US4636442A - Laminated structures of polyethylene terephthalate and elastomeric copolyesterethers - Google Patents
Laminated structures of polyethylene terephthalate and elastomeric copolyesterethers Download PDFInfo
- Publication number
- US4636442A US4636442A US06/786,433 US78643385A US4636442A US 4636442 A US4636442 A US 4636442A US 78643385 A US78643385 A US 78643385A US 4636442 A US4636442 A US 4636442A
- Authority
- US
- United States
- Prior art keywords
- glycol
- polyesterether
- shaped article
- film
- article according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
- B32B27/285—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/672—Dicarboxylic acids and dihydroxy compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2553/00—Packaging equipment or accessories not otherwise provided for
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31786—Of polyester [e.g., alkyd, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
Abstract
Description
TABLE 1 __________________________________________________________________________ Oriented Film Properties ASTM Commercial Commercial Method Units PET Coex #1 Coex #2 Product #1 Product #2 __________________________________________________________________________ Film Thickness (after mils 1.25 1.20 1.20 1.0 0.5 orient.) Tensile Strength (MD/TD) D-882 10.sup.3 psi 36.5/37.7 26.2/25.4 25.0/25.4 25.7/33.8 36.3/39.0 Break Elongation (MD/TD) D-882 % 97/105 86/80 92/77 105/53 98/121 Yield Strength (MD/TD) D-882 10.sup.3 psi 15.9/15.4 9.80/11.8 9.96/11.3 4.9/33.8 13.3/11.2 Film Modulus (MD/TD) D-882 10.sup.5 psi 6.06/6.01 3.49/3.81 3.64/4.25 3.35/5.29 5.95/4.80 MVTR **** 1.65 2.31 1.92 0.32 -- CO.sub.2 Transmission Rate ***** 41.1 49.17 43.31 untst. -- O.sub.2 Transmission Rate D-3985 ****** 5.37 7.604 6.984 untst. -- (before flexing) Flex-Crack Resistance F-392 pinholes untst. 14 17 2-5 120 60 minutes __________________________________________________________________________ *Heat set for 2 minutes at 180° C. forcedair oven ****MVTR (Moisture Vapor Transmission Rate) gm. mils/100 sq. in./24 hours *****CO.sub.2 - cc mil/100 sq. in. 24 hour atm. ******O.sub.2 - cc mil/100 sq. in. 24 hour atm. Note: PET and Coex films were biaxially oriented (4 × 4 at 100° C.) Flex-crack resistance was determined by ASTM F392 which required flexing (Gelbo FlexTester) oriented film (8 × 11 inches) for a specific tim and using a red dye to determine the number of pinholes in a 6 × 8 inch area.
TABLE 2 __________________________________________________________________________ FILM LAYER THICKNESS THICKNESS AFTER BEFORE WT. FLEX-CRACK ORIENTATION ORIENTATION % *TRIREFRINGENCE RESISTANCE Example (Mils) (Mils) PCCE (Average) (MD-TD) (30 Min.) (60 Min.) __________________________________________________________________________ 10 1.25 9.8/4.0/8.0 15.1 1.5055 10.0 16.0 ff** 11 1.30 5.1/3.5/5.8 20.7 1.5044 6.0 17.8 ff 12 1.30 6.8/3.8/5.0 20.7 1.5005 3.0 19.0 38.8 13 1.25 6.0/6.0/7.5 26.6 1.5044 11.0 4.6 10.4 14 1.22 6.0/5.5/5.8 27.6 1.5057 9.0 3.2 14.4 15 1.20 8.8/6.0/5.8 26.5 1.5069 -6.0 4.6 14.2 16 1.10 5.0/4.0/5.0 24.6 1.5013 -1.0 17.4 41.6 17 1.10 4.8/4.3/4.0 28.4 1.5023 -3.0 18.4 39.8 18 1.20 5.5/5.0/5.0 27.8 1.5036 -1.0 10.4 17.0 19 1.20 6.0/4.5/6.0 23.4 1.5057 8.0 6.8 20.6 20 1.25 4.2/3.8/4.8 25.5 1.5060 10.0 12.2 32.0 21 1.25 4.3/4.0/4.8 26.3 1.5043 3.0 21.4 36.2 22 1.20 4.2/4.0/6.0 24.2 1.5051 6.0 22.2 55.8 23 1.18 7.8/7.0/8.3 26.1 1.5048 5.0 4.0 12.8 24 1.10 7.5/5.4/7.0 23.3 1.5075 6.0 4.2 21.0 25 1.10 5.0/4.0/4.5 25.5 1.5053 0.0 7.6 32.6 26 1.10 3.8/4.0/5.0 27.0 1.5063 2.0 4.2 26.6 27 1.10 8.0/3.5/5.3 17.7 1.5059 1.0 6.2 36.6 28 1.25 Monolayer 0.0 1.5834 -2.0 ff ff 29 1.25 Monolayer 0.0 1.5912 2.0 ff ff 30 1.25 Monolayer 0.0 1.5948 -1.0 30.4 ff __________________________________________________________________________ *Trirefringence indicates uniformity of orientation; closest to 0 for MDTD is most uniform. **ff film failure (shredded)
TABLE 3 __________________________________________________________________________ METHOD UNITS Ex. 31 Ex. 32 Ex. 33 Ex. 34 Ex. 35 __________________________________________________________________________ Film Thickness (oriented) Mils 1.25 1.22 1.20 1.20 1.18 Film Layer Thickness Mils 6/6/7.5 6/5.5/5.8 8.8/6/5.8 5.5/5/5/ 7.8/7/8.3 Weight % PCCE % 26.6 27.6 26.5 27.8 26.1 *Flex - Crack Resistance: 30 Minutes F392 pinholes 5 3 5 10 4 60 Minutes F392 pinholes 10 14 14 17 13 Tensile Strength (MD/TD) D882 10.sup.3 psi. 25.4/23.8 28.0/23.8 26.2/25.4 25.0/25.4 30.5/26.3 Break Elongation (MD/TD) D882 % 86/75 92/84 86/80 92/77 90/71 Break Stress (MD/TD) D882 10.sup.3 psi. 25.4/23.8 28.0/23.8 26.2/25.4 25.0/25.4 30.5/26.3 Yield Stress (MD/TD) D882 10.sup.3 psi. 9.0/12.8 9.39/11.9 9.80/11.8 9.96/11.3 10.5/13.9 Film Modulus (MD/TD) D882 10.sup.5 psi. 3.23/3.76 3.36/3.50 3.49/3.81 3.64/4.25 3.59/4.25 Film Tear Propagation: D1938 lb./in. 89.8/75.3 71.8/75.3 62/89.9 45.7/61.2 75.9/85.5 (MD/TD) Permeability Properties: O2 D3985 *** 8.253 7.828 7.604 6.984 7.884 CO2 TEC *** 57.60 58.61 49.17 43.31 59.23 MVTR TEC **** 2.67 2.83 2.31 1.92 3.02 __________________________________________________________________________ *Flex-crack resistance is determined by ASTMF392. Oriented film samples ( each) are run on the Gelbo flextester for 30 and 60 minutes and using a red dye to determine the number of pinholes in a 6 × 8 inch area. ***O2 cc mil/100 sq. in. 24 Hr. Atm. ***CO2 cc mil/100 sq. in. 24 Hr. Atm. ****MVTR gm. mil/100 sq. in. 24 Hr.
Claims (10)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/786,433 US4636442A (en) | 1985-10-11 | 1985-10-11 | Laminated structures of polyethylene terephthalate and elastomeric copolyesterethers |
EP86906214A EP0244445B1 (en) | 1985-10-11 | 1986-10-09 | Laminated structures of polyethylene terephthalate and elastomeric copolyesterethers |
PCT/US1986/002113 WO1987002331A1 (en) | 1985-10-11 | 1986-10-09 | Laminated structures of polyethylene terephthalate and elastomeric copolyesterethers |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/786,433 US4636442A (en) | 1985-10-11 | 1985-10-11 | Laminated structures of polyethylene terephthalate and elastomeric copolyesterethers |
Publications (1)
Publication Number | Publication Date |
---|---|
US4636442A true US4636442A (en) | 1987-01-13 |
Family
ID=25138561
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US06/786,433 Expired - Lifetime US4636442A (en) | 1985-10-11 | 1985-10-11 | Laminated structures of polyethylene terephthalate and elastomeric copolyesterethers |
Country Status (3)
Country | Link |
---|---|
US (1) | US4636442A (en) |
EP (1) | EP0244445B1 (en) |
WO (1) | WO1987002331A1 (en) |
Cited By (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4769273A (en) * | 1987-12-28 | 1988-09-06 | E. I. Du Pont De Nemours And Company | Bicomponent moisture barrier poly(etherimide) ester films |
US4772652A (en) * | 1986-05-27 | 1988-09-20 | Kuraray Co., Ltd. | Copolyester and polyester resin composition comprising said copolyester |
EP0297423A2 (en) * | 1987-06-30 | 1989-01-04 | Hoechst Celanese Corporation | Polyester moulding composition having particular processing properties |
JPS6480528A (en) * | 1987-09-22 | 1989-03-27 | Dainippon Printing Co Ltd | Laminated material of superior fragrance retention |
US4828927A (en) * | 1986-05-26 | 1989-05-09 | Agfa-Gevaert, N.V. | Sheet or web carrying an antistatic layer |
US4868062A (en) * | 1987-12-28 | 1989-09-19 | E. I. Du Pont De Nemours And Company | Vapor permeable poly(etherimide) ester elastomer films |
US5034263A (en) * | 1989-11-27 | 1991-07-23 | Eastman Kodak Company | Film laminate |
EP0493008A2 (en) * | 1990-12-21 | 1992-07-01 | Toray Industries, Inc. | Polyester film and photosensitive material |
EP0581970A1 (en) * | 1992-02-25 | 1994-02-09 | Toray Industries, Inc. | Biaxially oriented, laminated polyester film |
US5304224A (en) * | 1992-10-01 | 1994-04-19 | Minnesota Mining And Manufacturing Company | Coated abrasive article having a tear resistant backing |
US5355636A (en) * | 1992-10-01 | 1994-10-18 | Minnesota Mining And Manufacturing Company | Tear resistant coated abrasive article |
US5427842A (en) * | 1992-10-01 | 1995-06-27 | Minnesota Mining And Manufacturing Company | Tear resistant multilayer films and articles incorporating such films |
US5797877A (en) | 1993-10-01 | 1998-08-25 | Boston Scientific Corporation | Medical device balloons containing thermoplastic elastomers |
US5882774A (en) * | 1993-12-21 | 1999-03-16 | Minnesota Mining And Manufacturing Company | Optical film |
US5976424A (en) * | 1996-07-31 | 1999-11-02 | Minnesota Mining And Manufacturing Company | Method for making multilayer optical films having thin optical layers |
US6040061A (en) * | 1992-10-01 | 2000-03-21 | 3M Innovative Properties Company | Tear resistant multilayer films based on sebacic acid copolyesters and articles incorporating such films |
US6045895A (en) * | 1997-12-01 | 2000-04-04 | 3M Innovative Properties Company | Multilayer films having pressure sensitive adhesive layers |
US6132824A (en) | 1989-09-25 | 2000-10-17 | Schneider (Usa) Inc. | Multilayer catheter balloon |
US6136258A (en) | 1991-04-26 | 2000-10-24 | Boston Scientific Corporation | Method of forming a co-extruded balloon for medical purposes |
US6673423B2 (en) * | 1999-09-10 | 2004-01-06 | Dsm N.V. | Information-carrying moulded part |
US20040078052A1 (en) * | 2002-10-21 | 2004-04-22 | St. Pierre Ernest J. | Multilayer medical device |
US20040121172A1 (en) * | 2002-12-19 | 2004-06-24 | George Henry Hofmann | Co-extrudable multi-layer polymer |
US20040146670A1 (en) * | 2003-01-27 | 2004-07-29 | Albert Chin | Multilayer balloon catheter |
US6894204B2 (en) | 2001-05-02 | 2005-05-17 | 3M Innovative Properties Company | Tapered stretch removable adhesive articles and methods |
EP1547766A1 (en) * | 2002-09-10 | 2005-06-29 | Toray Industries, Inc. | Biaxially oriented polyester film |
WO2005061580A1 (en) * | 2003-12-04 | 2005-07-07 | Eastman Chemical Company | Shaped articles from cycloaliphatic polyester compositions |
US20050186370A1 (en) * | 1993-10-01 | 2005-08-25 | Boston Scientific Corporation, A Massachusetts Corporation | Medical device balloons containing thermoplastic elastomers |
US20060127657A1 (en) * | 2003-10-02 | 2006-06-15 | Energy Technology Group, Inc. | Elastomer and polyolefin resin based films and associated methods |
US7078582B2 (en) | 2001-01-17 | 2006-07-18 | 3M Innovative Properties Company | Stretch removable adhesive articles and methods |
US20070287017A1 (en) * | 2006-06-07 | 2007-12-13 | Toray Plastics (America), Inc. Lumirror Divison | High barrier laminate and process |
US20090022919A1 (en) * | 2006-06-07 | 2009-01-22 | Toray Plastics (America), Inc. | Lighter than air balloon made from a biaxially oriented polyester film |
US20090218707A1 (en) * | 1998-01-13 | 2009-09-03 | 3M Innovative Properties Company | Method for making pen/pmma multilayer optical films |
US7852560B2 (en) | 1993-12-21 | 2010-12-14 | 3M Innovative Properties Company | Display incorporating reflective polarizer |
US7947059B2 (en) | 2000-03-02 | 2011-05-24 | Boston Scientific Scimed, Inc. | Multilayer medical device |
US9186593B2 (en) | 2006-06-07 | 2015-11-17 | Toray Plastics (America), Inc. | Stretchable and formable lighter than air balloons made from a biaxially oriented polyester film |
US9561676B2 (en) | 2011-07-08 | 2017-02-07 | Toray Plastics (America), Inc. | Biaxially oriented bio-based polyester thin films and laminates for thermal transfer printing |
US10137625B2 (en) | 2011-07-08 | 2018-11-27 | Toray Plastics (America), Inc. | Biaxially oriented bio-based polyester films and laminates |
US11318721B2 (en) | 2016-06-28 | 2022-05-03 | Toray Plastics (America), Inc. | Method of forming a formable polyester film |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4349469A (en) * | 1981-02-17 | 1982-09-14 | Eastman Kodak Company | Copolyesterethers |
US4476189A (en) * | 1983-05-16 | 1984-10-09 | American Hoechst Corporation | Copolyester primed polyester film |
-
1985
- 1985-10-11 US US06/786,433 patent/US4636442A/en not_active Expired - Lifetime
-
1986
- 1986-10-09 WO PCT/US1986/002113 patent/WO1987002331A1/en active IP Right Grant
- 1986-10-09 EP EP86906214A patent/EP0244445B1/en not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4349469A (en) * | 1981-02-17 | 1982-09-14 | Eastman Kodak Company | Copolyesterethers |
US4476189A (en) * | 1983-05-16 | 1984-10-09 | American Hoechst Corporation | Copolyester primed polyester film |
Cited By (68)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4828927A (en) * | 1986-05-26 | 1989-05-09 | Agfa-Gevaert, N.V. | Sheet or web carrying an antistatic layer |
US4931538A (en) * | 1986-05-27 | 1990-06-05 | Kuraray Co., Ltd. | Copolyester and polyester resin composition comprising said copolyester |
US4772652A (en) * | 1986-05-27 | 1988-09-20 | Kuraray Co., Ltd. | Copolyester and polyester resin composition comprising said copolyester |
US4918156A (en) * | 1987-06-30 | 1990-04-17 | Hoechst Celanese Corporation | Polyester resin having improved processability |
EP0297423A3 (en) * | 1987-06-30 | 1989-08-23 | Hoechst Celanese Corporation | Polyester moulding composition having particular processing properties |
EP0297423A2 (en) * | 1987-06-30 | 1989-01-04 | Hoechst Celanese Corporation | Polyester moulding composition having particular processing properties |
JPS6480528A (en) * | 1987-09-22 | 1989-03-27 | Dainippon Printing Co Ltd | Laminated material of superior fragrance retention |
US4868062A (en) * | 1987-12-28 | 1989-09-19 | E. I. Du Pont De Nemours And Company | Vapor permeable poly(etherimide) ester elastomer films |
US4769273A (en) * | 1987-12-28 | 1988-09-06 | E. I. Du Pont De Nemours And Company | Bicomponent moisture barrier poly(etherimide) ester films |
US6132824A (en) | 1989-09-25 | 2000-10-17 | Schneider (Usa) Inc. | Multilayer catheter balloon |
US5034263A (en) * | 1989-11-27 | 1991-07-23 | Eastman Kodak Company | Film laminate |
EP0493008A3 (en) * | 1990-12-21 | 1992-08-12 | Toray Industries, Inc. | Polyester film and photosensitive material |
EP0493008A2 (en) * | 1990-12-21 | 1992-07-01 | Toray Industries, Inc. | Polyester film and photosensitive material |
US20050238833A1 (en) * | 1991-04-26 | 2005-10-27 | Boston Scientific Corporation, A Delaware Corporation | Co-extruded medical balloon |
US6482348B1 (en) | 1991-04-26 | 2002-11-19 | Boston Scientific Corporation | Method of forming a co-extruded balloon for medical purposes |
US6136258A (en) | 1991-04-26 | 2000-10-24 | Boston Scientific Corporation | Method of forming a co-extruded balloon for medical purposes |
US5747174A (en) * | 1992-02-25 | 1998-05-05 | Toray Industries, Inc. | Biaxially oriented, laminated polyester film |
EP0581970A1 (en) * | 1992-02-25 | 1994-02-09 | Toray Industries, Inc. | Biaxially oriented, laminated polyester film |
EP0581970A4 (en) * | 1992-02-25 | 1994-04-06 | Toray Industries, Inc. | |
US5304224A (en) * | 1992-10-01 | 1994-04-19 | Minnesota Mining And Manufacturing Company | Coated abrasive article having a tear resistant backing |
US6040061A (en) * | 1992-10-01 | 2000-03-21 | 3M Innovative Properties Company | Tear resistant multilayer films based on sebacic acid copolyesters and articles incorporating such films |
US5604019A (en) * | 1992-10-01 | 1997-02-18 | Minnesota Mining And Manufacturing Company | Tear resistant multilayer films and articles incorporating such films |
US5427842A (en) * | 1992-10-01 | 1995-06-27 | Minnesota Mining And Manufacturing Company | Tear resistant multilayer films and articles incorporating such films |
US5355636A (en) * | 1992-10-01 | 1994-10-18 | Minnesota Mining And Manufacturing Company | Tear resistant coated abrasive article |
US5797877A (en) | 1993-10-01 | 1998-08-25 | Boston Scientific Corporation | Medical device balloons containing thermoplastic elastomers |
US20050186370A1 (en) * | 1993-10-01 | 2005-08-25 | Boston Scientific Corporation, A Massachusetts Corporation | Medical device balloons containing thermoplastic elastomers |
US6086556A (en) | 1993-10-01 | 2000-07-11 | Boston Scientific Corporation | Medical device balloons containing thermoplastic elastomers |
US7781038B2 (en) | 1993-10-01 | 2010-08-24 | Boston Scientific Scimed, Inc. | Medical device balloons containing thermoplastic elastomers |
US5882774A (en) * | 1993-12-21 | 1999-03-16 | Minnesota Mining And Manufacturing Company | Optical film |
US20040043205A1 (en) * | 1993-12-21 | 2004-03-04 | 3M Innovative Properties Company | Optical film |
US7852560B2 (en) | 1993-12-21 | 2010-12-14 | 3M Innovative Properties Company | Display incorporating reflective polarizer |
US6613421B2 (en) | 1993-12-21 | 2003-09-02 | 3M Innovative Properties Company | Optical film |
US7297393B2 (en) | 1993-12-21 | 2007-11-20 | 3M Innovative Properties Company | Optical film |
US7083847B2 (en) | 1993-12-21 | 2006-08-01 | 3M Innovative Properties Company | Optical film |
US5976424A (en) * | 1996-07-31 | 1999-11-02 | Minnesota Mining And Manufacturing Company | Method for making multilayer optical films having thin optical layers |
US6045895A (en) * | 1997-12-01 | 2000-04-04 | 3M Innovative Properties Company | Multilayer films having pressure sensitive adhesive layers |
US20090218707A1 (en) * | 1998-01-13 | 2009-09-03 | 3M Innovative Properties Company | Method for making pen/pmma multilayer optical films |
US6673423B2 (en) * | 1999-09-10 | 2004-01-06 | Dsm N.V. | Information-carrying moulded part |
US7947059B2 (en) | 2000-03-02 | 2011-05-24 | Boston Scientific Scimed, Inc. | Multilayer medical device |
US7078582B2 (en) | 2001-01-17 | 2006-07-18 | 3M Innovative Properties Company | Stretch removable adhesive articles and methods |
US6894204B2 (en) | 2001-05-02 | 2005-05-17 | 3M Innovative Properties Company | Tapered stretch removable adhesive articles and methods |
EP1547766A1 (en) * | 2002-09-10 | 2005-06-29 | Toray Industries, Inc. | Biaxially oriented polyester film |
EP1547766A4 (en) * | 2002-09-10 | 2009-07-15 | Toray Industries | Biaxially oriented polyester film |
US7488339B2 (en) | 2002-10-21 | 2009-02-10 | Boston Scientific Scimed, Inc. | Multilayer medical device |
US20040078052A1 (en) * | 2002-10-21 | 2004-04-22 | St. Pierre Ernest J. | Multilayer medical device |
US7261935B2 (en) * | 2002-12-19 | 2007-08-28 | E. I. Du Pont De Nemours And Company | Co-extrudable multi-layer polymer |
US20040121172A1 (en) * | 2002-12-19 | 2004-06-24 | George Henry Hofmann | Co-extrudable multi-layer polymer |
US8231374B2 (en) | 2003-01-27 | 2012-07-31 | Boston Scientific Scimed, Inc. | Extrusion apparatus for making multilayer articles |
US20050266109A1 (en) * | 2003-01-27 | 2005-12-01 | Scimed Life Systems, Inc., A Delaware Corporation | Multilayer balloon catheter |
US6951675B2 (en) | 2003-01-27 | 2005-10-04 | Scimed Life Systems, Inc. | Multilayer balloon catheter |
US20040146670A1 (en) * | 2003-01-27 | 2004-07-29 | Albert Chin | Multilayer balloon catheter |
US20100203181A1 (en) * | 2003-01-27 | 2010-08-12 | Boston Scientific Scimed, Inc. | Extrusion apparatus for making multilayer articles |
US7713047B2 (en) | 2003-01-27 | 2010-05-11 | Boston Scientific Scimed, Inc. | Extrusion apparatus for making multilayer articles |
US7582341B2 (en) * | 2003-10-02 | 2009-09-01 | Exopack Technology Llc | Elastomer and polyolefin resin based films and associated methods |
US20060127657A1 (en) * | 2003-10-02 | 2006-06-15 | Energy Technology Group, Inc. | Elastomer and polyolefin resin based films and associated methods |
CN1890288B (en) * | 2003-12-04 | 2012-07-18 | 伊士曼化工公司 | Shaped articles from cycloaliphatic polyester compositions |
WO2005061580A1 (en) * | 2003-12-04 | 2005-07-07 | Eastman Chemical Company | Shaped articles from cycloaliphatic polyester compositions |
US7799399B2 (en) | 2006-06-07 | 2010-09-21 | Toray Plastics (America), Inc. | High barrier laminate and process |
US20090022919A1 (en) * | 2006-06-07 | 2009-01-22 | Toray Plastics (America), Inc. | Lighter than air balloon made from a biaxially oriented polyester film |
WO2007145898A1 (en) * | 2006-06-07 | 2007-12-21 | Toray Plastics (America), Inc. Lumirror Divison | High barrier laminate and process |
US20070287017A1 (en) * | 2006-06-07 | 2007-12-13 | Toray Plastics (America), Inc. Lumirror Divison | High barrier laminate and process |
US8236399B2 (en) | 2006-06-07 | 2012-08-07 | Toray Plastics (America), Inc. | Lighter than air balloon made from a biaxially oriented polyester film |
US8323759B2 (en) | 2006-06-07 | 2012-12-04 | Toray Plastics (America), Inc. | Lighter than air balloon made from a biaxially oriented polyester film |
US8399080B2 (en) | 2006-06-07 | 2013-03-19 | Toray Plastics (America), Inc. | Lighter than air balloon made from a biaxially oriented polyester film |
US9186593B2 (en) | 2006-06-07 | 2015-11-17 | Toray Plastics (America), Inc. | Stretchable and formable lighter than air balloons made from a biaxially oriented polyester film |
US9561676B2 (en) | 2011-07-08 | 2017-02-07 | Toray Plastics (America), Inc. | Biaxially oriented bio-based polyester thin films and laminates for thermal transfer printing |
US10137625B2 (en) | 2011-07-08 | 2018-11-27 | Toray Plastics (America), Inc. | Biaxially oriented bio-based polyester films and laminates |
US11318721B2 (en) | 2016-06-28 | 2022-05-03 | Toray Plastics (America), Inc. | Method of forming a formable polyester film |
Also Published As
Publication number | Publication date |
---|---|
EP0244445B1 (en) | 1990-01-03 |
WO1987002331A1 (en) | 1987-04-23 |
EP0244445A1 (en) | 1987-11-11 |
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