US5994040A - Processing composition for silver halide photographic light-sensitive material, developer and processing method using the same - Google Patents
Processing composition for silver halide photographic light-sensitive material, developer and processing method using the same Download PDFInfo
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- US5994040A US5994040A US08/810,424 US81042497A US5994040A US 5994040 A US5994040 A US 5994040A US 81042497 A US81042497 A US 81042497A US 5994040 A US5994040 A US 5994040A
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- United States
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- compound
- silver halide
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- -1 silver halide Chemical class 0.000 title claims abstract description 448
- 239000004332 silver Substances 0.000 title claims abstract description 137
- 229910052709 silver Inorganic materials 0.000 title claims abstract description 137
- 239000000463 material Substances 0.000 title claims abstract description 111
- 238000012545 processing Methods 0.000 title claims abstract description 75
- 239000000203 mixture Substances 0.000 title claims abstract description 58
- 238000003672 processing method Methods 0.000 title claims abstract description 17
- 150000001875 compounds Chemical class 0.000 claims abstract description 306
- 125000004432 carbon atom Chemical group C* 0.000 claims description 151
- 239000000839 emulsion Substances 0.000 claims description 129
- 125000000217 alkyl group Chemical group 0.000 claims description 128
- 125000001424 substituent group Chemical group 0.000 claims description 120
- 125000000623 heterocyclic group Chemical group 0.000 claims description 111
- 125000003118 aryl group Chemical group 0.000 claims description 93
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 78
- 125000003545 alkoxy group Chemical group 0.000 claims description 65
- 239000003795 chemical substances by application Substances 0.000 claims description 64
- 229910052757 nitrogen Inorganic materials 0.000 claims description 44
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 42
- 125000003342 alkenyl group Chemical group 0.000 claims description 37
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 32
- 229910021607 Silver chloride Inorganic materials 0.000 claims description 31
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 claims description 30
- 125000000304 alkynyl group Chemical group 0.000 claims description 27
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 27
- 229910052799 carbon Inorganic materials 0.000 claims description 26
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 22
- 239000000084 colloidal system Substances 0.000 claims description 20
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 19
- 230000006911 nucleation Effects 0.000 claims description 17
- 238000010899 nucleation Methods 0.000 claims description 17
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 11
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 8
- 125000004429 atom Chemical group 0.000 claims description 6
- 150000001768 cations Chemical group 0.000 claims description 6
- 239000010413 mother solution Substances 0.000 claims description 6
- 230000008030 elimination Effects 0.000 claims description 5
- 238000003379 elimination reaction Methods 0.000 claims description 5
- 239000002667 nucleating agent Substances 0.000 claims description 5
- 101100386054 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) CYS3 gene Proteins 0.000 abstract 1
- 101150035983 str1 gene Proteins 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 238
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 120
- 239000000975 dye Substances 0.000 description 108
- 239000008273 gelatin Substances 0.000 description 105
- 229920000159 gelatin Polymers 0.000 description 105
- 108010010803 Gelatin Proteins 0.000 description 104
- 235000019322 gelatine Nutrition 0.000 description 104
- 235000011852 gelatine desserts Nutrition 0.000 description 104
- 238000000034 method Methods 0.000 description 102
- 239000010410 layer Substances 0.000 description 96
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 64
- 238000011161 development Methods 0.000 description 63
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 61
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 60
- 150000003839 salts Chemical group 0.000 description 59
- 125000003277 amino group Chemical group 0.000 description 57
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 54
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 53
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 51
- 230000015572 biosynthetic process Effects 0.000 description 50
- 238000002360 preparation method Methods 0.000 description 42
- 238000005406 washing Methods 0.000 description 42
- 238000003786 synthesis reaction Methods 0.000 description 40
- 206010070834 Sensitisation Diseases 0.000 description 38
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 37
- 230000008313 sensitization Effects 0.000 description 37
- 125000005420 sulfonamido group Chemical group S(=O)(=O)(N*)* 0.000 description 36
- 239000013078 crystal Substances 0.000 description 35
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 34
- 125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 description 33
- 239000011780 sodium chloride Substances 0.000 description 33
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 32
- 125000004414 alkyl thio group Chemical group 0.000 description 31
- 125000004104 aryloxy group Chemical group 0.000 description 31
- 239000002253 acid Substances 0.000 description 30
- 239000000126 substance Substances 0.000 description 29
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 28
- 239000007864 aqueous solution Substances 0.000 description 28
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 28
- 125000002252 acyl group Chemical group 0.000 description 27
- 125000003396 thiol group Chemical group [H]S* 0.000 description 27
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 25
- 239000004094 surface-active agent Substances 0.000 description 25
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 24
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 description 24
- 239000000460 chlorine Substances 0.000 description 24
- 238000001914 filtration Methods 0.000 description 24
- 230000002829 reductive effect Effects 0.000 description 24
- 229910052717 sulfur Inorganic materials 0.000 description 24
- 229910001961 silver nitrate Inorganic materials 0.000 description 23
- 125000003282 alkyl amino group Chemical group 0.000 description 22
- 238000000576 coating method Methods 0.000 description 22
- 230000001235 sensitizing effect Effects 0.000 description 22
- 239000002245 particle Substances 0.000 description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 20
- 235000011121 sodium hydroxide Nutrition 0.000 description 20
- 239000002904 solvent Substances 0.000 description 20
- 238000003756 stirring Methods 0.000 description 20
- 235000010323 ascorbic acid Nutrition 0.000 description 19
- 150000001721 carbon Chemical group 0.000 description 19
- 239000011248 coating agent Substances 0.000 description 19
- 229920000642 polymer Polymers 0.000 description 19
- 239000007787 solid Substances 0.000 description 19
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 18
- 125000005110 aryl thio group Chemical group 0.000 description 18
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 18
- 125000005843 halogen group Chemical group 0.000 description 18
- 230000006641 stabilisation Effects 0.000 description 18
- 238000011105 stabilization Methods 0.000 description 18
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 17
- 229960000583 acetic acid Drugs 0.000 description 17
- 125000004423 acyloxy group Chemical group 0.000 description 17
- 229960005070 ascorbic acid Drugs 0.000 description 17
- 239000011668 ascorbic acid Substances 0.000 description 17
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 17
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 16
- 235000011054 acetic acid Nutrition 0.000 description 16
- 125000004442 acylamino group Chemical group 0.000 description 16
- 125000002947 alkylene group Chemical group 0.000 description 16
- 239000004816 latex Substances 0.000 description 16
- 229920000126 latex Polymers 0.000 description 16
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 15
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 15
- 238000001035 drying Methods 0.000 description 15
- 125000005647 linker group Chemical group 0.000 description 15
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 15
- SJOOOZPMQAWAOP-UHFFFAOYSA-N [Ag].BrCl Chemical compound [Ag].BrCl SJOOOZPMQAWAOP-UHFFFAOYSA-N 0.000 description 14
- 150000001450 anions Chemical class 0.000 description 14
- 229910052736 halogen Inorganic materials 0.000 description 14
- 239000003446 ligand Substances 0.000 description 14
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 14
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 14
- 230000035945 sensitivity Effects 0.000 description 14
- 125000004434 sulfur atom Chemical group 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
- 239000002585 base Substances 0.000 description 13
- 239000006185 dispersion Substances 0.000 description 13
- 239000000417 fungicide Substances 0.000 description 13
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 12
- 125000000732 arylene group Chemical group 0.000 description 12
- 125000000717 hydrazino group Chemical group [H]N([*])N([H])[H] 0.000 description 12
- XTEGVFVZDVNBPF-UHFFFAOYSA-N naphthalene-1,5-disulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1S(O)(=O)=O XTEGVFVZDVNBPF-UHFFFAOYSA-N 0.000 description 12
- 238000010992 reflux Methods 0.000 description 12
- ZFIQGRISGKSVAG-UHFFFAOYSA-N 4-methylaminophenol Chemical compound CNC1=CC=C(O)C=C1 ZFIQGRISGKSVAG-UHFFFAOYSA-N 0.000 description 11
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 11
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 11
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 11
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 11
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 11
- 239000000654 additive Substances 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 11
- 125000004093 cyano group Chemical group *C#N 0.000 description 11
- 230000000694 effects Effects 0.000 description 11
- 150000002148 esters Chemical group 0.000 description 11
- 230000000855 fungicidal effect Effects 0.000 description 11
- 239000011259 mixed solution Substances 0.000 description 11
- 239000011241 protective layer Substances 0.000 description 11
- 239000010948 rhodium Substances 0.000 description 11
- 229920006395 saturated elastomer Polymers 0.000 description 11
- 229910052711 selenium Inorganic materials 0.000 description 11
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 11
- 235000019345 sodium thiosulphate Nutrition 0.000 description 11
- 239000011593 sulfur Substances 0.000 description 11
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 10
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 10
- 229940113088 dimethylacetamide Drugs 0.000 description 10
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 10
- 238000011156 evaluation Methods 0.000 description 10
- 229910052731 fluorine Inorganic materials 0.000 description 10
- 150000002367 halogens Chemical class 0.000 description 10
- 150000002429 hydrazines Chemical class 0.000 description 10
- 125000001624 naphthyl group Chemical group 0.000 description 10
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 10
- 125000005740 oxycarbonyl group Chemical group [*:1]OC([*:2])=O 0.000 description 10
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 10
- 229920000120 polyethyl acrylate Polymers 0.000 description 10
- 230000005070 ripening Effects 0.000 description 10
- 239000011669 selenium Substances 0.000 description 10
- 229940006186 sodium polystyrene sulfonate Drugs 0.000 description 10
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 10
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 10
- MEKOFIRRDATTAG-UHFFFAOYSA-N 2,2,5,8-tetramethyl-3,4-dihydrochromen-6-ol Chemical compound C1CC(C)(C)OC2=C1C(C)=C(O)C=C2C MEKOFIRRDATTAG-UHFFFAOYSA-N 0.000 description 9
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 9
- 125000004453 alkoxycarbonyl group Chemical group 0.000 description 9
- 125000001769 aryl amino group Chemical group 0.000 description 9
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 9
- 239000002738 chelating agent Substances 0.000 description 9
- 230000001276 controlling effect Effects 0.000 description 9
- 125000006165 cyclic alkyl group Chemical group 0.000 description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 9
- 230000000977 initiatory effect Effects 0.000 description 9
- 125000002950 monocyclic group Chemical group 0.000 description 9
- 230000008569 process Effects 0.000 description 9
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 9
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 description 9
- 239000003381 stabilizer Substances 0.000 description 9
- 125000004149 thio group Chemical group *S* 0.000 description 9
- KDCGOANMDULRCW-UHFFFAOYSA-N 7H-purine Chemical compound N1=CNC2=NC=NC2=C1 KDCGOANMDULRCW-UHFFFAOYSA-N 0.000 description 8
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 8
- 125000005161 aryl oxy carbonyl group Chemical group 0.000 description 8
- 125000000656 azaniumyl group Chemical group [H][N+]([H])([H])[*] 0.000 description 8
- JEHKKBHWRAXMCH-UHFFFAOYSA-N benzenesulfinic acid Chemical compound O[S@@](=O)C1=CC=CC=C1 JEHKKBHWRAXMCH-UHFFFAOYSA-N 0.000 description 8
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 8
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 8
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 8
- 239000004327 boric acid Substances 0.000 description 8
- 235000010338 boric acid Nutrition 0.000 description 8
- 125000004122 cyclic group Chemical group 0.000 description 8
- 238000009472 formulation Methods 0.000 description 8
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 8
- 229910052737 gold Inorganic materials 0.000 description 8
- 239000010931 gold Substances 0.000 description 8
- 125000002883 imidazolyl group Chemical group 0.000 description 8
- 239000003112 inhibitor Substances 0.000 description 8
- 239000006224 matting agent Substances 0.000 description 8
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 8
- 229920000139 polyethylene terephthalate Polymers 0.000 description 8
- 239000005020 polyethylene terephthalate Substances 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 125000004076 pyridyl group Chemical group 0.000 description 8
- 238000011160 research Methods 0.000 description 8
- 125000000475 sulfinyl group Chemical group [*:2]S([*:1])=O 0.000 description 8
- 238000011282 treatment Methods 0.000 description 8
- PLFFHJWXOGYWPR-HEDMGYOXSA-N (4r)-4-[(3r,3as,5ar,5br,7as,11as,11br,13ar,13bs)-5a,5b,8,8,11a,13b-hexamethyl-1,2,3,3a,4,5,6,7,7a,9,10,11,11b,12,13,13a-hexadecahydrocyclopenta[a]chrysen-3-yl]pentan-1-ol Chemical compound C([C@]1(C)[C@H]2CC[C@H]34)CCC(C)(C)[C@@H]1CC[C@@]2(C)[C@]4(C)CC[C@@H]1[C@]3(C)CC[C@@H]1[C@@H](CCCO)C PLFFHJWXOGYWPR-HEDMGYOXSA-N 0.000 description 7
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 7
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
- INVVMIXYILXINW-UHFFFAOYSA-N 5-methyl-1h-[1,2,4]triazolo[1,5-a]pyrimidin-7-one Chemical compound CC1=CC(=O)N2NC=NC2=N1 INVVMIXYILXINW-UHFFFAOYSA-N 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 7
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 7
- 125000001931 aliphatic group Chemical group 0.000 description 7
- 150000001412 amines Chemical class 0.000 description 7
- 230000002421 anti-septic effect Effects 0.000 description 7
- 229910052801 chlorine Inorganic materials 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 7
- 239000010419 fine particle Substances 0.000 description 7
- 239000011737 fluorine Substances 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 7
- 239000004926 polymethyl methacrylate Substances 0.000 description 7
- 229910000027 potassium carbonate Inorganic materials 0.000 description 7
- 150000003284 rhodium compounds Chemical class 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 229910052938 sodium sulfate Inorganic materials 0.000 description 7
- 235000011152 sodium sulphate Nutrition 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- 101710134784 Agnoprotein Proteins 0.000 description 6
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 6
- SIKJAQJRHWYJAI-UHFFFAOYSA-N Indole Chemical compound C1=CC=C2NC=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-N 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 239000002202 Polyethylene glycol Substances 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- UMGDCJDMYOKAJW-UHFFFAOYSA-N aminothiocarboxamide Natural products NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 6
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 6
- 125000000129 anionic group Chemical group 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- XSCHRSMBECNVNS-UHFFFAOYSA-N benzopyrazine Natural products N1=CC=NC2=CC=CC=C21 XSCHRSMBECNVNS-UHFFFAOYSA-N 0.000 description 6
- 239000000872 buffer Substances 0.000 description 6
- 235000015165 citric acid Nutrition 0.000 description 6
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- LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 description 1
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- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
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- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
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- AUPJTDWZPFFCCP-GMFCBQQYSA-M sodium;2-[methyl-[(z)-octadec-9-enyl]amino]ethanesulfonate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCCN(C)CCS([O-])(=O)=O AUPJTDWZPFFCCP-GMFCBQQYSA-M 0.000 description 1
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- UOULCEYHQNCFFH-UHFFFAOYSA-M sodium;hydroxymethanesulfonate Chemical compound [Na+].OCS([O-])(=O)=O UOULCEYHQNCFFH-UHFFFAOYSA-M 0.000 description 1
- HVZAHYYZHWUHKO-UHFFFAOYSA-M sodium;oxido-phenyl-sulfanylidene-$l^{4}-sulfane Chemical compound [Na+].[O-]S(=S)C1=CC=CC=C1 HVZAHYYZHWUHKO-UHFFFAOYSA-M 0.000 description 1
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- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
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- 229960004793 sucrose Drugs 0.000 description 1
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- 238000010189 synthetic method Methods 0.000 description 1
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- 150000003498 tellurium compounds Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- AWDBHOZBRXWRKS-UHFFFAOYSA-N tetrapotassium;iron(6+);hexacyanide Chemical compound [K+].[K+].[K+].[K+].[Fe+6].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] AWDBHOZBRXWRKS-UHFFFAOYSA-N 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 150000003536 tetrazoles Chemical class 0.000 description 1
- 150000003475 thallium Chemical class 0.000 description 1
- JJJPTTANZGDADF-UHFFFAOYSA-N thiadiazole-4-thiol Chemical class SC1=CSN=N1 JJJPTTANZGDADF-UHFFFAOYSA-N 0.000 description 1
- 150000004867 thiadiazoles Chemical group 0.000 description 1
- 125000001113 thiadiazolyl group Chemical group 0.000 description 1
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- 125000001544 thienyl group Chemical group 0.000 description 1
- 125000001391 thioamide group Chemical group 0.000 description 1
- 125000005323 thioketone group Chemical group 0.000 description 1
- BRNULMACUQOKMR-UHFFFAOYSA-N thiomorpholine Chemical compound C1CSCCN1 BRNULMACUQOKMR-UHFFFAOYSA-N 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- AIDFGYMTQWWVES-UHFFFAOYSA-K triazanium;iridium(3+);hexachloride Chemical compound [NH4+].[NH4+].[NH4+].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Ir+3] AIDFGYMTQWWVES-UHFFFAOYSA-K 0.000 description 1
- CDMIYIVDILNBIJ-UHFFFAOYSA-N triazinane-4,5,6-trithione Chemical compound SC1=NN=NC(S)=C1S CDMIYIVDILNBIJ-UHFFFAOYSA-N 0.000 description 1
- ZMANZCXQSJIPKH-UHFFFAOYSA-O triethylammonium ion Chemical compound CC[NH+](CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-O 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- ZFVJLNKVUKIPPI-UHFFFAOYSA-N triphenyl(selanylidene)-$l^{5}-phosphane Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)(=[Se])C1=CC=CC=C1 ZFVJLNKVUKIPPI-UHFFFAOYSA-N 0.000 description 1
- 125000005580 triphenylene group Chemical group 0.000 description 1
- NZKWZUOYGAKOQC-UHFFFAOYSA-H tripotassium;hexachloroiridium(3-) Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[K+].[K+].[K+].[Ir+3] NZKWZUOYGAKOQC-UHFFFAOYSA-H 0.000 description 1
- OTOHACXAQUCHJO-UHFFFAOYSA-H tripotassium;hexachlororhodium(3-) Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[K+].[K+].[K+].[Rh+3] OTOHACXAQUCHJO-UHFFFAOYSA-H 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- WBPYTXDJUQJLPQ-LLMNDNAOSA-N tylosin Chemical compound O=CCC1CC(C)C(=O)\C=C\C(\C)=C\C(COC2C(C(OC)C(O)C(C)O2)OC)C(CC)OC(=O)CC(O)C(C)C1OC(C(C1N(C)C)O)OC(C)C1OC1CC(C)(O)C(O)C(C)O1 WBPYTXDJUQJLPQ-LLMNDNAOSA-N 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N urethane group Chemical group NC(=O)OCC JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/26—Processes using silver-salt-containing photosensitive materials or agents therefor
- G03C5/29—Development processes or agents therefor
- G03C5/30—Developers
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/061—Hydrazine compounds
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/34—Fog-inhibitors; Stabilisers; Agents inhibiting latent image regression
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/26—Processes using silver-salt-containing photosensitive materials or agents therefor
- G03C5/29—Development processes or agents therefor
- G03C5/30—Developers
- G03C2005/3007—Ascorbic acid
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/26—Processes using silver-salt-containing photosensitive materials or agents therefor
- G03C5/29—Development processes or agents therefor
- G03C5/305—Additives other than developers
Abstract
Description
__________________________________________________________________________ #STR7## No. R.sub.1 R.sub.2 R.sub.3 __________________________________________________________________________ A-1 --H --H --CH.sub.3 A-2 --OCH.sub.3 " " A-3 " --OCH.sub.3 " A-4 --NHCOCH.sub.3 --H " A-5 " --NHCOCH.sub.3 " A-6 --NHCONHCH.sub.3 --H " A-7 " --NHCONHCH.sub.3 " A-8 --NHCONH.sub.2 --H " A-9 " --NHCONH.sub.2 " A-10 --NHSO.sub.2 CH.sub.3 --H " A-11 " --NHSO.sub.2 CH.sub.3 " A-12 --OH --H " __________________________________________________________________________ #STR8## - No. R.sub.1 R.sub.2 __________________________________________________________________________ A-13 --NH.sub.2 --CH.sub.3 A-14 --NHSO.sub.2 NH.sub.2 " A-15 --NHCH.sub.3 " - A-16 " TR9## - A-17 --CH.sub.3 " - A-18 " TR10## - A-19 --H --C.sub.2 H.sub.5 A-20 --OCH.sub.3 " A-21 --NHCOCH.sub.3 " A-22 --NHCONH.sub.2 " A-23 --NHCSNH.sub.2 --CH.sub.3 A-24 --OCH.sub.2 CH.sub.2 NHSO.sub.2 CH.sub.3 --C.sub.2 H.sub.5 __________________________________________________________________________ #STR11## - No. R.sub.1 R.sub.2 R.sub.3 __________________________________________________________________________ A-25 --CH.sub.3 --H #STR12## - A-26 --OCH.sub.3 " " A-27 " --OCH.sub.3 " A-28 --NHCOCH.sub.3 --H " A-29 " --NHCOCH.sub.3 " A-30 --NHCONH.sub.2 --H " A-31 " --NHCONH.sub.2 " A-32 --NHCONHCH.sub.3 --H " A-33 --NHSO.sub.2 CH.sub.3 " " - A-34 " " #STR13## - A-35 --NHCONHCH.sub.3 " " A-36 --NHCONH.sub.2 " " __________________________________________________________________________ #STR14## - No. R.sub.1 R.sub.2 R.sub.3 R.sub.4 R.sub.5 __________________________________________________________________________ A-37 --NHCOCH.sub.3 --H --H #STR15## #STR16## - A-38 --OCH.sub.3 " " " " A-39 " --OCH.sub.3 " " " A-40 --H --H " " " A-41 " " --CH.sub.3 " " - A-42 " " --H --CH.sub.3 #STR17## - A-43 --OCH.sub.3 " " " " A-44 --NHCOCH.sub.3 " " " " A-45 --NHCONH.sub.2 " " " " A-46 --NHSO.sub.2 CH.sub.3 " " " " A-47 --NHCONHCH.sub.3 " " " " - A-48 " " 18## #STR19## #STR20## __________________________________________________________________________ #STR21## - No. R.sub.1 R.sub.2 __________________________________________________________________________ A-49 --CH.sub.3 #STR22## - A-50 #STR23## #STR24## - A-51 #STR25## #STR26## - A-52 #STR27## #STR28## - A-53 --CH.sub.3 #STR29## - A-54 #STR30## #STR31## __________________________________________________________________________ #STR32## - No. R.sub.1 R.sub.2 X __________________________________________________________________________ A-55 --H --H #STR33## - A-56 --OCH.sub.3 " " - A-57 " --OCH.sub.3 " - A-58 --NHCONH.sub.2 --H " A-59 --NHCONHCH.sub.3 " " - A-60 --NHCOCH.sub.3 --H #STR34## - A-61 --NHSO.sub.2 CH.sub.3 " #STR35## - A-62 --H " #STR36## - A-63 --OCH.sub.3 " " - A-64 " --OCH.sub.3 " - A-65 --NHCONH.sub.2 --H #STR37## - A-66 --NHSO.sub.2 CH.sub.3 " #STR38## - A-67 --H " #STR39## - A-68 --OCH.sub.3 " " A-69 " --OCH.sub.3 " A-70 --NHCONHCH.sub.3 --H " - A-71 --NHSO.sub.2 CH.sub.3 " #STR40## __________________________________________________________________________ #STR41## - No. R.sub.1 X __________________________________________________________________________ A-72 --H #STR42## - A-73 --OCH.sub.3 " A-74 --NHCONH.sub.2 " A-75 --NHSO.sub.2 CH.sub.3 " - A-76 --H #STR43## - A-77 --OCH.sub.3 " __________________________________________________________________________ #STR44## - No. R.sub.1 R.sub.2 R.sub.3 __________________________________________________________________________ A-78 --H --H #STR45## - A-79 --OCH.sub.3 " " A-80 --NHCONH.sub.2 " " - A-81 --NHSO.sub.2 CH.sub.3 " #STR46## - A-82 --OCH.sub.3 --OCH.sub.3 #STR47## __________________________________________________________________________ #STR48## - No. R.sub.1 R.sub.2 __________________________________________________________________________ A-83 --H #STR49## - A-84 --OCH.sub.3 " - A-85 --H #STR50## - A-86 --OCH.sub.3 " - A-87 --H #STR51## - A-88 --H #STR52## - A-89 " TR53## - A-90 " TR54## - A-91 --CO.sub.2 H --CH.sub.3 A-92 #STR55## - A-93 #STR56## - A-94 #STR57## - A-95 #STR58## - A-96 #STR59## - A-97 #STR60## - A-98 #STR61## - A-99 #STR62## - A-100 #STR63## - A-101 #STR64## __________________________________________________________________________ #STR65## - No. R.sub.1 R.sub.2 __________________________________________________________________________ A-103 --OCH.sub.3 --CH.sub.3 - A-104 --H #STR66## - A-105 " #STR67## __________________________________________________________________________ #STR68## - No. R.sub.1 R.sub.2 R.sub.3 __________________________________________________________________________ A-106 --SH #STR69## #STR70## - A-107 --SCH.sub.3 --CH.sub.3 --CH.sub.3 - A-108 --COOCH.sub.3 #STR71## #STR72## - A-109 --CONH.sub.2 " TR73## - A-110 --CH.sub.3 --CH.sub.3 - A-111 --CH.sub.2 OH " " - A-112 " " 75## - A-113 --H #STR76## #STR77## - A-114 --OCH.sub.3 " " - A-115 --CH.sub.3 --CH.sub.3 - A-116 " " 79## - A-117 " "R80## __________________________________________________________________________ #STR81## - No. R.sub.1 R.sub.2 R.sub.3 R.sub.4 R.sub.5 R.sub.6 __________________________________________________________________________ A-118 H H H --CH.sub.3 --CH.sub.3 - A-119 " " " " " - A-120 " " " " " - A-121 " " " " " - A-122 " " " " " - A-123 " " " " " - A-124 " " " " " - A-125 --OC.sub.2 H.sub.5 " " " " " - A-126 " " " " " - A-127 --C.sub.2 H.sub.4 OH " " " " " A-128 --Cl " " " " " A-129 --COCH.sub.3 " " " " " A-130 --SO.sub.3 Na H H H --CH.sub.3 --CH.sub.3 A-131 --COOH H H H " " A-132 --CH.sub.2 OH --CH.sub.2 OH H H " " A-133 --CH.sub.3 --CH.sub.3 --CH.sub.3 --CH.sub.3 --C.sub.2 H.sub.4 OH --C.sub.2 H.sub.4 OH - A-134 H H H ## --CH.sub.3 - A-135 " " " --C.sub.2 H.sub.4 OH " - A-136 " " " --CH.sub.3 " - A-136 " " " --CH.sub.2 C.tbd.CH " - A-137 H " " --CH.sub.2 CH═CH.s ub.2 --CH.sub.3 A-138 #STR96## - A-139 #STR97## __________________________________________________________________________
__________________________________________________________________________ #STR102## No. R.sub.1 R.sub.2 R.sub.3 __________________________________________________________________________ A'-1 --OCH.sub.2 CH.sub.2 OH --H --CH.sub.3 A'-2 --OCH.sub.2 CH.sub.2 OCH.sub.3 " " A'-3 --OCH.sub.3 --OCH.sub.3 " A'-4 --NHCOCH.sub.3 --H " A'-5 --CH.sub.2 OH --H " A'-6 --NHCONHCH.sub.3 --H " A'-7 --CH.sub.2 OH --CH.sub.2 OH " A'-8 --NHCONH.sub.2 --H " - A'-9 --H " 3## - A'-10 --NHSO.sub.2 CH.sub.3 --H " - A'-11 --H " 4## - A'-12 --OCH.sub.3 --H " __________________________________________________________________________ #STR105## - No. R.sub.1 R.sub.2 __________________________________________________________________________ A'-13 --CH.sub.3 - A'-14 --NHSO.sub.2 NH.sub.2 " - A'-15 " TR107## - A'-16 " TR108## - A'-17 --CH.sub.3 " - A'-18 " TR109## - A'-19 --OCH.sub.2 CH.sub.2 OH --C.sub.2 H.sub.5 A'-20 --OCH.sub.2 CH.sub.2 CH.sub.3 " - A'-21 --CH.sub.3 - A'-22 --Cl --CH.sub.3 A'-23 --NHCSNH.sub.2 --CH.sub.3 A'-24 --OCH.sub.2 CH.sub.2 NHSO.sub.2 CH.sub.2 --C.sub.2 H.sub.5 __________________________________________________________________________ #STR111## - No. R.sub.1 R.sub.2 R.sub.3 __________________________________________________________________________ A'-25 --OCH.sub.2 CH.sub.2 OH --H #STR112## - A'-26 --OCH.sub.2 CH.sub.2 OCH.sub.3 " " A'-27 --OCH.sub.3 H " A'-28 --NHCOCH.sub.3 --H " - A'-29 --CH.sub.2 OH --CH.sub.2 OH #STR113## - A'-30 --NHCONH.sub.2 --H " - A'-31 --OCH.sub.3 --H #STR114## - A'-32 --NHCONHCH.sub.3 --H " A'-33 --NHSO.sub.2 CH.sub.3 " " - A'-34 " " #STR115## - A'-35 --OC.sub.2 H.sub.5 " " A'-36 --SCH.sub.3 " " - A'-37 --NHCOCH.sub.3 --H #STR116## - A'-38 --OCH.sub.2 CH.sub.2 OH " " - A'-39 --OCH.sub.3 --OCH.sub.3 " A'-40 --OCH.sub.2 CH.sub.2 OCH.sub.3 --H " A'-41 --COCH.sub.3 " --CH.sub.3 A'-42 --OCH.sub.2 CH.sub.2 CH.sub.2 OH " --CH.sub.3 A'-43 --CH.sub.2 COOH " " - A'-44 " " 117## - A'-45 " " 118## - A'-46 --COOH " " - A'-47 --SO.sub.3 Na " " - A'-48 " TR119## #STR120## __________________________________________________________________________ #STR121## - No. R.sub.1 __________________________________________________________________________ A'-49 #STR122## - A'-50 #STR123## - A'-51 #STR124## - A'-52 #STR125## - A'-53 #STR126## - A'-54 #STR127## - A'-55 #STR128## - A'-56 #STR129## - A'-57 --C.sub.6 H.sub.5 - A'-58 #STR130## - A'-59 #STR131## - A'-60 #STR132## - A'-61 #STR133## - A'-62 #STR134## - A'-63 #STR135## - A'-64 #STR136## __________________________________________________________________________ #STR137## - No. R.sub.1 R.sub.2 __________________________________________________________________________ A'-65 --OCH.sub.3 --H A'-66 --OC.sub.2 H.sub.5 " A'-67 --OCH.sub.2 CH.sub.2 CH.sub.2 OCH.sub.3 " - A'-68 " TR138## - A'-69 " TR139## - A'-70 " TR140## - A'-71 " TR141## - A'-72 " TR142## - A'-73 --OCH.sub.3 --OCH.sub.3 A'-74 --NHCONH.sub.2 --H A'-75 --NHCONHCH.sub.3 " A'-76 --NHCOCH.sub.3 " A'-77 --NHSO.sub.2 CH.sub.3 --H A'-78 --NHSO.sub.2 NH.sub.2 " A'-79 --NHCSNH.sub.2 " A'-80 --OH " A'-81 --NH.sub.2 " A'-82 --NHCH.sub.3 " A'-83 --SC.sub.2 H.sub.4 OH " A'-84 --CH.sub.3 " A'-85 --C.sub.2 H.sub.5 " - A'-86 --H 143## - A'-87 --CH.sub.2 OH " A'-88 --CH.sub.2 CH.sub.2 OH " A'-89 H H - A'-90 --H 144## - A'-91 --OCH.sub.2 CH.sub.2 OH " A'-92 --CH.sub.3 --CH.sub.3 A'-93 --CH.sub.2 OH --CH.sub.2 OH A'-94 --OCH.sub.2 CH.sub.2 NHSO.sub.2 CH.sub.3 H A'-95 --Cl H A'-96 --OCH.sub.2 CH.sub.2 OCH.sub.3 --H A'-97 --OCH.sub.2 CO.sub.2 H " A'-98 --COCH.sub.3 " A'-99 --CONH.sub.2 " A'-100 --CO.sub.2 H " A'-101 --NHCONH.sub.2 --NHCONH.sub.2 A'-102 --NHCONHCH.sub.3 --NHCONHCH.sub.3 A'-103 --NHSO.sub.2 NHCH.sub.3 --H - A'-104 " TR145## - A'-105 " TR146## - A'-106 " TR147## - A'-107 " TR148## - A'-108 " TR149## A'-109 #STR150## - A'-110 #STR151## - A'-111 #STR152## - A'-112 #STR153## - A'-113 #STR154## - A'-114 #STR155## - A'-115 #STR156## - A'-116 #STR157## - A'-117 #STR158## - A'-118 #STR159## - A'-119 #STR160## - A'-120 #STR161## - A'-121 #STR162## - A'-122 #STR163## - A'-123 #STR164## - A'-124 #STR165## - A'-125 #STR166## - A'-126 #STR167## - A'-127 #STR168## - A'-128 #STR169## __________________________________________________________________________
______________________________________ AP-1 N-Methyl-p-aminophenol AP-2 p-Aminophenol AP-3 N-(β-Hydroxyethyl)-p-aminophenol AP-4 N-(4-Hydroxyphenyl)glycine AP-5 2-Methyl-p-aminophenol AP-6 p-Benzylaminophenol AP-7 2-Methoxy-p-aminophenol P-1 1-Phenyl-3-pyrazolidone P-2 1-Phenyl-4,4-dimethyl-3-pyrazolidone P-3 1-Phenyl-4-methyl-4-hydroxymethyl-3-pyrazolidone P-4 1-Phenyl-4,4-dihydroxymethyl-3-pyrazolidone P-5 1-Phenyl-5-methyl-3-pyrazolidone P-6 1-p-Aminophenyl-4,4-dimethyl-3-pyrazolidone P-7 1-p-Tolyl-4,4-dimethyl-3-pyrazolidone P-8 1-p-Tolyl-4-methyl-4-hydroxymethyl-3-pyrazolidone ______________________________________
- ##STR192## R = X = --H --C.sub.2 F.sub.4 --COOH (or --C.sub.2 F.sub.4 --COO.sup.⊖ K.sup.⊕) ##STR193## ##STR194## D-1 3-NHCOC.sub.9 H.sub.19 (n) 1a 1b 1c 1d D-2 ##STR195## 2a 2b 2c 2d D-3 ##STR196## 3a 3b 3c 3d D-4 ##STR197## 4a 4b 4c 4d D-5 ##STR198## 5a 5b 5c 5d D-6 ##STR199## 6a 6b 6c 6d D-7 2,4-(CH.sub.3).sub.2 -3-SC.sub.2 H.sub.4 --(OC.sub.2 H.sub.4).sub.4 --OC.sub.8 H.sub.17 7a 7b 7c 7d ##STR200## R = X = --H --CF.sub.2 H ##STR201## ##STR202## D-8 ##STR203## 8a 8e 8f 8g D-9 6-OCH.sub.3 -3-C.sub.5 H.sub.11 (t) 9a 9e 9f 9g D-10 ##STR204## 10a 10e 10f 10g D-11 ##STR205## 11a 11e 11f 11g D-12 ##STR206## 12a 12e 13f 13g D-13 ##STR207## 13a 13e 13f 13g D-14 ##STR208## 14a 14e 14f 14g ##STR209## X = Y = --CHO --COCF.sub.3 --SO.sub.2 CH.sub.3 ##STR210## D-15 ##STR211## 15a 15h 15i 15j D-16 ##STR212## 16a 16h 16i 16j D-17 ##STR213## 17a 17h 17i 17j D-18 ##STR214## 18a 18h 18i 18j D-19 ##STR215## 19a 19h 19i 19j D-20 3-NHSO.sub.2 NH--C.sub.8 H.sub.17 20a 20h 20i 20j D-21 ##STR216## 21a 21h 21i 21j R = --H --CF.sub.2 H ##STR217## --CONHC.sub.3 H.sub.7 D-22 ##STR218## 22a 22e 22k 22l D-23 ##STR219## 23a 23e 23k 23l D-24 ##STR220## 24a 24e 24k 24l D-25 ##STR221## 25a 25e 25k 25l D-26 ##STR222## 26a 26e 26k 26l D-27 ##STR223## 27a 27e 27k 27l D-28 ##STR224## 28a 28e 28k 28l ##STR225## R = Y = --H --CH.sub.2 OCH.sub.3 ##STR226## ##STR227## D-29 ##STR228## 29a 29m 29n 29f D-30 ##STR229## 30a 30m 30n 30f D-31 ##STR230## 31a 31m 31n 31f D-32 ##STR231## 32a 32m 32n 32f D-33 ##STR232## 33a 33m 33n 33f D-34 ##STR233## 34a 34m 34n 34f D-35 ##STR234## 35a 35m 35n 35f ##STR235## R = Y = --H --C.sub.3 H.sub.6 --COOH --CONHCH.sub.3 ##STR236## D-36 ##STR237## 36a 36o 36p 36q D-37 2-OCH.sub.3 -4-NHSO.sub.2 C.sub.12 H.sub.25 37a 37o 37p 37q D-38 3-NHCOC.sub.11 H.sub.23 -4-NHSO.sub.2 CF.sub.3 38a 38o 38p 38q D-39 ##STR238## 39a 39o 39p 39q D-40 4-OCO(CH.sub.2).sub.2 COOC.sub.6 H.sub.13 40a 40o 40p 40q D-41 ##STR239## 41a 41o 41p 41q D-42 ##STR240## 42a 42o 42p 42q D-43 ##STR241## D-44 ##STR242## D-45 ##STR243## D-46 ##STR244## D-47 ##STR245## D-48 ##STR246## D-49 ##STR247## D-50 ##STR248## D-51 ##STR249## D-52 ##STR250## D-53 ##STR251##
A--(B).sub.m (X)
- R = --H --CF.sub.3 ##STR253## ##STR254## 1 ##STR255## 1a' 1c' 1k' 1l' 2 ##STR256## 2a' 2c' 2k' 2l' 3 ##STR257## 3a' 3c' 3k' 3l' ##STR258## R = --H --CF.sub.2 H --CF.sub.3 --CF.sub.2 SCH.sub.3 4 ##STR259## 4a' 4e' 4c' 4r' 5 ##STR260## 5a' 5e' 5c' 5r' 6 ##STR261## 6a' 6e' 6c' 6r' 7 ##STR262## 7a' 7e' 7c' 7r' 8 8a' 8e' 8c' 8r' ##STR263## ##STR264## R = --H --CF.sub.2 H --CONHCH.sub.3 --CF.sub.2 OCH.sub.3 9 ##STR265## 9a' 9e' 9p' 9b' 10 ##STR266## 10a' 10e' 10p' 10b' R = --H --CF.sub.2 H ##STR267## ##STR268## 11 ##STR269## 11a' 11e' 11f' 11g' ##STR270## R = --H --CF.sub.2 H ##STR271## ##STR272## 12 ##STR273## 12a' 12e' 12s' 12g' 13 ##STR274## 13a' 13e' 13s' 13g' 14 ##STR275## 14a' 14e' 14s' 14g' 15 ##STR276## 15a' 15e' 15s' 15g' ##STR277## R = --H --CF.sub.2 H ##STR278## ##STR279## 16 ##STR280## 16a' 16e' 16s' 16g' 17 ##STR281## 17a' 17e' 17s' 17g' 18' ##STR282## 19' ##STR283## 20' ##STR284## 21' ##STR285## 22' ##STR286## ##STR287## R = --H --CF.sub.3 --CF.sub.2 H ##STR288## ##STR289## 23 ##STR290## 23a' 23c' 23e' 23g' 23d' 24 ##STR291## 24a' 24c' 24e' 24g' 24d' 25 ##STR292## 25a' 25c' 25e' 25g' 25d' 26 ##STR293## 26a' 26c' 26e' 26g' 26d' ##STR294## R = --H --CF.sub.3 --CF.sub.2 H --CONHCH.sub.3 ##STR295## --C.sub.2 F.sub.4 COOH 27 ##STR296## 27a' 27c' 27e' 27p' 27f' 27t' 28 ##STR297## 28a' 28c' 28e' 28p' 28f' 28t' 29 29a' 29c' 29e' 29p' 29f' 29t' ##STR298## 30 ##STR299## 30a' 30c' 30e' 30p' 30f' 30t' ##STR300## R = --H --CF.sub.3 ##STR301## ##STR302## 31 ##STR303## 31a' 31c' 31h' 31m' 32 ##STR304## 32a' 32c' 32h' 32m' 33 ##STR305## 33a' 33c' 33h' 33m' 34 ##STR306## 34a' 34c' 34h' 34m' 35 ##STR307## 35a' 35c' 35h' 35m' R = --H ##STR308## --CH.sub.2 OCH.sub.3 ##STR309## 36 ##STR310## 36a' 36n' 36i' 36j' 37 ##STR311## 37a' 37n' 37i' 37j' 38 38a' 38n' 38i' 38j' ##STR312## 39 ##STR313## 39a' 39n' 39i' 39j' 40 40a' 40n' 40i' 40j' ##STR314## R = --H ##STR315## --CF.sub.3 ##STR316## 41 ##STR317## 41a' 41q' 41c' 41u' 42 ##STR318## 42a' 42q' 42c' 42u' 43 ##STR319## 43a' 43q' 43c' 43u' 44 ##STR320## 44a' 44q' 44c' 44u' 45 45a' 45q' 45c' 45u' ##STR321##
______________________________________ Gelatin 3 g/m.sup.2 Latex: polyethyl acrylate 2 g/m.sup.2 Surface active agent: 40 mg/m.sup.2 Sodium p-dodecylbenzenesulfonate Compound (B) 110 mg/m.sup.2 SnO.sub.2 /Sb (weight ratio: 90/10, 200 mg/m.sup.2 average particle size: 0.20 μm) Dye: Mixture of Dye (a), Dye (b) and Dye (c) Dye (a) 70 mg/m.sup.2 Dye (b) 100 mg/m.sup.2 Dye (c) 50 mg/m.sup.2 ______________________________________ Dye (a) - #STR333## - Dye (b) - #STR334## - Dye (c) - #STR335## (Back Protective Layer)
______________________________________ Gelatin 0.8 mg/m.sup.2 Polymethyl methacrylate fine particles 30 mg/m .sup.2 (average particle size: 4.5 μm) Sodium dihexyl-α-sulfosuccinate 15 mg/m.sup.2 Sodium p-dodecylbenzenesulfonate 15 mg/m.sup.2 Sodium acetate 40 mg/m.sup.2 ______________________________________
γ=optical density (3.0-0.3)÷ΔlogE
______________________________________ Solution 1 Water 1.0 l Gelatin 20 g Sodium chloride 2 g 1,3-Dimethylimidazolidine-2-thione 20 mg Sodium benzenethiosulfonate 3 mg Solution 2 Water 600 ml Silver nitrate 150 g Solution 3 Water 600 ml Sodium chloride 45 g Potassium bromide 21 g K.sub.3 KrCl.sub.6 (0.001% aq. soln.) 15 ml (NH.sub.4).sub.3 RhBr.sub.6 (0.001% aq. soln.) 1.5 ml Solution 4 Water 200 ml Silver nitrate 50 g Solution 5 Water 2.00 ml Sodium chloride 15 g Potassium bromide 7 g K.sub.4 Fe(CN).sub.6 30 mg ______________________________________
______________________________________ Gelatin 1.5 g/m.sup.2 Surface active agent: Sodium p-dodecylbenzenesulfonate 30 mg/m.sup.2 Gelatin hardening agent: 1,2-bis(vinylsulfonylacetamido)- 100 mg/m.sup.2 ethane Dye: Mixture of the following Dyes (g), (h), (i) and (j) Dye (g) 50 mg/m.sup.2 Dye (h) 100 mg/m.sup.2 Dye (i) 30 mg/m.sup.2 Dye (j) 50 mg/m.sup.2 Proxel 1 mg/m.sup.2 ______________________________________
______________________________________ Gelatin 1.5 g/m.sup.2 Polymethyl methacrylate fine particles 20 mg/m.sup.2 (average particle size: 2.5 μm) Sodium p-dodecylbenzenesulfonate 15 mg/m.sup.2 Sodium dihexyl-α-sulfosuccinate 15 mg/m.sup.2 Sodium acetate 50 mg/m.sup.2 Proxel 1 mg/m.sup.2 ______________________________________
______________________________________ Core-shell type vinylidene chloride 15 g copolymer (1) 2,4-Dichloro-6-hydroxy-s-triazine 0.25 g Polystyrene fine particle 0.05 g (average particle size: 3 μm) Compound O 0.20 g Colloidal silica (Snowtex ZL, produced by 0.12 g Nissan Chemical KK, particle size: 70 to 100 μm) Water to make 100 g ______________________________________
______________________________________ Gelatin 1 g Methyl cellulose 0.05 g Compound P 0.02 g C.sub.12 H.sub.25 O(CH.sub.2 CH.sub.2 O).sub.10 H 0.03 g Compound A 3.5 × 10.sup.-3 g Acetic acid 0.2 g Water to make 100 g ______________________________________
______________________________________ 1-Phenyl-5-mercaptotetrazole 1 mg/m.sup.2 N-Oleyl-N-methyltaurin sodium salt 10 mg/m.sup.2 Compound B 10 mg/m.sup.2 Compound C 8 mg/m.sup.2 Compound D 15 mg/m.sup.2 n-Butyl acrylate/2-acetoacetoxyethyl 760 mg/m.sup.2 methacrylate/acrylic acid copolymer (89/8/3) Compound E (hardening agent) 105 mg/m.sup.2 Sodium polystyrenesulfonate 57 mg/m.sup.2 Hydrazine Compound D-10e 3 × 10.sup.-5 mol/m.sup.2 Nucleation Accelerator F-14 3 × 10.sup.-5 mol/m.sup.2 ______________________________________
______________________________________ Gelatin (Ca.sup.++ content: 2,700 ppm) 0.6 g/m.sup.2 Sodium p-dodecylbenzenesulfonate 10 mg/m.sup.2 Sodium polystyrenesulfonate 6 mg/m.sup.2 Compound A 1 mg/m.sup.2 Compound F 14 mg/m.sup.2 n-Butyl acrylate/2-acetoacetoxyethyl 250 mg/m.sup.2 methacrylate/acrylic acid copolymer (89/8/3) ______________________________________
______________________________________ Gelatin (Ca.sup.++ content: 2,700 ppm) 0.45 g/m.sup.2 Amorphous silica matting agent (average 40 mg/m.sup.2 particle size: 3.5 μm, pore diameter: 25 Å, surface area: 700 m.sup.2 /g) Amorphous silica matting agent (average 10 mg/m.sup.2 particle size: 2.5 μm, pore diameter: 170 Å, surface area: 300 m.sup.2 /g) N-Perfluorooctanesulfonyl-N-propylglycine 5 mg/m.sup.2 potassium Sodium p-dodecylbenzenesulfonate 30 mg/m.sup.2 Compound A 1 mg/m.sup.2 Liquid paraffin 40 mg/m.sup.2 Solid Disperse Dye G.sub.1 30 mg/m.sup.2 Solid Disperse Dye G.sub.2 150 mg/m.sup.2 Sodium polystyrenesulfonate 4 mg/m.sup.2 ______________________________________
______________________________________ SnO.sub.2 /Sb (9/1 by weight, average particle 186 mg/m.sup.2 size: 0.25 μm) Gelatin (Ca.sup.++ content: 3,000 ppm) 60 mg/m.sup.2 Sodium p-dodecylbenzenesulfonate 13 mg/m.sup.2 Sodium dihexyl-α-sulfosuccinate 12 mg/m.sup.2 Sodium polystyrenesulfonate 10 mg/m.sup.2 Compound A 1 mg/m.sup.2 ______________________________________
______________________________________ Gelatin (Ca.sup.++ content: 30 ppm) 1.94 g/m.sup.2 Polymethyl methacrylate fine particle 15 mg/m.sup.2 (average particle size: 3.4 μm) Compound J 140 mg/m.sup.2 Compound K 140 mg/m.sup.2 Compound L 30 mg/m.sup.2 Compound M 40 mg/m.sup.2 Sodium p-dodecylbenzenesulfonate 7 mg/m.sup.2 Sodium dihexyl-α-sulfosuccinate 29 mg/m.sup.2 Compound N 5 mg/m.sup.2 N-Perfluorooctanesulfonyl-N-propylglycine 5 mg/m.sup.2 potassium Sodium sulfate 150 mg/m.sup.2 Sodium acetate 40 mg/m.sup.2 Compound E (hardening agent) 105 mg/m.sup.2 ______________________________________
______________________________________ Developer Water 700 ml Sodium hydroxide 2.5 g Diethylenetriaminepentaacetic acid 4.0 g Sodium carbonate monohydrate 54.0 g Sodium sulfite 5.0 g Sodium erythorbate 40.0 g *Monol 7.5 g Potassium bromide 2.0 g Compound (X) 0.075 g Diethylene glycol 25.0 g Compound (Y) 0.72 g Acetic acid (90%) 10 ml pH (adjusted by NaOH or acetic acid) 9.7 Water (H.sub.2 O) to make 1 l ______________________________________ *Monol: N-methyl-p-aminophenol.1/2 sulfate Additives for Developer A Compound (X) - #STR343## - Compound Y - #STR344## (Formulation of Fixing Solution) Fixing Solution A Ammonium thiosulfate 359.1 g Disodium ethylenediaminetetraacetate 0.09 g dihydrate Sodium thiosulfate pentahydrate 32.8 g Sodium sulfite 75.0 g Sodium hydroxide 37.2 g glacial acetic acid 87.3 g Tartaric acid 8.76 g Sodium gluconate 6.6 g Aluminum sulfate 25.3 g pH (adjusted by sulfuric acid or 5.05 sodium hydroxide) Water to make 1 l ______________________________________
______________________________________ Solid agent part Ammonium thiosulfate 1,200 g Sodium thiosulfate 150 g Sodium acetate 400 g Sodium metabisulfite 200 g Liquid agent part Aluminum sulfate (27%) 300 g Sulfuric acid (75%) 30 g Sodium gluconate 20 g EDTA 0.3 g Citric acid 40 g ______________________________________
TABLE 1 __________________________________________________________________________ Light-Sensitive Light-Sensitive Material 1 Material 3 Process Formula D0510 D0510 G0330 D0510 D0510 G0330 No. (A) (11") (30") (30") (11") (30") (30") Remarks __________________________________________________________________________ 101 Monol 3.50 5.38 18 3.21 4.77 15 Comparison 102 A-1 3.89 5.38 17 3.78 4.63 14 Invention 103 A-2 4.42 5.38 22 4.57 4.74 14 Invention 104 A-3 3.89 5.40 22 3.67 4.64 20 Invention 105 A-116 4.54 5.38 22 4.59 4.68 20 Invention 106 A-118 4.47 5.37 22 4.61 4.65 20 Invention 107 A-10 3.85 5.40 18 3.66 4.75 18 Invention 108 A-120 4.46 5.37 22 4.58 4.70 20 Invention 109 A-18 3.79 5.35 20 3.68 4.70 17 Invention 110 A-23 4.21 5.35 18 4.04 4.70 17 Invention 111 A-38 4.52 5.38 22 4.60 4.63 20 Invention 112 A-4 3.95 5.40 18 3.79 4.66 14 Invention 113 A-39 4.00 5.41 17 3.80 4.60 15 Invention 114 A-43 4.23 5.40 18 4.07 4.81 15 Invention 115 A-100 3.90 5.35 17 3.88 4.63 14 Invention 116 A-14 3.85 5.37 17 3.67 4.63 14 Invention 117 A-61 3.80 5.37 20 3.60 4.70 19 Invention 118 A-64 3.95 5.33 20 3.80 4.62 14 Invention 119 A-8 4.36 5.39 20 4.25 4.71 18 Invention 120 A-78 4.11 5.35 20 4.06 4.66 16 Invention 121 A-95 3.90 5.30 17 3.79 4.60 14 Invention 122 A-103 3.95 5.35 19 4.00 4.65 15 Invention 123 p-aminophenol 1.82 3.50 5 1.66 3.01 7 Comparison __________________________________________________________________________
TABLE 2 ______________________________________ Process Formula D0510 D0510 G0330 No. (A) (11") ("20) (20") Remarks ______________________________________ 301 Monol 2.61 5.16 15 Comparison 302 A-2 3.76 5.24 18 Invention 303 A-3 3.23 5.26 21 " 304 A-116 3.81 5.18 21 " 305 A-10 3.22 5.20 16 " 306 A-18 3.30 5.20 16 " 307 A-118 3.80 5.22 21 " 308 A-4 3.35 5.25 14 " 309 A-43 3.37 5.22 15 " 310 A-61 3.28 5.23 16 " 311 A-8 3.64 5.23 15 " 312 A-78 3.39 5.20 15 " 313 A-95 3.52 5.18 14 " 314 A-103 3.38 5.25 14 " ______________________________________
__________________________________________________________________________ Solution (1): Inactive gelatin 30 g Crystal Habit Controlling Agent A 0.6 g Crystal Habit Controlling Agent B 0.4 g Crystal Habit Controlling Agent A - #STR346## - Crystal Habit Controlling Agent B - #STR347## - NaCl 4 g H.sub.2 O 1,750 ml Solution (2): AgNO.sub.3 7.6 g H.sub.2 O to make 30 ml Solution (3): NaCl 2.8 g H.sub.2 O to make 30 ml Solution (4): AgNO.sub.3 24.5 g H.sub.2 O to make 96 ml Solution (5): NaCl 0.3 g H.sub.2 O to make 65 ml Solution (6): AgNO.sub.3 101.9 g H.sub.2 O to make 400 ml Solution (7): NaCl 37.6 g H.sub.2 O to make 400 ml __________________________________________________________________________
__________________________________________________________________________ Solution (1): Inactive gelatin 30 g Crystal Habit Controlling Agent A 0.6 g Crystal Habit Controlling Agent B 0.4 g Crystal Habit Controlling Agent A - #STR348## - Crystal Habit Controlling Agent B - #STR349## - NaCl 4 g H.sub.2 O 1,750 ml Solution (2): AgNO.sub.3 7.6 g H.sub.2 O to make 30 ml Solution (3): NaCl 2.8 g H.sub.2 O to make 30 ml Solution (4): AgNO.sub.3 24.5 g H.sub.2 O to make 96 ml Solution (5): NaCl 0.3 g H.sub.2 O to make 65 ml Solution (6): AgNO.sub.3 101.9 g H.sub.2 O to make 400 ml Solution (7): NaCl 14.4 g KBr 47.0 g H.sub.2 O to make 400 ml __________________________________________________________________________
______________________________________ Gelatin (including gelatin in emulsion) 111 g Dextran (average molecular weight: 39,000) 21.5 g Sodium polyacrylate 5.1 g (average molecular weight: 400,000) Sodium polystyrenesulfonate 1.2 g (average molecular weight: 600,000) Potassium iodide 78 mg Hardener: The addition amount was controlled so that 1,2- bis(vinylsulfonylacetamido)ethane had a swelling ratio of 230%. Compound 1 42.1 mg Compound 2 10.3 g Compound 3 0.11 g Compound 4 8.5 mg Compound 5 0.43 g pH adjusted with NaOH 6.1 ______________________________________ Compound 1 - #STR353## - Compound 2 - #STR354## - Compound 3 - #STR355## - Compound 4 - #STR356## - Compound 5 - #STR357## To the coating solution prepared above, Dye Emulsified Product I was <Preparati on of Dye Emulsified Product a>
______________________________________ Gelatin 0.780 g/m.sup.2 Sodium polyacrylate 0.025 g/m.sup.2 (average molecular weight: 400,000) Sodium polystyrenesulfonate 0.0012 g/m.sup.2 (average molecular weight: 600,000) Polymethyl methacrylate 0.072 g/m.sup.2 (average particle size: 3.7 μm) Compound 6 0.018 g/m.sup.2 Compound 7 0.037 g/m.sup.2 Compound 8 0.0068 g/m.sup.2 Compound 9 0.0032 g/m.sup.2 Compound 10 0.0012 g/m.sup.2 Compound 11 0.0022 g/m.sup.2 Compound 12 0.030 g/m.sup.2 Proxel 0.0010 g/m.sup.2 pH adjusted with NaOH 6.8 ______________________________________ Compound 6 - #STR359## - Compound 7 - #STR360## - Compound 8 - #STR361## - Compound 9 - #STR362## - Compound 10 - #STR363## - Compound 11 - #STR364## - Compound 12 - #STR365## <Preparation of Support>
______________________________________ Butadiene-styrene copolymer latex 158 ml solution (butadiene having solid content of 40%/styrene = 31/69 by weight) 2,4-Dichloro-6-hydroxy-s-triazine 41 ml sodium salt 4% solution Distilled water 801 ml ______________________________________ *The latex solution contained Compound 13 as an emulsion-dispersing agent in an amount of 0.4 wt % based on the latex solid content. Dye Compound 1 - #STR367## - Dye Compound 3 - #STR368## - Dye Compound 4 - #STR369## - (Emulsion-Dispersing Agent) Compound 13 - #STR370## - (contained in an amount of 0.4 wt % based on the latex solid content) (3) Coating of Undercoat Layer
______________________________________ Gelatin 80 mg/m.sup.2 Dye Compound II (as dye solid content) 8 mg/m.sup.2 Compound 14 1.8 mg/m.sup.2 Compound 12 0.27 mg/m.sup.2 Matting Agent: polymethyl methacrylate having 2.5 mg/m.sup.2 an average particle size of 2.5 μm ______________________________________ Compound 14? ##STR371## <Preparation of Photographic Material>
______________________________________ Diethylenetriaminepentaacetic acid 8.0 g Sodium sulfite 20.0 g Sodium carbonate monohydrate 52.0 g Potassium carbonate 55.0 g Sodium erythorbate 60.0 g 4-Hydroxymethyl-4-methyl-1-phenyl-3- 13.2 g pyrazolidone 3,3'-Diphenyl-3,3'-dithiopropionic acid 1.44 g Diethylene glycol 50.0 g Compound 15 10 g Water to make 1 l pH adjusted by sodium hydroxide 10.1 ______________________________________ Compound 15 - #STR372## <Preparation of Development Replenisher>
______________________________________ Potassium bromide 11.1 g Acetic acid 10.8 g Water to make 55 ml ______________________________________
______________________________________ Water 0.5 l Ethylenediaminetetraacetic acid dihydrate 0.05 g Sodium thiosulfate 200 g Sodium bisulfite 98.0 g Sodium hydroxide 2.9 g pH was adjusted with NaOH to 5.2 and water was added to make 1 l. ______________________________________
______________________________________ Step Temperature Processing Time ______________________________________ Development 35° C. 8 seconds Fixing 35° C. 8 seconds Water washing 25° C. 7 seconds Drying 55° C. 6 seconds ______________________________________
TABLE 3 ______________________________________ Process No. Formula (A) Sensitivity Fog Remarks ______________________________________ 601 4-hydroxymethyl-4- 100 0.15 Comparison methyl-1-phenyl-3- pyrazolidone 602 A-1 120 0.14 Invention 603 A-2 150 0.13 " 604 A-3 120 0.13 " 605 A-116 170 0.14 " 606 A-118 170 0.12 " 607 A-10 120 0.14 " 608 A-120 170 0.12 " 609 A-18 120 0.14 " 610 A-23 150 0.13 " 611 A-38 170 0.14 " 612 A-4 140 0.15 " 613 A-39 150 0.12 " 614 A-43 130 0.14 " 615 A-100 130 0.10 " 616 A-14 120 0.14 " 617 A-61 120 0.13 " 618 A-64 170 0.11 " 619 A-8 150 0.12 " 620 A-78 130 0.13 " 621 A-95 130 0.11 " 622 A-103 150 0.12 " 623 p-aminophenol 70 0.14 Comparison ______________________________________
______________________________________ Solution 1: Water 1 l Gelatin 20 g Sodium chloride 3.0 g 1,3-Dimethylimidazolidine-2-thione 20 mg Sodium benzenethiosulfonate 8 mg Solution 2: Water 0.4 l Silver nitrate 100 g Solution 3: Water 0.4 l Sodium chloride 27.1 g Potassium bromide 21.0 g Ammonium hexachloroiridate(III) 20 ml (0.001% aqueous solution) Potassium hexachlororhodate(III) 6 ml (0.001% aqueous solution) ______________________________________
______________________________________ Solution 4: Water 0.4 l Sodium nitrate 100 g Solution 5: Water 0.4 l Sodium chloride 27.1 g Potassium bromide 21.0 g Potassium hexacyanoferrate(II) 10 ml (0.1% aqueous solution) ______________________________________
______________________________________ (Protective Upper Layer) Gelatin 0.3 g/m.sup.2 Silica matting agent having 25 mg/m.sup.2 an average particle size of 3.5 μm Compound-14 (gelatin dispersion) 20 mg/m.sup.2 Colloidal silica having a particle 30 mg/m.sup.2 size of from 10 to 20 μm Compound (F) 5 mg/m.sup.2 Sodium dodecylbenzenesulfonate 20 mg/m.sup.2 Compound (G) 20 mg/m.sup.2 (Protective Lower Layer) Gelatin 0.5 g/m.sup.2 Compound (H) 15 mg/m.sup.2 1,5-Dihydroxy-2-benzaldoxime 10 mg/m.sup.2 Polyethyl acrylate latex 150 mg/m.sup.2 (UL Layer) Gelatin 0.5 g/m.sup.2 Polyethyl acrylate latex 150 mg/m.sup.2 Compound (B) 40 mg/m.sup.2 Compound 15 10 mg/m.sup.2 ______________________________________
______________________________________ (Back Layer) Gelatin 3.3 g/m.sup.2 Sodium dodecylbenzenesulfonate 80 mg/m.sup.2 Dye (a) 40 mg/m.sup.2 Dye (b) 20 mg/m.sup.2 Dye (c) 90 mg/m.sup.2 1,3-Divinylsulfonyl-2-propanol 60 mg/m.sup.2 Polymethyl methacrylate fine particle 30 mg/m.sup.2 (average particle size: 6.5 μm) Compound (B) 120 mg/m.sup.2 (Electrically Conductive Layer) Gelatin 0.1 g/m.sup.2 Sodium dodecylbenzenesulfonate 20 mg/m.sup.2 SnO.sub.2 /Sb (9/1 by weight, average 200 mg/m.sup.2 particle size: 0.25 μm) ______________________________________
TABLE 4 __________________________________________________________________________ Composition of Developer Composition of Developer (Water was added to make 1 l. The pH was adjusted by using sodium hydroxide and acetic acid.) No. 1 2 3 4 5 6 7 __________________________________________________________________________ Diethylenetriamine 2 2 2 2 2 2 2 pentaacetic acid (g) Potassium carbonate (g) 33 33 33 33 33 33 33 Sodium carbonate (g) 28 28 28 28 28 28 28 Sodium hydrogencarbonate 25 25 25 25 25 25 25 (g) Sodium erythorbate (g) 45 45 45 45 45 45 45 N-Methyl-p-aminophenol (g) 7.5 -- -- -- -- 1 -- Compound (A-2) (g) -- 1 -- -- -- -- -- Compound (A-116) (g) -- -- 1 -- -- -- 1 Compound (A-118) (g) -- -- -- 1 -- -- -- Compound (A-119) (g) -- -- -- -- 1 -- -- KBr (g) 2 2 2 2 2 2 2 5-Methylbenzotriazole (g) 0.004 0.004 0.004 0.004 0.004 0.004 0.004 1-Phenyl-5-mercapto- 0.02 0.02 0.02 0.02 0.02 0.02 0.02 tetrazole (g) Sodium sulfite (g) 2 2 2 2 2 2 2 pH 9.7 9.7 9.7 9.7 9.7 9.7 10.6 Container coloration after 2 4 4 4 4 4 3 thermo Remarks Comparison Invention Invention Invention Invention Comparison Invention __________________________________________________________________________
______________________________________ Ammonium thiosulfate 360 g Disodium ethylenediaminetetraacetate 0.09 g dihydrate Sodium sulfate pentahydrate 33.0 g Sodium metasulfite 57.0 g Sodium hydroxide 37.2 g Acetic acid (100%) 90.0 g Tartaric acid 8.7 g Sodium gluconate 5.1 g Aluminum sulfate 25.2 g pH 4.85 ______________________________________
TABLE 5 ______________________________________ No. Developer No. Sensitivity Gradation Remarks ______________________________________ 1 1 100 22.0 Comparison 2 2 103 22.5 Invention 3 3 102 22.3 Invention 4 4 100 22.1 Invention 5 5 102 22.0 Invention 6 6 80 7.9 Comparison 7 7 108 27.0 Comparison ______________________________________
TABLE 6 __________________________________________________________________________ Replenishing Amount pH of Developer of Developer Fresh After Running No. Replenisher No. (ml/m.sup.2) Sensitivity Gradation Sensitivity Gradation Dot Quality Remarks __________________________________________________________________________ 8 9.7 1 160 100 22.0 95 18.4 3.0 Comparison 9 9.7 3 160 102 22.3 95 18.8 4.5 Invention 10 9.7 4 160 100 22.1 96 18.7 4.5 Invention 11 10.1 1 80 100 22.0 95 18.5 2.5 Comparison 12 10.1 2 80 103 22.5 96 19.2 4.0 Invention 13 10.1 4 80 100 22.1 95 18.8 4.0 Invention __________________________________________________________________________
______________________________________ Composition of Developer: ______________________________________ Developing agent shown in Table 19 Aminophenol derivative shown in Table 19 Diethylenetriaminepentaacetic acid 2 g Potassium carbonate 33 g Sodium carbonate 28 g Sodium hydrogencarbonate 25 g KBr 0.2 g 5-Methylbenzotriazole 0.004 g 1-Phenyl-5-mercaptotetrazole 0.02 g Sodium sulfite 2 g ______________________________________
TABLE 7 __________________________________________________________________________ Developer No. Developing Agent (g/l) Aminophenol Derivative (g/l) Remarks __________________________________________________________________________ 1 hydroquinone 23 N-methyl-p-aminophenol 7.5 Comparison 2 sodium erythorbate 45 N-methyl-p-aminophenol 7.5 Comparison 3 hydroquinone 23 A-115 3.6 Invention 4 hydroquinone 23 A-2 3.6 Invention 5 hydroquinone 23 A-139 5.0 Invention 6 sodium erythorbate 45 A-115 3.6 Invention 7 sodium erythorbate 45 A-2 3.6 Invention 8 sodium erythorbate 45 A-139 5.0 Invention 9 sodium erythorbate 45 A-3 3.0 Invention A-128 0.6 10 sodium erythorbate 45 A-115 1.0 Invention AM-1 2.5 __________________________________________________________________________ AM-1 - #STR374## A solid dispersion of each of Hydrazine Derivatives 1c', 5e' and 25c'
______________________________________ Solution 1: Water 1 l Gelatin 20 g Sodium chloride 3.0 g 1,3-Dimethylimidazolidine-2-thione 20 mg Sodium benzenethiosulfonate 8 mg Solution 2: Water 400 ml Silver nitrate 100 g Solution 3: Water 400 ml Sodium chloride 27.1 g Potassium bromide 21.0 g Ammonium hexachloroiridate(III) 20 ml (0.001% aqueous solution) Potassium hexachlororhodate(III) 6 ml (0.001% aqueous solution) ______________________________________
______________________________________ Solution 4: Water 400 ml Sodium nitrate 100 g Solution 5: Water 400 ml Sodium chloride 27.1 g Potassium bromide 21.0 g Potassium hexacyanoferrate(II) 10 ml (0.1% aqueous solution) ______________________________________
______________________________________ (Protective Upper Layer) Gelatin 0.3 g/m.sup.2 Silica matting agent having 25 mg/m.sup.2 an average particle size of 3.5 μm Compound (6) (gelatin dispersion) 20 mg/m.sup.2 Colloidal silica having a particle 30 mg/m.sup.2 size of from 10 to 20 μm Compound (7) 5 mg/m.sup.2 Sodium dodecylbenzenesulfonate 20 mg/m.sup.2 Compound (8) 20 mg/m.sup.2 (Protective Lower Layer) Gelatin 0.5 g/m.sup.2 Compound (9) 15 mg/m.sup.2 1,5-Dihydroxy-2-benzaldoxime 10 mg/m.sup.2 Polyethyl acrylate latex 150 mg/m.sup.2 (UL Layer) Gelatin 0.5 g/m.sup.2 Polyethyl acrylate latex 150 mg/m.sup.2 Compound (5) 40 mg/m.sup.2 Compound (10) 10 mg/m.sup.2 ______________________________________
__________________________________________________________________________ (Back Layer) Gelatin 3.3 g/m.sup.2 Sodium dodecylbenzenesulfonate 80 mg/m.sup.2 Compound (11) 40 mg/m.sup.2 Compound (12) 20 mg/m.sup.2 Compound (13) 90 mg/m.sup.2 1,3-Divinylsulfonyl-2-propanol 60 mg/m.sup.2 Polymethyl methacrylate fine particle 30 mg/m.sup.2 (average particle size: 6.5 μm) Compound (5) 120 mg/m.sup.2 (Electrically Conductive Layer) Gelatin 0.1 g/m.sup.2 Sodium dodecylbenzenesulfonate 20 mg/m.sup.2 SnO.sub.2 /Sb (9/1 by weight, average particle size: 0.25 μm) 200 mg/m.sup.2 __________________________________________________________________________ Sensitizing Dye (1) - #STR375## - Compound (1) - #STR376## - Compound (2) - #STR377## - Hydrazine Compound H - #STR378## - Compound (4) - #STR379## - Compound (5) A 3:1 mixture of n = 2 and n = 3: - #STR380## - Compound (6) - #STR381## - Compound (7) - #STR382## - Compound (8) - #STR383## - Compound (9) - #STR384## - Compound (10) - #STR385## - Compound (11) - #STR386## - Compound (12) - #STR387## - Compound (13) - #STR388##
TABLE 8 ______________________________________ Light- Hydrazine Addition Method of Sensitive No. Derivative No. Hydrazine Derivative ______________________________________ A Hydrazine dissolved in methanol Compound H before addition B 1c' dissolved in methanol before addition C 1c' added as a solid dispersion D 5e' added as a solid dispersion E 25c' added as a solid dispersion ______________________________________
______________________________________ Fixing Solution ______________________________________ Ammonium thiosulfate 120 g Disodium ethylenediaminetetraacetate 0.03 g dihydrate Sodium sulfate pentahydrate 11 g Sodium metasulfite 19 g Sodium hydroxide 12.4 g Acetic acid (100%) 30 g Tartaric acid 2.9 g Sodium gluconate 1.7 g Aluminium sulfate 8.4 g pH 4.8 ______________________________________
TABLE 9 __________________________________________________________________________ Test Developer Light- Linearity Taillessness No. No. Sensitive No. Gamma Practical Dm 1st Step (%) 15th Step (%) of Dots Remarks __________________________________________________________________________ 1-1 1 A 14 3.4 4 93 1 Comparison 1-2 1 B 14 3.7 4 93 2 Comparison 1-3 2 A 16 3.8 3 94 3 Invention 1-4 2 B 17 3.9 3 94 4 Invention 1-5 3 A 16 3.6 3 94 3 Invention 1-6 3 B 18 4.1 4 93 3 Invention 1-7 3 C 15 4.2 4 93 3 Invention 1-8 4 C 16 4.1 4 93 3 Invention 1-9 5 C 16 4.2 4 93 3 Invention 1-10 6 A 17 3.6 3 94 3 Comparison 1-11 6 B 20 4.5 4 93 4 Invention 1-12 6 C 21 4.6 4 93 4 Invention 1-13 6 D 20 4.6 4 93 4 Invention 1-14 6 E 22 4.5 4 93 4 Invention 1-15 7 C 21 4.6 4 93 4 Invention 1-16 8 C 20 4.5 4 93 4 Invention 1-17 9 B 22 4.7 4 93 5 Invention 1-18 9 C 21 4.7 5 92 5 Invention 1-19 9 D 22 4.8 5 92 5 Invention 1-20 9 E 20 4.7 5 92 5 Invention 1-21 10 C 21 4.8 5 92 5 Invention __________________________________________________________________________
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JP7090896 | 1996-03-04 | ||
JP8-070908 | 1996-03-04 | ||
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JP8-265076 | 1996-09-17 | ||
JP26507696A JP3539655B2 (en) | 1996-03-04 | 1996-09-17 | Processing composition for silver halide photographic light-sensitive material, developer and processing method using the same |
JP26508596A JP3539656B2 (en) | 1996-09-17 | 1996-09-17 | Processing composition for silver halide photographic light-sensitive material, developer and processing method using the same |
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US08/810,424 Expired - Fee Related US5994040A (en) | 1996-03-04 | 1997-03-04 | Processing composition for silver halide photographic light-sensitive material, developer and processing method using the same |
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US20040163695A1 (en) * | 1994-07-25 | 2004-08-26 | Carter Mark C. | Erectable canopy with reinforced roof structure |
US20040209204A1 (en) * | 2003-02-04 | 2004-10-21 | Mitsunori Hirano | Silver halide photographic light-sensitive material |
US20060128787A1 (en) * | 2002-07-17 | 2006-06-15 | Shouji Kamiya | Novel indoline compound and medicinal use thereof |
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KR100388345B1 (en) * | 1995-10-05 | 2004-03-30 | 교토 야쿠힝 고교 가부시키가이샤 | Novel heterocyclic derivatives and their medicinal uses |
EP0846981A1 (en) * | 1996-12-03 | 1998-06-10 | Konica Corporation | Method for processing black-and-white silver halide photographic light-sensitive material |
JP3614595B2 (en) * | 1997-01-28 | 2005-01-26 | 富士写真フイルム株式会社 | Development processing method |
EP0908764B1 (en) * | 1997-10-06 | 2002-03-27 | Agfa-Gevaert | Method of processing a black-and-white silver halide photographic material |
US6083672A (en) * | 1997-10-06 | 2000-07-04 | Agfa-Gevaert, N.V. | Method of processing a black-and-white silver halide photographic material |
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US20040163695A1 (en) * | 1994-07-25 | 2004-08-26 | Carter Mark C. | Erectable canopy with reinforced roof structure |
US6926021B2 (en) * | 1994-07-25 | 2005-08-09 | Mark C. Carter | Erectable canopy with reinforced roof structure |
US20050229962A1 (en) * | 1994-07-25 | 2005-10-20 | Carter Mark C | Erectable canopy with reinforced roof structure |
US20070119494A1 (en) * | 1994-07-25 | 2007-05-31 | Carter Mark C | Erectable canopy with reinforced roof structure |
US7448401B2 (en) | 1994-07-25 | 2008-11-11 | Carter Mark C | Erectable canopy with reinforced roof structure |
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US6673528B2 (en) | 2000-08-21 | 2004-01-06 | Eastman Kodak Company | Ascorbic acid developing compositions containing sugar and methods of use |
US20060128787A1 (en) * | 2002-07-17 | 2006-06-15 | Shouji Kamiya | Novel indoline compound and medicinal use thereof |
US7429612B2 (en) | 2002-07-17 | 2008-09-30 | Kyoto Pharmaceutical Industries, Ltd. | Indoline compound and medicinal use thereof |
US20040209204A1 (en) * | 2003-02-04 | 2004-10-21 | Mitsunori Hirano | Silver halide photographic light-sensitive material |
US20070224536A1 (en) * | 2003-02-04 | 2007-09-27 | Mitsunori Hirano | Silver halide photographic light-sensitive material |
US7887998B2 (en) | 2003-02-04 | 2011-02-15 | Fujifilm Corporation | Silver halide photographic light-sensitive material |
Also Published As
Publication number | Publication date |
---|---|
EP0793140A1 (en) | 1997-09-03 |
DE69702725D1 (en) | 2000-09-14 |
EP0793140B1 (en) | 2000-08-09 |
DE69702725T2 (en) | 2000-12-07 |
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