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Número de publicaciónUS3896807 A
Tipo de publicaciónConcesión
Fecha de publicación29 Jul 1975
Fecha de presentación13 Jun 1974
Fecha de prioridad13 Jun 1974
Número de publicaciónUS 3896807 A, US 3896807A, US-A-3896807, US3896807 A, US3896807A
InventoresGilbert Buchalter
Cesionario originalGilbert Buchalter
Exportar citaBiBTeX, EndNote, RefMan
Enlaces externos: USPTO, Cesión de USPTO, Espacenet
Article impregnated with skin-care formulations
US 3896807 A
Resumen
An article is provided which may be in the form of an article of apparel, such as a glove, or a topical applicator for use in applying a therapeutic substance to the skin, which article is impregnated with the oil phase of a cream formulation. The oil phase impregnant is in the form of a non-oily solid which upon addition of water or moisture thereto is activated to form a cream.
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Descripción  (El texto procesado por OCR puede contener errores)

I United States Patent 1 1 1 3,896,807

Buchalter July 29, 1975 [54] ARTICLE IMPREGNATED WITH 2,765,789 10/1956 Schmierer 128/260 4 2,804,424 8/1957 Stirn et a1. 424/14 SKIN CARE FORMULATIONS 2,804,425 8/1957 Smith et a1..... 424/26 Inventor: Gilbert Buchalter, 555 Mt. Prospect 3,328,259 6/1967 Anderson 424/28 Ave., Newark, NJ. 07014 3,490,454 1/1970" Goldfarb et a1 128/285 [22] Filed: June 13, 1974 Primary Exammer-Aldnch F. Medbery 1 1 pp N05 478,924 Attorney, Agent, or Firm-Lerner, David, Littenberg & Samuel [52] US. Cl. 128/26]; 128/263; 424/16;

424/26; 42 /2 [57 ABSTRACT [51] Int. Cl A6lm 35/00 [58 Field of Search 128/260, 261, 263, 8]; pmwsded wh'ch may be 1 424/28 1 6 26 l 4 art1c1e of apparel, such as a glove, or a top1ca1 applicator for use in applying a therapeutic substance to the skin, which article is'impregnated with the oil phase of [56] Reerences a cream formulation The oil phase impregnant is in UNITED STATES PATENTS the form of a non-oily solid which upon addition of 2,653,601 9/1953 Morrison 128/165 water or moisture thereto is activated to form a 2,664,087 12 1953 Lewis cream 2,671,446 3/1954 Mann 2,685,086 8/1954 Henry 128/260 X 26 Claims, N0 Drawings ARTICLE IMPREGNATED WITH SKIN-CARE FORMULATIONS FIELD OF THE INVENTION The 'present invention relates to an article such as a piece of apparel or an applicator pad, impregnated with the oil phase of a cream formulation which upon the addition of moisture thereto forms a skin-soothing cream.

BACKGROUND OF THE INVENTION The therapeutic effect which creams or oils have on the skin is unquestioned. For example, use of hand creams or facial creams are essentially in treating and- /or preventing chapping or chafing of the skin.

The prior art is replete with articles of apparel and applicator pads for use in applying therapeutic creams, lotions or oils to the skin. For example, U.S. Pat. No. 2,501,565 discloses a hand mitten impregnated with a cream such as lanolin and lemon oil; U.S. Pat. No. 2,916,036 discloses a rubber glove, the lining of which is impregnated with an unguent material such as lanolin; other patents disclosing gloves impregnated with creams include U.S. Pat. Nos. 3,116,732; 3,342,182; 3,298,368; 3,384,083; and 3,499,446. Other articles of apparel impregnated with various therapeutic cream or oil formulations are disclosed in U.S. Pat. Nos. 3,354,884 (facial mask); 2,716,981 (facial mask); 2,664,087 (foot slipper); 3,489,884 (diapers); and 3,585,998 (diaper liners).

Paper products, such as tissues and toilet tissues are knowwn to be impregnated with therapeutic cream or oil formulations. For example, U.S. Pat. No. 302,073 discloses a toilet paper impregnated with an unctuous or oily material such as vaseline, glycerine, paraffin or animal or vegetable oils. U.S. Pat. No. 1,687,643 discloses a toilet tissue coated with a creaam which coating may e covered with a layer of paraffin to prevent the fingers from becoming soiled by the cream. U.S. Pat. No. 1,868,862 discloses a detergent towel impregnated with a soap compound which may include glycerine. U.S. Pat. No. 2,032,645 discloses an absorbent paper product containing a wetting agent to preserve the paper against loss of absorbency. U.S. Pat. No. 2,944,931 discloses a sanitary paper containing lanolin in the form of an aqueous emulsion. U.S. Pat. No. 3,264,188 discloses a sanitary impregnated skin wiper, such as toilet tissue, impregnated with an oily material and an emulsifying agent.

Patents disclosing applicator pads or cloths or paper impregnated with creams or cream-like materials include U.S. Pat. Nos. 1,836,833; 2,495,066; 2,702,780; 2,999,265; 3,624,224; and 3,129,811.

The articles or applicator paper or pads impregnated with cream or cream-like materials, disclosedin the afore-mentioned patents are quite useful for administering such creams to the skin. However, these articles and applicators have the same serious drawback, namely, that they are greasy or oily to the touch. They tend to stain oil-absorbent materials upon contact thereby losing the cream and ruining the materials contacted therewith. Thus, they must be packaged with great care and at great expense. For example, the toilet tissue disclosed in U.S. Pat. No. 3,264,188 impregnated with an oil and an emulsifying agent must be wrapped in oil-resistant paper to provide a non-staining package.

U.S. Pat. No. 2,495,066 discloses a dusting and polishing paper impregnated with a stable oil-in-waater emulsion, which comprises a non-drying oil and one or more emulsifying or surface active agents and a flexibilizing or plasticizing agent. The above ingredients are applied to the paper as an aqueous emulsion and the paper is then dried over steam rolls. The result is that the so impregnated paper is somewhat tacky or sticky because some of the water of the aqueous emulsion has not been driven off by the heating over the steam rolls and resulted in emulsification.

STATEMENT OF THE INVENTION In accordance with the present invention, there is provided an article such as an article of apparel or a cream applicator which is impregnated with the oil phase of a cream formulation, in the form of a non-oily non-tacky solid, and which upon the addition of water or moisture thereto forms a therapeutic skin cream. The article of the invention is not greasy or oily to the touch and need not be packaged in oil resistant paper or other oil resistant packaging material and thus overcomes the afore-mentioned disadvantages associated with creams or cream-like or oily materials. Furthermore, the therapeutic composition or oil-phase carried by the articles of the invention is capable of controlled emulsion and sustained release of any other therapeutic substance or medicament present in said oil-phase, depending upon the type, melting point and amounts of oily materials and emulsifiers employed.

DETAILED DESCRIPTION OF THE INVENTION In accordance with one embodiment of the present invention, there is provided an article of apparel, such as a glove, glove liner, facial mask, slipper, diaper, sanitary napkin and the like, which is to be worn by the user so that an inside portion of said article comes into direct contact with the users skin in the area to which a therapeutic cream is to be applied. The article of apparel of the invention generally comprises-an outerportion which is worn away from the skin and an inner portion which comes into direct contactwith the skin of the user, which inner portion is impregnated withthe oil phase of a cream formulation which upon addition of moisture thereto forms a cream. The oil phase, be-

fore addition of water thereto, is in the form of a dry non-oily non-sticky solid atroom temperature, and I generally comprises an oily material and one or more emulsifying agents and may include in addition, one or Q more emollients, dyes, perfumes and/or pharmaceuticals.

nated with an oil phase of a cream formulation to form a new and most advantageous hand care product. The

glove or a pair of such gloves or liners maybe employed by themselves or as a separate liner under rubber gloves, under dress gloves, under work gloves or j gardening gloves. Furthermore, the 'glov esmay'l'be incorporated as permanent'liners intoany of 'the'afore gloves are worn while working, for examplefisu'ch'as rubber gloves worn during the washing of dishes, floors and the like, the moisture and heat produced by per- Where the article of the invention comprises 'a glove I or glove liner, the glove or glove liner may 'be inpregspiring of the hands, will be sufficient to cause emulsification of a portion of the oil phase to form a therapeutic cream. Since the cream forms while the gloves are being worn, and perhaps while the wearer is working, the so-formed cream has an opportunity to work its way into the pores of the skin to provide beneficial and therapeutic effects even after the gloves are removed.

Only a relatively small amount of emulsification is necessary to produce a therapeutic amount of cream. The perspiration and heat generated by the wearer will produce the necessary amount of moisture to form the desired therapeutic amount of cream.

As indicated above, in accordance with the invention, the oil phase may be impregnated into other articles which are employed in contact with the skin, such as facial masks, slippers or shoe linings, diapers, diaper liners, sanitary napkins, dresses, pants and even bandages. In all such applications the contact of the wearers skin will produce sufficient moisture and heat to cause emulsification of a portion of said oil phase.

Further in accordance with the present invention, there is provided an article for use in applying a therapeutic cream substance to the skin which article comprises a substrate impregnated with a therapeutic composition comprising the oil phase of a cream formulation in the form of a dry non-oily solid as described heretofore. Such substrate may comprise paper or a paper product, such as a tissue, towel, toilet tissue, woven and non-woven fabrics, and the like.

The oil phase which is in the form of a dry non-ily 'solid carried by the article of the invention comprises from about 1 to about 99% and preferably from about 30 to about 70 of an oily material and from about 99 to about 1% and preferably from about 70 to about 30% of an emulsifier.

Examples of oily materials suitable for use herein include, but are not limited to, mineral oil, petrolatum, paraffin, vegetable oil, such as linseed oil, soya bean oil or cotton seed oil, various animal oils, such as whale oil, lard oil, caster oil, olive oil, and isopropyl palmitate.

The emulsifying agents which may be employed herein cause emulsification of an oil upon contact with the oil without the necessity of high speed mechanical agitation. Such emulsifiers include anionic emulsifiers, cationic emulsifiers, and non-ionic emulsifiers. Examples of suitable emulsifiers include, but are not limited to, cetyl alcohol, as well as any one of those classified in the following groups.

1. A long chain fatty acid partial ester of a hexitol anhydride wherein the fatty acid has at least 6, preferably from 12 to 18, carbon atoms, including the long chain fatty acid partial esters of sorbitan, sorbide, mannitan and mannide and mixtures thereof. Examples of such esters are sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan monooleate, and sorbitan trioleate, These compounds are sold by Atlas Powder Company under the trade names, respectively, Span Span 40", Span 60", Span 80, and Span 85". Additional examples of such esters are sorbide monolaurate, sorbide monomyristate, the mannide monoesters of the acids present in distilled coconut oil fatty acids, mannide monostearates, and a mixture of mannitan monostearate, mannide monostearate, mannitan distearate. These esters particularly the monoesters, may be prepared by the methods described in the US Pat. Nos. 3,322,820, and 3,322,821,

to Kenneth R. Brown using as the fatty acid, for example, caproic, caprylic, capric, lauric, myristic, palmitic. oleic, linoleic, linolenic, ricinoleic, stearic, dihydroxy stearic, eleostearic and the like or any mixture thereof, including the fatty acids derived from animal fats and oils and vegtable oils such as lard, sardine oil, whale oil, menhaden oil, coconut oil, soya bean oil, corn oil, olive oil and the like.

2. Polyoxyalkylene derivatives of any one or any mixture of the foregoing hexitol anhydride long chain fatty acid partial esters, particularly the polyoxyethylene derivatives. Examples of such derivatives are polyoxyethylene derivative of sorbitan monolaurate, polyoxyethylene derivative of Sorbitan monopalmitate, polyoxyethylene derivative of sorbitan monostearate, polyoxyethylene derivative of sorbitan trioleate. These polyoxyethylene derivatives are sold by Atlas Powder Company under the tradenames, respectively, Tween 20", Tween 40, Tween 60, Tween and Tween They are prepared, in general, by reacting a long chain fatty acid partial ester of a hexitol anhydride with ethylene oxide or other alkylene oxide in large molar excess. Thus, for example, Tween 80 is formed by reacting about 5 mols of ethylene oxide per mol of sorbitan monooleate and Tween 85 is formed by reacting about 20 mols of ethylene oxide per mol of sorbitan trioleate.

3. Polyoxyalkylene derivatives of a glycol long chain fatty acid monoester, particularly the glycol monoesters of fatty acids having at least 12 carbon atoms such as those set forth above. Particularly effective derivatives are the polyoxyethylene derivatives formed by reacting a large molar excess of ethylene oxide with an ethylene, diethylene, propylene, butylene or triethylene, etc., glycol monoester of a fatty acid having from 12 to 18 carbon atoms. The preferred ones are those formed by reacting 20, 25 and 30 mols, respectively, of ethylene oxide per mol of propylene glycol monostearate. They are sold by Atlas Powder Company under the tradenames, respectively, G-2 l 50", G-2 l 60"and G-2l70". The product G-2l50is most effective.

4. Soaps of aliphatic acids, alkyl aryl sulfonates, alkyl aryl polyether sulfonates, fatty alcohol sulfates, and sulfonated aliphatic compounds.

Examples of suitable anionic emulsifiers include all soaps, potassium laurate, triethanol amine stearate, sodium lauryl sulfate, alkyl polyoxyethylene sulfates, and dioctyl sodium sulfosuccinate.

Other examples of suitable emulsifiers are Neutronyx 600, Triton X-lOO, Ninol 979, and Ethofat 242/20. Others are available. The preferred emulsifier is Promulgen G or D (polyethylene glycol ether complex of higher fatty alcohols).

Ninols are trade-marked products of Ninol Laboratories, Chicago, Illinois, made in accordance with Kritchevsky US. Pat. No. 2,089,212. They are condensation products of one mole of aliphatic monocarboxylic acid with at least two moles of alkylolamine. The compounds are readily dispersible or soluble in water, are stable in mildly acid and alkaline media, and are effective in the presence of calcium and magnesium ions.

The higher fatty acids (six or more carbon atoms) are preferred for the aliphatic radical. One such compound is Ninol 979. It is l00% active, nonionic, pale amber liquid with a specific gravity of 1.00 corresponding to the product of condensing lauric acid with diethanolamine.

Ethofats are trade-marked products of Armour and Company, Chemical Division, Chicago, Illinois. They are a family of fat-derived nonionic surface-active agents. They are polyoxyethylene-glycol esters of fatty acids.

They vary from fluid liquids to soft pastes depending upon length and saturation of the fatty chain and the relative proportion of the polyethylene glycol residue, which factors also control the solubilities.

The polyethylene glycol employed for the material may have have a molecular weight from 220 to 2200. The compounds Neutronyx are a family of trademarked materials made by Onyx Oil Chemical Company, Jersey City 2, New Jersey. They are nonionic surface-active agents, functioning as detergents, emulsifiers and dispersants. They vary from liquids to lowmelting wax-like solids, all dispersible in water. Being nonionic they are compatible with cationic and other nonionic compounds, such as quaternary ammonium compounds. They are stable in mildly acid and alkaline solutions. Chemically, they are ethers the various kinds being designated commercially by a number:

No. 330polyalkylether condensate of fatty acids No. 600-aromatic polyglycol ether, and specifically phenyl ether with polyethylene glycol No. 834polyalkyl ether condensate of fatty acids Neutronyx 600 is miscible in all proportions in water, has specific gravity of about 1, and in a 1% solution in water a pH of 7.3.

The Tritons are trade-marked materials of Rohm and Haas, Philadelphia 5, Pa. They vary from nonionic, to cationic and anionic activity, and are stable in strong acid and alkaline solutions.

The oil phase described above may also include emollients such as a cetyl alcohol, which also functions as a stiffening agent, propylene glycol, glycerine, triethylene glycol, spermaceti or other waxes, perfumes and- /or pharmaceuticals, as well as film formers, deodorants, opacifiers, astrigents, solvents and the like. In addition, stabilizers can be added to enhance the shelf life of the oil phase such has non-ionic surfactants, cellulose derivatives, protein and lecithin. All of the above types of materials are known in the art as additives of cream formulations.

The oil phase impregnated in the article of the invention upon the addition of water thereto, forms a cream or a less viscous lotion. In effect, that portion of the oil phase which comes into contact with moisture becomes emulsified. The phenomena can be described as microemulsificaton, that is emulsification of the oil phase at the point of contact with moisture which point will be that portion of the users skin which contacts the oil phase. Thus, complete emulsification of the entire oil phase impregnated in the article of the invention is avoided with the result that the oil phase impregnant is long lasting and is not exhausted after a single use. Furthermore, if a medicament or pharmaceutical is also incorporated into the oil phase, it will be used up in amounts corresponding to the amount of oil phase emulsified at any one time. Thus, the oil phase carrying the medicament or pharmaceutical can be characterized as a sustained release carrier. The length of time for sustained release of the cream and medicament is regulated by the melting point of the finished solid oil phase formulation, and the ease of emulsification thereof which is controlled by the amount and type of emulsifiers employed. Varying rates of emulsification will be desired depending upon whether the oil phase is impregnated in an article of apparel or an applicator for the cream formulation. For example, where a paper product or applicator is impregnated with the oil phase, a low melting point oil phase formulation will be desired since the paper product will probably be of the one time use-throw-away type, so that rapid and total emulsification is effected during the single use. With this type of product, it is preferred to employ an oily material which is liquid at room temperature as opposed to paraffin or petrolatum.

One of the essential features of the article of the invention is that the oil phase impregnated therein is a dry non-oil non-greasy solid at room temperature. The formulation of such an oil phase impregnant can only be obtained by impregnating the-article or substrate with a non-aqueous homogeneous liquid mixture of the components of the oil phase, such as by spraying the liquid mixture onto the article or substrate or dipping the article or substrate into the liquid oil phase until a desired amount is absorbed therein. Thereafter the article having the oil phase impregnated therein is cooled to cause the oil phase to solidify and form a non-oily dry solid at room temperature.

Generally, in forming the homogeneous liquid mixture forming the oil phase, it will be necessary to heat the components above the melting point of the highest melting component in the mixture so that all solids are reduced to liquid form. This can also be accomplished by mixing with the components of the oil phase nonaqueous solvents, such as acetone, chloroform, trichloroethylene, xylene, xylol, as well as other ketones, chlorinated hydrocarbons and aromatic solvents, with or without heating, to form a homogeneous liquid mixture of all components. The resulting liquid can then be applied to the article or substrate as described above and cooled to form a solid oil phase which has a smooth, non-sticky almost slippery finish.

Where upon cooling and solidification of the oil phase, one or more of the solvents mentioned above does not fomi a solid, these solvents may be easily removed from the remaining solids by, for example, wip ing or expression.

The above process where-in a solvent is employed to cause complete dissolution of the components of the oil phase is desirable where heat is not compatible with the article or substrate to be impregnated. Furthermore, heating is not essential where such solvents are employed.

It is essential that water not be present in the oil phase before emulsification is desired. If water is present during the formation of the homogeneous liquid mixture of the oil phase components, even upon drying over steam over steam rolls and the like, all of the water may not be removed; the result is that upon cooling and attempted solidification of the oil phase components, a tacky sticky product is produced.

The article or substrate treated with the homogeneous liquid mixture of oil phase components will be impregnated or coated with such oil phase depending upon the porosity or absorbability of such article or substrate.

The following are some of the specific applications of the present invention:

1. lmpregnation of the lining of rubber or plastic gloves.

a. Provides cosmetic hand care treatment by merely wearing gloves.

b. Provides lubrication for easier insertion of hands and removal of gloves c. hot hand care treatment by placing hands in hot water such as when doing dishes.

2. impregnation of dress or work glove lining. Provides cold weather hand care treatment and lubrication.

3. Impregnation of glove liner for winter sports such as skiing. in addition to cold weather hand care treatment and lubrication for ease of insertion and removel, the impregnated liner forms an extremely effective thermal barrier.

4. Impregnation of diaper liners and sanitary napkin covers. To prevent or eliminate chafing due to friction.

5. impregnation of tissues and towels, both woven and non-woven fabrics.

a. Cleansing b. Lubricating c. Softening d. Moisturizing e. Protecting In addition, articles or substrates impregnated with the dry non-aqueous oil phase will have long shelf life if kept in a dry cool place since the solid oil phase will not be actuated until addition of moisutre thereto.

The following examples represent preferred embodiments of the present invention.

EXAMPLE 1 About 40 g. light mineral oil, about 40 g. Promulgen- G (that is polyethylene glycol ether complex of higher fatty alcohols produced by Robinson-Wagner) and about g. of cetyl alcohol are heated at a temperature of about 90C while mixing until all solids are dissolved and a homogeneous liquid mixture is formed.

A glove lining is dipped into the mixture for a few seconds until saturated. The glove lining is then removed and allowed to cool at room temperature. The resulting product is found to have a smooth, non-sticky, almost slippery finish comprising the oil phase of a cream formulation.

Where the so treated glove lining is employed as a linear for rubber gloves and the combination employed while washing dishes with hot water, it is found that the perspiration released by the hands causes a light cream coating to form on the hands which is an effective barrier to prevent moisture evaporation from the hands.

EXAMPLE 2 The procedure of Example l is repeated except that an oil phase formulation comprising about g. of Promulgen G (described in Example I) is employed.

EXAMPLE 3 solvent mixture are allowed to dry until a dry non-oily solid oil phase is formed while the tissue remains soft and supple.

The tissue may be employed as a cleansing tissue so that upon application of moisture thereto the oil phase coating is emulsified to form a cleansing cream.

EXAMPLE 4 Following the procedure of Example 1, a tissue was impregnated with a homogeneous liquid mixture comprising 30 g. Tween and 50 g. of heavy mineral oil. The resulting tissue remained soft and supple and may be employed as a cleansing tissue so that upon application of moisture thereto the oil phase impregnated therein emulsifies to form cleansing cream.

EXAMPLE 5 Following the procedure of Example 1, a tissue was impregnated with a homogeneous liquid mixture comprising 30 g. SPAN 80, and 50 g. paraffin. The resulting tissue remained soft and supple and may be employed as a cleansing tissue so that upon applicattion of moisture thereto the oil phase impregnated therein emulsifies to form a cleansing cream.

EXAMPLE 6 Following the procedure of Example 1, a tissue was impregnated with a homogeneous liquid mixture comprising 30 g. Span 80, 50 g. paraffin and 10 g. cetyl alcohol. The resulting tissue remained soft and supple and may be employed as a cleansing tissue so that upon application of moisture thereto the oil phase impregnated therein emulsifies to form a cleansing cream.

What is claimed is:

1. An article to place in contact with the body for use in applying a cosmetic or therapeutic substance to the skin, comprising a substrate and a therapeutic or cosmetic composition carried by said substrate and comprising the oil phase of a cream formulation, said oil phase being a dry emulsifiable solid, which upon addition of moisture thereto forms an oil in water or water in oil emulsion.

2. The article of claim 1 wherein said oil phase comprises an oily material and an emulsifier. 3. The article of claim 2 wherein said oily material is selected from the group consisting of mineral oil, paraffin, petrolatum, vegetable oil, linseed oil, olive oil and isopropyl palmitate.

4. The article of claim 2 wherein said emulsifier is selected from the group consisting of cetyl alcohol, polyethylene glycol ether complexes of higher fatty alcohols, fatty acid soaps of organic bases selected from the group consisting of triethanolamine oleate, triisopropyl amine laurate, monoethyl amine stearate and diethyl amine palmitate, surface active agents selected from the group consisting of long chain fatty acid partial esters of a hexitol anhydride, and a polyoxyalkylene derivative of a long chain fatty acid monoester of a glycol, wherein the fatty acid contains 6 to 18 carbons, soaps of aliphatic acids, alkyl aryl sulfonates, alkyl aryl polyether sulfonates, fatty alcohol sulfates and sulfonated aliphatic compounds.

5. The article of claim 2 wherein said oily material comprises mineral oil and said emulsifier comprises a polyethylene glycol ether complex of higher alcohols.

6. The article of claim 5 wherein said oil phase further includes cetyl alcohol.

7. The article of claim 2 wherein said oil phase comprises, in addition one or more emollients, dyes, perfumes and/or pharmaceuticals.

8. The article of claim 1 wherein said substrate com prises a woven or non-woven material.

9. The article of claim 1 wherein said substrate comprises a tissue.

10. The article of claim 1 wherein said substrate comprises a face mask.

11. The article of claim 1 wherein said substrate comprises a shoe.

12. The article of claim 1 wherein said substrate comprises a foot slipper.

13. The article of claim 1 wherein said substrate comprises a diaper.

14. The article of claim 1 wherein said substrate comprises a bandage.

15. The article of claim 1 wherein said substrate comprises a glove.

16. The article of claim 1 wherein said substrate comprises a diaper liner.

17. The article of claim 1 wherein said substrate comprises a sanitary napkin.

18. The article of claim 1 wherein said substrate is a paper tissue.

19. The article of claim 1 wherein said substrate is a towel.

20. The article of claim 1 wherein said substrate is a paper towel.

21. A method of manufacturing an article for use in Ill applying a therapeutic or cosmetic substance to the skin, comprising providing a substrate and a therapeutic or cosmetic composition carried by said substrate, said composition comprising the oil phase of a cream formulation in the form of a dry solid, said solid com-v prising an oily material and one or more emulsifiers, wherein said therapeutic or cosmetic composition is formed by mixing together the oily material and emulsifiers while each material is in a liquid state to form a non-aqueous substantially homogeneous mixture, and while said mixture is in liquid form, applying the mixture to the substrate, and converting the mixture to a non-oily solid.

22. The method in accordance with claim 21 wherein the oily material and emulsifiers are heated to form an all liquid mixture.

23. The method in accordance with claim 22 wherein the liquid mixture is converted to a solid by cooling.

24. The method in accordance with claim 21 wherein the oily material and emulsifiers are mixed together in the presence of a solvent causes the oily material and emulsifiers to form a liquid mixture.

25. The method in accordance with claim 24 wherein the liquid mixture of the oily material and emulsifiers is converted to a solid by removing the solvent from the mixture.

26. The method of claim 22 wherein the oily material and emulsifiers are heated to at least the melting point of the highest melting component.

. UNITED STATES PATENT OFFICE CERTIFlCATE OF CORRECTLEON Patent No. ,807 Dated July 29, 1975 Inventor(s) GILBERT BUCHALTER It is certified that error appears in the above-identified patent and that said Letters Patent are hereby corrected as shown below:

Column 1, Line 29 "3,489,884" should read: 3,489,148

Column 1, Line'38, "may e" should read: may be Column 2, Line 51, "Where the article of the invention" should read: Where the article of apparel of the invention Column 10, Line 21, insert "which" between "solvent" and "causes".

Signed and Scaled-this 0 eleventh Day of November 1975 [SEAL] Attest:

C RUTH c. MASON c. MARSHALL DANN Arresting Officer (mnmisximwr of Patents um! Trademarks FORM PC4050 (10-59) UStOMM-fiC teams-1

Citas de patentes
Patente citada Fecha de presentación Fecha de publicación Solicitante Título
US2653601 *16 Nov 195029 Sep 1953Morrison Elizabeth MGlove
US2664087 *16 Ago 195029 Dic 1953John J LawlerMedicinal slipper
US2671446 *28 Oct 19529 Mar 1954Mann Ann S VBeauty mask
US2685086 *12 Jun 19533 Ago 1954Gifford H HenryUnderarm antiseptic deodorant pad
US2765789 *8 Oct 19529 Oct 1956Schmierer Helen LEyeshade applicator
US2804424 *24 Abr 195127 Ago 1957American Cyanamid CoMethod of preparing a tetracycline type antibiotic-containing wound dressing
US2804425 *2 Jul 195227 Ago 1957American Cyanamid CoChlortetracycline gauze and method for production
US3328259 *8 Ene 196427 Jun 1967Parachem CorpDressing for a wound containing a hemostatic agent and method of treating a wound
US3490454 *21 Oct 196620 Ene 1970United Merchants & MfgCatamenial products having a coating of rupturable microcapsules containing medicants
Citada por
Patente citante Fecha de presentación Fecha de publicación Solicitante Título
US4112167 *7 Ene 19775 Sep 1978The Procter & Gamble CompanySkin cleansing product having low density wiping zone treated with a lipophilic cleansing emollient
US4263363 *20 Dic 197921 Abr 1981Colgate-Palmolive CompanyDiaper containing oil and emulsifier
US4344930 *15 Sep 198017 Ago 1982Colgate-Palmolive CompanySkin care sponge
US4367227 *26 Dic 19784 Ene 1983Lever Brothers CompanyMethod and cosmetic composition for reducing sebum secretion
US4481243 *5 Ene 19846 Nov 1984The Procter & Gamble CompanyPattern treated tissue paper product
US4513051 *5 Ene 198423 Abr 1985The Procter & Gamble CompanyTissue paper product
US4543247 *6 Ene 198324 Sep 1985Bayer AktiengesellschaftGlrs vcollstd
US4544547 *14 Mar 19831 Oct 1985Bayer AktiengesellschaftSpreading agents; hydrophobic polyurethane
US4634436 *5 Jul 19836 Ene 1987Tour June TMethod for making a body wrap composition
US4690821 *28 Mar 19861 Sep 1987Creative Products Resource Associates, Ltd.Towel for skin moisturizing and drying
US4775372 *27 Mar 19874 Oct 1988Wilberg Janice LDevice for application of liquids to surface of hands
US4853978 *24 Jul 19878 Ago 1989Surgikos, Inc.Inner coating; surgery
US5073365 *1 Jun 198917 Dic 1991Advanced Polymer SystemsClinical and personal care articles enhanced by lubricants and adjuvants
US5089205 *25 Sep 198918 Feb 1992Becton, Dickinson And CompanyProcess for producing medical devices having antimicrobial properties
US5156843 *20 Mar 198920 Oct 1992Advanced Polymer Systems, Inc.Fabric impregnated with functional substances for controlled release
US5219340 *23 Jul 199115 Jun 1993Elaine SenecaColloidal oatmeal solution applicator
US5281186 *26 Ene 199325 Ene 1994Buckley Caroline MProtective breast cup arrangement
US5525345 *6 Mar 199511 Jun 1996The Proctor & Gamble CompanyPetroleum based emollient or fatty ester emollient, polyhydroxy fatty ester or amide immobilizing agent
US5538732 *12 Abr 199423 Jul 1996Creative Products Resource, Inc.Dermatology
US5552020 *21 Jul 19953 Sep 1996Kimberly-Clark CorporationTissue products containing softeners and silicone glycol
US5558873 *8 Mar 199524 Sep 1996Kimberly-Clark CorporationSoft tissue containing glycerin and quaternary ammonium compounds
US5601871 *6 Feb 199511 Feb 1997Krzysik; Duane G.Soft treated uncreped throughdried tissue
US5607081 *21 Sep 19944 Mar 1997Levy; DavidDispensing liquid container
US5607760 *3 Ago 19954 Mar 1997The Procter & Gamble CompanyDisposable absorbent article having a lotioned topsheet containing an emollient and a polyol polyester immobilizing agent
US5609587 *3 Ago 199511 Mar 1997The Procter & Gamble CompanyDiaper having a lotioned topsheet comprising a liquid polyol polyester emollient and an immobilizing agent
US5614202 *17 May 199425 Mar 1997Defina; Linda E.Moisturizing glove
US5614293 *19 Mar 199625 Mar 1997Kimberly-Clark CorporationSoft treated uncreped throughdried tissue
US5624676 *3 Ago 199529 Abr 1997The Procter & Gamble CompanyLotioned tissue paper containing an emollient and a polyol polyester immobilizing agent
US5635191 *28 Nov 19943 Jun 1997The Procter & Gamble CompanyDiaper having a lotioned topsheet containing a polysiloxane emollient
US5643588 *28 Nov 19941 Jul 1997The Procter & Gamble CompanyDiaper having a lotioned topsheet
US5650218 *16 Abr 199622 Jul 1997Kimberly-Clark CorporationSoft treated tissue
US5665426 *6 Feb 19959 Sep 1997Kimberly-Clark CorporationSoft treated tissue
US5702380 *23 Feb 199630 Dic 1997Walker; RosemarySanitary napkin
US5705164 *3 Ago 19956 Ene 1998The Procter & Gamble CompanyTissue paper with lotion of polyol polyester emollient, immobilization on surfaces
US5716692 *28 Feb 199610 Feb 1998The Procter & Gamble Co.Lotioned tissue paper
US5720966 *17 Ene 199624 Feb 1998The Procter & Gamble CompanyMedicated tissue paper product
US5730839 *21 Jul 199524 Mar 1998Kimberly-Clark Worldwide, Inc.Bulking; softness
US5756112 *14 Ene 199726 May 1998The Procter & Gamble CompanyCleaning wipes
US5763332 *5 Dic 19969 Jun 1998The Procter & Gamble CompanyCleaning wipes
US5863663 *5 Dic 199626 Ene 1999The Procter & Gamble CompanyWet-like cleaning wipes and like articles comprising a carrier treated with an emulsion having a continuous lipid phase
US5871763 *24 Abr 199716 Feb 1999Fort James CorporationSubstrate treated with lotion
US5885697 *12 Dic 199723 Mar 1999Kimberly-Clark Worldwide, Inc.Addition of wax uniformly distributerd on surface to increase the ability of the oil to remain at the surface of the tissue
US5908707 *5 Dic 19961 Jun 1999The Procter & Gamble CompanyEmulsion is sufficiently brittle that it ruptures when subjected to low shear pressures during use to release the dispersed polar phase.
US5922336 *27 Dic 199613 Jul 1999Deotexix Inc.Microcapsule-coated material
US5938649 *9 May 199717 Ago 1999Drypers CorporationAbsorbent articles with improved rash-preventing properties
US5941864 *26 Ago 199724 Ago 1999The Procter & Gamble CompanyDisposable absorbent article having improved fecal storage
US5944705 *4 Sep 199731 Ago 1999Drypers CorporationContaining aloe vera
US5948540 *30 Abr 19977 Sep 1999The Procter & Gamble CompanyWet cleaning wipe
US5951991 *26 Nov 199714 Sep 1999The Procter & Gamble CompanyLathering surfactant, water insoluble substrate, and conditioning emulsion added seperately from surfactant; substrate helps generate lather and aids in deposition of conditioning agents; dry form prior to use
US5952043 *25 Ago 199814 Sep 1999The Procter & Gamble CompanyHeating emulsion so the lipid phase is fluid, cooling to solidify on carrier; external lipid phase of the emulsion is sufficiently brittle that it ruptures during low shear to release dispersed internal polar phase; perianal cleaning
US5957906 *14 Nov 199728 Sep 1999The Procter & Gamble CompanyDiaper with improved feces management properties
US5968025 *27 Jun 199719 Oct 1999The Procter & Gamble CompanyAbsorbent article having a lotioned topsheet
US5972361 *25 Oct 199626 Oct 1999The Procter & Gamble CompanyCleansing products
US5977430 *14 Nov 19972 Nov 1999The Procter & Gamble CompanyAbsorbent article with macro-particulate storage structure
US5980919 *10 Nov 19979 Nov 1999Potlatch CorporationEmollient compositions and methods of application to a substrate by electrostatic spraying
US5980922 *5 Dic 19969 Nov 1999Procter & Gamble CompanyThe cleaning wipes comprising a carrier coated with a solidified waxy lipid layer containing a non-silicon emulsifier and a polar internal phase; hard surface cleaning and personal cleansing such as baby wipes
US5980931 *19 Nov 19979 Nov 1999The Procter & Gamble CompanyCleansing products having a substantially dry substrate
US6001381 *7 Ene 199814 Dic 1999The Procter & Gamble CompanyWet-like cleaning wipes and similar articles that are particularly useful in removing perianal soils, comprising a carrier comprising at least one polarpliobic region, an optional, preferred substrate such as tissue paper web
US6010491 *17 Mar 19994 Ene 2000The Procter & Gamble CompanyViscous fluid bodily waste management article
US6013063 *14 Nov 199711 Ene 2000The Procter & Gamble CompanyViscous fluid bodily waste management article
US6063397 *25 Oct 199616 May 2000The Procter & Gamble CompanyDisposable cleansing products for hair and skin
US6074655 *8 Feb 199913 Jun 2000The Procter & Gamble CompanyDisposable single use personal cleaning product
US6107537 *10 Sep 199722 Ago 2000The Procter & Gamble CompanyDisposable absorbent articles providing a skin condition benefit
US6117119 *28 Ago 199812 Sep 2000Silipos, Inc.Gelatinous body protection article having a therapeutic additive
US6118041 *27 Jun 199712 Sep 2000The Procter & Gamble CompanyDiaper having a lotioned topsheet
US6120488 *31 Oct 199719 Sep 2000The Procter & Gamble CompanyAbsorbent articles having cuffs and topsheet with skin care composition(s) disposed thereon
US6120783 *31 Oct 199719 Sep 2000The Procter & Gamble CompanyWeb materials with two or more skin care compositions disposed thereon and articles made therefrom
US6121165 *23 Jul 199819 Sep 2000The Procter & Gamble CompanyWet-like cleaning articles
US6132746 *22 May 199717 Oct 2000The Procter & Gamble CompanyCleansing products with improved moisturization
US6133166 *1 Jul 199717 Oct 2000The Procter & Gamble CompanyDry-feeling disposable wipes which release cleaning fluid when used
US6136775 *18 Dic 199824 Oct 2000Kimberly-Clark Worldwide, Inc.Absorbent wipe is provided impregnated with non-toxic, oil-based cleaning solvent comprising two diluent oils, and hydrophilic surfactant
US6149934 *23 Abr 199921 Nov 2000Kimberly-Clark Worldwide, Inc.Lotion formulation acts as a lubricant to reduceabrasion of the skin caused by liner and also transfers to the skin to provide improved skin health; for disposable products such as diapers, incontinence products
US6153208 *11 Sep 199828 Nov 2000The Procter & Gamble CompanyA water insoluble substrate having a separate cleansing and conditioning portions with different wet extensible, a lathering surfactant; dry washcloth
US6153209 *28 Sep 199928 Nov 2000The Procter & Gamble CompanyA skin care composition disposed on a portion of delivery vehicle, the skin care composition has a high water vapor permeation rate and a hunter b value, transferable to the wearer's skin via contact; diapers, sanitary napkins
US6156020 *14 Oct 19985 Dic 2000The Procter & Gamble CompanyAbsorbent article with micro-particulate storage member
US6156024 *3 Dic 19965 Dic 2000The Procter & Gamble CompanyAbsorbent articles having lotioned leg cuffs
US6156157 *21 Abr 19975 Dic 2000Kimberly-Clark Worldwide, Inc.Method for making soft tissue with improved bulk softness and surface softness
US6166285 *31 Oct 199726 Dic 2000The Procter & Gamble CompanyAbsorbent articles having cuffs with skin care composition disposed thereon
US618699226 Jul 199913 Feb 2001The Procter & Gamble CompanyViscous fluid bodily waste management article
US61876958 Dic 199813 Feb 2001Kimberly-Clark Worldwide, Inc.Uniformly distributed surface deposits of a chemical composition that contains an oil, a wax, and preferably a fatty alcohol. suitable compositions include those which have a melting point of 30-70 degrees c.
US61906784 Sep 199820 Feb 2001The Procter & Gamble CompanyComprises water insoluble substrate, lathering surfactant, and a conditioning component; lathering at low surfactant levels, cleansing and exfoliation, and delivery and deposition of conditioning ingredients result, this inventi
US621770719 Dic 199717 Abr 2001Kimberly-Clark Worldwide, Inc.Tissue product comprising additive composition disposed on major surface in at least one primary delivery zone having primary add-on level and at least one supplementary delivery zone having supplementary add-on level
US621788919 Nov 199917 Abr 2001The Proctor & Gamble CompanyPersonal care articles
US623171919 Dic 199715 May 2001Kimberly-Clark Worldwide, Inc.Multilayer; softness
US626158031 Ago 199817 Jul 2001The Procter & Gamble CompanyPaper web with lotion
US626797519 Nov 199931 Jul 2001The Procter & Gamble CompanyPersonal care articles
US628075725 May 199928 Ago 2001The Procter & Gamble CompanyCleansing articles for skin or hair
US6287581 *24 Ago 199911 Sep 2001Kimberly-Clark Worldwide, Inc.Absorbent articles providing skin health benefits
US629693630 Ene 19982 Oct 2001Kimberly-Clark Worldwide, Inc.Coform material having improved fluid handling and method for producing
US630025827 Ago 19999 Oct 2001Kimberly-Clark Worldwide, Inc.Nonwovens treated with surfactants having high polydispersities
US632280119 Nov 199927 Nov 2001The Procter & Gamble CompanyWater insoluble substrate of nonwoven ply and polymeric net, cleansing component
US633885522 Abr 199915 Ene 2002The Procter & Gamble CompanyDisposable cleaning sheets with froths and surfactants
US635274527 Oct 19995 Mar 2002Playtex Products, Inc.From rubber or latex
US6428794 *20 Sep 19956 Ago 2002The Procter & Gamble CompanyLotion composition for treating tissue paper
US644043724 Ene 200027 Ago 2002Kimberly-Clark Worldwide, Inc.Oil in water emulsion comprising natural fat or oil, sterol, humectant, surfactant, and water; enhances skin barrier; baby or hand wipes
US647519724 Ago 19995 Nov 2002Kimberly-Clark Worldwide, Inc.Absorbent articles having skin health benefits
US6476288 *22 Feb 20005 Nov 2002The Procter & Gamble CompanyAbsorbent articles having cuffs and topsheet with skin care composition(s) disposed thereon
US649192819 Ene 200010 Dic 2002The Procter & Gamble CompanyCloth or sponge for cleansing the skin, hair and hard surfaces; cleansing component comprising a surfactant in the layers
US649193316 Feb 200110 Dic 2002The Procter & Gamble CompanyPersonal care articles comprising hotmelt compositions
US649515118 Jun 200117 Dic 2002The Procter & Gamble CompanyDisposable product; dry water insolubility substrate; foamingsurfactant
US649828414 Nov 199724 Dic 2002The Procter & Gamble CompanyDisposable absorbent article with a skin care composition on an apertured top sheet
US650352620 Oct 20007 Ene 2003Kimberly-Clark Worldwide, Inc.Absorbent articles enhancing skin barrier function
US651502923 Abr 19994 Feb 2003Kimberly-Clark Worldwide, Inc.Absorbent garments, such as disposable diapers and adult incontinence garments, which include a hydrophilic lotionized bodyside liner for improved skin health benefits
US65340748 Feb 200118 Mar 2003Kimberly-Clark Worldwide, Inc.Absorbent articles providing skin health benefits
US65700542 May 200027 May 2003The Procter & Gamble CompanyDisposable products; multilayer, impervious backings, absorber core and overcoatings
US6586652 *24 Jun 19991 Jul 2003The Procter & Gamble CompanyArticle comprising liquid impervious backsheet joined to liquid pervious, hydrophilic topsheet having on outer surface lotion coating comprising water-free emollient and agent capable of immobilizing emollient, and absorbent core between
US661664129 Nov 20019 Sep 2003Unilever Home & Personal Care Usa, Division Of Conopco, Inc.Film on at least part of said fibers comprising: i. at least one member selected from the group consisting of lipid emollients, lubricants and protectants; and ii. a surfactant.
US66237467 Jul 199923 Sep 2003Cognis Deutschland Gmbh & Co. KgRapid, uniform penetration of recycled fibers; phase inversion temperature (PIT) material containing fatty esters and alcohols, fatty alcohol modified polyether and fatty acid partial glycerides; biodegradable
US6627787 *20 Jul 199930 Sep 2003The Procter & Gamble CompanySpraying, printing, coating or extruding emollient comprising petroleum, fatty acid ester, alkyl ethoxylate, fatty ester ethoxylate, and/or polysiloxane; feces abhesion
US66730541 Sep 20006 Ene 2004Silipos Inc.Vitamin incorporated into thermoplastic material
US667398428 Ago 20006 Ene 2004The Procter & Gamble CompanyAbsorbent article with macro-particulate storage member
US668993221 Dic 200110 Feb 2004Kimberly-Clark Worldwide, Inc.Absorbent articles with simplified compositions having good stability
US670353618 Dic 20029 Mar 2004The Procter & Gamble CompanyEnzyme inhibitor is transferred to skin with skin care composition and is available at skin/urine and skin/feces interfaces to inhibit enzymatic activity on skin and to reduce or prevent occurrence of inflammation
US670353714 Oct 19989 Mar 2004The Procter & Gamble CompanyAbsorbent article having improved fecal storage structure
US671644117 Dic 19996 Abr 2004The Procter & Gamble CompanyArticle comprising dispensing means with applied release composition including selected skin care active, release agent and barrier protectant; oleaginous, partially transferable to wearer's skin; contains ethoxylated c20-c40 fatty alcohol
US673038011 Ago 19984 May 2004Safeskin Corp.Readily-donned elastomeric articles
US674986022 Dic 200015 Jun 2004Kimberly-Clark Worldwide, Inc.Outer cover, a liquid permeable bodyside liner with 50-95% of an emollient, 1-40% of a viscosity enhancer and .1-10% of an extracted active botanical and an abosrbent body between; skin healthy diapers, adult incontinence products, etc.
US675652020 Oct 200029 Jun 2004Kimberly-Clark Worldwide, Inc.Hydrophilic compositions for use on absorbent articles to enhance skin barrier
US6792701 *26 Mar 200321 Sep 2004Linda RuffiniFootwear product for therapeutically treating the skin
US679393016 Abr 200321 Sep 2004The Procter & Gamble CompanyComprising: petrolatum; zinc oxide; rheological agent; behenyl alcohol; c2-c44 ester; and polyglyceryl ester
US679740030 Mar 200128 Sep 2004Cognis Deutschland Gmbh & Co. KgMoist wipes (II)
US680349610 Sep 199712 Oct 2004The Procter & Gamble CompanyMethod for maintaining or improving skin health
US682539312 Mar 200330 Nov 2004The Procter & Gamble CompanyAbsorbent article having a lotioned topsheet
US686096722 Ene 20021 Mar 2005Sca Hygiene Products GmbhA tissue paper penetrated with a lotion formulation being a liquid, viscous water in oil emulsion includes an oil, a nonionic water in oil emulsifier, a wax and a humectant; provides bulk softness to the tissue paper
US68615718 Ago 19971 Mar 2005The Procter & Gamble CompanyA liquid-permeable topsheet partially coated with lotion to benefit the skin and/or reduce the adherence of feces to the skin for easy cleaning; protective coatings; disposable products; diapers; training pants; incontinence
US6881207 *30 Jun 199819 Abr 2005Rhonda TracyDisposable diaper with padded waistband and legholes
US6896667 *27 Feb 200324 May 2005Linda A. CarterFoot and hand treatment system
US690569722 Ene 200214 Jun 2005Sca Hygiene Products GmbhLotioned fibrous web having a short water absorption time
US69535821 Jul 200211 Oct 2005Sheh Wei (Usa), Inc.Skin-enhancing glove and method of manufacture
US69558176 Sep 200218 Oct 2005The Procter & Gamble CompanyCleansing articles for skin or hair
US6972010 *17 Oct 20036 Dic 2005The Procter & Gamble CompanySanitary napkins/panty-liners/baby diapers; improved comfort/freshness
US700380410 Dic 200328 Feb 2006Kimberly-Clark Worldwide, Inc.Surgical gown incorporating a skin wellness agent
US700545318 Sep 200028 Feb 2006Miller Brewing CompanyPlant extracts comprising tetrahydroiso alpha acid or hexahydro beta acid at concentrations effective againsts staphylococcus aureus but not lactobacillus; preferential; disposable products
US70055573 Jul 200128 Feb 2006The Procter & Gamble CompanyFilm-forming compositions for protecting skin from body fluids and articles made therefrom
US703364513 May 200425 Abr 2006The Procter & Gamble Companycoating a skin contacting surface of an article of clothing with a mixture of a skin care ingredient, a carrier, and a rheological agent; the non flowable composition is readily transferable to a wearer's skin via contact
US711553519 Nov 19993 Oct 2006The Procter & Gamble CompanyDry, disposable article; layers of a water insoluble substrate of a composite and a non-scouring, lofty, low-density batting layer of hydrophobic, polyolefin fibers or polyester fibers, a non-lofty, fluid-permeable nonwoven layer and a cleansing component
US71155513 Jun 20033 Oct 2006The Procter & Gamble CompanyWater insoluble substrate; elastomer surface and foaming surfactant; disposable product; wetting, contacting skin
US716629229 Jun 200123 Ene 2007The Procter & Gamble CompanyTop-biased beneficial components on substrates
US719577121 Nov 200027 Mar 2007Kimberly-Clark Worldwide, Inc.Water-soluble lotions for paper products
US732043627 Feb 200422 Ene 2008Sca Hygiene Products AbMethod of producing an absorbent article and an absorbent article produced according to the method
US734801818 Nov 200425 Mar 2008The Procter & Gamble CompanyMethods of cleansing skin or hair with cleansing articles
US742300314 Ago 20019 Sep 2008The Procter & Gamble CompanyResist folding, especially refolding upon themselves even after an initial fold has been formed in the sheet.; used in dryers
US7427412 *21 Jun 200023 Sep 2008Color Access, Inc.Gel-based cosmetic composition
US745254731 Mar 200418 Nov 2008Johnson&Johnson Consumer Co., Inc.Product for treating the skin comprising a polyamine microcapsule wall and a skin lightening agent
US748537311 Sep 20033 Feb 2009Kimberly-Clark Worldwide, Inc.Lotioned tissue product with improved stability
US7509689 *2 Jun 200631 Mar 2009Reardon Timothy ABathing poncho
US754744311 Sep 200316 Jun 2009Kimberly-Clark Worldwide, Inc.Skin care topical ointment
US77717353 Abr 200310 Ago 2010Kimberly-Clark Worldwide, Inc.Bodyfacing surface composition includes hydrophilic solvent, a high molecular weight polyethylene glycol, grape seed or green tea extract, and optionally a fatty alcohol and/or acid
US777245529 Jun 199910 Ago 2010The Procter & Gamble CompanyDisposable article providing improved management of bodily exudates
US7850821 *24 Ago 200514 Dic 2010Daio Paper CorporationPolyester; softness ; tensile strength
US785166821 Jun 200614 Dic 2010The Procter & Gamble CompanyAbsorbent article and method for maintaining or improving skin health
US78675107 Sep 200611 Ene 2011BioLargo Life Technologies, IncMaterial having antimicrobial activity when wet
US787991529 Nov 20071 Feb 2011Cognis Ip Management GmbhEmulsions for finishing textiles and paper
US793585915 Ene 20043 May 2011The Procter & Gamble CompanyArticle having improved fecal storage structure
US7971276 *1 Dic 20055 Jul 2011Ansell Healthcare Products, LlcGlove with hand-friendly coating and method of making
US7972475 *9 Ene 20095 Jul 2011The Procter & Gamble CompanySoft tissue paper having a polyhydroxy compound and lotion applied onto a surface thereof
US798898313 Sep 20022 Ago 2011Ansell Healthcare Products LlcMicroencapsulation coating for gloves
US80442563 Mar 200925 Oct 2011The Procter And Gamble CompanyAbsorbent article having a stable skin care composition
US8053626 *11 Jun 20038 Nov 2011Sca Hygiene Products AbAbsorbent article containing a skincare composition and method of making and using same
US813838816 Nov 201020 Mar 2012The Procter & Gamble CompanyAbsorbent article and method for maintaining or improving skin health
US81569472 Feb 201017 Abr 2012Deanne ViolaMethod and apparatus for pedicure foot health protection
US822696418 Ene 200824 Jul 2012Biolargo Life Technologies, Inc.Systems and methods for cleaning liquid carriers related applications data
US827336717 Oct 200325 Sep 2012The Procter And Gamble CompanyIn particular to hygienic disposable absorbent articles like sanitary napkins, panty liners, tampons, incontinent pads, diapers, interlabial pads, breast pads, perspiration pads
US830978823 Ene 200913 Nov 2012The Procter And Gamble CompanyProtease inhibitors in absorbent articles
US837816829 Ene 200419 Feb 2013The Procter And Gamble CompanyArticle having a lotioned topsheet
US842088322 Nov 201116 Abr 2013The Procter & Gamble CompanyAbsorbent article and method for maintaining or improving skin health
US854586122 Dic 20041 Oct 2013Sca Hygiene Products GmbhTissue web treated with relatively low viscosity oil in water emulsion; easily be wet for excellent sinking behaviour in water; use as toilet paper
US856956824 Mar 201129 Oct 2013The Procter & Gamble CompanyArticle having improved fecal storage structure
US857461010 Ene 20115 Nov 2013Biolargo Life Technologies, Inc.Material having antimicrobial activity when wet
US858088212 Ago 201012 Nov 2013Joesph L. BarnesGlove-forming solution
US863279317 Ene 200721 Ene 2014The Procter & Gamble CompanyTop-biased beneficial components on substrates
US864264530 Ene 20124 Feb 2014Brooks Kelly Research, LLC.Pharmaceutical composition comprising Cannabinoids
US879571618 Nov 20045 Ago 2014The Procter & Gamble CompanySkin care compositions on a thin sanitary napkin
EP0300814A2 *22 Jul 198825 Ene 1989JOHNSON & JOHNSON MEDICAL, INC.Antimicrobial medical glove
EP0782869A1 *21 Nov 19969 Jul 1997TEBBE, GeroldMaterial coated with micro-capsules
EP0938886A2 *30 Dic 19981 Sep 1999Kimberly-Clark Worldwide, Inc.Cool feeling tissue
EP1032336A114 Nov 19976 Sep 2000THE PROCTER & GAMBLE COMPANYDisposable absorbent article with a skin care composition on an apertured topsheet
EP1360940A1 *18 Mar 200312 Nov 2003Belle L. ChouAnti-microbial elastomeric flexible article, such as a glove, and manufacturing method
EP1757261A2 *12 Jul 200228 Feb 2007JOHNSON & JOHNSON GmbHProducts comprising a sheet and a lipid and aqueous phase
EP1930500A1 *8 Dic 200611 Jun 2008Cognis IP Management GmbHEmulsions for the softening of textiles and paper
WO1994012115A1 *22 Nov 19939 Jun 1994Buchanan IncProtective medical glove and antibacterial/antiperspirant composition for reducing bacterial growth during use of medical gloves
WO1995016824A1 *30 Nov 199422 Jun 1995Procter & GambleLotion composition for imparting soft, lubricious feel to tissue paper
WO1995035411A1 *23 May 199528 Dic 1995Procter & GambleLotioned tissue paper
WO1995035412A1 *23 May 199528 Dic 1995Procter & GambleImproved lotion composition for treating tissue paper
WO1997006307A1 *25 Jul 199620 Feb 1997Procter & GambleLotioned tissue paper containing a liquid polyol polyester emollient and an immobilizing agent
WO2000004230A1 *7 Jul 199927 Ene 2000Achim AnsmannUse of pit emulsions
WO2000012170A1 *9 Ago 19999 Mar 2000Silipos IncGelatinous body protection article having a therapeutic additive
WO2001049935A1 *15 Dic 200012 Jul 2001Sca Hygiene Prod GmbhA method of applying frozen treatment chemicals to a fiber-based planar product and resulting products
WO2001076445A1 *30 Mar 200118 Oct 2001Cognis Deutschland GmbhMoist wipes (ii)
WO2004012698A2 *16 Jul 200312 Feb 2004Harald AlbrechtSoap-containing cleaning substrate
WO2004060432A116 Sep 200322 Jul 2004Kimberly Clark CoElastomeric articles with beneficial coating on skin-containing surface
WO2004075808A2 *23 Feb 200410 Sep 2004Carter Linda AFoot and hand treatment system
WO2005060774A1 *5 May 20047 Jul 2005Kimberly Clark CoSurgical gown incorporating a skin wellness agent
WO2006106546A1 *13 Mar 200612 Oct 2006Massimo Guarducci S R LTextile product having particular functional properties for the skin and process for the preparation thereof
WO2007025095A1 *24 Ago 20061 Mar 2007Procter & GambleBulk softened fibrous structures
WO2008067944A1 *29 Nov 200712 Jun 2008Cognis Ip Man GmbhEmulsions for finishing textiles and paper
WO2009021299A1 *8 Ago 200819 Feb 2009Leticia Gomes Tavares BalbinoPlastic gloves, boots and slippers coated with an emollient and sanitizing formula, intended for professional use by manicures / pedicures, that dispense the use of water due to providing hydration of the skin, nails and cuticles by occlusion
WO2013102256A1 *28 Dic 201211 Jul 2013Idéexaction Inc.Glove with moisture absorbent applicator layer
Clasificaciones
Clasificación de EE.UU.604/289, 604/304, 424/402, 2/901, 604/358, 604/360, 604/292, 424/443, 604/303
Clasificación internacionalA61K8/02, A61Q19/00, A41D13/11, A61K47/06, A61M35/00, A45D44/00, A41D19/00
Clasificación cooperativaY10S2/901, A41D13/11, A41D19/00, A61K8/0208, A61Q19/00, A61K8/02, A41D2400/32, A61K9/0014, A61K47/06, A61M35/00, A45D44/00
Clasificación europeaA61K8/02, A61K9/00M3, A61K47/06, A61K8/02C, A61M35/00, A61Q19/00, A41D13/11, A45D44/00, A41D19/00
Eventos legales
FechaCódigoEventoDescripción
4 Jun 1984AS02Assignment of assignor's interest
Owner name: PROCTER & GAMBLE COMPANY, 6100 CENTER HILL ROAD, C
Owner name: SZUCH, CLYDE A.
Effective date: 19840516
4 Jun 1984ASAssignment
Owner name: PROCTER & GAMBLE COMPANY, 6100 CENTER HILL ROAD, C
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:SZUCH, CLYDE A.;REEL/FRAME:004273/0245
Effective date: 19840516
Owner name: SZUCH, CLYDE, C/O PITNEY, HARDIN, KIPP & SZUCH, 16
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:BUCHALTER, GILBERT;REEL/FRAME:004273/0240
Effective date: 19840503