US3746905A - High vacuum, field effect electron tube - Google Patents

High vacuum, field effect electron tube Download PDF

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US3746905A
US3746905A US00210451A US3746905DA US3746905A US 3746905 A US3746905 A US 3746905A US 00210451 A US00210451 A US 00210451A US 3746905D A US3746905D A US 3746905DA US 3746905 A US3746905 A US 3746905A
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tube
emitter
field effect
collector
electron
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J Shelton
J Hagood
R Norman
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US Department of Army
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J1/00Details of electrodes, of magnetic control means, of screens, or of the mounting or spacing thereof, common to two or more basic types of discharge tubes or lamps
    • H01J1/02Main electrodes
    • H01J1/30Cold cathodes, e.g. field-emissive cathode
    • H01J1/304Field-emissive cathodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J21/00Vacuum tubes
    • H01J21/36Tubes with flat electrodes, e.g. disc electrode

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  • ABSTRACT An improved electron tube is provided which eliminates the need for a heated electron source and affords simplified construction.
  • the tube a high vacuum tube, is capable of operating over an extended range of electrical potentials.
  • the electron tube operates on the principle'of electric field effect emission for the electron source, requiring neither gas, vapor nor a heated electrode in its envelope.
  • Two active elements, an emitter and a collector, are enclosed in an evacuated chamber with outside connections to each element.
  • the collector is a metal plate and the emitter is an oxide-meta1 composite which contains a very large number of metal filaments embedded in an insulating oxide matrix.
  • the number of filaments normally exceed one million per square centimeter of exposed surface, having ends connected on the back side to a conducting plate for external connection.
  • FIG. 3 VOLTAGE IN KV FOR PLATE-CATHODE SPACING .25 .5 .75 1.0 L25 1.5 L75 2.0 2.25 2.5 0 IO z 2 1 7 2 z 8 E q w a; E 6 i Z 25% I t: 4 52s 2 ELECTRIC FIELD m v/m. BETWEEN ELECTRODES M FIG. 3
  • Prior art diode tubes include the high vacuum and the gas or vapor filled tube.
  • the gas filled tube is capable of drawing large currents but is usually limited to low voltages because of arcing and ultimate tube damage at high voltages.
  • the gas filled tube usually operates with a cold emitter and is capable of regulating voltages of the order of only a few hundred volts.
  • the high vacuum tube, often used for high voltage rectification is expensive and fragile. Heater-emitter isolation is difficult to achieve and a warm-up time is required before operation of the tube can begin.
  • the present invention is a field effect, diode electron tube capable of operating over an extended range of potentials.
  • the high vacuum, field effect tube requires no gas in the envelope, no heated (thermionic) emitter, and can be designed for operation over an extremely wide range of potentials and power requirements.
  • This field effect electron tube utilizes field emission as a means for obtaining electrons from the emitter or cath ode. Operation over an extended voltage range is achieved by varying the spacing between the two elements, emitter and collector, to obtain the desired electric field for the required current at the specified operating potential. Due to the fact that current is a function of the electric field only, for a given emitter, the electron tube'is capable of operating over a greater voltage range than conventional electron tubes used in similar functions.
  • FIG. 1 is a diagrammatic view of a preferred embodiment of the field effect, diode vacuum tube.
  • FIG. 2 is a diagrammatic, enlarged view of the electrodes and the electric field therebetween.
  • FIG. 3 is a typical voltage current curve for the field effect diode tube. r
  • FIG. 4 is a typical rectified circuit employing the field effect diode tube.
  • FIG. 5 is a typical voltage regulation circuit utilizing the present invention as a voltage regulator.
  • FIG. 6 shows a field effect, diode tube in a typical over voltage protection configuration
  • FIG. 1 discloses a preferred embodiment of the present invention.
  • a high vacuum, cold cathode diode 10 comprises two active elements, an emitter l2 and a oollector 14.
  • An envelope l6 forms an evacuated (vacuum) chamber housing the active elements.
  • Envelope 16 may be constructed of glass, ceramic or metal with insulating feedthroughs for external circuit connections.
  • Collector 14 is a metal plate which may be consturcted of molybdenum, tungsten or other metal suitable as an anode or electron collector.
  • Emitter 12 is an oxide-metal composite which contains metal rods 20 (filaments) embedded in an insulating oxide matrix 22.
  • the rods may also be of molybdenum, tungsten or other suitable metal.
  • Oxide 22 can be formed of any suitable oxide, such as uranium oxide which will insulate adjacent filaments.
  • Metal rods 20 are less than 1 micron in diameter and the quantity exceeds one million in each square centimeter of material. Rods 20 extend through the matrix and are attached to ametal backing plate 24 by brazing or soldering such that both thermal and electrical contact is made between the metal rods in the emitter and the backing plate.
  • the emitter backing plate 24 and collector 14 are connected to metal rods 26 and 28 respectively which feed through the insulated envelope 16 for providing external electrical connectors.
  • an electric field is generated in the region between collector (anode) 14 and the oxide-metal matrix emitter (cathode) 12.
  • the electric field concentrates on the ends of metal rods 20.
  • a high electric field is concentrated at these end points or surfaces 30.
  • the electric field causes emission of electrons from surfaces 30, with the electrons being drawn to collector 14, causing current to flow.
  • the amount of current flow depends on the field, the filament diameter and the number of filaments in the matrix.
  • a smal filament diameter enhances electron emission from the end thereof.
  • the field effect diode affords circuit over-voltage protection and is capable of satisfactory operation over a large range of potentials. No energy source is needed for over-voltage protection and the response time is limited only to the time required for the electrons to cross the small gap between the two conductors.
  • a voltage-current curve is shown in FIG. 3 for a typical tube 10. From this curve it is apparent that no current is drawn for lower voltages, but once a voltage is typical rectification of the generated signal.
  • an ac voltage is applied to anode 14
  • current will flow through tube 10 and load R with an electric potential being developed across R when the anode is at a higher potential than emitter 12, or for one-half cycle. During the other half-cycle, no current flows through the tube.
  • Suitable capacitors, chokes and resistors can be added for filtering, and two devices can be used for full wave rectification as done in conventional rectifiers.
  • field effect tube 10 is shown functioning as an extended range, voltage regulator similar in operation to operation of other voltage regulating devices.
  • Tube is typically connected in parallel with a load R across a battery 8+ and in series with a resistance Rs.
  • Rs a resistance
  • a steady current is maintained thorugh tube 10 as long as the source voltage B+ is constant.
  • variation of the B-llevel changes the current through diode 10.
  • the current through the regulating diode 10 increases in an exponential manner, dropping more voltage across Rs and regulating the potential supplied to load R.
  • field effect tube 10 is shown functioning as an over-voltage protection unit.
  • Tube 10 is typically connected in parallel across the device or equipment to be protected and is designed such that no current flows through the tube under normal conditions.
  • current will flow through field effect tube 10 which in turn removes the charge from the device or equipment to be protected.
  • applications of the field effect diode include protecting delicate electronic equipment from line surges, extinguishing'arcs in switches and draining off lightning strikes on missiles and other aircraft.
  • This field effect diode provides a multitude of advantages over prior art devices. Since the emitter operates at ambient temperature, no power is required to heat the emitter, which results in an inherently more efficient device.
  • the current flow in the tube, for a given emitter is a function of the electric field, thus allowing the emitter to be used for numerous functions over a wide range of potentials by varying the spacing between the emitter and the collector to achieve the required electric field for the specific application.
  • the design of the emitter is simplified since it is not necessary to contain the heat at the emitter as in designs that use thermionic emitters.
  • a high vacuum electron tube having an extended range of operation and comprising: first and second electrodes in spaced apart, coaxial relationship; a vacuum housing assembly for encompassing said electrodes; first and second conductors connected respec tively to said first and second electrodes and extending external of said housing for applying an electric potential thereto whereby an electric field and current flow is provided between said electrodes, and said first electrode having a plurality of parallel surfaces for emitting electrons at prevailing ambient temperatures toward said second electrode; said first electrode is an emitter assembly having a plurality of equally spaced parallell rods and said second electrode is a collector, said emitter having a plurality of uniformily spaced elongated rods having a minimum density of one million rods per square centimeter and extending toward said collector for providing current flow between the collector and emitter; said rods being of equal length, and having one end thereof in common; and said common ends being coupled to said first conductor; a backing plate electrically connected between one end of said rods and said conductor, and an insulating filler between said

Abstract

An improved electron tube is provided which eliminates the need for a heated electron source and affords simplified construction. The tube, a high vacuum tube, is capable of operating over an extended range of electrical potentials. The electron tube operates on the principle of electric field effect emission for the electron source, requiring neither gas, vapor nor a heated electrode in its envelope. Two active elements, an emitter and a collector, are enclosed in an evacuated chamber with outside connections to each element. The collector is a metal plate and the emitter is an oxide-metal composite which contains a very large number of metal filaments embedded in an insulating oxide matrix. The number of filaments normally exceed one million per square centimeter of exposed surface, having ends connected on the back side to a conducting plate for external connection.

Description

United States Shelton et al.
atent 1 1 HIGH VACUUM, FIELD EFFECT ELECTRON TUBE [75] Inventors: Joe Shelton;.1erry W. Hagood; Ralph L. Norman, all of Huntsville, Ala.
[73] Assignee: The United States of America as represented by the Secretary of the Army, Washington, DC.
22 Filed: Dec. 21, 1971 21 Appl. No.: 210,451
[52] US. Cl 313/309, 313/336, 313/351 [51] Int. Cl. H0lj l/l6, HOlj 19/10 [58] Field of Search 313/309, 336, 351
[56] References Cited UNITED STATES PATENTS 3,453,478 7/1969 Shoulders et a1. 313/336 X OTHER PUBLICATIONS C. A. Spindt, A Thin-Film Field-Emission Cathode,
J. Applied Physics, Vol. 39, No. 7, pp. 3504-3505, 6-1968 Primary Examiner-David Schonberg Assistant Examiner-Paul A. Sacher [5 7] ABSTRACT An improved electron tube is provided which eliminates the need for a heated electron source and affords simplified construction. The tube, a high vacuum tube, is capable of operating over an extended range of electrical potentials. The electron tube operates on the principle'of electric field effect emission for the electron source, requiring neither gas, vapor nor a heated electrode in its envelope. Two active elements, an emitter and a collector, are enclosed in an evacuated chamber with outside connections to each element. The collector is a metal plate and the emitter is an oxide-meta1 composite which contains a very large number of metal filaments embedded in an insulating oxide matrix. The number of filaments normally exceed one million per square centimeter of exposed surface, having ends connected on the back side to a conducting plate for external connection.
3 Claims, 6 Drawing Figures Patented July 17, 1973 3,746,905
FIG. 2
VOLTAGE IN KV FOR PLATE-CATHODE SPACING .25 .5 .75 1.0 L25 1.5 L75 2.0 2.25 2.5 0 IO z 2 1 7 2 z 8 E q w a; E 6 i Z 25% I t: 4 52s 2 ELECTRIC FIELD m v/m. BETWEEN ELECTRODES M FIG. 3
PROTECTED EQUIP. K)v
FIG. 4
Rs FIG. 5
REG. DIODE FIG. 5
1 HIGH VACUUM, FIELD EFFECT ELECTRON TUBE BACKGROUND OF THE INVENTION Prior art diode tubes include the high vacuum and the gas or vapor filled tube. The gas filled tube is capable of drawing large currents but is usually limited to low voltages because of arcing and ultimate tube damage at high voltages. The gas filled tube usually operates with a cold emitter and is capable of regulating voltages of the order of only a few hundred volts. The high vacuum tube, often used for high voltage rectification is expensive and fragile. Heater-emitter isolation is difficult to achieve and a warm-up time is required before operation of the tube can begin. Special designs are required to contain the heat at the thermionic emitter and to reduce damage caused by the transfer of heat from the thermionic emitter to other tube components. Cooling devices are required on high power tubes to dissipate the heat that leaks from the thermionic emit ter.
SUMMARY OF THE INVENTION The present invention is a field effect, diode electron tube capable of operating over an extended range of potentials. The high vacuum, field effect tube requires no gas in the envelope, no heated (thermionic) emitter, and can be designed for operation over an extremely wide range of potentials and power requirements. This field effect electron tube utilizes field emission as a means for obtaining electrons from the emitter or cath ode. Operation over an extended voltage range is achieved by varying the spacing between the two elements, emitter and collector, to obtain the desired electric field for the required current at the specified operating potential. Due to the fact that current is a function of the electric field only, for a given emitter, the electron tube'is capable of operating over a greater voltage range than conventional electron tubes used in similar functions.
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a diagrammatic view of a preferred embodiment of the field effect, diode vacuum tube.
FIG. 2 is a diagrammatic, enlarged view of the electrodes and the electric field therebetween.
FIG. 3 is a typical voltage current curve for the field effect diode tube. r
FIG. 4 is a typical rectified circuit employing the field effect diode tube.
FIG. 5 is a typical voltage regulation circuit utilizing the present invention as a voltage regulator.
FIG. 6 shows a field effect, diode tube in a typical over voltage protection configuration;
DESCRIPTION OF THE PREFERRED EMBODIMENT Referring now tothe drawings, wherein like numerals represent like parts in each figure, FIG. 1 discloses a preferred embodiment of the present invention. A high vacuum, cold cathode diode 10 comprises two active elements, an emitter l2 and a oollector 14. An envelope l6 forms an evacuated (vacuum) chamber housing the active elements. Envelope 16 may be constructed of glass, ceramic or metal with insulating feedthroughs for external circuit connections. Collector 14 is a metal plate which may be consturcted of molybdenum, tungsten or other metal suitable as an anode or electron collector. Emitter 12 is an oxide-metal composite which contains metal rods 20 (filaments) embedded in an insulating oxide matrix 22. The rods may also be of molybdenum, tungsten or other suitable metal. Oxide 22 can be formed of any suitable oxide, such as uranium oxide which will insulate adjacent filaments.
Metal rods 20 are less than 1 micron in diameter and the quantity exceeds one million in each square centimeter of material. Rods 20 extend through the matrix and are attached to ametal backing plate 24 by brazing or soldering such that both thermal and electrical contact is made between the metal rods in the emitter and the backing plate. The emitter backing plate 24 and collector 14 are connected to metal rods 26 and 28 respectively which feed through the insulated envelope 16 for providing external electrical connectors.
As an electrical potential is applied across the terminals of field effect tube 10, an electric field is generated in the region between collector (anode) 14 and the oxide-metal matrix emitter (cathode) 12. As depicted in the enlarged view of FIG. 2, the electric field concentrates on the ends of metal rods 20. A high electric field is concentrated at these end points or surfaces 30. The electric field causes emission of electrons from surfaces 30, with the electrons being drawn to collector 14, causing current to flow. The amount of current flow depends on the field, the filament diameter and the number of filaments in the matrix. A smal filament diameter enhances electron emission from the end thereof. These parameters are adjustable in conjunction with the emitter size for various applications ranging from low voltages to extremely high voltages. The theory of electric field emission from point sources is well established and is applicable to the emitter filaments. When a potential is applied to the tube, the non-uniform electric field is concentrated between'collector 14 and the ends of each filament 20.
The field effect diode affords circuit over-voltage protection and is capable of satisfactory operation over a large range of potentials. No energy source is needed for over-voltage protection and the response time is limited only to the time required for the electrons to cross the small gap between the two conductors.
A voltage-current curve is shown in FIG. 3 for a typical tube 10. From this curve it is apparent that no current is drawn for lower voltages, but once a voltage is typical rectification of the generated signal. When an ac voltage is applied to anode 14, current will flow through tube 10 and load R with an electric potential being developed across R when the anode is at a higher potential than emitter 12, or for one-half cycle. During the other half-cycle, no current flows through the tube.
Suitable capacitors, chokes and resistors can be added for filtering, and two devices can be used for full wave rectification as done in conventional rectifiers.
In FIG. 5 field effect tube 10 is shown functioning as an extended range, voltage regulator similar in operation to operation of other voltage regulating devices. Tube is typically connected in parallel with a load R across a battery 8+ and in series with a resistance Rs. During operation, a steady current is maintained thorugh tube 10 as long as the source voltage B+ is constant. However, variation of the B-llevel changes the current through diode 10. Hence, when the potential of the source increases, the current through the regulating diode 10 increases in an exponential manner, dropping more voltage across Rs and regulating the potential supplied to load R.
In FIG. 6, field effect tube 10 is shown functioning as an over-voltage protection unit. Tube 10 is typically connected in parallel across the device or equipment to be protected and is designed such that no current flows through the tube under normal conditions. However, when the voltage on the equipment to be protected begins to increase, due to static charges, lightning, surges, or other reason, current will flow through field effect tube 10 which in turn removes the charge from the device or equipment to be protected. Although not limited thereto, applications of the field effect diode include protecting delicate electronic equipment from line surges, extinguishing'arcs in switches and draining off lightning strikes on missiles and other aircraft.
This field effect diode provides a multitude of advantages over prior art devices. Since the emitter operates at ambient temperature, no power is required to heat the emitter, which results in an inherently more efficient device. The current flow in the tube, for a given emitter, is a function of the electric field, thus allowing the emitter to be used for numerous functions over a wide range of potentials by varying the spacing between the emitter and the collector to achieve the required electric field for the specific application. The design of the emitter is simplified since it is not necessary to contain the heat at the emitter as in designs that use thermionic emitters. The curve of voltage versus current for a diode using a field effect emitter, as shown in FIG. 3, is different from curves obtained from gas filled diodes and diodes with thermionic emitters. The curve obtained from the diode using the field effect emitter is continuous and the same basic equation holds for current values over several orders of magnitude. No breaks are apparent such as in the curve for thermionic emitters in the region where emitter saturation begins to occur. No electrons flow at zero potential as in a diode with closely spaced elements using a thermionic emitter. Unlike the gas filled tube which requires an activation voltage greater than the operating voltage, the diode containing a field effect emitter begins to draw current at lower voltages, thus providing better over-voltage protection for equipment than the gas filled tube.
Although a particular embodiment and form of the invention has been described, it will be obvious to those skilled in the art that modifications may be made without departing from the scope and spirit of the invention. Accordingly, it is understood that the invention is limited only by the claims appended hereto.
We claim:
1. A high vacuum electron tube having an extended range of operation and comprising: first and second electrodes in spaced apart, coaxial relationship; a vacuum housing assembly for encompassing said electrodes; first and second conductors connected respec tively to said first and second electrodes and extending external of said housing for applying an electric potential thereto whereby an electric field and current flow is provided between said electrodes, and said first electrode having a plurality of parallel surfaces for emitting electrons at prevailing ambient temperatures toward said second electrode; said first electrode is an emitter assembly having a plurality of equally spaced paralell rods and said second electrode is a collector, said emitter having a plurality of uniformily spaced elongated rods having a minimum density of one million rods per square centimeter and extending toward said collector for providing current flow between the collector and emitter; said rods being of equal length, and having one end thereof in common; and said common ends being coupled to said first conductor; a backing plate electrically connected between one end of said rods and said conductor, and an insulating filler between said rods; said second electrode is a planar collector having the collecting surface normal to the coaxially aligned elec trodes; and said rods having the other ends thereof terminated in a plane paralell with said collecting surface for providing an electric field between each of said rods and said collecting surface and current flow therebetween when a potential difference is developed across said electrodes; and wherein said filler is an oxidemetal matrix.
2. An electron tube as set forth in claim 1 wherein said rods are less than 1 micron in diameter.
3. An electron tube as set forth in claim 1 wherein said first electrode is an emitter requiring no heat for operation, current flow through the tube being a function of the field between the electrodes.

Claims (2)

  1. 2. An electron tube as set forth in claim 1 wherein said rods are less than 1 micron in diameter.
  2. 3. An electron tube as set forth in claim 1 wherein said first electrode is an emitter requiring no heat for operation, current flow through the tube being a function of the field between the electrodes.
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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3859550A (en) * 1973-12-06 1975-01-07 Jerry W Hagood Hybrid rectifier
US4012656A (en) * 1974-12-09 1977-03-15 Norman Ralph L X-ray tube
US4163949A (en) * 1977-12-27 1979-08-07 Joe Shelton Tubistor
US4175234A (en) * 1977-08-05 1979-11-20 University Of Virginia Apparatus for producing ions of thermally labile or nonvolatile solids
US4340845A (en) * 1980-07-16 1982-07-20 Leeman Labs, Inc. Stabilized cathode assembly for arc light source
US4345181A (en) * 1980-06-02 1982-08-17 Joe Shelton Edge effect elimination and beam forming designs for field emitting arrays
FR2635913A1 (en) * 1988-08-31 1990-03-02 Saint Louis Inst FIELD EMISSION DIODE
US4969850A (en) * 1988-07-13 1990-11-13 Thorn Emi Plc Method of manufacturing a cold cathode, field emission device and a field emission device manufactured by the method
US5089742A (en) * 1990-09-28 1992-02-18 The United States Of America As Represented By The Secretary Of The Navy Electron beam source formed with biologically derived tubule materials
US6097139A (en) * 1995-08-04 2000-08-01 Printable Field Emitters Limited Field electron emission materials and devices
US6353290B1 (en) * 1996-03-06 2002-03-05 The United States Of America As Represented By The Secretary Of The Army Microwave field emitter array limiter

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2287749A (en) * 1938-02-12 1942-06-23 Slayter Electronic Corp Method and apparatus for amplifying electrical currents
US2645742A (en) * 1947-03-20 1953-07-14 Int Standard Electric Corp Electric discharge device
US2916668A (en) * 1955-07-01 1959-12-08 Research Corp Heat stabilized field emission electron sources
US3453478A (en) * 1966-05-31 1969-07-01 Stanford Research Inst Needle-type electron source
US3466485A (en) * 1967-09-21 1969-09-09 Bell Telephone Labor Inc Cold cathode emitter having a mosaic of closely spaced needles
US3635157A (en) * 1968-12-30 1972-01-18 Continental Can Co Method and apparatus for electrostatically charging particles for printing or coating

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2287749A (en) * 1938-02-12 1942-06-23 Slayter Electronic Corp Method and apparatus for amplifying electrical currents
US2645742A (en) * 1947-03-20 1953-07-14 Int Standard Electric Corp Electric discharge device
US2916668A (en) * 1955-07-01 1959-12-08 Research Corp Heat stabilized field emission electron sources
US3453478A (en) * 1966-05-31 1969-07-01 Stanford Research Inst Needle-type electron source
US3466485A (en) * 1967-09-21 1969-09-09 Bell Telephone Labor Inc Cold cathode emitter having a mosaic of closely spaced needles
US3635157A (en) * 1968-12-30 1972-01-18 Continental Can Co Method and apparatus for electrostatically charging particles for printing or coating

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
C. A. Spindt, A Thin Film Field Emission Cathode, J. Applied Physics, Vol. 39, No. 7, pp. 3504 3505, 6 1968 *

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3859550A (en) * 1973-12-06 1975-01-07 Jerry W Hagood Hybrid rectifier
US4012656A (en) * 1974-12-09 1977-03-15 Norman Ralph L X-ray tube
US4175234A (en) * 1977-08-05 1979-11-20 University Of Virginia Apparatus for producing ions of thermally labile or nonvolatile solids
US4163949A (en) * 1977-12-27 1979-08-07 Joe Shelton Tubistor
US4345181A (en) * 1980-06-02 1982-08-17 Joe Shelton Edge effect elimination and beam forming designs for field emitting arrays
US4340845A (en) * 1980-07-16 1982-07-20 Leeman Labs, Inc. Stabilized cathode assembly for arc light source
US4969850A (en) * 1988-07-13 1990-11-13 Thorn Emi Plc Method of manufacturing a cold cathode, field emission device and a field emission device manufactured by the method
FR2635913A1 (en) * 1988-08-31 1990-03-02 Saint Louis Inst FIELD EMISSION DIODE
DE3924745A1 (en) * 1988-08-31 1990-03-08 Deutsch Franz Forsch Inst Field emission diode serving as heavy current switch - has cathode emitting surfaces formed by edges of thin conducting layers on insulating support
US5089742A (en) * 1990-09-28 1992-02-18 The United States Of America As Represented By The Secretary Of The Navy Electron beam source formed with biologically derived tubule materials
US6097139A (en) * 1995-08-04 2000-08-01 Printable Field Emitters Limited Field electron emission materials and devices
US6353290B1 (en) * 1996-03-06 2002-03-05 The United States Of America As Represented By The Secretary Of The Army Microwave field emitter array limiter

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