US4931324A - Decorative sheet material simulating the appearance of a base coat/clear coat paint finish - Google Patents
Decorative sheet material simulating the appearance of a base coat/clear coat paint finish Download PDFInfo
- Publication number
- US4931324A US4931324A US07/241,856 US24185688A US4931324A US 4931324 A US4931324 A US 4931324A US 24185688 A US24185688 A US 24185688A US 4931324 A US4931324 A US 4931324A
- Authority
- US
- United States
- Prior art keywords
- sheet material
- decorative sheet
- outer layer
- pigmented coating
- flexible
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/68—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts by incorporating or moulding on preformed parts, e.g. inserts or layers, e.g. foam blocks
- B29C70/78—Moulding material on one side only of the preformed part
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14311—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles using means for bonding the coating to the articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14778—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the article consisting of a material with particular properties, e.g. porous, brittle
- B29C45/14811—Multilayered articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C5/00—Processes for producing special ornamental bodies
- B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44F—SPECIAL DESIGNS OR PICTURES
- B44F1/00—Designs or pictures characterised by special or unusual light effects
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44F—SPECIAL DESIGNS OR PICTURES
- B44F1/00—Designs or pictures characterised by special or unusual light effects
- B44F1/02—Designs or pictures characterised by special or unusual light effects produced by reflected light, e.g. matt surfaces, lustrous surfaces
- B44F1/04—Designs or pictures characterised by special or unusual light effects produced by reflected light, e.g. matt surfaces, lustrous surfaces after passage through surface layers, e.g. pictures with mirrors on the back
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
- B60R13/02—Internal Trim mouldings ; Internal Ledges; Wall liners for passenger compartments; Roof liners
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
- B60R13/04—External Ornamental or guard strips; Ornamental inscriptive devices thereon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B62—LAND VEHICLES FOR TRAVELLING OTHERWISE THAN ON RAILS
- B62D—MOTOR VEHICLES; TRAILERS
- B62D29/00—Superstructures, understructures, or sub-units thereof, characterised by the material thereof
- B62D29/04—Superstructures, understructures, or sub-units thereof, characterised by the material thereof predominantly of synthetic material
- B62D29/043—Superstructures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/16—Making multilayered or multicoloured articles
- B29C45/1657—Making multilayered or multicoloured articles using means for adhering or bonding the layers or parts to each other
- B29C2045/166—Roughened surface bonds
- B29C2045/1662—Roughened surface bonds plasma roughened surface bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2715/00—Condition, form or state of preformed parts, e.g. inserts
- B29K2715/006—Glues or adhesives, e.g. hot melts or thermofusible adhesives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
- B29K2995/002—Coloured
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
- B29K2995/0022—Bright, glossy or shiny surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
- B29K2995/0026—Transparent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0037—Other properties
- B29K2995/0072—Roughness, e.g. anti-slip
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/722—Decorative or ornamental articles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/14—Layer or component removable to expose adhesive
- Y10T428/1424—Halogen containing compound
- Y10T428/1429—Fluorine
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/14—Layer or component removable to expose adhesive
- Y10T428/1424—Halogen containing compound
- Y10T428/1433—Coloring agent containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/16—Two dimensionally sectional layer
- Y10T428/162—Transparent or translucent layer or section
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24893—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including particulate material
- Y10T428/24909—Free metal or mineral containing
Definitions
- the present invention relates to sheet materials generally, and particularly relates to a sheet material which can be used to provide a decorative surface on automobile body panels and the like.
- Base coat/clear coat finishes pose significant (and expensive) pollution problems arising from the evaporation of harmful paint solvents. Moreover, they are difficult to provide on plastic automobile body panels, which are becoming a popular mode of construction in the industry. Finally, base coat/clear coat paint finishes in general involve multiple painting steps which are very expensive to perform when high quality standards are maintained.
- objects of the present invention are to provide a way to produce automobiles and the like with high quality decorative finishes like a base coat/clear coat finish, which can be used on molded plastic body panels, which does not require expensive painting steps, and which serves to reduce the emission control problems previously faced by manufacturers who wished to produce automobiles with base coat/clear coat finishes.
- a flexible decorative sheet material for use in surfacing automobile body panels and the like.
- This sheet material is characterized by having the appearance of a base coat/clear coat paint finish when viewing the outer surface thereof.
- the sheet material comprises a glossy, substantially transparent outer layer and a pigmented coating on the undersurface of the outer layer and visible therethrough.
- the glossy "wet look” is achieved by a combination of layered coatings, with the outer or top layer being of good optical clarity and exceptionally good surface smoothness.
- the outer layer must be of high gloss and should possess a high distinctness-of-image value, preferably of 65 percent or higher, and most desirably of 75 percent or higher.
- the outer layer should also have low surface haze, preferably a 2 degree haze value of 1 percent or less. Additionally, the outer layer must be weatherable, so as to withstand exposure to sunlight and temperature extremes without hazing, color change, cracking, crazing or embrittlement.
- the outer layer is formed from a substantially clear weatherable polymer, preferably a polymer selected from the group consisting of fluoropolymers, acrylate polymers, urethane polymers, vinyl polymers and blends thereof.
- the transparent outer layer is preferably of a thickness greater than that of the pigmented coating layer. The precise thickness of the pigmented coating is, however, selected to impart the specific predetermined appearance to the sheet material which is desired.
- the pigmented coating optionally has reflective flakes uniformly distributed therein to impart to the sheet material the appearance of a metallic base coat/clear coat paint finish.
- the reflective flakes in the pigmented coating are preferably oriented generally parallel to the outer layer.
- Sheet materials of the present invention include dual-color sheet materials which comprise a substantially transparent outer layer and a pigmented coating on the undersurface thereof, wherein the pigmented coating comprises a first pigmented coating on certain portions of the undersurface of the outer layer and visible therethrough, and a second pigmented coating of a different color on certain other portions of the undersurface of the outer layer, which second pigmented coating is also visible therethrough.
- the articles comprise a supporting substrate and a decorative sheet material adhered to one side of the substrate, conforming to the contoured surface to impart to the outer surface the appearance of a base coat/clear coat paint finish.
- the decorative sheet material is as described above.
- the supporting substrate which may be formed of a number of materials, is preferably a rigid metal substrate or a molded polymer substrate.
- the present invention allows paint and finish handling steps involving solvents to be performed in a central plant, and the "finish" to be shipped, in sheet form, to a number of automobile assembly plants and the like. This allows solvent emission control problems attendant to such procedures to be handled in a centralized location, reduces the emission control expenses at numerous assembly plants, and serves to reduce the cost and complexity of solvent emissions control in general.
- FIG. 1 is a cross-sectional view of a decorative sheet material of the present invention.
- FIG. 2 is a schematic diagram which illustrates the properties of sheet materials of the present invention.
- FIG. 3 is a schematic illustration of a method for making decorative sheet materials of the present invention.
- FIG. 4 is an article of the present invention with a portion broken away to show the decorative sheet material on the outer surface thereof.
- a decorative sheet material 10 of the present invention is illustrated in FIG. 1.
- the sheet material comprises a substantially clear outer film 11, a pigmented coating 12 on the undersurface of the film 11, and a bonding layer 13 carried by the inner surface of the pigmented coating.
- Films 11 for practicing the present invention should be selected so they are transparent, thermoformable and weatherable.
- the film 11 is about 0.5 to about 300 thousandths of an inch thick, and is preferably from about one to about two thousandths of an inch thick.
- Such films are preferably substantially molecularly unoriented cast films, as opposed to films which have been oriented or biaxially oriented, and are preferably substantially colorless.
- the cast film is formed before the pigmented coating is applied thereto.
- Such films are prepared by a number of known liquid casting methods, such as by spreading a solvent solution having a polymer dissolved therein onto a carrier with a casting die, doctor bar, or reverse roll coater, then evaporating the solvent, and then stripping the polymer film from the carrier.
- the reverse roll coating method is the preferred method of making liquid cast films for the present invention.
- Other liquid casting methods are also known and useful for practicing the present invention.
- a plastisol, organosol, or dispersion of the polymer can be cast onto the carrier instead of a solvent solution.
- polytetrafluoroethylene which is virtually insoluble, can be liquified and cast as a dispersion.
- Such liquid cast film processes, and some current uses of cast films, are discussed in Plastics Engineering, at pages 29-33 (May, 1983).
- substantially molecularly unoriented cast films are liquid cast films, and not melt cast films or films formed by extrusion.
- Polymers suitable for forming such cast films are preferably weatherable polymers selected to provide a film which will not significantly fade, peel, crack, or chalk when exposed to the environment, for the intended life of the product for which the decorative sheet material is made.
- weatherable polymers include fluoropolymers, acrylate polymers, urethane polymers, vinyl polymers, and blends thereof.
- Acrylate polymers useful for practicing the present invention are obtained from a variety of acrylic monomers, such as acrylic and methacrylic acids, and their amides, esters, salts, and corresponding nitriles.
- Particularly suitable monomers for such polymers are methyl methacrylate, ethyl acrylate, and acrylonitrile.
- the polymers may each be used in the form of homopolymers, or with various other monomers which can be copolymerized therewith.
- acrylate polymers useful for the present invention are polyacrylates and polymethacrylates which are homopolymers and copolymers of acrylic acid ester and methacrylic acid ester, such as, for example, polyacrylic acid isobutyl ester, polymethacrylic acid methyl ester, polymethacrylic acid ethylhexyl ester, polyacrylic acid ethyl ester; copolymers of various acrylic acid esters and/or methacrylic acid esters, such as, for example, methacrylic acid methyl ester/acrylic acid cyclohexyl ester copolymers; and copolymers of acrylic acid esters and/or methacrylic acid esters with styrene and/or alphamethylstyrene, as well as the graft polymers and copolymers and polymer mixtures composed of acrylic esters, methacrylic acid esters, styrene and butadiene.
- Fluoropolymers useful for practicing the present invention include polymers and copolymers formed from trifluoroethylene, tetrafluoroethylene, hexafluoropropylene, monochlorotrifluoroethylene and dichlorodifluoroethylene. Copolymers of these monomers formed from fluoroolefins such as vinylidene fluoride are also useful. Further illustrative examples of fluoropolymers useful for practicing the present invention include polyvinyl fluoride and polyvinylidene fluoride.
- the fluoropolymer may be a fluorinated ethylene/propylene copolymer (the easily fabricated "FEP” resins), or a copolymer of ethylene/chlorotrifluoroethylene such as "HALAR.”
- FEP fluorinated ethylene/propylene copolymer
- HALAR ethylene/chlorotrifluoroethylene
- Vinylidene fluoride/hexafluoropropene and vinylidene fluoride/perfluoro (alkyl vinyl ether) dipolymers and terpolymers with tetrafluoroethylene are additional illustrative fluoropolymers useful for practicing the present invention.
- a preferred weatherable polymer for use in the present invention is an alloy of an acrylic polymer and polyvinylidene fluoride, such as "FLUOREX" (a trademark of Rexham Corporation).
- Urethane polymers useful for practicing the present invention are prepared by reacting a polyisocyanate with a compound containing at least two active hydrogen atoms, such as a polyol, a polyamine, or a polyisocyanate.
- Polyurethane resins for use in the present invention should be selected from resins in which the reactants have been chosen to provide weatherable, thermoformable polymers. Numerous suitable polyurethane resins useful for practicing the present invention are available. Generally, aromatic polyisocyanates tend to yellow, and aliphatic polyisocyanates are more preferred. Particularly noteworthy recent developments in this area are disclosed in U.S. Pat. No.
- films formed of vinyl polymers such as polyvinylchloride films and films formed from copolymers thereof, may also be used to practice the present invention, though such films are generally not as weatherable as films formed from the previously discussed polymers.
- the pigmented coating 12 is preferably formed of the same polymer as the outer film 11, or may optionally be formed of a different polymer which will bond to the outer film 11 during the manufacture of the decorative sheet material, as explained below. Pigments are dispersed in the polymer at a suitable concentration to form a substantially opaque coating of the desired color.
- the specific pigments are selected as desired depending upon the desired color.
- the pigments are selected so that the coating will match the automotive paint standard, and the pigments employed may include conventional nonmetallic pigments as well as metallic pigments.
- the pigmented coating 12 is a metallic finish, and to this end, the coating has reflective flakes 14 uniformly distributed therein.
- the reflective flakes 14 may, for example, comprise aluminum flakes or mica flakes. Mica flakes used in the present invention may be untreated, or tinted or otherwise surface treated, as known in the art.
- the reflective flakes 14 are oriented generally parallel to the outer film 11, with the flakes preferably being oriented so the mean angle of inclination of the flakes to the outer film 11 is less than about 6.5 degrees. The precise limits of the angle of inclination depends on a number of conditions, including the particular type of reflective flake used, the composition of the pigmented coating 12, and the composition of the outer preformed film 11.
- the flakes contribute to the "flop" effect described previously. Flop is due to the orientation of the reflective flakes generally parallel to the surface of the finish. As illustrated in FIG. 2, the observer at A' sees the light A reflected by the flakes. A similar situation exists for the observer at B' with light B. Because of the phenomenon of flop, light intensity is lower at B' than A'; i.e., the finish appears darker at B' than A'.
- the bonding layer 13 carried by the inner surface of the pigmented coating 12 may comprise a coating or preferably a film laminated to the pigmented coating. Bonding of the pigmented coating 12 to a film bonding layer can be achieved in accordance with known laminating procedures, and with known adhesives.
- the bonding layer 13 is selected to bond to the substrate for which the decorative sheet material is intended. For example, a decorative sheet material having a fusible olefin bonding layer can be placed in a mold during injection of an olefin resin.
- Another approach is to bond a PVC film to a fluoropolymer pigment layer with an acrylic adhesive and, in turn, bond the PVC film to an olefin film with a polyester isocyanate adhesive.
- the pigmented coating 12 may also be laminated to an olefin film with a permanent type acrylic pressure-sensitive adhesive. Still another approach is to coat the pigmented layer 12 with a soluble olefin resin which adheres thereto and bonds to the injected resin without having or requiring an olefin film layer.
- a resin is chlorinated polyolefin 343-1 from Eastman Kodak. This resin may be used in conjunction with an acrylic primer or ingredient to bond to desired fluorocarbon films. Corona treatment of the olefin surface to be bonded to the cast film may optionally be used to achieve an optimum bond. Bonding may also be improved by surface treating the cast film, as by corona treatment.
- the preferred method for making the decorative sheet material 10 of the present invention is by reverse-roll coating, as illustrated in FIG. 3.
- Reverse-roll coating involves providing a puddle 20 of polymer solution between an applicator roll 21 and a metering roll 22.
- the rolls (21,22), which rotate in the same direction, are spaced apart a predetermined distance to meter a film 23a of the solution onto the applicator roll.
- the film on the applicator roll is then applied to a suitable smooth surfaced, high gloss carrier 24.
- a preferred carrier material for use in the invention is a polyethylene terephthalate (PET) film. PET films useful as a carrier for casting are manufactured in a number of grades depending on end use requirements.
- PET polyethylene terephthalate
- Most grades contain particulate material such as clay to slightly roughen the surface for improved slip. While this roughening improves film winding and handling, it increases surface haze and reduces distinctness-of-image (DOI) of films cast on such surfaces.
- DOI distinctness-of-image
- the preferred PET film for use in the present invention has no slip additive.
- Such films are commercially available with one side treatment or knurled edges to facilitate winding. Table 1 below illustrates the effect of surface roughness on haze and DOI of a nonmetallic FluorexTM lab-made black base coat/clear coat liquid cast film.
- the carrier is advanced past a spray apparatus and the film 23a is sprayed with a liquid pigmented polymer to form the pigment coating layer 12.
- a liquid pigmented polymer to form the pigment coating layer 12.
- An advantage of application by spraying is that the resulting appearance properties simulate that of spray-applied paint to a high degree. While other application methods may be employed, spray application is the preferred method when a metallic pigmented coating is employed. As the solvents and diluents dry from the coating, the pigments become oriented in a generally parallel orientation, similar to the orientation of metallic pigments in a spray-applied metallic automotive paint finish. In the preferred embodiment illustrated, the liquid pigmented polymer is sprayed on the film before the film has solidified.
- the coated film is then dried, removed from the carrier, and--if desired--provided with a bonding layer in accordance with known procedures. If flakes are present in the pigmented polymer, spraying the pigmented polymer onto the cast film before the cast film has solidified allows the flakes to settle into the cast layer somewhat, and gives a greater depth effect to the film.
- the foregoing procedure is preferably used to coat the entire undersurface of the cast film.
- a striking visual effect can be achieved by spraying portions of the undersurface of the cast film with a liquid pigmented polymer, after which the other portions of the undersurface of the cast film is sprayed with a liquid pigmented polymer pigmented a different color than the preceding pigmented polymer.
- This technique can be used to provide decorative sheet materials which have a two-tone colored appearance, and the coatings can overlap so that the colored regions provided by this technique feather into one another.
- these two polymer coatings provide an opaque and uninterrupted (in opacity) coating to the undersurface of the substantially clear film.
- the decorative sheet material of the present invention can be adhered to a supporting substrate in accordance with known laminating or bonding techniques.
- Illustrative examples of supporting substrates include metal, wood, and molded polymer substrates.
- a shaped article 30 of the present invention comprises a supporting substrate 31 which has a contoured outer surface, and a decorative sheet material 10 adhered to one side of the substrate so as to conform to the contoured surface of the substrate.
- particularly suitable shaped articles of the present invention are exterior automobile body parts such as body panels and bumpers.
- the decorative sheet material can be bonded to molded polymer substrates by placing the sheet material into a mold having a contoured, three-dimensional molding surface. A moldable polymer is then introduced into the mold on one side of the sheet material. The sheet material is then molded into a contoured three-dimensional configuration conforming to the molding surface of said mold, while molding said polymer to form a shaped article with the decorative sheet material adhered to the outer surface thereof.
- the decorative sheet material includes a bonding layer, as described above, formed of a polymer different from the pigmented coating, wherein the decorative sheet material is placed into the mold with the bonding layer oriented inwardly away from the molding surface so as to become adhered to the moldable polymer.
- Suitable polymers for the molded polymer substrate include, for example, polyvinyl chloride, polycarbonate, polystyrene, acrylonitrile-butadiene-styrene, polyethylene, polypropylene, polyethylene terephthalate glycol (PETG), nylon, and RIM urethanes.
- Polyolefin homopolymers and copolymers (ionomers, etc.) are inexpensive thermoplastic resins which have excellent molding properties and are particularly preferred for practicing the present invention.
- Polypropylene for example, when glass filled and foamed with a blowing agent, has performance properties suitable for structural or engineering uses.
- Acid copolymers of polyethylene, such as Du Pont's "SURLYN" are similar in performance and in addition have exceptional toughness.
- the tear strength of the preformed film is less than the bond strength of the preformed film to the supporting substrate. This will prevent tears from developing in the preformed film running across the surface of the article, and quickly destroying the article.
Abstract
Description
TABLE 1 ______________________________________ Film Grade Ra.sup.1 (μm) DOI.sup.2 (%) 2° Haze.sup.2 (%) ______________________________________ 4300 0.006 70 0.2 3000 0.010 68 0.4 2000 0.028 34 1.7 ______________________________________ .sup.1 Ra Average roughness was measured on the Surtronic 3P surface roughness measurement instrument. Ra is affected by the length of the sample surface measured and the cutoff wavelength of the measurement. Ra values in this test were taken at a sample length of 4.8 mm and a cutoff wavelength of 0.25 mm. .sup.2 DOI distinctnessof-image measurements and 2° Haze measurements were made on the Hunterlab Dorigon Model D47R6 instrument from Hunter Associates Laboratory, Inc of Reston, VA. The Dorigon D47R6 measures, in percent, the amount of incident light reflected from materials relative to a standard. For nonmetallic surfaces, the standard is the amount of light reflected by a piece of polished black glass with an index of refraction of 1.567. DOI and 2° Haze are each expresse as a percentage of the specular reflectance of the specimen being measured. DOI is the sharpness of the reflected image, as measured by the ratio of the reflectance at 0.3° from specular to the reflectance at the specular angle. DOI is zero for a perfect diffuser and 100 for a perfect mirror. The 2° Haze value is the amount of spreading of specular reflectance as measured by the ratio of specular reflectance at 2° from specular to reflectance at the specular angle. Haze is zer for a perfect mirror and 100 for a perfect diffuser.
Claims (19)
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/241,856 US4931324A (en) | 1986-10-28 | 1988-09-08 | Decorative sheet material simulating the appearance of a base coat/clear coat paint finish |
US07/461,662 US4943680A (en) | 1986-10-28 | 1990-01-08 | Method of making a decorative sheet material simulating the appearance of a base coat/clear coat paint finish |
US08/754,302 USRE36457E (en) | 1986-10-28 | 1996-10-21 | Injection molded plastic article with integrated weatherable pigmented film surface |
US08/734,339 USRE35894E (en) | 1986-10-28 | 1996-10-21 | Injection molded plastic article with integral weatherable pigmented film surface |
US08/736,410 USRE35970E (en) | 1986-10-28 | 1996-10-24 | Injection molded plastic article with integral weatherable pigmented film surface |
US09/342,773 US6180195B1 (en) | 1986-10-28 | 1999-06-29 | Automobile body formed of interconnected molded plastic articles |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/924,299 US4810540A (en) | 1986-10-28 | 1986-10-28 | Decorative sheet material simulating the appearance of a base coat/clear coat paint finish |
US07/241,856 US4931324A (en) | 1986-10-28 | 1988-09-08 | Decorative sheet material simulating the appearance of a base coat/clear coat paint finish |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US06/924,299 Continuation-In-Part US4810540A (en) | 1986-10-28 | 1986-10-28 | Decorative sheet material simulating the appearance of a base coat/clear coat paint finish |
Related Child Applications (5)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US92429586A Continuation | 1986-10-28 | 1986-10-28 | |
US07/461,662 Division US4943680A (en) | 1986-10-28 | 1990-01-08 | Method of making a decorative sheet material simulating the appearance of a base coat/clear coat paint finish |
US08/734,339 Continuation USRE35894E (en) | 1986-10-28 | 1996-10-21 | Injection molded plastic article with integral weatherable pigmented film surface |
US08/754,302 Continuation USRE36457E (en) | 1986-10-28 | 1996-10-21 | Injection molded plastic article with integrated weatherable pigmented film surface |
US08/736,410 Continuation USRE35970E (en) | 1986-10-28 | 1996-10-24 | Injection molded plastic article with integral weatherable pigmented film surface |
Publications (1)
Publication Number | Publication Date |
---|---|
US4931324A true US4931324A (en) | 1990-06-05 |
Family
ID=26934644
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US07/241,856 Expired - Lifetime US4931324A (en) | 1986-10-28 | 1988-09-08 | Decorative sheet material simulating the appearance of a base coat/clear coat paint finish |
Country Status (1)
Country | Link |
---|---|
US (1) | US4931324A (en) |
Cited By (89)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5037680A (en) * | 1989-07-10 | 1991-08-06 | Decoma International Inc. | Exterior automotive component with pigmented substrate and clear coating |
US5079084A (en) * | 1986-07-14 | 1992-01-07 | Toyota Jidosha Kabushiki Kaisha | Reactive injection molding of a reinforced plastic product and method for manufacturing thereof |
US5132148A (en) * | 1987-11-03 | 1992-07-21 | Eastman Kodak Company | Flexible and stretchable sheet material useful in forming protective and decorative coatings |
US5192611A (en) * | 1989-03-03 | 1993-03-09 | Kansai Paint Co., Ltd. | Patterned film forming laminated sheet |
US5194336A (en) * | 1989-12-16 | 1993-03-16 | Sumitomo Electric Industries Ltd. | Chromatically colored fluororesin-coated material |
US5202180A (en) * | 1990-02-06 | 1993-04-13 | Avery Dennison Corporation | Decorative web |
US5215826A (en) * | 1990-09-25 | 1993-06-01 | Rexham Industries Corp. | Surfacing film with thermoformable carrier layer |
WO1994009983A1 (en) * | 1992-11-05 | 1994-05-11 | Avery Dennison Corporation | Exterior automotive laminate with pressure-sensitive adhesive |
US5342666A (en) * | 1986-10-28 | 1994-08-30 | Rexham Industries Corp. | Injection molded plastic article with integral weatherable pigmented film surface |
US5618593A (en) * | 1991-05-08 | 1997-04-08 | The Standard Products Company | Weatherstrip molding and method of making same |
US5653927A (en) * | 1995-06-07 | 1997-08-05 | Avery Dennison Corporation | Control of metallic appearance in automotive cast paint films |
US5707697A (en) * | 1987-03-27 | 1998-01-13 | Avery Dennison Corporation | Dry paint transfer product having high DOI automotive paint coat |
WO1998015592A1 (en) * | 1996-10-07 | 1998-04-16 | E.I. Du Pont De Nemours And Company | Controlled gloss fluoropolymer films |
USRE35894E (en) * | 1986-10-28 | 1998-09-08 | Rexam Industries Corp. | Injection molded plastic article with integral weatherable pigmented film surface |
US5870643A (en) * | 1995-12-28 | 1999-02-09 | Eastman Kodak Company | Single-use flash cameras with reflector or siren |
EP0900681A1 (en) * | 1997-09-04 | 1999-03-10 | Commercial Body Fittings Ltd | Improved door seal |
US5968657A (en) * | 1997-08-18 | 1999-10-19 | 3M Innovative Properties Company | Paint film assembly with masking film and method of making same |
USRE36457E (en) * | 1986-10-28 | 1999-12-21 | Rexam Industries, Corp. | Injection molded plastic article with integrated weatherable pigmented film surface |
US6017989A (en) * | 1997-04-01 | 2000-01-25 | The Standard Products Company | Exterior automotive component of an elastomeric modified polyolefin material having pleasing appearance |
US6060135A (en) * | 1996-10-07 | 2000-05-09 | E. I. Du Pont De Nemours And Company | Lustrous laminate film structures |
US6096396A (en) * | 1998-01-21 | 2000-08-01 | Rexam Industries Corp. | Decorative sheet material suitable for use as a flexible weatherable paint film or decal |
US6110547A (en) * | 1997-04-01 | 2000-08-29 | Grand Polymer Co., Ltd. | Method of molding automobile outer trim part, laminated film or sheet for use therein and automobile outer trim part |
US6113838A (en) * | 1995-06-07 | 2000-09-05 | Avery Dennison Corporation | Control of metallic appearance in automotive cast paint films |
EP1034089A1 (en) * | 1997-10-08 | 2000-09-13 | E.I. Du Pont De Nemours And Company | Lustrous laminate film structures |
US6187233B1 (en) | 1998-12-15 | 2001-02-13 | Guardian Automotive Trim, Inc. | Automotive trim with clear top coat and method of making same |
US6197405B1 (en) * | 1996-06-14 | 2001-03-06 | Graphic Origins Limited | Surface decoration having a 3-dimensional effect, and method of producing a surface decoration having a 3-dimensional effect, as well as utilization of a decoration having a 3-dimensional effect |
US6254712B1 (en) | 1998-12-08 | 2001-07-03 | Avery Dennison Corporation | Extrusion coating process for making high transparency protective and decorative films |
US6284183B1 (en) | 1998-06-08 | 2001-09-04 | Avery Dennison Corporation | Thick sheet laminating process for making exterior automotive body panels |
WO2001068337A2 (en) * | 2000-03-16 | 2001-09-20 | 3D Media Solutions Nordic | A surface decoration having a 3-dimensional effect and method for producing same |
US6296732B1 (en) | 1995-06-07 | 2001-10-02 | Avery Dennison Corporation | Extrusion process for protective coatings for outdoor siding panels and the like |
US6319438B1 (en) * | 1998-12-15 | 2001-11-20 | Guardian Automotive Trim, Inc. | Extruded automotive trim and method of making same |
US6336988B1 (en) | 1995-06-07 | 2002-01-08 | Avery Dennison Corporation | Extrusion coating process for making protective and decorative films |
US6348117B1 (en) | 1996-10-07 | 2002-02-19 | E. I. Du Pont De Nemours And Company | Process of preparing textured fluoropolymer films |
WO2002038385A2 (en) | 2000-10-30 | 2002-05-16 | E.I. Dupont De Nemours And Company | Process for making protected printed images |
US6399193B1 (en) | 1998-12-18 | 2002-06-04 | The University Of Massachusetts Lowell | Surfacing laminate with bonded with pigmented pressure sensitive adhesive |
WO2002058944A1 (en) * | 2001-01-22 | 2002-08-01 | Formica Corporation | Decorative laminate assembly and method of producing same |
US6440546B1 (en) | 1999-10-13 | 2002-08-27 | Ream Industries Corp. | Gloss-adjusting mask layer with particulate filler |
EP1236585A2 (en) | 2001-02-16 | 2002-09-04 | E. I. du Pont de Nemours and Company | Decorative surfaces for architectural panels |
US20020160680A1 (en) * | 2001-01-22 | 2002-10-31 | Laurence Kenneth John | Decorative laminate assembly and method of producing same |
CN1096354C (en) * | 1997-10-08 | 2002-12-18 | 纳幕尔杜邦公司 | Lustrous laminate film structures |
US6551432B1 (en) | 1987-03-27 | 2003-04-22 | Avery Dennison Corporation | Dry paint transfer process and product |
US6565955B2 (en) | 1999-03-12 | 2003-05-20 | Soliant Llc | Bright indium-metallized formable film laminate |
US6579397B1 (en) | 1987-03-27 | 2003-06-17 | Avery Dennison Corporation | Dry paint transfer process for making deep draw high DOI automotive body panels |
US20030170460A1 (en) * | 1999-10-13 | 2003-09-11 | John Sienkiewicz | Extruded automotive trim and method of making same |
US20030190434A1 (en) * | 2002-04-05 | 2003-10-09 | Byers Alicia D. | Process for applying automotive quality effect coatings to metal substrates |
US6632518B1 (en) | 1998-10-14 | 2003-10-14 | E. I. Du Pont De Nemours And Company | Fluoropolymer film structures and laminates produced therefrom |
US6723427B1 (en) * | 1999-06-21 | 2004-04-20 | Avery Dennison Corporation | Fade printed decorative sheets and methods and apparatus for making the same |
US20040140457A1 (en) * | 2003-01-06 | 2004-07-22 | Service Arnold Lewis Montgomery | Electrically conductive polymer films |
US20040175572A1 (en) * | 2001-08-16 | 2004-09-09 | Horst Hintze-Bruning | Color-and/or effect producing films, method for production and use thereof |
US20040209057A1 (en) * | 1995-06-07 | 2004-10-21 | Enlow Howard H. | Extruded polymeric high transparency films |
US20040241420A1 (en) * | 2003-05-30 | 2004-12-02 | Hongyi Zhou | Methods for manufacturing silver multilayered films and the articles obtained therefrom |
US20040247876A1 (en) * | 2003-01-27 | 2004-12-09 | Robert Lafave | Decorative system composite and method |
US6858287B2 (en) | 2001-08-10 | 2005-02-22 | Soliant Llc | Formable bright film having discontinuous metallic layers |
US20050074623A1 (en) * | 2003-10-07 | 2005-04-07 | Vogel Randall Allen | Multi-layer lonomer sheet having improved weathering |
US20050074622A1 (en) * | 2003-10-07 | 2005-04-07 | Vogel Randall Allen | Multi-layer sheet comprising an ionomer layer |
US20050084697A1 (en) * | 2003-10-07 | 2005-04-21 | Smillie Benjamin A. | Multi-layer sheet having a weatherable surface layer |
US20050106386A1 (en) * | 2003-10-07 | 2005-05-19 | Vogel Randall A. | Thermoformable multi-layer sheet |
US20050129882A1 (en) * | 2003-12-16 | 2005-06-16 | Snow Larry G. | Processes for preparing printable and printed articles |
US20050129883A1 (en) * | 2003-12-16 | 2005-06-16 | Snow Larry G. | Print receptive articles |
DE102004010787A1 (en) * | 2004-03-05 | 2005-09-22 | Basf Coatings Ag | Method for producing a multilayer film F and its use |
US20060057392A1 (en) * | 2003-10-07 | 2006-03-16 | Smillie Benjamin A | Multi-layer sheet having a weatherable surface layer |
US20060068213A1 (en) * | 2004-09-29 | 2006-03-30 | O'brien Kevin | Decorative laminate assembly with improved tie sheet and bridging agent |
US20060105663A1 (en) * | 2004-10-04 | 2006-05-18 | Stefan Greulich | Polymer assemblies with decorative surfaces |
US20060122860A1 (en) * | 2004-12-02 | 2006-06-08 | Lafave Robert J | Method of producing a paint film part |
US20060286559A1 (en) * | 2005-06-15 | 2006-12-21 | Kraft Foods Holdings, Inc. | Nucleic acids for detection of Listeria |
US20070154704A1 (en) * | 2005-12-30 | 2007-07-05 | Debergalis Michael | Fluoropolymer coated films useful for photovoltaic modules |
US20070166469A1 (en) * | 2005-12-30 | 2007-07-19 | Snow Larry G | Fluoropolymer coating compositions containing adhesive polymers and substrate coating process |
US20080154004A1 (en) * | 2006-12-21 | 2008-06-26 | Ronald Earl Uschold | Crosslinkable Vinyl Fluoride Copolymers |
US20080213600A1 (en) * | 2005-05-03 | 2008-09-04 | Basf Coatings Aktiengesellschaft | Process for Producing Sheets (F) Bearing a Coating (B), the Resultant Sheets (F), and Their Use for Producing Moldings, Especially for Use in the Autombile Construction |
US20080261037A1 (en) * | 2007-04-23 | 2008-10-23 | E. I. Du Pont De Nemours And Company | Fluoropolymer Coated Film, Process for Forming the Same, and Fluoropolymer Liquid Composition |
CN100450739C (en) * | 2005-03-11 | 2009-01-14 | Lg化学株式会社 | Pvc-rubber flooring using rubber sol and method for producing the same |
US20090274922A1 (en) * | 2006-01-06 | 2009-11-05 | Roys John E | High Gloss Laminates for Decorative Automotive Parts |
WO2011018285A1 (en) | 2009-08-11 | 2011-02-17 | Evonik Degussa Gmbh | Aqueous silane systems for bare corrosion protection and corrosion protection of metals |
US8119235B1 (en) | 2000-04-14 | 2012-02-21 | E. I. Du Pont De Nemours And Company | Multilayer, co-extruded, ionomeric decorative surfacing |
ITVR20110120A1 (en) * | 2011-05-27 | 2012-11-28 | Giuseppe Billoni | TRANSFERABLE ARTICLE AND RELATIVE PRODUCTION METHOD. |
WO2013006616A1 (en) | 2011-07-06 | 2013-01-10 | Dow Global Technologies Llc | Optoelectronic devices incorporating fluoropolymer compositions for protection |
US20140065406A1 (en) * | 2011-05-04 | 2014-03-06 | Kth Holding Ab | Oxygen barrier for packaging applications |
US8927106B2 (en) | 2005-04-29 | 2015-01-06 | 3M Innovative Properties Company | Multilayer polyurethane protective films |
WO2015017616A1 (en) | 2013-08-02 | 2015-02-05 | E. I. Du Pont De Nemours And Company | Liquid fluoropolymer coating composition, fluoropolymer coated film, and process for forming the same |
WO2015073364A2 (en) | 2013-11-12 | 2015-05-21 | E. I. Du Pont De Nemours And Company | Pigment dispersion |
WO2015160568A1 (en) | 2014-04-17 | 2015-10-22 | E. I. Du Pont De Nemours And Company | Liquid fluoropolymer coating composition and fluoropolymer coated film |
WO2015160570A1 (en) | 2014-04-17 | 2015-10-22 | E. I. Du Pont De Nemours And Company | Transparent fluoropolymer coated films, building structures comprising these films and liquid fluoropolymer coating compositions |
WO2016097825A1 (en) * | 2014-12-18 | 2016-06-23 | Ferro Emiliano | Coating of parts or objects and method for obtaining it |
EP3178796A1 (en) * | 2010-04-30 | 2017-06-14 | Corning Incorporated | Glass article comprising anti-glare surface |
US9707746B2 (en) | 2008-01-19 | 2017-07-18 | Entrotech, Inc. | Protected graphics and related methods |
ITUA20163178A1 (en) * | 2016-05-05 | 2017-11-05 | I Dek S R L | FLEXIBLE DECORATIVE SHEET TO COVER A SUBSTRATE, RELATED TO USE AND PRODUCTION PROCESS. |
US10035932B2 (en) | 2007-09-25 | 2018-07-31 | Aero Advanced Paint Technology, Inc. | Paint replacement films, composites therefrom, and related methods |
US10265932B2 (en) | 2005-10-21 | 2019-04-23 | Entrotech, Inc. | Protective sheets, articles, and methods |
US11827823B2 (en) | 2016-09-20 | 2023-11-28 | Ppg Advanced Surface Technologies, Llc | Paint film appliques with reduced defects, articles, and methods |
Citations (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2880542A (en) * | 1957-05-29 | 1959-04-07 | Abraham S Butterweich | Decorative sheeting with multi-color sparkle effect |
US3524906A (en) * | 1967-10-10 | 1970-08-18 | American Cyanamid Co | Transparent and weatherable polymer blends of acrylate polymers and polyvinylidene fluoride |
US3549405A (en) * | 1965-03-29 | 1970-12-22 | Dow Chemical Co | Iridescent resinous film bodies and a substrate coated therewith |
US3697070A (en) * | 1970-06-19 | 1972-10-10 | Mobil Oil Corp | Metallizing coating compositions |
US3806397A (en) * | 1972-06-08 | 1974-04-23 | Kukoff J | Decorative articles |
US3988494A (en) * | 1972-04-10 | 1976-10-26 | Mobil Oil Corporation | Metallizing coating compositions |
US4126727A (en) * | 1976-06-16 | 1978-11-21 | Congoleum Corporation | Resinous polymer sheet materials having selective, decorative effects |
US4215170A (en) * | 1978-02-28 | 1980-07-29 | Eurographics Holding, N. V. | Metallization process |
US4248917A (en) * | 1977-07-18 | 1981-02-03 | Stauffer Chemical Company | Pressure sensitive products with decorative appearance |
US4307149A (en) * | 1979-11-05 | 1981-12-22 | Columbia Ribbon & Carbon Mfg. Co., Inc. | Transfer elements and process for making same |
US4311757A (en) * | 1979-06-06 | 1982-01-19 | Formica Corporation | Decorative metallic laminates |
GB2084513A (en) * | 1980-10-03 | 1982-04-15 | Nissan Motor | Sheet for ornamentation |
US4359491A (en) * | 1980-12-31 | 1982-11-16 | Jin An Industrial Co., Ltd. | Process for the preparation of a thermal transferable twinkling pattern |
US4409280A (en) * | 1981-09-21 | 1983-10-11 | Mannington Mills | Decorative surface coverings |
US4501852A (en) * | 1983-06-20 | 1985-02-26 | Mobay Chemical Corporation | Stable, aqueous dispersions of polyurethane-ureas |
US4533592A (en) * | 1984-08-02 | 1985-08-06 | Minnesota Mining And Manufacturing Company | Thermally stable flame retardant reflective and retroreflective trim |
US4578426A (en) * | 1983-06-24 | 1986-03-25 | Basf Aktiengesellschaft | Production of coatings |
US4584231A (en) * | 1983-12-02 | 1986-04-22 | Vcf Packaging Films, Inc. | Solvent cast acrylic film |
US4664859A (en) * | 1983-12-02 | 1987-05-12 | Vcf Films Inc. Div. Of Pmc | Process for solvent casting a film |
US4678690A (en) * | 1986-01-10 | 1987-07-07 | Rexham Corporation | Premasked decal |
US4769265A (en) * | 1983-01-10 | 1988-09-06 | Coburn Jr Joseph W | Laminated decorative film and methods of making same |
US4810540A (en) * | 1986-10-28 | 1989-03-07 | Rexham Corporation | Decorative sheet material simulating the appearance of a base coat/clear coat paint finish |
-
1988
- 1988-09-08 US US07/241,856 patent/US4931324A/en not_active Expired - Lifetime
Patent Citations (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2880542A (en) * | 1957-05-29 | 1959-04-07 | Abraham S Butterweich | Decorative sheeting with multi-color sparkle effect |
US3549405A (en) * | 1965-03-29 | 1970-12-22 | Dow Chemical Co | Iridescent resinous film bodies and a substrate coated therewith |
US3524906A (en) * | 1967-10-10 | 1970-08-18 | American Cyanamid Co | Transparent and weatherable polymer blends of acrylate polymers and polyvinylidene fluoride |
US3697070A (en) * | 1970-06-19 | 1972-10-10 | Mobil Oil Corp | Metallizing coating compositions |
US3988494A (en) * | 1972-04-10 | 1976-10-26 | Mobil Oil Corporation | Metallizing coating compositions |
US3806397A (en) * | 1972-06-08 | 1974-04-23 | Kukoff J | Decorative articles |
US4126727A (en) * | 1976-06-16 | 1978-11-21 | Congoleum Corporation | Resinous polymer sheet materials having selective, decorative effects |
US4248917A (en) * | 1977-07-18 | 1981-02-03 | Stauffer Chemical Company | Pressure sensitive products with decorative appearance |
US4215170A (en) * | 1978-02-28 | 1980-07-29 | Eurographics Holding, N. V. | Metallization process |
US4311757A (en) * | 1979-06-06 | 1982-01-19 | Formica Corporation | Decorative metallic laminates |
US4307149A (en) * | 1979-11-05 | 1981-12-22 | Columbia Ribbon & Carbon Mfg. Co., Inc. | Transfer elements and process for making same |
GB2084513A (en) * | 1980-10-03 | 1982-04-15 | Nissan Motor | Sheet for ornamentation |
US4359491A (en) * | 1980-12-31 | 1982-11-16 | Jin An Industrial Co., Ltd. | Process for the preparation of a thermal transferable twinkling pattern |
US4409280A (en) * | 1981-09-21 | 1983-10-11 | Mannington Mills | Decorative surface coverings |
US4769265A (en) * | 1983-01-10 | 1988-09-06 | Coburn Jr Joseph W | Laminated decorative film and methods of making same |
US4501852A (en) * | 1983-06-20 | 1985-02-26 | Mobay Chemical Corporation | Stable, aqueous dispersions of polyurethane-ureas |
US4578426A (en) * | 1983-06-24 | 1986-03-25 | Basf Aktiengesellschaft | Production of coatings |
US4584231A (en) * | 1983-12-02 | 1986-04-22 | Vcf Packaging Films, Inc. | Solvent cast acrylic film |
US4664859A (en) * | 1983-12-02 | 1987-05-12 | Vcf Films Inc. Div. Of Pmc | Process for solvent casting a film |
US4533592A (en) * | 1984-08-02 | 1985-08-06 | Minnesota Mining And Manufacturing Company | Thermally stable flame retardant reflective and retroreflective trim |
US4678690A (en) * | 1986-01-10 | 1987-07-07 | Rexham Corporation | Premasked decal |
US4810540A (en) * | 1986-10-28 | 1989-03-07 | Rexham Corporation | Decorative sheet material simulating the appearance of a base coat/clear coat paint finish |
Non-Patent Citations (2)
Title |
---|
Chemical Week, Jul. 4, 1984, p. 30, Automotive Coatings: Helping Detroit Woo Consumers. * |
Polymers Paint Colour Journal, Oct. 29, 1980, pp. 796 and 798, The Orientation of Aluminum Pigments in Automotive Finishes, Contributed by Toyo Aluminum K. K. * |
Cited By (164)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5079084A (en) * | 1986-07-14 | 1992-01-07 | Toyota Jidosha Kabushiki Kaisha | Reactive injection molding of a reinforced plastic product and method for manufacturing thereof |
US5514427A (en) * | 1986-10-28 | 1996-05-07 | Rexam Industries Corp. | Injection molded plastic article with integral weatherable pigmented film surface |
US6180195B1 (en) | 1986-10-28 | 2001-01-30 | Rexam Industries Corp. | Automobile body formed of interconnected molded plastic articles |
USRE36457E (en) * | 1986-10-28 | 1999-12-21 | Rexam Industries, Corp. | Injection molded plastic article with integrated weatherable pigmented film surface |
US5960527A (en) * | 1986-10-28 | 1999-10-05 | Rexam Industries Corp. | Method of injection molding plastic automobile body parts with integral weatherable pigmented film surface |
USRE35970E (en) * | 1986-10-28 | 1998-11-24 | Rexam Industries Corp. | Injection molded plastic article with integral weatherable pigmented film surface |
USRE35894E (en) * | 1986-10-28 | 1998-09-08 | Rexam Industries Corp. | Injection molded plastic article with integral weatherable pigmented film surface |
US5536539A (en) * | 1986-10-28 | 1996-07-16 | Rexam Industries Corp. | Injection molded plastic article with integral weatherable pigmented film surface |
US5342666A (en) * | 1986-10-28 | 1994-08-30 | Rexham Industries Corp. | Injection molded plastic article with integral weatherable pigmented film surface |
US20040123942A1 (en) * | 1987-03-27 | 2004-07-01 | Spain Patrick L. | Dry paint transfer process for making deep-draw high doi automotive body panels |
US6835267B1 (en) * | 1987-03-27 | 2004-12-28 | Avery Dennison Corporation | Dry paint transfer process and product |
US6551432B1 (en) | 1987-03-27 | 2003-04-22 | Avery Dennison Corporation | Dry paint transfer process and product |
US6579397B1 (en) | 1987-03-27 | 2003-06-17 | Avery Dennison Corporation | Dry paint transfer process for making deep draw high DOI automotive body panels |
US5707697A (en) * | 1987-03-27 | 1998-01-13 | Avery Dennison Corporation | Dry paint transfer product having high DOI automotive paint coat |
US6966962B2 (en) | 1987-03-27 | 2005-11-22 | Avery Dennison Corporation | Dry paint transfer-lamination process for making high DOI automotive body panels |
US6649003B1 (en) | 1987-03-27 | 2003-11-18 | Avery Dennison Corporation | Dry paint transfer lamination process for making high DOI automotive body panels |
US20040123941A1 (en) * | 1987-03-27 | 2004-07-01 | Spain Patrick L. | Dry paint transfer-lamination process for making high doi automotive body panels |
US6984280B2 (en) | 1987-03-27 | 2006-01-10 | Avery Dennison Coporation | Dry paint transfer process for making deep-draw high doi automotive body panels |
US6838130B1 (en) * | 1987-03-27 | 2005-01-04 | Avery Dennison Corporation | Dry paint transfer process and product |
US5916643A (en) * | 1987-03-27 | 1999-06-29 | Avery Dennison Corporation | Dry paint transfer-laminated body panels having deep-draw high DOI automotive paint coat |
US5132148A (en) * | 1987-11-03 | 1992-07-21 | Eastman Kodak Company | Flexible and stretchable sheet material useful in forming protective and decorative coatings |
US5192611A (en) * | 1989-03-03 | 1993-03-09 | Kansai Paint Co., Ltd. | Patterned film forming laminated sheet |
US5037680A (en) * | 1989-07-10 | 1991-08-06 | Decoma International Inc. | Exterior automotive component with pigmented substrate and clear coating |
US5194336A (en) * | 1989-12-16 | 1993-03-16 | Sumitomo Electric Industries Ltd. | Chromatically colored fluororesin-coated material |
US5202180A (en) * | 1990-02-06 | 1993-04-13 | Avery Dennison Corporation | Decorative web |
US5215826A (en) * | 1990-09-25 | 1993-06-01 | Rexham Industries Corp. | Surfacing film with thermoformable carrier layer |
US5618593A (en) * | 1991-05-08 | 1997-04-08 | The Standard Products Company | Weatherstrip molding and method of making same |
WO1994009983A1 (en) * | 1992-11-05 | 1994-05-11 | Avery Dennison Corporation | Exterior automotive laminate with pressure-sensitive adhesive |
US5518786A (en) * | 1992-11-05 | 1996-05-21 | Avery Dennison Corporation | Exterior automotive laminate with pressure sensitive adhesive |
US20040209057A1 (en) * | 1995-06-07 | 2004-10-21 | Enlow Howard H. | Extruded polymeric high transparency films |
US6113838A (en) * | 1995-06-07 | 2000-09-05 | Avery Dennison Corporation | Control of metallic appearance in automotive cast paint films |
US6733870B2 (en) | 1995-06-07 | 2004-05-11 | Avery Dennison Corporation | Extrusion coating process for making protective and decorative films |
US5653927A (en) * | 1995-06-07 | 1997-08-05 | Avery Dennison Corporation | Control of metallic appearance in automotive cast paint films |
US6296732B1 (en) | 1995-06-07 | 2001-10-02 | Avery Dennison Corporation | Extrusion process for protective coatings for outdoor siding panels and the like |
US6547912B2 (en) | 1995-06-07 | 2003-04-15 | Avery Dennison Corporation | Extrusion coating process for making high transparency protective and decorative films |
US6336988B1 (en) | 1995-06-07 | 2002-01-08 | Avery Dennison Corporation | Extrusion coating process for making protective and decorative films |
US5870643A (en) * | 1995-12-28 | 1999-02-09 | Eastman Kodak Company | Single-use flash cameras with reflector or siren |
US6197405B1 (en) * | 1996-06-14 | 2001-03-06 | Graphic Origins Limited | Surface decoration having a 3-dimensional effect, and method of producing a surface decoration having a 3-dimensional effect, as well as utilization of a decoration having a 3-dimensional effect |
US5972472A (en) * | 1996-10-07 | 1999-10-26 | E. I. Du Pont De Nemours And Company | Process of forming controlled gloss fluoropolymer films |
US6060135A (en) * | 1996-10-07 | 2000-05-09 | E. I. Du Pont De Nemours And Company | Lustrous laminate film structures |
WO1998015592A1 (en) * | 1996-10-07 | 1998-04-16 | E.I. Du Pont De Nemours And Company | Controlled gloss fluoropolymer films |
US6348117B1 (en) | 1996-10-07 | 2002-02-19 | E. I. Du Pont De Nemours And Company | Process of preparing textured fluoropolymer films |
US6110547A (en) * | 1997-04-01 | 2000-08-29 | Grand Polymer Co., Ltd. | Method of molding automobile outer trim part, laminated film or sheet for use therein and automobile outer trim part |
US6017989A (en) * | 1997-04-01 | 2000-01-25 | The Standard Products Company | Exterior automotive component of an elastomeric modified polyolefin material having pleasing appearance |
US6773804B2 (en) | 1997-08-06 | 2004-08-10 | Avery Dennison Corporation | Extruded polymeric high transparency films |
US5968657A (en) * | 1997-08-18 | 1999-10-19 | 3M Innovative Properties Company | Paint film assembly with masking film and method of making same |
US6083335A (en) * | 1997-08-18 | 2000-07-04 | 3M Innovative Properties Company | Paint film assembly with masking film and method of making same |
EP0900681A1 (en) * | 1997-09-04 | 1999-03-10 | Commercial Body Fittings Ltd | Improved door seal |
EP1034089A4 (en) * | 1997-10-08 | 2000-10-18 | Du Pont | Lustrous laminate film structures |
CN1096354C (en) * | 1997-10-08 | 2002-12-18 | 纳幕尔杜邦公司 | Lustrous laminate film structures |
EP1034089A1 (en) * | 1997-10-08 | 2000-09-13 | E.I. Du Pont De Nemours And Company | Lustrous laminate film structures |
US6096396A (en) * | 1998-01-21 | 2000-08-01 | Rexam Industries Corp. | Decorative sheet material suitable for use as a flexible weatherable paint film or decal |
US6709723B2 (en) * | 1998-06-08 | 2004-03-23 | Avery Dennison Corporation | Thick sheet lamination product for use in exterior automotive body panels |
US6284183B1 (en) | 1998-06-08 | 2001-09-04 | Avery Dennison Corporation | Thick sheet laminating process for making exterior automotive body panels |
US6632518B1 (en) | 1998-10-14 | 2003-10-14 | E. I. Du Pont De Nemours And Company | Fluoropolymer film structures and laminates produced therefrom |
US7070675B2 (en) | 1998-10-14 | 2006-07-04 | E. I. Du Pont De Nemours And Company | Fluoropolymer film structures and laminates produced therefrom |
US6254712B1 (en) | 1998-12-08 | 2001-07-03 | Avery Dennison Corporation | Extrusion coating process for making high transparency protective and decorative films |
US7005103B2 (en) | 1998-12-15 | 2006-02-28 | Guardian Automotive Trim, Inc. | Method of making a colored automotive trim product |
US6319438B1 (en) * | 1998-12-15 | 2001-11-20 | Guardian Automotive Trim, Inc. | Extruded automotive trim and method of making same |
US6602591B1 (en) | 1998-12-15 | 2003-08-05 | Guardian Automotive Trim, Inc. | Automotive trim with clear top coat and method of making same |
US6187233B1 (en) | 1998-12-15 | 2001-02-13 | Guardian Automotive Trim, Inc. | Automotive trim with clear top coat and method of making same |
US6399193B1 (en) | 1998-12-18 | 2002-06-04 | The University Of Massachusetts Lowell | Surfacing laminate with bonded with pigmented pressure sensitive adhesive |
US6565955B2 (en) | 1999-03-12 | 2003-05-20 | Soliant Llc | Bright indium-metallized formable film laminate |
US6723427B1 (en) * | 1999-06-21 | 2004-04-20 | Avery Dennison Corporation | Fade printed decorative sheets and methods and apparatus for making the same |
US20030170460A1 (en) * | 1999-10-13 | 2003-09-11 | John Sienkiewicz | Extruded automotive trim and method of making same |
US7195727B2 (en) | 1999-10-13 | 2007-03-27 | Guardian Industries Corp. | Extruded automotive trim and method of making same |
US6440546B1 (en) | 1999-10-13 | 2002-08-27 | Ream Industries Corp. | Gloss-adjusting mask layer with particulate filler |
WO2001068337A2 (en) * | 2000-03-16 | 2001-09-20 | 3D Media Solutions Nordic | A surface decoration having a 3-dimensional effect and method for producing same |
US20030039809A1 (en) * | 2000-03-16 | 2003-02-27 | Harald Johnsen | Surface decoration having a 3-dimesional effect and method for producing same |
WO2001068337A3 (en) * | 2000-03-16 | 2002-01-17 | 3D Media Solutions Nordic | A surface decoration having a 3-dimensional effect and method for producing same |
US8679619B2 (en) | 2000-04-14 | 2014-03-25 | E I Du Pont De Nemours And Company | Multilayer, co-extruded, ionomeric decorative surfacing |
US8119235B1 (en) | 2000-04-14 | 2012-02-21 | E. I. Du Pont De Nemours And Company | Multilayer, co-extruded, ionomeric decorative surfacing |
WO2002038385A2 (en) | 2000-10-30 | 2002-05-16 | E.I. Dupont De Nemours And Company | Process for making protected printed images |
US6626530B2 (en) | 2000-10-30 | 2003-09-30 | E. I. Du Pont De Nemours And Company | Process for making protected printed images |
US7081300B2 (en) | 2001-01-22 | 2006-07-25 | Formica Corporation | Decorative laminate assembly and method of producing same |
US20020160680A1 (en) * | 2001-01-22 | 2002-10-31 | Laurence Kenneth John | Decorative laminate assembly and method of producing same |
US6803110B2 (en) | 2001-01-22 | 2004-10-12 | Formica Corporation | Decorative laminate assembly and method for producing same |
WO2002058944A1 (en) * | 2001-01-22 | 2002-08-01 | Formica Corporation | Decorative laminate assembly and method of producing same |
US20050142330A1 (en) * | 2001-02-16 | 2005-06-30 | Albert Richard C. | Decorative surfaces for architectural panels |
EP1236585A2 (en) | 2001-02-16 | 2002-09-04 | E. I. du Pont de Nemours and Company | Decorative surfaces for architectural panels |
US6858287B2 (en) | 2001-08-10 | 2005-02-22 | Soliant Llc | Formable bright film having discontinuous metallic layers |
US20070104898A1 (en) * | 2001-08-16 | 2007-05-10 | Horst Hintze-Bruning | Color and/or effect films, their preparation and use |
US7682666B2 (en) | 2001-08-16 | 2010-03-23 | Basf Coatings Ag | Method of producing a color and/or effect film exhibiting an isotropic flop behavior and an isotropic color locus |
US20040175572A1 (en) * | 2001-08-16 | 2004-09-09 | Horst Hintze-Bruning | Color-and/or effect producing films, method for production and use thereof |
US20030190434A1 (en) * | 2002-04-05 | 2003-10-09 | Byers Alicia D. | Process for applying automotive quality effect coatings to metal substrates |
US20070138443A1 (en) * | 2003-01-06 | 2007-06-21 | Service Arnold L M | Electrically conductive polymer films and process for making same |
US7192536B2 (en) | 2003-01-06 | 2007-03-20 | E. I. Du Pont De Nemours And Company | Electrically conductive polymer films and process for making same |
US20040140457A1 (en) * | 2003-01-06 | 2004-07-22 | Service Arnold Lewis Montgomery | Electrically conductive polymer films |
US6932921B2 (en) | 2003-01-06 | 2005-08-23 | E. I. Du Pont De Nemours And Company | Electrically conductive polymer films |
US7833380B2 (en) | 2003-01-27 | 2010-11-16 | Laminate Products, Inc. | Decorative system composite and method |
US7144612B2 (en) | 2003-01-27 | 2006-12-05 | Laminate Products, Inc. | Decorative system composite and method |
US7399506B2 (en) | 2003-01-27 | 2008-07-15 | Laminate Products, Inc. | Decorative system composite and method |
US20080110564A1 (en) * | 2003-01-27 | 2008-05-15 | Robert Lafave | Decorative System Composite and Method |
US20040247876A1 (en) * | 2003-01-27 | 2004-12-09 | Robert Lafave | Decorative system composite and method |
US20060257592A1 (en) * | 2003-01-27 | 2006-11-16 | Robert Lafave | Decorative system composite and method |
WO2004108411A1 (en) * | 2003-05-30 | 2004-12-16 | General Electric Company | Methods for manufacturing silver multilayered films and the articles obtained therefrom |
US6916528B2 (en) | 2003-05-30 | 2005-07-12 | General Electric Company | Methods for manufacturing silver multilayered films and the articles obtained therefrom |
US20040241420A1 (en) * | 2003-05-30 | 2004-12-02 | Hongyi Zhou | Methods for manufacturing silver multilayered films and the articles obtained therefrom |
US20050084697A1 (en) * | 2003-10-07 | 2005-04-21 | Smillie Benjamin A. | Multi-layer sheet having a weatherable surface layer |
US20080026228A1 (en) * | 2003-10-07 | 2008-01-31 | E. I. Du Pont De Nemours And Company | Multi-Layer Sheet Having a Weatherable Surface Layer |
US7488399B2 (en) | 2003-10-07 | 2009-02-10 | E. I. Du Pont De Nemours And Company | Multi-layer sheet having a weatherable surface layer |
US20050106386A1 (en) * | 2003-10-07 | 2005-05-19 | Vogel Randall A. | Thermoformable multi-layer sheet |
US20050074623A1 (en) * | 2003-10-07 | 2005-04-07 | Vogel Randall Allen | Multi-layer lonomer sheet having improved weathering |
US20050074622A1 (en) * | 2003-10-07 | 2005-04-07 | Vogel Randall Allen | Multi-layer sheet comprising an ionomer layer |
US20060057392A1 (en) * | 2003-10-07 | 2006-03-16 | Smillie Benjamin A | Multi-layer sheet having a weatherable surface layer |
US7303793B2 (en) | 2003-10-07 | 2007-12-04 | E. I. Du Pont De Nemours And Company | Multi-layer sheet having a weatherable surface layer |
US20050129883A1 (en) * | 2003-12-16 | 2005-06-16 | Snow Larry G. | Print receptive articles |
US20090047449A1 (en) * | 2003-12-16 | 2009-02-19 | E.I. Du Pont De Nemours And Company | Processes for Preparing Printable and Printed Articles |
US7608311B2 (en) | 2003-12-16 | 2009-10-27 | E. I. Du Pont De Nemours And Company | Print receptive articles |
US20050129882A1 (en) * | 2003-12-16 | 2005-06-16 | Snow Larry G. | Processes for preparing printable and printed articles |
DE102004010787A1 (en) * | 2004-03-05 | 2005-09-22 | Basf Coatings Ag | Method for producing a multilayer film F and its use |
US20060068213A1 (en) * | 2004-09-29 | 2006-03-30 | O'brien Kevin | Decorative laminate assembly with improved tie sheet and bridging agent |
US20060105663A1 (en) * | 2004-10-04 | 2006-05-18 | Stefan Greulich | Polymer assemblies with decorative surfaces |
US20060122860A1 (en) * | 2004-12-02 | 2006-06-08 | Lafave Robert J | Method of producing a paint film part |
US7853454B2 (en) | 2004-12-02 | 2010-12-14 | Laminate Products, Inc. | Method of producing a paint film part |
CN100450739C (en) * | 2005-03-11 | 2009-01-14 | Lg化学株式会社 | Pvc-rubber flooring using rubber sol and method for producing the same |
US8927106B2 (en) | 2005-04-29 | 2015-01-06 | 3M Innovative Properties Company | Multilayer polyurethane protective films |
US10213992B2 (en) | 2005-04-29 | 2019-02-26 | 3M Innovative Properties Company | Multilayer polyurethane protective films |
US20080213600A1 (en) * | 2005-05-03 | 2008-09-04 | Basf Coatings Aktiengesellschaft | Process for Producing Sheets (F) Bearing a Coating (B), the Resultant Sheets (F), and Their Use for Producing Moldings, Especially for Use in the Autombile Construction |
US7968199B2 (en) | 2005-05-03 | 2011-06-28 | Basf Coatings Ag | Method for producing films having a coating the films obtained in this way and their use for producing molded parts in particular for use in automobile construction |
US20060286559A1 (en) * | 2005-06-15 | 2006-12-21 | Kraft Foods Holdings, Inc. | Nucleic acids for detection of Listeria |
US10265932B2 (en) | 2005-10-21 | 2019-04-23 | Entrotech, Inc. | Protective sheets, articles, and methods |
US20070166469A1 (en) * | 2005-12-30 | 2007-07-19 | Snow Larry G | Fluoropolymer coating compositions containing adhesive polymers and substrate coating process |
US20090293944A1 (en) * | 2005-12-30 | 2009-12-03 | E. I. Du Pont De Nemours And Company | Fluoropolymer Coated Films Useful for Photovoltaic Modules |
US20090260677A1 (en) * | 2005-12-30 | 2009-10-22 | E. I. Du Pont De Nemours And Company | Fluoropolymer Coated Films Useful for Photovoltaic Modules |
US7553540B2 (en) | 2005-12-30 | 2009-06-30 | E. I. Du Pont De Nemours And Company | Fluoropolymer coated films useful for photovoltaic modules |
EP2468833A1 (en) | 2005-12-30 | 2012-06-27 | E. I. du Pont de Nemours and Company | Fluoropolymer coating compositions containing adhesive polymers and substrate coating process |
US8197933B2 (en) | 2005-12-30 | 2012-06-12 | E.I. Du Pont De Nemours And Company | Fluoropolymer coated films useful for photovoltaic module |
US8062744B2 (en) | 2005-12-30 | 2011-11-22 | E. I. Du Pont De Nemours And Company | Fluoropolymer coated films useful for photovoltaic modules |
US20100247789A1 (en) * | 2005-12-30 | 2010-09-30 | E. I. Du Pont De Nemours And Company | Fluoropolymer coating compositions containing adhesive polymers and substrate coating process |
US8048518B2 (en) | 2005-12-30 | 2011-11-01 | E.I. Du Pont De Nemours And Company | Fluoropolymer coated films useful for photovoltaic modules |
US7981478B2 (en) | 2005-12-30 | 2011-07-19 | E. I. Du Pont De Nemours And Company | Fluoropolymer coating compositions containing adhesive polymers and substrate coating process |
US20070154704A1 (en) * | 2005-12-30 | 2007-07-05 | Debergalis Michael | Fluoropolymer coated films useful for photovoltaic modules |
US20090274922A1 (en) * | 2006-01-06 | 2009-11-05 | Roys John E | High Gloss Laminates for Decorative Automotive Parts |
US7842765B2 (en) | 2006-12-21 | 2010-11-30 | E. I. Du Pont De Nemours And Company | Crosslinkable vinyl fluoride copolymers |
US20080156367A1 (en) * | 2006-12-21 | 2008-07-03 | Ronald Earl Uschold | Crosslinkable Vinyl Fluoride Copolymer Coated Film and Process for Making Same |
US8124221B2 (en) | 2006-12-21 | 2012-02-28 | E. I. Du Pont De Nemours And Company | Crosslinkable vinyl fluoride copolymer coated film and process for making same |
US20080154004A1 (en) * | 2006-12-21 | 2008-06-26 | Ronald Earl Uschold | Crosslinkable Vinyl Fluoride Copolymers |
US20110086954A1 (en) * | 2007-04-23 | 2011-04-14 | E. I. Du Pont De Nemours And Company | Fluoropolymer liquid composition |
EP2468829A1 (en) | 2007-04-23 | 2012-06-27 | E. I. du Pont de Nemours and Company | Fluoropolymer coated film |
US8025928B2 (en) | 2007-04-23 | 2011-09-27 | E. I. Du Pont De Nemours And Company | Process for forming fluoropolymer coated film |
US20110086172A1 (en) * | 2007-04-23 | 2011-04-14 | E. I. Du Pont De Nemours And Company | Process for forming fluoropolymer coated film |
US20080261037A1 (en) * | 2007-04-23 | 2008-10-23 | E. I. Du Pont De Nemours And Company | Fluoropolymer Coated Film, Process for Forming the Same, and Fluoropolymer Liquid Composition |
US8168297B2 (en) | 2007-04-23 | 2012-05-01 | E. I. Du Pont De Nemours And Company | Fluoropolymer coated film, process for forming the same, and fluoropolymer liquid composition |
US11420427B2 (en) | 2007-09-25 | 2022-08-23 | Entrotech, Inc. | Paint replacement film, composites therefrom, and related methods |
US10035932B2 (en) | 2007-09-25 | 2018-07-31 | Aero Advanced Paint Technology, Inc. | Paint replacement films, composites therefrom, and related methods |
US9707746B2 (en) | 2008-01-19 | 2017-07-18 | Entrotech, Inc. | Protected graphics and related methods |
US11577501B2 (en) | 2008-01-19 | 2023-02-14 | Entrotech, Inc. | Protected graphics and related methods |
US10981371B2 (en) | 2008-01-19 | 2021-04-20 | Entrotech, Inc. | Protected graphics and related methods |
WO2011018285A1 (en) | 2009-08-11 | 2011-02-17 | Evonik Degussa Gmbh | Aqueous silane systems for bare corrosion protection and corrosion protection of metals |
EP3178796A1 (en) * | 2010-04-30 | 2017-06-14 | Corning Incorporated | Glass article comprising anti-glare surface |
US20140065406A1 (en) * | 2011-05-04 | 2014-03-06 | Kth Holding Ab | Oxygen barrier for packaging applications |
ITVR20110120A1 (en) * | 2011-05-27 | 2012-11-28 | Giuseppe Billoni | TRANSFERABLE ARTICLE AND RELATIVE PRODUCTION METHOD. |
US9219182B2 (en) | 2011-07-06 | 2015-12-22 | Dow Global Technologies Llc | Optoelectronic devices incorporating fluoropolymer compositions for protection |
WO2013006616A1 (en) | 2011-07-06 | 2013-01-10 | Dow Global Technologies Llc | Optoelectronic devices incorporating fluoropolymer compositions for protection |
WO2015017616A1 (en) | 2013-08-02 | 2015-02-05 | E. I. Du Pont De Nemours And Company | Liquid fluoropolymer coating composition, fluoropolymer coated film, and process for forming the same |
WO2015073364A2 (en) | 2013-11-12 | 2015-05-21 | E. I. Du Pont De Nemours And Company | Pigment dispersion |
US9637657B2 (en) | 2014-04-17 | 2017-05-02 | E I Du Pont De Nemours And Company | Liquid fluoropolymer coating composition and fluoropolymer coated film |
WO2015160570A1 (en) | 2014-04-17 | 2015-10-22 | E. I. Du Pont De Nemours And Company | Transparent fluoropolymer coated films, building structures comprising these films and liquid fluoropolymer coating compositions |
WO2015160568A1 (en) | 2014-04-17 | 2015-10-22 | E. I. Du Pont De Nemours And Company | Liquid fluoropolymer coating composition and fluoropolymer coated film |
WO2016097825A1 (en) * | 2014-12-18 | 2016-06-23 | Ferro Emiliano | Coating of parts or objects and method for obtaining it |
ITUA20163178A1 (en) * | 2016-05-05 | 2017-11-05 | I Dek S R L | FLEXIBLE DECORATIVE SHEET TO COVER A SUBSTRATE, RELATED TO USE AND PRODUCTION PROCESS. |
US11827823B2 (en) | 2016-09-20 | 2023-11-28 | Ppg Advanced Surface Technologies, Llc | Paint film appliques with reduced defects, articles, and methods |
US11884849B2 (en) | 2016-09-20 | 2024-01-30 | Ppg Advanced Surface Technologies, Llc | Paint film appliques with reduced defects, articles, and methods |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4931324A (en) | Decorative sheet material simulating the appearance of a base coat/clear coat paint finish | |
US4943680A (en) | Method of making a decorative sheet material simulating the appearance of a base coat/clear coat paint finish | |
US4810540A (en) | Decorative sheet material simulating the appearance of a base coat/clear coat paint finish | |
US5514427A (en) | Injection molded plastic article with integral weatherable pigmented film surface | |
US6835267B1 (en) | Dry paint transfer process and product | |
US5707697A (en) | Dry paint transfer product having high DOI automotive paint coat | |
EP0285071B1 (en) | Dry paint transfer process and product | |
KR940004023B1 (en) | Injection molded plastic article with integral weatherable pigmented film surface | |
USRE36457E (en) | Injection molded plastic article with integrated weatherable pigmented film surface | |
AU661744B2 (en) | Dry paint transfer process and product | |
USRE35894E (en) | Injection molded plastic article with integral weatherable pigmented film surface | |
JP2657050C (en) |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: REXHAM CORPORATION, NEW YORK, NEW YORK A DE CORP. Free format text: ASSIGNMENT OF ASSIGNORS INTEREST.;ASSIGNORS:ELLISON, THOMAS M.;WINTON, ROBERT A.;REEL/FRAME:004934/0496 Effective date: 19880902 |
|
AS | Assignment |
Owner name: REXHAM INDUSTRIES CORP. Free format text: CHANGE OF NAME;ASSIGNOR:REXHAM CORPORATION (CHANGED TO);REEL/FRAME:005771/0090 Effective date: 19910611 |
|
FEPP | Fee payment procedure |
Free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY |
|
FPAY | Fee payment |
Year of fee payment: 4 |
|
STCF | Information on status: patent grant |
Free format text: PATENTED CASE |
|
AS | Assignment |
Owner name: REXAM INDUSTRIES CORP., NORTH CAROLINA Free format text: CHANGE OF NAME;ASSIGNOR:REXHAM INDUSTRIES CORP.;REEL/FRAME:007824/0740 Effective date: 19950518 |
|
FPAY | Fee payment |
Year of fee payment: 8 |
|
FPAY | Fee payment |
Year of fee payment: 12 |
|
AS | Assignment |
Owner name: REXAM DELAWARE CORPORATION, NORTH CAROLINA Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:REXAM IMAGE PRODUCTS, INC.;REEL/FRAME:013221/0277 Effective date: 20020610 Owner name: REXAM IMAGE PRODUCTS INC., NORTH CAROLINA Free format text: MERGER;ASSIGNOR:REXAM INDUSTRIES CORP.;REEL/FRAME:013221/0272 Effective date: 20000713 Owner name: REXAM INDUSTRIES CORP., NORTH CAROLINA Free format text: CHANGE OF NAME;ASSIGNOR:REXHAM INDUSTRIES CORP.;REEL/FRAME:013221/0285 Effective date: 19950518 Owner name: REXHAM INDUSTRIES CORP., NORTH CAROLINA Free format text: RESTATED CERTIFICATE OF INCORPORATION;ASSIGNOR:REXHAM CORPORATION;REEL/FRAME:013221/0268 Effective date: 19901031 |
|
AS | Assignment |
Owner name: SOLIANT LLC, SOUTH CAROLINA Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:REXAM DELAWARE CORPORATION;REEL/FRAME:013231/0481 Effective date: 20020813 |