US4140639A - Clay-free wellbore fluid - Google Patents
Clay-free wellbore fluid Download PDFInfo
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- US4140639A US4140639A US05/772,436 US77243677A US4140639A US 4140639 A US4140639 A US 4140639A US 77243677 A US77243677 A US 77243677A US 4140639 A US4140639 A US 4140639A
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- guar gum
- lignosulfonate
- weight percent
- brine
- clay
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/02—Well-drilling compositions
- C09K8/04—Aqueous well-drilling compositions
- C09K8/06—Clay-free compositions
- C09K8/08—Clay-free compositions containing natural organic compounds, e.g. polysaccharides, or derivatives thereof
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S507/00—Earth boring, well treating, and oil field chemistry
- Y10S507/922—Fracture fluid
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S507/00—Earth boring, well treating, and oil field chemistry
- Y10S507/925—Completion or workover fluid
Definitions
- the present invention lies in the field of additives to wellbore fluids used while drilling wells in earth formations, completion operations after the drilling has been completed, workover, fracturing, and various other operations in a wellbore, that is, all of those fluids which are employed over the course of the life of a well.
- the invention is concerned with stablized additives to non-clay wellbore fluids such as various brines and emulsions of water and oil, more particularly the invention relates to additive compositions for use in wellbore fluids and to wellbore fluid containing these additive compositions.
- clay-based drilling fluids are not brines.
- a wellbore fluid can perform any one or more of a number of functions.
- the drilling fluid will generally provide a cooling medium for the rotary bit and a means to carry off the drilled particles. Since great volumes of drilling fluid are required for these two purposes, the fluids have been based on water. Water alone, however, does not have the capacity to carry the drilled particles from the borehole to the surface.
- clay-based fluids have for years preempted the field, because of the traditional and widely held theory in the field that the viscosity suitable for creating a particle carrying capacity in the drilling fluid could be achieved only with a drilling fluid having thixotropic properties, that is, the viscosity must be supplied by a material that will have sufficient gel strength to prevent the drilled particles from separating from the drilling fluid when agitation of the drilling fluid has ceased, for example, in a holding tank at the surface.
- hydratable clay or colloidal clay bodies such as bentonite or fuller's earth have been employed.
- the drilling fluids are usually referred to as "muds.”
- brine wellbore fluids are extensively employed.
- the use of clay-based drilling muds has provided the means of meeting the two basic requirements of drilling fluids, i.e., cooling and particle removal.
- the clay-based drilling muds have created problems for which solutions are needed.
- the drilled particles and any heaving shale material will be hydrated and taken up by the conventional clay-based drilling fluids.
- the continued addition of extraneous hydrated solid particles to the drilling fluid will increase the viscosity and necessitated costly and constant thinning and reformulation of the drilling mud to maintain its original properties.
- a third serious disadvantage of clay-based drilling fluids arises out of the thixotropic nature of the fluid.
- the separation of drilled particles is inhibited by the gel strength of the drilling mud. Settling of the drilled particles can require rather long periods of time and require settling ponds of large size.
- Fresh water wellbore fluids avoid many of the clay-based fluid problems, but may cause hydration of the formation.
- the brines have the advantage of containing hydration inhibiting materials such as potassium chloride, calcium chloride or the like. Quite apparently any solid particulate material would be easily separated from the brine solution since it is not hydrated. Thus, the properties of the brine are not changed by solid particulate matter from the wellbore. Similarly, since there is no opportunity for gas bubbles to become entrapped, blowouts are less likely in a clay-free brine-type wellbore fluid.
- clay-free brines are already the usual selection.
- guar gum has been used as a water loss control agent in wellbore fluids, in the same manner as starch, other natural gums, such as karaya, psyllium, tragacanth, talha, locust bean, ghatti and the like, cellulosic derivatives, such as carboxymethyl cellulose, carboxymethyl hydroxyethyl cellulose, synthetic polymers such as polyacrylic acid, polyethylene glycol, etc.
- other natural gums such as karaya, psyllium, tragacanth, talha, locust bean, ghatti and the like
- cellulosic derivatives such as carboxymethyl cellulose, carboxymethyl hydroxyethyl cellulose
- synthetic polymers such as polyacrylic acid, polyethylene glycol, etc.
- a non-clay wellbore fluid When a non-clay wellbore fluid is used for a purpose requiring relatively high viscosity, for example drilling, it is generally necessary to employ an additive to thicken the fluid to the point where it will have the necessary carrying capacity.
- additives to increase viscosity are commercially available, but most if not all of these have one or more limitations.
- the viscosifier may be slow to yield, i.e., it may take 15 minutes or more from the time of addition to the time when the fluid becomes thick enough to carry the cuttings.
- the additives may be effective over only a narrow low temperature range, permitting the fluid to thin out again when a higher temperature is reached.
- most of the viscosifiers have a limited service life, again thinning out after a period of use.
- Non-structured viscosity Asbestos and attapulgite are examples of the types of materials employed to obtain structured viscosity.
- the non-structured viscosity provides another unique benefit in that the carrying capacity will vary in the agitated and non-agitated states, so that when, for example, the agitation is reduced in a separating tank the carrying capacity will drop off and the cuttings and the like from the wellbore will fall out of the fluid, yet when agitated there is ample carrying capacity to carry the cuttings and the like to the surface from the wellbore.
- the present invention is an additive composition for use in brine wellbore fluids consisting essentially of from 15 to 95 weight percent guar gum or hydroxyalkyl guar gum and from 5 to 85 weight percent of a salt of lignosulfonate based on the total of guar or hydroxyalkyl guar and lignosulfonate salt.
- the additive composition will consist essentially of from 25 to 75 weight percent guar gum or hydroxyalkyl guar gum and 25 to 75 weight percent of a lignosulfonate salt on the same basis.
- the brine wellbore fluids containing a water loss reducing amount of the additive composition as defined above are also a part of this invention.
- a water loss reducing amount is used herein to mean that amount of the defined additive composition which will reduce the water loss of the brine wellbore over an untreated wellbore fluid and is preferably from about 0.1 to 3 weight percent of the additive composition as defined, based on the weight of wellbore fluid.
- Guar gum is a natural vegetable colloid commercially produced in the form of a powder.
- Commercial guar gum is a component of the legumenous seed Cyamopsis tetragonaloba. The gum occurs in the endosperm of these seeds where its natural function is to reserve food supply for the developing plant.
- Guar gum is a polysaccharide consisting of a complex carbohydrate polymer of galactose and mannose and is chemically classified as a galactomannan.
- Natural guar gum has a number of hydroxyls which readily react with alkylene oxides such as ethylene oxide, propylene oxide or butylene oxide.
- alkylene oxides such as ethylene oxide, propylene oxide or butylene oxide.
- reactive alkylene oxides include the homologs of these compounds represented by the general formulas: ##STR1## where R is an alkyl radical has 1 to 6 carbon atoms and R 1 is hydrogen or an alkyl radical having 1 to 6 carbon atoms.
- the homologous oxides react with the hydroxyl of the guar gum to produce hydroxy ethers with the hydroxyl group not terminally situated, for example 1,2- epoxy butane produces ⁇ -hydroxy butyl guar gum whereas ethylene oxide, propylene oxide or butylene oxide produce hydroxy alkylated ethers with the hydroxyl on the terminal carbon of the alkylated chain, e.g., 1,4-epoxy butane reacts with guar gum to produce 4-hydroxy butyl guar gum.
- higher-membered rings may be used to synthesize the hydroxy alkylated guar gum, however such higher membered rings are less chemical reactive, hence the practical likelihood of the economic preparation of this type of hydroxy alkylated guar gum is remote.
- the two and three membered rings are the most reactive and offer the likelihood of producing hydroxy alkylated guar gum on an economic level that may be used realistically as a wellbore fluid additive.
- a preferred group of hydroxy guar gum ethers are hydroxyethyl guar gum, 3-hydroxy propyl guar gum, 4-hydroxybutyl guar gum, 2-hydroxy butyl guar gum, 2-hydroxy propyl guar gum, and 3-hydroxy butyl guar gum.
- Magnesia is a highly infusible magnesium oxide (MgO), prepared by the calcination of magnesium carbonate, MgCO 3 ). Magnesia is only slightly soluble in water, e.g., 0.0086 grams/ 100 cc (86 ppm) of water at 30° and is essentially non-hydratable.
- MgO magnesium oxide
- One theory for the benefit of magnesia is that the very slightly soluble magnesia which is present in excess of its solubility in the wellbore fluid provides a reservoir of basicity of just the correct amount to maintain the pH of the fluid in the range at which the additive components are most stable.
- Magnesium hydroxide may be similarly viewed. This theory is proposed as a possible explanation for the operation of magnesia and magnesium hydroxide.
- the slight solubility of magnesia and magnesium hydroxide in wellbore fluids results in a very low magnesium ion concentration, that is, for example MgO has less than 0.001% or 10 ppm of magnesium ion concentration or dissolved magnesium, yet the pH remains strongly alkaline when employed in stabilizing amounts.
- the amount of magnesia or magnesium hydroxide in the composition may be greater than 50 weight percent without detriment to the operation of the composition in the wellbore fluid, e.g., several hundred times the specified minimum amount may be added with no ill effect on the viscosifier (guar gum or hydroxy alkyl guar gum) or the drilling fluid.
- the amount of the composition employed in the wellbore fluid is not critical and may vary for different applications of the fluid. Generally at least 0.5 pounds up to about 5 or 10 pounds of guar gum or hydroxy alkyl guar gum per U.S. barrel (42 U.S. gallons) will be employed. In addition, there may be at least 0.05 ppb of magnesia or magnesium hydroxide present in the wellbore fluid. This minimum amount of magnesia and magnesium hydroxide represents an excess of magnesia beyond that soluble in the wellbore fluid, e.g., greater than 0.0035 pounds of magnesia per barrel of water.
- Lignosulfonate water soluble salts are known as water loss reduction agents. However, the synergistic effect obtained with guar gum or hydroxyalkyl guar gum has not been known.
- Some suitable water soluble lignosulfonate salts are alkali and alkaline earth metal salts, chromium salts, iron salts, lead salts, ammomium salts thereof and the like.
- the alkali and alkaline earth lignosulfonate salts form a preferred embodiment, in particular sodium and calcium salts thereof.
- guar gum and hydroxyalkyl guar gum and the lignosulfonate salts such as calcium lignosulfonate and sodium lignosulfonate
- density modifying material such as calcium chloride, sodium chloride and zinc chloride may be present.
- any of the known additive materials may be added so long as the basic characteristics of the non-clay wellbore fluid are not changed.
- the pH of the drilling fluid after combining it with the additive composition of the present invention should be highly alkaline, i.e., preferably about 8.5 or more preferably 8.5 to about 11 to obtain yield.
- Brines provide the wellbore fluid of the present invention, and generally containing at least 1.0% by weight of a soluble salt of potassium, sodium or calcium in water.
- the brine may contain other soluble salts, for example, zinc, chromium, iron, copper and the like.
- the chlorides are employed because of availability, but other salts such as the bromides, sulfates and the like may be used.
- the soluble salts of the brine not only furnish the weighting material by adjusting the density of the solution, but also typically furnish the cations for inhibiting the fluid against hydration of solid materials.
- the wellbore fluid will contain a substantial amount of water, i.e., it is an aqueous based brine fluid. Oil may be present to form water-oil wellbore fluids with appropriate emulsifiers as known in the art.
- the present additive composition and amounts in the wellbore fluid relate only to the aqueous portion.
- One embodiment of the present invention is a wellbore fluid consisting essentially of water and an electrolyte inhibitor for preventing hydration, selected from the group consisting of at least 600 ppm calcium ion, at least 200 ppm aluminum ion or chromium ion, at least 1,500 ppm potassium chloride, at least 5000 ppm sodium chloride and combinations thereof.
- the components were added to a brine solution of NaCl.
- the additives other than guar gum or hydroxyalkyl guar gum (if any) were added to the brine first followed by the guar gum.
- the samples were dynamically aged for 16 hours at 175° F., cooled to room temperature (75° F.), stirred 5 minutes and tested.
- compositions, tests and results are set out below in Table I and Table II.
- the data shows the synergistic improvement in fluid loss in brine for guar or hydroxypropyl guar gum and calcium lignosulfonate.
Abstract
A clay-free, i.e., non-argillaceous brine wellbore fluid having unstructured viscosity and improved water loss properties from an additive composition present in an amount of 0.1 to 3 weight % based on wellbore fluid and consisting essentially of 15 to 95 weight % of guar gum or hydroxyalkyl guar gum and 5 to 85 weight % of a water soluble salt, preferably alkaline earth salt of lignosulfonate.
Description
This application is a continuation-in-part of applications Ser. Nos. 558,815 filed Mar. 17, 1975, now abandoned and 558,817 filed Mar. 17, 1975 now U.S, Pat. No. 4,025,443.
The present invention lies in the field of additives to wellbore fluids used while drilling wells in earth formations, completion operations after the drilling has been completed, workover, fracturing, and various other operations in a wellbore, that is, all of those fluids which are employed over the course of the life of a well.
Particularly, the invention is concerned with stablized additives to non-clay wellbore fluids such as various brines and emulsions of water and oil, more particularly the invention relates to additive compositions for use in wellbore fluids and to wellbore fluid containing these additive compositions.
Generally wellbore fluids will be either clay-based or brines which are clay-free. Fresh water systems are sometimes used, but the brines have certain advantages which are discussed below. These two classes are exclusive, that is, clay-based drilling fluids are not brines. A wellbore fluid can perform any one or more of a number of functions. For example, the drilling fluid will generally provide a cooling medium for the rotary bit and a means to carry off the drilled particles. Since great volumes of drilling fluid are required for these two purposes, the fluids have been based on water. Water alone, however, does not have the capacity to carry the drilled particles from the borehole to the surface.
In the drilling fluid class, clay-based fluids have for years preempted the field, because of the traditional and widely held theory in the field that the viscosity suitable for creating a particle carrying capacity in the drilling fluid could be achieved only with a drilling fluid having thixotropic properties, that is, the viscosity must be supplied by a material that will have sufficient gel strength to prevent the drilled particles from separating from the drilling fluid when agitation of the drilling fluid has ceased, for example, in a holding tank at the surface.
In order to obtain the requisite thixotropy or gel strength, hydratable clay or colloidal clay bodies such as bentonite or fuller's earth have been employed. As a result the drilling fluids are usually referred to as "muds." In other areas where particle carrying capacity may not be as critical, such as completion or workover, brine wellbore fluids are extensively employed. The use of clay-based drilling muds has provided the means of meeting the two basic requirements of drilling fluids, i.e., cooling and particle removal. However, the clay-based drilling muds have created problems for which solutions are needed. For example, since the clays must be hydrated in order to function, it is not possible to employ hydration inhibitors, such as calcium chloride, or if employed, their presence must be at a level which will not interfere with the clay hydration. In certain types of shales generally found in the Gulf Coast area of Texas and Louisiana, there is a tendency for the shale to disintegrate by swelling or cracking upon contact with the water, if hydration is not limited. Thus the uninhibited clay-based or fresh water drilling fluids may be prone to shale disintegration.
The drilled particles and any heaving shale material will be hydrated and taken up by the conventional clay-based drilling fluids. The continued addition of extraneous hydrated solid particles to the drilling fluid will increase the viscosity and necessitated costly and constant thinning and reformulation of the drilling mud to maintain its original properties.
Another serious disadvantage of the clay-based fluids is their susceptibility to the detrimental effect of brines which are often found in drilled formations, particularly Gulf Coast formations. Such brines can have a hydration inhibiting effect, detrimental to the hydration requirement for the clays.
A third serious disadvantage of clay-based drilling fluids arises out of the thixotropic nature of the fluid. The separation of drilled particles is inhibited by the gel strength of the drilling mud. Settling of the drilled particles can require rather long periods of time and require settling ponds of large size.
Other disadvantages of clay-based drilling fluids are their (1 ) tendency to prevent the escape of gas bubbles, when the viscosity of the mud rises too high by the incidental addition of hydratable material, which can result in blowouts; (2) the need for constant human control and supervision of the clay-based fluids because of the expectable, yet unpredictable, variations in properties; and (3) the formation of a thick cake on the internal surfaces of the wellbore.
Fresh water wellbore fluids avoid many of the clay-based fluid problems, but may cause hydration of the formation. The brines have the advantage of containing hydration inhibiting materials such as potassium chloride, calcium chloride or the like. Quite apparently any solid particulate material would be easily separated from the brine solution since it is not hydrated. Thus, the properties of the brine are not changed by solid particulate matter from the wellbore. Similarly, since there is no opportunity for gas bubbles to become entrapped, blowouts are less likely in a clay-free brine-type wellbore fluid.
Thus, the wellbore art now has two competing and incompatible water based systems which can be used in a full range of wellbore operations, i.e., the problem plagued clay-based wellbore fluids or the improved clay-free wellbore fluids, principally brines. In many areas of application, as noted above, clay-free brines are already the usual selection.
Quite frequently guar gum has been used as a water loss control agent in wellbore fluids, in the same manner as starch, other natural gums, such as karaya, psyllium, tragacanth, talha, locust bean, ghatti and the like, cellulosic derivatives, such as carboxymethyl cellulose, carboxymethyl hydroxyethyl cellulose, synthetic polymers such as polyacrylic acid, polyethylene glycol, etc. However, the stability of these materials has been a continuing problem, which usually means early and frequent make up of the water loss control material in wellbore operations.
When a non-clay wellbore fluid is used for a purpose requiring relatively high viscosity, for example drilling, it is generally necessary to employ an additive to thicken the fluid to the point where it will have the necessary carrying capacity. Several additives to increase viscosity are commercially available, but most if not all of these have one or more limitations. The viscosifier may be slow to yield, i.e., it may take 15 minutes or more from the time of addition to the time when the fluid becomes thick enough to carry the cuttings. The additives may be effective over only a narrow low temperature range, permitting the fluid to thin out again when a higher temperature is reached. In addition, most of the viscosifiers have a limited service life, again thinning out after a period of use.
Many of the water loss additives have been found to be suited for providing non-structured viscosity to non-clay wellbore fluids. Guar gum and/or hydroxyalkyl guar gum can provide non-structured, i.e., non-thixotropic viscosity to wellbore fluids. These materials are water soluble and non-ionic, thus they are not susceptible to being expelled from a brine solution, for example as are the soluble salts of carboxymethyl cellulose. The term "non-structured viscosity" as used here means one wherein viscosity is obtained by physio-chemical rather than by physical means. Asbestos and attapulgite are examples of the types of materials employed to obtain structured viscosity.
The non-structured viscosity provides another unique benefit in that the carrying capacity will vary in the agitated and non-agitated states, so that when, for example, the agitation is reduced in a separating tank the carrying capacity will drop off and the cuttings and the like from the wellbore will fall out of the fluid, yet when agitated there is ample carrying capacity to carry the cuttings and the like to the surface from the wellbore.
It is an advantage of the present additive compositions that they have extended stability and effectiveness over a higher temperature range. A particular feature is that faster yields are obtained by using the additive composition in wellbore fluids. A particular advantage of the present additive composition is that the water loss effectiveness is greater, and is extended beyond that normally achieved with guar gum and hydroxyalkyl guar gum. These and other advantages and features of the present invention will be apparent from the disclosure, descriptions and teachings set out below.
Briefly stated the present invention is an additive composition for use in brine wellbore fluids consisting essentially of from 15 to 95 weight percent guar gum or hydroxyalkyl guar gum and from 5 to 85 weight percent of a salt of lignosulfonate based on the total of guar or hydroxyalkyl guar and lignosulfonate salt. Preferably the additive composition will consist essentially of from 25 to 75 weight percent guar gum or hydroxyalkyl guar gum and 25 to 75 weight percent of a lignosulfonate salt on the same basis.
The brine wellbore fluids containing a water loss reducing amount of the additive composition as defined above are also a part of this invention.
A water loss reducing amount is used herein to mean that amount of the defined additive composition which will reduce the water loss of the brine wellbore over an untreated wellbore fluid and is preferably from about 0.1 to 3 weight percent of the additive composition as defined, based on the weight of wellbore fluid.
It has been surprisingly found that the combination of guar gum or hydroxyalkyl guar gum and salt of lignosulfonate produce an unexpected improvement in fluid loss over either component alone. One may have expected an additive improvement in fluid loss, but a completely unexpected synergistic improvement has been found to result. The presence of magnesia or magnesium hydroxide in amounts of 10% or more also provide additional improvement in fluid loss.
Guar gum is a natural vegetable colloid commercially produced in the form of a powder. Commercial guar gum is a component of the legumenous seed Cyamopsis tetragonaloba. The gum occurs in the endosperm of these seeds where its natural function is to reserve food supply for the developing plant. Guar gum is a polysaccharide consisting of a complex carbohydrate polymer of galactose and mannose and is chemically classified as a galactomannan.
Natural guar gum has a number of hydroxyls which readily react with alkylene oxides such as ethylene oxide, propylene oxide or butylene oxide. In addition reactive alkylene oxides include the homologs of these compounds represented by the general formulas: ##STR1## where R is an alkyl radical has 1 to 6 carbon atoms and R1 is hydrogen or an alkyl radical having 1 to 6 carbon atoms. The homologous oxides react with the hydroxyl of the guar gum to produce hydroxy ethers with the hydroxyl group not terminally situated, for example 1,2- epoxy butane produces β-hydroxy butyl guar gum whereas ethylene oxide, propylene oxide or butylene oxide produce hydroxy alkylated ethers with the hydroxyl on the terminal carbon of the alkylated chain, e.g., 1,4-epoxy butane reacts with guar gum to produce 4-hydroxy butyl guar gum.
In addition the two, three and four membered rings, higher-membered rings may be used to synthesize the hydroxy alkylated guar gum, however such higher membered rings are less chemical reactive, hence the practical likelihood of the economic preparation of this type of hydroxy alkylated guar gum is remote. The two and three membered rings are the most reactive and offer the likelihood of producing hydroxy alkylated guar gum on an economic level that may be used realistically as a wellbore fluid additive.
Both hydroxy ethylated and hydroxy propylated guar gum are currently commercially available at costs competitive with other non-thixotropic wellbore fluid viscosifiers, particularly if the excellent yield and filtrate properties are considered.
A preferred group of hydroxy guar gum ethers are hydroxyethyl guar gum, 3-hydroxy propyl guar gum, 4-hydroxybutyl guar gum, 2-hydroxy butyl guar gum, 2-hydroxy propyl guar gum, and 3-hydroxy butyl guar gum.
Magnesia is a highly infusible magnesium oxide (MgO), prepared by the calcination of magnesium carbonate, MgCO3 ). Magnesia is only slightly soluble in water, e.g., 0.0086 grams/ 100 cc (86 ppm) of water at 30° and is essentially non-hydratable. One theory for the benefit of magnesia is that the very slightly soluble magnesia which is present in excess of its solubility in the wellbore fluid provides a reservoir of basicity of just the correct amount to maintain the pH of the fluid in the range at which the additive components are most stable. Magnesium hydroxide may be similarly viewed. This theory is proposed as a possible explanation for the operation of magnesia and magnesium hydroxide.
The slight solubility of magnesia and magnesium hydroxide in wellbore fluids results in a very low magnesium ion concentration, that is, for example MgO has less than 0.001% or 10 ppm of magnesium ion concentration or dissolved magnesium, yet the pH remains strongly alkaline when employed in stabilizing amounts. The amount of magnesia or magnesium hydroxide in the composition may be greater than 50 weight percent without detriment to the operation of the composition in the wellbore fluid, e.g., several hundred times the specified minimum amount may be added with no ill effect on the viscosifier (guar gum or hydroxy alkyl guar gum) or the drilling fluid.
The amount of the composition employed in the wellbore fluid is not critical and may vary for different applications of the fluid. Generally at least 0.5 pounds up to about 5 or 10 pounds of guar gum or hydroxy alkyl guar gum per U.S. barrel (42 U.S. gallons) will be employed. In addition, there may be at least 0.05 ppb of magnesia or magnesium hydroxide present in the wellbore fluid. This minimum amount of magnesia and magnesium hydroxide represents an excess of magnesia beyond that soluble in the wellbore fluid, e.g., greater than 0.0035 pounds of magnesia per barrel of water.
Lignosulfonate water soluble salts are known as water loss reduction agents. However, the synergistic effect obtained with guar gum or hydroxyalkyl guar gum has not been known. Some suitable water soluble lignosulfonate salts are alkali and alkaline earth metal salts, chromium salts, iron salts, lead salts, ammomium salts thereof and the like. The alkali and alkaline earth lignosulfonate salts form a preferred embodiment, in particular sodium and calcium salts thereof.
In addition to the guar gum and hydroxyalkyl guar gum, and the lignosulfonate salts such as calcium lignosulfonate and sodium lignosulfonate, other conventional wellbore additives, density modifying material such as calcium chloride, sodium chloride and zinc chloride may be present. In other words, any of the known additive materials may be added so long as the basic characteristics of the non-clay wellbore fluid are not changed.
It has been found that the pH of the drilling fluid after combining it with the additive composition of the present invention should be highly alkaline, i.e., preferably about 8.5 or more preferably 8.5 to about 11 to obtain yield.
Brines provide the wellbore fluid of the present invention, and generally containing at least 1.0% by weight of a soluble salt of potassium, sodium or calcium in water. In addition, the brine may contain other soluble salts, for example, zinc, chromium, iron, copper and the like. Generally, the chlorides are employed because of availability, but other salts such as the bromides, sulfates and the like may be used. The soluble salts of the brine, not only furnish the weighting material by adjusting the density of the solution, but also typically furnish the cations for inhibiting the fluid against hydration of solid materials.
The wellbore fluid will contain a substantial amount of water, i.e., it is an aqueous based brine fluid. Oil may be present to form water-oil wellbore fluids with appropriate emulsifiers as known in the art. The present additive composition and amounts in the wellbore fluid, however, relate only to the aqueous portion.
One embodiment of the present invention is a wellbore fluid consisting essentially of water and an electrolyte inhibitor for preventing hydration, selected from the group consisting of at least 600 ppm calcium ion, at least 200 ppm aluminum ion or chromium ion, at least 1,500 ppm potassium chloride, at least 5000 ppm sodium chloride and combinations thereof.
In these Examples the components were added to a brine solution of NaCl. The additives, other than guar gum or hydroxyalkyl guar gum (if any) were added to the brine first followed by the guar gum. The samples were dynamically aged for 16 hours at 175° F., cooled to room temperature (75° F.), stirred 5 minutes and tested.
The compositions, tests and results are set out below in Table I and Table II.
The data shows the synergistic improvement in fluid loss in brine for guar or hydroxypropyl guar gum and calcium lignosulfonate.
TABLE I
__________________________________________________________________________
Example No.
1 2 3 4 5 6 7 8 9 10 11 12
__________________________________________________________________________
9.1 ppg NaCl
Brine, bbl 1 1 1 1 1 1 1 1 1 1 1 1
Guargum, ppb
1.75
1.75
1.75
1.75
1.75
1.75
1.75
1.75
1.7
1.7
1.7
1.7
MgO, ppb .2 .6 1.0
2.0
5.0 0.9
Mg(OH).sub.2,ppb .2 .6 1.0 0.9
Calcium Ligno-
Sulfonate ppb 1.7
1.7
1.7
Apparent
Viscosity,cp
20 23.5
24 233/4
251/4
20.5
20 22.5
15.5
7.5
17.5
16
Plastic
Viscosity,cp
13 14 14 14.5
14.5
13 12 13 11 7 12.5
12
Yield Point
#/100 sq.ft.
14 19 20 18.5
22.5
15 16 19 9 1 10 8
Gels,
Initial/10 min.
3/3
3/3
3/3
3/3
4/4
2/2.5
2/3
3/3
2/3
2/3
2/3
2/2
pH 9.8
9.9
9.8
9.9
10.0
8.7
9.0
9.2
7.6
6.9
9.8
8.5
API Fluid
Loss, cc 110.0
98.0
94.0
88.0
64.3
176.0
80.5
147.0
105
24 18 60
Example No.
13 14 15 16 17 18 19
9.1 ppg NaCl
Brine, bbl 1 1 1 1 1 1 1
Guargum, ppb 3.4
MgO, ppb .9 .6
Mg(OH).sub.2,ppb
HPG* 3.4
Calcium Ligno-
Sulfonate, ppb
1.7
1.7
2.0
2.0
3.4
Apparent
Viscosity,cp
2 2 2 2 1.5
56 45
Plastic
Viscosity,cp
2 2 2 2 1 27 20
Yield Point
#/100 sq.ft.
0 0 0 0 1 58 50
pH 5.8
9.5
6.6
9.4
6.2
7.0
7.4
API Fluid
Loss,cc 190
75 120
65 50 37.0
80
__________________________________________________________________________
*Hydroxypropyl guar gum
TABLE II
__________________________________________________________________________
Example No.
20 21 22 23 24 25 26 27 28 29 30 31 32 33
__________________________________________________________________________
9.1 ppg NaCl
Brine, bbl
1 1 1 1 1 1 1 1 1 1 1 1 1 1
HPG, ppb 1.75
1.75
1.75
1.75
1.75
1.75
1.75
1.75
1.75
1.75
1.75
1.75
1.75
1.75
MgO, ppb .01 .05
.1 .2 .6 1.0
2.0
5.0
Mg(OH).sub.2,ppb .2 .6 1.0
10% HCl, cc
1.0
Apparent
Viscosity,cp
20.8
22 20.3
20.3
21.5
23 21 22 22.5
231/4 24.5
20 21 21
Plastic
Viscosity,cp
12 13 12 12.5
12 14 12 13 12 13.5
13.5
12 12 12
Yield Point,
#/100 sq.ft.
7.5 18 16.5
16.5
19.0
18 18 18 21 19.5
22 16 18 18
Gels,
Initial/10 min.
3/3 3/3 3/3
3/3 4/4
4/4
4/4
4/4
4/4
4/4
4/4
3/3 3/3
3/4
pH 6.9 8.2 7.6
8.5 9.4
9.8
9.9
9.95
10.0
10.1
10.3
8.9 9.4
9.4
API Fluid
Loss, cc 250+
258+
327
315+
326
311
253
159
130
178
90.8
321+
285
208
__________________________________________________________________________
These compositions and tests were done in the same manner as those of Examples 1-33. The results are set out in Table III.
TABLE III
__________________________________________________________________________
Example No. 34 35 36 37 38
__________________________________________________________________________
9.1 ppg
9.1 ppg
9.1 ppg
9.1 ppg
9.1 ppg
Brine, 1 bbl NaCl NaCl NaCl NaCl NaCl
HPG, ppb 2 2 2 2 2
Calcium
LignoSulfonate,ppb 2 2
Magnesium
Oxide, ppb 0.6 0.6
Magnesium
Hydroxide, ppb 0.6
TEST DATA:
Apparent Viscosity, cp
25 11 22.5 26.5 25.1
Plastic Viscosity, cp
13 9 13 14 13.5
Yield Point,
#/100 sq. ft.
24 4 19 25 24
Gels, Initial/10 Min.
4/4 3/3 4/4 5/5 4/4
pH 7.8 6.7 9.8 9.9 9.3
API Fluid Loss, cc
323 67 39.8 180 249
__________________________________________________________________________
These examples demonstrate the range of relative amounts of guar gum or hydroxyalkyl guar gum over which the synergistic improvement in water loss was observed (note Examples 43 and 49 are outside the scope of the claims). The samples for testing were made up in the same manner as Examples 1-33 and tested in the same manner. The results are reported in TABLE IV.
TABLE IV
__________________________________________________________________________
Example No. 39 40 41 42 43 44 45 46 47 48 49 50
__________________________________________________________________________
9.1 ppg
9.1 ppg
9.1 ppg
9.1 ppg
9.1 ppg
9.1 ppg
9.1 9.1 9.1 9.1 9.1 9.1
Brine, 1 bbl NaCl
NaCl
NaCl
NaCl
NaCl
NaCl
NaCl
NaCl
NaCl
NaCl
NaCl
NaCl
Guar Gum ppb 1.9 1.7 1.5 .5 .3 .1
HPG, ppb 1.9 1.7 1.5 .5 .3 .1
Calcium
LignoSulfonate,ppb
.1 .3 .5 1.5 1.7 1.9 .1 .3 .5 1.5 1.7 1.9
TEST DATA:
Apparent Viscosity, cp
16.5
14 7.5 3 3 2 12 8.5 6.5 3 3 2.5
Plastic Viscosity, cp
13 11 7 2 3 2 10 8 6 2 2 2
Yield Point,
#/100 sq. ft. 7 6 1 2 0 1 5 1 1 2 2 1
pH 7.6 7.4 7.4 7.0 6.8 7.0 7.3 7.3 7.3 6.8 6.9 6.8
API Fluid Loss,cc
35 40 23 33 47 50 37 40 37 41 73 90
__________________________________________________________________________
Claims (10)
1. An additive composition for use in clay-free non-thixotropic, brine wellbore fluids having improved fluid loss properties consisting essentially of from 15 to 95 weight percent hydroxyalkyl guar gum selected from the group consisting of hydroxyethyl guar gum and hydroxypropyl guar gum and from 5 to 85 weight percent of an alkaline earth metal salt of lignosulfonate.
2. The additive composition according to claim 1 consisting essentially of 25 to 75 weight percent of said hydroxyalkyl guar gum and from 25 to 75 weight percent of said alkaline earth metal salt of lignosulfonate.
3. The additive composition according to claim 1 wherein said lignosulfonate salt is calcium lignosulfonate.
4. The additive composition according to claim 3 containing hydroxypropyl guar gum.
5. A clay-free non-thixotropic, brine wellbore fluid comprising at least 1% of a soluble salt of potassium, sodium or calcium in water and a water loss reducing amount of an additive composition consisting essentially of 15 to 95 weight percent hydroxyalkyl guar gum selected from the group consisting of hydroxyethyl guar gum and hydroxypropyl guar gum and from 5 to 85 weight percent of an alkaline earth metal salt of lignosulfonate.
6. The brine well bore fluid according to claim 5 containing from about 0.1 to 3 weight percent of said additive composition, based on the weight of wellbore fluid.
7. The brine wellbore fluid according to claim 5 wherein said additive composition consist essentially of from 25 to 75 weight percent hydroxyalkyl guar gum and from 25 to 75 weight percent of said alkaline earth metal salt of lignosulfonate.
8. The brine wellbore fluid according to claim 5 wherein said hydroxyalkyl guar gum is hydroxyethyl guar gum.
9. The brine wellbore fluid according to claim 5 wherein said lignosulfonate salt is calcium lignosulfonate.
10. The brine wellbore fluid according to claim 9 containing hydroxypropyl guar gum.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US55881575A | 1975-03-17 | 1975-03-17 |
Related Parent Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US55881575A Continuation-In-Part | 1975-03-17 | 1975-03-17 | |
| US05/558,817 Continuation-In-Part US4025443A (en) | 1975-03-17 | 1975-03-17 | Clay-free wellbore fluid |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US05/901,475 Division US4172801A (en) | 1975-03-17 | 1978-05-01 | Clay-free wellbore fluid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US4140639A true US4140639A (en) | 1979-02-20 |
Family
ID=24231102
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US05/772,436 Expired - Lifetime US4140639A (en) | 1975-03-17 | 1977-02-28 | Clay-free wellbore fluid |
| US05/861,861 Expired - Lifetime US4151096A (en) | 1975-03-17 | 1977-12-19 | Clay-free wellbore fluid |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US05/861,861 Expired - Lifetime US4151096A (en) | 1975-03-17 | 1977-12-19 | Clay-free wellbore fluid |
Country Status (3)
| Country | Link |
|---|---|
| US (2) | US4140639A (en) |
| CA (1) | CA1070491A (en) |
| GB (1) | GB1542960A (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4247402A (en) * | 1978-03-13 | 1981-01-27 | Brinadd Company | Clay-free, thixotropic wellbore fluid |
| US4350601A (en) * | 1979-03-26 | 1982-09-21 | The Dow Chemical Co. | Preparation of viscosifiers for zinc salt workover and completion brines |
| US4415463A (en) * | 1979-06-22 | 1983-11-15 | The Dow Chemical Co. | Preparation of viscosifiers for zinc salt workover and completion brines |
| US4453598A (en) * | 1982-09-20 | 1984-06-12 | Singer Arnold M | Drilling mud displacement process |
| US4455241A (en) * | 1982-02-16 | 1984-06-19 | Phillips Petroleum Company | Wellbore fluid |
| US4456537A (en) * | 1981-10-13 | 1984-06-26 | Oliver Jr John E | Chemically cleaning drilling/completion/packer brines |
| US4515699A (en) * | 1981-10-13 | 1985-05-07 | Oliver Jr John E | Chemically cleaning drilling/completion/packer brines |
| US4528102A (en) * | 1981-10-13 | 1985-07-09 | Oliver Jr John E | Chemically cleaning aqueous fluid of insoluble solids |
| US5228524A (en) * | 1992-02-25 | 1993-07-20 | Baker Hughes Incorporated | Fluid system for controlling fluid losses during hydrocarbon recovery operations |
| US5325921A (en) * | 1992-10-21 | 1994-07-05 | Baker Hughes Incorporated | Method of propagating a hydraulic fracture using fluid loss control particulates |
| US5504062A (en) * | 1992-10-21 | 1996-04-02 | Baker Hughes Incorporated | Fluid system for controlling fluid losses during hydrocarbon recovery operations |
| US5612293A (en) * | 1994-12-22 | 1997-03-18 | Tetra Technologies, Inc. | Drill-in fluids and drilling methods |
| CN104402013A (en) * | 2014-10-30 | 2015-03-11 | 南京大学 | Method for improving attapulgite clay colloid viscosity by use of food gum and improvement of pulping method |
| US9790421B2 (en) | 2013-04-10 | 2017-10-17 | Ecolab Usa Inc. | Choline-based crosslinker compositions for fracturing fluids |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4451389A (en) * | 1980-05-22 | 1984-05-29 | Phillips Petroleum Company | Aqueous gels |
| US4321968A (en) * | 1980-05-22 | 1982-03-30 | Phillips Petroleum Company | Methods of using aqueous gels |
| AU556313B2 (en) * | 1982-12-29 | 1986-10-30 | Stauffer Chemical Company | Oil well drilling composition of aqueous alkali/polymer |
| GB2164370B (en) | 1984-09-11 | 1988-01-27 | Shell Int Research | Drilling fluid |
| JPS61163986A (en) * | 1985-01-16 | 1986-07-24 | Nitto Chem Ind Co Ltd | Method for stabilizing fracturing fluid |
| FR2577982A1 (en) * | 1985-02-27 | 1986-08-29 | Exxon Production Research Co | POLYMER-BASED COMPOSITIONS FOR THE THICKENING OF AQUEOUS SOLUTIONS, PROCESSES FOR THEIR PREPARATION AND THEIR APPLICATION IN PETROLEUM EXTRACTION |
| JPS61275374A (en) * | 1985-05-31 | 1986-12-05 | Nitto Chem Ind Co Ltd | Method of stabilizing fracturing fluid |
| CA1294485C (en) * | 1985-10-15 | 1992-01-21 | Shigeo Yasuno | Fabricated meat products like crab leg meat and process for manufacturing the same |
| US4743384A (en) * | 1986-05-13 | 1988-05-10 | Aqualon Company | Carboxymethyl guar based drilling fluids |
| US5009267A (en) * | 1988-11-14 | 1991-04-23 | Nalco Chemical Company | Method for temporarily reducing permeability of subterranean formations |
| US5132025A (en) * | 1990-12-03 | 1992-07-21 | Hays Ricky A | Oil well drilling mud and brine recycling system |
| US5480863A (en) * | 1993-02-16 | 1996-01-02 | Phillips Petroleum Company | Brine viscosification |
| US5358050A (en) * | 1993-03-18 | 1994-10-25 | Atlantic Richfield Company | Method for killing a gas blowout of a well |
| US5955401A (en) * | 1996-05-17 | 1999-09-21 | Baroid Technology, Inc. | Clay-free biodegradable wellbore fluid and method for using same fluid |
| US7456135B2 (en) * | 2000-12-29 | 2008-11-25 | Halliburton Energy Services, Inc. | Methods of drilling using flat rheology drilling fluids |
| US7572755B2 (en) * | 2000-12-29 | 2009-08-11 | Halliburton Energy Services, Inc. | Drilling fluid comprising a vinyl neodecanoate polymer and method for enhanced suspension |
| US20030036484A1 (en) * | 2001-08-14 | 2003-02-20 | Jeff Kirsner | Blends of esters with isomerized olefins and other hydrocarbons as base oils for invert emulsion oil muds |
| US6887832B2 (en) * | 2000-12-29 | 2005-05-03 | Halliburton Energy Service,S Inc. | Method of formulating and using a drilling mud with fragile gels |
| EP1356010B1 (en) * | 2000-12-29 | 2010-06-30 | Halliburton Energy Services, Inc. | Thinners for invert emulsions |
| WO2002053676A1 (en) | 2000-12-29 | 2002-07-11 | Halliburton Energy Services, Inc. | Thinners for invert emulsions |
| US9739132B2 (en) * | 2013-08-07 | 2017-08-22 | Baker Hughes Incorporated | Well treatment fluids and methods |
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| US2908597A (en) * | 1957-06-06 | 1959-10-13 | William L Owen | Treatment of starches and gums, and compositions thereof |
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| US4003838A (en) * | 1973-04-27 | 1977-01-18 | Chemical Additives Company | Water loss reduction agents |
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| US2854407A (en) * | 1956-07-10 | 1958-09-30 | Great Western Drilling Company | Drilling fluid and method |
| US2856356A (en) * | 1956-07-25 | 1958-10-14 | Texas Co | Preparation of a drilling fluid composition and method of use |
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| US3220947A (en) * | 1962-06-26 | 1965-11-30 | Minerals & Chem Philipp Corp | Agent for thickening aqueous liquids |
| US3319715A (en) * | 1965-02-17 | 1967-05-16 | Dow Chemical Co | Polysaccharide b-1459 and mg(oh) in brines used in well treatments |
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1975
- 1975-12-12 CA CA242,091A patent/CA1070491A/en not_active Expired
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1977
- 1977-02-28 US US05/772,436 patent/US4140639A/en not_active Expired - Lifetime
- 1977-12-19 US US05/861,861 patent/US4151096A/en not_active Expired - Lifetime
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB771110A (en) * | 1955-12-20 | 1957-03-27 | Gen Mills Inc | Improvements in or relating to the drilling of wells |
| US2908597A (en) * | 1957-06-06 | 1959-10-13 | William L Owen | Treatment of starches and gums, and compositions thereof |
| US3483121A (en) * | 1966-09-06 | 1969-12-09 | Gen Mills Inc | Formation fracturing |
| US3723408A (en) * | 1970-05-26 | 1973-03-27 | Gen Mills Chem | Hydroxyalkyl polygalactomannans by reaction with certain halo fatty acid compounds |
| US3677961A (en) * | 1970-12-28 | 1972-07-18 | Milchem Inc | Galactomannan composition and treatment for the prevention of thixotrophy destruction of same by ligands |
| US3878110A (en) * | 1972-10-24 | 1975-04-15 | Oil Base | Clay-free aqueous sea water drilling fluids containing magnesium oxide or calcium oxide as an additive |
| US4003838A (en) * | 1973-04-27 | 1977-01-18 | Chemical Additives Company | Water loss reduction agents |
| US3988246A (en) * | 1974-05-24 | 1976-10-26 | Chemical Additives Company | Clay-free thixotropic wellbore fluid |
| US4025443A (en) * | 1975-03-17 | 1977-05-24 | Jackson Jack M | Clay-free wellbore fluid |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4247402A (en) * | 1978-03-13 | 1981-01-27 | Brinadd Company | Clay-free, thixotropic wellbore fluid |
| US4350601A (en) * | 1979-03-26 | 1982-09-21 | The Dow Chemical Co. | Preparation of viscosifiers for zinc salt workover and completion brines |
| US4415463A (en) * | 1979-06-22 | 1983-11-15 | The Dow Chemical Co. | Preparation of viscosifiers for zinc salt workover and completion brines |
| US4528102A (en) * | 1981-10-13 | 1985-07-09 | Oliver Jr John E | Chemically cleaning aqueous fluid of insoluble solids |
| US4456537A (en) * | 1981-10-13 | 1984-06-26 | Oliver Jr John E | Chemically cleaning drilling/completion/packer brines |
| US4515699A (en) * | 1981-10-13 | 1985-05-07 | Oliver Jr John E | Chemically cleaning drilling/completion/packer brines |
| US4455241A (en) * | 1982-02-16 | 1984-06-19 | Phillips Petroleum Company | Wellbore fluid |
| US4453598A (en) * | 1982-09-20 | 1984-06-12 | Singer Arnold M | Drilling mud displacement process |
| US5228524A (en) * | 1992-02-25 | 1993-07-20 | Baker Hughes Incorporated | Fluid system for controlling fluid losses during hydrocarbon recovery operations |
| US5325921A (en) * | 1992-10-21 | 1994-07-05 | Baker Hughes Incorporated | Method of propagating a hydraulic fracture using fluid loss control particulates |
| US5504062A (en) * | 1992-10-21 | 1996-04-02 | Baker Hughes Incorporated | Fluid system for controlling fluid losses during hydrocarbon recovery operations |
| US5612293A (en) * | 1994-12-22 | 1997-03-18 | Tetra Technologies, Inc. | Drill-in fluids and drilling methods |
| US9790421B2 (en) | 2013-04-10 | 2017-10-17 | Ecolab Usa Inc. | Choline-based crosslinker compositions for fracturing fluids |
| CN104402013A (en) * | 2014-10-30 | 2015-03-11 | 南京大学 | Method for improving attapulgite clay colloid viscosity by use of food gum and improvement of pulping method |
Also Published As
| Publication number | Publication date |
|---|---|
| CA1070491A (en) | 1980-01-29 |
| US4151096A (en) | 1979-04-24 |
| GB1542960A (en) | 1979-03-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AS | Assignment |
Owner name: TEXAS UNITED CHEMICAL CORPORATION, A TX CORP. Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNOR:BRINADD COMPANY, INC.;REEL/FRAME:004194/0293 Effective date: 19831110 Owner name: TEXAS UNITED CHEMICAL CORPORATION, TEXAS Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:BRINADD COMPANY, INC.;REEL/FRAME:004194/0293 Effective date: 19831110 |