US7626195B2 - Organic light-emitting device and method of fabricating the same - Google Patents

Organic light-emitting device and method of fabricating the same Download PDF

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US7626195B2
US7626195B2 US10/945,969 US94596904A US7626195B2 US 7626195 B2 US7626195 B2 US 7626195B2 US 94596904 A US94596904 A US 94596904A US 7626195 B2 US7626195 B2 US 7626195B2
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layer
reflective metal
emitting device
organic light
oxide layer
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Hyun-Eok Shin
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Samsung Display Co Ltd
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Samsung Mobile Display Co Ltd
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    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/80—Constructional details
    • H10K59/805—Electrodes
    • H10K59/8051—Anodes
    • H10K59/80518—Reflective anodes, e.g. ITO combined with thick metallic layers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00—Organic light-emitting devices
    • H10K50/80—Constructional details
    • H10K50/805—Electrodes
    • H10K50/81—Anodes
    • H10K50/818—Reflective anodes, e.g. ITO combined with thick metallic layers
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B33/00—Electroluminescent light sources
    • H05B33/12—Light sources with substantially two-dimensional radiating surfaces
    • H05B33/26—Light sources with substantially two-dimensional radiating surfaces characterised by the composition or arrangement of the conductive material used as an electrode
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K2102/00—Constructional details relating to the organic devices covered by this subclass
    • H10K2102/301—Details of OLEDs
    • H10K2102/302—Details of OLEDs of OLED structures
    • H10K2102/3023—Direction of light emission
    • H10K2102/3026—Top emission

Definitions

  • the present invention relates to an organic light-emitting device and a method of fabricating the same and, more particularly, to an organic light-emitting device with a reflective anode and a method of fabricating the same.
  • an organic light-emitting device comprises an anode, an organic emission layer placed on the anode, and a cathode placed on the organic emission layer.
  • a hole is injected from the anode into the organic emission layer, and an electron is injected from the cathode into the organic emission layer.
  • the hole and electron injected into the organic emission layer are combined to create excitons, wherein an electronic transition of the excitons from an excited state to a ground state causes light to be emitted.
  • the anode is formed in a reflective type to reflect the light
  • the cathode is formed in a transmissive type to transmit the light, so that the light emitted from the organic emission layer can be emitted in a direction toward the cathode.
  • the reflective anode is made of a conductive material which has excellent reflective properties and a proper work function, but there is no single material that simultaneously has such properties and is applicable. Therefore, to satisfy the foregoing properties, the reflective anode has been made of material having a multi-layered structure.
  • the conventional organic light-emitting device suffers from one or more of the following disadvantages: deterioration of the interfacial properties between a reflective metal layer and a transparent conductive layer may cause the reflective metal layer to have low reflectivity; and corrosion caused by a galvanic phenomenon may occur between the reflective metal layer and the transparent conductive layer, wherein the corrosion may be spread along an interface between the reflective metal layer and the transparent conductive layer.
  • an aspect of the present invention provides an organic light-emitting device comprising: an anode including a reflective metal layer, a transparent conductive layer, and a reflective metal oxide layer interposed therebetween; a cathode; and an organic functional layer interposed between the transparent conductive layer of the anode and the cathode, and provided with at least an organic emission layer.
  • the reflective metal oxide layer is a native oxide layer or a sputtered oxide layer.
  • the reflective metal oxide layer may have a thickness of 10 to 50 ⁇ .
  • Another aspect of the invention provides a method of fabricating an organic light-emitting device, the method comprising the steps of: providing a substrate; forming a reflective metal layer on the substrate; forming a reflective metal oxide layer on the reflective metal layer; forming a transparent conductive layer on the reflective metal oxide layer; forming an organic functional layer having at least an organic emission layer on the transparent conductive layer; and forming a cathode on the organic functional layer.
  • the step of forming the reflective metal oxide layer is performed by exposing the reflective metal layer to air or using a sputtering method.
  • the steps of forming the reflective metal layer and the reflective metal oxide layer are performed in situ by the sputtering method.
  • FIG. 1 is a cross-sectional view for illustrating a method of fabricating an organic light-emitting device with a conventional reflective anode
  • FIG. 2 is a cross-sectional view for illustrating a method of fabricating an organic light-emitting device according to an embodiment of the present invention
  • FIG. 3 is a cross-sectional view for illustrating a method of fabricating an organic light-emitting device according to another embodiment of the present invention
  • FIG. 4 is a graph showing the reflectivity of reflective anodes based on an example and a comparative example 1, and the reflectivity of a reflective metal layer based on a comparative example 2 with respect to a wavelength;
  • FIG. 5 is a picture showing a reflective anode according to a comparative example 1.
  • FIG. 1 is a cross-sectional view for illustrating a method of fabricating an organic light-emitting device with a conventional reflective anode.
  • an aluminum layer 12 a and an indium tin oxide (ITO) layer 12 b are sequentially formed on a substrate 10 .
  • a photoresist pattern is formed on the ITO layer 12 b , and the ITO layer 12 b and the aluminum layer 12 a are sequentially etched, using the photoresist pattern as a mask.
  • an anode 12 is formed to have stacked structure of the aluminum layer 12 a and the ITO layer 12 b .
  • the photoresist pattern is removed using a strip solution.
  • an organic emission layer (not shown) is formed on the anode 12
  • a cathode is formed on the organic emission layer, thereby fabricating the organic light-emitting device.
  • the ITO layer 12 b of the anode 12 has a high work function and is transparent, and the aluminum layer 12 a has excellent reflective properties. Therefore, the anode 12 not only readily injects the hole to the organic emission layer, but also effectively reflects the light emitted from the organic emission layer.
  • a work function difference between the aluminum layer 12 b and the ITO layer 12 b is relatively large, so that the interfacial properties therebetween may be deteriorated. Such deterioration of the interfacial properties may cause the aluminum layer 12 a , i.e., the reflective anode 12 to have low reflectivity.
  • the aluminum layer 12 a and the ITO layer 12 b are also exposed to the strip solution. Therefore, corrosion caused by a galvanic phenomenon may occur between the aluminum layer 12 a and the ITO layer 12 b , wherein the corrosion may be spread along an interface between the aluminum layer 12 a and the ITO layer 12 b.
  • FIG. 2 is a cross-sectional view for illustrating a method of fabricating an organic light-emitting device according to an embodiment of the present invention.
  • the substrate 100 comprises at least one thin film transistor.
  • a reflective metal layer 110 a is formed on the substrate 100 .
  • the reflective metal layer 110 a is a metal layer for reflecting light and is preferably made of a metal material having excellent reflective properties, that is, reflective metal material.
  • the reflective metal layer 110 a is made of aluminum (Al), aluminum alloy, silver (Ag), or silver alloy. More preferably, the reflective metal layer 110 a is made of aluminum-neodymium (AlNd). Generally, such reflective metal materials have low work functions.
  • the reflective metal layer 110 a is preferably formed by a sputtering method. Also, the reflective metal layer 110 a preferably has a thickness of 500 ⁇ or more. If the reflective metal layer 110 a has a thickness of below 500 ⁇ , it does not have proper reflectivity.
  • a reflective metal oxide layer 110 b is formed on the reflective metal layer 110 a .
  • the reflective metal oxide layer 110 b is preferably made of an oxide layer of the metal material employed in forming the reflective metal layer 110 a .
  • the reflective metal oxide layer 110 b may be made of an oxide layer of metal material which is different from the metal material employed in forming the reflective metal layer 110 a .
  • the reflective metal oxide layer 110 b is preferably made of an aluminum oxide layer, an aluminum-alloy oxide layer, a silver oxide layer, or a silver-alloy oxide layer.
  • the reflective metal oxide layer 110 b can be formed by exposing the reflective metal layer 110 a formed on the substrate 10 to air.
  • the reflective metal layer 110 a reacts to oxygen of the air, thereby forming the reflective metal oxide layer 10 b as a native oxide layer.
  • the time of exposing the reflective metal layer 110 a to the air is preferably twenty minutes or more.
  • the reflective metal oxide layer 110 b can be formed by the sputtering method after forming the reflective metal layer 110 a .
  • the reflective metal oxide layer 110 b is a sputtered oxide layer.
  • the reflective metal layer 110 a and the reflective metal oxide layer 110 b are formed in situ by the sputtering method.
  • the reflective metal material is processed by the sputtering method at a vacuum atmosphere so as to form the reflective metal layer 110 a , and then the reflective metal material is processed by the sputtering method at an oxygen atmosphere so as to form the reflective metal oxide layer 110 b.
  • a transparent conductive layer 110 c is formed on the reflective metal oxide layer 110 b .
  • the transparent conductive layer 110 c is preferably made of an indium tin oxide (ITO) layer or an indium zinc oxide (IZO) layer, which has conductivity, transparency, and a high work function.
  • ITO indium tin oxide
  • IZO indium zinc oxide
  • Such transparent conductive layer 110 c preferably has a thickness of 50 to 200 ⁇ .
  • a photoresist pattern is formed on the transparent conductive layer 110 c . Then, the transparent conductive layer 110 c , the reflective metal oxide layer 110 b , and the reflective metal layer 110 a are sequentially etched, using the photoresist pattern as a mask. Thus, a reflective anode 110 is formed.
  • the reflective anode 110 has a layered structure of the reflective metal layer 110 a , the reflective metal oxide layer 110 b , and the transparent conductive layer 110 c , in sequence. Thereafter, the photoresist pattern is removed using a strip solution.
  • the reflective metal oxide layer 110 b acts to prevent the reflective metal layer 110 a from contacting with the transparent conductive layer 110 c . Therefore, even if the work function difference between the reflective metal layer 110 a and the transparent conductive layer 110 c is large, interfacial properties therebetween are prevented from being deteriorated. In other words, the reflectivity of the reflective anode 110 is enhanced. Further, even though both the reflective metal layer 110 a and the transparent conductive layer 110 c are also exposed to the strip solution while the photoresist pattern is removed by the strip solution, corrosion caused by a galvanic phenomenon does not occur therebetween because the reflective metal layer 110 a and the transparent conductive layer 110 c are not in contact with each other. Therefore, the corrosion is prevented from spreading along an interface between the reflective metal layer 110 a and the transparent conductive layer 110 c.
  • the reflective metal oxide layer 110 b preferably has a thickness of 50 ⁇ or below.
  • the reflective metal oxide layer 110 b preferably has a thickness of 10 ⁇ or more. Consequently, the reflective metal oxide layer 110 b preferably has a thickness of 10 to 50 ⁇ .
  • a pixel defining layer 120 may be formed on the transparent conductive layer 110 c .
  • the pixel defining layer 120 is exposed using a photomask, thereby forming an opening 120 a in the pixel defining layer 120 .
  • a predetermined region of the transparent conductive layer 110 c is exposed.
  • an emission region of the organic light-emitting device is defined by the opening 120 a .
  • the pixel defining layer 120 is preferably made of benzocyclobutene (BCB), acrylic photoresist, phenol photoresist, or polyimide photoresist.
  • an organic functional layer 155 having at least an organic emission layer 140 is formed on the exposed transparent conductive layer 110 c .
  • a hole transporting layer 130 is preferably formed on the transparent conductive layer 110 c before forming the organic emission layer 140 . More preferably, a hole injection layer (not shown) is formed on the transparent conductive layer 110 c before forming the hole transporting layer 130 .
  • an electron transporting layer 150 is preferably formed on the organic emission layer 140 . More preferably, an electron injection layer (not shown) is formed on the electron transporting layer 150 .
  • a cathode 160 is formed on the organic functional layer 155 .
  • the cathode 160 is preferably made of magnesium (Mg), calcium (Ca), aluminum (Al), silver (Ag), or barium (Ba), having a thickness as much as the light can be transmitted therethrough.
  • the organic light-emitting device can be fabricated with the reflective anode 110 , the cathode 160 , and the organic functional layer 155 interposed therebetween.
  • the light emitted from the organic emission layer 140 is emitted through the cathode 160 toward the outside, and is also reflected from the reflective metal layer 110 a of the anode 110 , thereby being emitted through the cathode 160 toward the outside.
  • the reflective metal layer 110 a i.e., the anode 110 is improved in the reflectivity, so that the intensity of the light emitted to the outside is enhanced, that is, the brightness of the organic light-emitting device is increased.
  • FIG. 3 is a cross-sectional view for illustrating a method of fabricating an organic light-emitting device according to another embodiment of the present invention.
  • the substrate 200 comprises at least one thin film transistor.
  • a cathode 210 is formed on the substrate 200 .
  • the cathode 210 is preferably made of magnesium (Mg), calcium (Ca), aluminum (Al), silver (Ag), or barium (Ba), having a thickness as much as the light can be transmitted therethrough.
  • a pixel defining layer 220 is formed on the cathode 210 .
  • the pixel defining layer 220 is exposed using a photomask, thereby forming an opening 220 a in the pixel defining layer 220 .
  • an emission region of the organic light-emitting device is defined by the opening 220 a .
  • the pixel defining layer 120 is preferably made of benzocyclobutene (BCB), acrylic photoresist, phenol photoresist, or polyimide photoresist.
  • an organic functional layer 255 having at least an organic emission layer 240 is formed on the exposed cathode 210 .
  • an electron transporting layer 230 is preferably formed on the cathode 210 before forming the organic emission layer 240 . More preferably, an electron injection layer (not shown) is formed on the cathode 210 before forming the electron transporting layer 230 .
  • a hole transporting layer 250 is preferably formed on the organic emission layer 240 . More preferably, a hole injection layer (not shown) is formed on the hole transporting layer 250 .
  • a transparent conductive layer 260 a is formed on the organic functional layer 255 .
  • the transparent conductive layer 260 a is preferably made of an indium tin oxide (ITO) layer or an indium zinc oxide (IZO) layer, which has conductivity, transparency, and a high work function.
  • ITO indium tin oxide
  • IZO indium zinc oxide
  • Such transparent conductive layer 260 a preferably has a thickness of 50 to 200 ⁇ .
  • a reflective metal oxide layer 260 b is formed on the transparent conductive layer 260 a .
  • the reflective metal oxide layer 260 b is preferably made of an oxide of the metal material employed for the following reflective metal layer. But, the reflective metal oxide layer 110 b may be made of an oxide layer of metal material which is different from the metal material employed in forming the reflective metal layer 110 a .
  • the reflective metal oxide layer 260 b is preferably made of an aluminum oxide layer, an aluminum-alloy oxide layer, a silver oxide layer, or a silver-alloy oxide layer.
  • the reflective metal oxide layer 260 b can be formed by the sputtering method. In this case, the reflective metal oxide layer 260 b is a sputtered oxide layer.
  • a reflective metal layer 260 c is formed on the reflective metal oxide layer 260 b .
  • the reflective metal layer 260 c is a metal layer for reflecting light and is preferably made of a metal material having excellent reflective properties, that is, reflective metal material.
  • the reflective metal layer 260 c is made of aluminum (Al), aluminum alloy, silver (Ag), or silver alloy. More preferably, the reflective metal layer 260 c is made of aluminum-neodymium (AlNd). Generally, such reflective metal materials have low work functions.
  • the reflective metal layer 260 c is preferably formed by the sputtering method. Also, the reflective metal layer 260 c preferably has a thickness of 500 ⁇ or more. If the reflective metal layer 260 c has a thickness of below 500 ⁇ , it does not have proper reflectivity.
  • the reflective metal oxide layer 260 b and the reflective metal layer 260 c are formed in situ by the sputtering method.
  • the reflective metal material is processed by the sputtering method at an oxygen atmosphere so as to form the reflective metal oxide layer 260 b
  • the reflective metal material is processed by the sputtering method at a vacuum atmosphere so as to form the reflective metal layer 260 c .
  • a reflective anode 260 is formed.
  • the reflective anode 260 has a layered structure of the transparent conductive layer 260 a , the reflective metal oxide layer 260 b , and the reflective metal layer 260 a , in sequence.
  • the reflective metal oxide layer 260 b acts to prevent the reflective metal layer 260 c from contacting with the transparent conductive layer 260 a . Therefore, even if the work function difference between the reflective metal layer 260 c and the transparent conductive layer 260 a is large, interfacial properties therebetween are prevented from being deteriorated. In other words, the reflective anode 260 , i.e., the reflective metal layer 260 c has improved reflective properties.
  • the reflective metal oxide layer 260 b preferably has a thickness of 50 ⁇ or below.
  • the reflective metal oxide layer 260 b preferably has a thickness of 10 ⁇ or more. Consequently, the reflective metal oxide layer 260 b preferably has a thickness of 10 to 50 ⁇ .
  • the organic light-emitting device can be fabricated with the cathode 210 , the anode 260 , and the organic functional layer 255 interposed therebetween.
  • the light emitted from the organic emission layer 240 is emitted through the cathode 210 toward the outside, and is also reflected from the reflective metal layer 210 c of the anode 260 , thereby being emitted through the cathode 210 toward the outside.
  • the reflective metal layer 210 c i.e., the anode 260 is improved in the reflectivity, so that the intensity of the light emitted to the outside is enhanced, that is, the brightness of the organic light-emitting device is increased.
  • An aluminum layer (reflective metal layer) was formed on a substrate to a thickness of about 1,000 ⁇ , and the substrate with the aluminum layer was exposed to the air for twenty minutes, thereby forming an aluminum oxide layer (reflective metal oxide layer) having a thickness of about 30 ⁇ on the aluminum layer. Then, ITO (transparent conductive layer) having a thickness of about 100 ⁇ was formed on the aluminum oxide layer. Thereafter, a photoresist pattern was formed on the transparent conductive layer, and then the transparent conductive layer, the aluminum oxide layer, and the aluminum layer are in turn etched using the photoresist pattern as a mask, thereby forming the reflective anode.
  • a reflective anode was formed by the same method as the example except forming an aluminum layer (reflective metal layer) with a thickness of about 1,000 ⁇ on a substrate, and forming the ITO (transparent conductive layer) having a thickness of about 100 ⁇ on the aluminum layer.
  • An aluminum layer (reflective metal layer) was formed on a substrate to a thickness of about 1,000 ⁇ .
  • FIG. 4 is a graph showing the reflectivity of reflective anodes based on the example and the comparative example 1, and the reflectivity of a reflective metal layer based on the comparative example 2 with respect to a wavelength.
  • the reflectivity thereof is approximately uniform as 100% with respect to all incident wavelengths.
  • the reflectivity of the reflective anode according to the comparative example 1 (referred to as “b” in FIG. 4 ) is approximately 55% through 87%, wherein the shorter the wavelength is the lower the reflectivity is.
  • the reflectivity of the reflective anode according to the example (referred to as “a” in FIG. 4 ) is approximately 85% through 95%, wherein the shorter the wavelength is the lower the reflectivity is, but the reflectivity is slowly decreased as compared with the comparative example 2.
  • the reflectivity of the reflective anode according to the example is substantially improved as compared with that of the comparative example 1, and the reflectivity is not substantially changed depending on the wavelength.
  • the reflective anode improved in the reflectivity enhances the brightness of the organic light-emitting device.
  • the reflectivity is not substantially changed depending on the wavelength. Therefore, in the case of a full-colored organic light-emitting device, the brightness is uniformly realized according to colors.
  • FIG. 5 is a picture showing the reflective anode according to the comparative example 1. Referring to FIG. 5 , in the reflective anode according to the comparative example 1, corrosion caused by a galvanic phenomenon occurred between the aluminum layer and the transparent conductive layer, and the corrosion was spread along an interface between the aluminum layer and the transparent conductive layer.
  • the present invention provides an organic light-emitting device with a reflective anode and a method of fabricating the same, in which the reflective anode has high reflectivity, the reflectivity thereof is not substantially changed depending on wavelengths, and the reflective anode is free from defects caused by a galvanic phenomenon.
  • the failure rate of the organic light-emitting device is decreased, the brightness thereof is increased, and the brightness is uniformly realized according to colors in the case of a full-colored organic light-emitting device.

Abstract

An organic light-emitting device is constructed with an anode provided with a reflective metal layer, a transparent conductive layer, and a reflective metal oxide layer interposed therebetween, a cathode, and an organic functional layer interposed between the transparent conductive layer of the anode and the cathode, and provided with at least an organic emission layer. With this configuration, the reflective anode has high reflectivity, the reflectivity thereof is not substantially changed depending on wavelengths, and the reflective anode is free from defects caused by a galvanic phenomenon.

Description

CLAIM OF PRIORITY
This application claims all the benefits accruing under 35 U.S.C. §119 from Korea Patent Application No. 2003-86149 filed on Nov. 29, 2003, the disclosure of which is incorporated herein by reference in its entirety.
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to an organic light-emitting device and a method of fabricating the same and, more particularly, to an organic light-emitting device with a reflective anode and a method of fabricating the same.
2. Description of the Related Art
Generally, an organic light-emitting device comprises an anode, an organic emission layer placed on the anode, and a cathode placed on the organic emission layer. In the organic light-emitting device, when a voltage is applied between the anode and the cathode, a hole is injected from the anode into the organic emission layer, and an electron is injected from the cathode into the organic emission layer. The hole and electron injected into the organic emission layer are combined to create excitons, wherein an electronic transition of the excitons from an excited state to a ground state causes light to be emitted.
In the organic light-emitting device, the anode is formed in a reflective type to reflect the light, and the cathode is formed in a transmissive type to transmit the light, so that the light emitted from the organic emission layer can be emitted in a direction toward the cathode.
Here, it is preferable that the reflective anode is made of a conductive material which has excellent reflective properties and a proper work function, but there is no single material that simultaneously has such properties and is applicable. Therefore, to satisfy the foregoing properties, the reflective anode has been made of material having a multi-layered structure.
However, the conventional organic light-emitting device suffers from one or more of the following disadvantages: deterioration of the interfacial properties between a reflective metal layer and a transparent conductive layer may cause the reflective metal layer to have low reflectivity; and corrosion caused by a galvanic phenomenon may occur between the reflective metal layer and the transparent conductive layer, wherein the corrosion may be spread along an interface between the reflective metal layer and the transparent conductive layer.
SUMMARY OF THE INVENTION
It is an object of the present invention to provide an improved organic light-emitting device.
It is further an objective of the present invention to provide an organic light-emitting device with a reflective anode and a method of fabricating the same, in which the reflective anode has high reflectivity and is free from defects caused by a galvanic phenomenon.
To achieve the above and other objectives, an aspect of the present invention provides an organic light-emitting device comprising: an anode including a reflective metal layer, a transparent conductive layer, and a reflective metal oxide layer interposed therebetween; a cathode; and an organic functional layer interposed between the transparent conductive layer of the anode and the cathode, and provided with at least an organic emission layer.
Preferably, the reflective metal oxide layer is a native oxide layer or a sputtered oxide layer. And the reflective metal oxide layer may have a thickness of 10 to 50 Å.
Another aspect of the invention provides a method of fabricating an organic light-emitting device, the method comprising the steps of: providing a substrate; forming a reflective metal layer on the substrate; forming a reflective metal oxide layer on the reflective metal layer; forming a transparent conductive layer on the reflective metal oxide layer; forming an organic functional layer having at least an organic emission layer on the transparent conductive layer; and forming a cathode on the organic functional layer.
The step of forming the reflective metal oxide layer is performed by exposing the reflective metal layer to air or using a sputtering method. Preferably, the steps of forming the reflective metal layer and the reflective metal oxide layer are performed in situ by the sputtering method.
BRIEF DESCRIPTION OF THE DRAWINGS
A more complete appreciation of the present invention, and many of the above and other features and advantages of the present invention, will be readily apparent as the same becomes better understood by reference to the following detailed description when considered in conjunction with the accompanying drawings in which like reference symbols indicate the same or similar components, wherein:
FIG. 1 is a cross-sectional view for illustrating a method of fabricating an organic light-emitting device with a conventional reflective anode;
FIG. 2 is a cross-sectional view for illustrating a method of fabricating an organic light-emitting device according to an embodiment of the present invention;
FIG. 3 is a cross-sectional view for illustrating a method of fabricating an organic light-emitting device according to another embodiment of the present invention;
FIG. 4 is a graph showing the reflectivity of reflective anodes based on an example and a comparative example 1, and the reflectivity of a reflective metal layer based on a comparative example 2 with respect to a wavelength; and
FIG. 5 is a picture showing a reflective anode according to a comparative example 1.
 DETAILED DESCRIPTION OF THE INVENTION
The present invention will now be described more fully hereinafter with reference to the accompanying drawings, in which preferred embodiments of the invention are shown. This invention may, however, be embodied in different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art. In the drawings, a layer placed on another layer or a substrate indicates that a layer is directly formed on another layer or the substrate or that a layer is formed thereon via a third layer. Like numbers refer to like elements throughout the specification.
FIG. 1 is a cross-sectional view for illustrating a method of fabricating an organic light-emitting device with a conventional reflective anode.
Referring to FIG. 1, an aluminum layer 12 a and an indium tin oxide (ITO) layer 12 b are sequentially formed on a substrate 10. Then, a photoresist pattern is formed on the ITO layer 12 b, and the ITO layer 12 b and the aluminum layer 12 a are sequentially etched, using the photoresist pattern as a mask. Thus, an anode 12 is formed to have stacked structure of the aluminum layer 12 a and the ITO layer 12 b. Thereafter, the photoresist pattern is removed using a strip solution. Subsequently, an organic emission layer (not shown) is formed on the anode 12, and a cathode (not shown) is formed on the organic emission layer, thereby fabricating the organic light-emitting device.
The ITO layer 12 b of the anode 12 has a high work function and is transparent, and the aluminum layer 12 a has excellent reflective properties. Therefore, the anode 12 not only readily injects the hole to the organic emission layer, but also effectively reflects the light emitted from the organic emission layer.
However, In general, a work function difference between the aluminum layer 12 b and the ITO layer 12 b is relatively large, so that the interfacial properties therebetween may be deteriorated. Such deterioration of the interfacial properties may cause the aluminum layer 12 a, i.e., the reflective anode 12 to have low reflectivity. Further, while the photoresist pattern is removed by the strip solution, the aluminum layer 12 a and the ITO layer 12 b are also exposed to the strip solution. Therefore, corrosion caused by a galvanic phenomenon may occur between the aluminum layer 12 a and the ITO layer 12 b, wherein the corrosion may be spread along an interface between the aluminum layer 12 a and the ITO layer 12 b.
FIG. 2 is a cross-sectional view for illustrating a method of fabricating an organic light-emitting device according to an embodiment of the present invention.
Referring to FIG. 2, there is provided a substrate 100. In the case of an active matrix type organic light-emitting device, the substrate 100 comprises at least one thin film transistor.
A reflective metal layer 110 a is formed on the substrate 100. The reflective metal layer 110 a is a metal layer for reflecting light and is preferably made of a metal material having excellent reflective properties, that is, reflective metal material. Preferably, the reflective metal layer 110 a is made of aluminum (Al), aluminum alloy, silver (Ag), or silver alloy. More preferably, the reflective metal layer 110 a is made of aluminum-neodymium (AlNd). Generally, such reflective metal materials have low work functions.
Further, the reflective metal layer 110 a is preferably formed by a sputtering method. Also, the reflective metal layer 110 a preferably has a thickness of 500 Å or more. If the reflective metal layer 110 a has a thickness of below 500 Å, it does not have proper reflectivity.
A reflective metal oxide layer 110 b is formed on the reflective metal layer 110 a. The reflective metal oxide layer 110 b is preferably made of an oxide layer of the metal material employed in forming the reflective metal layer 110 a. But, the reflective metal oxide layer 110 b may be made of an oxide layer of metal material which is different from the metal material employed in forming the reflective metal layer 110 a. The reflective metal oxide layer 110 b is preferably made of an aluminum oxide layer, an aluminum-alloy oxide layer, a silver oxide layer, or a silver-alloy oxide layer.
The reflective metal oxide layer 110 b can be formed by exposing the reflective metal layer 110 a formed on the substrate 10 to air. Thus, the reflective metal layer 110 a reacts to oxygen of the air, thereby forming the reflective metal oxide layer 10 b as a native oxide layer. At this time, the time of exposing the reflective metal layer 110 a to the air is preferably twenty minutes or more. Alternately, the reflective metal oxide layer 110 b can be formed by the sputtering method after forming the reflective metal layer 110 a. In this case, the reflective metal oxide layer 110 b is a sputtered oxide layer. Preferably, the reflective metal layer 110 a and the reflective metal oxide layer 110 b are formed in situ by the sputtering method. In this case, the reflective metal material is processed by the sputtering method at a vacuum atmosphere so as to form the reflective metal layer 110 a, and then the reflective metal material is processed by the sputtering method at an oxygen atmosphere so as to form the reflective metal oxide layer 110 b.
A transparent conductive layer 110 c is formed on the reflective metal oxide layer 110 b. The transparent conductive layer 110 c is preferably made of an indium tin oxide (ITO) layer or an indium zinc oxide (IZO) layer, which has conductivity, transparency, and a high work function. Such transparent conductive layer 110 c preferably has a thickness of 50 to 200 Å.
A photoresist pattern is formed on the transparent conductive layer 110 c. Then, the transparent conductive layer 110 c, the reflective metal oxide layer 110 b, and the reflective metal layer 110 a are sequentially etched, using the photoresist pattern as a mask. Thus, a reflective anode 110 is formed. The reflective anode 110 has a layered structure of the reflective metal layer 110 a, the reflective metal oxide layer 110 b, and the transparent conductive layer 110 c, in sequence. Thereafter, the photoresist pattern is removed using a strip solution.
In the anode 110, the reflective metal oxide layer 110 b acts to prevent the reflective metal layer 110 a from contacting with the transparent conductive layer 110 c. Therefore, even if the work function difference between the reflective metal layer 110 a and the transparent conductive layer 110 c is large, interfacial properties therebetween are prevented from being deteriorated. In other words, the reflectivity of the reflective anode 110 is enhanced. Further, even though both the reflective metal layer 110 a and the transparent conductive layer 110 c are also exposed to the strip solution while the photoresist pattern is removed by the strip solution, corrosion caused by a galvanic phenomenon does not occur therebetween because the reflective metal layer 110 a and the transparent conductive layer 110 c are not in contact with each other. Therefore, the corrosion is prevented from spreading along an interface between the reflective metal layer 110 a and the transparent conductive layer 110 c.
Electric conduction between the reflective metal layer 110 a and the transparent conductive layer 110 c may be implemented by a tunneling effect of an electric charge through the reflective metal oxide layer 110 b. Therefore, the reflective metal oxide layer 110 b preferably has a thickness of 50 Å or below. Besides, to prevent the reflective metal layer 110 a from contacting with the transparent conductive layer 110 c, the reflective metal oxide layer 110 b preferably has a thickness of 10 Å or more. Consequently, the reflective metal oxide layer 110 b preferably has a thickness of 10 to 50 Å.
A pixel defining layer 120 may be formed on the transparent conductive layer 110 c. The pixel defining layer 120 is exposed using a photomask, thereby forming an opening 120 a in the pixel defining layer 120. Through the opening 120 a, a predetermined region of the transparent conductive layer 110 c is exposed. Further, an emission region of the organic light-emitting device is defined by the opening 120 a. The pixel defining layer 120 is preferably made of benzocyclobutene (BCB), acrylic photoresist, phenol photoresist, or polyimide photoresist.
Further, an organic functional layer 155 having at least an organic emission layer 140 is formed on the exposed transparent conductive layer 110 c. In forming the organic functional layer 155, a hole transporting layer 130 is preferably formed on the transparent conductive layer 110 c before forming the organic emission layer 140. More preferably, a hole injection layer (not shown) is formed on the transparent conductive layer 110 c before forming the hole transporting layer 130. Further, in forming the organic functional layer 155, an electron transporting layer 150 is preferably formed on the organic emission layer 140. More preferably, an electron injection layer (not shown) is formed on the electron transporting layer 150.
A cathode 160 is formed on the organic functional layer 155. The cathode 160 is preferably made of magnesium (Mg), calcium (Ca), aluminum (Al), silver (Ag), or barium (Ba), having a thickness as much as the light can be transmitted therethrough.
Thus, the organic light-emitting device can be fabricated with the reflective anode 110, the cathode 160, and the organic functional layer 155 interposed therebetween. In the organic light-emitting device, the light emitted from the organic emission layer 140 is emitted through the cathode 160 toward the outside, and is also reflected from the reflective metal layer 110 a of the anode 110, thereby being emitted through the cathode 160 toward the outside. As described above, the reflective metal layer 110 a, i.e., the anode 110 is improved in the reflectivity, so that the intensity of the light emitted to the outside is enhanced, that is, the brightness of the organic light-emitting device is increased.
FIG. 3 is a cross-sectional view for illustrating a method of fabricating an organic light-emitting device according to another embodiment of the present invention.
Referring to FIG. 3, there is provided a substrate 200. In the case of an active matrix type organic light-emitting device, the substrate 200 comprises at least one thin film transistor.
A cathode 210 is formed on the substrate 200. The cathode 210 is preferably made of magnesium (Mg), calcium (Ca), aluminum (Al), silver (Ag), or barium (Ba), having a thickness as much as the light can be transmitted therethrough.
A pixel defining layer 220 is formed on the cathode 210. The pixel defining layer 220 is exposed using a photomask, thereby forming an opening 220 a in the pixel defining layer 220. Through the opening 220 a, a predetermined region of the cathode 210 is exposed. Further, an emission region of the organic light-emitting device is defined by the opening 220 a. The pixel defining layer 120 is preferably made of benzocyclobutene (BCB), acrylic photoresist, phenol photoresist, or polyimide photoresist.
Further, an organic functional layer 255 having at least an organic emission layer 240 is formed on the exposed cathode 210. In forming the organic functional layer 255, an electron transporting layer 230 is preferably formed on the cathode 210 before forming the organic emission layer 240. More preferably, an electron injection layer (not shown) is formed on the cathode 210 before forming the electron transporting layer 230. Further, in forming the organic functional layer 255, a hole transporting layer 250 is preferably formed on the organic emission layer 240. More preferably, a hole injection layer (not shown) is formed on the hole transporting layer 250.
A transparent conductive layer 260 a is formed on the organic functional layer 255. The transparent conductive layer 260 a is preferably made of an indium tin oxide (ITO) layer or an indium zinc oxide (IZO) layer, which has conductivity, transparency, and a high work function. Such transparent conductive layer 260 a preferably has a thickness of 50 to 200 Å.
A reflective metal oxide layer 260 b is formed on the transparent conductive layer 260 a. The reflective metal oxide layer 260 b is preferably made of an oxide of the metal material employed for the following reflective metal layer. But, the reflective metal oxide layer 110 b may be made of an oxide layer of metal material which is different from the metal material employed in forming the reflective metal layer 110 a. The reflective metal oxide layer 260 b is preferably made of an aluminum oxide layer, an aluminum-alloy oxide layer, a silver oxide layer, or a silver-alloy oxide layer. The reflective metal oxide layer 260 b can be formed by the sputtering method. In this case, the reflective metal oxide layer 260 b is a sputtered oxide layer. A reflective metal layer 260 c is formed on the reflective metal oxide layer 260 b. The reflective metal layer 260 c is a metal layer for reflecting light and is preferably made of a metal material having excellent reflective properties, that is, reflective metal material. Preferably, the reflective metal layer 260 c is made of aluminum (Al), aluminum alloy, silver (Ag), or silver alloy. More preferably, the reflective metal layer 260 c is made of aluminum-neodymium (AlNd). Generally, such reflective metal materials have low work functions.
Further, the reflective metal layer 260 c is preferably formed by the sputtering method. Also, the reflective metal layer 260 c preferably has a thickness of 500 Å or more. If the reflective metal layer 260 c has a thickness of below 500 Å, it does not have proper reflectivity.
Preferably, the reflective metal oxide layer 260 b and the reflective metal layer 260 c are formed in situ by the sputtering method. In this case, the reflective metal material is processed by the sputtering method at an oxygen atmosphere so as to form the reflective metal oxide layer 260 b, and then the reflective metal material is processed by the sputtering method at a vacuum atmosphere so as to form the reflective metal layer 260 c. Thus, a reflective anode 260 is formed. The reflective anode 260 has a layered structure of the transparent conductive layer 260 a, the reflective metal oxide layer 260 b, and the reflective metal layer 260 a, in sequence.
In the anode 260, the reflective metal oxide layer 260 b acts to prevent the reflective metal layer 260 c from contacting with the transparent conductive layer 260 a. Therefore, even if the work function difference between the reflective metal layer 260 c and the transparent conductive layer 260 a is large, interfacial properties therebetween are prevented from being deteriorated. In other words, the reflective anode 260, i.e., the reflective metal layer 260 c has improved reflective properties.
Electric conduction between the reflective metal layer 260 c and the transparent conductive layer 260 a may be implemented by a tunneling effect of an electric charge through the reflective metal oxide layer 260 b. Therefore, the reflective metal oxide layer 260 b preferably has a thickness of 50 Å or below. Besides, to prevent the reflective metal layer 260 a from contacting with the transparent conductive layer 260 c, the reflective metal oxide layer 260 b preferably has a thickness of 10 Å or more. Consequently, the reflective metal oxide layer 260 b preferably has a thickness of 10 to 50 Å.
Thus, the organic light-emitting device can be fabricated with the cathode 210, the anode 260, and the organic functional layer 255 interposed therebetween. In the organic light-emitting device, the light emitted from the organic emission layer 240 is emitted through the cathode 210 toward the outside, and is also reflected from the reflective metal layer 210 c of the anode 260, thereby being emitted through the cathode 210 toward the outside. As described above, the reflective metal layer 210 c, i.e., the anode 260 is improved in the reflectivity, so that the intensity of the light emitted to the outside is enhanced, that is, the brightness of the organic light-emitting device is increased.
Hereinbelow, an example of the present invention will be described, and the scope of the present invention is not limited to the following example.
EXAMPLE
An aluminum layer (reflective metal layer) was formed on a substrate to a thickness of about 1,000 Å, and the substrate with the aluminum layer was exposed to the air for twenty minutes, thereby forming an aluminum oxide layer (reflective metal oxide layer) having a thickness of about 30 Å on the aluminum layer. Then, ITO (transparent conductive layer) having a thickness of about 100 Å was formed on the aluminum oxide layer. Thereafter, a photoresist pattern was formed on the transparent conductive layer, and then the transparent conductive layer, the aluminum oxide layer, and the aluminum layer are in turn etched using the photoresist pattern as a mask, thereby forming the reflective anode.
Comparative Example 1
A reflective anode was formed by the same method as the example except forming an aluminum layer (reflective metal layer) with a thickness of about 1,000 Å on a substrate, and forming the ITO (transparent conductive layer) having a thickness of about 100 Å on the aluminum layer.
Comparative Example 2
An aluminum layer (reflective metal layer) was formed on a substrate to a thickness of about 1,000 Å.
FIG. 4 is a graph showing the reflectivity of reflective anodes based on the example and the comparative example 1, and the reflectivity of a reflective metal layer based on the comparative example 2 with respect to a wavelength.
Referring to FIG. 4, in the case of the reflective metal layer according to the comparative example 2 (referred to as “c” in FIG. 4), the reflectivity thereof is approximately uniform as 100% with respect to all incident wavelengths. On the other hand, the reflectivity of the reflective anode according to the comparative example 1 (referred to as “b” in FIG. 4) is approximately 55% through 87%, wherein the shorter the wavelength is the lower the reflectivity is. Further, the reflectivity of the reflective anode according to the example (referred to as “a” in FIG. 4) is approximately 85% through 95%, wherein the shorter the wavelength is the lower the reflectivity is, but the reflectivity is slowly decreased as compared with the comparative example 2.
As a result, the reflectivity of the reflective anode according to the example is substantially improved as compared with that of the comparative example 1, and the reflectivity is not substantially changed depending on the wavelength. Thus, the reflective anode improved in the reflectivity enhances the brightness of the organic light-emitting device. Further, the reflectivity is not substantially changed depending on the wavelength. Therefore, in the case of a full-colored organic light-emitting device, the brightness is uniformly realized according to colors.
FIG. 5 is a picture showing the reflective anode according to the comparative example 1. Referring to FIG. 5, in the reflective anode according to the comparative example 1, corrosion caused by a galvanic phenomenon occurred between the aluminum layer and the transparent conductive layer, and the corrosion was spread along an interface between the aluminum layer and the transparent conductive layer.
As described above, the present invention provides an organic light-emitting device with a reflective anode and a method of fabricating the same, in which the reflective anode has high reflectivity, the reflectivity thereof is not substantially changed depending on wavelengths, and the reflective anode is free from defects caused by a galvanic phenomenon. Hence, the failure rate of the organic light-emitting device is decreased, the brightness thereof is increased, and the brightness is uniformly realized according to colors in the case of a full-colored organic light-emitting device.
While the present invention has been described with reference to a particular embodiment, it is understood that the disclosure has been made for purpose of illustrating the invention by way of examples and is not limited to limit the scope of the invention. And one skilled in the art can make amend and change the present invention without departing from the scope and spirit of the invention.

Claims (17)

1. An organic light-emitting device, comprising:
an anode comprising a reflective metal layer, a transparent conductive layer, and a reflective metal oxide layer interposed between the reflective metal layer and the transparent conductive layer, with the reflective metal oxide layer having a thickness of approximately 10 Å to approximately 50 Å and being an oxide layer of the reflective metal layer, and the reflective metal layer being formed of one material selected from a group consisting of aluminum (Al), aluminum alloy, silver (Ag), and silver alloy;
a cathode;
an organic functional layer interposed between the transparent conductive layer of the anode and the cathode, the organic functional layer comprising at least an organic emission layer; and
a substrate on which one of the anode and the cathode is placed.
2. The organic light-emitting device as claimed in claim 1, wherein the reflective metal layer is formed of aluminum-neodymium (AlNd).
3. The organic light-emitting device as claimed in claim 1, wherein the reflective metal oxide layer is formed of one selected from a group consisting of an aluminum oxide layer, an aluminum-alloy oxide layer, a silver oxide layer, and a silver-alloy oxide layer.
4. The organic light-emitting device as claimed in claim 1, wherein the reflective metal oxide layer is a native oxide layer or a sputtered oxide layer.
5. The organic light-emitting device as claimed in claim 1, wherein the transparent conductive layer is one of an indium tin oxide (ITO) layer and an indium zinc oxide (IZO) layer.
6. The organic light-emitting device as claimed in claim 1, wherein the cathode is formed of one selected from a group consisting of magnesium (Mg), calcium (Ca), aluminum (Al), silver (Ag), and barium (Ba).
7. The organic light-emitting device as claimed in claim 1, wherein the anode is placed on the substrate, and the cathode is placed on the organic functional layer.
8. The organic light-emitting device as claimed in claim 1, wherein the cathode is placed on the substrate, and the anode is placed on the organic functional layer.
9. A method of fabricating an organic light-emitting device, the method comprising the steps of:
providing a substrate;
forming a reflective metal layer on the substrate;
exposing the reflective metal layer to air to form a reflective metal oxide layer with a
thickness of approximately 10 Å to approximately 50 Å;
forming a transparent conductive layer on the reflective metal oxide layer; providing a cathode; and
forming an organic functional layer having at least an organic emission layer between the transparent conductive layer and the cathode, and the reflective metal layer being formed of one material selected from a group consisting of aluminum (Al), aluminum alloy, silver (Ag), and silver alloy.
10. An organic light-emitting device fabricated by the method of claim 9.
11. An organic light-emitting device fabricated by the process of claim 9, comprised of the anode placed on the substrate, and a cathode placed on the organic functional layer.
12. A method of fabricating an organic light-emitting device, the method comprising the steps of:
providing a substrate;
forming a cathode on the substrate;
forming an organic functional layer provided with at least an organic emission layer on the cathode; and
forming an anode on the organic functional layer, wherein the step of forming the anode comprises forming a transparent conductive layer on the organic functional layer, forming a reflective metal oxide layer having a thickness of approximately 10 Å to approximately 50 Å and being an oxide of the reflective metal layer on the transparent conductive layer, and forming a reflective metal layer of one material selected from a group consisting of aluminum, aluminum alloy, silver, and silver alloy on the reflective metal oxide layer.
13. The method as claimed in claim 12, wherein the step of forming the reflective metal oxide layer is performed by a sputtering method.
14. The method as claimed in claim 12, wherein the steps of forming the reflective metal layer and the reflective metal oxide layer is performed in situ by the sputtering method.
15. An organic light-emitting device fabricated by the method of claim 12.
16. A method of fabricating an organic light-emitting device, the method comprising the steps of:
providing a substrate;
forming a reflective metal layer on the substrate;
sputtering reflective metal material at an oxygen atmosphere on the reflective metal layer to form a reflective metal oxide layer with a thickness of approximately 10 Å to approximately 50 Å;
forming a transparent conductive layer on the reflective metal oxide layer;
forming an organic functional layer having at least an organic emission layer on the transparent conductive layer; and
providing a cathode on the organic functional layer, and the reflective metal layer being formed of one material selected from a group consisting of aluminum (Al), aluminum alloy, silver (Ag), and silver alloy.
17. An organic light-emitting device fabricated by the method of claim 16.
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