US4120731A - Method of making molten silicon infiltration reaction products and products made thereby - Google Patents
Method of making molten silicon infiltration reaction products and products made thereby Download PDFInfo
- Publication number
- US4120731A US4120731A US05/660,261 US66026176A US4120731A US 4120731 A US4120731 A US 4120731A US 66026176 A US66026176 A US 66026176A US 4120731 A US4120731 A US 4120731A
- Authority
- US
- United States
- Prior art keywords
- silicon
- mold
- carbon
- silicon carbide
- particulated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/58—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides
- C04B35/583—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on borides, nitrides, i.e. nitrides, oxynitrides, carbonitrides or oxycarbonitrides or silicides based on boron nitride
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/56—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
- C04B35/565—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide
- C04B35/573—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide obtained by reaction sintering or recrystallisation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12486—Laterally noncoextensive components [e.g., embedded, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/16—Two dimensionally sectional layer
- Y10T428/163—Next to unitary web or sheet of equal or greater extent
- Y10T428/164—Continuous two dimensionally sectional layer
- Y10T428/166—Glass, ceramic, or metal sections [e.g., floor or wall tile, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/30—Self-sustaining carbon mass or layer with impregnant or other layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
Definitions
- FIG. 2 An additional aspect of the present invention can be seen by FIG. 2, showing how a silicon carbide composite can be formed in accordance with one method of the present invention based on the infiltration by molten silicon into a mold cavity containing a refractory base structure in contact with a contiguous preform consisting of a mixture of carbon particles and a particulated inorganic material.
- the source of the silicon is contained in the space above the mold cavity.
- machinable castings having a density of from 1.6 g/cm 3 2.7 g/cm 3 which are the infiltration products of reaction of molten silicon and a substantially uniform mixture comprising by volume
- the contiguous machinable layer can be applied onto the base structure either directly or by in-situ formation based on molten silicon infiltration.
- the contiguous layer at thicknesses of from 0.01 inch to 1 inch or more can be fabricated onto an appropriate base structure, where contiguous layer thickness may correspondingly vary from 0.1 to 100 times the thickness of the base structure.
- Example 2 As described in Example 1, the mold and the supporting structure were placed inside of a furnace and heated to a temperature of about 1600° C. Upon being converted to molten silicon, infiltration was immediate. After about 15 minutes at 1600° C the mold was allowed to cool.
Abstract
Infiltration reaction products are provided of molten silicon and certain blends of particulated carbon and various particulated inorganic materials substantially unreactive to molten silicon, such as boron nitride particles. These molten silicon infiltration products of reaction are readily machinable and can be applied, or formed in-situ as contiguous layers on silicon carbide, or silicon-silicon carbide substrates, etc., to produce multilayer composites having an improved impact strength over the base refractory structure.
Description
The present invention relates to a method for making infiltration products of reaction of molten silicon and blends of particulated carbon and a particulated inorganic material, such as boron nitride particles. More particularly, the present invention relates to readily machinable silicon carbide compositions, and composites of such compositions as a contiguous layer on a silicon carbide base structure.
As shown in copending application Ser. No. 572,969, filed Apr. 30, 1975, of William Laskow and Robert Morelock, there is described a method for making silicon carbide-silicon matrix composites by the infiltration of carbon fibers by molten silicon. Although the resulting silicon carbide-silicon matrix materials and method for making such shaped structures represented a significant advance in manufacture of high performance shaped ceramics, it has been found that in many instances the impact resistance of the shaped ceramic structures is not sufficiently high to qualify them for a variety of uses.
The present invention is based on the discovery that readily machinable reaction products also based on molten silicon infiltration can be made by effecting molten silicon infiltration into a substantially uniform blend of particulated carbon and a finely divided inorganic material substantially nonreactive to molten silicon, such as boron nitride particles.
In addition to the above-described machinable reaction products based on molten silicon infiltration, there is also provided by the present invention, silicon carbide refractory composite structures having substantially improved impact strength over shaped silicon carbide refractories of the prior art. These composites of silicon carbide or silicon-silicon carbide can have a refractory base structure, and an exterior contiguous layer of the above-described machinable reaction product based on molten silicon infiltration. The silicon carbide composites of the present invention can be made by introducing molten silicon into a mold whereby the contiguous machinable layer in contact with the base structure is formed in-situ. The latter silicon carbide base structure moreover may be formed simultaneously with the contiguous layer by molten silicon infiltration of the base structure in the form of a carbon fiber preform.
Further features of the present invention can be seen from the drawings, where in
FIG. 1 there is shown a mold filled with a mixture of carbon particles and a particulated inorganic material, such as boron nitride, and above the mold there is shown silicon powder or granules in contact with carbon fiber wicks constituting a molten silicon source for infiltration into the mixture of carbon particles and particulated inorganic material.
An additional aspect of the present invention can be seen by FIG. 2, showing how a silicon carbide composite can be formed in accordance with one method of the present invention based on the infiltration by molten silicon into a mold cavity containing a refractory base structure in contact with a contiguous preform consisting of a mixture of carbon particles and a particulated inorganic material. The source of the silicon is contained in the space above the mold cavity.
Another feature of the present invention can be seen from FIG. 3, where there is shown silicon in contact with carbon wicks above a mold. The mold is filled with a carbon fiber preform which is surrounded by a contiguous preform of a mixture of particulated carbon and a particulated inorganic material.
An additional aspect of the present invention can be seen from FIG. 4, showing the use of a multilayer contiguous preform on a base structure to produce a further modification of the composite of the present invention.
As shown by FIG. 1, there is provided by the present invention, machinable castings having a density of from 1.6 g/cm3 2.7 g/cm3 which are the infiltration products of reaction of molten silicon and a substantially uniform mixture comprising by volume
(A) from 45% to 90% of particulated carbon having up to an equal proportion by volume based on the volume of (A), of silicon carbide particules, and
(B) from 10% to 55% of a particulated inorganic material substantially inert to molten silicon at temperatures up to 1600° C having an average particle size of from 0.1 to 2000 microns and a Mohs hardness value falling within the range of 1-7.
The machinable castings of the present invention can be initially molded into any desired configuration and thereafter cut by conventional means. These relatively light weight silicon carbide containing materials resulting from the infiltration by molten silicon into the mixture containing carbon particles can be cut with steel saw, drilled, sanded, filed, etc., to any desired shape. If desired to be used as a protective impact resistant coating or layer, the machinable castings can be welded at a self supporting thickness onto a silicon or silicon carbide substrate to improve the substrate impact strength. This procedure can be used as an optional alternative to the procedure shown by FIG. 2, where the machinable layer is cast in-situ.
In addition to the above described uses, the machinable castings of the present invention can be cut to a thickness of from 0.01 to 1 or more inches and used as thermal gradient barriers on various substrates where attachment can be achieved by mechanical insertion, bolting, etc., combustors in such applications as diffusers, transition pieces, etc. Other uses are, for example, molds for metal casting, gas burner components, tooling, lap surface plates, and high temperature fixtures.
There is also provided by the present invention a method for making a silicon carbide composite, comprising a refractory base structure and a contiguous machinable or compliant layer structure, which comprises,
(1) introducing molten silicon into a mold substantially filled with a composite having a base structure, and a contiguous exterior layer, where the base structure is a member selected from
(i) a shaped mass of silicon carbide,
(ii) a composite of silicon and silicon carbide, and
(iii) a carbon fiber preform
and the contiguous exterior layer comprises a uniform mixture of particulated carbon and a particulated inorganic material substantially non-reactive to molten silicon and having a Mohs hardness in the range of from about 1 to about 7,
(2) allowing the molten silicon to fully infiltrate into said mold, while allowing gases of reaction to vent therefrom and
(3) removing the resulting silicon carbide composite from the mold.
Included by the types of particulated carbon which can be used in making the machinable castings of the present invention, or the contiguous layers on the composites of the present invention are carbon fiber or graphite fiber, carbonized plant fibers, lamp black, fine divided coal, wood, charcoal, etc. The particulated inorganic material which can be employed in combination with the carbon particles includes, for example, boron nitride, aluminum oxide, magnesium oxide, silicon nitride, etc., having an average aggregate size of from 1 to 2000 microns. It is understood that individual crystallites or subparticles which may comprise the aggregates can be substantially smaller.
The machinable castings of the present invention also can include the reaction product of molten silicon and the mixture of carbon fiber, or graphite fiber, or mixtures thereof, and the aforedescribed inorganic material which mixture can also comprise up to 50% by volume of other fillers, such as silicon carbide whiskers, or other particulated forms of silicon carbide. In addition to silicon carbide, other filler materials also can be used which are substantially nonreactive to molten silicon and include, for example, aluminum oxide, or zirconium oxide filaments. It may be advantageous to coat such filler materials with carbon, for example, by pyrolytic deposition from carbonaceous gas or gas mixture. The carbon coating promotes wetting and provides a chemical barrier between the oxide and the filament. The mixture of carbon fiber and inorganic material, such as boron nitride, can be present in the mold either in the form of a free flowing powder, or as a rigid preform which can be made by mixing together the inorganic material and optionally any other filler with a bonding agent for graphite, or carbon fiber, such as the graphite suspensions available from the Dylon Company. In accordance with the method of the present invention, shaped parts made from the carbon fiber and inorganic material containing mixture have improved impact resistance and abradability.
In FIG. 1, there is more particularly shown apparatus for making the machinable castings of the present invention. There is shown a side view of a mold support at 10 and a powdered silicon charge at 11. Infiltration by molten silicon into the mixture of particulated carbon and particulated inorganic material at 13 can be effected at temperatures of 1400° C to 1700° C through wicks at 12 which can be carbon fibers, such as WYK braid, or WYB tow of Union Carbide typical lengths being 3 CM. At 14 and 15 hot gas vents are provided to relieve build-up of mold pressure.
Melting of the powdered silicon can be effected by placing the apparatus of FIG. 1, into a suitable furnace. If desired, heating coils can be used to surround the powdered silicon source. A mold release agent, such as boron nitride, can be sprayed onto the inside walls of the mold, as shown in the application of William B Hillig, Ser. No. 419,286, filed Nov. 27, 1973, now abandoned and assigned to the same assignee as the present invention.
There is further shown in FIG. 2, a side view of a mold having a base part of silicon carbide refractory at 23, which includes silicon-silicon carbide refractories. There is shown at 22, contiguous self-supporting preforms of the mixture of carbon particles and particles of the inorganic material as previously defined. If desired, the contiguous preforms can be made in a variety of shapes from pastes of the mixture of particulated ingredients by standard techniques using Dylon as previously indicated. Again, infiltration of molten silicon from the powdered source at 20 through carbon wicks at 21, can provide the in-situ formation of the composite of the refractory base and a machinable, compliant contiguous layer.
At FIG. 3, there is shown an additional way of making a composite by an in-situ procedure to form a refractory silicon-silicon carbide base and a compliant machinable exterior layer. A molten silicon source is shown at 30 and carbon fiber wicks at 31. Contiguous layers of the mixture of carbon particles and particles of inorganic material are shown at 32. At 33, there is shown a carbon fiber preform which can be fabricated by standard techniques.
As used hereinafter, the term carbon fiber or filaments includes commercially available carbon fiber as previously defined. The carbon fiber includes, for example, "high strength" graphite having a tensile psi of typically 250,000 psi, a modulus of 20 × 106 psi and a carbonized density of 1.6 g/cc, as shown by Johnson et al U.S. Pat. No. 3,412,062. Preferably, the carbon fiber has a specific gravity of about 1.3 to 1.5 and includes, for example, WYK braid, WYB tow of Union Carbide Corp., and other carbonized fibers, such as carbon felt. In addition to carbonized rayon fibers, any carbon fibers having a specific gravity as defined above derived from polymeric or natural organics, such as polyacrylonitrile, polyacetylene, such as shown by Krutchen U.S. Pat. No. 3,852,235, assigned to the same assignee as the present invention, polyvinyl chloride, polyvinyl acetate, etc., can be employed. The term "preform", as used hereinafter, is preferably a shaped structure of oriented carbon fibers, such as a pre-preg. To make a preform, a carbon fiber tow, braid or cloth is treated with molten wax or other binder, such as cellulose nitrate, colloidal graphite, etc.
More particularly at FIG. 4, there is shown a base structure at 44, in contact with a multi-layer contiguous compliant exterior structure at 42-44. The base structure can consist of a silicon carbide refractory, as shown by FIG. 2, or a carbon fiber preform, as shown in FIG. 3. The contiguous layer structure can consist of a preform mixture of carbon particles and particles of inorganic material at 42, a middle layer of carbon fiber or carbon sheet at 43, and another preform similar to 42 and 44. Improved impact strength and toughness can be imparted to the machinable contiguous layer and the base layer upon infiltration by molten silicon.
In addition to the above described machinable castings, there is also provided by the present invention, composites comprising,
(C) a contiguous machinable exterior layer, and
(D) a refractory base structure, where the contiguous machinable exterior layer is the infiltration product of reaction by molten silicon and a substantially uniform mixture comprising by volume,
from 45% to 90% of particulated carbon having up to an equal proportion by volume, based on the total volume of the mixture of silicon carbide particles, and
from 10% to 55% of a particulated inorganic material, substantially inert to molten silicon at temperatures up to 1600° C, having an average particle size of from 0.1 to 2000 microns, and a Mohs hardness value falling within the range of 1-7, and the refractory base structure is a member selected from the class of shaped silicon carbide refractories and the infiltration product of reaction by molten silicon and a carbon fiber preform.
In accordance with the method of the present invention, the above-described composites of the present invention can be fabricated to gas turbine shroud sections, aircraft engine shroud sections, gas turbine transition pieces, diesel engine pistons and rings, heat exchange pipes, hot processing dies, combustion liners, fusion reactor hardware, wear resistant tiles, etc.
As previously indicated, in making the above composites of the present invention, the contiguous machinable layer can be applied onto the base structure either directly or by in-situ formation based on molten silicon infiltration. For example, the contiguous layer at thicknesses of from 0.01 inch to 1 inch or more can be fabricated onto an appropriate base structure, where contiguous layer thickness may correspondingly vary from 0.1 to 100 times the thickness of the base structure.
In order that those skilled in the art will be better able to practice the invention, the following examples are given by way of illustration and not by way of limitation. All parts are by weight, unless otherwise specified.
A mixture of 25% by weight or 20% by volume of boron nitride obtained from the Carborundum Company, designated SHP-40 and 75% by weight or 80% by volume of a graphite suspension obtained from the Dylon Company, designated grade AE was blended to a thick paste consistancy. The paste was then molded to a flat rectangle having a 1/8 inch thickness and allowed to dry in the air.
A mold was fabricated from Armco Speer 580 graphite having an initial thickness of about 3/4 inch by machining it to produce a mold cavity of about 1/8 inch × 1/8 inch × 3 inches. The inside of the mold cavity was then coated with a boron nitride aerosol. The above blend of boron nitride and graphite was then cut to size and inserted into the mold. A carbon having an inside diameter of 11/4 inches and about 2 inches high having a 1/8 inch diameter hold drilled at the bottom and a carbon fiber wick extending through the hole was placed on top of the mold. The carbon fiber wick was WYK braid of Union Carbide and it extended about 0.125 inches above the top of the hole and also touched the above-described blend in the mold. The crucible was then charged with solid silicon pieces employing about 15% excess of the amount of silicon required to fill the mold cavity in the molten state. The assembly was transferred to a resistance furnace in which a vacuum of 1 × 10-2 torr would be achieved. The assembly was heated to a temperature of about 1600° C. It was found that the mixture in the mold reacted immediately with the molten silicon. The mold assembly was kept in the furnace for about 15 minutes after reaching 1600° C. The mold assembly was then allowed to cool and the resulting part was removed from the mold. There was obtained a cast part having the same dimensions as the original blend of boron nitride and graphite.
Based on method of preparation, the cast part was the infiltration product of reaction by molten silicon and a mixture of 25% by weight of boron nitride and 75% by weight of graphite which expressed in terms of volume is about 20% by volume of boron nitride and 80% by volume of graphite. The density of the casting was found to be 2.1 g/cm3. The casting was then placed in a vice and cut with a steel saw to produce a specimen 1/8 inch × 11/2 inches × 1/8 inch. It was found that the casting was readily machinable; the remaining portion of the casting could be readily filed out with a steel file.
A 1 inch × 2 inches × 1/8 inch flat plate of the above machinable casting is placed as a contiguous layer on a 1 inch × 2 inches × 1/2 inch block of silicon carbide. The resulting composite is then furnace heated in an inert atmosphere for 15 minutes at a temperature of 1500° C. There is obtained a composite upon cooling having the machinable casting integrally welded onto the silicon carbide refractory base.
An impact test was performed to compare the impact strength of a 1 inch × 2 inches × 1/2 inch block of silicon carbide and the above composite. Impact resistance is determined by striking the surface of a test sample with a 4.5 mm ball bearing at a velocity of about 200 meters per second and at an incident angle of about 80°. It is found that the composite of the silicon carbide having the machinable casting welded on as a contiguous layer has an impact resistance superior to the impact resistance of the silicon carbide base structure free of such contiguous layer.
Blends of graphite and boron nitride were fabricated in accordance with the procedure of Example 1 to produce slabs having a thickness of about 1/8 inch. A mold was then machined out of a Speer 580 graphite, in accordance with the procedure of Example 1 having a cavity of 1 inch × 3 inches × 0.1 inch. The mold was coated with boron nitride. A silicon carbide part was then placed in the mold surrounded by the preformed strips of graphite and boron nitride cut to size which totally filled the mold. As shown in FIG. 2, three holes having a 0.125 diameter were cut into the top of the mold and several vent holes were drilled into the bottom of the mold. Into the holes at the top of the mold there was placed carbon fiber wicks which protruded about 1/8 inch above the top of the mold while contacting the boron nitride-graphite strips within the mold. Particulated silicon was then charged to the cavity above the top of the mold using about a 15% excess over that volume required in molten form to fully infiltrate the mold.
As described in Example 1, the mold and the supporting structure were placed inside of a furnace and heated to a temperature of about 1600° C. Upon being converted to molten silicon, infiltration was immediate. After about 15 minutes at 1600° C the mold was allowed to cool.
Removal of the part from the mold was readily achieved because the mold surface had been sprayed with boron nitride prior to being filled with the carbon-boron nitride strips and silicon carbide part. Based on method of preparation there was obtained a composite of a silicon carbide refractory having approximately a 1/8 inch contiguous layer of the molten silicon infiltration product of reaction by molten silicon and a mixture of graphite and boron nitride. It was found that the contiguous layer was integrally bonded to the silicon carbide refractory base.
The impact strength of the above described composite was substantially the same as the impact strength of the composite formed in accordance with Example 1 by welding the piece of the machinable casting onto the surface of the silicon carbide structure by a furnace treatment. In addition to improved impact strength, the contiguous layer was found to be readily machinable as evidenced by being readily abraded by use of a diamond saw blade which was capable of cutting into the surface of the layer at a rate of between 0.05 to 0.5 inch per second. The diamond wheel had a 4 inch diameter having a 3/8 inch width, a diamond grit size of 150 mesh, rotating at 5500, RPM, at a depth of 0.002 inch and a cutting speed of 0.2 inch per second, pulling forces of 90 to 600 grams were used.
A carbon fiber preform is prepared from low modulus WCA carbon cloth of Union Carbide Corporation, using an aqueous colloidal suspension of graphite as a binder. The carbon fiber preform was machined to a shape similar to that shown by FIG. 3. Following the procedure of Example 2, strips of boron nitride-graphite mixture which had been molded to a thickness of about 1/8 inch were placed in a 1 inch × 3 inches × 0.1 inch mold previously coated with boron nitride which had been machined from Speer 580 graphite. The space above the mold was then charged with silicon powder.
Following the procedure of Example 2, infiltration by molten silicon in the mold resulted in the production of a composite having a silicon-silicon carbide base structure and a contiguous exterior layer of the reaction product of molten silicon and a mixture of graphite and graphite-boron nitride. The impact strength of the aforementioned composite as tested in accordance with the procedure of Example 1, showed that it exhibited improved impact as compared to a silicon-silicon carbide refractory part which was molded from the same mold without the use of the exterior graphite-boron nitride contiguous layer allowing for the use of a proportionately larger carbon fiber preform which was sufficient to completely fill the mold cavity.
As shown by FIG. 4, a mold was vertically fabricated to accommodate a carbon fiber preform in the mold adjacent to a multi-layer contiguous structure consisting of carbon cloth sandwiched in between two strips of a graphite-boron nitride blend which was fabricated in accordance with Example 1. Prior to the incorporation of the carbon fiber preform and the aforementioned contiguous layer structure, the mold surface had been coated with boron nitride in a standard manner. Molten silicon infiltration was effected in accordance with the procedure of Example 2. Upon cooling a composite part was separated from the mold. It was found that molten silicon infiltration occurred in the contiguous graphite-boron nitride layers and the carbon fiber preform. Infiltration also occurred in the intermediate layer of carbon cloth constituting part of the contiguous layer. It was further found that the contiguous layer on the silicon-silicon carbide refractory substrate was somewhat tougher and less machinable than the contiguous layer of Example 2. However, the impact resistance of the resulting composite is superior to that of Example 2.
Although the above examples are limited to only a few of the very many variables and compositions which can be employed in the practice of the present invention, it should be understood that the present invention is broadly directed to machinable castings as set forth in the broad description preceding these examples as well as composites of silicon carbide having a machinable contiguous layer which can be formed in accordance with the practice of the present invention as well as a method for making such composites.
Claims (3)
1. Machinable castings having a density of from 1.6 to 2.7 g/cm3 which are the infiltration products of reaction under vacuum conditions and at a temperature of from 1400° C to 1700° C of molten silicon and a substantially uniform mixture consisting essentially of by volume
(A) from 45% to 90% of particulated carbon having up to an equal proportion by volume based on the volume of (A) of silicon carbide particles, and
(B) from 10% to 55% of particulated boron nitride.
2. A machinable casting in accordance with claim 1, where the particulated carbon is in the form of carbon fiber.
3. A particulated casting in accordance with claim 1, where the particulated carbon is in the form of a mixture of carbon fiber and silicon carbide particles.
Priority Applications (16)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/660,261 US4120731A (en) | 1976-02-23 | 1976-02-23 | Method of making molten silicon infiltration reaction products and products made thereby |
FR7702358A FR2341534A1 (en) | 1976-02-23 | 1977-01-28 | MACHINABLE MOLDINGS OBTAINED BY INFILTRATION OF MOLTEN SILICON |
GB3805/77A GB1556881A (en) | 1976-02-23 | 1977-01-31 | Method of making molten silicon infiltration reaction products and products made thereby |
BE174632A BE851054A (en) | 1976-02-23 | 1977-02-03 | MACHINABLE MOLDINGS OBTAINED BY INFILTRATION OF MOLTEN SILICON |
IT20154/77A IT1075555B (en) | 1976-02-23 | 1977-02-10 | METHOD FOR MAKING INFILTRATION PRODUCTS BY SILICATION REACTION AND PRODUCTS MADE WITH IT |
CA272,280A CA1096895A (en) | 1976-02-23 | 1977-02-18 | Molten silicon infiltration reaction products |
DE2760422A DE2760422C2 (en) | 1976-02-23 | 1977-02-19 | |
DE19772707299 DE2707299A1 (en) | 1976-02-23 | 1977-02-19 | PROCESS FOR PRODUCING REACTION PRODUCTS FROM MOLTEN SILICON BY INFILTRATION AND THE PRODUCTS OBTAINED WITH IT |
CH319382A CH641750A5 (en) | 1976-02-23 | 1977-02-21 | METHOD FOR PRODUCING SILICON CARBIDE COMPOSITES. |
CH213677A CH636587A5 (en) | 1976-02-23 | 1977-02-21 | METHOD FOR PRODUCING MACHINABLE CASTING BODIES. |
NLAANVRAGE7701852,A NL184316C (en) | 1976-02-23 | 1977-02-21 | METHOD FOR MANUFACTURING A MECHANICALLY MACHINE CAST AND METHOD FOR MANUFACTURING A SILICON CARBIDE COMPOSITION |
JP1783777A JPS52121614A (en) | 1976-02-23 | 1977-02-22 | Silicon carbide mold articles*compound articles and manufacture |
NO770578A NO145006C (en) | 1976-02-23 | 1977-02-22 | COMPOSITION OF SILICON CARBID CONTAINING GOODS AND PROCEDURES IN MANUFACTURING THEREOF |
US05/849,186 US4148894A (en) | 1976-02-23 | 1977-11-07 | Method of making molten silicon infiltration reaction products and products made thereby |
NO800678A NO145836C (en) | 1976-02-23 | 1980-03-10 | MACHINABLE CASTLES CONSISTING OF SILICON INFILTRATION PRODUCTS IN PARTICULAR BORNITRID, CARBON AND EVENTS SILICON CARBID |
JP61066120A JPS61251577A (en) | 1976-02-23 | 1986-03-26 | Silicon carbide formed body |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US05/660,261 US4120731A (en) | 1976-02-23 | 1976-02-23 | Method of making molten silicon infiltration reaction products and products made thereby |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US05/849,186 Division US4148894A (en) | 1976-02-23 | 1977-11-07 | Method of making molten silicon infiltration reaction products and products made thereby |
Publications (1)
Publication Number | Publication Date |
---|---|
US4120731A true US4120731A (en) | 1978-10-17 |
Family
ID=24648771
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US05/660,261 Expired - Lifetime US4120731A (en) | 1976-02-23 | 1976-02-23 | Method of making molten silicon infiltration reaction products and products made thereby |
US05/849,186 Expired - Lifetime US4148894A (en) | 1976-02-23 | 1977-11-07 | Method of making molten silicon infiltration reaction products and products made thereby |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US05/849,186 Expired - Lifetime US4148894A (en) | 1976-02-23 | 1977-11-07 | Method of making molten silicon infiltration reaction products and products made thereby |
Country Status (11)
Country | Link |
---|---|
US (2) | US4120731A (en) |
JP (2) | JPS52121614A (en) |
BE (1) | BE851054A (en) |
CA (1) | CA1096895A (en) |
CH (2) | CH636587A5 (en) |
DE (2) | DE2707299A1 (en) |
FR (1) | FR2341534A1 (en) |
GB (1) | GB1556881A (en) |
IT (1) | IT1075555B (en) |
NL (1) | NL184316C (en) |
NO (2) | NO145006C (en) |
Cited By (45)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4177047A (en) * | 1978-07-27 | 1979-12-04 | Joy Manufacturing Company | Electrostatic precipitators |
US4238433A (en) * | 1978-12-15 | 1980-12-09 | General Electric Company | Method of making molten silicon infiltration reaction products |
US4247304A (en) * | 1978-12-29 | 1981-01-27 | General Electric Company | Process for producing a composite of polycrystalline diamond and/or cubic boron nitride body and substrate phases |
US4275095A (en) * | 1979-07-31 | 1981-06-23 | Warren Consultants, Inc. | Composite article and method of making same |
US4325930A (en) * | 1980-01-02 | 1982-04-20 | Societe Europeenne De Propulsion | Producing a silicon carbide structure and multidirectional silicon carbide texture |
US4353963A (en) * | 1980-12-17 | 1982-10-12 | General Electric Company | Process for cementing diamond to silicon-silicon carbide composite and article produced thereby |
US4385020A (en) * | 1980-03-27 | 1983-05-24 | General Electric Company | Method for making shaped silicon-silicon carbide refractories |
US4417906A (en) * | 1980-07-09 | 1983-11-29 | General Electric Company | Process for production of silicon carbide composite |
US4448591A (en) * | 1981-01-21 | 1984-05-15 | General Electric Company | Cutting insert having unique cross section |
US4453951A (en) * | 1980-07-09 | 1984-06-12 | General Electric Co. | Process for the production of silicone carbide composite |
US4460382A (en) * | 1981-12-16 | 1984-07-17 | General Electric Company | Brazable layer for indexable cutting insert |
US4544517A (en) * | 1981-12-16 | 1985-10-01 | General Electric Co. | Automatic composite press technique for producing cutting inserts |
US4572848A (en) * | 1983-07-29 | 1986-02-25 | Hoechst Ceramtec Aktiengesellschaft | Process for the production of molded bodies from silicon-infiltrated, reaction-bonded silicon carbide |
US4626516A (en) * | 1985-07-31 | 1986-12-02 | General Electric Company | Infiltration of Mo-containing material with silicon |
US4698070A (en) * | 1981-12-16 | 1987-10-06 | General Electric Company | Cutting insert for interrupted heavy machining |
US4737328A (en) * | 1985-07-29 | 1988-04-12 | General Electric Company | Infiltration of material with silicon |
US4886682A (en) * | 1987-12-14 | 1989-12-12 | General Electric Company | Process for producing a filament-containing composite in a ceramic matrix |
US4931311A (en) * | 1987-12-21 | 1990-06-05 | General Electric Company | Method of obtaining a filament-containing composite with a boron nitride coated matrix |
US4944904A (en) * | 1987-06-25 | 1990-07-31 | General Electric Company | Method of obtaining a fiber-containing composite |
US4971851A (en) * | 1984-02-13 | 1990-11-20 | Hewlett-Packard Company | Silicon carbide film for X-ray masks and vacuum windows |
US4981822A (en) * | 1989-02-17 | 1991-01-01 | General Electric Company | Composite containing coated fibrous material |
US5015540A (en) * | 1987-06-01 | 1991-05-14 | General Electric Company | Fiber-containing composite |
US5021367A (en) * | 1987-06-25 | 1991-06-04 | General Electric Company | Fiber-containing composite |
US5043303A (en) * | 1987-09-28 | 1991-08-27 | General Electric Company | Filament-containing composite |
US5330854A (en) * | 1987-09-24 | 1994-07-19 | General Electric Company | Filament-containing composite |
US5376427A (en) * | 1988-12-27 | 1994-12-27 | General Electric Company | Ceramic composite containing coated fibrous material |
US5432253A (en) * | 1989-12-18 | 1995-07-11 | General Electric Company | Composite containing fibrous material |
US5580834A (en) * | 1993-02-10 | 1996-12-03 | The Morgan Crucible Company Plc | Self-sintered silicon carbide/carbon graphite composite material having interconnected pores which may be impregnated and raw batch and process for producing same |
US5628938A (en) * | 1994-11-18 | 1997-05-13 | General Electric Company | Method of making a ceramic composite by infiltration of a ceramic preform |
US5656563A (en) * | 1993-02-10 | 1997-08-12 | The Morgan Crucible Company Plc | Dense, self-sintered silicon carbide/carbon graphite composite |
US5968653A (en) * | 1996-01-11 | 1999-10-19 | The Morgan Crucible Company, Plc | Carbon-graphite/silicon carbide composite article |
US6024898A (en) * | 1996-12-30 | 2000-02-15 | General Electric Company | Article and method for making complex shaped preform and silicon carbide composite by melt infiltration |
US6335105B1 (en) | 1999-06-21 | 2002-01-01 | General Electric Company | Ceramic superalloy articles |
US6368663B1 (en) | 1999-01-28 | 2002-04-09 | Ishikawajima-Harima Heavy Industries Co., Ltd | Ceramic-based composite member and its manufacturing method |
US6395203B1 (en) | 1999-08-30 | 2002-05-28 | General Electric Company | Process for producing low impurity level ceramic |
US6398991B1 (en) | 1998-06-25 | 2002-06-04 | Coorstek, Inc. | Processes for making a silicon carbide composition |
US6403158B1 (en) | 1999-03-05 | 2002-06-11 | General Electric Company | Porous body infiltrating method |
US6503441B2 (en) | 2001-05-30 | 2003-01-07 | General Electric Company | Method for producing melt-infiltrated ceramic composites using formed supports |
EP1346967A2 (en) * | 2002-03-19 | 2003-09-24 | Sgl Carbon Ag | Method for infiltration of porous carbon composites |
US6774073B2 (en) | 2002-07-29 | 2004-08-10 | Coorstek, Inc. | Graphite loaded silicon carbide and methods for making |
US20050244581A1 (en) * | 2004-05-03 | 2005-11-03 | Jacques Thebault | Method of manufacturing a part out of impervious thermostructural composite material |
US20060169404A1 (en) * | 2003-02-17 | 2006-08-03 | Jacques Thebault | Method of siliconising thermostructural composite materials and parts thus produced |
US20080190552A1 (en) * | 2004-06-24 | 2008-08-14 | Eric Bouillon | Method For Soldering Composite Material Parts |
US20140048978A1 (en) * | 2012-08-16 | 2014-02-20 | General Electric Company | Consumable core for manufacture of composite articles and related method |
CN111848201A (en) * | 2020-07-24 | 2020-10-30 | 西安超码科技有限公司 | Carbon/carbon crucible with silicon carbide/silicon coating and preparation method thereof |
Families Citing this family (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4109050A (en) * | 1976-12-09 | 1978-08-22 | General Electric Company | Coated silicon-based ceramic composites and method for making same |
DE2964962D1 (en) * | 1978-09-02 | 1983-04-07 | Schunk & Ebe Gmbh | Joint endoprosthesis |
US4220455A (en) * | 1978-10-24 | 1980-09-02 | General Electric Company | Polycrystalline diamond and/or cubic boron nitride body and process for making said body |
DE2852410C2 (en) * | 1978-12-04 | 1981-12-03 | Kernforschungsanlage Jülich GmbH, 5170 Jülich | Process and device for the production of silicon carbide molded bodies |
IE49733B1 (en) * | 1978-12-29 | 1985-12-11 | Gen Electric | Integral composite of polycrystalline diamond and/or cubic boron nitride body phase and substrate phase and process for making it |
US4353953A (en) * | 1978-12-29 | 1982-10-12 | General Electric Company | Integral composite of polycrystalline diamond and/or cubic boron nitride body phase and substrate phase |
US4536442A (en) * | 1979-08-23 | 1985-08-20 | General Electric Company | Process for making diamond and cubic boron nitride compacts |
US4381271A (en) * | 1981-02-02 | 1983-04-26 | General Electric Company | Use of fired fibrous graphite in fabricating polycrystalline diamond and/or cubic boron nitride/silicon carbide/silicon composite bodies |
DE3108259C2 (en) * | 1981-03-05 | 1984-06-28 | Kernforschungsanlage Jülich GmbH, 5170 Jülich | Process for the production of silicon carbide bodies |
US4606738A (en) * | 1981-04-01 | 1986-08-19 | General Electric Company | Randomly-oriented polycrystalline silicon carbide coatings for abrasive grains |
JPS58104067A (en) * | 1981-12-14 | 1983-06-21 | 信越化学工業株式会社 | Alkali-resistant silicon carbide sintered body and manufacture |
GB2137975B (en) * | 1983-04-12 | 1986-09-17 | Atomic Energy Authority Uk | Joining silicon carbide bodies |
GB8323994D0 (en) * | 1983-09-07 | 1983-10-12 | Atomic Energy Authority Uk | Reaction-bonded silicon carbide artefacts |
US4789506A (en) * | 1986-11-07 | 1988-12-06 | Gas Research Institute | Method of producing tubular ceramic articles |
DE3719606A1 (en) * | 1987-06-12 | 1988-12-22 | Hoechst Ceram Tec Ag | METHOD FOR SILICOLATING POROUS SHAPED BODIES MADE OF SILICON CARBIDE OR SILICON CARBIDE / CARBON |
JPS6440291U (en) * | 1987-09-04 | 1989-03-10 | ||
US5004034A (en) * | 1988-11-10 | 1991-04-02 | Lanxide Technology Company, Lp | Method of surface bonding materials together by use of a metal matrix composite, and products produced thereby |
US5336350A (en) * | 1989-10-31 | 1994-08-09 | General Electric Company | Process for making composite containing fibrous material |
WO1991017279A1 (en) * | 1990-05-09 | 1991-11-14 | Lanxide Technology Company, Lp | Rigidized filler materials for metal matrix composites |
US5316851A (en) * | 1991-06-12 | 1994-05-31 | General Electric Company | Silicon carbide composite with metal boride coated fiber reinforcement |
EP0519641A1 (en) * | 1991-06-17 | 1992-12-23 | General Electric Company | Silicon carbide composite with coated fiber reinforcement and method of forming |
EP0519644B1 (en) * | 1991-06-17 | 1996-12-11 | General Electric Company | Silicon carbide composite with metal nitride coated fiber reinforcement |
US7658781B1 (en) | 1999-07-23 | 2010-02-09 | Marlene Rossing, legal representative | Silicon-containing composite bodies, and methods for making same |
US6503572B1 (en) | 1999-07-23 | 2003-01-07 | M Cubed Technologies, Inc. | Silicon carbide composites and methods for making same |
US20090130435A1 (en) | 1999-07-23 | 2009-05-21 | Aghajanian Michael K | Intermetallic-containing composite bodies, and methods for making same |
US20050181209A1 (en) * | 1999-08-20 | 2005-08-18 | Karandikar Prashant G. | Nanotube-containing composite bodies, and methods for making same |
US8128861B1 (en) | 2000-07-21 | 2012-03-06 | M Cubed Technologies, Inc. | Composite materials and methods for making same |
DE10231278A1 (en) * | 2002-07-10 | 2004-02-05 | Sgl Carbon Ag | Ceramic composite body |
KR100520436B1 (en) * | 2003-01-30 | 2005-10-11 | 한국과학기술원 | Method for Making Oxidation Protective Double Coating for Carbon/Carbon Composite |
KR100520435B1 (en) * | 2003-01-30 | 2005-10-11 | 한국과학기술원 | Method for Making Oxidation Protective Coating for Carbon/Carbon Composite |
US20060062985A1 (en) * | 2004-04-26 | 2006-03-23 | Karandikar Prashant G | Nanotube-containing composite bodies, and methods for making same |
US8652226B2 (en) * | 2008-09-16 | 2014-02-18 | Diamond Innovations, Inc. | Abrasive particles having a unique morphology |
WO2014150936A1 (en) | 2013-03-15 | 2014-09-25 | Lazur Andrew J | Melt infiltration apparatus and method for molten metal control |
WO2014151094A1 (en) | 2013-03-15 | 2014-09-25 | Rolls-Royce Corporation | Melt infiltration wick attachment |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB713710A (en) * | 1952-06-17 | 1954-08-18 | Arthur Abbey | Improvements in or relating to refractory carbon articles |
US2887393A (en) * | 1956-03-12 | 1959-05-19 | Carborundum Co | Refractory bodies containing boron nitride |
US3035325A (en) * | 1958-02-21 | 1962-05-22 | Carborundum Co | Method of making silicon carbide bodies |
US3246275A (en) * | 1962-06-18 | 1966-04-12 | Kanthal Ab | Electric resistance elements of silicon carbide and metal silicide |
US3364975A (en) * | 1964-11-24 | 1968-01-23 | Monsanto Co | Process of casting a molten metal with dispersion of fibrous form of beta silicon carbide |
US3649432A (en) * | 1970-07-13 | 1972-03-14 | Monsanto Co | Corrugated board constructions |
US3725015A (en) * | 1970-06-08 | 1973-04-03 | Norton Co | Process for forming high density refractory shapes and the products resulting therefrom |
US3796564A (en) * | 1969-06-19 | 1974-03-12 | Carborundum Co | Dense carbide composite bodies and method of making same |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2943008A (en) * | 1956-07-17 | 1960-06-28 | Electro Refractories & Abrasiv | Refractory articles |
US2992127A (en) * | 1958-12-23 | 1961-07-11 | Texas Instruments Inc | Novel graphite articles and method of making |
US3095316A (en) * | 1959-09-30 | 1963-06-25 | Union Carbide Corp | Process for coating carbonaceous articles with silicon dioxide |
US3131089A (en) * | 1961-01-25 | 1964-04-28 | Union Carbide Corp | Carbon article coated with boron carbide and boron nitride, and process of making the same |
US3458341A (en) * | 1964-08-10 | 1969-07-29 | Gen Electric | Metal boride-metal carbide-graphite deposition |
US3462340A (en) * | 1965-07-28 | 1969-08-19 | Us Air Force | Fiber-containing pyrolytic composite material |
US3672936A (en) * | 1968-04-18 | 1972-06-27 | Carborundum Co | Reinforced carbon and graphite articles |
US3955038A (en) * | 1973-04-09 | 1976-05-04 | Sandvik Aktiebolag | Hard metal body |
US4035541A (en) * | 1975-11-17 | 1977-07-12 | Kennametal Inc. | Sintered cemented carbide body coated with three layers |
-
1976
- 1976-02-23 US US05/660,261 patent/US4120731A/en not_active Expired - Lifetime
-
1977
- 1977-01-28 FR FR7702358A patent/FR2341534A1/en active Granted
- 1977-01-31 GB GB3805/77A patent/GB1556881A/en not_active Expired
- 1977-02-03 BE BE174632A patent/BE851054A/en not_active IP Right Cessation
- 1977-02-10 IT IT20154/77A patent/IT1075555B/en active
- 1977-02-18 CA CA272,280A patent/CA1096895A/en not_active Expired
- 1977-02-19 DE DE19772707299 patent/DE2707299A1/en active Granted
- 1977-02-19 DE DE2760422A patent/DE2760422C2/de not_active Expired
- 1977-02-21 CH CH213677A patent/CH636587A5/en not_active IP Right Cessation
- 1977-02-21 NL NLAANVRAGE7701852,A patent/NL184316C/en not_active IP Right Cessation
- 1977-02-21 CH CH319382A patent/CH641750A5/en not_active IP Right Cessation
- 1977-02-22 NO NO770578A patent/NO145006C/en unknown
- 1977-02-22 JP JP1783777A patent/JPS52121614A/en active Granted
- 1977-11-07 US US05/849,186 patent/US4148894A/en not_active Expired - Lifetime
-
1980
- 1980-03-10 NO NO800678A patent/NO145836C/en unknown
-
1986
- 1986-03-26 JP JP61066120A patent/JPS61251577A/en active Granted
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB713710A (en) * | 1952-06-17 | 1954-08-18 | Arthur Abbey | Improvements in or relating to refractory carbon articles |
US2887393A (en) * | 1956-03-12 | 1959-05-19 | Carborundum Co | Refractory bodies containing boron nitride |
US3035325A (en) * | 1958-02-21 | 1962-05-22 | Carborundum Co | Method of making silicon carbide bodies |
US3246275A (en) * | 1962-06-18 | 1966-04-12 | Kanthal Ab | Electric resistance elements of silicon carbide and metal silicide |
US3364975A (en) * | 1964-11-24 | 1968-01-23 | Monsanto Co | Process of casting a molten metal with dispersion of fibrous form of beta silicon carbide |
US3796564A (en) * | 1969-06-19 | 1974-03-12 | Carborundum Co | Dense carbide composite bodies and method of making same |
US3725015A (en) * | 1970-06-08 | 1973-04-03 | Norton Co | Process for forming high density refractory shapes and the products resulting therefrom |
US3649432A (en) * | 1970-07-13 | 1972-03-14 | Monsanto Co | Corrugated board constructions |
Cited By (59)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4177047A (en) * | 1978-07-27 | 1979-12-04 | Joy Manufacturing Company | Electrostatic precipitators |
US4238433A (en) * | 1978-12-15 | 1980-12-09 | General Electric Company | Method of making molten silicon infiltration reaction products |
US4247304A (en) * | 1978-12-29 | 1981-01-27 | General Electric Company | Process for producing a composite of polycrystalline diamond and/or cubic boron nitride body and substrate phases |
US4275095A (en) * | 1979-07-31 | 1981-06-23 | Warren Consultants, Inc. | Composite article and method of making same |
US4325930A (en) * | 1980-01-02 | 1982-04-20 | Societe Europeenne De Propulsion | Producing a silicon carbide structure and multidirectional silicon carbide texture |
US4385020A (en) * | 1980-03-27 | 1983-05-24 | General Electric Company | Method for making shaped silicon-silicon carbide refractories |
US4417906A (en) * | 1980-07-09 | 1983-11-29 | General Electric Company | Process for production of silicon carbide composite |
US4453951A (en) * | 1980-07-09 | 1984-06-12 | General Electric Co. | Process for the production of silicone carbide composite |
US4353963A (en) * | 1980-12-17 | 1982-10-12 | General Electric Company | Process for cementing diamond to silicon-silicon carbide composite and article produced thereby |
US4448591A (en) * | 1981-01-21 | 1984-05-15 | General Electric Company | Cutting insert having unique cross section |
US4698070A (en) * | 1981-12-16 | 1987-10-06 | General Electric Company | Cutting insert for interrupted heavy machining |
US4544517A (en) * | 1981-12-16 | 1985-10-01 | General Electric Co. | Automatic composite press technique for producing cutting inserts |
US4460382A (en) * | 1981-12-16 | 1984-07-17 | General Electric Company | Brazable layer for indexable cutting insert |
US4572848A (en) * | 1983-07-29 | 1986-02-25 | Hoechst Ceramtec Aktiengesellschaft | Process for the production of molded bodies from silicon-infiltrated, reaction-bonded silicon carbide |
US4971851A (en) * | 1984-02-13 | 1990-11-20 | Hewlett-Packard Company | Silicon carbide film for X-ray masks and vacuum windows |
US4737328A (en) * | 1985-07-29 | 1988-04-12 | General Electric Company | Infiltration of material with silicon |
US4626516A (en) * | 1985-07-31 | 1986-12-02 | General Electric Company | Infiltration of Mo-containing material with silicon |
US5015540A (en) * | 1987-06-01 | 1991-05-14 | General Electric Company | Fiber-containing composite |
US4944904A (en) * | 1987-06-25 | 1990-07-31 | General Electric Company | Method of obtaining a fiber-containing composite |
US5021367A (en) * | 1987-06-25 | 1991-06-04 | General Electric Company | Fiber-containing composite |
US5330854A (en) * | 1987-09-24 | 1994-07-19 | General Electric Company | Filament-containing composite |
US5043303A (en) * | 1987-09-28 | 1991-08-27 | General Electric Company | Filament-containing composite |
US4886682A (en) * | 1987-12-14 | 1989-12-12 | General Electric Company | Process for producing a filament-containing composite in a ceramic matrix |
US4931311A (en) * | 1987-12-21 | 1990-06-05 | General Electric Company | Method of obtaining a filament-containing composite with a boron nitride coated matrix |
US5376427A (en) * | 1988-12-27 | 1994-12-27 | General Electric Company | Ceramic composite containing coated fibrous material |
US5387299A (en) * | 1988-12-27 | 1995-02-07 | General Electric Company | Ceramic composite containing coated fibrous material |
US4981822A (en) * | 1989-02-17 | 1991-01-01 | General Electric Company | Composite containing coated fibrous material |
US5432253A (en) * | 1989-12-18 | 1995-07-11 | General Electric Company | Composite containing fibrous material |
US5580834A (en) * | 1993-02-10 | 1996-12-03 | The Morgan Crucible Company Plc | Self-sintered silicon carbide/carbon graphite composite material having interconnected pores which may be impregnated and raw batch and process for producing same |
US5656563A (en) * | 1993-02-10 | 1997-08-12 | The Morgan Crucible Company Plc | Dense, self-sintered silicon carbide/carbon graphite composite |
US5707567A (en) * | 1993-02-10 | 1998-01-13 | The Morgan Crucible Company Plc | Process for producing a self-sintered silicon carbide/carbon graphite composite material having interconnected pores which maybe impregnated |
US5976429A (en) * | 1993-02-10 | 1999-11-02 | The Morgan Crucible Company, Plc | Process for producing dense, self-sintered silicon carbide/carbon-graphite composites |
US5628938A (en) * | 1994-11-18 | 1997-05-13 | General Electric Company | Method of making a ceramic composite by infiltration of a ceramic preform |
US5968653A (en) * | 1996-01-11 | 1999-10-19 | The Morgan Crucible Company, Plc | Carbon-graphite/silicon carbide composite article |
US6024898A (en) * | 1996-12-30 | 2000-02-15 | General Electric Company | Article and method for making complex shaped preform and silicon carbide composite by melt infiltration |
US6398991B1 (en) | 1998-06-25 | 2002-06-04 | Coorstek, Inc. | Processes for making a silicon carbide composition |
US6368663B1 (en) | 1999-01-28 | 2002-04-09 | Ishikawajima-Harima Heavy Industries Co., Ltd | Ceramic-based composite member and its manufacturing method |
US6403158B1 (en) | 1999-03-05 | 2002-06-11 | General Electric Company | Porous body infiltrating method |
US6335105B1 (en) | 1999-06-21 | 2002-01-01 | General Electric Company | Ceramic superalloy articles |
US6395203B1 (en) | 1999-08-30 | 2002-05-28 | General Electric Company | Process for producing low impurity level ceramic |
US6503441B2 (en) | 2001-05-30 | 2003-01-07 | General Electric Company | Method for producing melt-infiltrated ceramic composites using formed supports |
EP1346967A2 (en) * | 2002-03-19 | 2003-09-24 | Sgl Carbon Ag | Method for infiltration of porous carbon composites |
US20030178733A1 (en) * | 2002-03-19 | 2003-09-25 | Jens Rosenloecher | Process for the infiltration of porous carbon composites |
US7238308B2 (en) | 2002-03-19 | 2007-07-03 | Audi Ag | Process for the infiltration of porous carbon composites |
EP1346967A3 (en) * | 2002-03-19 | 2004-11-03 | Sgl Carbon Ag | Method for infiltration of porous carbon composites |
US6774073B2 (en) | 2002-07-29 | 2004-08-10 | Coorstek, Inc. | Graphite loaded silicon carbide and methods for making |
US20050037915A1 (en) * | 2002-07-29 | 2005-02-17 | Coorstek, Inc. | Graphite loaded silicon carbide and methods for making |
US7015165B2 (en) | 2002-07-29 | 2006-03-21 | Coorstek, Inc. | Graphite loaded silicon carbide and methods for making |
US20090120743A1 (en) * | 2003-02-17 | 2009-05-14 | Snecma Propulsion Solide | Method of siliciding thermostructural composite materials, and parts obtained by the method |
US20060169404A1 (en) * | 2003-02-17 | 2006-08-03 | Jacques Thebault | Method of siliconising thermostructural composite materials and parts thus produced |
US7497918B2 (en) * | 2003-02-17 | 2009-03-03 | Snecma Propulsion Solide | Method of siliciding thermostructural composite materials, and parts obtained by the method |
US8261891B2 (en) | 2003-02-17 | 2012-09-11 | Snecma Propulsion Solide | Method of siliciding thermostructural composite materials, and parts obtained by the method |
US20050244581A1 (en) * | 2004-05-03 | 2005-11-03 | Jacques Thebault | Method of manufacturing a part out of impervious thermostructural composite material |
US7736554B2 (en) * | 2004-05-03 | 2010-06-15 | Snecma Propulsion Solide | Method of manufacturing a part out of impervious thermostructural composite material |
US20080190552A1 (en) * | 2004-06-24 | 2008-08-14 | Eric Bouillon | Method For Soldering Composite Material Parts |
US20140048978A1 (en) * | 2012-08-16 | 2014-02-20 | General Electric Company | Consumable core for manufacture of composite articles and related method |
US9751807B2 (en) * | 2012-08-16 | 2017-09-05 | General Electric Company | Consumable core for manufacture of composite articles and related method |
CN111848201A (en) * | 2020-07-24 | 2020-10-30 | 西安超码科技有限公司 | Carbon/carbon crucible with silicon carbide/silicon coating and preparation method thereof |
CN111848201B (en) * | 2020-07-24 | 2022-09-02 | 西安超码科技有限公司 | Carbon/carbon crucible with silicon carbide/silicon coating and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
CA1096895A (en) | 1981-03-03 |
NO145006C (en) | 1981-12-28 |
FR2341534B1 (en) | 1982-10-15 |
JPS52121614A (en) | 1977-10-13 |
NL184316B (en) | 1989-01-16 |
NO770578L (en) | 1977-08-24 |
DE2760422C2 (en) | 1989-12-14 |
NO145836C (en) | 1982-06-09 |
NO800678L (en) | 1977-08-24 |
CH636587A5 (en) | 1983-06-15 |
JPS61251577A (en) | 1986-11-08 |
JPS6257595B2 (en) | 1987-12-01 |
GB1556881A (en) | 1979-11-28 |
IT1075555B (en) | 1985-04-22 |
DE2707299A1 (en) | 1977-09-15 |
FR2341534A1 (en) | 1977-09-16 |
NO145836B (en) | 1982-03-01 |
JPS6141871B2 (en) | 1986-09-18 |
CH641750A5 (en) | 1984-03-15 |
NL7701852A (en) | 1977-08-25 |
DE2707299C2 (en) | 1989-03-02 |
NL184316C (en) | 1989-06-16 |
US4148894A (en) | 1979-04-10 |
BE851054A (en) | 1977-08-03 |
NO145006B (en) | 1981-09-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4120731A (en) | Method of making molten silicon infiltration reaction products and products made thereby | |
US4238433A (en) | Method of making molten silicon infiltration reaction products | |
RU2176628C2 (en) | Composite material (variants) and method or preparing thereof, method of treating fibrous semi-finished product (variants) | |
US4242106A (en) | Composite of polycrystalline diamond and/or cubic boron nitride body/silicon carbide substrate | |
US4158687A (en) | Method for producing heat-resistant composite materials reinforced with continuous silicon carbide fibers | |
CA2301775C (en) | Method of manufacturing a diamond-silicon carbide-silicon composite and a composite produced by this method | |
US4240835A (en) | Method of making a shaped silicon carbide-silicon matrix composite and articles made thereby | |
US3852099A (en) | Dense silicon carbide ceramic and method of making same | |
US4385020A (en) | Method for making shaped silicon-silicon carbide refractories | |
GB2122179A (en) | Producing silicon carbide bodies | |
KR20000076057A (en) | Fibre-reinforced composite ceramics infiltrated with molten metal | |
JPH05105521A (en) | Carbon-fiber reinforced silicon nitride-based nano-composite material and its production | |
EP0192040B1 (en) | Fluoride infiltrated carbide or nitride composite | |
US5328878A (en) | Aluminum nitride refractory materials and methods for making the same | |
US5571758A (en) | Nitrogen-reacted silicon carbide material | |
US4019913A (en) | Process for fabricating silicon carbide articles | |
US5667742A (en) | Methods for making preforms for composite formation processes | |
US3329514A (en) | Refractory body and method of making same | |
JPH05163065A (en) | Silicon-free infiltrate-forming composite material of silicon carbide and molybdenum silicide | |
RU2814669C1 (en) | Method of producing structural ceramics by additive technology for articles of complex geometry | |
JPS63215566A (en) | Ceramic composite material | |
EP0334415A1 (en) | Improved process for the production of ceramic components |