US5232653A - Process for preparing surface-upgraded molded articles using a low thermal inertia mold - Google Patents

Process for preparing surface-upgraded molded articles using a low thermal inertia mold Download PDF

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US5232653A
US5232653A US07/782,406 US78240691A US5232653A US 5232653 A US5232653 A US 5232653A US 78240691 A US78240691 A US 78240691A US 5232653 A US5232653 A US 5232653A
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mold
upgrading
film
heating
halves
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US07/782,406
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Antonio Addeo
Vincenzo Cocca
Ivano Tommasi
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Centro Sviluppo Settori Impiego SRL
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Centro Sviluppo Settori Impiego SRL
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/42—Component parts, details or accessories; Auxiliary operations
    • B29C49/48—Moulds
    • B29C49/52—Moulds having decorating or printing means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00—Moulds or cores; Details thereof or accessories therefor
    • B29C33/02—Moulds or cores; Details thereof or accessories therefor with incorporated heating or cooling means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00—Moulds or cores; Details thereof or accessories therefor
    • B29C33/02—Moulds or cores; Details thereof or accessories therefor with incorporated heating or cooling means
    • B29C33/04—Moulds or cores; Details thereof or accessories therefor with incorporated heating or cooling means using liquids, gas or steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/24—Lining or labelling
    • B29C49/2408—In-mould lining or labelling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/42—Component parts, details or accessories; Auxiliary operations
    • B29C49/48—Moulds
    • B29C49/4823—Moulds with incorporated heating or cooling means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
    • B29C51/16—Lining or labelling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
    • B29C51/26—Component parts, details or accessories; Auxiliary operations
    • B29C51/42—Heating or cooling
    • B29C51/428—Heating or cooling of moulds or mould parts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
    • B29C49/42—Component parts, details or accessories; Auxiliary operations
    • B29C49/48—Moulds
    • B29C2049/4874—Moulds characterised by the material, e.g. having different thermal conductivities or hardness
    • B29C2049/4876—Moulds characterised by the material, e.g. having different thermal conductivities or hardness one material being heat insulating material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00—Moulds or cores; Details thereof or accessories therefor
    • B29C33/02—Moulds or cores; Details thereof or accessories therefor with incorporated heating or cooling means
    • B29C33/04—Moulds or cores; Details thereof or accessories therefor with incorporated heating or cooling means using liquids, gas or steam
    • B29C33/048—Moulds or cores; Details thereof or accessories therefor with incorporated heating or cooling means using liquids, gas or steam using steam
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10—Methods of surface bonding and/or assembly therefor
    • Y10T156/1002—Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina
    • Y10T156/1028—Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina by bending, drawing or stretch forming sheet to assume shape of configured lamina while in contact therewith

Definitions

  • the present invention concerns a low thermal inertia mold.
  • the present invention relates to a low thermal inertia mold and its use for the surface upgrading of articles manufactured by blow molding or thermoforming.
  • Coupling of surface-upgrading films to manufactured articles made of thermoplastic materials is a known technique in the injection molding technology.
  • the technique is utilized to confer finished articles an external surface exhibiting improved mechanical, aesthetic or decorative characteristics.
  • Said technique can be carried out by two methods: the first method involves positioning in the mold a polymeric film supporting a layer of surface-upgrading material, which is transferred from the film onto the external surface of the manufactured articles during the production process; the second method is based on using films which consist themselves of the surface-upgrading material and which remain adhered to the molded object as a result of the melting of their surface layer in contact with the manufactured article.
  • the film can be positioned in the mold by different techniques, e.g. unwinding of reels placed in proximity of the mold, or performing a direct deposition in the mold using automated devices similar to those adopted for labelling of bottles. In both cases, the film is held in the mold by appropriate techniques, e.g. by applying vacuum or by effect of electrostatic charges.
  • An alternative method to overcome this limitation could have been that of improving chemical compatibility between upgrading materials and polymers used to mold the article, e.g. chemical etching, flame treatment, exposure to a corona discharge, application of primers, etc.
  • the Applicant has now found a system for rendering coupling possible, without resorting to particular modifications of the substrate to promote the adhesion of surface-upgrading films, which is based on using a low thermal inertia mold in the processing stage (blow molding or thermoforming).
  • Said mold permits rapid thermal changes, as a result of an appropriate cooling/heating system, thereby allowing to:
  • the molds referred to in the present invention are molds for blow molding and thermoforming.
  • the cooling system inserted in one of the two mold-halves preferably consists of at least one coil in which a cooling fluid is circulated, e.g. water, whereas the heating system may consist of one or more resistors or of an additional coil in which a high temperature fluid is circulated, e.g. superheated steam or heat-transfer oil.
  • a cooling fluid e.g. water
  • the heating system may consist of one or more resistors or of an additional coil in which a high temperature fluid is circulated, e.g. superheated steam or heat-transfer oil.
  • the heating system is positioned between the surface of the mold-half impression and the cooling system, or, in the case of at least one coil utilized for each of the systems, the coil can be single and first the high temperature fluid and subsequently the cooling fluid are circulated in said coil.
  • Both the cooling and the heating systems are located in the proximity of the surface of the mold-half impression. This means that both systems are located at a distance from said surface of at least 0.5 cm and generally comprised between 1.5 and 5 cm.
  • the part of the mold-half containing the two cooling and heating systems is preferably made of a high thermal conductivity metal, such as copper, silver, brass, bronze, aluminum, etc.
  • the part of the mold-half comprising the two cooling and heating systems can be separated from the remaining part of the mold-half by a thermal insulating layer, made for example of ceramic material.
  • a process for preparing molded articles having an upgraded surface by blow molding using the mold which is object of the present invention comprises:
  • a process for preparing molded articles having an upgraded surface by thermoforming, using the mold which is object of the present invention comprises:
  • thermoforming the sheet or foil coupling it to the surface-upgrading film
  • thermoplastic polymers constituting the extruded tubes (blow molding) and the sheets or foils (thermoforming) are those normally utilized in said technologies.
  • said polymers comprise: polystyrene, impact modified polystyrene, polystyrene modified with polar monomers such as acrylonitrile, styrene containing alloys such as ABS, SAN, etc., polyvinylchloride, high, medium and low density polyethylene, polypropylene, impact modified polypropylene, ethylene/propylene copolymers, acrylic and/or methacrylic resins, polymethylmethacrylates, polyester resins such as PET, PBT, etc., or mixtures thereof.
  • Preferred products are polystyrene, impact modified polystyrene, styrene containing alloys, polypropylene and impact modified polypropylene.
  • Said films are also well known to the skilled in the art.
  • Said films also made of thermoplastic polymers, comprise, as described above, a surface-upgrading layer and an adhering layer or may consist, according to the present invention, of a single surface-upgrading layer.
  • the upgrading layer generally consists of high melting polymers or polymers exhibiting high scratch resistance, such as polyethyleneterephthalate, polymethylmethacrylate, etc.
  • FIG. 1 shows a cross-section of a low thermal inertia mold for blow molding
  • FIG. 2 shows a cross-section of a low thermal inertia mold for thermoforming.
  • the present mold consists of two mold-halves (2) and (2').
  • a cooling system (3) consisting of an hydraulic circuit (coil)
  • a heating system (4) consisting of electrical resistances have been placed in one of the two mold-halves (2). Both systems are positioned in the proximity of the surface of the mold-half impression and are thermally insulated from the body of the mold-half through an isolating layer (1).
  • the operation of the mold is clear on the basis of the figures and the preceding description.
  • AN extruded tube or planar sheet (5) ready to be processed by blow molding or thermoforming, is positioned between the two halves (2) and (2') of the mold.
  • a surface-upgrading film (7) interposed between the tube or sheet (5) and the mold-half (2) is unwound from a reel (6) and tensioned by the roll (8).
  • the mold is closed and molding proceeds according to the conventional technologies.
  • the tube or sheet is molded taking the form of the object to be produced by simultaneously pressing the surface-upgrading film (7) against the mold-half impression (2). Still maintaining the mold closed, one thereafter proceeds to adhere the film onto the surface of the molded article.
  • the mold-half impression (2) is heated, through the resistors (4), to a temperature sufficiently high as to melt the film, or to transfer the surface-upgrading layer, thereafter cooling the same impression through the cooling circuit (3), thereby solidifiying the film, or layer, which remains attached to the surface of the molded article.

Abstract

Blow molding and thermoforming processes in which a mold system having low thermal inertia mold-halves provided with heating and cooling systems is utilized for producing plastic articles coated with surface-upgrading films of high melting polymers or polymers exhibiting a high scratch resistance to improve mechanical characteristics of the molded article. The films may be positioned, before the mold is closed, close to the low thermal inertia mold-halves. Rapid heating and rapid cooling of the mold-halves in contact with the surface-upgraded films permit strength adhesion of the upgrading material to the surface of the molded article.

Description

FIELD OF THE INVENTION
The present invention concerns a low thermal inertia mold.
More in particular the present invention relates to a low thermal inertia mold and its use for the surface upgrading of articles manufactured by blow molding or thermoforming.
BACKGROUND OF THE INVENTION
Coupling of surface-upgrading films to manufactured articles made of thermoplastic materials is a known technique in the injection molding technology. The technique is utilized to confer finished articles an external surface exhibiting improved mechanical, aesthetic or decorative characteristics.
Said technique can be carried out by two methods: the first method involves positioning in the mold a polymeric film supporting a layer of surface-upgrading material, which is transferred from the film onto the external surface of the manufactured articles during the production process; the second method is based on using films which consist themselves of the surface-upgrading material and which remain adhered to the molded object as a result of the melting of their surface layer in contact with the manufactured article.
In both of the above described methods, high temperature/pressure conditions typical of injection molding are required, in addition to chemical compatibility between the materials, in order to achieve a permanent adhesion of the surface-upgrading material to the manufactured article.
The film can be positioned in the mold by different techniques, e.g. unwinding of reels placed in proximity of the mold, or performing a direct deposition in the mold using automated devices similar to those adopted for labelling of bottles. In both cases, the film is held in the mold by appropriate techniques, e.g. by applying vacuum or by effect of electrostatic charges.
With this technique manufactured articles are produced such as wheel covers for motor vehicles, panels made of artificial wood or artificial marble, articles for cosmetics, etc.
However, the utilization of the upgrading films presently on the market can less feasibly be proposed for the conventional blow molding and thermoforming technologies, since these technologies are characterized by remarkably lower temperatures and pressures than in injection molding.
An alternative method to overcome this limitation could have been that of improving chemical compatibility between upgrading materials and polymers used to mold the article, e.g. chemical etching, flame treatment, exposure to a corona discharge, application of primers, etc.
Experience has however demonstrated that in the case of blow molding or thermoforming these compatibilization techniques, in addition to increasing the production costs, have not given good practical results in terms of long term adhesion.
THE PRESENT INVENTION
The Applicant has now found a system for rendering coupling possible, without resorting to particular modifications of the substrate to promote the adhesion of surface-upgrading films, which is based on using a low thermal inertia mold in the processing stage (blow molding or thermoforming).
Said mold permits rapid thermal changes, as a result of an appropriate cooling/heating system, thereby allowing to:
(a) establish at the surface level of the article (and therefore of the upgrading film) temperature values which are greater than the typical values of blow molding or thermoforming an consequently permit adhesion of the upgrading material to the surface of the molded object; and
(b) rapidly cool the adhered film to temperature values which permit extraction of the finished article from the mold.
It is therefore an object of the present invention to provide a low thermal inertia mold consisting of two mold-halves, each reproducing half of the impression of the article to be produced, characterized in that at least one of said mold-halves comprises within the interior a cooling system and a heating system located in the proximity of the surface of the mold-half impression.
In particular the molds referred to in the present invention are molds for blow molding and thermoforming.
The cooling system inserted in one of the two mold-halves preferably consists of at least one coil in which a cooling fluid is circulated, e.g. water, whereas the heating system may consist of one or more resistors or of an additional coil in which a high temperature fluid is circulated, e.g. superheated steam or heat-transfer oil.
According to a preferred embodiment of the mold object of the present invention the heating system is positioned between the surface of the mold-half impression and the cooling system, or, in the case of at least one coil utilized for each of the systems, the coil can be single and first the high temperature fluid and subsequently the cooling fluid are circulated in said coil.
Both the cooling and the heating systems are located in the proximity of the surface of the mold-half impression. This means that both systems are located at a distance from said surface of at least 0.5 cm and generally comprised between 1.5 and 5 cm.
In order to favor heat transfer through the mold-half surface, the part of the mold-half containing the two cooling and heating systems is preferably made of a high thermal conductivity metal, such as copper, silver, brass, bronze, aluminum, etc.
Even though not necessary, in order to again favor the above mentioned heat transfer, the part of the mold-half comprising the two cooling and heating systems can be separated from the remaining part of the mold-half by a thermal insulating layer, made for example of ceramic material.
A process for preparing molded articles having an upgraded surface by blow molding using the mold which is object of the present invention, comprises:
(a) positioning a surface-upgrading film close to at least one of the two mold-halves of the open mold for blow molding, said mold-half containing, in the proximity of the surface of the mold-half impression, the cooling system and the heating system;
(b) extruding a tube of a thermoplastic polymer in between the two open mold-halves, closing the mold and inflating air into the tube;
(c) rapidly heating (20-120 seconds) the surface of the mold-half in contact with the surface-upgrading film to a temperature greater than 100° C., generally between 120° and 200° C.;
(d) rapidly cooling (20-120 seconds) the surface of the mold-half to a temperature close to that of the inflated tube,
(e) stopping the inflation and extracting the finished article, after possible further cooling.
Analogously, a process for preparing molded articles having an upgraded surface by thermoforming, using the mold which is object of the present invention, comprises:
(a) positioning a surface-upgrading film close to at least one of the two mold-halves of the open thermoforming mold, said mold-half containing, in the proximity of the surface of the mold-half impression, the cooling system and the heating system;
(b) heating a sheet or foil of thermoplastic polymer to its softening temperature;
(c) thermoforming the sheet or foil, coupling it to the surface-upgrading film;
(d) rapidly heating (20-120 seconds) the surface of the mold-half in contact with the upgrading film to a temperature greater than 100° C., generally between 120° and 200° C.;
(e) rapidly cooling (20-120 seconds) the surface of the mold-half to a temperature close to that of the thermoformed sheet;
(f) extracting the finished article, after possible further cooling.
In the above described molding processes by blow molding or thermoforming, the thermoplastic polymers constituting the extruded tubes (blow molding) and the sheets or foils (thermoforming) are those normally utilized in said technologies. Examples of said polymers comprise: polystyrene, impact modified polystyrene, polystyrene modified with polar monomers such as acrylonitrile, styrene containing alloys such as ABS, SAN, etc., polyvinylchloride, high, medium and low density polyethylene, polypropylene, impact modified polypropylene, ethylene/propylene copolymers, acrylic and/or methacrylic resins, polymethylmethacrylates, polyester resins such as PET, PBT, etc., or mixtures thereof.
Preferred products are polystyrene, impact modified polystyrene, styrene containing alloys, polypropylene and impact modified polypropylene.
Surface-upgrading films are also well known to the skilled in the art. Said films, also made of thermoplastic polymers, comprise, as described above, a surface-upgrading layer and an adhering layer or may consist, according to the present invention, of a single surface-upgrading layer. The upgrading layer generally consists of high melting polymers or polymers exhibiting high scratch resistance, such as polyethyleneterephthalate, polymethylmethacrylate, etc.
A practical embodiment, which exemplifies and is in no way limitative to the mold object of the present invention, is illustrated in the attached drawings wherein:
FIG. 1 shows a cross-section of a low thermal inertia mold for blow molding; and
FIG. 2 shows a cross-section of a low thermal inertia mold for thermoforming.
Referring to the figures, the present mold consists of two mold-halves (2) and (2'). A cooling system (3), consisting of an hydraulic circuit (coil), and a heating system (4) consisting of electrical resistances have been placed in one of the two mold-halves (2). Both systems are positioned in the proximity of the surface of the mold-half impression and are thermally insulated from the body of the mold-half through an isolating layer (1). The operation of the mold is clear on the basis of the figures and the preceding description. AN extruded tube or planar sheet (5), ready to be processed by blow molding or thermoforming, is positioned between the two halves (2) and (2') of the mold. A surface-upgrading film (7) interposed between the tube or sheet (5) and the mold-half (2) is unwound from a reel (6) and tensioned by the roll (8). At the moment of fabrication, the mold is closed and molding proceeds according to the conventional technologies. The tube or sheet is molded taking the form of the object to be produced by simultaneously pressing the surface-upgrading film (7) against the mold-half impression (2). Still maintaining the mold closed, one thereafter proceeds to adhere the film onto the surface of the molded article. To said purpose only the mold-half impression (2) is heated, through the resistors (4), to a temperature sufficiently high as to melt the film, or to transfer the surface-upgrading layer, thereafter cooling the same impression through the cooling circuit (3), thereby solidifiying the film, or layer, which remains attached to the surface of the molded article.
As a result of the position of the two systems, as well as of the presence of the insulating layer (1), only the surface of the mold-half (2) undergoes the above described heating/cooling effect, which, for the same reasons, can be rapidly and exclusively accomplished at the surface level of the molded article.
In the practice of the present invention, changes, modifications and variations can be made to the various parts which constitute the low thermal inertia mold illustrated, as a mean of providing an example, in the figures of the attached drawings, while remaining within the spirit and scope of the present invention.

Claims (8)

What is claimed is:
1. A blow molding process for making articles that are at least partially covered by a surface-upgrading layer, the process comprising:
(a) positioning a surface-upgrading film close to an internal surface of at least one of two mold-halves of a blow molding mold while the mold is open, the at least one of two mold-halves comprising means for heating and cooling at least part of said internal surface;
(b) extruding a tube made of a first thermoplastic polymer between the two open mold-halves, closing the mold and inflating the tube with air to blow mold the tube against the surface-upgrading film;
(c) rapidly heating at least part of said internal surface to a temperature sufficient to melt the surface-upgrading film to adhere the surface-upgrading film to the inflated tube;
(d) rapidly cooling at least part of said internal surface to a temperature close to that of the inflated tube; and
(e) stopping the inflation and extracting the finished article;
wherein, the surface-upgrading film is a second thermoplastic polymer having a melting point which is higher than the melting point of the first thermoplastic polymer.
2. The process of claim 1 wherein the surface-upgrading film is unwound from a reel configured at one side of the mold and tensioned by a roll configured at a different side of the mold.
3. The process of claim 1 wherein at least part of said internal surface is heated to a temperature from 120° C.-200° C.
4. The process of claim 1 wherein the heating and cooling steps are conducted for 20-120 seconds.
5. A thermoforming process for making articles that are at least partially covered by a surface-upgrading layer, the process comprising:
(a) positioning a surface-upgrading film close to an internal surface of at least one of two mold-halves of a thermoforming mold while the mold is open, the at least one of two mold-halves comprising means for heating and cooling at least part of said internal surface;
(b) heating a sheet or foil made of a first thermoplastic polymer to the softening temperature of the polymer;
(c) thermoforming the sheet or foil and coupling it to the surface-upgrading film;
(d) rapidly heating at least part of said internal surface to a temperature sufficient to melt the surface-upgrading film so that the surface-upgrading film adheres to the thermoformed sheet;
(e) rapidly cooling at least part of said internal surface to a temperature close to that of the thermoformed sheet; and
(f) extracting the finished article;
wherein the surface-upgrading film comprises a second thermoplastic polymer having a melting point which is higher than the softening point of the first thermoplastic polymer.
6. The process of claim 5 wherein the surface-upgrading film is unwound from a reel configured at one side of the mold and tensioned by a roll configured at a different side of the mold.
7. The process of claim 5 wherein at least part of said internal surface is heated to a temperature from 120° C.-200° C.
8. The process of claim 5 wherein the heating and cooling steps are conducted for 20-120 seconds.
US07/782,406 1990-11-02 1991-10-25 Process for preparing surface-upgraded molded articles using a low thermal inertia mold Expired - Fee Related US5232653A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT02196590A IT1244146B (en) 1990-11-02 1990-11-02 LOW THERMAL INERTIA MOLD AND ITS USE IN THE SURFACE FINISHING OF OBJECTS OBTAINED BY "BLOW MOLDING" OR THERMOFORMING
IT21965A/90 1990-11-02

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EP (1) EP0483849B1 (en)
JP (1) JPH0623754A (en)
KR (1) KR920009539A (en)
AT (1) ATE121989T1 (en)
DE (1) DE69109445T2 (en)
DK (1) DK0483849T3 (en)
ES (1) ES2071887T3 (en)
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Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5534218A (en) * 1992-10-28 1996-07-09 Krupp Kautex Maschinenbau Gmbh Process for the production of a hollow body of thermoplastic material
US5562873A (en) * 1994-08-15 1996-10-08 Matrex Furniture Components, Inc. Method for forming a cushion
US5804127A (en) * 1995-05-29 1998-09-08 Ube Industries, Ltd. Blow molding method
US5866172A (en) * 1996-06-20 1999-02-02 Westvaco Corporation Ozone treatment for composite paperboard/ polymer package
US5925302A (en) * 1994-04-25 1999-07-20 Dai Nippon Printing Co., Ltd. Method for forming a pattern onto an article during injection molding
US6523778B2 (en) 2000-06-29 2003-02-25 The Night Fun Co., Llc Illuminated emergency signaling device and flying balloon
US6846445B2 (en) 2002-09-04 2005-01-25 Byung Kim Method for rapid mold heating and cooling
US20050161151A1 (en) * 2003-10-31 2005-07-28 Cabraja Mark S. Cushion forming apparatus and method of use
US20070281137A1 (en) * 2006-06-01 2007-12-06 Kuolih Tsai Heat-transfer label assembly and apparatus for applying heat-transfer labels
US20080303194A1 (en) * 2007-06-08 2008-12-11 Sabic Innovative Plastics Ip B.V. Mold apparatus for forming polymer and method
US20090115104A1 (en) * 2007-10-26 2009-05-07 Sabic Innovative Plastics Ip B.V. System and Method for Forming Polymer
US20090194908A1 (en) * 2007-12-28 2009-08-06 Chung Yuan Christian University Mold for injection molding and an injection molding device/method with surface quality improvement ability
US20100170782A1 (en) * 2006-08-02 2010-07-08 Szokolay Robert E Mold Tooling with Integrated Thermal Management Fluid Channels and Method
US20100237543A1 (en) * 2009-03-20 2010-09-23 Paul Le Roi Thermoforming mould with thermal insulation and associated method
US8663537B2 (en) 2012-05-18 2014-03-04 3M Innovative Properties Company Injection molding apparatus and method
US9938178B2 (en) * 2013-08-15 2018-04-10 Corning Incorporated Methods of manufacturing glass articles using anisothermal temperature profiles
US10427329B2 (en) 2014-06-27 2019-10-01 Sabic Global Technologies B.V. Induction heated mold apparatus with multimaterial core and method of using the same
EP3024632B1 (en) * 2013-07-26 2020-04-01 Alpla-Werke Alwin Lehner GMBH & Co.KG In-mould decoration of an article and removing of the decoration
US11148344B1 (en) * 2020-04-21 2021-10-19 Elc Management Llc Blow molding method and apparatus

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2694906B1 (en) 1992-08-20 1994-09-23 Acb Press for forming a piece of composite material comprising fibrous reinforcements in a polymer matrix.
US6048189A (en) * 1995-04-05 2000-04-11 Japan Synthetic Rubber Co., Ltd. Blow molding apparatus
TW340089B (en) 1996-05-28 1998-09-11 Idemitsu Petrochemical Co Method and apparatus for manufacturing hollow formed items
DE10019496A1 (en) * 2000-04-19 2001-10-25 Kiefel Gmbh Paul Process for the partial surface profiling of carrier parts to be laminated with a decorative material
JP4739232B2 (en) 2004-11-30 2011-08-03 三菱電機株式会社 Moving handrail repair device for passenger conveyor
ITMC20080215A1 (en) * 2008-12-03 2010-06-04 Futura Stampi Srl MOLD FOR THE THERMOFORMING OF POLYESTER CEILING.
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HUE036540T2 (en) * 2014-06-30 2018-07-30 Persico Spa Apparatus and method for coupling and/or edge folding panels with hot glue activation
CN106273294B (en) * 2016-08-10 2019-03-08 蚌埠市多宝塑模科技有限公司 A kind of mold heating mechanism
CN108297381B (en) * 2018-02-02 2019-09-24 广东腾业科技有限公司 Printing process in a kind of mould of blow molding thin-walled pressure vessel
DE102018007824B3 (en) * 2018-10-04 2020-01-23 Kiefer Werkzeugbau Gmbh Process for applying a label to a deep-drawn molded part and mold for carrying out the process

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1587186A (en) * 1968-10-11 1970-03-13
US3736201A (en) * 1970-11-19 1973-05-29 S Teraoka Method for molding bowl-shaped articles
JPS5720328A (en) * 1980-07-10 1982-02-02 Dainippon Printing Co Ltd Metal mold for heat treatment
JPS5973926A (en) * 1982-10-22 1984-04-26 Hitachi Ltd Molding method of hollow double wall vessel, having projecting section on inner surface
JPS59150731A (en) * 1983-02-18 1984-08-29 Hitachi Ltd Hollow double-wall box and method and apparatus for forming the same
JPS61148021A (en) * 1984-12-21 1986-07-05 Toyoda Gosei Co Ltd Blow molding method and its device
JPS63249615A (en) * 1987-04-06 1988-10-17 Chiyoda Gravure Insatsushiya:Kk Method for simultaneous molding and transfer decorating
JPS63252718A (en) * 1986-11-08 1988-10-19 Kamaya Kagaku Kogyo Co Ltd Decorating method for hollow molded object and its device
US5017126A (en) * 1988-09-27 1991-05-21 Ube Industries, Ltd. Blow molding apparatus
US5041247A (en) * 1988-09-29 1991-08-20 General Electric Company Method and apparatus for blow molding parts with smooth surfaces

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3340714A (en) * 1963-11-19 1967-09-12 Bell Telephone Labor Inc Method for deforming metal-plastic laminates
US4795517A (en) * 1986-06-05 1989-01-03 Astechnologies, Inc. Process for shaping and covering cushion foam

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1587186A (en) * 1968-10-11 1970-03-13
US3736201A (en) * 1970-11-19 1973-05-29 S Teraoka Method for molding bowl-shaped articles
JPS5720328A (en) * 1980-07-10 1982-02-02 Dainippon Printing Co Ltd Metal mold for heat treatment
JPS5973926A (en) * 1982-10-22 1984-04-26 Hitachi Ltd Molding method of hollow double wall vessel, having projecting section on inner surface
JPS59150731A (en) * 1983-02-18 1984-08-29 Hitachi Ltd Hollow double-wall box and method and apparatus for forming the same
JPS61148021A (en) * 1984-12-21 1986-07-05 Toyoda Gosei Co Ltd Blow molding method and its device
JPS63252718A (en) * 1986-11-08 1988-10-19 Kamaya Kagaku Kogyo Co Ltd Decorating method for hollow molded object and its device
JPS63249615A (en) * 1987-04-06 1988-10-17 Chiyoda Gravure Insatsushiya:Kk Method for simultaneous molding and transfer decorating
US5017126A (en) * 1988-09-27 1991-05-21 Ube Industries, Ltd. Blow molding apparatus
US5041247A (en) * 1988-09-29 1991-08-20 General Electric Company Method and apparatus for blow molding parts with smooth surfaces

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Kiek Othmer, 3rd Edition, vol. 6, pp. 406 407. *
Kiek-Othmer, 3rd Edition, vol. 6, pp. 406-407.

Cited By (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5534218A (en) * 1992-10-28 1996-07-09 Krupp Kautex Maschinenbau Gmbh Process for the production of a hollow body of thermoplastic material
US6416306B2 (en) 1994-04-25 2002-07-09 Dai Nippon Printing Co., Ltd. Apparatus for forming pattern onto article during injection molding
US5925302A (en) * 1994-04-25 1999-07-20 Dai Nippon Printing Co., Ltd. Method for forming a pattern onto an article during injection molding
US6270331B1 (en) 1994-04-25 2001-08-07 Dai Nippon Printing Co., Ltd. Apparatus for forming pattern onto article during injection molding
US20010022413A1 (en) * 1994-04-25 2001-09-20 Dai Nippon Printing Co., Ltd. Apparatus for forming pattern onto article during injection molding
US6413069B2 (en) 1994-04-25 2002-07-02 Dai Nippon Printing Co., Ltd. Apparatus for forming pattern onto article during injection molding
US7114936B2 (en) 1994-04-25 2006-10-03 Dai Nippon Printing Co., Ltd. Apparatus for forming pattern onto article during injection molding
US6648621B2 (en) 1994-04-25 2003-11-18 Dai Nippon Printing Co., Ltd. Apparatus for forming pattern onto article during injection molding
US5562873A (en) * 1994-08-15 1996-10-08 Matrex Furniture Components, Inc. Method for forming a cushion
US5804127A (en) * 1995-05-29 1998-09-08 Ube Industries, Ltd. Blow molding method
US6045647A (en) * 1995-05-29 2000-04-04 Ube Industries, Ltd. Laminating blow molding method using shifting members
US5866172A (en) * 1996-06-20 1999-02-02 Westvaco Corporation Ozone treatment for composite paperboard/ polymer package
US6523778B2 (en) 2000-06-29 2003-02-25 The Night Fun Co., Llc Illuminated emergency signaling device and flying balloon
US6846445B2 (en) 2002-09-04 2005-01-25 Byung Kim Method for rapid mold heating and cooling
US7320737B2 (en) 2003-10-31 2008-01-22 Tiger Sales, Inc. Cushion forming apparatus and method of use
US20050161151A1 (en) * 2003-10-31 2005-07-28 Cabraja Mark S. Cushion forming apparatus and method of use
US20070281137A1 (en) * 2006-06-01 2007-12-06 Kuolih Tsai Heat-transfer label assembly and apparatus for applying heat-transfer labels
US8215943B2 (en) * 2006-06-01 2012-07-10 Avery Dennison Corporation Heat-transfer label assembly and apparatus for applying heat-transfer labels
US20100170782A1 (en) * 2006-08-02 2010-07-08 Szokolay Robert E Mold Tooling with Integrated Thermal Management Fluid Channels and Method
US8403659B2 (en) * 2006-08-02 2013-03-26 Robert E. Szokolay Mold tooling with integrated thermal management fluid channels and method
US8840386B2 (en) 2007-06-08 2014-09-23 Sabic Innovative Plastics Ip B.V. Mold apparatus for forming polymer and method
US20080303194A1 (en) * 2007-06-08 2008-12-11 Sabic Innovative Plastics Ip B.V. Mold apparatus for forming polymer and method
US8021135B2 (en) 2007-06-08 2011-09-20 Sabic Innovative Plastics Ip B.V. Mold apparatus for forming polymer and method
US20090115104A1 (en) * 2007-10-26 2009-05-07 Sabic Innovative Plastics Ip B.V. System and Method for Forming Polymer
US9096009B2 (en) 2007-10-26 2015-08-04 Sabic Global Technologies B.V. Method for forming a polymer part
US20090194908A1 (en) * 2007-12-28 2009-08-06 Chung Yuan Christian University Mold for injection molding and an injection molding device/method with surface quality improvement ability
US20100237543A1 (en) * 2009-03-20 2010-09-23 Paul Le Roi Thermoforming mould with thermal insulation and associated method
US8714962B2 (en) * 2009-03-20 2014-05-06 A.R.C.I.L. Thermoforming mould with thermal insulation and associated method
US8663537B2 (en) 2012-05-18 2014-03-04 3M Innovative Properties Company Injection molding apparatus and method
EP3024632B1 (en) * 2013-07-26 2020-04-01 Alpla-Werke Alwin Lehner GMBH & Co.KG In-mould decoration of an article and removing of the decoration
US9938178B2 (en) * 2013-08-15 2018-04-10 Corning Incorporated Methods of manufacturing glass articles using anisothermal temperature profiles
US10611661B2 (en) 2013-08-15 2020-04-07 Corning Incorporated Methods of manufacturing glass articles using anisothermal temperature profiles
US10427329B2 (en) 2014-06-27 2019-10-01 Sabic Global Technologies B.V. Induction heated mold apparatus with multimaterial core and method of using the same
US11148344B1 (en) * 2020-04-21 2021-10-19 Elc Management Llc Blow molding method and apparatus

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DE69109445T2 (en) 1995-09-07
TW241224B (en) 1995-02-21
EP0483849B1 (en) 1995-05-03
DK0483849T3 (en) 1995-07-17
IT9021965A1 (en) 1992-05-02
KR920009539A (en) 1992-06-25
ES2071887T3 (en) 1995-07-01
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JPH0623754A (en) 1994-02-01
EP0483849A1 (en) 1992-05-06

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