US911960A - Composition for treating fuel. - Google Patents

Composition for treating fuel. Download PDF

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Publication number
US911960A
US911960A US40955208A US1908409552A US911960A US 911960 A US911960 A US 911960A US 40955208 A US40955208 A US 40955208A US 1908409552 A US1908409552 A US 1908409552A US 911960 A US911960 A US 911960A
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US
United States
Prior art keywords
fuel
composition
coal
ingredients
oxalic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US40955208A
Inventor
Edward H Ellis
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ELLIS HEATING Co
ALFRED D CHANDLER
Original Assignee
ELLIS HEATING Co
ALFRED D CHANDLER
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ELLIS HEATING Co, ALFRED D CHANDLER filed Critical ELLIS HEATING Co
Priority to US40955208A priority Critical patent/US911960A/en
Application granted granted Critical
Publication of US911960A publication Critical patent/US911960A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00Treating solid fuels to improve their combustion
    • C10L9/10Treating solid fuels to improve their combustion by using additives

Definitions

  • This invention has for its object to provide a composition for application to coal and other fuels for the purpose of making the combustion of the fuel relatively complete, and thus obtaining the maximum thermal efficiency of the fuel and economy in the use thereof, and reducing to the minimum the escape of unconsumed combustible matter and the volume of black or dark smoke resulting therefrom, particularly in the case of soft coal.
  • the invention also has for its object to enable coal to be thoroughly consumed to a fine ash without the formation of clinkers.
  • the invention consists in a composition
  • Oxalic acid with the other ingredients, cokes the coal so quickly that the carbon does not have opportunity to escape before it is entirely consumed.
  • the desirability of increasing the length of time in consuming coal is for the sake of economy because more heat is obtained, with the chemicals added, than from the same amount of fuel without chemicals.
  • the accelerating effect of potassium chlorate is offset by the oxalic acid which has the aforesaid faculty of hardening the mass of fuel which, while increasing the heat, prolongs the length of time required to consume the fuel thereby making a great saving of fuel;
  • composition may be applied to Specification of Letters latent.
  • the fuel in the form of dry powder produced by suitably pulverizing and mixing the ingredients, I prefer to apply the same in solution, the ingredients being dissolved in water and the solution sprinkled on the fuel.
  • the following are the preferred relative proportions of the ingredients specified, as I have found that said proportions give a satisfactory result.
  • Fifty gallons of water is given as an approximate amount but may be varied according to the quality and kind of fuel used.
  • the said ingredients being thoroughly dissolved, the solution is used by sprinkling it on the fuel, preferably before the latter is introduced into the furnace.
  • the water is used to insure the thorough saturation of the chemical to the coal.
  • the solution should be sprinkled on the fuel so as to wet all parts of it and better results are obtained by putting fuel in the fire while wet, but it can be used after the mixture has dried on the fuel, thus allowing the user to wet large amounts of fuel at one time.
  • composition may be advantageously applied to anthracite coal, and other fuels, including wood, peat, etc. It may also be advantageously used by applying it to a body of fire brick or other refractory material, and placing the latter in or upon a mass of burning coal.
  • Potassium chlorate is an oxidizing agent and accelerates the union of the fuel with the oxygen of the air and thereby hastens the action of the other ingredients.
  • Sal-ammoniac and sodium chlorid are both put in for the purpose of reducing black smoke to a minimum, without relying on one alone.
  • the amount of chemical used to sprinkle fuel is varied, according to quality and kind, but a fair average is two gallons to the cwt. Another advantage of this chemical is, that it may be thrown in on top of the fire in the liquid state, causing all of the aforesaid effects.
  • a fuel-treating composition comprising potassium chlorate, sal ammoniac or its e'qhivalent, oxalic acid, and sodium chlorid.

Description

EDWARD H. ELLIS, OF BOSTON, MASSACHUSETTS, ASSIGNOR, BY MESNE ASSIGNMENTS, TO
EDWARD H. ELLIS AND ALFRED D. CHANDLER, OF BROOKLINE, MASSACHUSETTS, TRUS- TEES OF ELLIS HEATING COMPANY.
COMPOSITION FOR TREATING FUEL.
Application filed January 6, 1908.
To all whom it may concern:
Be it known that I, EDWARD H. ELLIs, of Boston, in the county of Suffolk and State of Massachusetts, have invented certain new and useful Improvements in Compositions for Treating Fuel, of which the following is a specification.
This invention has for its object to provide a composition for application to coal and other fuels for the purpose of making the combustion of the fuel relatively complete, and thus obtaining the maximum thermal efficiency of the fuel and economy in the use thereof, and reducing to the minimum the escape of unconsumed combustible matter and the volume of black or dark smoke resulting therefrom, particularly in the case of soft coal.
The invention also has for its object to enable coal to be thoroughly consumed to a fine ash without the formation of clinkers.
The invention consists in a composition,
the chief ingredients of which are; first,
pqt as siumwchlorate; secondly, salammo niac; and thirdly, oxalic acid. These ingredients form a compound which when presented. to burning coal, produces the following desirable results; via, first, it supplies oxygen in a nascent state; secondly, it neutralizes the gases; and thirdly, it increases the length of time required to consume the fuel, the first result being due to the potassium chlorate, the second to the salammoniac and the third to the oxalic acid, this last being due to the fact that oxalic acid has a tendency to coke soft coal and thus make a hard mass which will not be consumed as rapidly as it would be in its natural state. Oxalic acid, with the other ingredients, cokes the coal so quickly that the carbon does not have opportunity to escape before it is entirely consumed. The desirability of increasing the length of time in consuming coal is for the sake of economy because more heat is obtained, with the chemicals added, than from the same amount of fuel without chemicals. The accelerating effect of potassium chlorate is offset by the oxalic acid which has the aforesaid faculty of hardening the mass of fuel which, while increasing the heat, prolongs the length of time required to consume the fuel thereby making a great saving of fuel;
' While the composition may be applied to Specification of Letters latent.
Patented Feb. 9, 1909.
Serial No. 409,552.
the fuel in the form of dry powder produced by suitably pulverizing and mixing the ingredients, I prefer to apply the same in solution, the ingredients being dissolved in water and the solution sprinkled on the fuel. The following are the preferred relative proportions of the ingredients specified, as I have found that said proportions give a satisfactory result. Potassium chlorate one pound, sal ammoniac one-half pound, oxalic acid one pound," sodium cnlorid fifteen pounds, water fifty gallons. Fifty gallons of water is given as an approximate amount but may be varied according to the quality and kind of fuel used. The said ingredients being thoroughly dissolved, the solution is used by sprinkling it on the fuel, preferably before the latter is introduced into the furnace. The water is used to insure the thorough saturation of the chemical to the coal. The solution should be sprinkled on the fuel so as to wet all parts of it and better results are obtained by putting fuel in the fire while wet, but it can be used after the mixture has dried on the fuel, thus allowing the user to wet large amounts of fuel at one time.
Practical tests have demonstrated that bituminous coal treated with the described composition, burns without emitting black smoke, the combustion being more complete; that the quantity of heat given out is increased that /a material saving of fuel is effected, and that the quantity of ashes and slag or clinke i" produced is materially reduced. The reason for the decrease in ashes and clinkers is due to the fact of the perfect combustion which consumes everything combustible before the fire will go out. The use of the said composition also enables blowers and forced draft apparatus to be dispensed with; reduces the space required for coal, reduces the quantity of soot deposited on flue surfaces, etc., and gives better results from relatively low grades of coal than from more expensive coal used Without it.
The composition may be advantageously applied to anthracite coal, and other fuels, including wood, peat, etc. It may also be advantageously used by applying it to a body of fire brick or other refractory material, and placing the latter in or upon a mass of burning coal. The combustion of the complete and attended with all the abovementioned advantages,
Potassium chlorate is an oxidizing agent and accelerates the union of the fuel with the oxygen of the air and thereby hastens the action of the other ingredients. Sal-ammoniac and sodium chlorid are both put in for the purpose of reducing black smoke to a minimum, without relying on one alone. The amount of chemical used to sprinkle fuel is varied, according to quality and kind, but a fair average is two gallons to the cwt. Another advantage of this chemical is, that it may be thrown in on top of the fire in the liquid state, causing all of the aforesaid effects.
It will be understood from the foregoing,
equivalent, and oxalic acid. 2. A fuel-treating composition comprising potassium chlorate, sal ammoniac or its e'qhivalent, oxalic acid, and sodium chlorid. In testimony whereof I have afliXed my signature, in presence of two witnesses.
EDWVARD H. ELLIS.
Witnesses:
O. F. BROWN, P. W. PEZZETTL
US40955208A 1908-01-06 1908-01-06 Composition for treating fuel. Expired - Lifetime US911960A (en)

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US40955208A US911960A (en) 1908-01-06 1908-01-06 Composition for treating fuel.

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Cited By (19)

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US20060210463A1 (en) * 2005-03-17 2006-09-21 Comrie Douglas C Reducing mercury emissions from the burning of coal
US20070168213A1 (en) * 2006-01-18 2007-07-19 Comrie Douglas C Methods of operating a coal burning facility
US20070184394A1 (en) * 2006-02-07 2007-08-09 Comrie Douglas C Production of cementitious ash products with reduced carbon emissions
US20080286703A1 (en) * 2004-06-28 2008-11-20 Nox Ii International Ltd. Reducing Sulfur Gas Emissions Resulting from the Burning of Carbonaceous Fuels
US7758827B2 (en) 2005-03-17 2010-07-20 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal
US20110195003A1 (en) * 2010-02-04 2011-08-11 Ada Environmental Solutions, Llc Method and system for controlling mercury emissions from coal-fired thermal processes
US8124036B1 (en) 2005-10-27 2012-02-28 ADA-ES, Inc. Additives for mercury oxidation in coal-fired power plants
US8383071B2 (en) 2010-03-10 2013-02-26 Ada Environmental Solutions, Llc Process for dilute phase injection of dry alkaline materials
US8496894B2 (en) 2010-02-04 2013-07-30 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
US8524179B2 (en) 2010-10-25 2013-09-03 ADA-ES, Inc. Hot-side method and system
US8784757B2 (en) 2010-03-10 2014-07-22 ADA-ES, Inc. Air treatment process for dilute phase injection of dry alkaline materials
US8883099B2 (en) 2012-04-11 2014-11-11 ADA-ES, Inc. Control of wet scrubber oxidation inhibitor and byproduct recovery
US8951487B2 (en) 2010-10-25 2015-02-10 ADA-ES, Inc. Hot-side method and system
US8974756B2 (en) 2012-07-25 2015-03-10 ADA-ES, Inc. Process to enhance mixing of dry sorbents and flue gas for air pollution control
US9017452B2 (en) 2011-11-14 2015-04-28 ADA-ES, Inc. System and method for dense phase sorbent injection
US10350545B2 (en) 2014-11-25 2019-07-16 ADA-ES, Inc. Low pressure drop static mixing system
US10465137B2 (en) 2011-05-13 2019-11-05 Ada Es, Inc. Process to reduce emissions of nitrogen oxides and mercury from coal-fired boilers
US10767130B2 (en) 2012-08-10 2020-09-08 ADA-ES, Inc. Method and additive for controlling nitrogen oxide emissions
US11298657B2 (en) 2010-10-25 2022-04-12 ADA-ES, Inc. Hot-side method and system

Cited By (68)

* Cited by examiner, † Cited by third party
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US20080286703A1 (en) * 2004-06-28 2008-11-20 Nox Ii International Ltd. Reducing Sulfur Gas Emissions Resulting from the Burning of Carbonaceous Fuels
US9133408B2 (en) 2004-06-28 2015-09-15 Nox Ii, Ltd. Reducing sulfur gas emissions resulting from the burning of carbonaceous fuels
US8574324B2 (en) 2004-06-28 2013-11-05 Nox Ii, Ltd. Reducing sulfur gas emissions resulting from the burning of carbonaceous fuels
US11732888B2 (en) 2005-03-17 2023-08-22 Nox Ii, Ltd. Sorbents for coal combustion
US9822973B2 (en) 2005-03-17 2017-11-21 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal
US20090117019A1 (en) * 2005-03-17 2009-05-07 Comrie Douglas C Reducing mercury emissions from the burning of coal
US7674442B2 (en) 2005-03-17 2010-03-09 Comrie Douglas C Reducing mercury emissions from the burning of coal
US7758827B2 (en) 2005-03-17 2010-07-20 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal
US7776301B2 (en) 2005-03-17 2010-08-17 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal
US8501128B2 (en) 2005-03-17 2013-08-06 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal
US11732889B2 (en) 2005-03-17 2023-08-22 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal by remote sorbent addition
US20110203499A1 (en) * 2005-03-17 2011-08-25 Nox Ii, Ltd. Reducing Mercury Emissions From The Burning Of Coal
US11060723B2 (en) 2005-03-17 2021-07-13 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal by remote sorbent addition
US9169453B2 (en) 2005-03-17 2015-10-27 Nox Ii, Ltd. Sorbents for coal combustion
US8226913B2 (en) 2005-03-17 2012-07-24 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal
US20060210463A1 (en) * 2005-03-17 2006-09-21 Comrie Douglas C Reducing mercury emissions from the burning of coal
US9416967B2 (en) 2005-03-17 2016-08-16 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal
US9702554B2 (en) 2005-03-17 2017-07-11 Nox Ii, Ltd. Sorbents for coal combustion
US7507083B2 (en) 2005-03-17 2009-03-24 Douglas C Comrie Reducing mercury emissions from the burning of coal
US7955577B2 (en) 2005-03-17 2011-06-07 NOx II, Ltd Reducing mercury emissions from the burning of coal
US10962224B2 (en) 2005-03-17 2021-03-30 Nox Ii, Ltd. Sorbents for coal combustion
US8545778B2 (en) 2005-03-17 2013-10-01 Nox Ii, Ltd. Sorbents for coal combustion
US9945557B2 (en) 2005-03-17 2018-04-17 Nox Ii, Ltd. Sorbents for coal combustion
US8658115B2 (en) 2005-03-17 2014-02-25 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal
US8703081B2 (en) 2005-03-17 2014-04-22 Nox Ii, Ltd. Sorbents for coal combustion
US10670265B2 (en) 2005-03-17 2020-06-02 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal
US10641483B2 (en) 2005-03-17 2020-05-05 Nox Ii, Ltd. Sorbents for coal combustion
US8920158B2 (en) 2005-03-17 2014-12-30 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal
US10612779B2 (en) 2005-03-17 2020-04-07 Nox Ii, Ltd. Sorbents for coal combustion
US10359192B2 (en) 2005-03-17 2019-07-23 Nox Ii, Ltd. Reducing mercury emissions from the burning of coal
US8293196B1 (en) 2005-10-27 2012-10-23 ADA-ES, Inc. Additives for mercury oxidation in coal-fired power plants
US8124036B1 (en) 2005-10-27 2012-02-28 ADA-ES, Inc. Additives for mercury oxidation in coal-fired power plants
US20070168213A1 (en) * 2006-01-18 2007-07-19 Comrie Douglas C Methods of operating a coal burning facility
US8150776B2 (en) 2006-01-18 2012-04-03 Nox Ii, Ltd. Methods of operating a coal burning facility
US20070184394A1 (en) * 2006-02-07 2007-08-09 Comrie Douglas C Production of cementitious ash products with reduced carbon emissions
US8496894B2 (en) 2010-02-04 2013-07-30 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
US10427096B2 (en) 2010-02-04 2019-10-01 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
US9352275B2 (en) 2010-02-04 2016-05-31 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
US20110195003A1 (en) * 2010-02-04 2011-08-11 Ada Environmental Solutions, Llc Method and system for controlling mercury emissions from coal-fired thermal processes
US9221013B2 (en) 2010-02-04 2015-12-29 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
US9884286B2 (en) 2010-02-04 2018-02-06 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
US8372362B2 (en) 2010-02-04 2013-02-12 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
US11213787B2 (en) 2010-02-04 2022-01-04 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
US10843130B2 (en) 2010-02-04 2020-11-24 ADA-ES, Inc. Method and system for controlling mercury emissions from coal-fired thermal processes
US9149759B2 (en) 2010-03-10 2015-10-06 ADA-ES, Inc. Air treatment process for dilute phase injection of dry alkaline materials
US8383071B2 (en) 2010-03-10 2013-02-26 Ada Environmental Solutions, Llc Process for dilute phase injection of dry alkaline materials
US8784757B2 (en) 2010-03-10 2014-07-22 ADA-ES, Inc. Air treatment process for dilute phase injection of dry alkaline materials
US10124293B2 (en) 2010-10-25 2018-11-13 ADA-ES, Inc. Hot-side method and system
US11298657B2 (en) 2010-10-25 2022-04-12 ADA-ES, Inc. Hot-side method and system
US9657942B2 (en) 2010-10-25 2017-05-23 ADA-ES, Inc. Hot-side method and system
US8951487B2 (en) 2010-10-25 2015-02-10 ADA-ES, Inc. Hot-side method and system
US8524179B2 (en) 2010-10-25 2013-09-03 ADA-ES, Inc. Hot-side method and system
US10730015B2 (en) 2010-10-25 2020-08-04 ADA-ES, Inc. Hot-side method and system
US10731095B2 (en) 2011-05-13 2020-08-04 ADA-ES, Inc. Process to reduce emissions of nitrogen oxides and mercury from coal-fired boilers
US10465137B2 (en) 2011-05-13 2019-11-05 Ada Es, Inc. Process to reduce emissions of nitrogen oxides and mercury from coal-fired boilers
US11118127B2 (en) 2011-05-13 2021-09-14 ADA-ES, Inc. Process to reduce emissions of nitrogen oxides and mercury from coal-fired boilers
US9017452B2 (en) 2011-11-14 2015-04-28 ADA-ES, Inc. System and method for dense phase sorbent injection
US9409123B2 (en) 2012-04-11 2016-08-09 ASA-ES, Inc. Control of wet scrubber oxidation inhibitor and byproduct recovery
US8883099B2 (en) 2012-04-11 2014-11-11 ADA-ES, Inc. Control of wet scrubber oxidation inhibitor and byproduct recovery
US10159931B2 (en) 2012-04-11 2018-12-25 ADA-ES, Inc. Control of wet scrubber oxidation inhibitor and byproduct recovery
US11065578B2 (en) 2012-04-11 2021-07-20 ADA-ES, Inc. Control of wet scrubber oxidation inhibitor and byproduct recovery
US10758863B2 (en) 2012-04-11 2020-09-01 ADA-ES, Inc. Control of wet scrubber oxidation inhibitor and byproduct recovery
US9889405B2 (en) 2012-04-11 2018-02-13 ADA-ES, Inc. Control of wet scrubber oxidation inhibitor and byproduct recovery
US8974756B2 (en) 2012-07-25 2015-03-10 ADA-ES, Inc. Process to enhance mixing of dry sorbents and flue gas for air pollution control
US10767130B2 (en) 2012-08-10 2020-09-08 ADA-ES, Inc. Method and additive for controlling nitrogen oxide emissions
US11384304B2 (en) 2012-08-10 2022-07-12 ADA-ES, Inc. Method and additive for controlling nitrogen oxide emissions
US11369921B2 (en) 2014-11-25 2022-06-28 ADA-ES, Inc. Low pressure drop static mixing system
US10350545B2 (en) 2014-11-25 2019-07-16 ADA-ES, Inc. Low pressure drop static mixing system

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