|Número de publicación||US5630372 A|
|Tipo de publicación||Concesión|
|Número de solicitud||US 08/506,334|
|Fecha de publicación||20 May 1997|
|Fecha de presentación||25 Jul 1995|
|Fecha de prioridad||25 Jul 1995|
|También publicado como||CA2226653A1, CA2226653C, DE19681506T0, DE19681506T1, WO1997005481A1|
|Número de publicación||08506334, 506334, US 5630372 A, US 5630372A, US-A-5630372, US5630372 A, US5630372A|
|Inventores||Joseph W. Ramsey, Peter L. Gill|
|Cesionario original||Ramsey; Joseph W., Gill; Peter L.|
|Exportar cita||BiBTeX, EndNote, RefMan|
|Citas de patentes (11), Citada por (29), Clasificaciones (10), Eventos legales (4)|
|Enlaces externos: USPTO, Cesión de USPTO, Espacenet|
1. Field of the Invention
With regard to the classification of art, this invention is believed to be found in the general class entitled SIGNALS AND INDICATORS and more particularly to those subclasses pertaining to those that are CHEMICALLY ACTIVATED.
2. Description of Related Art
Useful life indicators are known in the prior art. One example in the known prior art is U.S. Pat. No., 4,812,053 which issued to Bhattacharjee on Mar. 14, 1989. This cited patent has advanced the art but accuracy, repeatability and reliability still remain an identified need. The present invention addresses those above identified needs. The present invention provides a structure that allow at least one of its indicating portions to remain dormant from the time of manufacture until the time of activation. After activation, the present invention provides an indication means that is activated by a component of an ambient fluid. This present invention also includes a membrane member which protects the indicator material.
This invention may be briefly summarized as an on demand usable life indicator comprising: a base member, an indicator material, an adhesive layer, and co-layered cover member. The base member is impermeable to a selected ambient fluid. The indicator material is applied to one side of the base member in a predetermined pattern. The indicator material has a selected composition for providing a visual indication when exposed to a predetermined component of an ambient fluid for a predetermined period of time. The adhesive layer is applied with a predetermined pattern over the exposed side of the indicator material. The adhesive layer has impermeable properties with respect to said ambient fluid. The predetermined pattern being configured for providing exposure of at least one selected portion of the indicator material to the ambient fluid. The co-layered layered cover member covers the adhesive layer. One of the layers being impermeable to the selected ambient fluid for isolating said indicator material from the ambient fluid. A second layer being permeable to the selected ambient fluid. The second layer is adhered to the adhesive layer for providing a membrane between the ambient fluid and the indicator material. The first layer is selectably removable from said second layer for exposing the selected portion of the indicating layer to the selected ambient fluid.
In addition to the above summary, the following disclosure is intended to be detailed to insure adequacy and aid in the understanding of the invention. However, this disclosure, showing particular embodiments of the invention, is not intended to describe each new inventive concept which may arise. These specific embodiments have been chosen to show at least one preferred or best mode for the on demand useful life indicator of the present invention. These specific embodiments, as shown in the accompanying drawings, may also include diagrammatic symbols for the purpose of illustration and understanding.
FIG. 1 represents a cross-sectional view of an on demand useful life indicator of the present invention.
In the following description and in the appended claims, various details are identified by specific names for convenience. These names are intended to be generic in their application while differentiating between the various details. The corresponding reference numbers refer to like members throughout the several figures of the drawing.
The drawing accompanying and forming a part of this specification disclose details of construction for the sole purpose of explanation. It is to be understood that structural details may be modified without departing from the concept and principles of the claimed invention. This invention may be incorporated into other structural forms than those that are shown.
Referring to the drawing a usable life indicator is generally identified as 10. That usable life indicator 10 includes a base member 12, an indicator material layer 14; an adhesive layer 16; and a co-layered cover member 18.
The base member 12 is preferably made of a material that is impermeable to a selected ambient fluid. The ambient fluid may be either a gas or a liquid. However the base member 12 may be made of a material that is impervious to gas and liquid. This base member 12 may be a flexible thermoplastic material or a metallic foil that is applied as a self-adhesive label.
The indicator material layer 14 is applied onto one side of the base material. Printing the indicator material 14 in a selected pattern is among the methods of application. The indicator material should have a selected composition. This selected composition will provide a visual indication when exposed to a selected component of an ambient fluid for a selected period of time. This indication may be a change of color or a change from a visual color to a lack of color. It may be necessary to apply this indicator material in a controlled or inert atmosphere such as Nitrogen. The selected component should be absent from the controlled atmosphere for avoiding a false indication. It may be necessary to cure or dry the indicator layer to a preferred state.
After the indicator material layer 14 is brought to a preferred cured condition, the adhesive layer 16 is applied thereon and thereover. The adhesive layer may be applied in a selected pattern by a processes such as printing; coating; or laminating. Preferably, the adhesive layer is composed of a material that is impermeable to the selected component of the ambient fluid. Any voids in the adhesive layer will allow the selected component in the ambient fluid to come in contact with the indicator layer. This adhesive layer may be pressure sensitive; heat activated; or contact type.
A co-layered cover member 18 is applied over the adhesive layer 16. This co-layered cover member 18 includes at least two layers. The first or outer layer 20 is impermeable to the selected component of the ambient fluid. The surface of the second or inner layer 22, directly contacting the adhesive layer, is rendered impermeable to the selected component of the ambient fluid due to the impermeability of the adhesive 16. The inner layer 22 has a greater adhesion to the adhesive layer 16 than to the outer layer 20. This allows the outer layer to be selectively removed without removal of the inner layer 22. Removal of the outer layer 20 allows a selected component of the ambient fluid to permeate through inner layer 22 and any voids in the adhesive layer 16. The rate of change of the visual indication of the indicator material layer 14 may be controlled by its composition or by controlling the permeability of the inner layer 22. The inner layer 22 also acts as a membrane for protecting the surface of the adhesive layer 16 and the indicator material layer 14 from abrasion. One Example of co-layered material is Technimagic™ which is produced by Technicote.
The usable life indicator 10 has a relatively long shelf life when the outer layer and the base member are not punctured. It is only when the outer layer 20 is removed that the timing of the period for a selected useful life begins.
The composition of the adhesive layer 16 may be formulated to include the selected component of the ambient fluid. This type of formulation would provide a perceptible change to the indicator material 14 directly in contact with the adhesive layer 16. This arrangement would provide a self-contained norm for judging the degree of color or lack of color. "This self-contained norm may be utilized by visually comparing the area of any indicating material 14 interior of the void areas in the adhesive layer 16 with the self-contained norm. Any visual comparison is made by viewing any visual changes to the indicating material 14 though the exposed surface of inner layer 22 after the outer layer 20 has been removed."
One example of a useable life indicator includes an indicator material layer 14 that is sensitive to an acid or a base component of the ambient fluid. The indicator material 14 may be formulated with litmus like properties. Some examples of materials having litmus properties are Phenolphthalein, Phenolsulfonethalein and the like.
A second example of a useable life indicator includes an indicator material layer 14 that is sensitive to carbon dioxide as the active component of the ambient fluid. The indicator material 14 may be formulated with Oxidation/Reduction properties. One example of those materials that change properties when exposed to carbon dioxide is Thymolphthalein, but not limited thereto.
A third example of a useable life indicator includes an indicator material layer 14 that is sensitive to oxygen as the active component of the ambient fluid. The indicator material 14 may be formulated with Oxidation/Reduction properties. One example of those materials that change properties when exposed to oxygen is Methyl Orange, but not limited thereto.
A fourth example of a useable life indicator includes an indicator material layer 14 that is sensitive to ozone as the active component of the ambient fluid. The indicator material 14 may be formulated with Oxidation/Reduction properties. One example of those materials that change properties when exposed to ozone is Crystal Violet, but not limited thereto.
A fifth example of a useable life indicator includes an indicator material layer 14 that is sensitive to chlorine as the active component of the ambient fluid. The indicator material 14 may be formulated with Oxidation/Reduction properties. One example of those materials that change properties when exposed to chlorine is Metacresol Purple, but not limited thereto.
A sixth example of a useable life indicator includes an indicator material layer 14 that is sensitive to carbon monoxide as the active component of the ambient fluid. The indicator material 14 may be formulated with Oxidation/Reduction properties. One example of those materials that change properties when exposed to carbon monoxide is Alizarin Yellow, but not limited thereto.
As mentioned above, the adhesive layer in any or all of the examples mentioned above may be formulated with the component of the ambient fluid to provide the norm as described above. The color or visual indication of that area of the indicator material 14 not in contact with the adhesive would remain as applied until the outer layer 20 is removed. The area of the indicator material 14 in direct contact with the adhesive layer 16 would change to the color or visual indication that is to be used as a norm.
Directional terms such as "upper", "lower", "inner", "outer" and the like may have been used in the description. These terms are applicable to the embodiments shown and described in conjunction with the drawings. These terms are merely used for the purpose of description in connection with the drawings and do not necessarily apply to the position in which the present invention may be used.
While these particular embodiments of the present invention have been shown and described, it is to be understood that the invention is rot limited thereto and protection is sought to the broadest extent that the prior art allows.
|Patente citada||Fecha de presentación||Fecha de publicación||Solicitante||Título|
|US2918033 *||10 Oct 1957||22 Dic 1959||Martin J Snyder||Pipe leakage detector|
|US2918893 *||17 Nov 1955||29 Dic 1959||Clyde A Norton||Leakage indicator for liquid fuel systems|
|US3018611 *||31 Ago 1959||30 Ene 1962||Timer device and method for determination|
|US3243303 *||27 Jun 1962||29 Mar 1966||Johnson Leighton C||Temperature monitor employing a flowable aqueous composition containing dispersed polyvinyl acetate as a flow retardant|
|US3952746 *||29 Jul 1974||27 Abr 1976||Summers F Wayne||Humidity indicating diaper cover|
|US4205043 *||4 May 1978||27 May 1980||Esch Victor H||Hazardous atmosphere badge|
|US4212153 *||7 Feb 1978||15 Jul 1980||Herculite Protective Fabrics Corporation||Time color indicator|
|US4248597 *||12 Dic 1978||3 Feb 1981||Akzona Incorporated||Time watch or depletion indicator for removable substances|
|US4550150 *||19 Nov 1980||29 Oct 1985||Allied Corporation||Coloration of acetylenic monomers by gases|
|US4812053 *||7 Ago 1987||14 Mar 1989||Lifelines Technology, Inc.||Activatable time-temperature indicator|
|US5482000 *||15 Jun 1994||9 Ene 1996||Patent Master, Inc.||Surface mount overheat indicator with projecting fusible disk|
|Patente citante||Fecha de presentación||Fecha de publicación||Solicitante||Título|
|US5797344 *||13 Mar 1997||25 Ago 1998||Ramsey; Joseph W.||On-demand useful life indicator and method of making same|
|US6536370 *||25 Nov 1998||25 Mar 2003||Advanced Micro Devices, Inc.||Elapsed time indicator for controlled environments and method of use|
|US7185601 *||1 Mar 2001||6 Mar 2007||Micron Technology, Inc.||Chemically sensitive warning apparatus and method|
|US7434535 *||31 Dic 2003||14 Oct 2008||Church & Dwight Co., Inc.||Timing device|
|US7808861||1 Sep 2005||5 Oct 2010||Abraham Wien||Expiration date system|
|US7864022 *||7 Mar 2008||4 Ene 2011||S&C Electric Company||Wear indicator for a circuit interrupter exhaust control device|
|US7940605||14 Jul 2006||10 May 2011||Prasidiux, Llc||Stimulus indicating device employing polymer gels|
|US8077554||13 Oct 2006||13 Dic 2011||Ambrozy Rel S||Stimulus indicating device employing polymer gels|
|US8166906||12 Dic 2007||1 May 2012||Ambrozy Rel S||Stimulus indicating device employing polymer gels|
|US8183045 *||21 Ago 2005||22 May 2012||Skyrad, Ltd.||Indicating device for temperature sensitive products|
|US8288178 *||6 Ago 2009||16 Oct 2012||Renesas Electronics Corporation||Lead frame, method of manufacturing the same, and method of manufacturing semiconductor device|
|US8619507||14 Ene 2013||31 Dic 2013||Prasidiux, Llc||Stimulus indicating device employing polymer gels|
|US9063015||1 May 2006||23 Jun 2015||Prasidiux Llp||Stimulus indication employing polymer gels|
|US9182292||5 Mar 2008||10 Nov 2015||Prasidiux, Llc||Stimulus indicating device employing polymer gels|
|US9588053 *||28 Feb 2013||7 Mar 2017||Firestone Industrial Products Company, Llc||Replacement indicator, elastomeric articles and methods|
|US20030235119 *||17 Jul 2001||25 Dic 2003||Abraham Wien||Expiration date system|
|US20050141348 *||31 Dic 2003||30 Jun 2005||Adamy Steven T.||Timing device|
|US20050286350 *||1 Sep 2005||29 Dic 2005||Abraham Wien||Expiration date system|
|US20060202757 *||12 May 2006||14 Sep 2006||Ikuroh Ichitsubo||Power amplifier with integrated sensors|
|US20060260533 *||13 Abr 2006||23 Nov 2006||Thomas Parias||Expiration warning patch for gas expiration date management|
|US20060262828 *||1 May 2006||23 Nov 2006||Ambrozy Rel S||Stimulus indication employing polymer gels|
|US20070036038 *||14 Jul 2006||15 Feb 2007||Ambrozy Rel S||Stimulus indicating device employing polymer gels|
|US20080009067 *||21 Ago 2005||10 Ene 2008||Skyrad Ltd.||Indicating Device for Temperature Sensitive Products|
|US20080217298 *||7 Mar 2008||11 Sep 2008||S & C Electric Co.||Wear Indicator for a Circuit Interrupter Exhaust Control Device|
|US20100035368 *||6 Ago 2009||11 Feb 2010||Nec Electronics Corporation||Lead frame, method of manufacturing the same, and method of manufacturing semiconductor device|
|US20150000589 *||28 Feb 2013||1 Ene 2015||Firestone Industrial Products Company, Llc||Replacement indicator, elastomeric articles and methods|
|US20150253252 *||3 Oct 2013||10 Sep 2015||Insignia Technologies Ltd||Indicator Device|
|US20160011157 *||27 Feb 2014||14 Ene 2016||Insignia Technologies Ltd||Time Passage Indicator|
|WO2002006904A1 *||17 Jul 2001||24 Ene 2002||Abraham Wien||Expiration date system|
|Clasificación de EE.UU.||116/206, 426/87|
|Clasificación internacional||C12Q1/26, G01N31/22|
|Clasificación cooperativa||G01N31/225, G01N31/223, C12Q1/26|
|Clasificación europea||C12Q1/26, G01N31/22D4, G01N31/22D|
|19 Jun 2000||FPAY||Fee payment|
Year of fee payment: 4
|8 Dic 2004||REMI||Maintenance fee reminder mailed|
|20 May 2005||LAPS||Lapse for failure to pay maintenance fees|
|19 Jul 2005||FP||Expired due to failure to pay maintenance fee|
Effective date: 20050520