US3756907A - Production of perforated non woven fibrous webs - Google Patents

Production of perforated non woven fibrous webs Download PDF

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US3756907A
US3756907A US00090251A US3756907DA US3756907A US 3756907 A US3756907 A US 3756907A US 00090251 A US00090251 A US 00090251A US 3756907D A US3756907D A US 3756907DA US 3756907 A US3756907 A US 3756907A
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slits
web
binder
fibers
holes
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US00090251A
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W Heling
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Carl Freudenberg KG
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Carl Freudenberg KG
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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/64Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/425Cellulose series
    • D04H1/4258Regenerated cellulose series
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326Condensation or reaction polymers
    • D04H1/4334Polyamides
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/587Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • Y10T156/1052Methods of surface bonding and/or assembly therefor with cutting, punching, tearing or severing
    • Y10T156/1056Perforating lamina

Definitions

  • the present invention relates to the production of perforated non-woven fabrics, i.e. non-woven fabrics provided with holes.
  • Non-woven fabrics are being used today for many purposes.
  • a mat is first prepared and then sprayed or impregnated with a binding agent. Then the mat thus impregnated is subjected to a heat treatment wherein the binding agent, latex for example, is set or vulcanized.
  • the sheet material thus preparedhas good resiliency and can be used as a stiffening insert, i.e. interfacing, or for many other purposes, e.g., as throw-away cloths.
  • non-woven fabrics containing holes in any desired pattern can be prepared very simply by first suspending the fibers in a very great excess of water (about :1 part fibers to 1000 parts water), as is done in the manufacture of paper.
  • the water also contains a binding agent, e.g., latex. It is desirable to coagulate the latex, because then the precipitated binding agent deposits itself preferentially on the surface of the fibers simultaneously suspended in the water. Then the fiber suspension containing the binding agent is poured onto a screen, e.g., a screen as described in Voith Anlagen und Konstruktion, No. 16, May 1967, Article No. 12, reprint 1782, thereby forming a coherent web of fibers.
  • a binding agent e.g., latex.
  • the coagulation of the binding agent can be brought about by the addition of acid or salts or by the electrical reversal of the charge of the binding agent dispersion, using known methods.
  • the use of heat-sensitized latices is also possible.
  • the binding agent coagulates as soon as a certain temperature is reached, which can be very low, e.g., 35 C.
  • the mat is first drained as well as possible. Then the mat, still wet, is placed on a suitable support and provided with a plurality of small slits.
  • the slits may have, for example, a length of 2 to 8 mm.
  • the second slit is made, until a whole row of slits is produced.
  • a second row of slits is created, preferably in such a manner that an offsetting of the slits results, i.e. the slits are staggered.
  • the slits can be produced with fine spring blades or with rollers having razor-blade-like segments. Apparatus suitable for the slitting of plastic sheet materials can be used for the instant slitting operation.
  • FIG. 1 is a schematic plan view of a fiber web which has been slit
  • FIG. 2 is a schematic plan view of the web after it has been partially set, stretched transversely of the slits and setting of the binder has been completed.
  • a nonwoven fleece or mat 11 containing binder is laid down in paper making fashion as described hereinabove and the wet fleece is slit to provide staggered rows of slits 12.
  • the mat is given a preliminary drying on a cylinder or drum dryer to such an extent that it contains only to moisture (with reference to the fiber weight). Then, in the final drying process at about 130-160 C, it is stretched by about 30 to 50% transversely of the slits and at the same time dried. This widens the slits to holes 13 of generally diamond-shaped configuration as can be seen in FIG. 2. Since at the same time a vulcanization or setting of the binding agent takes place the holes are stabilized.
  • the end product in certain embodiments resembles expanded metal structures in that the bonded web turns up sideways between openings 13 to give a three-dimensional effect.
  • EXAMPLE 2.5 kg. of 3 denier rayon fibers 10 cm. long and 2.5 kg. of 6 denier nylon fibers 20 cm. long are dispersed in 10 liters of water.
  • the coagulated latex is thereby deposited on the surface of the fibers.
  • the thus prepared fiber slurry is poured onto a Hydroformer Steigsieb, sold by the German firm Voit cif Heidenheim, i.e. the suspension is poured onto a moving sieve having a width of 1.5 m. at such a speed that the resulting nonwoven on the screen has a weight of 50 g./m.
  • the still wet fleece is freed from as much water as possible, i.e. down to 200% of water based upon the fiber weight.
  • the still wet fleece is forwarded onto a backing consisting of foamed rubber.
  • the sheet structure is slit with a slittling machine as described in Czech Patent 114,838, the slits having a length of 4 mm. The distance between slits in the same line is 3 mm.; the lateral distance between adjacent lines of slits is 2 mm.
  • the thus slit fleece is dried on a drum dryer, the metal surface of which is heated to C fiber-weight. Thenthe fleece-is forwarded to a tenter frame wherein the width of the fleece band is expanded from 1.5 to 2.4 m. whereupon the slits are converted into diamond like openings.
  • the length of a slit is 4 mm. but after the expansion the length is only 3 mm. but, on the other hand, the original width which is practically zero is brought to 2 mm.
  • the temperature of the air in the tenter frame is 140 C., the binder thereupon setting so that even upon removal from the frame the fabric maintains its shape and three-dimensional appearance.
  • the fibers suitable for practicing the invention include synthetic fibers such as nylon, polyester, acrylics, olefins, cellulosics such as acetate, rayon, and the like, as well as natural fibers such as cotton, wool, and the like, and blends thereof. Their deniers and lengths may be varied widely.
  • the fibers may be laid down into the initial fleece by the wet lay process described hereinabove or by the known dry lay processes, involving air deposit or crosslaying of carded laps.
  • the binder may be included in the liquid in the event of Wet laying or it may be subsequently applied by spraying, coating or the like; in the case of dry laying by air deposit the binder may be deposited simultaneously with the fibers or it may be postapplied as by sprinkling, liquid impregnation, spraying or foam impregnation. If the binder is applied as a dry solid, the initial partial setting may be achieved by a light heating to render tacky the outside of the binder particles.
  • the type and proportion of binder to fiber may also vary widely as is known in the non-woven art depending upon the intended end use and desired hand.
  • the partial setting may be effected either before or after slitting. If the water content is very high it may be desirable to provide a resilient backing to facilitate slitting before partial setting.
  • the slitting itself can be effected by localized melting in the case of fusible fibers although it is preferably effected by cutting.
  • transverse stretching depends upon the proportion of holes desired in the final structure and the disposition and arrangement of the slits. Drying or completion of setting of the binder is of course effected with the fabric in stretched condition so as to retain the expanded, perforated or open configuration.
  • the new fabric In contrast with existing perforated non-Wovens wherein the action of water jets to displace fibers and form holes causes bunching up of fibers about the holes, the new fabric is characterized by a substantially uniform distribution of fibers throughout the fabric, even around the holes. The three-dimensional effect gives a unique hand and appearance not heretofore realized with fiber products.
  • Process of producing perforated non-woven fabrics which comprises forming a non-woven fibrous web containing a binder, forming elongated slits in said web, partially setting the binder, stretchin said web transversely of said slits whereby said slits form holes, and completing setting of said binder with said web in stretched condition whereby said web is bonded and retains said holes even upon release of the stretching force.
  • slits range in length from about 2 to 8 mm. and are arranged in rows where they are spaced from adjacent slits by about 2 to 8 mm.

Abstract

PERFORATED NON-WOVEN FABRICS ARE PRODUCED BY FORMING A FIBROUS WEB CONTAINING A BINDER, FORMING ELONGATED SLITS IN SAID WEB, PARTIALLY SETTING THE BINDER, STRETCHING SAID WEB TRANSVERSELY OF SAID SLITS WHEREBY SAID SLITS FORM HOLES, AND COMPLETING SETTING OF SAID BINDER WITH SAID WEB IN STRETCHED CONDITION WHEREBY SAID WEB IS BONDED AND RETAINS SAID HOLES EVEN UPON RELEASE OF THE STRETCHING FORCE.

Description

w. HELING PRODUCTION OF PERFORATED NON-WOVEN FIBROUS WEBS Filed Nov. 17, 1970 Sept. 4, 1973 INVENTOR WILHELM HELING BURGESS. DINKLAGE 8. SPRUNG ATTORNEYS.
FIG. 2.
United States Patent US. Cl. 162-114 7 Claims ABSTRACT OF THE DISCLOSURE Perforated non-woven fabrics are produced by forming a fibrous web containing a binder, forming elongated slits in said web, partially setting the binder, stretching said web transversely of said slits whereby said slits form holes, and completing setting of said binder with said web in stretched condition whereby said web is bonded and retains said holes even upon release of the stretching force.
The present invention relates to the production of perforated non-woven fabrics, i.e. non-woven fabrics provided with holes.
Non-woven fabrics are being used today for many purposes. For their manufacture, a mat is first prepared and then sprayed or impregnated with a binding agent. Then the mat thus impregnated is subjected to a heat treatment wherein the binding agent, latex for example, is set or vulcanized. The sheet material thus preparedhas good resiliency and can be used as a stiffening insert, i.e. interfacing, or for many other purposes, e.g., as throw-away cloths.
In other applications it is desirable to produce a pattern of holes in the final product. This, however, requires a considerable investment in equipment. First the mat must be laid on a sieve and then be covered with a perforated plate, somewhat in the manner of US. Pat. 2,861,251. Then strong jets of water are shot from above through the holes in the plate. The water driven with great force through the holes pushes aside the fibers therebelow and then exits through the sieve. The mat thus perforated is still not very stable and must then be impregnated, at an additional great investment in equipment, so that it will be strengthened.
It has now been found that non-woven fabrics containing holes in any desired pattern can be prepared very simply by first suspending the fibers in a very great excess of water (about :1 part fibers to 1000 parts water), as is done in the manufacture of paper.
The water also contains a binding agent, e.g., latex. It is desirable to coagulate the latex, because then the precipitated binding agent deposits itself preferentially on the surface of the fibers simultaneously suspended in the water. Then the fiber suspension containing the binding agent is poured onto a screen, e.g., a screen as described in Voith Forschung und Konstruktion, No. 16, May 1967, Article No. 12, reprint 1782, thereby forming a coherent web of fibers.
The coagulation of the binding agent can be brought about by the addition of acid or salts or by the electrical reversal of the charge of the binding agent dispersion, using known methods. The use of heat-sensitized latices is also possible. Here the binding agent coagulates as soon as a certain temperature is reached, which can be very low, e.g., 35 C.
Basically, the prior coagulation of the binding agent onto the fibers can be omitted. In this case, of course, considerably more binding agent must be added, because when the mixture is poured onto the screen a large part of the binding agent is lost with the Water. If, however, it is Patented .Sept. 4, 1973 first coagulated, nearly all of the binding agent deposits on the -fibers, so that, when the mixture is poured onto the screen, almost nothing but pure water flows through the screen. v
After a wet continuous mat of fibers containing binding agent has formed, the mat is first drained as well as possible. Then the mat, still wet, is placed on a suitable support and provided with a plurality of small slits. The slits may have, for example, a length of 2 to 8 mm. At a distance of the same order of magnitude, the second slit is made, until a whole row of slits is produced. At a distance of a few millimeters from the first row of slits a second row of slits is created, preferably in such a manner that an offsetting of the slits results, i.e. the slits are staggered. The slits can be produced with fine spring blades or with rollers having razor-blade-like segments. Apparatus suitable for the slitting of plastic sheet materials can be used for the instant slitting operation.
. The invention will be further described with reference to the accompanying drawings wherein:
FIG. 1 is a schematic plan view of a fiber web which has been slit; and
FIG. 2 is a schematic plan view of the web after it has been partially set, stretched transversely of the slits and setting of the binder has been completed.
Referring now more particularly to the drawing, a nonwoven fleece or mat 11 containing binder is laid down in paper making fashion as described hereinabove and the wet fleece is slit to provide staggered rows of slits 12.
Either before or after the slitting operation, the mat is given a preliminary drying on a cylinder or drum dryer to such an extent that it contains only to moisture (with reference to the fiber weight). Then, in the final drying process at about 130-160 C, it is stretched by about 30 to 50% transversely of the slits and at the same time dried. This widens the slits to holes 13 of generally diamond-shaped configuration as can be seen in FIG. 2. Since at the same time a vulcanization or setting of the binding agent takes place the holes are stabilized. The end product in certain embodiments resembles expanded metal structures in that the bonded web turns up sideways between openings 13 to give a three-dimensional effect.
The invention will be further described in the following illustrative example wherein all parts are by weight unless otherwise stated.
EXAMPLE 2.5 kg. of 3 denier rayon fibers 10 cm. long and 2.5 kg. of 6 denier nylon fibers 20 cm. long are dispersed in 10 liters of water. To this dispersion there are added 2 kg. of Butofan KR 2345 which is a coagulatable butadiene-acrylonitrile latex sold by Farbenfabriken Bayer. Then there are added 0.08 kg. of Pol-imin SN 20 which is a coagulant causing the Butofan to coagulate. The coagulated latex is thereby deposited on the surface of the fibers. With continuous stirrin the thus prepared fiber slurry is poured onto a Hydroformer Steigsieb, sold by the German firm Voit cif Heidenheim, i.e. the suspension is poured onto a moving sieve having a width of 1.5 m. at such a speed that the resulting nonwoven on the screen has a weight of 50 g./m. By suction the still wet fleece is freed from as much water as possible, i.e. down to 200% of water based upon the fiber weight. Then the still wet fleece is forwarded onto a backing consisting of foamed rubber. Here the sheet structure is slit with a slittling machine as described in Czech Patent 114,838, the slits having a length of 4 mm. The distance between slits in the same line is 3 mm.; the lateral distance between adjacent lines of slits is 2 mm.
Subsequently the thus slit fleece is dried on a drum dryer, the metal surface of which is heated to C fiber-weight. Thenthe fleece-is forwarded to a tenter frame wherein the width of the fleece band is expanded from 1.5 to 2.4 m. whereupon the slits are converted into diamond like openings. Originally the length of a slit is 4 mm. but after the expansion the length is only 3 mm. but, on the other hand, the original width which is practically zero is brought to 2 mm. The temperature of the air in the tenter frame is 140 C., the binder thereupon setting so that even upon removal from the frame the fabric maintains its shape and three-dimensional appearance.
The fibers suitable for practicing the invention include synthetic fibers such as nylon, polyester, acrylics, olefins, cellulosics such as acetate, rayon, and the like, as well as natural fibers such as cotton, wool, and the like, and blends thereof. Their deniers and lengths may be varied widely. The fibers may be laid down into the initial fleece by the wet lay process described hereinabove or by the known dry lay processes, involving air deposit or crosslaying of carded laps. The binder may be included in the liquid in the event of Wet laying or it may be subsequently applied by spraying, coating or the like; in the case of dry laying by air deposit the binder may be deposited simultaneously with the fibers or it may be postapplied as by sprinkling, liquid impregnation, spraying or foam impregnation. If the binder is applied as a dry solid, the initial partial setting may be achieved by a light heating to render tacky the outside of the binder particles. The type and proportion of binder to fiber may also vary widely as is known in the non-woven art depending upon the intended end use and desired hand.
As noted, the partial setting may be effected either before or after slitting. If the water content is very high it may be desirable to provide a resilient backing to facilitate slitting before partial setting. The slitting itself can be effected by localized melting in the case of fusible fibers although it is preferably effected by cutting.
The extent of transverse stretching depends upon the proportion of holes desired in the final structure and the disposition and arrangement of the slits. Drying or completion of setting of the binder is of course effected with the fabric in stretched condition so as to retain the expanded, perforated or open configuration.
In contrast with existing perforated non-Wovens wherein the action of water jets to displace fibers and form holes causes bunching up of fibers about the holes, the new fabric is characterized by a substantially uniform distribution of fibers throughout the fabric, even around the holes. The three-dimensional effect gives a unique hand and appearance not heretofore realized with fiber products.
It will be appreciated that the instant specification and examples are set forth by way of illustration and not limitation, and that various modifications and changes may be made without departing from the spirit and scope of the present invention.
What is claimed is:
1. Process of producing perforated non-woven fabrics which comprises forming a non-woven fibrous web containing a binder, forming elongated slits in said web, partially setting the binder, stretchin said web transversely of said slits whereby said slits form holes, and completing setting of said binder with said web in stretched condition whereby said web is bonded and retains said holes even upon release of the stretching force.
2. Process according to claim 1, wherein said slits are provided in a plurality of staggered rows.
3. Process according to claim 1, wherein said web is wet and is dried to a water content of approximately to based on the weight of fiber, thereby to effect partial setting of said binder, completion of setting being effected by completion of drying.
4. Process according to claim 1, wherein said slits range in length from about 2 to 8 mm. and are arranged in rows where they are spaced from adjacent slits by about 2 to 8 mm.
5. Process according to claim 1, wherein the web is formed by suspending fibers in water containing a binder, and pouring the suspension onto a screen to leave a wet binder-containing web.
6. Process according to claim 5, wherein the binder is in the suspension in coagulated condition.
7. Process according to claim 6, wherein the wet binder-containing web is dried to a water content of approximately 80 to 100% based on the weight of fiber, thereby to effect partial setting of said binder, completion of setting being effected by completion of drying, said slits ranging in length from about 2 to 8 mm. and being arranged in staggered rows in which they are spaced from adjacent slits by about 2 to 8 mm.
References Cited UNITED STATES PATENTS 3,293,104 12/1966 Hull 156-229 X 3,042,576 7/1962 Harmon et al 162-114 2,697,678 12/1954 Ness et al. 156229 X 3,253,317 5/1966 Such 162-114 X S. LEON BASHORE, Primary Examiner A. L. CORBIN, Assstant Examiner US. Cl. X.R.
19l6l P; 156229, 252; 162--197
US00090251A 1969-12-01 1970-11-17 Production of perforated non woven fibrous webs Expired - Lifetime US3756907A (en)

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DE19691960141 DE1960141A1 (en) 1969-12-01 1969-12-01 Process for the production of perforated nonwovens

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EP0103376A2 (en) * 1982-07-22 1984-03-21 The Wiggins Teape Group Limited Paper making machinery
US4469734A (en) * 1981-11-24 1984-09-04 Kimberly-Clark Limited Microfibre web products
US4701237A (en) * 1983-10-17 1987-10-20 Kimberly-Clark Corporation Web with enhanced fluid transfer properties and method of making same
US5415715A (en) * 1992-06-04 1995-05-16 Societe Europeenne De Propulsion Method of manufacturing a honey comb structure of thermostructural composite material
US5628097A (en) * 1995-09-29 1997-05-13 The Procter & Gamble Company Method for selectively aperturing a nonwoven web
US5714107A (en) * 1994-05-20 1998-02-03 Kimberly-Clark Worldwide, Inc. Perforated nonwoven fabrics
US6329016B1 (en) 1997-09-03 2001-12-11 Velcro Industries B.V. Loop material for touch fastening
US6342285B1 (en) 1997-09-03 2002-01-29 Velcro Industries B.V. Fastener loop material, its manufacture, and products incorporating the material
US6423884B1 (en) 1996-10-11 2002-07-23 Kimberly-Clark Worldwide, Inc. Absorbent article having apertures for fecal material
US20030042195A1 (en) * 2001-09-04 2003-03-06 Lois Jean Forde-Kohler Multi-ply filter
US6869659B2 (en) 1997-09-03 2005-03-22 Velcro Industries B.V. Fastener loop material, its manufacture, and products incorporating the material
US6989075B1 (en) * 2000-11-03 2006-01-24 The Procter & Gamble Company Tension activatable substrate
US20120028559A1 (en) * 2010-07-29 2012-02-02 Rockwell Automation Technologies, Inc. System and method for ventilating and isolating electrical equipment
US10272000B2 (en) * 2014-11-06 2019-04-30 The Procter & Gamble Company Patterned apertured webs and methods for making the same
USD898923S1 (en) * 2018-06-01 2020-10-13 Kinesio Ip Llc Adhesive tape
USD948223S1 (en) * 2017-09-01 2022-04-12 3M Innovative Properties Company Patterned reflective material
USD965990S1 (en) * 2017-09-01 2022-10-11 3M Innovative Properties Company Patterned reflective material

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Cited By (24)

* Cited by examiner, † Cited by third party
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AT294748B (en) 1971-12-10
FR2070215B1 (en) 1975-01-10
GB1328227A (en) 1973-08-30
FR2070215A1 (en) 1971-09-10
DE1960141A1 (en) 1971-06-03
BE759386A (en) 1971-05-25
NL7010683A (en) 1971-06-03

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