US8709134B2 - Reversible ethylene oxide capture in porous frameworks - Google Patents
Reversible ethylene oxide capture in porous frameworks Download PDFInfo
- Publication number
- US8709134B2 US8709134B2 US13/147,357 US201013147357A US8709134B2 US 8709134 B2 US8709134 B2 US 8709134B2 US 201013147357 A US201013147357 A US 201013147357A US 8709134 B2 US8709134 B2 US 8709134B2
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- United States
- Prior art keywords
- ethylene oxide
- mof
- porous
- gas
- framework
- Prior art date
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- 238000011084 recovery Methods 0.000 abstract description 5
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- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
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- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
- B01J20/3244—Non-macromolecular compounds
- B01J20/3246—Non-macromolecular compounds having a well defined chemical structure
- B01J20/3248—Non-macromolecular compounds having a well defined chemical structure the functional group or the linking, spacer or anchoring group as a whole comprising at least one type of heteroatom selected from a nitrogen, oxygen or sulfur, these atoms not being part of the carrier as such
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
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Abstract
Description
TABLE 1 |
Diverse characteristics of the benchmark MOFs |
SBU* | Open metal | Functionalized | Ultrahigh | Surface area, | Pore volume, |
MOF | 0D | 1D | sites† | pore‡ | Catenated§ | surface area | m2/g¶ | cm3/g |
MOF-5 | ▪ | ▪ | 2,205 | 1.22 | ||||
IRMOF-3 | ▪ | ▪ | 1,568 | 1.07 | ||||
MOF-74 | ▪ | ▪ | 632 | 0.39 | ||||
MOF-177 | ▪ | ▪ | 3,875 | 1.59 | ||||
MOF-199 | ▪ | ▪ | 1,264 | 0.75 | ||||
IRMOF-62 | ▪ | ▪ | ▪ | 1,814 | 0.99 | |||
*Secondary building units (SBUs) are either discreet inorganic clusters (0D) or linear chains (1D). | ||||||||
†MOF-74 contains pyramidal 5-coordinate zinc, and MOF-199 contains square 4-coordinate copper. | ||||||||
‡IRMOF-3 contains amino functionality, and IRMOF-62 contains alkyne functionality. | ||||||||
§IRMOF-62 is quadruply interpenetrated. | ||||||||
¶Surface areas calculated by the BET method for samples used in this study. These may differ from reported values as a result of variation in handling and activation procedures. |
TABLE 2 |
Dynamic adsorption capacities of the benchmark MOFs for gaseous |
contaminants measured in grams of gas per gram of adsorbent |
Improvement | ||||||||
Gas | MOF-5 | IRMOF-3 | MOF-74 | MOF-177 | MOF-199 | IRMOF-62 | BPL carbon | factor * |
Sulfur dioxide | 0.001 | 0.006 | 0.194 † | <0.001 | 0.032 | <0.001 | 0.033 | 5.88 |
Ammonia | 0.006 | 0.105 † | 0.093 | 0.042 | 0.087 | 0.023 | 0.001 | 105 |
Chlorine | ‡ | 0.335 † | ‡ | <0.001 | 0.036 | 0.092 | 0.190 | 1.76 |
Tetrahydrothiophene | 0.001 | 0.007 | 0.090 | <0.001 | 0.351 † | 0.084 | 0.123 | 2.85 |
Benzene | 0.002 | 0.056 | 0.096 | 0.001 | 0.176 † | 0.109 | 0.155 | 1.14 |
Dichloromethane | <0.001 | 0.001 | 0.032 | <0.001 | 0.055 † | 0.019 | 0.053 | 1.04 |
Ethylene oxide | 0.001 | 0.002 | 0.110 | <0.001 | 0.095 † | 0.011 | 0.010 | 9.50 |
* Expresses the ratio of dynamic adsorption capacity of the best-performing MOF (†) to that of BPL carbon. | ||||||||
† Best-pcrforming MOFs. | ||||||||
‡ Experiments were not performed because of corrosion of the apparatus by chlorine. |
Claims (16)
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