US8291944B2 - Hydrogen filling method and station - Google Patents
Hydrogen filling method and station Download PDFInfo
- Publication number
- US8291944B2 US8291944B2 US12/515,029 US51502907A US8291944B2 US 8291944 B2 US8291944 B2 US 8291944B2 US 51502907 A US51502907 A US 51502907A US 8291944 B2 US8291944 B2 US 8291944B2
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- cryogenic pump
- fuel cell
- tank
- degassing tank
- filling station
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C9/00—Methods or apparatus for discharging liquefied or solidified gases from vessels not under pressure
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
- F17C13/02—Special adaptations of indicating, measuring, or monitoring equipment
- F17C13/021—Special adaptations of indicating, measuring, or monitoring equipment having the height as the parameter
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C13/00—Details of vessels or of the filling or discharging of vessels
- F17C13/02—Special adaptations of indicating, measuring, or monitoring equipment
- F17C13/025—Special adaptations of indicating, measuring, or monitoring equipment having the pressure as the parameter
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C5/00—Methods or apparatus for filling containers with liquefied, solidified, or compressed gases under pressures
- F17C5/002—Automated filling apparatus
- F17C5/007—Automated filling apparatus for individual gas tanks or containers, e.g. in vehicles
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C5/00—Methods or apparatus for filling containers with liquefied, solidified, or compressed gases under pressures
- F17C5/02—Methods or apparatus for filling containers with liquefied, solidified, or compressed gases under pressures for filling with liquefied gases
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2221/00—Handled fluid, in particular type of fluid
- F17C2221/01—Pure fluids
- F17C2221/012—Hydrogen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/01—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
- F17C2223/0146—Two-phase
- F17C2223/0153—Liquefied gas, e.g. LPG, GPL
- F17C2223/0161—Liquefied gas, e.g. LPG, GPL cryogenic, e.g. LNG, GNL, PLNG
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/03—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the pressure level
- F17C2223/033—Small pressure, e.g. for liquefied gas
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2223/00—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
- F17C2223/04—Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by other properties of handled fluid before transfer
- F17C2223/042—Localisation of the removal point
- F17C2223/046—Localisation of the removal point in the liquid
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2225/00—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel
- F17C2225/01—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel characterised by the phase
- F17C2225/0146—Two-phase
- F17C2225/0153—Liquefied gas, e.g. LPG, GPL
- F17C2225/0161—Liquefied gas, e.g. LPG, GPL cryogenic, e.g. LNG, GNL, PLNG
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2225/00—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel
- F17C2225/03—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel characterised by the pressure level
- F17C2225/035—High pressure, i.e. between 10 and 80 bars
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2225/00—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel
- F17C2225/04—Handled fluid after transfer, i.e. state of fluid after transfer from the vessel characterised by other properties of handled fluid after transfer
- F17C2225/042—Localisation of the filling point
- F17C2225/046—Localisation of the filling point in the liquid
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2227/00—Transfer of fluids, i.e. method or means for transferring the fluid; Heat exchange with the fluid
- F17C2227/01—Propulsion of the fluid
- F17C2227/0128—Propulsion of the fluid with pumps or compressors
- F17C2227/0135—Pumps
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2250/00—Accessories; Control means; Indicating, measuring or monitoring of parameters
- F17C2250/04—Indicating or measuring of parameters as input values
- F17C2250/0404—Parameters indicated or measured
- F17C2250/0408—Level of content in the vessel
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2250/00—Accessories; Control means; Indicating, measuring or monitoring of parameters
- F17C2250/04—Indicating or measuring of parameters as input values
- F17C2250/0404—Parameters indicated or measured
- F17C2250/043—Pressure
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2260/00—Purposes of gas storage and gas handling
- F17C2260/04—Reducing risks and environmental impact
- F17C2260/046—Enhancing energy recovery
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2265/00—Effects achieved by gas storage or gas handling
- F17C2265/03—Treating the boil-off
- F17C2265/031—Treating the boil-off by discharge
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2265/00—Effects achieved by gas storage or gas handling
- F17C2265/03—Treating the boil-off
- F17C2265/032—Treating the boil-off by recovery
- F17C2265/036—Treating the boil-off by recovery with heating
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2270/00—Applications
- F17C2270/01—Applications for fluid transport or storage
- F17C2270/0134—Applications for fluid transport or storage placed above the ground
- F17C2270/0139—Fuel stations
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
- F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
- F17C2270/00—Applications
- F17C2270/01—Applications for fluid transport or storage
- F17C2270/0165—Applications for fluid transport or storage on the road
- F17C2270/0184—Fuel cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/2931—Diverse fluid containing pressure systems
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/6416—With heating or cooling of the system
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/8593—Systems
- Y10T137/85978—With pump
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/8593—Systems
- Y10T137/85978—With pump
- Y10T137/85986—Pumped fluid control
- Y10T137/86027—Electric
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/8593—Systems
- Y10T137/86493—Multi-way valve unit
- Y10T137/86574—Supply and exhaust
Definitions
- the present invention relates to a hydrogen filling station and method.
- the invention relates more specifically to a hydrogen filling station, particularly for refueling vehicle tanks with hydrogen gas, comprising a source tank intended to contain liquefied hydrogen, a withdrawing pipe for withdrawing the liquefied hydrogen from the source tank to at least one user station, an electric cryogenic pump positioned in the withdrawing pipe, an electric power source connected to the cryogenic pump to supply the latter with electricity.
- Generating a high pressure using a pump for liquid hydrogen reduces the energy consumption of a refueling system by a factor of about five as compared with an equivalent system using a gas compressor.
- the evaporative losses of liquid hydrogen in a cryogenic pump such as this may be substantial if the pump is not being used optimally.
- This liquid hydrogen is removed from the compression chamber before being pumped, so that the fluid drawn into the pumping cylinder is not a biphasic mixture which would lower the efficiency of the pump designed to pump only liquid.
- the evaporative hydrogen gas has therefore to be removed at relatively low pressure (intake pressure).
- a cryogenic pump will always generate a degassing delivery corresponding to an evaporation of cryogenic liquid within the pump housing.
- This purge of hydrogen gas is mostly discharged to the atmosphere or recompressed using a gas compressor, but so doing is not satisfactory in terms of the energy balance sheet and makes the plant more complicated.
- the present invention relates to a hydrogen filling station, especially a hydrogen filling station, for refueling vehicle tanks with hydrogen gas.
- the hydrogen filling station comprises a source tank intended to contain liquefied hydrogen (LH2), a withdrawing pipe for withdrawing the liquefied hydrogen from the source tank to at least one user station, an electric cryogenic pump positioned in the withdrawing pipe, and an electric power source connected to the cryogenic pump to supply the latter with electricity.
- the electric power source comprises at least one fuel cell.
- the station also comprises a degassing tank fluidically connected to the cryogenic pump via a degassing line in order to recover at least some of the hydrogen gas that evaporates within the pump.
- FIG. 1 provides a schematic which depicts the structure and operation of a hydrogen filling station according to the present invention.
- the hydrogen filling station according to the invention in other respects as per the generic definition thereof given above, is essentially characterized in that the electric power source comprises at least one fuel cell.
- embodiments of the invention may comprise one or more of the following features:
- the invention also relates to a hydrogen refueling method, particularly for refueling vehicle tanks with hydrogen gas, using a filling station comprising a source tank intended to contain liquefied hydrogen (LH2), a withdrawing pipe for withdrawing liquefied hydrogen from the source tank to at least one user station, an electric cryogenic pump positioned in the withdrawing pipe, characterized in that it comprises a step in which the cryogenic pump is electrically powered via a fuel cell.
- a filling station comprising a source tank intended to contain liquefied hydrogen (LH2)
- a withdrawing pipe for withdrawing liquefied hydrogen from the source tank to at least one user station
- an electric cryogenic pump positioned in the withdrawing pipe, characterized in that it comprises a step in which the cryogenic pump is electrically powered via a fuel cell.
- the filling station comprises a hydrogen gas user station 30 supplied from a source tank 1 of liquefied hydrogen (LH2).
- the hydrogen gas is conveyed from the source tank 1 to the user station 30 via a withdrawing pipe 3 for withdrawing liquid hydrogen (insulated line under vacuum).
- the liquid hydrogen withdrawing pipe 3 comprises, from upstream to downstream (that is to say from the source tank 1 toward the user station 30 ): an isolating valve 2 (optional), temperature 4 and pressure 5 sensors (optional), a high-pressure cryogenic pump 6 , a pressure sensor 7 situated on the delivery line of the pump 6 , an exchanger 8 (high-pressure vaporizer) for vaporizing the liquid hydrogen into a gas and a high-pressure regulating valve 9 .
- the pump 6 is connected via a degassing line 110 and an isolating valve 10 (optional) to a degassing tank 11 intended to collect the biphasic mixture of liquid hydrogen and hydrogen gas that is generated by the pump 6 .
- the cryogenic pump 6 compresses the liquid hydrogen from the source tank 1 . Because, notably, of friction within the pump 6 , some of the fluid is discharged at low pressure in the form of biphasic liquid via the line 110 into the degassing tank 11 .
- One gas outlet 112 from the degassing tank 11 is connected to the supply inlet 170 of a fuel cell 17 via a supply pipe 111 .
- the supply pipe 111 comprises, from upstream to downstream, a heat exchanger 13 (low-pressure vaporizer), a first pressure sensor 15 , a degassing control valve 14 , a second pressure sensor 23 and a divert-to-atmosphere ATM controlled by a valve 16 that acts as an overpressure safety dump valve.
- a heat exchanger 13 low-pressure vaporizer
- first pressure sensor 15 a first pressure sensor 15
- a degassing control valve 14 a second pressure sensor 23
- a divert-to-atmosphere ATM controlled by a valve 16 that acts as an overpressure safety dump valve.
- a proportional integral derivative (PID) regulator 22 for controlling the power of the fuel cell 17 receives, at input:
- the regulator 22 at output 22 c delivers a control signal for controlling the instantaneous electrical power of the fuel cell 17 (for example as a percentage % P of the nominal power of the cell that ranges between 0 and 100%).
- a level sensor 12 that senses the liquid level in the degassing tank 11 is connected to a proportional integral derivative (PID) regulator that controls said level in this degassing tank 11 .
- PID proportional integral derivative
- the level-controlling proportional integral derivative regulator 21 receives at input 21 a the measured liquid level and a datum C for controlling the liquid level within the degassing tank 11 .
- the electric power output 17 a of the fuel cell 17 is connected 18 a to the electrical supply input of the pump 6 via 17 a an electric power switching and regulating member 18 .
- the electric power switching and regulating member 18 is also connected by a line 18 b to an electrical network 19 and receives at input 18 c a datum % PO of the intake power of the pump 6 .
- a device 20 for measuring and controlling the pressure in the source tank 1 (pressurizing or depressurizing line 20 a ) is connected to the proportional integral derivative regulator 21 that controls the level in the degassing tank 11 .
- the output signal 21 c from the regulator 21 that controls the level in the degassing tank 11 is transmitted to the device 20 that measures and controls the pressure in the source tank 1 .
- the device 20 that measures and controls the pressure in the source tank 1 may also control a degassing control valve 14 by sending it a datum opening signal 20 b.
- the output signal 21 c from the regulator 21 is, for example, the percentage (%) of opening of the degassing control valve 14 .
- the liquefied hydrogen stored at a set pressure and at a temperature lower than the corresponding saturation temperature is supplied by the source tank 1 via the insulated vacuum line 3 comprising the isolating valve 2 .
- the high-pressure liquid hydrogen is removed by a pump 6 .
- the pressure of the liquid hydrogen is measured by the sensor 7 , then the liquid hydrogen is heated by the exchanger 8 .
- the high-pressure hydrogen gas is delivered via the upstream-pressure regulating valve 9 .
- the use of the hydrogen gas for example at pressures of the order of 700 bar, is available downstream of this valve 9 .
- Some of the fluid used by the pump 6 is removed at low pressure in the form of a biphasic (gas-liquid) liquid via the degassing line 110 and the valve 10 to the degassing tank 11 .
- the intake pressure of the pump 6 is controlled in such a way that there is always liquid present in the degassing tank 11 .
- the degassing tank 11 is located with a head on the pump 6 . That is to say that the intake bath of the pump 6 is always under an atmosphere of liquid hydrogen (essentially without any gas). That avoids any risk of cavitation in the pump 6 .
- the exchanger 13 downstream of the degassing tank 11 can be used to heat up the gas originating from the evaporation of liquid in the pump 6 .
- the degassing control valve 14 allows the hydrogen gas to be recirculated to the fuel cell 17 (which is, for example, of the PEM type).
- the cell 17 therefore creates a direct current 17 a which is inverted by the electric regulating and switching member 8 .
- the inverter 18 may possibly supplement the electric power supplied by the cell 17 with additional electric power 18 b supplied by the electric network 19 .
- the inverter 18 may possibly supply the electric network with additional power 18 b produced by the fuel cell ( 17 ).
- valve 16 that acts as a safety dump valve may channel excess hydrogen gas to the atmosphere ATM.
- the device 20 for measuring and controlling the pressure in the source tank 1 may work as follows: the measurement and control device 20 receives information from the PID regulator 21 which is aimed at controlling the liquid level in the degassing tank 11 . If the liquid level is higher than the datum level C then the output signal 21 c from the regulator 21 decreases. If the liquid level is below the datum level C then the output signal 21 c from the regulator 21 increases. Under normal operation, the datum signal 21 b for the opening of the gas control valve 14 may simply be a copy of the output signal 21 c from the regulator 21 .
- the datum level ( 20 a ) for controlling the pressure in the source tank 1 is increased, for example by increments of 100 mbar every 30 seconds until the control signal 21 c output by the regulator 21 falls below a lower value (for example 90%).
- the datum level 20 a for controlling the pressure in the source tank 1 is decreased, for example in increments of 100 mbar every 30 seconds until the signal 21 c output by the regulator 21 rises above a predefined value (for example 10%).
- the gas that has escaped via the control valve 14 is then collected toward the fuel cell 17 . That allows the pump 6 to be powered via the electric power signal 17 a , 18 a . In this way, it is possible to decrease or even eliminate the contribution 18 b and the dependency of the station on the electric network 19 .
- the electricity produced by the cell 17 can be returned to the network 19 and/or to auxiliary systems of the station, such as sales outlets, lighting. This may make the filling station completely autonomous in terms of its electrical energy requirements.
- Power supply management may be designed as follows: the fuel cell 17 receives, by default, all the hydrogen degassed from the degassing tank 11 and produces electricity using this recirculated hydrogen. If the amount of hydrogen degassed is too great by comparison with the nominal power P of the fuel cell then the pressure measured by the second sensor 23 increases and the vent valve 16 is opened. Likewise if the cell 17 is shut down, then the valve 16 may vent all the hydrogen degassed from the tank 11 to the atmosphere.
- the electricity produced by the fuel cell 17 is sent as appropriate to the inverter of the switching and regulating member 18 .
- the inverter of the switching and regulating member 18 Depending on:
- the source tank 1 may be situated below ground level (buried).
- the pump 6 may be situated above the tank, by virtue of the device 20 for measuring and controlling the pressure in the source tank 1 (which acts as a dynamic regulating block).
- the invention advantageously makes it possible to derive maximum benefit from the hydrogen that is vaporized inside the cryogenic pumps without requiring compression.
- the transfers of power from the pump 6 to the fluid as a result of friction and the like generally range between 8 and 21% of the total power of the pump.
- the fuel cell 17 can therefore, on the one hand, provide electricity to power the pump 6 , but any excess electricity obtained can also power an electric network 19 or other users.
- the hydrogen fully discharges its function of energy carrier and can make the entire filling station completely autonomous in terms of electrical energy requirements.
- the filling station may therefore be immune to power cuts in particular.
- the invention therefore makes it possible to make skillful good use in a fuel cell of the evaporative gas losses.
Abstract
Description
-
- the station comprises a degassing tank fluidically connected to the cryogenic pump via a degassing line in order to recover at least some of the hydrogen gas that evaporates within the pump,
- the degassing tank comprises a gas withdrawal outlet connected via a supply pipe to a fuel supply inlet of the fuel cell,
- the supply pipe comprises a heat exchanger intended to heat the gas from the degassing tank, and a control valve for controlling the gas admitted to the fuel supply inlet of the fuel cell,
- the supply pipe comprises a dump valve that discharges the gas to the atmosphere in the event of a set overpressure in the supply pipe,
- the withdrawing pipe for withdrawing liquid hydrogen from the source tank comprises, positioned downstream of the pump, a heat exchanger intended to heat up the withdrawn hydrogen, and a regulating valve,
- the station comprises a switching and regulating member for switching and regulating the electric supply power delivered to the pump, this member being connected, on the one hand, to an electric power output of the fuel cell and, on the other hand, to the electric supply input of the pump, the electric power source also comprising an electricity distributing network connected to the switching and regulating member, said switching and regulating member being designed selectively to allow the pump to be electrically powered by the network and/or the fuel cell or electrical power delivered by the fuel cell to be transferred to the network,
- the station comprises a measurement and control member for measuring and controlling the pressure within the source tank and capable of increasing or decreasing the pressure within this tank,
- the station comprises a device for measuring the level of liquid in the degassing tank, this device being connected to the member that measures and controls the pressure within the source tank, said member for measuring and controlling the pressure within the source tank also being connected to the valve that controls the gas admitted to the fuel cell, so as to control the opening/closure of this valve according to the measured level of liquid in the degassing tank,
- the source tank is situated below ground level, being, for example, buried, the pump being situated at the level of the source tank or above the latter,
- the fuel cell generates a DC current, and in that the switching and regulating member that switches and regulates the electric supply power delivered to the pump comprises an inverter capable of converting direct current into alternating current,
- the filling station also comprises a station for refueling with liquefied hydrogen from the source tank, so that supplies of hydrogen gas and/or of liquefied hydrogen can be replenished simultaneously or otherwise.
-
- the method comprises a step in which hydrogen gas vaporized by the pump is recirculated to supply the fuel cell with fuel,
- the hydrogen gas vaporized by the pump passes through and is stored in a buffer degassing tank situated between the pump and the fuel cell, and in that the method involves:
- a step of measuring the level of liquid in the degassing tank,
- a step of controlling the amount of gas admitted to supply the fuel cell according to the level of liquid measured in the degassing tank,
- when the liquid level measured in the degassing tank is above a first threshold level, the amount of gas admitted to supply the fuel cell is decreased, and when the liquid level measured in the degassing tank is below a second threshold level, the amount of gas admitted to supply the fuel cell is increased,
- the method comprises a step of measuring the liquid level in the degassing tank and a step of controlling the intake pressure of the cryogenic pump so as to maintain a set level of liquid in the degassing tank,
- the method comprises a step of increasing the intake pressure of the pump when the liquid level measured in the degassing tank is below a first set datum level and a step of decreasing the intake pressure of the pump when the liquid level measured in the degassing tank is below a second set datum level different from or equal to the first datum level,
- the excess electrical power supplied by the pump is returned to a network and/or auxiliary electrical systems such as lighting,
- when the amount of gas admitted to supply the fuel cell exceeds a first set high threshold level, the pressure in the source tank is increased in increments as long as the amount of gas admitted to supply the fuel cell does not drop back below a second high threshold level which is lower than the first high threshold level;
- when the amount of gas admitted to supply the fuel cell is below a set first low threshold level, the pressure in the source tank is decreased in decrements as long as the amount of gas admitted to supply the fuel cell does not exceed a second low threshold level which is higher than the first low threshold level.
-
- the hydrogen
gas pressure measurement 22 a taken by thesecond pressure sensor 23, and - a datum CP for controlling the electric power of the
fuel cell 17.
- the hydrogen
-
- the current 17 a received,
- the pump power %
PO datum level 18 c, and - the current 18 a needed to operate the
pump 6 in accordance with the datum level % PO,
the switching and regulatingmember 18 distributes electrical current to theelectric network 19 or draws current therefrom.
Claims (21)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0655042A FR2908859B1 (en) | 2006-11-22 | 2006-11-22 | METHOD AND STATION FOR REFUELING IN HYDROGEN |
FR0655042 | 2006-11-22 | ||
PCT/FR2007/052116 WO2008062117A1 (en) | 2006-11-22 | 2007-10-10 | Hydrogen filling method and station |
Publications (2)
Publication Number | Publication Date |
---|---|
US20100212772A1 US20100212772A1 (en) | 2010-08-26 |
US8291944B2 true US8291944B2 (en) | 2012-10-23 |
Family
ID=38093364
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/515,029 Active 2029-05-10 US8291944B2 (en) | 2006-11-22 | 2007-10-10 | Hydrogen filling method and station |
Country Status (7)
Country | Link |
---|---|
US (1) | US8291944B2 (en) |
EP (1) | EP2095009B1 (en) |
JP (1) | JP2010510463A (en) |
CN (1) | CN101542185A (en) |
CA (1) | CA2670220A1 (en) |
FR (1) | FR2908859B1 (en) |
WO (1) | WO2008062117A1 (en) |
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US20100193070A1 (en) * | 2007-07-23 | 2010-08-05 | L'Air Liquide Societe Annoyme Pour L'Etude Et L'Exploitaaaaaation Des Procedes Georges Claude | Method for Filling a Tank with Pressurized Gas |
US8978715B2 (en) * | 2007-07-23 | 2015-03-17 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method for filling a tank with pressurized gas |
US9291309B2 (en) | 2009-07-22 | 2016-03-22 | Shell Oil Company | Hydrogen dispensing system and method thereof |
US9383063B2 (en) | 2009-07-22 | 2016-07-05 | Shell Oil Company | Hydrogen dispensing system and method thereof |
US20170225843A1 (en) * | 2014-06-06 | 2017-08-10 | Fisher Scientific Company, L.L.C. | Tamper-Evident Closure Assembly Including Outer Shell, And Related Systems And Methods |
US10035627B2 (en) * | 2014-06-06 | 2018-07-31 | Fisher Scientific Company, L.L.C. | Tamper-evident closure assembly including outer shell, and related systems and methods |
US10400712B2 (en) * | 2015-04-30 | 2019-09-03 | Westport Power Inc. | Intelligent pressure management system for cryogenic fluid systems |
US10982626B2 (en) | 2015-04-30 | 2021-04-20 | Westport Power Inc. | Intelligent pressure management system for cryogenic fluid systems |
US10774992B2 (en) * | 2015-10-05 | 2020-09-15 | Cryostar Sas | Method for supplying cryogenic liquid, and facility for implementing said method |
US20190137038A1 (en) * | 2016-04-28 | 2019-05-09 | Linde Aktiengesellschaft | Hydrogen filling station with liquid hydrogen |
US10059215B1 (en) | 2017-03-08 | 2018-08-28 | A3 Labs, Llc | Energy source supply systems, energy source supply devices, and related methods |
US10478929B2 (en) | 2017-03-08 | 2019-11-19 | A3 Labs LLC | Energy source supply systems, energy source supply devices, and related methods |
US11097627B2 (en) | 2017-03-08 | 2021-08-24 | A3 Labs LLC | Energy source supply systems, energy source supply devices, and related methods |
US11667202B2 (en) | 2017-03-08 | 2023-06-06 | A3 Labs LLC | Energy source supply systems, energy source supply devices, and related methods |
US11300248B2 (en) * | 2017-08-31 | 2022-04-12 | Messer Se & Co. Kgaa | Device and process for filling a mobile refrigerant tank with a cryogenic refrigerant |
US11073245B2 (en) * | 2018-11-12 | 2021-07-27 | L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method and installation for storing and dispensing liquefied hydrogen |
US11174993B2 (en) * | 2018-12-25 | 2021-11-16 | Samtech Corporation | Hydrogen station and operating method for hydrogen station |
US20220314938A1 (en) * | 2021-03-30 | 2022-10-06 | Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) | Compressor unit |
Also Published As
Publication number | Publication date |
---|---|
WO2008062117A1 (en) | 2008-05-29 |
FR2908859B1 (en) | 2009-02-20 |
CN101542185A (en) | 2009-09-23 |
US20100212772A1 (en) | 2010-08-26 |
JP2010510463A (en) | 2010-04-02 |
EP2095009A1 (en) | 2009-09-02 |
EP2095009B1 (en) | 2013-05-22 |
FR2908859A1 (en) | 2008-05-23 |
CA2670220A1 (en) | 2008-05-29 |
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