US4394414A - Aqueous sizing composition for glass fibers for use on chopped glass fibers - Google Patents
Aqueous sizing composition for glass fibers for use on chopped glass fibers Download PDFInfo
- Publication number
- US4394414A US4394414A US06/268,541 US26854181A US4394414A US 4394414 A US4394414 A US 4394414A US 26854181 A US26854181 A US 26854181A US 4394414 A US4394414 A US 4394414A
- Authority
- US
- United States
- Prior art keywords
- sizing composition
- glass fiber
- cationic
- aqueous
- aqueous sizing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H13/00—Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
- D21H13/36—Inorganic fibres or flakes
- D21H13/38—Inorganic fibres or flakes siliceous
- D21H13/40—Inorganic fibres or flakes siliceous vitreous, e.g. mineral wool, glass fibres
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2962—Silane, silicone or siloxane in coating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/603—Including strand or fiber material precoated with other than free metal or alloy
- Y10T442/604—Strand or fiber material is glass
Abstract
Description
______________________________________ Ingredients 120 gallons (454.2 liters) Cold Water 208 liters Hot Water (40° C.) 18.9 liters Cationic lubricant 2529.7 grams 0.56 weight percent (Cation-X) 33-39 percent solids Hot Water 18.9 liters Urea (100% solids) 2404 grams 0.53 weight percent Cationic silicone 865.4 grams 0.19 weight percent polymer emulsion (Dow Corning emulsion 108) ______________________________________
______________________________________ Cation-X cationic lubricant 640 grams 0.59 weight percent Urea 200 grams 0.51 weight percent of the aqueous sizing composition Cationic silicone polymer 200 grams 0.17 weight percent emulsion (Emulsion 108) of the aqueous sizing composition ______________________________________
______________________________________ Cation-X cationic lubricant 1920 grams 1.69weight percent Urea 600 grams 1.46 weight percentCationic silicone polymer 600 grams 0.5 weight percent emulsion (DC 108) ______________________________________
______________________________________ Vinyl tris (2-methoxyethoxy silane) 50 0.13 weight percent A172 available from Union Carbide grams Cation-X cationic lubricant 640 0.59 weight percent grams Urea 200 0.51 weight percent grams Cationic silicone polymer 200 0.18 weight percent (DC 108) grams ______________________________________
TABLE I __________________________________________________________________________ Non-Woven Mat Made Flexibility of Example Mat LOI Disp. Disp. Tensile Strengths,.sup.(1) MD 3".sup.(2) Tear.sup.(5) Taber.sup.(6) by Glass Fibers Wt. % Chem. Rating Dry Cold Wet cw/d.sup.(3) Hot Wet hw/d.sup.(4) (grams) (units) MIT __________________________________________________________________________ cycles.sup.(7) Commercial 1.81# 19.7 250 HR Good 95.5 88.5 0.93 35.7 0.37 335 44 24 KAT Ex. 1 2.02# 17.7 250 HR Good 75.5 58.5 0.77 4.2 0.06 544 45 70 KAT Ex. 1 2.00# 16.1 250 HR Good 59.0 45.2 0.77 5.0 0.08 535 34 49 FFD Ex. 1 1.94# 20.0 250 HR Good 79.3 50.0 0.63 2.2 0.03 541 59 56 KAT Ex. 1 2.38# 17.1 250 HR Good 116.2 100.2 0.86 32.7 0.28 547 78 19 KAT Ex. 1 2.01# 11.7 250 HR Good 104.2 75.7 0.73 23.0 0.22 391 52 27 KAT Ex. 1 2.22# 14.6 250 HR Good 114.0 107.0 0.94 32.0 0.28 373 94 19 KAT Ex. 1 1.98# 19.8 250 HR Fair+ 86.2 60.5 0.70 3.0 0.03 617 63 51 FFD Ex. 1 2.09# 17.4 250 HR Fair 99.2 92.7 0.93 23.7 0.24 413 56 14 FFD Ex. 1 1.90# 15.7 250 HR Good 44.0 35.5 0.81 2.7 0.06 583 33 54 KAT Ex. 1 1.96# 17.6 250 HR Fair+ 70.5 54.2 0.77 4.0 0.06 520 38 36 FFD __________________________________________________________________________ .sup.(1) Tensile strength was measured on Instron Machine with 3" span moving at 0.5 in./min. .sup.(2) MD3" refers to tensile strength in the machine direction for a " × 3" square specimen. .sup.(3) cw/d refers to cold wet retained. .sup.(4) hw/d refers to hot wet retained. .sup.(5) Tear strength measured by standard Elmendorf Tearing Test at (1600 grams). .sup.(6) Taber test for flexibility at 15° bending angle with 100 units as the highest obtained unit. .sup.(7) MIT tests cycles to break in a standard MIT testing machine with 0.03 inch jaw with 0.5 Kg tension.
TABLE II __________________________________________________________________________ Binder Resin Urea Formaldehyde Resins Commercial Designations from Pacific Resins & Chemicals, Mat of Dispersion Average Tensile Inc. Glass Fibers System Strength lb./in. __________________________________________________________________________ 3958D Commercial Nopcosperse FFD/Natrasol 29.04 250 HR Example 1 Nopcosperse FFD/Natrasol 17.21 250 HR 3958E Commercial Nopcosperse FFD/Natrasol 22.62 250 HR Example 1 Nopcosperse FFD/Natrasol 22.85 250 HR 3958F Commercial Nopcosperse FFD/Natrasol 29.52 250 HR Example 1 Nopcosperse FFD/Natrasol 38.43 250 HR 3958G Commercial Nopcosperse FFD/Natrasol 24.59 250 HR Example 1 Nopcosperse FFD/Natrasol 20.82 250 HR 3958D Commercial Katapol/Natrasol 250 HR 26.38 Example 1 Katapol/Natrasol 250 HR 12.78 3958E Commercial Katapol/Natrasol 250 HR 25.34 Example 1e Katapol/Natrasol 250 HR 20.95 3958F Commercial Katapol/Natrasol 250 HR 29.79 Example 1 Katapol/Natrasol 250 HR 24.83 3958G Commercial Katapol/Natrasol 250 HR 23.81 Example 1 Katapol/Natrasol 250 HR 11.28 __________________________________________________________________________ D is a neutral urea formaldehyde resin. E is a cationic urea formaldehyde resin (chemically modified to be cationic). F is an anionic urea formaldehyde resin (chemically modified to be anionic). G is a neutral urea formaldehyde resin.
Claims (21)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/268,541 US4394414A (en) | 1981-05-29 | 1981-05-29 | Aqueous sizing composition for glass fibers for use on chopped glass fibers |
US06/422,126 US4477524A (en) | 1981-05-29 | 1982-09-23 | Aqueous sizing composition for glass fibers for use on chopped glass fibers |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/268,541 US4394414A (en) | 1981-05-29 | 1981-05-29 | Aqueous sizing composition for glass fibers for use on chopped glass fibers |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US06/422,126 Division US4477524A (en) | 1981-05-29 | 1982-09-23 | Aqueous sizing composition for glass fibers for use on chopped glass fibers |
Publications (1)
Publication Number | Publication Date |
---|---|
US4394414A true US4394414A (en) | 1983-07-19 |
Family
ID=23023439
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US06/268,541 Expired - Lifetime US4394414A (en) | 1981-05-29 | 1981-05-29 | Aqueous sizing composition for glass fibers for use on chopped glass fibers |
Country Status (1)
Country | Link |
---|---|
US (1) | US4394414A (en) |
Cited By (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4592956A (en) * | 1984-10-05 | 1986-06-03 | Ppg Industries, Inc. | Treated glass fibers and aqueous dispersion and nonwoven mat of the glass fibers |
US4681805A (en) * | 1985-12-23 | 1987-07-21 | Ppg Industries, Inc. | Strands of chemically treated glass fibers having a reduced tendency to give gumming deposits |
US4681802A (en) * | 1984-10-05 | 1987-07-21 | Ppg Industries, Inc. | Treated glass fibers and aqueous dispersion and nonwoven mat of the glass fibers |
US4990556A (en) * | 1989-04-19 | 1991-02-05 | Dow Corning Toray Silicone Ltd. | Silicone rubber or gel particles containing mineral oil |
US5074339A (en) * | 1986-10-14 | 1991-12-24 | Oberdorfer Gmbh & Co. Kg Industriegewebe-Technik | Double layered paper making forming fabric with a coarse structured running side and a fine structured paper side |
US5376701A (en) * | 1990-01-15 | 1994-12-27 | Exxon Chemical Patents Inc. | Thermoplastic polymer fibre composition |
WO1999026872A1 (en) * | 1997-11-21 | 1999-06-03 | Owens Corning | Process and composition for improving the uniformity of size application |
US20050202227A1 (en) * | 2004-03-10 | 2005-09-15 | Kajander Richard E. | Silane based coatings on glass fiber reinforcements in gypsum board |
US20050233657A1 (en) * | 2004-04-16 | 2005-10-20 | Grove Dale A | Coated facer |
US20050266757A1 (en) * | 2003-10-17 | 2005-12-01 | Roekens Bertrand J | Static free wet use chopped strands (WUCS) for use in a dry laid process |
US20050266225A1 (en) * | 2003-10-17 | 2005-12-01 | Georgia-Pacific Gypsum, Corp. | Interior wallboard and method of making same |
US20060137799A1 (en) * | 2004-12-29 | 2006-06-29 | Enamul Haque | Thermoplastic composites with improved sound absorbing capabilities |
US20060240236A1 (en) * | 2005-04-25 | 2006-10-26 | G-P Gypsum Corp. | Interior wallboard and method of making same |
US7138023B2 (en) | 2003-10-17 | 2006-11-21 | Owens-Corning Fiberglas Technology, Inc. | Development of thermoplastic composites using wet use chopped strand (WUCS) |
US20080014532A1 (en) * | 2006-07-14 | 2008-01-17 | 3M Innovative Properties Company | Laminate body, and method for manufacturing thin substrate using the laminate body |
US20080050571A1 (en) * | 2004-12-28 | 2008-02-28 | Enamul Haque | Polymer/WUCS mat for use in automotive applications |
US20080057283A1 (en) * | 2006-08-29 | 2008-03-06 | Arthur Blinkhorn | Reinforced acoustical material having high strength, high modulus properties |
US20080251187A1 (en) * | 2003-10-17 | 2008-10-16 | Enamul Haque | Composite material with improved structural, acoustic and thermal properties |
US20090017248A1 (en) * | 2007-07-13 | 2009-01-15 | 3M Innovative Properties Company | Layered body and method for manufacturing thin substrate using the layered body |
US20090017323A1 (en) * | 2007-07-13 | 2009-01-15 | 3M Innovative Properties Company | Layered body and method for manufacturing thin substrate using the layered body |
US20100055439A1 (en) * | 2008-08-29 | 2010-03-04 | Lee Jerry H C | WUCS Fibers Having Improved Flowing And Dispersing Properties |
US20110151176A1 (en) * | 2008-09-02 | 2011-06-23 | Ryota Akiyama | Method of manufacturing wafer laminated body, device of manufacturing wafer laminated body, wafer laminated body, method of peeling support body, and method of manufacturing wafer |
DE102010023770A1 (en) | 2010-06-15 | 2011-12-15 | Basf Se | Thermoplastic molding composition, useful e.g. to produce circuit board, comprises polyamide, flame retardant comprising phosphinic acid salt, nitrogen-containing flame retardant and optionally zinc salt, layered silicate and additive |
US8349706B2 (en) | 2003-11-12 | 2013-01-08 | 3M Innovtive Properties Company | Semiconductor surface protecting method |
CN105000809A (en) * | 2015-06-30 | 2015-10-28 | 营口市广吉玻璃纤维有限公司 | Organic silicon resin film-forming agent impregnating agent for glass fiber drawing |
Citations (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2758026A (en) * | 1952-05-31 | 1956-08-07 | American Cyanamid Co | Sized waterlaid glass fiber products and process of preparing the same |
US2897170A (en) * | 1954-04-09 | 1959-07-28 | American Cyanamid Co | Antistatic treatment with a quaternary ammonium compound containing a polyetheneoxy grouping and products thereof |
US3085126A (en) * | 1960-02-26 | 1963-04-09 | Johns Manville | Method of producing a battery separator and product thereof |
US3215585A (en) * | 1962-12-28 | 1965-11-02 | Pittsburgh Plate Glass Co | Composite glass fiber products and process of preparing the same |
US3253978A (en) * | 1961-07-19 | 1966-05-31 | C H Dexter & Sons Inc | Method of forming an inorganic waterlaid sheet containing colloidal silica and cationic starch |
US3395071A (en) * | 1962-09-13 | 1968-07-30 | Wacker Chemie Gmbh | Method of preparing asbestos sheets from aqueous slurries containing silicone resin emulsions |
US3423314A (en) * | 1966-01-19 | 1969-01-21 | Dow Corning | Antistatic lubricant as a process finish for synthetic fibers |
US3423235A (en) * | 1964-11-23 | 1969-01-21 | Dow Corning | Organosiloxane-containing finishes for organic fibers |
US3488217A (en) * | 1968-02-29 | 1970-01-06 | Du Pont | Process for imparting a soft feel to textile fiber and the resulting fiber |
US3493425A (en) * | 1967-01-09 | 1970-02-03 | Dow Corning | Lubricated fibers |
US3556754A (en) * | 1969-06-27 | 1971-01-19 | Union Carbide Corp | Coating compositions for glass fibers |
US3706695A (en) * | 1970-10-12 | 1972-12-19 | Dow Corning | Method of preparing a silicone emulsion and regenerating same and electrically conductive product |
US3749638A (en) * | 1971-01-11 | 1973-07-31 | Owens Corning Fiberglass Corp | Formation of non-woven structures from fibrous glass dispersion |
US3759740A (en) * | 1968-08-06 | 1973-09-18 | Dow Corning | Process for binding pigments to glass fabrics |
US3844825A (en) * | 1972-11-30 | 1974-10-29 | American Cyanamid Co | Method of producing an acrylic fiber having an improved touch like animal hair |
US3944702A (en) * | 1974-06-24 | 1976-03-16 | Dow Corning Corporation | Fibrous structures bonded with a silsesquioxane-containing composition |
US3979253A (en) * | 1974-04-22 | 1976-09-07 | The United States Of America As Represented By The Secretary Of The Navy | Method for dispersing glass fibers for the preparation of glass filter media |
US4014726A (en) * | 1974-03-18 | 1977-03-29 | Owens-Corning Fiberglas Corporation | Production of glass fiber products |
US4020212A (en) * | 1974-09-13 | 1977-04-26 | Phillips Petroleum Company | Polyolefin fibers useful as fiberfill treated with finishing agent comprising an organopolysiloxane and a surface active softener |
US4052257A (en) * | 1974-11-29 | 1977-10-04 | Owens-Corning Fiberglas Corporation | Method of producing glass mats |
US4052256A (en) * | 1974-07-31 | 1977-10-04 | Owens-Corning Fiberglas Corporation | Method of dispersing glass fibers using a linear polysiloxane and dispersion obtained thereby |
US4105567A (en) * | 1976-02-12 | 1978-08-08 | Th. Goldschmidt Ag | Organosilicon compounds and textile fiber finishes containing them |
US4105569A (en) * | 1977-02-07 | 1978-08-08 | George A. Goulston Co., Ltd. | Yarn finish formulation |
US4118272A (en) * | 1977-03-03 | 1978-10-03 | Gaf Corporation | Continuous wet-laid process for making high-strength glass fiber mats |
US4178203A (en) * | 1978-01-24 | 1979-12-11 | Gaf Corporation | Method of increasing the strength of wet glass fiber mats made by the wet-laid process |
US4178204A (en) * | 1978-01-24 | 1979-12-11 | Gaf Corporation | Wet-strength of wet glass fiber mats by treatment with anionic polyelectrolytes |
US4178206A (en) * | 1978-02-10 | 1979-12-11 | Gaf Corporation | Method of forming glass fiber dispersions with cationic quaternary ammonium surfactants having at least two long chain groups |
US4179331A (en) * | 1977-11-15 | 1979-12-18 | Gaf Corporation | Glass fiber dispersions for making uniform glass fiber mats by the wet-laid process |
US4183782A (en) * | 1978-07-11 | 1980-01-15 | Gaf Corporation | Method of producing glass mats using novel glass fiber dispersion composition |
US4210697A (en) * | 1978-09-15 | 1980-07-01 | Pall Corporation | Process for preparing hydrophobic porous fibrous sheet material of high strength and porosity and product |
US4259190A (en) * | 1979-09-13 | 1981-03-31 | Ppg Industries, Inc. | Glass fibers with reduced tendency to form gumming deposits and sizing composition |
US4271229A (en) * | 1979-09-04 | 1981-06-02 | Ppg Industries, Inc. | Sizing composition to yield sized glass fibers with improved UV stability |
US4311626A (en) * | 1980-09-25 | 1982-01-19 | Toray Silicone Company, Ltd. | Silicone compositions for the treatment of fibers |
-
1981
- 1981-05-29 US US06/268,541 patent/US4394414A/en not_active Expired - Lifetime
Patent Citations (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2758026A (en) * | 1952-05-31 | 1956-08-07 | American Cyanamid Co | Sized waterlaid glass fiber products and process of preparing the same |
US2897170A (en) * | 1954-04-09 | 1959-07-28 | American Cyanamid Co | Antistatic treatment with a quaternary ammonium compound containing a polyetheneoxy grouping and products thereof |
US3085126A (en) * | 1960-02-26 | 1963-04-09 | Johns Manville | Method of producing a battery separator and product thereof |
US3253978A (en) * | 1961-07-19 | 1966-05-31 | C H Dexter & Sons Inc | Method of forming an inorganic waterlaid sheet containing colloidal silica and cationic starch |
US3395071A (en) * | 1962-09-13 | 1968-07-30 | Wacker Chemie Gmbh | Method of preparing asbestos sheets from aqueous slurries containing silicone resin emulsions |
US3215585A (en) * | 1962-12-28 | 1965-11-02 | Pittsburgh Plate Glass Co | Composite glass fiber products and process of preparing the same |
US3423235A (en) * | 1964-11-23 | 1969-01-21 | Dow Corning | Organosiloxane-containing finishes for organic fibers |
US3423314A (en) * | 1966-01-19 | 1969-01-21 | Dow Corning | Antistatic lubricant as a process finish for synthetic fibers |
US3493425A (en) * | 1967-01-09 | 1970-02-03 | Dow Corning | Lubricated fibers |
US3488217A (en) * | 1968-02-29 | 1970-01-06 | Du Pont | Process for imparting a soft feel to textile fiber and the resulting fiber |
US3759740A (en) * | 1968-08-06 | 1973-09-18 | Dow Corning | Process for binding pigments to glass fabrics |
US3556754A (en) * | 1969-06-27 | 1971-01-19 | Union Carbide Corp | Coating compositions for glass fibers |
US3706695A (en) * | 1970-10-12 | 1972-12-19 | Dow Corning | Method of preparing a silicone emulsion and regenerating same and electrically conductive product |
US3749638A (en) * | 1971-01-11 | 1973-07-31 | Owens Corning Fiberglass Corp | Formation of non-woven structures from fibrous glass dispersion |
US3844825A (en) * | 1972-11-30 | 1974-10-29 | American Cyanamid Co | Method of producing an acrylic fiber having an improved touch like animal hair |
US4014726A (en) * | 1974-03-18 | 1977-03-29 | Owens-Corning Fiberglas Corporation | Production of glass fiber products |
US3979253A (en) * | 1974-04-22 | 1976-09-07 | The United States Of America As Represented By The Secretary Of The Navy | Method for dispersing glass fibers for the preparation of glass filter media |
US3944702A (en) * | 1974-06-24 | 1976-03-16 | Dow Corning Corporation | Fibrous structures bonded with a silsesquioxane-containing composition |
US4052256A (en) * | 1974-07-31 | 1977-10-04 | Owens-Corning Fiberglas Corporation | Method of dispersing glass fibers using a linear polysiloxane and dispersion obtained thereby |
US4020212A (en) * | 1974-09-13 | 1977-04-26 | Phillips Petroleum Company | Polyolefin fibers useful as fiberfill treated with finishing agent comprising an organopolysiloxane and a surface active softener |
US4052257A (en) * | 1974-11-29 | 1977-10-04 | Owens-Corning Fiberglas Corporation | Method of producing glass mats |
US4105567A (en) * | 1976-02-12 | 1978-08-08 | Th. Goldschmidt Ag | Organosilicon compounds and textile fiber finishes containing them |
US4105569A (en) * | 1977-02-07 | 1978-08-08 | George A. Goulston Co., Ltd. | Yarn finish formulation |
US4118272A (en) * | 1977-03-03 | 1978-10-03 | Gaf Corporation | Continuous wet-laid process for making high-strength glass fiber mats |
US4179331A (en) * | 1977-11-15 | 1979-12-18 | Gaf Corporation | Glass fiber dispersions for making uniform glass fiber mats by the wet-laid process |
US4178204A (en) * | 1978-01-24 | 1979-12-11 | Gaf Corporation | Wet-strength of wet glass fiber mats by treatment with anionic polyelectrolytes |
US4178203A (en) * | 1978-01-24 | 1979-12-11 | Gaf Corporation | Method of increasing the strength of wet glass fiber mats made by the wet-laid process |
US4178206A (en) * | 1978-02-10 | 1979-12-11 | Gaf Corporation | Method of forming glass fiber dispersions with cationic quaternary ammonium surfactants having at least two long chain groups |
US4183782A (en) * | 1978-07-11 | 1980-01-15 | Gaf Corporation | Method of producing glass mats using novel glass fiber dispersion composition |
US4210697A (en) * | 1978-09-15 | 1980-07-01 | Pall Corporation | Process for preparing hydrophobic porous fibrous sheet material of high strength and porosity and product |
US4271229A (en) * | 1979-09-04 | 1981-06-02 | Ppg Industries, Inc. | Sizing composition to yield sized glass fibers with improved UV stability |
US4259190A (en) * | 1979-09-13 | 1981-03-31 | Ppg Industries, Inc. | Glass fibers with reduced tendency to form gumming deposits and sizing composition |
US4311626A (en) * | 1980-09-25 | 1982-01-19 | Toray Silicone Company, Ltd. | Silicone compositions for the treatment of fibers |
Non-Patent Citations (3)
Title |
---|
Copending patent application Ser. No. 238,724, filed Feb. 27, 1981. * |
Copending patent application, "Aqueous Sizing Composition for Glass Fibers for Use in Producing Mat", Ser. No. 268,542, filed May 28, 1981. * |
Product Information, Information About Silicone Emulsions, Dow Corning Corporation. * |
Cited By (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4592956A (en) * | 1984-10-05 | 1986-06-03 | Ppg Industries, Inc. | Treated glass fibers and aqueous dispersion and nonwoven mat of the glass fibers |
US4681802A (en) * | 1984-10-05 | 1987-07-21 | Ppg Industries, Inc. | Treated glass fibers and aqueous dispersion and nonwoven mat of the glass fibers |
US4681805A (en) * | 1985-12-23 | 1987-07-21 | Ppg Industries, Inc. | Strands of chemically treated glass fibers having a reduced tendency to give gumming deposits |
US5074339A (en) * | 1986-10-14 | 1991-12-24 | Oberdorfer Gmbh & Co. Kg Industriegewebe-Technik | Double layered paper making forming fabric with a coarse structured running side and a fine structured paper side |
US4990556A (en) * | 1989-04-19 | 1991-02-05 | Dow Corning Toray Silicone Ltd. | Silicone rubber or gel particles containing mineral oil |
US5376701A (en) * | 1990-01-15 | 1994-12-27 | Exxon Chemical Patents Inc. | Thermoplastic polymer fibre composition |
WO1999026872A1 (en) * | 1997-11-21 | 1999-06-03 | Owens Corning | Process and composition for improving the uniformity of size application |
US5955518A (en) * | 1997-11-21 | 1999-09-21 | Owens Corning Fiberglas Technology, Inc. | Process and composition for improving the uniformity of size application |
US7989370B2 (en) | 2003-10-17 | 2011-08-02 | Georgia-Pacific Gypsum Llc | Interior wallboard and method of making same |
US20050266757A1 (en) * | 2003-10-17 | 2005-12-01 | Roekens Bertrand J | Static free wet use chopped strands (WUCS) for use in a dry laid process |
US20050266225A1 (en) * | 2003-10-17 | 2005-12-01 | Georgia-Pacific Gypsum, Corp. | Interior wallboard and method of making same |
US20110121482A1 (en) * | 2003-10-17 | 2011-05-26 | Roekens Bertrand J | Methods of forming low static non-woven chopped strand mats |
US7138023B2 (en) | 2003-10-17 | 2006-11-21 | Owens-Corning Fiberglas Technology, Inc. | Development of thermoplastic composites using wet use chopped strand (WUCS) |
US20080251187A1 (en) * | 2003-10-17 | 2008-10-16 | Enamul Haque | Composite material with improved structural, acoustic and thermal properties |
US8349706B2 (en) | 2003-11-12 | 2013-01-08 | 3M Innovtive Properties Company | Semiconductor surface protecting method |
US20050202227A1 (en) * | 2004-03-10 | 2005-09-15 | Kajander Richard E. | Silane based coatings on glass fiber reinforcements in gypsum board |
US7429544B2 (en) * | 2004-04-16 | 2008-09-30 | Owens Corning Intellectual Capital, Llc | Coated facer |
US20050233657A1 (en) * | 2004-04-16 | 2005-10-20 | Grove Dale A | Coated facer |
US8039058B2 (en) | 2004-04-16 | 2011-10-18 | Owens Corning Intellectual Cap | Methods of forming gypsum facers and gypsum boards incorporating gypsum facers |
US20090202716A1 (en) * | 2004-04-16 | 2009-08-13 | Grove Dale A | Coated Facer |
US20080050571A1 (en) * | 2004-12-28 | 2008-02-28 | Enamul Haque | Polymer/WUCS mat for use in automotive applications |
US20060137799A1 (en) * | 2004-12-29 | 2006-06-29 | Enamul Haque | Thermoplastic composites with improved sound absorbing capabilities |
US7807592B2 (en) | 2005-04-25 | 2010-10-05 | Georgia-Pacific Gypsum Llc | Interior wallboard and method of making same |
US20060240236A1 (en) * | 2005-04-25 | 2006-10-26 | G-P Gypsum Corp. | Interior wallboard and method of making same |
US7635657B2 (en) | 2005-04-25 | 2009-12-22 | Georgia-Pacific Gypsum Llc | Interior wallboard and method of making same |
US20100048080A1 (en) * | 2005-04-25 | 2010-02-25 | Georgia-Pacific Gypsum Llc | Interior Wallboard and Method of Making Same |
US20090115075A1 (en) * | 2006-07-14 | 2009-05-07 | Kessel Carl R | Method for manufacturing thin substrate using a laminate body |
US7759050B2 (en) | 2006-07-14 | 2010-07-20 | 3M Innovative Properties Company | Method for manufacturing thin substrate using a laminate body |
US20080014532A1 (en) * | 2006-07-14 | 2008-01-17 | 3M Innovative Properties Company | Laminate body, and method for manufacturing thin substrate using the laminate body |
US20080057283A1 (en) * | 2006-08-29 | 2008-03-06 | Arthur Blinkhorn | Reinforced acoustical material having high strength, high modulus properties |
US8652288B2 (en) | 2006-08-29 | 2014-02-18 | Ocv Intellectual Capital, Llc | Reinforced acoustical material having high strength, high modulus properties |
US20090017323A1 (en) * | 2007-07-13 | 2009-01-15 | 3M Innovative Properties Company | Layered body and method for manufacturing thin substrate using the layered body |
US20090017248A1 (en) * | 2007-07-13 | 2009-01-15 | 3M Innovative Properties Company | Layered body and method for manufacturing thin substrate using the layered body |
US20100055439A1 (en) * | 2008-08-29 | 2010-03-04 | Lee Jerry H C | WUCS Fibers Having Improved Flowing And Dispersing Properties |
US20110151176A1 (en) * | 2008-09-02 | 2011-06-23 | Ryota Akiyama | Method of manufacturing wafer laminated body, device of manufacturing wafer laminated body, wafer laminated body, method of peeling support body, and method of manufacturing wafer |
DE102010023770A1 (en) | 2010-06-15 | 2011-12-15 | Basf Se | Thermoplastic molding composition, useful e.g. to produce circuit board, comprises polyamide, flame retardant comprising phosphinic acid salt, nitrogen-containing flame retardant and optionally zinc salt, layered silicate and additive |
CN105000809A (en) * | 2015-06-30 | 2015-10-28 | 营口市广吉玻璃纤维有限公司 | Organic silicon resin film-forming agent impregnating agent for glass fiber drawing |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4394414A (en) | Aqueous sizing composition for glass fibers for use on chopped glass fibers | |
US4461804A (en) | Aqueous sizing composition for glass fibers for use in producing a mat | |
US4465500A (en) | Method for sizing glass fibers | |
US4728573A (en) | Glass fibers for reinforcing polymers | |
EP0208197B1 (en) | Chemically treated glass fibers | |
EP0750594B1 (en) | Glass fiber sizing and sized glass fibers and polyolefin reinforcing articles | |
US4394418A (en) | Aqueous sizing composition and glass fibers made therewith for reinforcing thermosetting polymers | |
US4681802A (en) | Treated glass fibers and aqueous dispersion and nonwoven mat of the glass fibers | |
KR100245067B1 (en) | Forming size compositions, glass fibers coated with the same and fabrics woven from such coated fibers | |
US4457785A (en) | Treated glass fibers and nonwoven sheet-like mat and method | |
US4394475A (en) | Aqueous sizing composition for producing sized glass fiber strands with improved slip flow properties | |
US5130197A (en) | Glass fibers for reinforcing polymers | |
US5604270A (en) | Chemical treating composition for glass fibers having emulsified epoxy with good stability and the treated glass fibers | |
US4397913A (en) | Starch-containing treating composition for glass fibers and treated glass fibers and strands | |
US4477524A (en) | Aqueous sizing composition for glass fibers for use on chopped glass fibers | |
US4265704A (en) | Method of dispersing bundles of glass fibers for making glass fiber mats by the wet-laid process | |
US4361465A (en) | Glass fibers with improved dispersibility in aqueous solutions and sizing composition and process for making same | |
EP0002002B1 (en) | Method of making uniform glass fiber mats by the wet-laid process from an aqueous dispersion | |
JPH0791394B2 (en) | Fiber-containing thermoplastic material by wet lamination and aqueous dispersion for preparing the same | |
US4370169A (en) | Aqueous dispersion of glass fibers and method and composition for producing same | |
US4681658A (en) | Treated glass fibers and nonwoven sheet-like mat and method | |
US4592956A (en) | Treated glass fibers and aqueous dispersion and nonwoven mat of the glass fibers | |
US4500600A (en) | Size composition for glass fibers | |
US4861812A (en) | Compositions for preparing cement-adhesive reinforcing fibers | |
US4626289A (en) | Treated glass fibers and aqueous dispersion and nonwoven mat of glass fibers |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: PPG INDUSTRIES, INC., PITTSBURGH, PA. A CORP. OF P Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNORS:BROWN, DANIEL G.;MOTSINGER, DONALD L.;REEL/FRAME:003893/0107;SIGNING DATES FROM 19810526 TO 19810527 |
|
STCF | Information on status: patent grant |
Free format text: PATENTED CASE |
|
MAFP | Maintenance fee payment |
Free format text: PAYMENT OF MAINTENANCE FEE, 4TH YEAR, PL 96-517 (ORIGINAL EVENT CODE: M170); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY Year of fee payment: 4 |
|
FEPP | Fee payment procedure |
Free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY |
|
MAFP | Maintenance fee payment |
Free format text: PAYMENT OF MAINTENANCE FEE, 8TH YEAR, PL 96-517 (ORIGINAL EVENT CODE: M171); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY Year of fee payment: 8 |
|
MAFP | Maintenance fee payment |
Free format text: PAYMENT OF MAINTENANCE FEE, 12TH YEAR, LARGE ENTITY (ORIGINAL EVENT CODE: M185); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY Year of fee payment: 12 |
|
AS | Assignment |
Owner name: PPG INDUSTRIES OHIO, INC., OHIO Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:PPG INDUSTRIES, INC.;REEL/FRAME:009737/0591 Effective date: 19990204 |
|
AS | Assignment |
Owner name: PPG INDUSTRIES OHIO, INC., OHIO Free format text: CORRECTIVE ASSIGNMENT TO CORRECT INCORRECT PROPERTY NUMBERS 08/666726;08/942182;08/984387;08/990890;5645767;5698141;5723072;5744070;5753146;5783116;5808063;5811034 PREVIOUSLY RECORDED ON REEL 009737 FRAME 0591. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT;ASSIGNOR:PPG INDUSTRIES, INC.;REEL/FRAME:032513/0174 Effective date: 19990204 |