|Número de publicación||US3896807 A|
|Tipo de publicación||Concesión|
|Fecha de publicación||29 Jul 1975|
|Fecha de presentación||13 Jun 1974|
|Fecha de prioridad||13 Jun 1974|
|Número de publicación||US 3896807 A, US 3896807A, US-A-3896807, US3896807 A, US3896807A|
|Cesionario original||Gilbert Buchalter|
|Exportar cita||BiBTeX, EndNote, RefMan|
|Citas de patentes (9), Citada por (292), Clasificaciones (36), Eventos legales (2)|
|Enlaces externos: USPTO, Cesión de USPTO, Espacenet|
I United States Patent 1 1 1 3,896,807
Buchalter July 29, 1975  ARTICLE IMPREGNATED WITH 2,765,789 10/1956 Schmierer 128/260 4 2,804,424 8/1957 Stirn et a1. 424/14 SKIN CARE FORMULATIONS 2,804,425 8/1957 Smith et a1..... 424/26 Inventor: Gilbert Buchalter, 555 Mt. Prospect 3,328,259 6/1967 Anderson 424/28 Ave., Newark, NJ. 07014 3,490,454 1/1970" Goldfarb et a1 128/285  Filed: June 13, 1974 Primary Exammer-Aldnch F. Medbery 1 1 pp N05 478,924 Attorney, Agent, or Firm-Lerner, David, Littenberg & Samuel  US. Cl. 128/26]; 128/263; 424/16;
424/26; 42 /2 [57 ABSTRACT  Int. Cl A6lm 35/00 [58 Field of Search 128/260, 261, 263, 8]; pmwsded wh'ch may be 1 424/28 1 6 26 l 4 art1c1e of apparel, such as a glove, or a top1ca1 applicator for use in applying a therapeutic substance to the skin, which article is'impregnated with the oil phase of  Reerences a cream formulation The oil phase impregnant is in UNITED STATES PATENTS the form of a non-oily solid which upon addition of 2,653,601 9/1953 Morrison 128/165 water or moisture thereto is activated to form a 2,664,087 12 1953 Lewis cream 2,671,446 3/1954 Mann 2,685,086 8/1954 Henry 128/260 X 26 Claims, N0 Drawings ARTICLE IMPREGNATED WITH SKIN-CARE FORMULATIONS FIELD OF THE INVENTION The 'present invention relates to an article such as a piece of apparel or an applicator pad, impregnated with the oil phase of a cream formulation which upon the addition of moisture thereto forms a skin-soothing cream.
BACKGROUND OF THE INVENTION The therapeutic effect which creams or oils have on the skin is unquestioned. For example, use of hand creams or facial creams are essentially in treating and- /or preventing chapping or chafing of the skin.
The prior art is replete with articles of apparel and applicator pads for use in applying therapeutic creams, lotions or oils to the skin. For example, U.S. Pat. No. 2,501,565 discloses a hand mitten impregnated with a cream such as lanolin and lemon oil; U.S. Pat. No. 2,916,036 discloses a rubber glove, the lining of which is impregnated with an unguent material such as lanolin; other patents disclosing gloves impregnated with creams include U.S. Pat. Nos. 3,116,732; 3,342,182; 3,298,368; 3,384,083; and 3,499,446. Other articles of apparel impregnated with various therapeutic cream or oil formulations are disclosed in U.S. Pat. Nos. 3,354,884 (facial mask); 2,716,981 (facial mask); 2,664,087 (foot slipper); 3,489,884 (diapers); and 3,585,998 (diaper liners).
Paper products, such as tissues and toilet tissues are knowwn to be impregnated with therapeutic cream or oil formulations. For example, U.S. Pat. No. 302,073 discloses a toilet paper impregnated with an unctuous or oily material such as vaseline, glycerine, paraffin or animal or vegetable oils. U.S. Pat. No. 1,687,643 discloses a toilet tissue coated with a creaam which coating may e covered with a layer of paraffin to prevent the fingers from becoming soiled by the cream. U.S. Pat. No. 1,868,862 discloses a detergent towel impregnated with a soap compound which may include glycerine. U.S. Pat. No. 2,032,645 discloses an absorbent paper product containing a wetting agent to preserve the paper against loss of absorbency. U.S. Pat. No. 2,944,931 discloses a sanitary paper containing lanolin in the form of an aqueous emulsion. U.S. Pat. No. 3,264,188 discloses a sanitary impregnated skin wiper, such as toilet tissue, impregnated with an oily material and an emulsifying agent.
Patents disclosing applicator pads or cloths or paper impregnated with creams or cream-like materials include U.S. Pat. Nos. 1,836,833; 2,495,066; 2,702,780; 2,999,265; 3,624,224; and 3,129,811.
The articles or applicator paper or pads impregnated with cream or cream-like materials, disclosedin the afore-mentioned patents are quite useful for administering such creams to the skin. However, these articles and applicators have the same serious drawback, namely, that they are greasy or oily to the touch. They tend to stain oil-absorbent materials upon contact thereby losing the cream and ruining the materials contacted therewith. Thus, they must be packaged with great care and at great expense. For example, the toilet tissue disclosed in U.S. Pat. No. 3,264,188 impregnated with an oil and an emulsifying agent must be wrapped in oil-resistant paper to provide a non-staining package.
U.S. Pat. No. 2,495,066 discloses a dusting and polishing paper impregnated with a stable oil-in-waater emulsion, which comprises a non-drying oil and one or more emulsifying or surface active agents and a flexibilizing or plasticizing agent. The above ingredients are applied to the paper as an aqueous emulsion and the paper is then dried over steam rolls. The result is that the so impregnated paper is somewhat tacky or sticky because some of the water of the aqueous emulsion has not been driven off by the heating over the steam rolls and resulted in emulsification.
STATEMENT OF THE INVENTION In accordance with the present invention, there is provided an article such as an article of apparel or a cream applicator which is impregnated with the oil phase of a cream formulation, in the form of a non-oily non-tacky solid, and which upon the addition of water or moisture thereto forms a therapeutic skin cream. The article of the invention is not greasy or oily to the touch and need not be packaged in oil resistant paper or other oil resistant packaging material and thus overcomes the afore-mentioned disadvantages associated with creams or cream-like or oily materials. Furthermore, the therapeutic composition or oil-phase carried by the articles of the invention is capable of controlled emulsion and sustained release of any other therapeutic substance or medicament present in said oil-phase, depending upon the type, melting point and amounts of oily materials and emulsifiers employed.
DETAILED DESCRIPTION OF THE INVENTION In accordance with one embodiment of the present invention, there is provided an article of apparel, such as a glove, glove liner, facial mask, slipper, diaper, sanitary napkin and the like, which is to be worn by the user so that an inside portion of said article comes into direct contact with the users skin in the area to which a therapeutic cream is to be applied. The article of apparel of the invention generally comprises-an outerportion which is worn away from the skin and an inner portion which comes into direct contactwith the skin of the user, which inner portion is impregnated withthe oil phase of a cream formulation which upon addition of moisture thereto forms a cream. The oil phase, be-
fore addition of water thereto, is in the form of a dry non-oily non-sticky solid atroom temperature, and I generally comprises an oily material and one or more emulsifying agents and may include in addition, one or Q more emollients, dyes, perfumes and/or pharmaceuticals.
nated with an oil phase of a cream formulation to form a new and most advantageous hand care product. The
glove or a pair of such gloves or liners maybe employed by themselves or as a separate liner under rubber gloves, under dress gloves, under work gloves or j gardening gloves. Furthermore, the 'glov esmay'l'be incorporated as permanent'liners intoany of 'the'afore gloves are worn while working, for examplefisu'ch'as rubber gloves worn during the washing of dishes, floors and the like, the moisture and heat produced by per- Where the article of the invention comprises 'a glove I or glove liner, the glove or glove liner may 'be inpregspiring of the hands, will be sufficient to cause emulsification of a portion of the oil phase to form a therapeutic cream. Since the cream forms while the gloves are being worn, and perhaps while the wearer is working, the so-formed cream has an opportunity to work its way into the pores of the skin to provide beneficial and therapeutic effects even after the gloves are removed.
Only a relatively small amount of emulsification is necessary to produce a therapeutic amount of cream. The perspiration and heat generated by the wearer will produce the necessary amount of moisture to form the desired therapeutic amount of cream.
As indicated above, in accordance with the invention, the oil phase may be impregnated into other articles which are employed in contact with the skin, such as facial masks, slippers or shoe linings, diapers, diaper liners, sanitary napkins, dresses, pants and even bandages. In all such applications the contact of the wearers skin will produce sufficient moisture and heat to cause emulsification of a portion of said oil phase.
Further in accordance with the present invention, there is provided an article for use in applying a therapeutic cream substance to the skin which article comprises a substrate impregnated with a therapeutic composition comprising the oil phase of a cream formulation in the form of a dry non-oily solid as described heretofore. Such substrate may comprise paper or a paper product, such as a tissue, towel, toilet tissue, woven and non-woven fabrics, and the like.
The oil phase which is in the form of a dry non-ily 'solid carried by the article of the invention comprises from about 1 to about 99% and preferably from about 30 to about 70 of an oily material and from about 99 to about 1% and preferably from about 70 to about 30% of an emulsifier.
Examples of oily materials suitable for use herein include, but are not limited to, mineral oil, petrolatum, paraffin, vegetable oil, such as linseed oil, soya bean oil or cotton seed oil, various animal oils, such as whale oil, lard oil, caster oil, olive oil, and isopropyl palmitate.
The emulsifying agents which may be employed herein cause emulsification of an oil upon contact with the oil without the necessity of high speed mechanical agitation. Such emulsifiers include anionic emulsifiers, cationic emulsifiers, and non-ionic emulsifiers. Examples of suitable emulsifiers include, but are not limited to, cetyl alcohol, as well as any one of those classified in the following groups.
1. A long chain fatty acid partial ester of a hexitol anhydride wherein the fatty acid has at least 6, preferably from 12 to 18, carbon atoms, including the long chain fatty acid partial esters of sorbitan, sorbide, mannitan and mannide and mixtures thereof. Examples of such esters are sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan monooleate, and sorbitan trioleate, These compounds are sold by Atlas Powder Company under the trade names, respectively, Span Span 40", Span 60", Span 80, and Span 85". Additional examples of such esters are sorbide monolaurate, sorbide monomyristate, the mannide monoesters of the acids present in distilled coconut oil fatty acids, mannide monostearates, and a mixture of mannitan monostearate, mannide monostearate, mannitan distearate. These esters particularly the monoesters, may be prepared by the methods described in the US Pat. Nos. 3,322,820, and 3,322,821,
to Kenneth R. Brown using as the fatty acid, for example, caproic, caprylic, capric, lauric, myristic, palmitic. oleic, linoleic, linolenic, ricinoleic, stearic, dihydroxy stearic, eleostearic and the like or any mixture thereof, including the fatty acids derived from animal fats and oils and vegtable oils such as lard, sardine oil, whale oil, menhaden oil, coconut oil, soya bean oil, corn oil, olive oil and the like.
2. Polyoxyalkylene derivatives of any one or any mixture of the foregoing hexitol anhydride long chain fatty acid partial esters, particularly the polyoxyethylene derivatives. Examples of such derivatives are polyoxyethylene derivative of sorbitan monolaurate, polyoxyethylene derivative of Sorbitan monopalmitate, polyoxyethylene derivative of sorbitan monostearate, polyoxyethylene derivative of sorbitan trioleate. These polyoxyethylene derivatives are sold by Atlas Powder Company under the tradenames, respectively, Tween 20", Tween 40, Tween 60, Tween and Tween They are prepared, in general, by reacting a long chain fatty acid partial ester of a hexitol anhydride with ethylene oxide or other alkylene oxide in large molar excess. Thus, for example, Tween 80 is formed by reacting about 5 mols of ethylene oxide per mol of sorbitan monooleate and Tween 85 is formed by reacting about 20 mols of ethylene oxide per mol of sorbitan trioleate.
3. Polyoxyalkylene derivatives of a glycol long chain fatty acid monoester, particularly the glycol monoesters of fatty acids having at least 12 carbon atoms such as those set forth above. Particularly effective derivatives are the polyoxyethylene derivatives formed by reacting a large molar excess of ethylene oxide with an ethylene, diethylene, propylene, butylene or triethylene, etc., glycol monoester of a fatty acid having from 12 to 18 carbon atoms. The preferred ones are those formed by reacting 20, 25 and 30 mols, respectively, of ethylene oxide per mol of propylene glycol monostearate. They are sold by Atlas Powder Company under the tradenames, respectively, G-2 l 50", G-2 l 60"and G-2l70". The product G-2l50is most effective.
4. Soaps of aliphatic acids, alkyl aryl sulfonates, alkyl aryl polyether sulfonates, fatty alcohol sulfates, and sulfonated aliphatic compounds.
Examples of suitable anionic emulsifiers include all soaps, potassium laurate, triethanol amine stearate, sodium lauryl sulfate, alkyl polyoxyethylene sulfates, and dioctyl sodium sulfosuccinate.
Other examples of suitable emulsifiers are Neutronyx 600, Triton X-lOO, Ninol 979, and Ethofat 242/20. Others are available. The preferred emulsifier is Promulgen G or D (polyethylene glycol ether complex of higher fatty alcohols).
Ninols are trade-marked products of Ninol Laboratories, Chicago, Illinois, made in accordance with Kritchevsky US. Pat. No. 2,089,212. They are condensation products of one mole of aliphatic monocarboxylic acid with at least two moles of alkylolamine. The compounds are readily dispersible or soluble in water, are stable in mildly acid and alkaline media, and are effective in the presence of calcium and magnesium ions.
The higher fatty acids (six or more carbon atoms) are preferred for the aliphatic radical. One such compound is Ninol 979. It is l00% active, nonionic, pale amber liquid with a specific gravity of 1.00 corresponding to the product of condensing lauric acid with diethanolamine.
Ethofats are trade-marked products of Armour and Company, Chemical Division, Chicago, Illinois. They are a family of fat-derived nonionic surface-active agents. They are polyoxyethylene-glycol esters of fatty acids.
They vary from fluid liquids to soft pastes depending upon length and saturation of the fatty chain and the relative proportion of the polyethylene glycol residue, which factors also control the solubilities.
The polyethylene glycol employed for the material may have have a molecular weight from 220 to 2200. The compounds Neutronyx are a family of trademarked materials made by Onyx Oil Chemical Company, Jersey City 2, New Jersey. They are nonionic surface-active agents, functioning as detergents, emulsifiers and dispersants. They vary from liquids to lowmelting wax-like solids, all dispersible in water. Being nonionic they are compatible with cationic and other nonionic compounds, such as quaternary ammonium compounds. They are stable in mildly acid and alkaline solutions. Chemically, they are ethers the various kinds being designated commercially by a number:
No. 330polyalkylether condensate of fatty acids No. 600-aromatic polyglycol ether, and specifically phenyl ether with polyethylene glycol No. 834polyalkyl ether condensate of fatty acids Neutronyx 600 is miscible in all proportions in water, has specific gravity of about 1, and in a 1% solution in water a pH of 7.3.
The Tritons are trade-marked materials of Rohm and Haas, Philadelphia 5, Pa. They vary from nonionic, to cationic and anionic activity, and are stable in strong acid and alkaline solutions.
The oil phase described above may also include emollients such as a cetyl alcohol, which also functions as a stiffening agent, propylene glycol, glycerine, triethylene glycol, spermaceti or other waxes, perfumes and- /or pharmaceuticals, as well as film formers, deodorants, opacifiers, astrigents, solvents and the like. In addition, stabilizers can be added to enhance the shelf life of the oil phase such has non-ionic surfactants, cellulose derivatives, protein and lecithin. All of the above types of materials are known in the art as additives of cream formulations.
The oil phase impregnated in the article of the invention upon the addition of water thereto, forms a cream or a less viscous lotion. In effect, that portion of the oil phase which comes into contact with moisture becomes emulsified. The phenomena can be described as microemulsificaton, that is emulsification of the oil phase at the point of contact with moisture which point will be that portion of the users skin which contacts the oil phase. Thus, complete emulsification of the entire oil phase impregnated in the article of the invention is avoided with the result that the oil phase impregnant is long lasting and is not exhausted after a single use. Furthermore, if a medicament or pharmaceutical is also incorporated into the oil phase, it will be used up in amounts corresponding to the amount of oil phase emulsified at any one time. Thus, the oil phase carrying the medicament or pharmaceutical can be characterized as a sustained release carrier. The length of time for sustained release of the cream and medicament is regulated by the melting point of the finished solid oil phase formulation, and the ease of emulsification thereof which is controlled by the amount and type of emulsifiers employed. Varying rates of emulsification will be desired depending upon whether the oil phase is impregnated in an article of apparel or an applicator for the cream formulation. For example, where a paper product or applicator is impregnated with the oil phase, a low melting point oil phase formulation will be desired since the paper product will probably be of the one time use-throw-away type, so that rapid and total emulsification is effected during the single use. With this type of product, it is preferred to employ an oily material which is liquid at room temperature as opposed to paraffin or petrolatum.
One of the essential features of the article of the invention is that the oil phase impregnated therein is a dry non-oil non-greasy solid at room temperature. The formulation of such an oil phase impregnant can only be obtained by impregnating the-article or substrate with a non-aqueous homogeneous liquid mixture of the components of the oil phase, such as by spraying the liquid mixture onto the article or substrate or dipping the article or substrate into the liquid oil phase until a desired amount is absorbed therein. Thereafter the article having the oil phase impregnated therein is cooled to cause the oil phase to solidify and form a non-oily dry solid at room temperature.
Generally, in forming the homogeneous liquid mixture forming the oil phase, it will be necessary to heat the components above the melting point of the highest melting component in the mixture so that all solids are reduced to liquid form. This can also be accomplished by mixing with the components of the oil phase nonaqueous solvents, such as acetone, chloroform, trichloroethylene, xylene, xylol, as well as other ketones, chlorinated hydrocarbons and aromatic solvents, with or without heating, to form a homogeneous liquid mixture of all components. The resulting liquid can then be applied to the article or substrate as described above and cooled to form a solid oil phase which has a smooth, non-sticky almost slippery finish.
Where upon cooling and solidification of the oil phase, one or more of the solvents mentioned above does not fomi a solid, these solvents may be easily removed from the remaining solids by, for example, wip ing or expression.
The above process where-in a solvent is employed to cause complete dissolution of the components of the oil phase is desirable where heat is not compatible with the article or substrate to be impregnated. Furthermore, heating is not essential where such solvents are employed.
It is essential that water not be present in the oil phase before emulsification is desired. If water is present during the formation of the homogeneous liquid mixture of the oil phase components, even upon drying over steam over steam rolls and the like, all of the water may not be removed; the result is that upon cooling and attempted solidification of the oil phase components, a tacky sticky product is produced.
The article or substrate treated with the homogeneous liquid mixture of oil phase components will be impregnated or coated with such oil phase depending upon the porosity or absorbability of such article or substrate.
The following are some of the specific applications of the present invention:
1. lmpregnation of the lining of rubber or plastic gloves.
a. Provides cosmetic hand care treatment by merely wearing gloves.
b. Provides lubrication for easier insertion of hands and removal of gloves c. hot hand care treatment by placing hands in hot water such as when doing dishes.
2. impregnation of dress or work glove lining. Provides cold weather hand care treatment and lubrication.
3. Impregnation of glove liner for winter sports such as skiing. in addition to cold weather hand care treatment and lubrication for ease of insertion and removel, the impregnated liner forms an extremely effective thermal barrier.
4. Impregnation of diaper liners and sanitary napkin covers. To prevent or eliminate chafing due to friction.
5. impregnation of tissues and towels, both woven and non-woven fabrics.
a. Cleansing b. Lubricating c. Softening d. Moisturizing e. Protecting In addition, articles or substrates impregnated with the dry non-aqueous oil phase will have long shelf life if kept in a dry cool place since the solid oil phase will not be actuated until addition of moisutre thereto.
The following examples represent preferred embodiments of the present invention.
EXAMPLE 1 About 40 g. light mineral oil, about 40 g. Promulgen- G (that is polyethylene glycol ether complex of higher fatty alcohols produced by Robinson-Wagner) and about g. of cetyl alcohol are heated at a temperature of about 90C while mixing until all solids are dissolved and a homogeneous liquid mixture is formed.
A glove lining is dipped into the mixture for a few seconds until saturated. The glove lining is then removed and allowed to cool at room temperature. The resulting product is found to have a smooth, non-sticky, almost slippery finish comprising the oil phase of a cream formulation.
Where the so treated glove lining is employed as a linear for rubber gloves and the combination employed while washing dishes with hot water, it is found that the perspiration released by the hands causes a light cream coating to form on the hands which is an effective barrier to prevent moisture evaporation from the hands.
EXAMPLE 2 The procedure of Example l is repeated except that an oil phase formulation comprising about g. of Promulgen G (described in Example I) is employed.
EXAMPLE 3 solvent mixture are allowed to dry until a dry non-oily solid oil phase is formed while the tissue remains soft and supple.
The tissue may be employed as a cleansing tissue so that upon application of moisture thereto the oil phase coating is emulsified to form a cleansing cream.
EXAMPLE 4 Following the procedure of Example 1, a tissue was impregnated with a homogeneous liquid mixture comprising 30 g. Tween and 50 g. of heavy mineral oil. The resulting tissue remained soft and supple and may be employed as a cleansing tissue so that upon application of moisture thereto the oil phase impregnated therein emulsifies to form cleansing cream.
EXAMPLE 5 Following the procedure of Example 1, a tissue was impregnated with a homogeneous liquid mixture comprising 30 g. SPAN 80, and 50 g. paraffin. The resulting tissue remained soft and supple and may be employed as a cleansing tissue so that upon applicattion of moisture thereto the oil phase impregnated therein emulsifies to form a cleansing cream.
EXAMPLE 6 Following the procedure of Example 1, a tissue was impregnated with a homogeneous liquid mixture comprising 30 g. Span 80, 50 g. paraffin and 10 g. cetyl alcohol. The resulting tissue remained soft and supple and may be employed as a cleansing tissue so that upon application of moisture thereto the oil phase impregnated therein emulsifies to form a cleansing cream.
What is claimed is:
1. An article to place in contact with the body for use in applying a cosmetic or therapeutic substance to the skin, comprising a substrate and a therapeutic or cosmetic composition carried by said substrate and comprising the oil phase of a cream formulation, said oil phase being a dry emulsifiable solid, which upon addition of moisture thereto forms an oil in water or water in oil emulsion.
2. The article of claim 1 wherein said oil phase comprises an oily material and an emulsifier. 3. The article of claim 2 wherein said oily material is selected from the group consisting of mineral oil, paraffin, petrolatum, vegetable oil, linseed oil, olive oil and isopropyl palmitate.
4. The article of claim 2 wherein said emulsifier is selected from the group consisting of cetyl alcohol, polyethylene glycol ether complexes of higher fatty alcohols, fatty acid soaps of organic bases selected from the group consisting of triethanolamine oleate, triisopropyl amine laurate, monoethyl amine stearate and diethyl amine palmitate, surface active agents selected from the group consisting of long chain fatty acid partial esters of a hexitol anhydride, and a polyoxyalkylene derivative of a long chain fatty acid monoester of a glycol, wherein the fatty acid contains 6 to 18 carbons, soaps of aliphatic acids, alkyl aryl sulfonates, alkyl aryl polyether sulfonates, fatty alcohol sulfates and sulfonated aliphatic compounds.
5. The article of claim 2 wherein said oily material comprises mineral oil and said emulsifier comprises a polyethylene glycol ether complex of higher alcohols.
6. The article of claim 5 wherein said oil phase further includes cetyl alcohol.
7. The article of claim 2 wherein said oil phase comprises, in addition one or more emollients, dyes, perfumes and/or pharmaceuticals.
8. The article of claim 1 wherein said substrate com prises a woven or non-woven material.
9. The article of claim 1 wherein said substrate comprises a tissue.
10. The article of claim 1 wherein said substrate comprises a face mask.
11. The article of claim 1 wherein said substrate comprises a shoe.
12. The article of claim 1 wherein said substrate comprises a foot slipper.
13. The article of claim 1 wherein said substrate comprises a diaper.
14. The article of claim 1 wherein said substrate comprises a bandage.
15. The article of claim 1 wherein said substrate comprises a glove.
16. The article of claim 1 wherein said substrate comprises a diaper liner.
17. The article of claim 1 wherein said substrate comprises a sanitary napkin.
18. The article of claim 1 wherein said substrate is a paper tissue.
19. The article of claim 1 wherein said substrate is a towel.
20. The article of claim 1 wherein said substrate is a paper towel.
21. A method of manufacturing an article for use in Ill applying a therapeutic or cosmetic substance to the skin, comprising providing a substrate and a therapeutic or cosmetic composition carried by said substrate, said composition comprising the oil phase of a cream formulation in the form of a dry solid, said solid com-v prising an oily material and one or more emulsifiers, wherein said therapeutic or cosmetic composition is formed by mixing together the oily material and emulsifiers while each material is in a liquid state to form a non-aqueous substantially homogeneous mixture, and while said mixture is in liquid form, applying the mixture to the substrate, and converting the mixture to a non-oily solid.
22. The method in accordance with claim 21 wherein the oily material and emulsifiers are heated to form an all liquid mixture.
23. The method in accordance with claim 22 wherein the liquid mixture is converted to a solid by cooling.
24. The method in accordance with claim 21 wherein the oily material and emulsifiers are mixed together in the presence of a solvent causes the oily material and emulsifiers to form a liquid mixture.
25. The method in accordance with claim 24 wherein the liquid mixture of the oily material and emulsifiers is converted to a solid by removing the solvent from the mixture.
26. The method of claim 22 wherein the oily material and emulsifiers are heated to at least the melting point of the highest melting component.
. UNITED STATES PATENT OFFICE CERTIFlCATE OF CORRECTLEON Patent No. ,807 Dated July 29, 1975 Inventor(s) GILBERT BUCHALTER It is certified that error appears in the above-identified patent and that said Letters Patent are hereby corrected as shown below:
Column 1, Line 29 "3,489,884" should read: 3,489,148
Column 1, Line'38, "may e" should read: may be Column 2, Line 51, "Where the article of the invention" should read: Where the article of apparel of the invention Column 10, Line 21, insert "which" between "solvent" and "causes".
Signed and Scaled-this 0 eleventh Day of November 1975 [SEAL] Attest:
C RUTH c. MASON c. MARSHALL DANN Arresting Officer (mnmisximwr of Patents um! Trademarks FORM PC4050 (10-59) UStOMM-fiC teams-1
|Patente citada||Fecha de presentación||Fecha de publicación||Solicitante||Título|
|US2653601 *||16 Nov 1950||29 Sep 1953||Morrison Elizabeth M||Glove|
|US2664087 *||16 Ago 1950||29 Dic 1953||John J Lawler||Medicinal slipper|
|US2671446 *||28 Oct 1952||9 Mar 1954||Mann Ann S V||Beauty mask|
|US2685086 *||12 Jun 1953||3 Ago 1954||Gifford H Henry||Underarm antiseptic deodorant pad|
|US2765789 *||8 Oct 1952||9 Oct 1956||Schmierer Helen L||Eyeshade applicator|
|US2804424 *||24 Abr 1951||27 Ago 1957||American Cyanamid Co||Method of preparing a tetracycline type antibiotic-containing wound dressing|
|US2804425 *||2 Jul 1952||27 Ago 1957||American Cyanamid Co||Chlortetracycline gauze and method for production|
|US3328259 *||8 Ene 1964||27 Jun 1967||Parachem Corp||Dressing for a wound containing a hemostatic agent and method of treating a wound|
|US3490454 *||21 Oct 1966||20 Ene 1970||United Merchants & Mfg||Catamenial products having a coating of rupturable microcapsules containing medicants|
|Patente citante||Fecha de presentación||Fecha de publicación||Solicitante||Título|
|US4112167 *||7 Ene 1977||5 Sep 1978||The Procter & Gamble Company||Skin cleansing product having low density wiping zone treated with a lipophilic cleansing emollient|
|US4263363 *||20 Dic 1979||21 Abr 1981||Colgate-Palmolive Company||Emulsion-containing absorbent article having improved water holding capacity|
|US4344930 *||15 Sep 1980||17 Ago 1982||Colgate-Palmolive Company||Skin care sponge|
|US4367227 *||26 Dic 1978||4 Ene 1983||Lever Brothers Company||Method and cosmetic composition for reducing sebum secretion|
|US4481243 *||5 Ene 1984||6 Nov 1984||The Procter & Gamble Company||Pattern treated tissue paper product|
|US4513051 *||5 Ene 1984||23 Abr 1985||The Procter & Gamble Company||Tissue paper product|
|US4543247 *||6 Ene 1983||24 Sep 1985||Bayer Aktiengesellschaft||Ectoparasiticide-containing collars for pets|
|US4544547 *||14 Mar 1983||1 Oct 1985||Bayer Aktiengesellschaft||Ectoparasiticide-containing polyurethanes|
|US4634436 *||5 Jul 1983||6 Ene 1987||Tour June T||Method for making a body wrap composition|
|US4690821 *||28 Mar 1986||1 Sep 1987||Creative Products Resource Associates, Ltd.||Towel for skin moisturizing and drying|
|US4775372 *||27 Mar 1987||4 Oct 1988||Wilberg Janice L||Device for application of liquids to surface of hands|
|US4853978 *||24 Jul 1987||8 Ago 1989||Surgikos, Inc.||Antimicrobial medical glove|
|US5073365 *||1 Jun 1989||17 Dic 1991||Advanced Polymer Systems||Clinical and personal care articles enhanced by lubricants and adjuvants|
|US5089205 *||25 Sep 1989||18 Feb 1992||Becton, Dickinson And Company||Process for producing medical devices having antimicrobial properties|
|US5156843 *||20 Mar 1989||20 Oct 1992||Advanced Polymer Systems, Inc.||Fabric impregnated with functional substances for controlled release|
|US5219340 *||23 Jul 1991||15 Jun 1993||Elaine Seneca||Colloidal oatmeal solution applicator|
|US5281186 *||26 Ene 1993||25 Ene 1994||Buckley Caroline M||Protective breast cup arrangement|
|US5525345 *||6 Mar 1995||11 Jun 1996||The Proctor & Gamble Company||Lotion composition for imparting soft, lubricious feel to tissue paper|
|US5538732 *||12 Abr 1994||23 Jul 1996||Creative Products Resource, Inc.||Medicated applicator sheet for topical drug delivery|
|US5552020 *||21 Jul 1995||3 Sep 1996||Kimberly-Clark Corporation||Tissue products containing softeners and silicone glycol|
|US5558873 *||8 Mar 1995||24 Sep 1996||Kimberly-Clark Corporation||Soft tissue containing glycerin and quaternary ammonium compounds|
|US5601871 *||6 Feb 1995||11 Feb 1997||Krzysik; Duane G.||Soft treated uncreped throughdried tissue|
|US5607081 *||21 Sep 1994||4 Mar 1997||Levy; David||Cleaning assembly|
|US5607760 *||3 Ago 1995||4 Mar 1997||The Procter & Gamble Company||Disposable absorbent article having a lotioned topsheet containing an emollient and a polyol polyester immobilizing agent|
|US5609587 *||3 Ago 1995||11 Mar 1997||The Procter & Gamble Company||Diaper having a lotioned topsheet comprising a liquid polyol polyester emollient and an immobilizing agent|
|US5614202 *||17 May 1994||25 Mar 1997||Defina; Linda E.||Moisturizing glove|
|US5614293 *||19 Mar 1996||25 Mar 1997||Kimberly-Clark Corporation||Soft treated uncreped throughdried tissue|
|US5624676 *||3 Ago 1995||29 Abr 1997||The Procter & Gamble Company||Lotioned tissue paper containing an emollient and a polyol polyester immobilizing agent|
|US5635191 *||28 Nov 1994||3 Jun 1997||The Procter & Gamble Company||Diaper having a lotioned topsheet containing a polysiloxane emollient|
|US5643588 *||28 Nov 1994||1 Jul 1997||The Procter & Gamble Company||Diaper having a lotioned topsheet|
|US5650218 *||16 Abr 1996||22 Jul 1997||Kimberly-Clark Corporation||Soft treated tissue|
|US5665426 *||6 Feb 1995||9 Sep 1997||Kimberly-Clark Corporation||Soft treated tissue|
|US5702380 *||23 Feb 1996||30 Dic 1997||Walker; Rosemary||Sanitary napkin|
|US5705164 *||3 Ago 1995||6 Ene 1998||The Procter & Gamble Company||Lotioned tissue paper containing a liquid polyol polyester emollient and an immobilizing agent|
|US5716692 *||28 Feb 1996||10 Feb 1998||The Procter & Gamble Co.||Lotioned tissue paper|
|US5720966 *||17 Ene 1996||24 Feb 1998||The Procter & Gamble Company||Medicated tissue paper product|
|US5730839 *||21 Jul 1995||24 Mar 1998||Kimberly-Clark Worldwide, Inc.||Method of creping tissue webs containing a softener using a closed creping pocket|
|US5756112 *||14 Ene 1997||26 May 1998||The Procter & Gamble Company||Carrier substrate treated with high internal water phase inverse emulsion made with an organopolysiloxane-polyoxyalkylene emulsifier|
|US5763332 *||5 Dic 1996||9 Jun 1998||The Procter & Gamble Company||Cleaning articles comprising a polarphobic region and a high internal phase inverse emulsion|
|US5863663 *||5 Dic 1996||26 Ene 1999||The Procter & Gamble Company||Wet-like cleaning wipes and like articles comprising a carrier treated with an emulsion having a continuous lipid phase|
|US5871763 *||24 Abr 1997||16 Feb 1999||Fort James Corporation||Substrate treated with lotion|
|US5885697 *||12 Dic 1997||23 Mar 1999||Kimberly-Clark Worldwide, Inc.||Soft treated tissue|
|US5908707 *||5 Dic 1996||1 Jun 1999||The Procter & Gamble Company||Cleaning articles comprising a high internal phase inverse emulsion and a carrier with controlled absorbency|
|US5922336 *||27 Dic 1996||13 Jul 1999||Deotexix Inc.||Microcapsule-coated material|
|US5938649 *||9 May 1997||17 Ago 1999||Drypers Corporation||Absorbent articles with improved rash-preventing properties|
|US5941864 *||26 Ago 1997||24 Ago 1999||The Procter & Gamble Company||Disposable absorbent article having improved fecal storage|
|US5944705 *||4 Sep 1997||31 Ago 1999||Drypers Corporation||Absorbent articles with improved rash-preventing properties|
|US5948540 *||30 Abr 1997||7 Sep 1999||The Procter & Gamble Company||Carrier substrate treated with high internal phase inverse emulsions made with an organopolysiloxane-polyoxyalkylene emulsifier|
|US5951991 *||26 Nov 1997||14 Sep 1999||The Procter & Gamble Company||Cleansing products with improved moisturization|
|US5952043 *||25 Ago 1998||14 Sep 1999||The Procter & Gamble Company||Process for making wet-like cleaning wipes and like articles comprising an emulsion having a continuous lipid phase|
|US5957906 *||14 Nov 1997||28 Sep 1999||The Procter & Gamble Company||Diaper with improved feces management properties|
|US5968025 *||27 Jun 1997||19 Oct 1999||The Procter & Gamble Company||Absorbent article having a lotioned topsheet|
|US5972361 *||25 Oct 1996||26 Oct 1999||The Procter & Gamble Company||Cleansing products|
|US5977430 *||14 Nov 1997||2 Nov 1999||The Procter & Gamble Company||Absorbent article with macro-particulate storage structure|
|US5980919 *||10 Nov 1997||9 Nov 1999||Potlatch Corporation||Emollient compositions and methods of application to a substrate by electrostatic spraying|
|US5980922 *||5 Dic 1996||9 Nov 1999||Procter & Gamble Company||Cleaning articles treated with a high internal phase inverse emulsion|
|US5980931 *||19 Nov 1997||9 Nov 1999||The Procter & Gamble Company||Cleansing products having a substantially dry substrate|
|US6001381 *||7 Ene 1998||14 Dic 1999||The Procter & Gamble Company||Cleaning articles comprising a polarphobic region and a high internal phase inverse emulsion|
|US6010491 *||17 Mar 1999||4 Ene 2000||The Procter & Gamble Company||Viscous fluid bodily waste management article|
|US6013063 *||14 Nov 1997||11 Ene 2000||The Procter & Gamble Company||Viscous fluid bodily waste management article|
|US6063397 *||25 Oct 1996||16 May 2000||The Procter & Gamble Company||Disposable cleansing products for hair and skin|
|US6074655 *||8 Feb 1999||13 Jun 2000||The Procter & Gamble Company||Cleansing products|
|US6107537 *||10 Sep 1997||22 Ago 2000||The Procter & Gamble Company||Disposable absorbent articles providing a skin condition benefit|
|US6117119 *||28 Ago 1998||12 Sep 2000||Silipos, Inc.||Gelatinous body protection article having a therapeutic additive|
|US6118041 *||27 Jun 1997||12 Sep 2000||The Procter & Gamble Company||Diaper having a lotioned topsheet|
|US6120488 *||31 Oct 1997||19 Sep 2000||The Procter & Gamble Company||Absorbent articles having cuffs and topsheet with skin care composition(s) disposed thereon|
|US6120783 *||31 Oct 1997||19 Sep 2000||The Procter & Gamble Company||Web materials with two or more skin care compositions disposed thereon and articles made therefrom|
|US6121165 *||23 Jul 1998||19 Sep 2000||The Procter & Gamble Company||Wet-like cleaning articles|
|US6132746 *||22 May 1997||17 Oct 2000||The Procter & Gamble Company||Cleansing products with improved moisturization|
|US6133166 *||1 Jul 1997||17 Oct 2000||The Procter & Gamble Company||Cleaning articles comprising a cellulosic fibrous structure having discrete basis weight regions treated with a high internal phase inverse emulsion|
|US6136775 *||18 Dic 1998||24 Oct 2000||Kimberly-Clark Worldwide, Inc.||Wet wipe with non-aqueous, oil-based solvent for industrial cleaning|
|US6149934 *||23 Abr 1999||21 Nov 2000||Kimberly-Clark Worldwide, Inc.||Absorbent article having a lotionized bodyside liner|
|US6153208 *||11 Sep 1998||28 Nov 2000||The Procter & Gamble Company||Cleansing and conditioning article for skin or hair|
|US6153209 *||28 Sep 1999||28 Nov 2000||The Procter & Gamble Company||Article having a transferable breathable skin care composition thereon|
|US6156020 *||14 Oct 1998||5 Dic 2000||The Procter & Gamble Company||Absorbent article with micro-particulate storage member|
|US6156024 *||3 Dic 1996||5 Dic 2000||The Procter & Gamble Company||Absorbent articles having lotioned leg cuffs|
|US6156157 *||21 Abr 1997||5 Dic 2000||Kimberly-Clark Worldwide, Inc.||Method for making soft tissue with improved bulk softness and surface softness|
|US6166285 *||31 Oct 1997||26 Dic 2000||The Procter & Gamble Company||Absorbent articles having cuffs with skin care composition disposed thereon|
|US6186992||26 Jul 1999||13 Feb 2001||The Procter & Gamble Company||Viscous fluid bodily waste management article|
|US6187695||8 Dic 1998||13 Feb 2001||Kimberly-Clark Worldwide, Inc.||Cool feeling tissue product and method|
|US6190678||4 Sep 1998||20 Feb 2001||The Procter & Gamble Company||Cleansing and conditioning products for skin or hair with improved deposition of conditioning ingredients|
|US6217707||19 Dic 1997||17 Abr 2001||Kimberly-Clark Worldwide, Inc.||Controlled coverage additive application|
|US6217889||19 Nov 1999||17 Abr 2001||The Proctor & Gamble Company||Personal care articles|
|US6231719||19 Dic 1997||15 May 2001||Kimberly-Clark Worldwide, Inc.||Uncreped throughdried tissue with controlled coverage additive|
|US6261580||31 Ago 1998||17 Jul 2001||The Procter & Gamble Company||Tissue paper with enhanced lotion transfer|
|US6267975||19 Nov 1999||31 Jul 2001||The Procter & Gamble Company||Personal care articles|
|US6280757||25 May 1999||28 Ago 2001||The Procter & Gamble Company||Cleansing articles for skin or hair|
|US6287581 *||24 Ago 1999||11 Sep 2001||Kimberly-Clark Worldwide, Inc.||Absorbent articles providing skin health benefits|
|US6296936||30 Ene 1998||2 Oct 2001||Kimberly-Clark Worldwide, Inc.||Coform material having improved fluid handling and method for producing|
|US6300258||27 Ago 1999||9 Oct 2001||Kimberly-Clark Worldwide, Inc.||Nonwovens treated with surfactants having high polydispersities|
|US6322801||19 Nov 1999||27 Nov 2001||The Procter & Gamble Company||Personal care articles|
|US6338855||22 Abr 1999||15 Ene 2002||The Procter & Gamble Company||Cleansing articles for skin and/or hair which also deposit skin care actives|
|US6352745||27 Oct 1999||5 Mar 2002||Playtex Products, Inc.||Method of making fragranced gloves|
|US6428794 *||20 Sep 1995||6 Ago 2002||The Procter & Gamble Company||Lotion composition for treating tissue paper|
|US6440437||24 Ene 2000||27 Ago 2002||Kimberly-Clark Worldwide, Inc.||Wet wipes having skin health benefits|
|US6475197||24 Ago 1999||5 Nov 2002||Kimberly-Clark Worldwide, Inc.||Absorbent articles having skin health benefits|
|US6476288 *||22 Feb 2000||5 Nov 2002||The Procter & Gamble Company||Absorbent articles having cuffs and topsheet with skin care composition(s) disposed thereon|
|US6491928||19 Ene 2000||10 Dic 2002||The Procter & Gamble Company||Water-flux limiting cleansing articles|
|US6491933||16 Feb 2001||10 Dic 2002||The Procter & Gamble Company||Personal care articles comprising hotmelt compositions|
|US6495151||18 Jun 2001||17 Dic 2002||The Procter & Gamble Company||Cleansing articles for skin or hair|
|US6498284||14 Nov 1997||24 Dic 2002||The Procter & Gamble Company||Disposable absorbent article with a skin care composition on an apertured top sheet|
|US6503526||20 Oct 2000||7 Ene 2003||Kimberly-Clark Worldwide, Inc.||Absorbent articles enhancing skin barrier function|
|US6515029||23 Abr 1999||4 Feb 2003||Kimberly-Clark Worldwide, Inc.||Absorbent article having a hydrophilic lotionized bodyside liner|
|US6534074||8 Feb 2001||18 Mar 2003||Kimberly-Clark Worldwide, Inc.||Absorbent articles providing skin health benefits|
|US6570054||2 May 2000||27 May 2003||The Procter & Gamble Company||Absorbent article having a stable skin care composition|
|US6586652 *||24 Jun 1999||1 Jul 2003||The Procter & Gamble Company||Absorbent article having a lotioned topsheet|
|US6616641||29 Nov 2001||9 Sep 2003||Unilever Home & Personal Care Usa, Division Of Conopco, Inc.||Impregnated matrix and method for making same|
|US6623746||7 Jul 1999||23 Sep 2003||Cognis Deutschland Gmbh & Co. Kg||PIT emulsions, methods of softening paper using the same, and paper substrates treated therewith|
|US6627787 *||20 Jul 1999||30 Sep 2003||The Procter & Gamble Company||Diaper having a lotioned topsheet|
|US6673054||1 Sep 2000||6 Ene 2004||Silipos Inc.||Body protection article having a gelatinous material with a therapeutic additive|
|US6673984||28 Ago 2000||6 Ene 2004||The Procter & Gamble Company||Absorbent article with macro-particulate storage member|
|US6689932||21 Dic 2001||10 Feb 2004||Kimberly-Clark Worldwide, Inc.||Absorbent articles with simplified compositions having good stability|
|US6703536||18 Dic 2002||9 Mar 2004||The Procter & Gamble Company||Disposable absorbent article having a skin care composition containing an enzyme inhibitor|
|US6703537||14 Oct 1998||9 Mar 2004||The Procter & Gamble Company||Absorbent article having improved fecal storage structure|
|US6716441||17 Dic 1999||6 Abr 2004||The Procter & Gamble Company||Compositions for efficient release of active ingredients|
|US6730380||11 Ago 1998||4 May 2004||Safeskin Corp.||Readily-donned elastomeric articles|
|US6749860||22 Dic 2000||15 Jun 2004||Kimberly-Clark Worldwide, Inc.||Absorbent articles with non-aqueous compositions containing botanicals|
|US6756520||20 Oct 2000||29 Jun 2004||Kimberly-Clark Worldwide, Inc.||Hydrophilic compositions for use on absorbent articles to enhance skin barrier|
|US6792701 *||26 Mar 2003||21 Sep 2004||Linda Ruffini||Footwear product for therapeutically treating the skin|
|US6793930||16 Abr 2003||21 Sep 2004||The Procter & Gamble Company||Absorbent article having a stable skin care composition|
|US6797400||30 Mar 2001||28 Sep 2004||Cognis Deutschland Gmbh & Co. Kg||Moist wipes (II)|
|US6803496||10 Sep 1997||12 Oct 2004||The Procter & Gamble Company||Method for maintaining or improving skin health|
|US6825393||12 Mar 2003||30 Nov 2004||The Procter & Gamble Company||Absorbent article having a lotioned topsheet|
|US6860967||22 Ene 2002||1 Mar 2005||Sca Hygiene Products Gmbh||Tissue paper penetrated with softening lotion|
|US6861571||8 Ago 1997||1 Mar 2005||The Procter & Gamble Company||Article having a lotioned topsheet|
|US6881207 *||30 Jun 1998||19 Abr 2005||Rhonda Tracy||Disposable diaper with padded waistband and legholes|
|US6896667 *||27 Feb 2003||24 May 2005||Linda A. Carter||Foot and hand treatment system|
|US6905697||22 Ene 2002||14 Jun 2005||Sca Hygiene Products Gmbh||Lotioned fibrous web having a short water absorption time|
|US6953582||1 Jul 2002||11 Oct 2005||Sheh Wei (Usa), Inc.||Skin-enhancing glove and method of manufacture|
|US6955817||6 Sep 2002||18 Oct 2005||The Procter & Gamble Company||Cleansing articles for skin or hair|
|US6972010 *||17 Oct 2003||6 Dic 2005||The Procter & Gamble Company||Absorbent article comprising an agent able to convey a perception to the wearer, without the need to create the external condition perceived|
|US7003804||10 Dic 2003||28 Feb 2006||Kimberly-Clark Worldwide, Inc.||Surgical gown incorporating a skin wellness agent|
|US7005453||18 Sep 2000||28 Feb 2006||Miller Brewing Company||Use of hop acids to inhibit growth of Staphylococcus aureus and prevent toxic shock syndrome|
|US7005557||3 Jul 2001||28 Feb 2006||The Procter & Gamble Company||Film-forming compositions for protecting skin from body fluids and articles made therefrom|
|US7033645||13 May 2004||25 Abr 2006||The Procter & Gamble Company||Process for applying a stable skin care composition to a substrate|
|US7115535||19 Nov 1999||3 Oct 2006||The Procter & Gamble Company||Personal care articles comprising batting|
|US7115551||3 Jun 2003||3 Oct 2006||The Procter & Gamble Company||Cleansing articles for skin or hair|
|US7166292||29 Jun 2001||23 Ene 2007||The Procter & Gamble Company||Top-biased beneficial components on substrates|
|US7195771||21 Nov 2000||27 Mar 2007||Kimberly-Clark Worldwide, Inc.||Water-soluble lotions for paper products|
|US7320436||27 Feb 2004||22 Ene 2008||Sca Hygiene Products Ab||Method of producing an absorbent article and an absorbent article produced according to the method|
|US7348018||18 Nov 2004||25 Mar 2008||The Procter & Gamble Company||Methods of cleansing skin or hair with cleansing articles|
|US7423003||14 Ago 2001||9 Sep 2008||The Procter & Gamble Company||Fold-resistant cleaning sheet|
|US7427412 *||21 Jun 2000||23 Sep 2008||Color Access, Inc.||Gel-based cosmetic composition|
|US7452547||31 Mar 2004||18 Nov 2008||Johnson&Johnson Consumer Co., Inc.||Product for treating the skin comprising a polyamine microcapsule wall and a skin lightening agent|
|US7485373||11 Sep 2003||3 Feb 2009||Kimberly-Clark Worldwide, Inc.||Lotioned tissue product with improved stability|
|US7509689 *||2 Jun 2006||31 Mar 2009||Reardon Timothy A||Bathing poncho|
|US7547443||11 Sep 2003||16 Jun 2009||Kimberly-Clark Worldwide, Inc.||Skin care topical ointment|
|US7771735||3 Abr 2003||10 Ago 2010||Kimberly-Clark Worldwide, Inc.||Absorbent articles with compositions for reducing irritation response|
|US7772455||29 Jun 1999||10 Ago 2010||The Procter & Gamble Company||Disposable article providing improved management of bodily exudates|
|US7850821 *||24 Ago 2005||14 Dic 2010||Daio Paper Corporation||Household thin paper|
|US7851668||21 Jun 2006||14 Dic 2010||The Procter & Gamble Company||Absorbent article and method for maintaining or improving skin health|
|US7867510||7 Sep 2006||11 Ene 2011||BioLargo Life Technologies, Inc||Material having antimicrobial activity when wet|
|US7879915||29 Nov 2007||1 Feb 2011||Cognis Ip Management Gmbh||Emulsions for finishing textiles and paper|
|US7935859||15 Ene 2004||3 May 2011||The Procter & Gamble Company||Article having improved fecal storage structure|
|US7971276 *||1 Dic 2005||5 Jul 2011||Ansell Healthcare Products, Llc||Glove with hand-friendly coating and method of making|
|US7972475 *||9 Ene 2009||5 Jul 2011||The Procter & Gamble Company||Soft tissue paper having a polyhydroxy compound and lotion applied onto a surface thereof|
|US7988983||13 Sep 2002||2 Ago 2011||Ansell Healthcare Products Llc||Microencapsulation coating for gloves|
|US8044256||3 Mar 2009||25 Oct 2011||The Procter And Gamble Company||Absorbent article having a stable skin care composition|
|US8053626 *||11 Jun 2003||8 Nov 2011||Sca Hygiene Products Ab||Absorbent article containing a skincare composition and method of making and using same|
|US8138388||16 Nov 2010||20 Mar 2012||The Procter & Gamble Company||Absorbent article and method for maintaining or improving skin health|
|US8156947||2 Feb 2010||17 Abr 2012||Deanne Viola||Method and apparatus for pedicure foot health protection|
|US8226964||18 Ene 2008||24 Jul 2012||Biolargo Life Technologies, Inc.||Systems and methods for cleaning liquid carriers related applications data|
|US8273367||17 Oct 2003||25 Sep 2012||The Procter And Gamble Company||Articles comprising a mint odor-free cooling agent|
|US8309788||23 Ene 2009||13 Nov 2012||The Procter And Gamble Company||Protease inhibitors in absorbent articles|
|US8378168||29 Ene 2004||19 Feb 2013||The Procter And Gamble Company||Article having a lotioned topsheet|
|US8420883||22 Nov 2011||16 Abr 2013||The Procter & Gamble Company||Absorbent article and method for maintaining or improving skin health|
|US8545861||22 Dic 2004||1 Oct 2013||Sca Hygiene Products Gmbh||Lotioned fibrous web having a short water absorption time|
|US8569568||24 Mar 2011||29 Oct 2013||The Procter & Gamble Company||Article having improved fecal storage structure|
|US8574610||10 Ene 2011||5 Nov 2013||Biolargo Life Technologies, Inc.||Material having antimicrobial activity when wet|
|US8580882||12 Ago 2010||12 Nov 2013||Joesph L. Barnes||Glove-forming solution|
|US8632793||17 Ene 2007||21 Ene 2014||The Procter & Gamble Company||Top-biased beneficial components on substrates|
|US8642645||30 Ene 2012||4 Feb 2014||Brooks Kelly Research, LLC.||Pharmaceutical composition comprising Cannabinoids|
|US8795716||18 Nov 2004||5 Ago 2014||The Procter & Gamble Company||Skin care compositions on a thin sanitary napkin|
|US8907154||8 Mar 2013||9 Dic 2014||The Procter & Gamble Company||Sanitary napkins with hydrophobic lotions|
|US8981177||6 Jul 2010||17 Mar 2015||The Procter & Gamble Company||Disposable article providing improved management of bodily exudates|
|US9035123||1 Oct 2002||19 May 2015||The Procter & Gamble Company||Absorbent article having a lotioned topsheet|
|US9393197||24 Jun 2013||19 Jul 2016||Kimberly-Clark Worldwide, Inc.||Stable emulsion for prevention of skin irritation and articles using same|
|US9414601||24 Jul 2008||16 Ago 2016||Biolargo Life Technologies, Incorporated||Material having antimicrobial activity when wet|
|US9511006||21 Jun 2013||6 Dic 2016||Kimberly-Clark Worldwide, Inc.||Dispersible moist wipe with emulsion for prevention of skin irritation|
|US20020120241 *||22 Dic 2000||29 Ago 2002||Tyrrell David John||Absorbent articles with hydrophilic compositions containing anionic polymers|
|US20020120242 *||22 Dic 2000||29 Ago 2002||Tyrrell David John||Absorbent articles with hydrophilic compositions containing botanicals|
|US20020128615 *||22 Dic 2000||12 Sep 2002||Tyrrell David John||Absorbent articles with non-aqueous compositions containing anionic polymers|
|US20020146561 *||22 Ene 2002||10 Oct 2002||Guido Baumoller||Lotioned fibrous web having a short water absorption time|
|US20020147433 *||29 Ene 2002||10 Oct 2002||Mcosker Jocelyn Elaine||Proton donating actives in absorbent articles|
|US20020148583 *||22 Ene 2002||17 Oct 2002||Guido Baumoller||Tissue paper penetrated with softening lotion|
|US20020165508 *||22 Ene 2002||7 Nov 2002||Klofta Thomas James||Absorbent article having a stable skin care composition|
|US20030017193 *||1 Jul 2002||23 Ene 2003||Chou Belle L.||Skin-enhancing glove and method of manufacture|
|US20030031703 *||7 Ago 2001||13 Feb 2003||Mcmeekin Linda J.||Textured article|
|US20030035824 *||29 Jun 2001||20 Feb 2003||The Procter & Gamble Company||Top-biased beneficial components on substrates|
|US20030077307 *||3 Jul 2001||24 Abr 2003||The Procter & Gamble Company||Film-forming compositions for protecting skin from body fluids and articles made therefrom|
|US20030077962 *||28 May 2002||24 Abr 2003||Krzysik Duane Gerard||Absorbent tissues providing skin barrier enhancement|
|US20030113364 *||6 Sep 2002||19 Jun 2003||The Procter & Gamble Company||Cleansing articles for skin or hair|
|US20030130636 *||22 Dic 2001||10 Jul 2003||Brock Earl David||System for improving skin health of absorbent article wearers|
|US20030171724 *||27 Feb 2003||11 Sep 2003||Carter Linda A.||Foot and hand treatment system|
|US20030194425 *||15 Jul 2002||16 Oct 2003||L'oreal||Moist cleansing, skin care or cosmetic article|
|US20030204893 *||2 May 2002||6 Nov 2003||Chou Belle L.||Elastomeric flexible article and manufacturing method|
|US20030206943 *||23 May 2003||6 Nov 2003||The Procter & Gamble Company||Sanitary napkins with hydrophobic lotions|
|US20030206979 *||3 Abr 2003||6 Nov 2003||Kimberly-Clark Worldwide, Inc.||Absorbent articles with compositions for reducing irritation response|
|US20030207632 *||3 May 2002||6 Nov 2003||Brooks Joann Adele||Disposable washcloth article and a method of making and using the washcloth|
|US20030228351 *||3 Jun 2003||11 Dic 2003||The Procter & Gamble Company||Cleansing articles for skin or hair|
|US20030228352 *||3 Jun 2003||11 Dic 2003||The Procter & Gamble Company||Cleansing articles for skin or hair|
|US20040024374 *||11 Jun 2003||5 Feb 2004||Madeleine Hjorth||Absorbent article containing a skincare composition and method of making and using same|
|US20040064117 *||1 Oct 2002||1 Abr 2004||The Procter & Gamble Company||Absorbent article having a lotioned topsheet|
|US20040081680 *||17 Oct 2003||29 Abr 2004||The Procter & Gamble Company||Articles comprising a mint odor-free cooling agent|
|US20040082654 *||17 Oct 2003||29 Abr 2004||The Procter & Gamble Company||Cooling compositons|
|US20040082928 *||17 Oct 2003||29 Abr 2004||The Procter & Gamble Company||Absorbent article comprising an agent able to convey a perception to the wearer, without the need to create the external condition perceived|
|US20040091519 *||5 Nov 2003||13 May 2004||Samuel Amdur||Disposable gloves with allatoin|
|US20040091520 *||5 Nov 2003||13 May 2004||Samuel Amdur||Disposable gloves with at least one alpha hydroxy acid|
|US20040122382 *||23 Dic 2002||24 Jun 2004||Kimberly-Clark Worldwide, Inc.||Elastomeric articles with beneficial coating on a surface|
|US20040167479 *||20 Feb 2003||26 Ago 2004||The Procter & Gamble Company||Hemorrhoid treatment pad|
|US20040170589 *||27 Feb 2004||2 Sep 2004||Gatto Joseph Anthony||Sanitary napkins with hydrophobic lotions|
|US20040175343 *||19 Mar 2004||9 Sep 2004||The Procter & Gamble Company||Compositions for efficient release of active ingredients|
|US20040193126 *||29 Ene 2004||30 Sep 2004||The Procter & Gamble Company||Article having a lotioned topsheet|
|US20040199136 *||29 Ene 2004||7 Oct 2004||Roe Donald Carroll||Article having a lotioned topsheet|
|US20040208984 *||13 May 2004||21 Oct 2004||The Procter & Gamble Company||Process for applying a stable skin care composition to a substrate|
|US20040227008 *||27 Feb 2004||18 Nov 2004||Sca Hygiene Products Ab||Method of producing an absorbent article and an absorbent article produced according to the method|
|US20050031817 *||7 Ago 2003||10 Feb 2005||Littleton Kermit R.||Readily donned, powder-free elastomeric article|
|US20050031847 *||12 Jul 2002||10 Feb 2005||Nicholas Martens||Products comprising a sheet and a lipid and aqueous phase|
|US20050058669 *||11 Sep 2003||17 Mar 2005||Kimberly-Clark Worldwide, Inc.||Skin care topical ointment|
|US20050058833 *||11 Sep 2003||17 Mar 2005||Kimberly-Clark Worldwide, Inc.||Lotioned tissue product with improved stability|
|US20050059941 *||11 Sep 2003||17 Mar 2005||Kimberly-Clark Worldwide, Inc.||Absorbent product with improved liner treatment|
|US20050066414 *||13 Sep 2002||31 Mar 2005||Yu E. Anthony||Microencapsulation coating for gloves|
|US20050074484 *||7 Oct 2003||7 Abr 2005||Estanislao Roderico B.||Product for administration of active agents to different areas of the skin|
|US20050075255 *||18 Nov 2004||7 Abr 2005||The Procter & Gamble Company||Methods of cleansing skin or hair with cleansing articles|
|US20050100573 *||22 Dic 2004||12 May 2005||Sca Hygiene Products Gmbh||Lotioned fibrous web having a short water absorption time|
|US20050112180 *||22 Nov 2003||26 May 2005||Chou Belle L.||Antimicrobial elastomeric flexible article and manufacturing method|
|US20050125873 *||10 Dic 2003||16 Jun 2005||Kimberly-Clark Worldwide, Inc.||Surgical gown incorporating a skin wellness agent|
|US20050129651 *||18 Nov 2004||16 Jun 2005||Gatto Joseph A.||Sanitary napkins with hydrophobic lotions|
|US20050136531 *||17 Dic 2003||23 Jun 2005||Kimberly-Clark Worldwide, Inc.||Folded substrate with applied chemistry|
|US20050148962 *||18 Nov 2004||7 Jul 2005||Raphael Warren||Skin care compositions on a thin sanitary napkin|
|US20050203473 *||14 Abr 2005||15 Sep 2005||The Procter & Gamble Company||Absorbent article comprising an agent able to convey a perception to the wearer, without the need to create the external condition perceived|
|US20050208112 *||17 May 2005||22 Sep 2005||The Procter & Gamble Company||Article having a lotioned topsheet|
|US20050226834 *||31 Mar 2004||13 Oct 2005||Danilo Lambino||Product for treating the skin|
|US20050228328 *||7 Jun 2005||13 Oct 2005||Carter Linda A||Burn, sunburn, and cellulite treatment system|
|US20060062816 *||9 Sep 2005||23 Mar 2006||Gatto Joseph A||Sanitary napkins with hydrophobic lotions|
|US20060070167 *||1 Dic 2005||6 Abr 2006||Ansell Healthcare Products Llc||Glove with hand-friendly coating and method of making|
|US20060121807 *||16 Jul 2003||8 Jun 2006||Harald Albrecht||Soap-containing cleansing substrate|
|US20060128591 *||16 Jul 2003||15 Jun 2006||Harald Albrecht||Detergent-dipped cleaning substrate|
|US20060143782 *||7 Oct 2004||6 Jul 2006||Sherry Ajluni||Glove with skin lotion|
|US20060269509 *||31 May 2005||30 Nov 2006||Excelda Corporation||Scent eliminating composition including colloidal silver|
|US20070083169 *||2 Oct 2006||12 Abr 2007||Philip Krugman||Towelette|
|US20070116748 *||17 Ene 2007||24 May 2007||Olaf Isele||Top-biased beneficial components on substrates|
|US20070157359 *||2 Jun 2006||12 Jul 2007||Reardon Timothy A||Bathing poncho|
|US20080063694 *||7 Sep 2006||13 Mar 2008||Biolargo Life Technologies, Incorporated||Material having antimicrobial activity when wet|
|US20080102093 *||31 Oct 2006||1 May 2008||Close Kenneth B||Appliance for delivering a composition, the appliance having an elastic layer and a shielding layer|
|US20080103460 *||31 Oct 2006||1 May 2008||Close Kenneth B||Method for making an appliance for delivering a composition, the appliance having an elastic layer and a shielding layer|
|US20080103461 *||31 Oct 2006||1 May 2008||Johnson Kroy D||Appliance for delivering a composition, the appliance having an outer fibrous layer and inner liquid-impermeable layer|
|US20080116096 *||17 Nov 2006||22 May 2008||Johnson Kroy D||Liquid-permeable appliance for delivering a composition|
|US20080121592 *||18 Ene 2008||29 May 2008||Biolargo Life Technologies, Incorporated||Systems and methods for cleaning liquid carriers related applications data|
|US20080196143 *||23 Abr 2008||21 Ago 2008||Shen Wei (Usa), Inc.||Skin-Enhancing Glove and Method of Manufacture|
|US20080207867 *||24 Ago 2005||28 Ago 2008||Daio Paper Corporation||Household Thin Paper|
|US20090028915 *||24 Jul 2008||29 Ene 2009||Biolargo Life Technologies, Incorporated||Material having antimicrobial activity when wet|
|US20090065014 *||5 May 2008||12 Mar 2009||Tomiyo Nagata||Adhesive patch with unique shape for the heel of the foot|
|US20090093777 *||4 Oct 2007||9 Abr 2009||Vilar Robert L||Aswipe|
|US20090131890 *||23 Ene 2009||21 May 2009||Francis James Rourke||Protease inhibitors in absorbent articles|
|US20090162446 *||3 Mar 2009||25 Jun 2009||Joseph Anthony Gatto||Absorbent article having a stable skin care composition|
|US20090188637 *||9 Ene 2009||30 Jul 2009||Eric Chan||Soft tissue paper having a polyhydroxy compound and lotion applied onto a surface thereof|
|US20100008957 *||11 Jul 2008||14 Ene 2010||Kimberly-Clark Worldwide, Inc.||Formulations having improved compatibility with nonwoven substrates|
|US20100008958 *||11 Jul 2008||14 Ene 2010||Kimberly-Clark Worldwide, Inc.||Substrates having formulations with improved transferability|
|US20100242796 *||29 Nov 2007||30 Sep 2010||Cognis Ip Management Gmbh||Emulsions for Finishing Textiles and Paper|
|US20100274209 *||6 Jul 2010||28 Oct 2010||Roe Donald C||Disposable Article Providing Improved Management of Bodily Exudates|
|US20110104303 *||10 Ene 2011||5 May 2011||Biolargo Life Technologies, Inc.||Material having antimicrobial activity when wet|
|US20110186068 *||2 Feb 2010||4 Ago 2011||Deanne Viola||Method and Apparatus for Pedicure Foot Health Protection|
|US20140373250 *||28 Dic 2012||25 Dic 2014||Idéexaction Inc.||Glove with moisture abosrbent applicator layer|
|EP0300814A3 *||22 Jul 1988||19 Dic 1990||Surgikos Inc.||Antimicrobial medical glove|
|EP0782869A1 *||21 Nov 1996||9 Jul 1997||TEBBE, Gerold||Material coated with micro-capsules|
|EP0938886A2 *||30 Dic 1998||1 Sep 1999||Kimberly-Clark Worldwide, Inc.||Cool feeling tissue|
|EP0938886A3 *||30 Dic 1998||30 May 2001||Kimberly-Clark Worldwide, Inc.||Cool feeling tissue|
|EP1032336B2 †||14 Nov 1997||14 Abr 2010||THE PROCTER & GAMBLE COMPANY||Disposable absorbent article with a skin care composition on an apertured topsheet|
|EP1757261A2 *||12 Jul 2002||28 Feb 2007||JOHNSON & JOHNSON GmbH||Products comprising a sheet and a lipid and aqueous phase|
|EP1757261A3 *||12 Jul 2002||11 Jun 2008||JOHNSON & JOHNSON GmbH||Products comprising a sheet and a lipid and aqueous phase|
|EP1930500A1 *||8 Dic 2006||11 Jun 2008||Cognis IP Management GmbH||Emulsions for the softening of textiles and paper|
|WO1994012115A1 *||22 Nov 1993||9 Jun 1994||Buchanan, Inc.||Protective medical glove and antibacterial/antiperspirant composition for reducing bacterial growth during use of medical gloves|
|WO1995016824A1 *||30 Nov 1994||22 Jun 1995||The Procter & Gamble Company||Lotion composition for imparting soft, lubricious feel to tissue paper|
|WO1995035411A1 *||23 May 1995||28 Dic 1995||The Procter & Gamble Company||Lotioned tissue paper|
|WO1995035412A1 *||23 May 1995||28 Dic 1995||The Procter & Gamble Company||Improved lotion composition for treating tissue paper|
|WO1997006307A1 *||25 Jul 1996||20 Feb 1997||The Procter & Gamble Company||Lotioned tissue paper containing a liquid polyol polyester emollient and an immobilizing agent|
|WO2000004230A1 *||7 Jul 1999||27 Ene 2000||Cognis Deutschland Gmbh||Use of pit emulsions|
|WO2000012170A1 *||9 Ago 1999||9 Mar 2000||Silipos Inc.||Gelatinous body protection article having a therapeutic additive|
|WO2001049935A1 *||15 Dic 2000||12 Jul 2001||Sca Hygiene Products Gmbh||A method of applying frozen treatment chemicals to a fiber-based planar product and resulting products|
|WO2001076445A1 *||30 Mar 2001||18 Oct 2001||Cognis Deutschland Gmbh & Co. Kg||Moist wipes (ii)|
|WO2004012698A2 *||16 Jul 2003||12 Feb 2004||Beiersdorf Ag||Soap-containing cleaning substrate|
|WO2004012698A3 *||16 Jul 2003||8 Abr 2004||Beiersdorf Ag||Soap-containing cleaning substrate|
|WO2004060432A1||16 Sep 2003||22 Jul 2004||Kimberly-Clark Worldwide, Inc.||Elastomeric articles with beneficial coating on skin-containing surface|
|WO2004075808A2 *||23 Feb 2004||10 Sep 2004||Carter, Linda, A.||Foot and hand treatment system|
|WO2004075808A3 *||23 Feb 2004||10 Mar 2005||Carter Linda A||Foot and hand treatment system|
|WO2005060774A1 *||5 May 2004||7 Jul 2005||Kimberly-Clark Worldwide, Inc.||Surgical gown incorporating a skin wellness agent|
|WO2006106546A1 *||13 Mar 2006||12 Oct 2006||Massimo Guarducci S.R.L.||Textile product having particular functional properties for the skin and process for the preparation thereof|
|WO2007025095A1 *||24 Ago 2006||1 Mar 2007||The Procter & Gamble Company||Bulk softened fibrous structures|
|WO2008067944A1 *||29 Nov 2007||12 Jun 2008||Cognis Ip Management Gmbh||Emulsions for finishing textiles and paper|
|WO2009021299A1 *||8 Ago 2008||19 Feb 2009||Balbino Leticia Gomes Tavares||Plastic gloves, boots and slippers coated with an emollient and sanitizing formula, intended for professional use by manicures / pedicures, that dispense the use of water due to providing hydration of the skin, nails and cuticles by occlusion|
|WO2013102256A1 *||28 Dic 2012||11 Jul 2013||Idéexaction Inc.||Glove with moisture absorbent applicator layer|
|Clasificación de EE.UU.||604/289, 604/304, 424/402, 2/901, 604/358, 604/360, 604/292, 424/443, 604/303|
|Clasificación internacional||A61K8/02, A61Q19/00, A41D13/11, A61K47/06, A61M35/00, A45D44/00, A41D19/00|
|Clasificación cooperativa||Y10S2/901, A41D13/11, A41D19/00, A61K8/0208, A61Q19/00, A61K8/02, A41D2400/32, A61K9/0014, A61K47/06, A61M35/00, A45D44/00|
|Clasificación europea||A61K8/02, A61K9/00M3, A61K47/06, A61K8/02C, A61M35/00, A61Q19/00, A41D13/11, A45D44/00, A41D19/00|
|4 Jun 1984||AS02||Assignment of assignor's interest|
Owner name: PROCTER & GAMBLE COMPANY, 6100 CENTER HILL ROAD, C
Owner name: SZUCH, CLYDE A.
Effective date: 19840516
|4 Jun 1984||AS||Assignment|
Owner name: PROCTER & GAMBLE COMPANY, 6100 CENTER HILL ROAD, C
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:SZUCH, CLYDE A.;REEL/FRAME:004273/0245
Effective date: 19840516
Owner name: SZUCH, CLYDE, C/O PITNEY, HARDIN, KIPP & SZUCH, 16
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:BUCHALTER, GILBERT;REEL/FRAME:004273/0240
Effective date: 19840503