and oxygen using energy rich radiation. Exemplary are sodium cetyl sulfonate, potassium stearyl sulfonate, and triethanolamine myristyl sulfonate.
- alpha-olefin sulfonates have the formula:
- R is an alkylene (ethylenically unsaturated) radical having from about 10 to about 20 carbon atoms, and M is hydrogen, or an alkali metal, ammonium or organic amine cation.
- sulfonates are obtained by sulfonation of aIpha-olefins of the general formula:
- R is an alkyl radical having from about nine to about 19 carbon atoms.
- exemplary is the sodium salt of the alpha-olefin sulfonic acid obtained by the sulfonation of a mixture of alpha-olefins having from 14 to 18 carbon atoms.
- alkyl sulfates which have the formula:
- R is an alkyl radical having from about 10 to about 22 carbon atoms
- M is hydrogen, an alkali metal, ammonium, or an organic amine cation.
- exemplary are sodium coconut oil fatty alcohols sulfate, potassium cetyl alcohol sulfate, ammonium stearyl alcohol sulfate, and triethanolamine lauryl alcohol sulfate.
- alkyl oxyalkylene sulfates have the general formula:
- R is an alkyl radical having from about 12 to about 20 carbon atoms.
- R is hydrogen or methyl.
- M is hydrogen, or an alkali metal, ammonium or organic amine cation.
- 11 is an integer representing the average number of the oxyalkylene units indicated, and is within the range from 2 to 6. It will be understood that n can represent an average number, such as 2.5.
- Exemplary are the sodium salt of sulfonated lauryl alcohol condensed with 3 moles of ethylene oxide, and the potassium salt of sulfonated cetyl stearyl alcohol condensed with 2 moles of propylene oxide, and then 2 moles of ethylene oxide.
- alkyl phenol oxyalkylene sulfates are examples of mixed nonioniczanionic surfactants.
- alkyl phenol oxyalkylene sulfates have the general formula:
- R is as above.
- R is a straight or branched alkyl radical having from four to about 16 carbon atoms
- R is hydrogen or a straight or branched alkyl radical having from one to about 14 carbon atoms, the total number of carbon atoms in R and R being within the range from eight to 24.
- n represents the number of units enclosed by the brackets, and is a number from 1 to 6. It will be understood that n can be an average value, such as 3.5.
- Exemplary are sodium nonyl phenol oxyethylene sulfate (condensed with 4 moles of ethylene oxide), potassium dinonyl phenol oxyethylene sulfate (condensed with 6 mole of ethylene oxide), ammonium dibutyl phenol oxyethylene sulfate (condensed with 3 mole of ethylene oxide), and triethanolamine dodecylcresol oxyethylene sulfate (condensed with 4 moles of ethylene oxide).
- nonionic surfactants which can be employed include the polyoxyalkylene glycol monoethers, monoamines, monoamides, monocarboxylic acid esters and monothiocarboxylic acid esters.
- alkyl oxyalkylene ether and ester and thioether and ester derivatives have the following general formula:
- R is as above, and R is a straight or branched chain saturated or unsaturated hydrocarbon group having from about five to about 18 carbon atoms, or an aralkyl group having an aryl nucleus to which is attached a straight or branched chain saturated or unsaturated hydrocarbon group having from about eight to about 18 carbon atoms, linked through A to the aryl nucleus.
- A is either oxygen, thioether, amino, arnido, a carboxylic acid ester or a thiocarboxylic acid ester group.
- n is a number from 8 to 35, and can represent an average number, such as 10.5.
- R radicals include amyl, octyl, nonyl, decyl, tetradecyl, lauryl, myristyl, cetyl, or stearyl.
- exemplary aralkyl groups include octylphenyl, nonylphenyl, decylphenyl, and stearylphenyl. These compounds are prepared by condensation of the corresponding alcohol, mercaptan, amine, oxy or thio fatty acids or esters with ethylene oxide. Exemplary are the condensation products of oleyl or lauryl alcohol, mercaptan or amine, or oleic or lauric acid, with from 8 to 17 moles of ethylene oxide, and the polyoxyethylene ester of tall oil fatty acids.
- the polyoxyalkylene surfactants have the formula:
- R is as above.
- R is a straight or branched chain saturated or unsaturated hydrocarbon group having at least five carbon atoms up to about 18 carbon atoms.
- A is oxygen or sulfur, and n is a number within the range from 8 to 35.
- R may, for example, be a straight or branched chain amyl, octyl, nonyl, dodecyl, tetradecyl, lauryl, cetyl, myn'styl or stearyl group.
- exemplary are condensation products of octyl and nonyl phenol and thiophenol with from 8 to 17 moles of ethylene oxide.
- Organic compounds suitable for forming Y are compounds in which the hydrogen atoms are activated by an oxygen atom, such as in a hydroxyl group, a phenol group or a carboxyl group, or by a basic nitrogen atom, such as in an amine group and amide group, a sulfamide group, a carbamide group, and a thiocarbamide group, or by a sulfur atom, such as in a mercaptan.
- an oxygen atom such as in a hydroxyl group, a phenol group or a carboxyl group
- a basic nitrogen atom such as in an amine group and amide group, a sulfamide group, a carbamide group, and a thiocarbamide group
- sulfur atom such as in a mercaptan.
- Exemplary Y compounds are glycerol, ethylene glycol, propylene glycol, methanol, ethanol, isopropanol, nbutanol, Z-ethylhexanol, lauryl alcohol, cetyl alcohol, stearyl alcohol, eicosanol, oleyl alcohol, so-called OXO-alcohol mixtures, butanediol, pentaerythritol, oxalic acid, triethanolamine, aniline, resorcinol, triisopropanolamine, sucrose, ethylenediamine, diethylenetriamine, acetamide, coconut oil fatty amine, methyl mercaptan, dode'cyl mercaptan, hexadecyl mercaptan, 61C.
- polyoxyalkylene glycol ether surfactants has the formula:
- Y is an organic residue as defined above, and R, R R and R are selected from the group consisting of hydrogen, aliphatic and aromatic radicals, at least one of these substituents not being hydrogen.
- n is a number greater than 6.4, as determined by hydroxyl number, and X is a water-solubilizing group, as defined in U.S. PAT. Nos. 2,674,691 and 2,677,700.
- Exemplary of this type of compound are the fatty alcohol styrene oxide condensates containing 7 moles of styrene oxide, with the water-solubilizing group X being 70 moles of ethylene oxide.
- the sequestrant employed in accordance with the invention to capture calcium and magnesium ions in hard water is an amino polycarboxylic acid or salt having the general formula:
- N- (CzHdTUnCHzCO OM A is CH COOM or CH CH OH.
- M is hydrogen or an alkali metal, such as sodium and potassium or ammonium, and n is a number from 0 to 5.
- nitrilotriacetic acid ethylenediamine tetraacetic acid
- the mono-, di-, triand tetra-sodium salts of ethylene diamine tetraacetic acid the mono-, diand tri-sodium salts of nitrilotriacetic acid
- the mono-, di-, tri-, tetraand penta-sodium salts of diethylenetriamine pentaacetic acid and the mono-, diand tri-potassium salts of hydroxethylethylenediamine triacetic acid.
- the detergent compositions of the invention may also contain or are for use with a bleaching or oxidizing agent, such as an inorganic peroxide which serves as a bleaching agent.
- a bleaching or oxidizing agent such as an inorganic peroxide which serves as a bleaching agent.
- Suitable peroxides are the perborates, persulfates, percarbonates and perpyrophosphates, in the form of their watersoluble salts, preferably their alkali metal salts.
- Exemplary are sodium perborate, potassium persulfate, potassium percarbonate, K C O and sodium perpyrophosphate Na i-1 11 O2'2H2O.
- tetrasodium pyrophosphate sodium carbonate, sodium sulfate, potassium carbonate, potassium sulfate, sodium silicate, potassium silicate.
- Optical whitening agents, coloring agents and perfumes can also be added.
- Soil-suspending agents can also be incorporated, such as sodium carboxymethyl cellulose, hydroxyethyl cellulose, and ethylhydroxy-ethyl cellulose, as well as starch, polyethylene glycols, and polyvinyl alcohol.
- Pentasodium tripolyphosphate 15.2% 0.5 g/l Bleaching agent Sodium perborate Builders Sodium carbonate Sodium silicate Nonionic surfactant Condensation product of tallow fatty alcohol and 8 moles ethylene oxide 30.3% r g/l TABLE VI Alkyl oxypropylcnc Copper Example no. phosphoric ncid dissolved (mg/l) Control D None [03 it Mono-cetyl oxypropylcne phosphoric acid was effective in inhibiting copper corrosion.
- EXAMPLE 9 A detergent formulation'was prepared, as shown in Table VIII. This composition was dissolved in water of 5 dH, to the solution concentration shown in the Table.
- the detergent compositions prepared according to the invention show a very substantial decrease in the corrosion of copper, zinc and aluminum. Copper, aluminum and zinc corrosion is inhibited even when hard water is used in the preparation of the detergent solution. It, furthermore, was proved by test washing that the compositions according to the invention provide very good washing results and that, in addition, the resulting detergents are low foaming, which is important where the detergents are used in automatic washing machines.
- Tetrasodium salt of ethylenediamine tetraaoetic acid 22. 9 1. 6 Pentasodium tripolyphosphate 11.5 0.8 Bleaching agent:
- compositions were each dissolved in water of 15 of hardness (l/ Mg-hardness, 4/5 Ca-hardness) to the solution concentration indicated.
- alkyl oxypropylene phosphoric acid esters were effective in inhibiting copper corrosion by the sodium ethylenediaminetetraacetic acid and the peroxide bleaching agent.
- a detergent composition for use in hard and soft water consisting essentially of an organic surfactant selected from the group consisting of anionic and nonionic organic surfactants, an aminocarboxylic acid or salt sequestrant in an amount to sequester calcium and magnesium ions in hard water and a mono-alkyl oxypropylene phosphoric acid ester of the formula OM R0(Ca e )no OM wherein R is an alkyl group having from 15 to 20 carbon atoms and M is selected from the group consisting of hydrogen, alkali metals, ammonium and strongly basic organic amine cations, and n is a number within the range from 1 to 4, in an amount to lessen the corrosive effect of the aminocarboxylic acid on copper, zinc and aluminum, in the presence of a bleaching or oxidizing agent.
- an organic surfactant selected from the group consisting of anionic and nonionic organic surfactants, an aminocarboxylic acid or salt sequestrant in an amount to sequester calcium and magnesium
- a detergent composition according to claim 1 consisting essentially of a bleaching or oxidizing agent in an amount within the range from about 5 to about 40 percent by weight.
- a detergent composition according to claim 1, in which the aminocarboxylic acid or salt sequestrant has the general formula:
- A is CH COO1-l OR -CH CH Ol-l
- M is hydrogen, or an alkali metal, ammonium or organic amine cation
- n is a number from 0 to 5.
- a detergent composition according to claim 1 consisting essentially of one or more of builders, in an amount within the range from about 10 to about percent of the total weight of the detergent composition.
- a detergent composition according to claim 1 in which 16.
- a detergent composition according to claim 1, in the form of a concentrated aqueous solution having a solids conthe phosphoric acid ester is monostearyl di(oxypropylene) 5 tent offi'om about to about 75 percent by weightorthophosphoric acid ester.
Abstract
Detergent compositions are provided that are especially formulated with a sequestrant for use in hard water, and optionally, a bleaching agent, and that contain a corrosion inhibitor lessening the tendency of the composition to attack copper, zinc and aluminum.
Description
United States Patent Hellsten et al. [451 Apr. 11, 1972 [54] DETERGENT COMPOSITIONS 282/95 CONTAINING A SEQUESTRANT AND OPTIONALLY A BLEACHING AGENT [561 References CM HAVING A REDUCED TENDENCY T0 UNITED STATES PATENTS ATTACK COPPER ZINC AND 2,921,908 1/1960 McCune ..252/135 x ALUMINUM 3,004,056 10/1961 Nann, Jr. et a1 ..252/89 x A 21220: 211222 21121;: ::..=1;.-.-;.-.- gsf f stenungs'md 3,522,184 7/1970 Nakagawa et a] ..252/99 [73] Assignee: M0 Och Domsjo Aktiebolag, Omskoldsvik, Primary ExaminerMayer weinblan Sweden Attorney-Janes & Chapman [22] Filed: Aug. 6, 1969 [57] ABSTRACT [21] Appl. No.: 848,084 Detergent compositions are provided that are especially formulated with a sequestrant for use in hard water, and optionally, a bleaching agent, and that contain a corrosion in- [52] US. Cl ..252/99, 252/89, 252/95, hibitor lessening the tendency of the composition to attack 252/135 252/389 252/DIG' 1 copper, zinc and aluminum. [51] Int. Cl. ..Clld 7/54 [58] Field of Search ..282/99, 89, 135, 389, DIG. 1; 17 Claims, N0 Drawings In order to obtain a satisfactory detergent action in hard water, it is necessary in most detergent compositions to include a sequestrant that is capable of capturing calcium and magnesium ions present in the hard water, and reducing their concentration in the washing solution to less than g./l. Pentasodium tripolyphosphate is widely used for this purpose. However, the use of phosphates in detergent compositions is no longer favored, because the phosphate content in the wash water has a considerable nutrient value, and if high phosphate waste waters find their way into fresh water streams and lakes, the growth of plant life therein is greatly accelerated, leading even to a choking up of the water courses. Since detergent formulations of the synthetic detergent type are now widely used, it is important to formulate them with nonor low-phosphate sequestrants.
Sequestrants of the aminocarboxylic acid type, such as ethylene diamine tetraacetic acid and nitriloacetic acid, and their alkali metal and amine salts, are capable of reducing the calcium and magnesium ion concentration in hard water to the desired low level, but they strongly increase the corrosive attack of detergent solutions containing them on copper, zinc and aluminum, as well as metal alloys containing these metals. Such corrosive attack is accentuated if the detergent composition also includes bleaching agents of the peroxide type. Since copper, zinc and aluminum and their alloys are widely used in dishwashing and clothes washing machines, for example, in the protective conduits for the electric heating elements, which are of nickel-plated copper, in brass valve seats, in copper liquid thermometers, in zinc alloy pump wheels, and in zinc-plated steel outer drums, in pump casings,.and the like, such corrosion presents a particularly serious problem, and must be inhibited if such sequestrants'are to be used in detergent formulations.
Phosphoric acid esters of alkyl glyceryl ethers, and phosphoric acid esters of ethylene oxide adducts of fatty alcohols have been proposed as inhibitors of the corrosive effect of detergent compositions containing aminocarboxylic acid chelating agents. However, the effectiveness of these phosphoric acid esters is greatly reduced in the presence of bleaching or oxidizing agents, so that these esters are not capable of imparting a sufficient corrosion inhibiting effect to detergent formulations containing or to be used with a bleaching agent.
The salts of monocetyl and monostearyl phosphates are good metal corrosion inhibitors in detergent compositions based on nonionic and/or anionic surfactants, but these alkyl phosphates form difficultly soluble calcium and magnesium salts. Consequently, they cannot be employed in detergent formulations intended for use in hard water, unless sequestrants are also present. However, these alkyl phosphates are relatively ineffective in inhibiting the corrosive effect of aminocarboxylic acid sequestrants, such as ethylene diamine 'tetraacetic acid and propylene diamine tetraacetic acid.
In accordance with the invention, it has been determined that monoalkyl oxypropylene phosphoric acid esters display excellent corrosion-inhibiting properties in synthetic surfactant detergent or washing compositions containing aminocarboxylic acid sequestrants and bleaching or oxidizing agents, such as'peroxides, and demonstrate this effect in both soft and hard water. The monoalkyl oxypropylene phosphoric acid esters can be used either in acid form or in salt form. If the acid form is used, the salt form may be formed in situ in the aqueous detergent or washing solution.
The monoalkyl oxypropylene phosphoric acid ester corrosion inhibitors in accordance with the invention are defined by the following general formula:
In the above formula, R is a straight or branched chain alkyl radical having from 5 about to about b and preferably from 16 to 18 carbon atoms.
M is hydrogen, an alkali metal, such as sodium or potassium, ammonium or a strongly basic organic amine, such as tributylamine, monoethanolamine, diethanolamine, or triethanolamine.
n is a number representing the average number of propylene oxide ether units, and is within the range from about I to about 4, and preferably 1 or 2. It will be understood that when n is greater than 1, mixtures can be present, and probably will be, when propylene oxide is condensed with the alcohol. In such cases, It represents an average number, and can be any fractional number within the range from 1 to 4, for instance, 1.2, 2.5 or 3.3.
R can be, for example, pentadecyl, palmityl (cetyl), margaryl, stearyl, nonadecyl, and arachidyl.
Exemplary monoalkyl oxypropylene phosphoric acid esters monopalmityltri(oxypropylene) phosphoric acid, monostearyldi(oxy-propylene)phosphoric acid, monomargaryldi(oxypropylene)phosphoric acid, monononadecyl 0xypropylene phosphoric acid, monoarachidyl oxypropylene phosphoric acid, monostearyltetra(oxypropylene) phosphoric acid, monostearyl tri(oxypropylene) phosphoric acid, monopalmityl(cetyl)tetra(oxypropylene) phosphoric acid,
monopalmityl(cetyl)(oxypropylene)1.5 phos phoric acid monostearyl air sropylenn, phospmi c acid, and monomargaryl (oxypropylene) phosphoric acid, and the sodium, potassium, ammonium, tributylamine and triethanolamine salts thereof.
In addition to the monoalkyloxypropylene phosphoric acid ester, the essential ingredients of the detergent compositions of the invention are a synthetic detergent or surfactant, which can be of the anionic and/or nonionic type, and an aminocarboxylic acid chelating agent. The monoaklyloxypropylene phosphoric acid ester is intended to be used in the presence of a bleaching or oxidizing agent, such as a peroxide bleaching agent, and this is an optional ingredient, but it can be added later, when the washing solution is prepared. In addition to these components, which with the monoalkyloxpropylene phosphoric acid ester are the only essential components, there can be included as optional components builders, fillers, optical whitening agents, coloring agents, perfumes, and other conventional detergent formulation components.
As compared to detergent formulations of this type that do not contain monoalkyloxypropylene phosphoric acid esters, the detergent formulations of the invention have a reduced tendency to corrode copper, zinc and aluminum, and alloys containing such metals. In order to keep the tendency to corrode such metals at-a minimum, the weight ratio of monoalkyl oxypropylene phosphoric acid ester to surfactant should be within the range from about 10:1 to about 1:10.
The detergent compositions of the invention have the following formulation, based on the solids content:
Overall range Preferred range ior zo a 2m 30% Ste 15% Monoalkylpropylene glycol ether phosphoric acid ester Optional ingredients Bleaching or oxidizing agent, such as peroxide Builders, soil suspending agents, and other additives l to 20% 2 to 5% 5 to 40% l5 to 30% IO to 20 to 60% The essential and optional components of the detergent compositions of the invention are solids, for the most part, and consequently the detergent compositions of the invention are conveniently formulated and marketed as solids, in any particulate form, as, for instance, powders, flakes, granules, spray-dried ovoids or spheres, pellets, or other agglomerates. Preferably, the composition is in the form of particles produced by drying an aqueous mixture or slurry of the componcnt. Spray-drying is a preferred drying method, since it produces friable light particles which dissolve rapidly and completely in water. Other drying methods include suspension-drying and drum drying, the latter procedure being particularly useful in the production of particulate detergent mixtures in flake or large particle form.
The detergent composition can also be formulated as an aqueous concentrate which forms a washing solution upon dilution with water. The concentrate has as high a composition solids content as possible, within the range from 20 to 75 percent, preferably from 30 to 60 percent by weight. The upper limit of solids content is normally determined by the solubility of the components in water or other solvent or suspending medium, such as ethyl alcohol, or methyl alcohol. However, solubility in water or other solvent can be increased in the concentrate by the addition of solubilizing agents. To some extent, the monoalkyloxypropylene phosphoric acid esters display a solubilizing effect on the other ingredients. This effect can be increased by the addition of other hydrotropic substances, such as sodium xylene sulfonate and sodium toluene sulfonate. Organic solvents can be used, such as ethyl alcohol or methyl alcohol.
The synthetic detergent or surfactant employed in the compositions of the invention can be of the anionic type, of the nonionic type, or the mixed nonionic-anionic type. Mixtures of anionic and nonionic surfactants can also be employed. Among the anionic surfactants which can be employed are the alkyl aryl sulfonates, the alkyl sulfonates, the alpha-olefin sulfonates, the alkyl ether polyglycol sulfates, and the alkyl phenol ether sulfates. These are all known compounds.
Exemplary of the alkyl aryl sulfonates are the alkyl benzene sulfonates, which have the general formula:
SOaM
I R is a straight or branched chain alkyl radical having from about four to about 18 carbon atoms. R is hydrogen or a straight or branched chain alkyl radical having from one to about 12 carbon atoms. The total of the number of carbon atoms in R and R is within the range from about and to about 24. M is hydrogen, or an alkali metal, ammonium or organic amine cation.
Examples of suitable alkyl benzene sulfonates are sodium dodecylbenzene sulfonate, sodium polypropylene benzene sulfonate (Lewis Pat. No. 2,477,383), sodium tridecylbenzene sulfonate, sodium cetylbenzene sulfonate, potassium dodecyl toluene sulfonate, triethanolamine dodecylbenzene sulfonate, potassium dinonylbenzene sulfonate, sodium didodecylbenzene sulfonate, and ammonium polypropylene benzene sulfonate.
The alkyl sulfonates have the general formula:
R, is a straight or branched chain alkyl group having from about ten to about twenty carbon atoms, and M is hydrogen, or an alkali metal, ammonium or organic amine cation. Such sulfonates are obtained by sulfonating paraffmic hydrocarbons with a mixture of sulfur dioxide and oxygen using energy rich radiation. Exemplary are sodium cetyl sulfonate, potassium stearyl sulfonate, and triethanolamine myristyl sulfonate.
The alpha-olefin sulfonates have the formula:
R, -so, M
R, is an alkylene (ethylenically unsaturated) radical having from about 10 to about 20 carbon atoms, and M is hydrogen, or an alkali metal, ammonium or organic amine cation. Such sulfonates are obtained by sulfonation of aIpha-olefins of the general formula:
R is an alkyl radical having from about nine to about 19 carbon atoms. Exemplary is the sodium salt of the alpha-olefin sulfonic acid obtained by the sulfonation of a mixture of alpha-olefins having from 14 to 18 carbon atoms.
Also useful are the alkyl sulfates, which have the formula:
R is an alkyl radical having from about 10 to about 22 carbon atoms, and M is hydrogen, an alkali metal, ammonium, or an organic amine cation. Exemplary are sodium coconut oil fatty alcohols sulfate, potassium cetyl alcohol sulfate, ammonium stearyl alcohol sulfate, and triethanolamine lauryl alcohol sulfate.
The alkyl oxyalkylene sulfates have the general formula:
R is an alkyl radical having from about 12 to about 20 carbon atoms. R is hydrogen or methyl. M is hydrogen, or an alkali metal, ammonium or organic amine cation. 11 is an integer representing the average number of the oxyalkylene units indicated, and is within the range from 2 to 6. It will be understood that n can represent an average number, such as 2.5. Exemplary are the sodium salt of sulfonated lauryl alcohol condensed with 3 moles of ethylene oxide, and the potassium salt of sulfonated cetyl stearyl alcohol condensed with 2 moles of propylene oxide, and then 2 moles of ethylene oxide.
These and the alkyl phenol oxyalkylene sulfates below are examples of mixed nonioniczanionic surfactants.
The alkyl phenol oxyalkylene sulfates have the general formula:
R is as above. R is a straight or branched alkyl radical having from four to about 16 carbon atoms, and R is hydrogen or a straight or branched alkyl radical having from one to about 14 carbon atoms, the total number of carbon atoms in R and R being within the range from eight to 24. n represents the number of units enclosed by the brackets, and is a number from 1 to 6. It will be understood that n can be an average value, such as 3.5. Exemplary are sodium nonyl phenol oxyethylene sulfate (condensed with 4 moles of ethylene oxide), potassium dinonyl phenol oxyethylene sulfate (condensed with 6 mole of ethylene oxide), ammonium dibutyl phenol oxyethylene sulfate (condensed with 3 mole of ethylene oxide), and triethanolamine dodecylcresol oxyethylene sulfate (condensed with 4 moles of ethylene oxide).
The nonionic surfactants which can be employed include the polyoxyalkylene glycol monoethers, monoamines, monoamides, monocarboxylic acid esters and monothiocarboxylic acid esters.
The alkyl oxyalkylene ether and ester and thioether and ester derivatives have the following general formula:
R is as above, and R is a straight or branched chain saturated or unsaturated hydrocarbon group having from about five to about 18 carbon atoms, or an aralkyl group having an aryl nucleus to which is attached a straight or branched chain saturated or unsaturated hydrocarbon group having from about eight to about 18 carbon atoms, linked through A to the aryl nucleus.
A is either oxygen, thioether, amino, arnido, a carboxylic acid ester or a thiocarboxylic acid ester group. n is a number from 8 to 35, and can represent an average number, such as 10.5.
Exemplary R radicals include amyl, octyl, nonyl, decyl, tetradecyl, lauryl, myristyl, cetyl, or stearyl. Exemplary aralkyl groups include octylphenyl, nonylphenyl, decylphenyl, and stearylphenyl. These compounds are prepared by condensation of the corresponding alcohol, mercaptan, amine, oxy or thio fatty acids or esters with ethylene oxide. Exemplary are the condensation products of oleyl or lauryl alcohol, mercaptan or amine, or oleic or lauric acid, with from 8 to 17 moles of ethylene oxide, and the polyoxyethylene ester of tall oil fatty acids.
In the case where R is aralkyl, the polyoxyalkylene surfactants have the formula:
R, is as above. R is a straight or branched chain saturated or unsaturated hydrocarbon group having at least five carbon atoms up to about 18 carbon atoms.
A is oxygen or sulfur, and n is a number within the range from 8 to 35.
R may, for example, be a straight or branched chain amyl, octyl, nonyl, dodecyl, tetradecyl, lauryl, cetyl, myn'styl or stearyl group. Exemplary are condensation products of octyl and nonyl phenol and thiophenol with from 8 to 17 moles of ethylene oxide.
Also useful are the mixed polyoxyethylene oxypropylene ethers having the formula:
These compounds are described in U.S. Pat. Nos. 2,674,619 to Lundsted, dated Apr. 6, 1954, and 2,677,700 to Jackson et al., dated May 6, 1954. They are condensates of a 1,2-alkylene oxide, such as 1,2-propylene oxide and 1,2-ethylene oxide, the ethylene oxide residues constituting from 20 to 90 percent of the resulting concentrate. Y as defined in these patents is the residue of an organic compound containing therein a single hydrogen atom capable of reacting with a 1,2-alkylene oxide, and the total of x and y is from 2 to 20. x and y mayalso be zero. n is a number from 1 to p is a number from 1 to 5, and the average weight of the entire block polymer is from 1,000 to 4,000.
Organic compounds suitable for forming Y are compounds in which the hydrogen atoms are activated by an oxygen atom, such as in a hydroxyl group, a phenol group or a carboxyl group, or by a basic nitrogen atom, such as in an amine group and amide group, a sulfamide group, a carbamide group, and a thiocarbamide group, or by a sulfur atom, such as in a mercaptan.
Exemplary Y compounds are glycerol, ethylene glycol, propylene glycol, methanol, ethanol, isopropanol, nbutanol, Z-ethylhexanol, lauryl alcohol, cetyl alcohol, stearyl alcohol, eicosanol, oleyl alcohol, so-called OXO-alcohol mixtures, butanediol, pentaerythritol, oxalic acid, triethanolamine, aniline, resorcinol, triisopropanolamine, sucrose, ethylenediamine, diethylenetriamine, acetamide, coconut oil fatty amine, methyl mercaptan, dode'cyl mercaptan, hexadecyl mercaptan, 61C.
Exemplary of this type of nonionic surfactants are propylene glycol condensed with 20 moles of propylene oxide and then with 5 moles of ethylene oxide, Y being hydroxyl, n l, x y 5, m 21, andp= 1, as well as ethylene diamine with which have been condensed 12 moles of propylene oxide followed by 10 moles of ethylene oxide, Y being an ethylene diamine residue, n 4,x=0, y= 2.5, m= 3, andp=4.
Another type of polyoxyalkylene glycol ether surfactants has the formula:
Y is an organic residue as defined above, and R, R R and R are selected from the group consisting of hydrogen, aliphatic and aromatic radicals, at least one of these substituents not being hydrogen. n is a number greater than 6.4, as determined by hydroxyl number, and X is a water-solubilizing group, as defined in U.S. PAT. Nos. 2,674,691 and 2,677,700.
Exemplary of this type of compound are the fatty alcohol styrene oxide condensates containing 7 moles of styrene oxide, with the water-solubilizing group X being 70 moles of ethylene oxide.
The sequestrant employed in accordance with the invention to capture calcium and magnesium ions in hard water is an amino polycarboxylic acid or salt having the general formula:
MOO OOH:
N- (CzHdTUnCHzCO OM A is CH COOM or CH CH OH. M is hydrogen or an alkali metal, such as sodium and potassium or ammonium, and n is a number from 0 to 5. Exemplary are nitrilotriacetic acid, ethylenediamine tetraacetic acid, the mono-, di-, triand tetra-sodium salts of ethylene diamine tetraacetic acid, the mono-, diand tri-sodium salts of nitrilotriacetic acid, the mono-, di-, tri-, tetraand penta-sodium salts of diethylenetriamine pentaacetic acid, and the mono-, diand tri-potassium salts of hydroxethylethylenediamine triacetic acid.
The detergent compositions of the invention may also contain or are for use with a bleaching or oxidizing agent, such as an inorganic peroxide which serves as a bleaching agent. Suitable peroxides are the perborates, persulfates, percarbonates and perpyrophosphates, in the form of their watersoluble salts, preferably their alkali metal salts. Exemplary are sodium perborate, potassium persulfate, potassium percarbonate, K C O and sodium perpyrophosphate Na i-1 11 O2'2H2O.
As builders and fillers, there can be used tetrasodium pyrophosphate, sodium carbonate, sodium sulfate, potassium carbonate, potassium sulfate, sodium silicate, potassium silicate. Optical whitening agents, coloring agents and perfumes can also be added.
Soil-suspending agents can also be incorporated, such as sodium carboxymethyl cellulose, hydroxyethyl cellulose, and ethylhydroxy-ethyl cellulose, as well as starch, polyethylene glycols, and polyvinyl alcohol.
The following Examples in the opinion of the inventors represent preferred embodiments of their invention.
EXAMPLES 1 TO 4 TABLE I by Solution Composition weight Concentration 1.6 g]! 0.8 g/l The tendency of each solution to corrode copper metal was determined by the following test.
To 100 ml. portions of this solution there was added 0.4 g./l. of the alkylether phosphoric acid ester shown in Table II.
To each 100 m]. sample, and a control sample without the phosphoric acid ester, there was added 0.5 g. of copper powder, and the solutions boiled for 30 minutes. After removing the copper powder by filtration, the copper content of each sample was determined by means of an atom absorption photometer. The amount of copper dissolved represents the amount of copper removed by corrosion, and is thus a measure of the tendency of the detergent solution to corrode copper.
For comparison, to show the relative effectiveness of an alkyl phosphoric acid ester, (monocetyl ortho phosphate) was added to another 100 cc. sample (control B), and tested in the same way.
The data are given in TAble ll.
The results for Control A, vis-a-vis Examples 1 to 4, in Table II show that the alkyl oxypropylene phosphoric acid esters of Examples 1 to 4 were effective in inhibiting copper corrosion by the sodium ethylenediaminetetraacetic acid and the peroxide bleaching agent. On the other hand, the alkyl phosphoric acid ester, Control B, was virtually ineffective. This demonstrates the importance of the oxypropylene group in the phosphoric acid ester, in corrosion inhibition.
EXAMPLES 5 TO 7 A detergent composition was prepared to the formulation shown in Table III. This was dissolved in water of 15 of hardness to form a solution of the concentration indicated.
To 100 ml. portions of this solution, 0.4 g./l. of the alkyl oxypropylene phosphoric acid esters listed in Table IV was added. Thereafter, the amount of copper dissolved by the detergent solutions were determined, in the test described in Examples l to 4.
TABLE 11 TABLE W Go per disso ved Example Solution Alkyl oxypropyiene Copper dissolved Number Alkyl oxypropylene phosphoric acid ester 1 (mg./l.) Example phosphoric Control A None 99 acid ester Control B: Mono'c'e't'fibiiiib'iihfimiid 90 OH Control C None 46 5 Mono-cetyl 010E330 P Oxypropylene:
phosphoric acid 19 O OH 50 6 lg/lono-cetyl l 1 Mono cetyl oxypropylene phosphoric acid-.." 43 22333522"; 15
OH 7 lVlono-stearyl d|(oxypropylene)- C1tH3aO CH-CH2O}I phosphate 34 H3 0 OH 2 Mono cet ldi ox ro lene hos horlc acid- 38 y W W )p p The results in Table IV show that the alkyl oxypropylene OH hos hates of Exam les 5 to 7 are effective in inhibitin P P g CmHas[0CH-CH o P copper COII'OSlOll by nitrilotriacetic acid and peroxide H3 0 0H bleaching agents.
3 Mono stearyl oxypropylenephosphoric acid... 49 EXAMPLE 8 A detergent composition was prepared to the formulation shown in Table V. The composition was dissolved in water of Ha ii OH 5 dl-l to the solution concentration shown.
4 Monostearyl-di(oxypropylene)phosphoric acid. 57 TABLE V CHHCHIO CHCH2]zO-|1]\ 7O by Solution H3 0 OH Composition weight Concentration 1 The alkylether phosphoric acid esters Were prepared by reacting the alcohol (cetyl alcohol (hexadecyl alcohol) or stearyl alcohol (heptadccyl 9 alcohol with propylene oxide, and then reacting the alkyl oxypropylene 'f miniomace'lc alcohol with ortho phosphoric acid. The acid form was added to the acid 30.3% I g/l solution, but the sodium salt. thereof was possibly formed therein in situ. Pentasodium tripolyphosphate 15.2% 0.5 g/l Bleaching agent Sodium perborate Builders Sodium carbonate Sodium silicate Nonionic surfactant Condensation product of tallow fatty alcohol and 8 moles ethylene oxide 30.3% r g/l TABLE VI Alkyl oxypropylcnc Copper Example no. phosphoric ncid dissolved (mg/l) Control D None [03 it Mono-cetyl oxypropylcne phosphoric acid The results in Table VI show that the monocetyl oxypropylene phosphoric acid was effective in inhibiting copper corrosion.
To another 100 ml. sample of this solution was added 0.3 g./l. of mono-cetyl oxypropylene phosphoric acid. The tendency of this solution to corrode zinc metal was then determined, in comparison with a control that did not contain the phosphoric acid ester. The solution was refluxed for 30 minutes with 0.5 g. zinc powder, the undissolved powder was removed by filtration, and the zinc content of the solution was determined by means of an atom absorption photometer. The results are shown in Table VII.
TABLE VII Alkyl oxypropylene Zinc Example not phosphoric acid ester dissolved (mg/l) Control E None 215 8 Monc-cetyl oxypropylenephosphoric acid 80 The results show that the cetyl oxypropylene phosphoric acid is quite effective in inhibiting zinc corrosion.
EXAMPLE 9 A detergent formulation'was prepared, as shown in Table VIII. This composition was dissolved in water of 5 dH, to the solution concentration shown in the Table.
To a 100 ml. portion of this detergent solution was added 0.3 g./l. mono-cetyl oxypropylene phosphoric acid. Then in comparison with a control, the portion was boiled with an aluminum sheet 3 centimeters square for 30 minutes. The alummum content of the solution was then determined, by means of an atom absorption photometer. The results are shown in Table IX.
TABLE IX Alkyl oxypropylene Aluminum Example no.
phosphoric acid dissolved (mg/l) Control F None 375 9 Mono-cetyl oxypropylene phosphoric acid 74 The results in Table IX show that the cetyl oxypropylene phosphoric acid is effective in inhibiting corrosion of aluminum metal.
The detergent compositions prepared according to the invention, as seen from the above Examples, show a very substantial decrease in the corrosion of copper, zinc and aluminum. Copper, aluminum and zinc corrosion is inhibited even when hard water is used in the preparation of the detergent solution. It, furthermore, was proved by test washing that the compositions according to the invention provide very good washing results and that, in addition, the resulting detergents are low foaming, which is important where the detergents are used in automatic washing machines.
EXAMPLES 10 TO 13 prepared, containing the TABLE X Solution concen- Percent tration, Composition by weight g./l. Sequestrants:
Tetrasodium salt of ethylenediamine tetraaoetic acid 22. 9 1. 6 Pentasodium tripolyphosphate 11.5 0.8 Bleaching agent:
Sodium perborate 22. 9 1. 6 Builder:
Sodium carbonate 28. 5 2. 0 N onionic surfactant:
Condensation product of tallow fatty alcohol and 8 moles ethylene oxide 8.6 0.6 Corrosion Inhibitor:
Monoalkyl oxypropylene phosphoric acid ester.. 5. 6 0. 4
Mono cetyl oxy propyienephosphoric acid OH EXAMPLE 10 CnHa3-O CHCHzO-I1]\ H3 0 OH Mono cetyl di(oxypropylene) phosphoric acid EXAMPLE 11 CitHa3[OCHCH2-]2OII H3 0 OH Mono stearyl oxypropylenephosphoric acid OH EXAMPLE 12 C1aHa1--OCH-CH2-0fi\ H: O OH 'Mouo steary1-di(oxypropylene) phosphoric acid-.."
EXAMPLE 13 CraH37[O-CH-CH2]zO-:l]
H; O OH The results obtained were the same as for the corresponding alkyl oxypropylene phosphoric acid esters of Examples 1 to 4. The compositions tested were effective in inhibiting copper corrosion by the sodium ethylenediaminetetracetic acid and 5 the peroxide bleaching agent.
EXAMPLES 14 TO 17 Four detergent compositions were prepared, containing the l ingredients shown in Table XI.
These compositions were each dissolved in water of 15 of hardness (l/ Mg-hardness, 4/5 Ca-hardness) to the solution concentration indicated.
TABLE XI Solution Percelnt $015011- y 1'8. 011 Composition Weight gJll Sequestrants:
Tctrasodium ethylenediamine tetraacetlc acid 29. 6 1. 6 Pentasodium tripolyphosphate 14. 8 0. 8 Builder:
Sodium carbonate 37. 0 2. 0 Nonionic Surfactant: 2 5
Condensation product of tallow fatty alcohol and 8 moles ethylene oxide 11. 1 0. 6 Corrosion Inhibitor:
Monoalkyl oxypropylene phosphoric acid ester 7. 5 0. 4
Mono cctyl oxy propylenephosphoric acid 0H EXAMPLE 14 C1s aa-OCHOH2O-fi\ CH3 0 OH Mono cetyl di(oxypropyiene) phosphoric acid EXAMPLE 15 CroH4a[O(l3HCH:--]zOIlE|\ CH; 0 OH Mono stearyl oxypropylenephosphorlc acid EXAMPLE 16 1a a1O-CHGH -0fi\ H3 0 OH Mono stearyi-di(oxypropylene)phosphoric acid OH EXAMPLE 17 C15H37l0 CHCH2]2O:|EI\
The tendency of each solution to corrode copper metal in the presence of sodium perborate was determined by the following test.
To 100 ml. portions of this solution there was added 0.6 g./l. of sodium perborate. The resulting solutions were then tested as in Examples 1 to 4.
The results showed that the alkyl oxypropylene phosphoric acid esters were effective in inhibiting copper corrosion by the sodium ethylenediaminetetraacetic acid and the peroxide bleaching agent.
Having regard to the foregoing disclosure, the following is claimed as the inventive and patentable embodiments thereof:
1. A detergent composition for use in hard and soft water consisting essentially of an organic surfactant selected from the group consisting of anionic and nonionic organic surfactants, an aminocarboxylic acid or salt sequestrant in an amount to sequester calcium and magnesium ions in hard water and a mono-alkyl oxypropylene phosphoric acid ester of the formula OM R0(Ca e )no OM wherein R is an alkyl group having from 15 to 20 carbon atoms and M is selected from the group consisting of hydrogen, alkali metals, ammonium and strongly basic organic amine cations, and n is a number within the range from 1 to 4, in an amount to lessen the corrosive effect of the aminocarboxylic acid on copper, zinc and aluminum, in the presence of a bleaching or oxidizing agent.
2. A detergent composition according to claim 1, in which the weight ratio of surfactant to phosphoric acid ester is within the range from about 10:1 to about 1:10.
3. A detergent composition according to claim 1, in which the amount of surfactant is within the range from about 2 to about 30 percent by weight, the amount of the aminocarboxylic acid is within the range from about 2 to about 30 by weight, and the amount of phosphoric acid ester is within the range from about 1 to about 20 percent by weight.
4. A detergent composition according to claim 1, consisting essentially of a bleaching or oxidizing agent in an amount within the range from about 5 to about 40 percent by weight.
5. A detergent composition according to claim 4, in which the bleaching agent is a peroxide salt.
6. A detergent composition according to claim 5, in which the bleaching agent is selected from the group consisting of the perborates, persulphates, percarbonates, and perpyrophosphates of the alkali metals.
7. A detergent composition according to claim 1, in which the anionic surfactant is selected from the group consisting of alkylaryl sulphonates, alkyl sulphonates, a-olefin sulphonates, alkyl sulphonates, alkyl oxyalkylene sulphates, and alkylphenol oxyalkylene sulphates.
8. A detergent composition according to claim 1, in which the nonionic surfactant has the general formula where R is selected from the group consisting of hydrocarbon groups having from 15 to 18 carbon atoms and aralkyl groups having a hydrocarbon group having from eight to 18 carbon atoms attached at the aryl nucleus and linked to A through the aryl nucleus, R is selected from the group consisting of hydrogen and methyl, A is either oxygen or sulphur, or an amino, amido, carboxylic acid ester or thiocarboxylic acid ester group. and n is a number from 8 to 35.
9. A detergent composition according to claim 1, in which the nonionic surfactant has the general formula Y (C H O) .r a smt z rmn .H. where Y is OH or a nucleating organic residue containing active hydrogen atoms, and the total of x and y is from 2 to 20, m is from 1 to 25, p is from 1 to 5 and the mean molecular weight of the entire block polymer is from 1,000 to 4,000.
10. A detergent composition according to claim 1, in which the aminocarboxylic acid or salt sequestrant has the general formula:
MOOCCH: A
where A is CH COO1-l OR -CH CH Ol-l, M is hydrogen, or an alkali metal, ammonium or organic amine cation, and n is a number from 0 to 5.
11. A detergent composition according to claim 1, consisting essentially of one or more of builders, in an amount within the range from about 10 to about percent of the total weight of the detergent composition.
12. A detergent composition according to claim 1, in which the phosphoric acid ester is monocetyloxypropylenc orthophosphoric acid ester.
13. A detergent composition according to claim 1, in which the phosphoric acid ester is monocetyldi(oxypropylene) orthophosphoric acid ester.
14. A detergent composition according to claim 1, in which the phosphoric acid ester is monostearyloxypropylene orthophosphoric acid ester.
15. A detergent composition according to claim 1, in which 16. A detergent composition according to claim 1 in solid particulate form.
17. A detergent composition according to claim 1, in the form of a concentrated aqueous solution having a solids conthe phosphoric acid ester is monostearyl di(oxypropylene) 5 tent offi'om about to about 75 percent by weightorthophosphoric acid ester.
23 x13 UNRTED STATES PATENT OFFICE CERTHECATE 9F RRE CTN Patent No. .3, 655, 559 Dated April 11, 1972 Inv mfl Martin Hellsten et al.
It is certified that error appears in the above-identified patent and that said Lettere Patent: are hereby corrected as shown below:
Column 2, line3 I "520" should be 20] Column 2, line 39 "monoaklyloxypropylene" should be monoalkyloxypropylene Column 4, line 60 "mole" should be moles Column 4, line 61 "mole" should-be moles Column 5, line 41 l"Y [c H o) (c H o) (c' H o) H,,"
Column 6, line 41 '"hydroxethylethylenediamine" should be hydroxyethylethylenediamine Column 7, line 32 "TAble" should be Table OH OH Column 7, Table 11, I 4/ Formula lines 45 'O Should 16 s n E 0 0H" O\OH ms-12o 3,655, 569 Page Z Column 12, line 49 (C H (C H O) H should be x 3 6 m Z 4 Y]P Column 12, line 63 "OR" should be or Signed and sealed this 27th day of March 1973.
(SEAL) Attest:
EDWARD M.PLETCHER,JR.' ROBERT GOTTSCHALK Attesting Officer Commissioner of Patents UNITED STATES PATENT @FFICE CERTWICATE M fiQRREUEWN Patent: No. 3,655,569 Dated April 11, 1972 l v t r( MARTIN HELLSTEN, ET. AL.
It is certified that: error appears in the above-identified patent and that said Letters Patent are hereby corrected as shown below:
Column 12, lines 44 and 46, cancel the quotation mark Signed and glw this 20th day of November 1973.,
(SEAL) Attest:
EDWARD M.FLE'ICHER,JR. RENE D. TEGT'MEYER Attesting Officer Acting Commissioner of Patents FORM PO-1050 (IO-69) USCOMM-DC 60376-P69 fl' U.Sv GOVERNMENT PRINTING OFFICE I969 0--366-334,
Claims (16)
- 2. A detergent composition according to claim 1, in which the weight ratio of surfactant to phosphoric acid ester is within the range from about 10:1 to about 1:10.
- 3. A detergent composition according to claim 1, in which the amount of surfactant is within the range from about 2 to about 30 percent by weight, the amount of the aminocarboxylic acid is within the range from about 2 to about 30 by weight, and the amount of phosphoric acid ester is within the range from about 1 to about 20 percent by weight.
- 4. A detergent composition according to claim 1, consisting essentially of a bleaching or oxidizing agent in an amount within the range from about 5 to about 40 percent by weight.
- 5. A detergent composition according to claim 4, in which the bleaching agent is a peroxide salt.
- 6. A detergent composition according to claim 5, in which the bleaching agent is selected from the group consisting of the perborates, persulphates, percarbonates, and perpyrophosphates of the alkali metals.
- 7. A detergent composition according to claim 1, in which the anionic surfactant is selected from the group consisting of alkylaryl sulphonates, alkyl sulphonates, Alpha -olefin sulphonates, alkyl sulphonates, alkyl oxyalkylene sulphates, and alkylphenol oxyalkylene sulphates.
- 8. A detergent composition according to claim 1, in which the nonionic surfactant has the general formula where R is selected from the group consisting of hydrocarbon groups having from 15 to 18 carbon atoms and aralkyl groups having a hydrocarbon group having from eight to 18 carbon atoms attached at the aryl nucleus and linked to A through the aryl nucleus, R8 is selected from the group consisting of hydrogen and methyl, ''''A is either oxygen or sulphur, or an amino, amido, carboxylic acid ester or thiocarboxylic acid ester group''''. and n is a number from 8 to 35.
- 9. A detergent composition according to claim 1, in which the nonionic surfactant has the general formula Yn ( (C2H4O)x(C3H6O)m(C2H4O)y) pHn where Y is OH or a nucleaTing organic residue containing active hydrogen atoms, and the total of x and y is from 2 to 20, m is from 1 to 25, p is from 1 to 5 and the mean molecular weight of the entire block polymer is from 1,000 to 4,000.
- 10. A detergent composition according to claim 1, in which the aminocarboxylic acid or salt sequestrant has the general formula: where A is -CH2COOH OR -CH2CH2OH, M is hydrogen, or an alkali metal, ammonium or organic amine cation, and n is a number from 0 to 5.
- 11. A detergent composition according to claim 1, consisting essentially of one or more of builders, in an amount within the range from about 10 to about 80 percent of the total weight of the detergent composition.
- 12. A detergent composition according to claim 1, in which the phosphoric acid ester is monocetyloxypropylene orthophosphoric acid ester.
- 13. A detergent composition according to claim 1, in which the phosphoric acid ester is monocetyldi(oxypropylene) orthophosphoric acid ester.
- 14. A detergent composition according to claim 1, in which the phosphoric acid ester is monostearyloxypropylene orthophosphoric acid ester.
- 15. A detergent composition according to claim 1, in which the phosphoric acid ester is monostearyl di(oxypropylene) orthophosphoric acid ester.
- 16. A detergent composition according to claim 1 in solid particulate form.
- 17. A detergent composition according to claim 1, in the form of a concentrated aqueous solution having a solids content of from about 20 to about 75 percent by weight.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE10699/68A SE313629B (en) | 1968-08-08 | 1968-08-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3655569A true US3655569A (en) | 1972-04-11 |
Family
ID=20292718
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US848084A Expired - Lifetime US3655569A (en) | 1968-08-08 | 1969-08-06 | Detergent compositions containing a sequestrant and optionally a bleaching agent having a reduced tendency to attack copper, zinc and aluminum |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US3655569A (en) |
| CH (1) | CH512582A (en) |
| DE (1) | DE1938718B2 (en) |
| DK (2) | DK130747B (en) |
| FI (1) | FI51366C (en) |
| FR (1) | FR2015278B1 (en) |
| GB (1) | GB1267217A (en) |
| NL (1) | NL163822C (en) |
| NO (1) | NO130687C (en) |
| SE (1) | SE313629B (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3779931A (en) * | 1970-12-10 | 1973-12-18 | Henkel & Cie Gmbh | Compositions useful in the aqueous cold-bleaching of textiles including optical brighteners |
| US3850832A (en) * | 1971-12-17 | 1974-11-26 | Henkel & Cie Gmbh | Washing, rinsing and cleansing agent compositions containing furan-maleic anhydride copolymer sequestering agents |
| US3850831A (en) * | 1971-07-15 | 1974-11-26 | Mo Och Domsjoe Ab | Liquid detergent compositions containing surfactants and peroxide bleaching agents |
| US4430244A (en) | 1982-03-04 | 1984-02-07 | Colgate-Palmolive Company | Silicate-free bleaching and laundering composition |
| US4707292A (en) * | 1985-04-03 | 1987-11-17 | Kao Corporation | Detergent composition |
| US4909986A (en) * | 1985-07-23 | 1990-03-20 | Dainippon Ink | Aqueous deodorants and deodorizing methods |
| US5611992A (en) * | 1994-05-24 | 1997-03-18 | Champion Technologies Inc. | Corrosion inhibitor blends with phosphate esters |
| US5611991A (en) * | 1994-05-24 | 1997-03-18 | Champion Technologies, Inc. | Corrosion inhibitor containing phosphate groups |
| US5728660A (en) * | 1993-04-05 | 1998-03-17 | Eet, Inc. | Extraction fluids for removal of contaminants from surfaces |
| US5929012A (en) * | 1995-02-28 | 1999-07-27 | Procter & Gamble Company | Laundry pretreatment with peroxide bleaches containing chelators for iron, copper or manganese for reduced fabric damage |
| US6207226B1 (en) * | 1997-08-26 | 2001-03-27 | Kansai Paint Co., Ltd. | Metallic coating method |
| WO2009007122A1 (en) * | 2007-07-10 | 2009-01-15 | Atotech Deutschland Gmbh | Solution and process for increasing the solderability and corrosion resistance of metal or metal alloy surface |
| WO2012013490A1 (en) | 2010-07-27 | 2012-02-02 | Buck-Chemie Gmbh | Adhering acidic sanitary cleaner and fragrancer |
| US20210260566A1 (en) * | 2020-02-21 | 2021-08-26 | Tersus Environmental Llc | Enhanced Reduction Bioremediation Method Using In-situ Alcoholysis |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4115457A (en) * | 1976-07-07 | 1978-09-19 | Sandoz Ltd. | Polyglycol ether derivatives |
| DE3316724A1 (en) * | 1983-05-07 | 1984-11-08 | Henkel KGaA, 4000 Düsseldorf | AGENT AND METHOD FOR CLEANING AND PASSIVATING METALS BY SPRAYING |
| NZ226288A (en) * | 1987-09-30 | 1991-02-26 | Colgate Palmolive Co | Stable non-aqueous suspensions for fabrics |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2921908A (en) * | 1956-07-02 | 1960-01-19 | Procter & Gamble | Sequestering composition containing a corrosion inhibitor |
| US3004056A (en) * | 1959-11-12 | 1961-10-10 | Gen Aniline & Film Corp | Surface active compositions |
| US3033889A (en) * | 1958-10-21 | 1962-05-08 | Gen Aniline & Film Corp | Phosphate esters of branched chain alcohols |
| US3122508A (en) * | 1960-07-28 | 1964-02-25 | Gen Aniline & Film Corp | Heavy duty detergent compositions |
| US3522184A (en) * | 1966-05-02 | 1970-07-28 | Kao Corp | Granular bleaching agent composition and method for making thereof |
-
0
- DK DK130747D patent/DK130747A/da unknown
-
1968
- 1968-08-08 SE SE10699/68A patent/SE313629B/xx unknown
-
1969
- 1969-07-30 DE DE1938718A patent/DE1938718B2/en active Granted
- 1969-08-05 FR FR696926919A patent/FR2015278B1/fr not_active Expired
- 1969-08-06 NO NO3221/69A patent/NO130687C/no unknown
- 1969-08-06 US US848084A patent/US3655569A/en not_active Expired - Lifetime
- 1969-08-06 GB GB1267217D patent/GB1267217A/en not_active Expired
- 1969-08-07 CH CH1201869A patent/CH512582A/en not_active IP Right Cessation
- 1969-08-08 NL NL6912138.A patent/NL163822C/en not_active IP Right Cessation
- 1969-08-08 FI FI692333A patent/FI51366C/en active
- 1969-08-08 DK DK428069AA patent/DK130747B/en not_active IP Right Cessation
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2921908A (en) * | 1956-07-02 | 1960-01-19 | Procter & Gamble | Sequestering composition containing a corrosion inhibitor |
| US3033889A (en) * | 1958-10-21 | 1962-05-08 | Gen Aniline & Film Corp | Phosphate esters of branched chain alcohols |
| US3004056A (en) * | 1959-11-12 | 1961-10-10 | Gen Aniline & Film Corp | Surface active compositions |
| US3122508A (en) * | 1960-07-28 | 1964-02-25 | Gen Aniline & Film Corp | Heavy duty detergent compositions |
| US3522184A (en) * | 1966-05-02 | 1970-07-28 | Kao Corp | Granular bleaching agent composition and method for making thereof |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3779931A (en) * | 1970-12-10 | 1973-12-18 | Henkel & Cie Gmbh | Compositions useful in the aqueous cold-bleaching of textiles including optical brighteners |
| US3850831A (en) * | 1971-07-15 | 1974-11-26 | Mo Och Domsjoe Ab | Liquid detergent compositions containing surfactants and peroxide bleaching agents |
| US3850832A (en) * | 1971-12-17 | 1974-11-26 | Henkel & Cie Gmbh | Washing, rinsing and cleansing agent compositions containing furan-maleic anhydride copolymer sequestering agents |
| US4430244A (en) | 1982-03-04 | 1984-02-07 | Colgate-Palmolive Company | Silicate-free bleaching and laundering composition |
| US4707292A (en) * | 1985-04-03 | 1987-11-17 | Kao Corporation | Detergent composition |
| US4909986A (en) * | 1985-07-23 | 1990-03-20 | Dainippon Ink | Aqueous deodorants and deodorizing methods |
| US5728660A (en) * | 1993-04-05 | 1998-03-17 | Eet, Inc. | Extraction fluids for removal of contaminants from surfaces |
| US5611991A (en) * | 1994-05-24 | 1997-03-18 | Champion Technologies, Inc. | Corrosion inhibitor containing phosphate groups |
| US5611992A (en) * | 1994-05-24 | 1997-03-18 | Champion Technologies Inc. | Corrosion inhibitor blends with phosphate esters |
| US5929012A (en) * | 1995-02-28 | 1999-07-27 | Procter & Gamble Company | Laundry pretreatment with peroxide bleaches containing chelators for iron, copper or manganese for reduced fabric damage |
| US6207226B1 (en) * | 1997-08-26 | 2001-03-27 | Kansai Paint Co., Ltd. | Metallic coating method |
| WO2009007122A1 (en) * | 2007-07-10 | 2009-01-15 | Atotech Deutschland Gmbh | Solution and process for increasing the solderability and corrosion resistance of metal or metal alloy surface |
| US20100196727A1 (en) * | 2007-07-10 | 2010-08-05 | Atotech Deutschland Gmbh | Solution and process for increasing the solderability and corrosion resistance of metal or metal alloy surface |
| US8337606B2 (en) | 2007-07-10 | 2012-12-25 | Atotech Deutschland Gmbh | Solution and process for increasing the solderability and corrosion resistance of metal or metal alloy surface |
| WO2012013490A1 (en) | 2010-07-27 | 2012-02-02 | Buck-Chemie Gmbh | Adhering acidic sanitary cleaner and fragrancer |
| DE102010032417A1 (en) * | 2010-07-27 | 2012-02-02 | Buck- Chemie Gmbh | Acidic acid sanitary cleaning and fragrancing agent |
| US9102906B2 (en) | 2010-07-27 | 2015-08-11 | Buck-Chemie Gmbh | Adhering acidic sanitary cleaner and fragrancer |
| US20210260566A1 (en) * | 2020-02-21 | 2021-08-26 | Tersus Environmental Llc | Enhanced Reduction Bioremediation Method Using In-situ Alcoholysis |
| US11577231B2 (en) * | 2020-02-21 | 2023-02-14 | Tersus Environmental Llc | Enhanced reduction bioremediation method using in-situ alcoholysis |
Also Published As
| Publication number | Publication date |
|---|---|
| DK130747C (en) | 1975-09-08 |
| DK130747B (en) | 1975-04-07 |
| NL6912138A (en) | 1970-02-10 |
| NO130687C (en) | 1975-01-22 |
| DE1938718C3 (en) | 1980-04-03 |
| FR2015278A1 (en) | 1970-04-24 |
| CH512582A (en) | 1971-09-15 |
| NL163822C (en) | 1980-10-15 |
| DE1938718A1 (en) | 1970-02-19 |
| DE1938718B2 (en) | 1979-08-02 |
| NL163822B (en) | 1980-05-16 |
| NO130687B (en) | 1974-10-14 |
| DK130747A (en) | |
| GB1267217A (en) | 1972-03-15 |
| SE313629B (en) | 1969-08-18 |
| FI51366C (en) | 1976-12-10 |
| FR2015278B1 (en) | 1974-02-22 |
| FI51366B (en) | 1976-08-31 |
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