US3665922A

US3665922A - Sanitary napkin with improved wrap material

Info

Publication number: US3665922A
Application number: US878393A
Authority: US
Inventors: Robert F Skora
Original assignee: Kimberly Clark Corp
Current assignee: Kimberly Clark Corp
Priority date: 1969-11-20
Filing date: 1969-11-20
Publication date: 1972-05-30
Anticipated expiration: 1989-05-30

Abstract

A sanitary napkin having a conventional central pad of absorbent material, and an improved wrap material disposed around the central pad and comprising a high-loft, nonwoven fabric having a discontinuous backing layer of flexible adhesive. The fabric includes a multiplicity of hydrophobic fibers individually looped outwardly from the backing layer with the ends of each loop embedded in the backing layer.

Description

ilnited States Patent Skora [451 May 30,1972

[54] SANITARY NAPKIN WITH IMPROVED WRAP MATERIAL [72] Inventor: Robert F. Skora, Neenah, Wis.

[73] Assignee: Kimberly-Clark Corporation, Neenah,

I Wis. V

[22] Filed: Nov. 20, 1969 [21] Appl. No.: 878,393

[52] US. Cl. ..l28/290, 161/148 [51] Int. Cl. ..A6lf 13/16 [58] Field of Search... .....128/284, 287, 288, 290, 296;

[56] References Cited UNITED STATES PATENTS Johnson ..128/290 W Morin 128/284 Bletzineer et a1. 128/290 Primary ExaminerCharles F. Rosenbaum Attorney-Wolfe, Hubbard, Leydig, Voit & Osann, Ltd.

[57] ABSTRACT A sanitary napkin having a conventional central pad of absorbent material, and an improved wrap material disposed around the central pad and comprising a high-loft, nonwoven fabric having a discontinuous backing layer of flexible adhesive. The fabric includes a multiplicity of hydrophobic fibers individually looped outwardly from the backing layer with the ends of each loop embedded in the backing layer.

9 Claims, 13 Drawing Figures Patented May 30, 1972 3 Sheets-Sheet l Patented May 30, 1972 3,665,922

3 Sheets-Sheet 2 424m! amawym/ Fga Wra /11:

Patented May 30, 1972 3,665,922

3 Sheets-Sheet SANITARY NAPKIN WITH IMPROVED MATERIAL The present invention relates generally to sanitary napkins and, more particularly, to a sanitary napkin having an improved wrap material.

It is a primary object of the present invention to provide a sanitary napkin having improved ability to absorb and retain menstrual exudate.

It is another object of the invention to provide an improved sanitary napkin of the type described above which provides extremely rapid absorption of menstrual exudate.

A further object of the invention is to provide an improved sanitary napkin of the foregoing type which is soft and comfortable to the user.

Yet another object of the invention is to provide such an improved sanitary napkin which minimizes retention of menstrual exudate in the wrap material.

Other objects and advantages of the invention will be apparent from the following detailed description taken in connection with the accompanying drawings, in which:

FIG. 1 is a perspective view of a sanitary napkin embodying the invention, with fragments thereof broken away to reveal the internal structure; I

FIG. 2 is a section taken along line 2--2 in FIG. 1;

FIG. 3 is an enlarged fragmentary perspective view of one of the internal elements in the napkin of FIGS. 1 and 2;

FIG. 4 is a schematic side elevation of one form of apparatus which may be used to produce the improved wrap material included in the napkin of FIGS. 1 and 2;

FIG. 5 is a fragmentary plan view somewhat simplified and exaggerated for the sake of clarity of illustration, of an illustrative web of base material prepared by the apparatus of FIG. 4 with portions of the material broken away to expose the various layers;

FIG. 6 is a fragmentary plan view of the wrap material employed in the napkin of FIGS. 1 and 2, with portions broken away to expose the various layers;

FIG. 7 is an enlarged, simplified and somewhat exaggerated section taken along section line 7-7 in FIG. 6;

FIG. 8 is an enlarged, simplified and somewhat exaggerated section taken along line 8-8 in FIG. 6;

FIG. 9 is an enlarged schematic detail in side elevation of the forming drum and gathering blade of the apparatus shown in FIG. 4;

FIG. 10 is a further enlarged schematic side elevation illus trating in somewhat idealized fashion the sequence of gathering and looping of individual fibers;

FIG. 11 is an enlarged schematic fragmentary view taken along the lines 11-11 of FIG. 10 showing a fragment of the fiber web and adhesive pattern with illustrative fibers attached to the adhesive;

FIG. 12 is a simplified schematic view taken along the lines 12-12 of still another sequence as shown in FIG. 10', and

FIG. 13 is an enlarged schematic bottom view showing the sequence of the partial consolidation or closing of the open adhesive pattern to form a discontinuous adhesive backing.

While the invention will be described in connection with certain preferred embodiments, it will be understood that it is not intended to limit the invention to these particular embodiments. On the contrary, it is intended to cover all alternative, modifications, and equivalent arrangements as may be included within the spirit and scope of the invention.

In sanitary napkin construction, it is desirable to have an absorbent structure which (1) immediately accepts body exudate, (2) rapidly transports the exudate away from the discharge source, and (3) efiectively contains the exudate within the confines of the napkin, all while the top surface of the napkin is maintained relatively dry. In addition, the absorbed exudate should not be allowed to spread to the sides of the napkin, run over the top edges of the napkin, or soak through the bottom of the napkin, especially if the absorptive capacity of the napkin has not been reached.

Turning now to the drawings, and referring first to FIGS. 1 and 2, there is shown a sanitary napkin 10 having a main absorbent core 11 of fluid absorbent material, a fluid control element l2, and a fluid pervious wrapper 13 enclosing the absorbent elements and overlapped in a known manner, and providing end tabs for fastening purposes. The absorbent core 11 may be of varying construction, including top and bottom layers comprising multiple plies of cellulose wadding 14 and a central pad of wood fluff 15. Alternatively, the core 11 may be all fluff. Other known absorbent materials such as batts of cotton and/or various types of synthetic fibers may also be used for the main body portion. The main body portion, in itself being of conventional construction, acts only as a cooperating part of the present invention, the important requisite being that the core be lower in density and consequently have larger interstices than the central element 12.

Other parts of the illustrative pad construction are also known, such as the fluid impervious baffle 16 of plastic film or the like which is often employed to inhibit strike through, and sidestrips 17, such as waxed tissue, or water-resistant film,

' may be employed to inhibit inadvertent side staining caused by migration of exudate to side edges of the pad. If desired, a second control element 18 may be provided on the opposite side of the pad from the control element 12 mentioned previously.

The particular control element 12 employed in the illustrative embodiment shown most clearly in FIG. 3, is described in more detail in US. Pat. No. 3,375,827, assigned to the assignee of the present invention. The control element 25 preferably has an embossed pattern defining various degrees of compression, so that it has a significantly higher average of density and smaller pores than the

interior core elements

14 and 15 which make up the main absorbent pad 1 1.

In accordance with the present invention, the sanitary napkin is provided with an improved wrap material comprising a high-loft, nonwoven fabric, having a discontinuous backing layer of flexible adhesive disposed adjacent the central pad, and a multiplicity of fibers individually looped outwardly from said backing layer with the ends of each loop embedded in the backing layer. Thus, in the illustrative embodiment, the wrapper material 13 is a high-loft, nonwoven material preferably prepared by the method and apparatus illustrated in FIG. 4. This apparatus includes a web forming section 20 and an adhesive compacting and fiber looping section 30. The web forming section 20 is generally similar to the apparatus disclosed in copending applications Ser. No. 498,929 and Ser. No. 553,483.

Multiple slivers 21 of heat-settable textile fibers are drawn from their respective supply cans (not shown) into a draw frame 22 which comprises a series of pairs of grooved rolls 23, the rolls of each pair being driven by appropriate gearing well known in the art, at a peripheral rate of speed slightly faster than the rate of operation of the preceding pair. As the juxtaposed slivers pass through draw frame 22, the individual fibers are drafted and spread out to form a flat striated web of substantially alined fibers as shown at 24. Web 24 is maintained on a supporting conveyor sheet 25 on the surface of which a patterned adhesive has been previously applied.

In the illustrative arrangement the conveyor sheet 15 comprises an endless conveyor belt treated on at least its upper surface with a release agent, e.g., a woven glass fiber with a surface coating of tetrafluoroethylene resin. Other release coatings are well known, and comprise such materials as silicone, fatty acid metal complexes, certain acrylic polymers, and the like. Heat resistant films or thin metal sheets treated with release agents may also be used as the carrier sheet.

Prior to the time the web 24 is picked up by the belt 25, the latter has imprinted on its release-treated surface a pattern of flexible thermoplastic adhesive such as is shown at 26 in FIG. 5. It is understood that the adhesive is actually on the underside of belt 25 which becomes the upper surface after passing around roll 27 whereby the adhesive pattern 26 directly contacts the fiber web 24. The pattern is shown as being visible in FIG. 5 only for illustrative purposes.

The belt 25 is fed around roll 27 at a speed slightly in excess of the delivery speed of the final pair of rolls 23 in order to maintain web 24 under slight tension whereby the individual highly-drafted fibers are retained in their alined and tensioned condition. Drive rolls 28, 29 are rotated to drive belt 25 at a speed sufficient to maintain the proper tension on the web 24.

In the method shown for applying adhesive, the belt 25 is fed through a nip formed between a printing roll 30 and a backup roll 31 maintained in very light pressure engagement therewith. The surface of printing roll 30 is provided with an intaglio pattern which picks up adhesive 32 from dip pan 33. Part of the adhesive thus picked up is removed by a doctor blade 34 leaving only the intaglio patterned surface filled. The printing roll 30 then transfers this metered amount of adhesive in a preselected pattern to the underside of release coated belt 25. The pattern shown in FIG. is in the form of an open diamond pattern of adhesive.

Since the surface of belt 25 is treated with a release coating, the adhesive remains substantially on the surface with no penetration therein and is preferably in a somewhat tacky condition. The printed belt is drawn from the printing nip around roll 27 positioned closely adjacent the output end of draw frame 22, and, as stated above, at a speed slightly in excess of the delivery speed of the last two rolls in the draw frame. The web 24 emerging from the draw frame 22 is deposited on the tacky adhesive on belt 25 and held in tensioned engagement therewith by the adhesive and the above-mentioned speed differential. This continuous tension prevents the fibers in the web from losing their highly drafted and alined condition.

If desired, additional alined and highly drafted fibers may be added to the web 24 on the adhesively printed belt 25. For this purpose a second draw frame 35 similar to the draw frame 22 is provided to draw additional slivers 36 of fibers from their supply cans (not shown) and, after drafting and alining them, deposit the fibers on the moving web 24 carried by the belt 25. In such cases, the amount of adhesive printed on the belt 25 is increased so that some penetrations of the adhesive pattern reach the fibers from the second draw frame 35, and together with the speed differential of the belt 25 relative to the last pair of rolls in the draw frame 35, maintains these fibers under slight tension whereby they also maintain their highly drafted and alined condition.

An example of the web 24 formed by the apparatus is shown in FIG. 5. As previously mentioned, a series of parallel and diagonally disposed lines of adhesive are printed in crisscross fashion on the belt to form pattern 26 of adhesive having substantial open spaces in the configuration of diamonds. It should be appreciated, of course, that FIG. 5 is only intended to be illustrativ and, while the lines representing the fibers for both components 24a and 24b are spaced apart for clarity, in practice the highly drafted fibers of both components are very close to one another. Following deposit of web components 240 and 2412 on the adhesive printed belt 25, the belt is drawn around a heated drum 39 where fusing and curing of the adhesive is substantially completed while the web 24 is maintained in firm contact therewith to bond the individual fibers. To insure effective heating and fusing of the adhesive, it is desirable that travel of the combined belt and web be around a substantial portion of the drum 39. In the illustrated embodiment, a fly roll 39 a is disposed to provide wrap for the combined belt and web as they travel around the drum 39 to insure complete embedment of the fibers in the adhesive. The fibers of the web 24 are thus bonded together while retaining their highly drafted and substantially alined condition in the particular pattern in which they were deposited on the open pattern of adhesive 26 printed on the belt 25.

After leaving the fly roll 39a, the combined web 24 and belt 25 are preferably passed over the drive roll 29 which also serves as a cooling drum, to set the adhesive. The bonded web 24 is stripped from the release coated surface of the belt 25 by the guide roll 41 as the web leaves the cooling roll 29.

In general, any of the various known adhesives may be employed. It should, however, be appreciated that the particular adhesive used is dependent upon the characteristics of the flexible heat-settable fibrous web that is being employed, i.e. the adhesive should be reactivatable and softened in the heat-setting range of the particular fibrous material being used. In addition, the adhesives should also: be applicable to the base web 24 by procedures which will not disarrange the fibrous structure of the web; be reactivatable in the subsequent adhesive gathering and partial consolidation stage of the process; and form a flexible discontinuous backing layer for the finished fabric and should strongly bond the fiber loops in place.

While various well-known adhesives may be employed in the foregoing process, advantages reside in the use of plastisols, which are colloidal dispersions of synthetic resins in a suitable organic ester plasticizer, and which under the influence of heat provide good binding power while remaining soft and flexible. While many adhesives of this type are known, those found particularly useful for incorporation in the product of this invention include vinyl chloride polymers, and copolymers of vinyl chloride with other vinyl resins, plasticized by organic phthalates, sebacates, or adipates. These provide a fast curing plastisol adhesive characterized by relatively low viscosity, low migration tendencies, and minimium volatility. Such adhesives remain soft and flexible after curing, and can be reactivated by subsequent heating.

It has been found that other adhesive systems may be employed in the process, such as organisols, utilizing resins such as the vinyl chloride polymers, and copolymers. Furthermore, other adhesives may be employed provided that they satisfy specified characteristics in the base web produced in the web forming stage, and in the finished fabric produced in the adhesive compacting and fiber looping stage. For example, emulsions of thermoplastic resins such as acrylics and rubber-like compounds, illustratively ABS, have the requisite properties to serve as the bonding adhesive for the web 24.

The base material made as heretofore described and comprising a web of highly-drafted, heat-settable, fibers embedded in an open adhesive pattern, is then fed into the adhesive consolidating and fiber looping section 40 of the system shown in FIG. 4. The web 24 while still under tension is fed around an idler roll 42 and onto the surface of a heated forming drum 47. The forming drum is maintained at a temperature which will soften the adhesive to a tacky state so that it adheres to the drum surface while also heating the fibers sufficiently to bring them into their heat-setting range. In its preferred embodiment the drum 47 is made of metal with a highly polished chromium plated surface which is internally heated. Also, the web 24 is desirably arranged to travel a substantial distance around the drum 47 (i.e. have a relatively high degree of wrap) with the open pattern of adhesive 26 in contact with the heated drum surface to provide adequate residence time.

As the web 24 is fed onto the drum 47 the heat from the drum surface heats the fibers to their heat-setting temperature range and reactivates and softens the adhesive printed on the underside of the web, causing it to become tacky and to adhere slightly to the drum surface thereby maintaining the web under constant tension. The drum temperature should be maintained below the melting point of the adhesive to prevent dispersion of the adhesive into the fibers of the web and to minimize bonding of the adhesive lines as will hereinafter be described in greater detail. The web of fibers and softened adhesive is reformed by the cooperative action of the drum 47 and a gathering blade 48 having a flat edge 49. The blade edge 49 operates to consolidate the open adhesive pattern 26 into a backing layer of adhesive while simultaneously looping the fibers of the web outwardly from the open spaces in the original adhesive pattern. The reformed and consolidated material 50 then leaves the blade edge 49 and onto a flat takeoff surface 51 and a discharge conveyor 52.

The speed at which the material leaves the gathering blade is closely coordinated with the surface speed of the drum to heat set the fibers in their looped positions while rendering the adhesive non-tacky so the consolidation of the adhesive will only be partial and the bonding of transverse lines of adhesive minimized. To this end and as shown in FIG. 4, this may be accomplished by maintaining the take-off surface 51 at the ambient temperature or slightly higher by directing an air spray 53 at the bottom surface of take-off member 51. While this provides adequate cooling to carry out the objectives of the conditioning step, other means such as a water spray or a refrigerated fluid could be employed to provide a lower temperature if desired. Indeed, as long as the fluid is inert as regards the fibers and adhesives, application may be directly on the partially consolidated and reformed web. The take-away speed should then be set so that, at the temperature of the take-away surface, the fibers will be heat set and yet the bonding of merging lines of adhesive will be minimized. In this connection, it should be noted that the the adhesive should be maintained below its melting point to minimize the flowing together of the merging adhesive lines which would provide undesired bonds.

Turning now to FIGS. through 13, the method of making the elastic, high-loft, nonwoven fabric 50 will be explained in greater detail in connection with an illustrative sequence of the gathering and looping of single fibers of the web 24 (FIGS. 10 through 12) and the partial consolidation of the illustrative diamond adhesive pattern 26 (FIG. 13). As seen in FIG. 11, the fiber has a portion P which extends across the open space of the diamond pattern of adhesive 26 from point A to B where it is embedded in the adhesive. Referring to FIG. 10, the series of views in this Figure illustrates how the portion P of the fiber is formed into a loop; when point A being carried around the heated drum 47 impinges against the gathering blade edge 49, its forward motion is halted and it is scraped along the surface of the drum. Point B continues to advance with the drum surface since due to its softened and tacky condition it adheres to the the smooth drum surface.

As point B advances relative to point A, the portion P of the fiber between points A and B is caused to bow outwardly from the drum surface. Finally, point B overtakes point A and these points of adhesive are brought close together without being consolidated as seen in FIG. 12. In the meantime, fiber portion P has been looped outwardly from the drum surface. While this is occurring, of course, additional adhesive points C-D, etc., travelling around the drum 47 impinge against the gathering blade edge 49 causing a consolidation of these adhesive points and looping of their intermediate fiber portions P as is also indicated in FIG. 12. This occurs simultaneously at all points across the web at the blade edge producing a backing layer of adhesive from which extends the multiplicity of loops formed by the fibers of the base web. The layer of adhesive is carried away from the blade edge along the take-off surface 51 and provides a backing layer for the outwardly looped fibers, thus producing the fabric 50.

Also, not only does each fiber portion P loop outwardly from the drum surface but as the loop is formed it may twist or turn. The degree of loop twisting, and indeed, whether any twisting occurs, is dependent upon such factors as the degree of adhesive consolidation, fiber stiffness, blade angle (as hereinafter defined) and relative uniformity of loop size. In a particular situation, the formed loops may turn through an angle of up to 180.

FIG. 13 illustrates the partial consolidation that is desired when the open adhesive pattern is the exemplary diamond pattern. Thus, considering a single diamond S, each of the four comers T represents the crossing point of two intersecting lines of adhesive U and V. At every corner T then, as the adhesive is scraped along the surface of the drum, the crossing adhesive lines U and V are brought closer and closer together. The points closest to the corners T merge first because of the shorter distance of separation. Accordingly, point P on line U will merge with point P on line V before point P will meet point P Similarly, on the other side of the comer, the closer set of points (e.g. P and P,,) will merge before points P and P To provide the desired wrap material for use in the present invention, the take-away speed is maintained at a rate such that the adhesive diamonds are not completely consolidated but are collapsed into fiat hexagonal shapes in which the crossing points of adhesive have been transformed by partial consolidation of the adhesive into lines that form the sides of the highly elongated hexagons, as shown in FIG. 13. The closed, compact form of the nonwoven fabric may be stretched apart to break the bonds of minimal strength (i.e. the bonds that will break before adhesive rupture or other degradation of the product). The fabric is then allowed to relax to come to an equilibrium state in its drawn or open position.

The drawing may be accomplished by hand and can be achieved by pulling the fabric apart (i.e. along the machine direction). As shown in FIG. 4, the fabric exit end of the conveyor 52 may be provided with a roll 54 to fon'n a nip and a pair of rolls 55, also forming a nip. Drawing is accomplished by driving the rollers 55 at a higher speed.

With respect to the loops, it should be appreciated that the heights of the fiber loops throughout the fabric vary according to the spacing between the points of attachment of each fiber to the open adhesive pattern in the base web. Referring to FIGS. 8, l1, and 12, it will be seen, for example, that the loop formed by the fiber portion P, between the points of adhesive attachment CD will have a lower height than the loop formed by the longer fiber portion P between the points A,B. This results in a dense fabric with the lower loops supporting and filling around the higher loops and the top surface of the fabric being formed by the tops of the higher loops.

In accordance with an important aspect of this invention, the base web used to form the high-loft wrap material comprises fine denier, heat-settable, hydrophobic fibers. The fine denier of the fibers provides desired softness to the fabric, the heat settable characteristic improves the loft or bulk stability of the fabric, and the hydrophobic nature of the fibers provides a wrap material which is substantially non-wetting, while at the same time readily passing menstrual fluids therethrough. The denier of the fibers is preferably in the range of from about 1.5 to about 3.0 denier. Suitable hydrophobic properties are provided by fibers of polyester, polypropylene, or acrylic. By heat-settable it is meant that the material will maintain the looped configuration into which it has been formed in accordance with the present invention, regardless of whether the stability of the loop may be attributed to what is technically considered heat setting or whether the setting is the result of some other phenomena. Representative examples of suitable materials include any of the commercially available acrylic fibers such as, for example, Creslon" (American Cyanamide, Stamford Conn.) and Orlon (E.l. du Pont de Nemours and Company, Wilmington, Del.) and olefins such as polypropylene. If desired, a blend of fibers may be used in which only a portion of the fibers are heat settable. This will not, of course, provide the optimum elastic properties. Moreover, not only highly drafted webs and carded webs of staple length fibers may be used for the base but also garneted and air laid webs of such fibers as well as directly laid alined webs of monofilament. It has been noted, however, that when webs such as carded webs are used for the base web in which an important proportion of the fibers are randomly oriented, those fibers not alined with the machine direction appear to interfere with the loop production by the gathering blade and the ultimate stretch characteristics. The most regular formation of loops and optimum elastic and stretch in the formed fabric has been produced with those base webs having the highest proportion of fibers alined with the machine direction as, for example, the highly drafted webs made with the apparatus illustrated in FIG. 4.

The present invention may be more completely understood from the following examples, which are illustrative of the invention but are not intended as limiting the scope of the invention. The method and apparatus of FIG. 4 was employed for forming the wrap material for the products described in the ensuing examples. The adhesive used as a plastisol formulation including, by weight: Geon 135" polyvinyl chloride resin (manufactured by B.F. Goodrich, Akron, Oh. about 60 parts per 100 parts resin of GP-261" dioctyl phthalate plasticizer (B.F. Goodrich), about 2.5 parts per 100 parts resin of CAB- O-SlL" pyrogenic silica (Cabot Corporation, Boston, Massachusetts) and a sufficient amount of mineral spirits to bring the viscosity into the desired range (generally from about 3 to 5 percent by weight, based on the total weight of the other components for a viscosity range of 3,500 4,000 cps). The viscosities were measured with a Brookfield viscometer using a No. 4 spindle and operating at rpm. The polyester used in the Examples was Fortrel Type 400 stable fibers, com mercially available from Celanese Fibers Marketing Company, Charlotte, NC. The approximate tenacity of these fibers is 4.8 g.p.d. with elongation at break falling in the 45-55 percent range. Other physical properties include: loop tenacity (g.p.d.) 4.4, initial modulus (g.p.d.) -40-45, yield stress (g.p.d.) 1.0, yield strain 3.7 percent, specific gravity 1.38 and melting point 500 F.

EXAMPLE 1 The base web was made from polyester fiber having a denier of about 2.25 and an average fiber length of ZB-inches. The polyvinyl chloride plastisol, having a viscosity of from 3,700 to 4,000 centipoises, was applied in diagonal lines one fourth inches apart in both directions to form a diamond pattern. Rotogravure printing was employed and the intaglio roll had adhesive cells or lines 0.006 inches deep and 0.028 inches wide. The weight of the base web was about 12.8 grams/sq. yd., with equal weights of fiber and adhesive being included.

The preheat drum 39 in the first stage of forming the web was maintained at about 300 F. and operated at a surface speed of 65 ft./min. The base web 24 was thus carried to the heating drum 37 at a surface speed of 65 ft../min.

The gathering blade 48 was positioned at an angle of of 54 and maintained against the drum with a pressure of 27 p.s.i. The drum (9 inches in diameter) was internally heated and maintained at a temperature of about 260 F.

The take away speed was 8 ft./min. to provide a take away ratio (i.e. surface speed around drum/take away speed) of 8.125. The resultant product weighed about 104 g/yd. This material then opened between two nips, the first traveling one sixth the speed of the second, and then allowed to relax. This final product, which weighed 32 g/ydF, was used as a pad wrap.

EXAMPLE ll Example 1 was repeated, except that the blade angle was varied between 17 and 74 (17, 34, 37, 45, 54, and 74 being specifically used), and the weight of the base web was about 13 grams/sq.yd., with equal weights of fiber and adhesive being included.

Elastic nonwoven material capable of being stretched up to about twice its opened machine direction length with a recoverability of from 80 percent to 100 percent was obtained when the blade angle was between about 20 and 54 (i.e. optimum stretch was not obtained with angles of 17 and 74).

EXAMPLE Ill The base web was made from polyester fiber having a denier of 2.25 and an average fiber length of 3 inches. The polyvinyl chloride plastisol having a viscosity of about 3,800 centipoise was applied in diagonal lines one quarter inches apart in both directions to form a diamond pattern. The intaglio roll used was the same as in Example I. The base web, which weighed 12.5 grams/yd. was cured on the preheat drum 39 at 290 F. at a surface speed of 5 8 fpm. It was then carried to the heating drum 37. The gathering blade 48 was positioned at an angle of 74 and maintained with a pressure of 27 p.s.i. The drum 37 was heated to a temperature of 270 F. The take away was run at 40 ft..min. (i.e., 1.45 to 1 ratio). The resultant product weighed 18.1 g/yd.

As has been thus seen from the preceding Examples, elastic, high-loft nonwoven wraps can be made in accordance with the present invention by carefully controlling certain process parameters. Initially, the edge angle must be kept within certain critical ranges, depending upon the other parameters involved such as, for example, type of adhesive pattern and fiber stifiness. Thus, while angles of from about 20 to about 120 could be employed, the critical range narrows when fiber stiffness, type of adhesive and the adhesive pattern are known. For example, with 2.25 denier polyester, a polyvinyl chloride plastisol and a diamond pattern, a range of from about 20 to 54 should be employed.

The take away speed of the fabric from the blade edge is also important. With the blade 48 having an edge angle within the preferred range, and assuming the take away surface is cooled to substantially an ambient temperature, e.g. 75 F. to F., the normal ratio of the surface speed of the heating drum 37 to the take away speed should be maintained in the range of from about 5:1 to about 10: l with a ratio of 7 to 8:1 being preferred. By increasing the ratio above 10: 1, by slowing down the fabric take away speed, more adhesive consolidation has been obtained and the mass of the fiber loops is made somewhat more dense, so that a fabric with a higher weight has been produced; but the adhesive lines become more strongly bonded together so subsequent drawing cannot open the adhesive. By increasing the fabric take away speed, such that the fabric is not allowed to gather at the blade edge, the fabric will be drawn or extended while the adhesive layer is still in a plastic condition, thereby opening the adhesive layer, but not allowing sufficient residence time for the fibers to become as well heat set. Such webs while not as elastic still retain the properties of rapid passage of exudate and no strikeback. (See Example III).

Further parameters that affect adhesive consolidation fiber looping at the blade edge and the stretchability and elasticity characteristics of the elastic nonwoven fabric are the adhesive pattern applied to the fibers in the formation of the base web, the adhesive weight as a percentage of the weight of the web, and the area of the web covered by the adhesive pattern. The adhesive was applied in the preparation of Examples 1 AND 11 in the form of diagonal lines, criss-crossed, to provide an open diamond pattern with the size of the opening in the diamond in the machine direction less than the lengths of the fibers used for the base webs. Thus, where Fortrel" T-400 polyester was used, with fiber lengths of from 2% to 3 inches, a V4 inch diamond pattern applying adhesive to 20 percent to 25 percent of the total web surface was found effective. The transverse adhesive lines, when consolidated by the action of the gathering blade, are moved into proximity or abutment with each other but are only minimally bonded together. Thus, when the closed form of the elastic nonwoven is opened, the original pattern will reappear but will be foreshortened (i.e. the machine direction distance of the pattern will be less).

In the application of the adhesive to the base web, it has been observed that by increasing the adhesive viscosity a sharp, distinct printed pattern will be obtained such that the fibers are securely attached to the adhesive at distinct spaced points and are not embedded in adhesive throughout their length. It is desired to have spaced points of fiber adhesive attachment so that fiber loops will be distinctly and separately formed at the gathering blade so as to extend outwardly from the bonding adhesive layer. Fiber sizes over the entire prepared range of 1.5 to 3.0 denier have been successfully utilized in the base web with a Mr inch diamond pattern of adhesive. With the light weight webs of polyester used in the Examples, the ratio of fiber to adhesive was approximately 1: 1. It has been found that the degree of adhesive-fiber attachment in the base web is affected when the fiber to adhesive ratio with such type fibers is increased above about 2521, so that the fiber loops do not form properly at the blade nor do the fibers have sufficient attachment to the adhesive layer in the finished fabric. On the other hand, increasing the relative amount of adhesive in the base web tends to produce a thicker adhesive layer in the finished material and more secure fiber attachment, but the adhesive lines tend to disperse so that the pattern becomes less open affecting the height of the loops, which is undesirable. The fiber-adhesive ratio will be different, however, for base webs of yarns and threads where it appears that less amounts of adhesive, relatively speaking, will provide adequate attachment of the loops to the adhesive backing layer. For the purposes of the present invention, the aforementioned parameters are all preferably selected to provide a final gathered web of about to about 40 grams/yd.

It is also recognized that to produce a material in accordance with the invention, the elements should be sufficiently flexible to allow the loops to form under the action of the adhesive consolidating and gathering blade. Thus, neither stiff strands which do not loop-under the action of the gathering blade, nor multiple strand yarns in which the lay of the strands opposes the tendency of the loops being formed to assume their equilibrium position under the action of the blade,

will satisfactorily serve as elements of the base web when it is.

desired to produce a fabric fully in accordance with the invention.

As shown in FIG. 4, the fabric is carried along the take-away surface 51 by the action of the conveyor 62. Since the adhesive backing is hot and tacky as the fabric flows onto the takeaway surface 51 which is maintained substantially at ambient temperatures, that surface may be treated with a nonstick or release coating to insure that the fabric may be drawn smoothly along the surface.

To cool the belt of the conveyor 52 and prevent it from becoming overheated from the hot adhesive back of the fabric 50, streams of air may be blown against the underside of the belt from suitably placed air nozzles 60. This will also serve to cool the fabric 50, although it may be necessary or desirable to pass the fabric through a cooling station or zone to cool the adhesive and thermoplastic fibers clearly below their softening temperatures or to eliminate tackiness of the adhesive.

The improved wrap material provided by this invention provides rapid passage of the relatively viscous menstrual exudate into the absorbent core material, and yet the exudate does not strike back through the wrap material. In fact, the wrap material is essentially non-wettable by exudate. It is believed that these results are due to the unique combination of characteristics of the wrap material, particularly its bulk or loft and its hydrophobic nature. To demonstrate the significantly improved results obtained with sanitary napkins embodying this invention, a number of napkins of the type illustrated in FIGS. l-3, made with a high-loft wrap material of the type described in Example III, were subjected to comparative tests with conventional commercial Kotex and Modess napkins. In these tests, three different samples of each of the three napkin types were tested by placing on each napkin 3 ml. of liquid having a viscosity of 25 cps. at a shear of 23 sec. -1 on a Brookfield viscometer, and then measuring the time (in seconds) required for all the fluid to penetrate the wrap material of each pad. These tests were repeated using different test liquids having the same viscosity as the liquid described above, this time using only one sample of each of the three napkin types for each liquid sample. The data recorded in the foregoing tests was as follows:

a 6.9 sec. 7.9 sec. 4.2 sec. Pad No. 3 7.1 sec. 6.6 sec. 4.5 sec.

7.1 sec. 6.8 sec. 4.3 sec. Average 16.1 sec. 13.45 sec. 10.65 sec. Liquid No. 2

Average 16.1 sec. 13.45 sec. 10.65 sec. Liquid No. 3

Average 6.43 sec. 6.55 sec. 4.75 sec.

As can be seen from the foregoing data, the napkins of the present invention consistently provided the more rapid absorption characteristics. Furthermore, it was observed that there was substantially no wetting of the wrap material in the napkins of the invention.

1 claim as my invention:

1. A sanitary napkin comprising the combination of a central pad of absorbent material and an elastic wrap disposed around said central pad of absorbent material and comprising an elastic high-loft, nonwoven fabric having a discontinuous backing layer of flexible adhesive disposed adjacent said central pad and a multiplicity of heat settable hydrophobic fibers individually looped outwardly from said backing layer and heat set in the looped form with the ends of each loop embedded in said backing layer, said wrap being elastic to provide conformability enabling more unifonn contact with said central pad.

2. A sanitary napkin as set forth in claim 1 wherein the fiber-to-adhesive ratio in said high-loft wrap material is from about 1:1 to about 2.5:1.

3. A sanitary napkin as set forth in claim 1 wherein said high-loft wrap material weighs from about 15 to about 40 grams/yd.

4. A sanitary napkin as set forth in claim 1 wherein the fibers in said high-loft wrap material have a denier of from about 1.5 to about 3.0.

5. An improved sanitary napkin as set forth in claim I wherein said backing layer of said napkin fabric comprises a series of interconnected hexagons of adhesive.

6. An improved sanitary napkin as set forth in claim 5 wherein the spacing of said points varies regularly for said fibers throughout the fabric so that said loops vary in height regularly throughout the fabric.

7. An improved sanitary napkin as set forth in claim 1 wherein said fiber loops in said napkin fabric lie in planes extending in the cross direction of the fabric.

8. An improved sanitary napkin as set forth in claim 1 wherein said napkin fabric comprises a discontinuous, flexible backing of adhesive and a multiplicity of heat-set fibers each embedded at spaced longitudinal points in said backing layer and with the fiber portions between said points being looped outwardly from said backing layer.

9. In a sanitary napkin having a central pad of absorbent material, an improved elastic wrap disposed around said central pad and extending outwardly beyond the opposite ends thereof for providing fastening tabs, said wrap comprising an elastic high-loft, nonwoven fabric having a discontinuous backing layer of flexible adhesive disposed adjacent said central pad and a multiplicity of heat settable hydrophobic fibers individually looped outward1y from said backing layer and heat set in the looped form with the ends of each loop embedded in said backing layer, said loops extending over the open spaces in said discontinuous backing layer, said open spaces facilitating the passing of fluids through said wrap to said central pad of absorbent material, said elastic wrap enabling more uniform contact with said central pad.

Claims

2. A sanitary napkin as set forth in claim 1 wherein the fiber-to-adhesive ratio in said high-loft wrap material is from about 1:1 to about 2.5:1.
3. A sanitary napkin as set forth in claim 1 wherein said high-loft wrap material weighs from about 15 to about 40 grams/yd.2
4. A sanitary napkin as set forth in claim 1 wherein the fibers in said high-loft wrap material have a denier of from about 1.5 to about 3.0.
5. An improved sanitary napkin as set forth in claim 1 wherein said backing layer of said napkin fabric comprises a series of interconnected hexagons of adhesive.
6. An improved sanitary napkin as set forth in claim 5 wherein the spacing of said points varies regularly for said fibers throughout the fabric so that said loops vary in height regularly throughout the fabric.
7. An improved sanitary napkin as set forth in claim 1 wherein said fiber loops in said napkin fabric lie in planes extending in the cross direction of the fabric.
8. An improved sanitary napkin as set forth in claim 1 wherein said napkin fabric comprises a discontinuous, flexible backing of adhesive and a multiplicity of heat-set fibers each embedded at spaced longitudinal points in said backing layer and with the fiber portions between said points being looped outwardly from said backing layer.
9. In a sanitary napkin having a central pad of absorbent material, an improved elastic wrap disposed around said central pad and extending outwardly beyond the opposite ends thereof for providing fastening tabs, said wrap comprising an elastic high-loft, nonwoven fabric having a discontinuous backing layer of flexible adhesive disposed adjacent said central pad and a multiplicity of heat settable hydrophobic fibers individually looped outwardly from said backing layer and heat set in the looped form with the ends of each loop embedded in said backing layer, said loops extending over the open spaces in said discontinuous backing layer, said open spaces facilitating the passing of fluids through said wrap to said central pad of absorbent matErial, said elastic wrap enabling more uniform contact with said central pad.