US6723643B1 - Method for chemical mechanical polishing of thin films using end-point indicator structures - Google Patents
Method for chemical mechanical polishing of thin films using end-point indicator structures Download PDFInfo
- Publication number
- US6723643B1 US6723643B1 US10/391,435 US39143503A US6723643B1 US 6723643 B1 US6723643 B1 US 6723643B1 US 39143503 A US39143503 A US 39143503A US 6723643 B1 US6723643 B1 US 6723643B1
- Authority
- US
- United States
- Prior art keywords
- cmp
- layer
- depositing
- substrate
- cmr
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C13/00—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00
- G11C13/0002—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using resistive RAM [RRAM] elements
- G11C13/0007—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using resistive RAM [RRAM] elements comprising metal oxide memory material, e.g. perovskites
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N70/00—Solid-state devices without a potential-jump barrier or surface barrier, and specially adapted for rectifying, amplifying, oscillating or switching
- H10N70/011—Manufacture or treatment of multistable switching devices
- H10N70/061—Patterning of the switching material
- H10N70/066—Patterning of the switching material by filling of openings, e.g. damascene method
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N70/00—Solid-state devices without a potential-jump barrier or surface barrier, and specially adapted for rectifying, amplifying, oscillating or switching
- H10N70/20—Multistable switching devices, e.g. memristors
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N70/00—Solid-state devices without a potential-jump barrier or surface barrier, and specially adapted for rectifying, amplifying, oscillating or switching
- H10N70/801—Constructional details of multistable switching devices
- H10N70/821—Device geometry
- H10N70/826—Device geometry adapted for essentially vertical current flow, e.g. sandwich or pillar type devices
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N70/00—Solid-state devices without a potential-jump barrier or surface barrier, and specially adapted for rectifying, amplifying, oscillating or switching
- H10N70/801—Constructional details of multistable switching devices
- H10N70/881—Switching materials
- H10N70/883—Oxides or nitrides
- H10N70/8836—Complex metal oxides, e.g. perovskites, spinels
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C2213/00—Indexing scheme relating to G11C13/00 for features not covered by this group
- G11C2213/30—Resistive cell, memory material aspects
- G11C2213/31—Material having complex metal oxide, e.g. perovskite structure
Definitions
- This Application is related to Device and method for reversible resistance change induced by electric pulses in non-crystalline perovskite unipolar programmable memory; Ser. No. 10/072,225, filed Feb. 7, 2002.
- This invention relates to CMP processes for use in fabrication of integrated circuits generally, and specifically to CMP used to fabricate a non-volatile resistance RAM structure and CMOS processes to make the memory devices, particularly CMR/PCMO devices.
- CMR Colossal Magnetoresistance
- PCMO Pr 0.7 CaO 0.3 MnO 3
- RRAM novel non-volatile resistance random access memory
- a PCMO thin film has been grown on both epitaxial YBa 2 Cu 3 O 7 (YBCO) and partial epitaxial Pt substrates via pulsed laser abrasion (PLA) technique, Liu et al., Electric - pulse - induced reversible resistance change effect in magnetoresistive films, Applied Physics Letters, 76, 2749, 2000; and Liu et al., U.S. Pat. No. 6,204,139, granted Mar. 20, 2001, for Method of switching the properties of perovskite materials used in thin film resistors.
- X-Ray diffraction (XRD) polar figures confirm the epitaxial properties of PCMO thin films.
- Liu et al. A new concept for non - volatile memory: the electric - pulse induced resistive change effect in Colossal Magnetoresistive thin films, JPL Publication 01-15; Non-Volatile Memory Technology Symposium 2001; November, 2001, pp 18-24, provides additional research information in the field of CMR-containing integrated circuits.
- U.S. Pat. No. 6,204,139 describes the resistance change which occurred when electric pulses are applied at room temperature to PCMO thin films.
- the PCMO thin films were deposited on both epitaxial YBa 2 Cu 3 O 7 (YBCO) and partial epitaxial Pt substrates by pulsed laser deposition (PLD).
- YBCO epitaxial YBa 2 Cu 3 O 7
- PLD pulsed laser deposition
- a method of CMP thin films during fabrication of IC devices includes preparing a substrate, including building IC component structures on the substrate; depositing a bottom electrode on the substrate; depositing a first CMP layer having a first known CMP selectivity on the substrate; patterning the first CMP layer to form a pattern having a lower margin; forming indicator structures on the first CMP layer in the pattern; depositing a second CMP layer having a second known CMP selectivity relative to that of the first CMP layer, including depositing portions of the second CMP layer in the pattern of the first CMP layer; CMP the structure so that the indicator structures are removed and any portion of the first CMP layer and second CMP layer are removed to a level corresponding to the lower margin; and completing the IC structure.
- Another object of the invention is to provide a method for CMP of CMR materials formed on oxide layers or nitride layers.
- a further object of the invention is to provide for CMP of CMR materials with a silica and ammonium hydroxide slurry.
- FIG. 1 depicts a prior art RRAM cell having a damascene structure for PCMO deposition.
- FIG. 2 is a schematic representation of metal patterns which are pre-laid under CMR films for CMP CMR end point detection.
- FIGS. 3-7 depict steps in an end-point-structure-making process.
- FIGS. 8-10 are photos of various steps in the method of the invention.
- the method of the invention provides a practical method for end point detecting as well as colossal magnetoresistive (CMR) thickness control in chemical mechanical polishing (CMP) CMR-containing IC devices.
- CMR colossal magnetoresistive
- CMP chemical mechanical polishing
- an integrated circuit substrate 10 has any number of IC components formed thereon, including a bottom electrode 12 , and an oxide or nitride layer 14 , referred to herein as a first CMP layer having a known CMP selectivity.
- a damascene trench 16 is formed in the first CMP layer, exposing a portion of the upper surface of bottom electrode 12 .
- special patterned end-point indicator structures 18 are laid down before the deposition of a CMR film 20 , which indicator structures may be seen to extend upwardly into the CMR, or other IC film.
- Indicator structures 18 may also be formed under “dented” portions of the overlying IC film layer.
- CMR material is transparent in thin layers, therefor, the indicator structures may be seen though the overlying CMR layer.
- This pattern is gradually polished off during CMP of the CMR film. The end point of CMP is obtained when indicator structure 18 pattern is gone, resulting in a portion of the CMR layer and first CMP layer being removed by CMP, until indicator structures are gone, leaving the CMR layer only in trench 16 .
- the method of the invention is described in connection with a preferred embodiment relating to a specific type of IC component, e.g., PCMO, the method of the invention is not limited to use with the IC component used as an example, and may be applied to an IC fabrication.
- the method of the invention is a process that constructs the end-point indicator structures on the wafer surface includes the following steps:
- substrate 10 includes any number of IC structures, including a bottom electrode 12 , e.g., a platinum bottom electrode.
- An oxide or nitride first CMP layer 14 is formed over the substrate and bottom electrode. Layer 14 is also referred to herein as a first CMP layer.
- a trench 16 is formed in first CMP layer 14 .
- a photo resist layer 22 is applied to the wafer. The photo resist is pattered with a metal mask 24 which contains an end-point structure pattern.
- the wafer is placed in a buffered oxide etch (BOE) 50:1 after being developed for one to two minutes. This will provide an etched step of between about 20 nm to 40 nm in depth.
- BOE buffered oxide etch
- a metal indicator layer 26 is deposited, e.g., titanium to a thickness of about 5 nm or aluminum to a thickness of about 10 nm, with PVD being the accepted method for such deposition. E-beam evaporation is one technique which is appropriate for this purpose.
- the metal-coated wafers are dipped into a photoresist removal solution, e.g., acetone or EKC, resulting in the structure of FIG. 5, having indicator structures 28 formed in trenches in first CMP layer 14 .
- a photoresist removal solution e.g., acetone or EKC
- a layer of CMR material 30 is deposited in the structure.
- layer 30 may be any material which is (1) required to be partially removed or smoothed by CMP; and (2) has a known CMP selectivity relative to the CMP selectivity of layer 14 .
- Layer 30 is also referred to herein as a second CMP layer.
- layer 14 the first CMP layer, has a first known CMP selectivity
- Layer 14 may be silicon dioxide or silicon nitride.
- Layer 30 is a second CMP layer having a second known CMP selectivity relative to the first known CMP selectivity.
- SiO 2 PCMO and SiN
- SiO 2 polishes at a CMP rate faster than PCMO
- Other CMR materials polish at about the same rate as PCMO.
- CMP is performed in a slurry which will work on oxide, nitride and CMR materials.
- the method of the invention uses a silica+ammonium hydroxide (NH 4 OH) slurry, which has been found to be effective on CMR materials as well as on SiO 2 and SiN.
- CMP continues until end-point indicator structures 28 are removed, indicating that the CMP is complete and that a desired amount of the CMR has been removed.
- FIG. 7 the structure is depicted after CMP, wherein only a portion of first CMP layer 14 remains, with trench 16 being filled with CMR material 30 .
- the indicator structures, the upper portion of CMR layer 30 and a portion of first CMP layer 14 have been removed by CMP, which is performed until the indicator structures are removed.
- FIG. 8 is a photo of an indicator structure 28 , formed on a SiN layer 32 , which has a transparent PCMO CMR layer 34 deposited thereon. A trench 16 is also filled with PCMO CMR material.
- FIG. 9 depicts partial removal of PCMO CMR layer 34 outside of trench 16 and partial removal of indicator structure 28 . In FIG. 10, all that remains in PCMO CMR material 34 in trench 16 and SiN layer 32 . Careful observation of the demise of indicator structures 28 provides a positive indicator of the extend of the CMP process, and provides an indicator which is used to stop the CMP process before the CMP process removes significant portions of the first CMP layer.
Abstract
Description
Claims (12)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/391,435 US6723643B1 (en) | 2003-03-17 | 2003-03-17 | Method for chemical mechanical polishing of thin films using end-point indicator structures |
JP2004075423A JP2004282085A (en) | 2003-03-17 | 2004-03-16 | Chemical mechanical polishing method of thin film using end point indicator structure |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/391,435 US6723643B1 (en) | 2003-03-17 | 2003-03-17 | Method for chemical mechanical polishing of thin films using end-point indicator structures |
Publications (1)
Publication Number | Publication Date |
---|---|
US6723643B1 true US6723643B1 (en) | 2004-04-20 |
Family
ID=32069625
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/391,435 Expired - Lifetime US6723643B1 (en) | 2003-03-17 | 2003-03-17 | Method for chemical mechanical polishing of thin films using end-point indicator structures |
Country Status (2)
Country | Link |
---|---|
US (1) | US6723643B1 (en) |
JP (1) | JP2004282085A (en) |
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6849891B1 (en) * | 2003-12-08 | 2005-02-01 | Sharp Laboratories Of America, Inc. | RRAM memory cell electrodes |
US20050110117A1 (en) * | 2003-11-24 | 2005-05-26 | Sharp Laboratories Of America, Inc. | 3d rram |
US20050258027A1 (en) * | 2003-09-15 | 2005-11-24 | Makoto Nagashima | Back-biased face target sputtering based programmable logic device |
US20060081467A1 (en) * | 2004-10-15 | 2006-04-20 | Makoto Nagashima | Systems and methods for magnetron deposition |
US20060081466A1 (en) * | 2004-10-15 | 2006-04-20 | Makoto Nagashima | High uniformity 1-D multiple magnet magnetron source |
US20060099813A1 (en) * | 2004-10-21 | 2006-05-11 | Sharp Laboratories Of America, Inc. | Chemical mechanical polish of PCMO thin films for RRAM applications |
US20060276036A1 (en) * | 2004-10-15 | 2006-12-07 | Makoto Nagashima | Systems and methods for plasma etching |
US20070084717A1 (en) * | 2005-10-16 | 2007-04-19 | Makoto Nagashima | Back-biased face target sputtering based high density non-volatile caching data storage |
US20070084716A1 (en) * | 2005-10-16 | 2007-04-19 | Makoto Nagashima | Back-biased face target sputtering based high density non-volatile data storage |
US20070205096A1 (en) * | 2006-03-06 | 2007-09-06 | Makoto Nagashima | Magnetron based wafer processing |
US20070224770A1 (en) * | 2006-03-25 | 2007-09-27 | Makoto Nagashima | Systems and methods for fabricating self-aligned memory cell |
US20080011600A1 (en) * | 2006-07-14 | 2008-01-17 | Makoto Nagashima | Dual hexagonal shaped plasma source |
US20080014750A1 (en) * | 2006-07-14 | 2008-01-17 | Makoto Nagashima | Systems and methods for fabricating self-aligned memory cell |
US20080011603A1 (en) * | 2006-07-14 | 2008-01-17 | Makoto Nagashima | Ultra high vacuum deposition of PCMO material |
US20080283495A1 (en) * | 2007-05-17 | 2008-11-20 | Samsung Electronics Co., Ltd | Micro electro mechanical system device and method of manufacturing the same |
US8308915B2 (en) | 2006-09-14 | 2012-11-13 | 4D-S Pty Ltd. | Systems and methods for magnetron deposition |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6204139B1 (en) | 1998-08-25 | 2001-03-20 | University Of Houston | Method for switching the properties of perovskite materials used in thin film resistors |
-
2003
- 2003-03-17 US US10/391,435 patent/US6723643B1/en not_active Expired - Lifetime
-
2004
- 2004-03-16 JP JP2004075423A patent/JP2004282085A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6204139B1 (en) | 1998-08-25 | 2001-03-20 | University Of Houston | Method for switching the properties of perovskite materials used in thin film resistors |
Non-Patent Citations (2)
Title |
---|
Liu et al., A new concept for non-volatile memory: the electric-pulse induced resistive change effect in Colossal Magnetoresistive thin films, JPL Publication 01-15; Non-Volatile Memory Technology Symposium 2001; Nov., 2001, pp 18-24. |
Liu et al., Electric-pulse-induced reversible resistance change effect in magnetoresistive films, Applied Physics Letters, vol. 76, No. 19; May 8, 2000, pp 2749-2751. |
Cited By (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070119705A1 (en) * | 2003-09-15 | 2007-05-31 | Makoto Nagashima | Back-biased face target sputtering based memory data sensing technique |
US20050258027A1 (en) * | 2003-09-15 | 2005-11-24 | Makoto Nagashima | Back-biased face target sputtering based programmable logic device |
US20070007124A1 (en) * | 2003-09-15 | 2007-01-11 | Makoto Nagashima | Back-biased face target sputtering based memory with low oxygen flow rate |
US20050110117A1 (en) * | 2003-11-24 | 2005-05-26 | Sharp Laboratories Of America, Inc. | 3d rram |
US7009278B2 (en) * | 2003-11-24 | 2006-03-07 | Sharp Laboratories Of America, Inc. | 3d rram |
US6849891B1 (en) * | 2003-12-08 | 2005-02-01 | Sharp Laboratories Of America, Inc. | RRAM memory cell electrodes |
US20060081467A1 (en) * | 2004-10-15 | 2006-04-20 | Makoto Nagashima | Systems and methods for magnetron deposition |
US20060081466A1 (en) * | 2004-10-15 | 2006-04-20 | Makoto Nagashima | High uniformity 1-D multiple magnet magnetron source |
US20060276036A1 (en) * | 2004-10-15 | 2006-12-07 | Makoto Nagashima | Systems and methods for plasma etching |
US20060099813A1 (en) * | 2004-10-21 | 2006-05-11 | Sharp Laboratories Of America, Inc. | Chemical mechanical polish of PCMO thin films for RRAM applications |
US7205238B2 (en) * | 2004-10-21 | 2007-04-17 | Sharp Laboratories Of America, Inc. | Chemical mechanical polish of PCMO thin films for RRAM applications |
US20070084717A1 (en) * | 2005-10-16 | 2007-04-19 | Makoto Nagashima | Back-biased face target sputtering based high density non-volatile caching data storage |
US20070084716A1 (en) * | 2005-10-16 | 2007-04-19 | Makoto Nagashima | Back-biased face target sputtering based high density non-volatile data storage |
US20070205096A1 (en) * | 2006-03-06 | 2007-09-06 | Makoto Nagashima | Magnetron based wafer processing |
US20070224770A1 (en) * | 2006-03-25 | 2007-09-27 | Makoto Nagashima | Systems and methods for fabricating self-aligned memory cell |
US8395199B2 (en) | 2006-03-25 | 2013-03-12 | 4D-S Pty Ltd. | Systems and methods for fabricating self-aligned memory cell |
US20080014750A1 (en) * | 2006-07-14 | 2008-01-17 | Makoto Nagashima | Systems and methods for fabricating self-aligned memory cell |
US20080011603A1 (en) * | 2006-07-14 | 2008-01-17 | Makoto Nagashima | Ultra high vacuum deposition of PCMO material |
US7932548B2 (en) | 2006-07-14 | 2011-04-26 | 4D-S Pty Ltd. | Systems and methods for fabricating self-aligned memory cell |
US8367513B2 (en) | 2006-07-14 | 2013-02-05 | 4D-S Pty Ltd. | Systems and methods for fabricating self-aligned memory cell |
US20080011600A1 (en) * | 2006-07-14 | 2008-01-17 | Makoto Nagashima | Dual hexagonal shaped plasma source |
US8454810B2 (en) | 2006-07-14 | 2013-06-04 | 4D-S Pty Ltd. | Dual hexagonal shaped plasma source |
US8308915B2 (en) | 2006-09-14 | 2012-11-13 | 4D-S Pty Ltd. | Systems and methods for magnetron deposition |
US20080283495A1 (en) * | 2007-05-17 | 2008-11-20 | Samsung Electronics Co., Ltd | Micro electro mechanical system device and method of manufacturing the same |
US8282196B2 (en) | 2007-05-17 | 2012-10-09 | Samsung Electronics Co., Ltd. | Micro electro mechanical system device and method of manufacturing the same |
Also Published As
Publication number | Publication date |
---|---|
JP2004282085A (en) | 2004-10-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6723643B1 (en) | Method for chemical mechanical polishing of thin films using end-point indicator structures | |
US7205238B2 (en) | Chemical mechanical polish of PCMO thin films for RRAM applications | |
US7038230B2 (en) | Horizontal chalcogenide element defined by a pad for use in solid-state memories | |
US8105948B2 (en) | Use of CMP to contact a MTJ structure without forming a via | |
US8268667B2 (en) | Memory device using ion implant isolated conductive metal oxide | |
US6849891B1 (en) | RRAM memory cell electrodes | |
US6746910B2 (en) | Method of fabricating self-aligned cross-point memory array | |
US11177437B2 (en) | Alignment through topography on intermediate component for memory device patterning | |
US20070184613A1 (en) | Phase change RAM including resistance element having diode function and methods of fabricating and operating the same | |
US20070158632A1 (en) | Method for Fabricating a Pillar-Shaped Phase Change Memory Element | |
US9679844B2 (en) | Manufacturing a damascene thin-film resistor | |
US5897371A (en) | Alignment process compatible with chemical mechanical polishing | |
US20070263322A1 (en) | Magnetic devices having magnetic features with CMP stop layers | |
TWI396258B (en) | Resistor random access memory structure having a defined small area of electrical contact | |
US7381616B2 (en) | Method of making three dimensional, 2R memory having a 4F2 cell size RRAM | |
CN109585285A (en) | The forming method of semiconductor device | |
JP2006318982A (en) | Storage element and its manufacturing method, and etching method | |
US7615459B1 (en) | Manufacturing method for variable resistive element | |
EP3841624B1 (en) | Methods for manufacturing magnetoresistive stack devices | |
CN112151669B (en) | Method for manufacturing memory element | |
CN112133820A (en) | Method for preparing MRAM bottom electrode | |
CN104576397B (en) | The preparation method of Split-gate flash memory | |
Hu | Chemical-mechanical polishing of dielectric thin films for integrated giant magnetoresistance non-volatile memories | |
JP2006080264A (en) | Manufacturing method of semiconductor device | |
JPH11274120A (en) | Manufacture of integrated circuit |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: SHARP LABORATORIES OF AMERICA, INC., WASHINGTON Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:PAN, WEI;EVANS, DAVID R.;BURMASTER, ALLEN W.;REEL/FRAME:013889/0579 Effective date: 20030317 |
|
STCF | Information on status: patent grant |
Free format text: PATENTED CASE |
|
FPAY | Fee payment |
Year of fee payment: 4 |
|
FPAY | Fee payment |
Year of fee payment: 8 |
|
AS | Assignment |
Owner name: SHARP KABUSHIKI KAISHA, JAPAN Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:SHARP LABORATORIES OF AMERICA, INC.;REEL/FRAME:028443/0415 Effective date: 20120626 |
|
FEPP | Fee payment procedure |
Free format text: PAYER NUMBER DE-ASSIGNED (ORIGINAL EVENT CODE: RMPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY Free format text: PAYOR NUMBER ASSIGNED (ORIGINAL EVENT CODE: ASPN); ENTITY STATUS OF PATENT OWNER: LARGE ENTITY |
|
AS | Assignment |
Owner name: INTELLECTUAL PROPERTIES I KFT., HUNGARY Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:SHARP KABUSHIKI KAISHA;REEL/FRAME:029567/0218 Effective date: 20120924 |
|
AS | Assignment |
Owner name: XENOGENIC DEVELOPMENT LIMITED LIABILITY COMPANY, D Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:INTELLECTUAL PROPERTIES I KFT.;REEL/FRAME:029614/0607 Effective date: 20120926 |
|
FPAY | Fee payment |
Year of fee payment: 12 |