Búsqueda Imágenes Maps Play YouTube Noticias Gmail Drive Más »
Iniciar sesión
Usuarios de lectores de pantalla: deben hacer clic en este enlace para utilizar el modo de accesibilidad. Este modo tiene las mismas funciones esenciales pero funciona mejor con el lector.

Patentes

  1. Búsqueda avanzada de patentes
Número de publicaciónUSRE30233 E
Tipo de publicaciónConcesión
Número de solicitudUS 05/600,154
Fecha de publicación18 Mar 1980
Fecha de presentación29 Jul 1975
Fecha de prioridad28 May 1971
Número de publicación05600154, 600154, US RE30233 E, US RE30233E, US-E-RE30233, USRE30233 E, USRE30233E
InventoresWilliam C. Lane, Donald E. Moffatt
Cesionario originalThe Mead Corporation
Exportar citaBiBTeX, EndNote, RefMan
Enlaces externos: USPTO, Cesión de USPTO, Espacenet
Multiple layer decorated paper, laminate prepared therefrom and process
US RE30233 E
Resumen
A decorated multiple layer paper suitable for use as a top surface in resin impregnated abrasion resistance decorated laminates, and the laminates prepared therefrom, said multiple layer having a base layer and a top layer, the top layer comprising abrasion resisting mineral particles having a hardness of 7 or more on the Moh scale and a particle size ranging from 10 to 75 microns, and with a printed pattern over the exposed surface of the top layer. The multiple layer paper is made by depositing a base layer on a paper machine forming wire, and while the base layer is in a wet state and still supported on the forming wire, depositing the top layer thereover. Abrasion resistant decorative laminates are prepared from said decorated multiple layer paper by saturating said paper with a resin, suitably a thermosetting resin followed by uniting with a core and curing of said resin.
Imágenes(1)
Previous page
Next page
Reclamaciones(13)
What is claimed is:
1. An abrasion resistant laminate comprising a core and a resin impregnated cured decorated surface paper, said surface paper, prior to resin impregnation comprising
(a) a paper base layer;
(b) a top layer integral with said base layer and comprising from about 2 to 100 percent by weight of abrasion resisting mineral particles having a hardness of from 7 to 10 on the Moh scale and an average particle size ranging from 10 to 75 microns, and
(c) printing applied on the exposed outer surface of said top layer.
2. The abrasion resistant laminate of claim 1 wherein said resin is a thermosetting resin.
3. The abrasion resistant laminate of claim 1 wherein said top layer includes fibers.
4. The abrasion resistant laminate of claim .[.2.]. .Iadd.3 .Iaddend.wherein said top layer comprises from 10% to 50% of said mineral particles and from 90% to 50% of said fibers.
5. The abrasion resistant laminate of claim 1 wherein said mineral particles are alumina.
6. The abrasion rsistant laminate of claim 1 wherein said mineral particles are silica.
7. The abrasion resistant laminate of claim 1 wherein said mineral particles are silicon carbide.
8. The abrasion resistant laminate of claim 1 wherein said mineral particles are a mixture of tungsten carbide and borron carbide.
9. The abrasion resistant laminates of claim 1 wherein said top layer has a basis weight ranging from 1 to 20 lbs. per ream of 3000 sq. ft.
10. The abrasion resistant laminate of claim 1 wherein said base layer comprises fibers.
11. The abrasion resistant laminate of claim 9 wherein said base layer has a basis weight ranging from 10 to 100 lbs. per ream of 3000 sq. ft.
12. The abrasion resistant laminate of claim 1 wherein said base layer comprises fibers and opacifying pigments, and has a basis weight ranging from 30 to 100 lbs. per ream of 3000 sq. ft. and said top layer comprises from 10% to 50% alumina having a particle size distribution of 96% in the size range of 20 to 60 microns and 90% to 50% of bleached hardwood fibers, said top layer having a basis weight ranging from 4 to 14 lbs. per ream of 3000 sq. ft. .Iadd.13. An abrasion resistant laminate comprising a core and a resin impregnated printed decor paper, said printed decor paper comprising:
(a) a base paper layer of fibers and opacifying pigments; and
(b) integral with said base paper layer a printed layer comprising a mixture of abrasion resisting mineral particles having a hardness of 7 to 10 on the Moh scale and print receptive fibers, the fibers and abrasion resisting mineral particles being present in said printed layer in an amount and size to impart printability to the printed surface of the printed layer and to provide such abrasion resistance to said decor paper that upon lamination, without the presence of overlay paper, the resulting laminate has a wear rate of under 0.08 gm/100 cycles and a minimum of 400 cycles in the NEMA Method LD1-2.01 abrasion test, the printing on said printed layer being on the surface opposite the surface integral with said base layer. .Iaddend. .Iadd.14. The abrasion resistant laminate of claim 13 wherein said base paper layer has a dry basis weight ranging from 30 to 100 lbs. per ream of 3000 sq. ft. and said printed layer has a dry basis weight ranging from 4 to 14 lbs. per ream of 3000 sq. ft. .Iaddend. .Iadd.15. The abrasion resistant laminate of claim 13 wherein said printed layer includes a small amount of adhesive. .Iaddend. .Iadd.16. The abrasion resistant laminate of claim 15 wherein said adhesive is starch. .Iaddend. .Iadd.17. The abrasion resistant laminate of claim 13 wherein said decor paper includes a thin fiber layer over said printable layer. .Iaddend. .Iadd.18. An abrasion resistant laminate comprising a core and a resin impregnated printed decor paper, said printed decor paper comprising:
(a) a base paper layer;
(b) integral with said base paper layer a printed layer comprising a mixture of abrasion resisting mineral particles having a hardness of 7 to 10 on the Moh scale and print receptive fibers, the fibers and abrasion resisting mineral particles being present in said printed layer in an amount and size to impart printability to the printed layer and to provide such abrasion resistance to said decor paper that upon lamination, without the presence of overlay paper, the resulting laminate has a wear rate of under 0.08 gm/100 cycles and a minimum of 400 cycles in the NEMA Method LD1-2.01 abrasion test; and
(c) the printing on said printed layer being on the surface opposite the
surface integral with said base paper layer. .Iaddend. .Iadd. 19. The abrasion resistant laminate of claim 18 wherein said base paper layer has a dry basis weight ranging from 30 to 100 lbs. per ream of 3000 sq. ft. and said printed layer has a dry basis weight ranging from 4 to 14 lbs. per ream of 3000 sq. ft. .Iaddend..Iadd. 20. An abrasion resistant laminate comprising a core and a resin impregnated printed decor paper, said printed decor paper comprising:
(a) a base paper layer of fibers and opacifying pigments; and
(b) integral with said base paper layer a printed layer comprising a mixture of abrasion resisting alumina particles, print receptive fibers and starch, the fibers and abrasion resisting alumina particles being present in said printed layer in an amount and size to impart printability to the printable surface of the printed layer and to provide such abrasion resistance to said decor paper that upon lamination, without the presence of overlay paper, the resulting laminate has a wear rate of under 0.08 gm/100 cycles and a minimum of 400 cycles in the NEMA Method LD1-2.01 abrasion test, the printing on said printed layer being on the surface opposite the surface integral with said base paper layer. .Iaddend. .Iadd.21. The abrasion resistant laminate of claim 20 wherein said base paper layer has a dry basis weight ranging from 30 to 100 lbs. per ream of 3000 sq. ft. and said printed layer has a dry basis weight ranging from 4 to 14 lbs. per ream of 3000 sq. ft. .Iaddend..Iadd. 22. The abrasion resistant laminate of claim 20 wherein said decor paper includes a thin fiber layer over said printed layer. .Iaddend.
Descripción
REFERENCE TO RELATED APPLICATION

This application is a continuation-in-part of copending application Ser. No. 147,839, filed May 28, 1971 now abandoned.

BACKGROUND OF THE INVENTION

(1) Field of the invention

The present invention relates to laminates, more particularly to laminates having a high degree of abrasion resistance and suitable for table and counter tops, wall panels, floor surfacing, tableware and the like.

(2) Description of the prior art

Typically, laminates may be made from papers or fabrics by impregnating them with resins of various kinds, assembling several layers and consolidating the assembly into a unitary structure while converting the resin to a cured state. Resins used may be any selected from phenolics, aminoplasts, polyesters, polyurethanes, epoxy resins and the like. Consolidation of the layers to a unitary laminated structure may involve pressures ranging from essentially zero (with contact only between the layers comprising the final laminate) to 2000 lb. per sq. in. or more. Curing or setting of the resins may be accomplished at room temperature, or elevated temperatures (of the order of 150°-180° C.) to reduce the time required for curing.

The selection of the paper or fabric to be used, and the resin for impregnation is governed by the intended end-use of the finished laminate. For some end uses, surface decoration is not required or wanted, but in many instances colors and/or patterns are desired to add eye appeal to the finished laminate. While color and/or pattern decoration may be wanted for an outer surface of the laminate, the core or base functions primarily as a strengthening support, and may comprise wood, such as plywood, multiple layers of unbleached or dark colored paper or cloth, and may utilize dark colored, less expensive impregnating resins, such as phenolic resins.

When decorated laminates are desired, an outer surface layer, hereinafter called "decor," is used to cover the core layer or layers. This colored or decorated paper, may be pigmented with titanium dioxide and/or other opacifying pigments to mask the dark-colored core stock. The decor layer may be impregnated with a wide variety of resins, which may be applied to the decor in latex form, or as solutions in suitable solvents.

To impart wear and/or abrasion resistance to such decorated laminates, it has long been the practice to place a resin-impregnated surfacing paper, hereinafter called "overlay" over the decor sheet. Upon consolidating the laminate, generally under heat and pressure, the overlay sheet becomes transparent, permitting the printed pattern to be seen. More recently, particles of silica have been incorporated in overlay papers to give added abrasion resistance to laminates incorporating them. Likewise, printed decor papers have been coated with resin syrups containing abrasion resisting particles of silica, sometimes with added fibers or micro-crystalline cellulose. All the known prior art relating to abrasion resistant laminates applies a wear layer of some type over the printed pattern.

SUMMARY OF THE INVENTION

This invention relates to a multiple layer decor paper having abrasion-resisting mineral particles incorporated in the top layer thereof and having printing on the surface of said top layer, the paper being adapted to saturation with resins and incorporation into wear resistant decorative laminates, and to decorative laminates produced therefrom.

In one embodiment, the multiple-layer decor paper of this invention has a base layer of fibers and opacifying fillers, with a top layer comprising fibers and abrasion resistant mineral particles. An intermediate layer may be provided and contain decorative inclusions such as planchets or sequins, chopped foil or the like. The top surface of the paper is printed to provide the desired appearance, color and/or pattern desired in a completed laminate.

Typically, the abrasion resistant decorative laminates of this invention have a top surface ply of resin impregnated printed decor paper of this invention bonded to a base or core. No overlay is required. Surprisingly, even though the printing is applied on or over the top layer of the paper, and thus over the wear-resisting mineral particles incorporated therein, standard NEMA abrasion tests give wear rates well under 0.08 gm./100 cycles, and require up to 3000 cycles or more to the end-point (this being taken as the point where one-half the printed pattern has been abraded away). By contrast, prior art laminates with conventional decor papers require the use of overlay papers to meet the NEMA Class A specification of 400 cycles and a wear rate of 0.08 gm./100 cycles.

So far as we know, no one prior to our invention has incorporated abrasion resisting mineral particles in a top layer of a multi-layer decor paper, printed over this top layer (and thus over the abrasion resisting mineral particles), and, incorporated such paper in a laminate with no overlay to achieve the desired high abrasion resistance in the finished laminate. With the decorative pattern applied over the abrasion resistant layer, it is indeed unexpected that even nominal abrasion resistance is obtained, let alone values several times greater than that prior achieved with conventional overlay papers.

Accordingly, it is an object of this invention to provide a multi-layer decor paper having abrasion resisting mineral particles incorporated in the top layer thereof, with decorative printing applied over said top layer, such printed multi-layer decor being adapted to impregnation with resins to produce abrasion resistant decorative laminates.

It is a further object of this invention to provide a decor paper having improved quality of printing applied thereto.

It is yet another object to provide abrasion resistant laminates of improved post-forming characteristics.

Another object of this invention is to provide simplified methods for producing decor papers and laminates prepared therefrom, which laminates exhibit unusually high resistance to abrasion, without the need to incorporate overlays therein.

These and other objects will become apparent from the description which follows.

DESCRIPTION OF THE INVENTION

In the accompanying drawings:

FIG. 1 is a diagrammatic, greatly enlarged elevational section through the printed, multiple layer decor paper of this invention;

FIG. 2 is a diagrammatic, elevational section through a decorated, abrasion resistant laminate of this invention; and

FIG. 3 is a graphical showing of abrasion resistance of the decorative laminates of this invention as a function of the amount of alumina added to the decor paper of this invention.

(1) Multiple layer printed decor

The multiple layer printed decor of this invention has a base layer comprising fibers and most often, opacifying pigments such as titanium dioxide, although for some end uses of laminates where opacity of the decor is not required, the base layer may be free of opacifying pigments. Additionally, the base layer may contain strengthening agents, and formation and retention aids, all as known in the art. The weight per ream of the base layer is not critical, and may range from 10 to 100 lbs. or more per ream of 500 sheets, 24"×36" (3000 sq. ft.) A preferred range is from 30 to 100 lbs./3000 sq. ft., and very suitable opaque decors can be produced from base layers of 60 lbs./3000 sq. ft.

Such base layers are formed on the wire of a conventional paper machine having one or more secondary headboxes, with the fiber stock for the base layer delivered to the forming wire by means of a primary headbox, all as well known in the art.

To the formed, wet base layer, while still carried by the forming wire of the paper machine is added a top layer comprising abrasion resisting mineral particles. This top layer may also include fibers, and a range of mineral particles to fibers from 100% mineral particles to 5% mineral particles is useful. A preferred range is from 10% mineral particles to 50% mineral particles, with the balance made up of fibers, and excellent results are obtained with 25% mineral particles and 75% fibers. In general, the base layer must be fairly well formed but not too free of water, prior to application of the top layer, to allow the top layer components to partially mix and combine with the base layer. The dandy roll and wet presses help to accomplish the bonding together of the base and top layers, but the top layer will consist essentially of the composition as applied from the secondary headbox.

Generally speaking the mineral particles are adequately retained in the top layer by entanglement with the fibers present. However, if more positive retention is desired, a small amount of an adhesive such as starch may be incorporated in the top layer, or a thin layer of additional fibers may be applied over the top layer to intermingle and bond the mineral particles therein. Such additional fibers are suitably applied by a tertiary headbox, in an amount of the order of 2 lbs./3000 sq. ft.

Depending on the end-use properties desired in the laminates to be manufactured using the multiple layer decor of this invention, the amount of top layer applied to the base layer can range from 1 to 20 lbs./3000 sq. ft., with a preferred range of 4 to 14 lbs./3000 sq. ft. (dry basis). Excellent results are obtained with a top layer amounting to 4 to 10 lbs./3000 sq. ft. dry basis.

The abrasion resisting mineral particles comprising the top layer are selected from materials having a hardness of 7 or more on the Moh hardness scale. Such materials as silica, alumina, alundum, corundum, emery, spinel, as well as other materials such as tungsten carbide, zirconium boride, titanium nitride, tantalum carbide, beryllium carbide, silicon carbide, aluminum boride, boron carbide, diamond dust, and mixtures thereof may be used. The suitability of the abrasion resisting mineral particles will depend on such factors as availability and cost of a particular material, particle size available and color. For very light or white background colors, it is desirable to use essentially colorless mineral particles, such as alumina or silica. On the other hand, color of the mineral particles is not critical for colored decor papers, since the print patterns are applied over the surface thereof. Considering cost, availability, hardness, particle sizes available and lack of color, alumina is a preferred mineral for incorporation in the top layer.

The average particle size and particle size distribution of the mineral particles used in producing the multiple layer decor of this invention are quite important. Very fine particles of 2 microns or less, such as exhibited by the more conventional mineral fillers used in printing papers do not yield the desired high abrasion resistance in laminates. A useful range of particle size according to this invention is from 10 micron average particle size up to 75 micron average particle size. Average particle sizes much over 75 microns are coarse enough to interfere with printing detail, and may cause undue wear on caul plates. Also, fairly closely sized mineral particles are preferred to those having a wide range of particle diameters. A preferred average particle size of 40 microns has given excellent results. Alumina (Moh hardness of 9) with an average size designation of 40 microns and having the following size distribution is available from Micro Abrasives Corporation of Westfield, Mass. under the grade designation "Microgrit WCA-40" and is well-suited for our purposes:

______________________________________Size, microns:     Percent by weight______________________________________60 and over         450-60              1740-50              2930-40              3825-30              12Under 25            0______________________________________

As may be seen from the data, 67% of this material falls in the size range of 30 to 50 microns and 96% in the size range of 25-60 microns, and is a fairly closely sized material.

After deposition of the top layer over the base layer by means of a secondary headbox on the paper machine, the wet, double layer web is pressed, dried and may be calendered, all as known in the art, followed by application of a decorative printed pattern to the surface of the top layer to yield the multiple-layer decor paper of this invention, as shown in the diagrammatic vertical section of FIG. 1.

(2) Abrasion resistant laminate

The decorated, abrasion resistant plastic laminate of this invention is prepared by treating or impregnating the printed multiple layer decor of FIG. 1 with a suitable resin, drying and assembling the impregnated multiple layer decor as the surface layer, printed side out over a base or core and consolidating the assembly as by use of heat and pressure to cure the resin therein. A typical resulting laminate, such as is shown in diagrammatic vertical section in FIG. 2, although it does not contain an overlay over the print surface, still exhibits excellent abrasion resistance and high quality decorative print quality, making it suitable for numerous applications where severe wear may be expected, such as furniture, table tops and counter tops, flooring and the like. This is a wholly unexpected result, since the print pattern has not been covered with a wear-resisting layer such as an overlay paper of a coating of abrasion resisting material over the print pattern.

It should be evident that the key feature of this invention centers on achieving high abrasion resistance in a finished, decorative laminate by use of a multiple layer structure in a decor surface ply, the abrasion resistance being attributable to abrasion resisting mineral particles comprising the outer surface layer of the decor, with the printed pattern applied over this surface layer. Thus, the core of the laminate may be of any desired type, and such cores as wood, particle board, plaster board, asbestos board and the like are contemplated as being within the scope of the invention, as well as the commonly used plies of unbleached kraft paper impregnated with resins such as phenol-aldehyde resins.

Similarly, the base layer of the multiple layer decor of this invention may utilize fibers of a wide variety, these being selected to impart desired properties in finished laminates to meet particular end-use requirements. For example, the base layer may comprise asbestos or glass fibers where flame resistance is desired, and synthetic organic fibers may be used, such as nylon, rayon, acrylic, polyolefin and the like.

Selection of the resin for impregnation of the multiple layer printed decor will largely be governed by the intended end use of the finished laminate. Aminoplasts such as melaminealdehyde resins, acrylics such as polyacrylonitrile, polyester resins such as diallyl phthalate, phenolic resins, polyurethanes, and epoxy resins may be used.

The various embodiments of the invention will become apparent from the examples which follow. In the examples, the laminates of the invention, which incorporate the printed multiple layer decor of the invention were evaluated for abrasion resistance according to NEMA Method DL1-2.01. Values reported are the number of abrasive cycles required to reach an end point, which is taken as the point where one-half of the decorative print pattern has been abraded away. The wear rate is reported as the weight lost by the test laminate per 100 revolutions of the abrading wheels of the test instrument, the Taber abrasor. It should be noted that accepted industry standards for Class A laminates (suitable for table and counter tops) is a minimum of 400 cycles, with a wear rate not to exceed 0.08 gm. per 100 revolutions.

Printing quality of the multiple layer decors and laminates prepared therefrom was measured by measuring the ink receptivity of the surface of the top layer. Using a proof press and a uniform halftone plate, decor samples were printed under controlled standardized conditions using a constant metered amount of black ink on the plate. Reflectance of the resulting print was measured by a reflectance measuring instrument known as a "Densichron" to give numerical values representative of the blackness of the printed image, the blacker image resulting when the decor surface layer is more receptive to ink. Accordingly, the lower the Densichron reading, the better the printed result.

EXAMPLE 1

Bleached alpha pulp was beaten to a freeness of 500 ml. (Canadian Standard) and formed on a paper machine into a base layer weighing 22 lbs./3000 sq. ft. (dry basis). To the wet base layer on the foaming wire of the paper machine was added, by means of a secondary headbox, 10 lbs./3000 sq. ft. (dry basis) of a mixture of 1 part bleached alpha pulp and 1 part 325 mesh silica (substantially 100% finer than 44 microns). The double layer decor so formed had a total basis weight of 32 lbs./3000 sq. ft. (dry basis), with a silica content of 15.6%, based on total decor, most of the silica being retained in the top layer. After pressing, drying and calendering, the exposed side of the top layer was printed with a wood grain pattern. This printed double layer decor was then impregnated with a melamine resin and assembled, with six plies of corestock, as the top ply (printed side out) of a laminate. After pressing and curing, the laminate showed an abrasion resistance of 350 cycles and a wear rate of 0.015 gm./100 cycles. By comparison, a laminate made from the decor comprising the base layer only, and having the same print pattern, had an abrasion resistance of 100 cycles and a wear rate of 0.059 gm./100 cycles. Thus, the double layer decor of this invention improved abrasion resistance by a factor of 3.5, and wear rate by a factor of almost 4.

EXAMPLES 2 THROUGH 8 INCL.

In the examples which follow, the same base layer was used throughout, as follows: 31 parts of bleached softwood pulp, 25 parts bleached hardwood pulp and 44 parts of titanium dioxide were blended and refined to a freeness of 425 to 450 ml. (Canadian Standard). This furnish included 0.25 part of a dispersing agent for the dioxide and 1.5 parts of a wet strength agent. This composition was delivered to the primary headbox of a paper machine at a rate to form a base layer of 66.3 lbs./3000 sq. ft. (dry basis). A portion of the base layer was pressed and dried without application of any top layer, for use as a control in connection with the examples representing the invention. To a further portion of the base layer, water was added by means of a secondary headbox to check on the amount of base layer washed through the paper machine wire by reason of the application of a top layer, using the same secondary headbox. The base layer prepared in this manner had a basis weight of 60.5 lbs./3000 sq. ft. (dry basis).

A fiber component for use in the top layer, in combination with various kinds of abrasion resisting mineral particles, comprised bleached hardwood pulp refined to a freeness of 425 ml. (Canadian Standard). The fiber component was mixed in various ratios with a variety of abrasion resistant mineral particles, then applied by means of a secondary headbox to the wet primary layer on the wire of the paper machine. The double layer web, in each case, was then pressed, dried and calendered. Following this, the same printed pattern was applied to the exposed side of the top layer of the several different examples.

Each of the double layer printed decors was then impregnated with a 50% solution of the same melamineformaldehyde resin to give a 48-52% resin content and dried to a volatile content of about 6%. Laminates were then prepared by employing the resin impregnated multiple layer decors as surface sheets, printed side out, over six sheets of corestock. Pressing and curing were under the same time, temperature and pressure conditions in each case.

__________________________________________________________________________              Control                   Example              plus         Control              H.sub.2 O                   2    3    4    5     6     7     8__________________________________________________________________________Top layer composition:Hardwood fibers, percent                   50   50   50   50    50    50    5040μ Al.sub.2 O.sub.3, percent                   50   5090μ Al.sub.2 O.sub.3, percent  50   5040μ SiC, percent                          5035-40μ Norbide 320.sup.3                        50    50Physical properties:Basis wt., base layer         66.3 60.5 60.5 60.4 60.5 60.5  60.5  60.5  60.5Basis wt., top layer    6.5  8.5  4.6  5.2   4.4   6.3   7.8Basis wt., total         66.3 60.5 67.0 69.0 65.1 65.7  64.9  66.8  68.3Ash, total percent         38.6 38.2 38.8 38.5 37.4 36.2  37.3  39.7  40.2Ash, TiO.sub.2, percent         38.6 38.2 34.6 33.5 35.5 35.2  35.6  34.6  33.9Mineral particles, percent                   4.2  5.0  1.9  1.0   1.7   5.1   6.3Abrasion tests on laminates:Cycles to end point         93        625  783  233  208   1.917 3,200 3,833Wear rate, gm./100 cycles         0.077     0.0111                        0.0071                             0.0281                                  0.0387                                        0.0033                                              0.0023                                                    0.0018Printing evaluation:Densichron-decor         30.0      29.0 27.0 28.0 26.0  30.0  38.0  37.0Densichron-laminate         13.5      11.0 10.5 11.0 10.5  13.0  24.5  21.5__________________________________________________________________________ .sup.3 Norbide is a mixture of tungsten carbide and boron carbide having hardness in excess of 9 on the Moh scale.
EXAMPLES 9 THROUGH 16 INCL.

In this series of examples, the base layer as used in Examples 2 through 8 was used throughout. The top layer utilized the same hardwood fiber component in 1:1 ratios with alumina of different particle sizes to show the relationship between particle size and abrasion resistance of laminates, as well as relative print quality, other factors being held constant. Results are tabulated below.

______________________________________  Av.    Alumina  Densi-  Abra- Resistance  particle         in total chron-  sion  wear,  size,  decor,   lami-   cycles                                g./100  μ   percent  nate    to E.P.                                cycles______________________________________Control            0       18.5  100   0.0710Example No.: 9       40       3.3      16.8  767   0.009110       40       4.6      16.3  900   0.007611       40       4.9      15.0  944   0.007012       60-65    3.5      16.5  1,050 0.006213       60-65    4.0      18.0  1,087 0.005614       75       2.7      16.7  210   0.027115       75       3.5      15.5  342   0.014216       90       2.5      15.8  450   0.0152______________________________________

As may be seen, optimum abrasion resistance is obtained in the particle size range of 40 to 65 microns. In all cases, printing quality, as judged by Densichron readings, was equal to or somewhat better than the control.

EXAMPLES 17 THROUGH 20

Using the base layer of Example 2, the top layer was varied by using a mixture of two different sized alumina powders, one being closely sized at 60 to 95 microns and the other being an unsized fraction having particles ranging from 1 to 60 microns, and a weight-average size of 40 microns. These were compared with laminates having closely sized 40 micron alumina in the top layer.

__________________________________________________________________________Example number     17   18   19   20__________________________________________________________________________Top layer composition:Bleached hardwook pulp, percent              50   50   50   6040μ alumina          50   4060-65μ alumina  33             26.4Unsized alumina    17        13.6Physical properties:Basis wt, base layer              58.0 59.0 59.5 57.5Basis wt, top layer              5.5  5.5  5.5  5.0Basis wt, total    63.5 61.5 65.0 62.5TiO.sub.2, percent 36.2 36.2 36.2 36.4Alumina percent    3.8  3.8  3.0  2.1Abrasion tests:Cycles to end point              550  833  664  625Wear rate, gm./100 cycles              0.0090                   0.0080                        0.0106                             0.0106Ink receptivity: Densichron-laminate              18.0 16.5 16.0 16.8__________________________________________________________________________

From this data, it may be seen that closely sized 40 micron alumina gives somewhat better abrasion resistance than the mixture, although all these examples meet NEMA standards for Class A laminates.

EXAMPLES 21 THROUGH 25 INCL.

In this series of examples, using the base layer of Example 2, the ratio of fibers to 40 micron alumina was varied over wide limits. The following tabulation shows the results obtained.

______________________________________Example number  21      22     23   24   25______________________________________Top layer composition:Bl. hardwood fibers, per-cent            80      70     40   20   040μ alumina, percent           20      30     60   80   100Physical properties:Basis wt., base layer           58.5    59.0   60.5 61.0 59.5Basis wt., top layer           5.5     4.5    3.5  4.3  2.0Basis wt., total           64.0    63.5   64.0 65.3 61.5TiO.sub.2, percent           36.5    37.1   37.7 37.2 38.6Alumina, percent           2.2     2.4    3.4  4.9  2.2Abrasion tests:Cycles to end point           442     552    787  1,210                                    810Wear rate, gm./100 cycles           0.0131  .0106  .0070                               .0051                                    .0066Ink receptivity: Densichron-laminate        15.3    16.0   16.3 16.5 17.5______________________________________

These examples show that, as the proportion of fibers decreases in the top layer, abrasion resistance generally increases. While Example 25, containing no fiber in the top layer shows a decrease in abrasion resistance, note that the weight of top layer applied is only 2 lbs. per 3000 sq. ft.

EXAMPLES 26 THROUGH 34 INCL.

In these examples, the base layer composition was the same and consisted of:

______________________________________                   Parts______________________________________Bleached softwood sulfite pulp                     27.7Bleached hardwood sulfite pulp                     27.7Bleached softwood sulfate pulp                     27.7Titanium dioxide          2.0Diatomaceous earth        14.9Zinc oxide                2.9Dyes to produce brown color                     6.49______________________________________

This composition was processed in conventional paper-making equipment, and refined to a freeness of 425 ml. (Canadian Standard). It was delivered to the primary headbox of a paper machine and formed into a base layer of 60 lbs. per ream of 3000 sq. ft.

The top layer, applied over the base layer by a secondary headbox, consisted of bleached hardwood sulfite and closely sized 40 micron alumina (available from Micro Abrasives Corp. and identified as Microgrit WCA040). The amount of top layer applied as well as the ratio of fibers to alumina were varied as shown in the following tabulation.

The multi-layer decor papers produced in these examples were printed, saturated with a melamine resin and made into laminates according to Example 2. Tests of the papers and laminates are set forth in the following tabulation.

__________________________________________________________________________            Example number       Control            26 27 28 29 30 31 32 33 34__________________________________________________________________________Top layer composition:Fibers, percent  50 50 50 50 50 50 50 67 6740μ alumina, percent            50 50 50 50 50 50 50 33 33Physical properties:Basis wt., base layer       59.6 62.0               59.6                  61.0                     59.6                        61.0                           59.6                              59.6                                 59.6                                    6.15Basis wt., top layer            4.9               7.0                  8.0                     8.2                        9.0                           12.0                              13.9                                 8.4                                    8.5Basis wt., total       59.6 66.9               66.6                  69.0                     67.8                        70.0                           71.6                              73.5                                 68.0                                    70.0Total ash, percent       20.2 22.9               23.8                  24.9                     24.3                        24.4                           25.5                              26.3                                 23.0                                    23.2Ash, base, percent       20.2 18.8               18.1                  17.9                     17.8                        17.6                           16.8                              16.4                                 17.8                                    17.8Alumina, percent       0    4.1               5.7                  7.0                     6.5                        6.8                           8.7                              9.9                                 5.2                                    5.4Abrasion tests:Cycles to E.P.       130  1,100               1,100                  1,500                     1,300                        1,575                           1,900                              2,125                                 1,140                                    1,150Wear rate, gm./100 c       .0650            .0057               .0055                  .0041                     .0044                        .0041                           .0040                              .0042                                 .0063                                    .0051Ink receptivity:Densichron-decor       41.0 39.0               36.0                  35.5                     37.0                        36.0                           35.5                              33.5                                 36.0                                    36.0Densichron-laminate       31.2 32.0               30.1                  30.0                     32.5                        29.3                           28.0                              26.7                                 28.5                                    29.4__________________________________________________________________________

FIG. 3 has been constructed from the data obtained in these examples, and shows the relationship between abrasion resistance of the laminate and the amount of alumina in the top layer. Denischron data show that, in each case, ink receptivity of the double layer decor paper is improved over the control. Visual examination of the completed laminates confirms this. The improvement in printing quality is probably traceable to the presence of relatively fine hardwood fibers and closely sized mineral particles in the top surface of the double layer decor.

It is also interesting to note that, in each case, the final color of the laminate was indistinguishable from the final color of the laminate prepared from the control (base layer only), even though no coloring dyes or pigments were incorporated in the top layer. This indicates that the top layer has become essentially transparent following resin impregnation, pressing and curing.

EXAMPLE 35

In this example, the base layer of Example 2 was used. To this layer, while on the wire of a paper machine, was added an intermediate layer having a composition of 50 parts bleached hardwood sulfite fibers and 50 parts of 40-micron alumina to which was added a sufficient quantity of sequins cut from aluminum foil to yield approximately 100 sequins in each 10 sq. inches of the intermediate layer. Over the surface of the intermediate layer, while it and the base layer were still carried by the wire of the paper machine, a top layer of 50 parts bleached hardwood sulfite fibers and 50 parts 40-micron alumina was added by means of a third headbox. The resultant 3-layer product was pressed dried, calendered and printed to yield a multiple layer decor. The base layer had a basis weight of 60.5 lbs./3000 sq. ft., the intermediate layer a basis weight of 3.0 lbs./3000 sq. ft. and the top layer a basis weight of 2.8 lbs./3000 sq. ft. for a total of 66.3 lbs./3000 sq. ft.

This three layered decor was incorporated in a laminate according to Example 2. When tested, the laminate showed an abrasion resistance of 1500 cycles and a wear rate of 0.0046 gm./100 cycles.

EXAMPLES 36 THROUGH 38 INCL.

Using the base layer of Example 2, top layers using blends of bleached hardwood sulfite pulp and cotton linters were used, with 40 micron alumina as the abrasion resisting mineral particles. The results are tabulated below:

______________________________________           Example number           Control                  36     37     38______________________________________Top layer composition:Bleached hardwood pulp, percent             0        20     35   67Cotton linters, percent             0        30     1540μ alumina, percent             0        50     50   33Physical properties:Basis wt., base layer             58.5     59.0   59.0 61.0Basis wt., top layer       4.0    3.8  2.8Basis wt., total  58.5     63.0   62.8 63.8TiO.sub.2, percent             39.9     37.4   37.5 38.1Alumina, percent  0        1.7    1.7  1.7Abrasion tests:Cycles to end point             74       683    663  535Wear rate, gm./100 cycles             .0716    .0075  .0092                                  .0102Ink receptivity:Densichron-decor  31.0     31.0   31.2 30.8Densichron-laminate             16.3     16.3   15.3 15.3______________________________________

All the laminates had adequate levels of abrasion resistance and ink receptivity. Additionally, the laminates of Examples 36 and 37, each of which contained cotton linters in the surface layer, showed very acceptable post-formability, being capable of post forming to 1/2-inch radius bends with no perceptible cracking or crazing in the bend region. Both the control and Example 38 could not be post formed to 1/2-inch radius without objectionable cracking and/or crazing.

EXAMPLE 39

In this example, the printed multi-layer decor paper of Example 33 was saturated with 58% of a polyester resin, then pressed at 270° F. for 2 minutes at 200 p.s.i. The finished laminate was tested for its abrasion resistance in comparison with a similar laminate using the single layer printed decor of the control sample for Examples 26-34, with the following results:

______________________________________Abrasion resistance             Control    Example 39______________________________________Cycles to end-point             300        500Wear rate, gm./100 cycles             0.068      0.0484______________________________________
EXAMPLES 40 THROUGH 43

The printed multi-layer decors of Examples 28 and 33 were each saturated with a low pressure melamine resin and with a diallyl phthalate resin crosslinked with styrene. The low pressure melamine samples were pressed for 3.25 minutes at 300° F. and 300 p.s.i., while the diallyl phthalate samples were cured for 9 minutes at 240° F. under 50 p.s.i. with the following results:

______________________________________Example number       40      41      42    43    Control______________________________________Decor fromexample number       28      33      28    33    39Resin used.sup.1       LPM     LPM     DAP   DAP   DAPCycles to end-point       1.500   1.060   530   490   290Wear rate,  0.0058  0.0073  0.0240                             0.0314                                   0.0710gm./100 cycles______________________________________ .sup.1 LPM is low pressure melamine. DAP is diallyl phthalate.

While the low pressure melamine is a harder resin than diallyl phthalate, both show marked improvement in abrasion resistance resulting from the decor of this invention.

EXAMPLES 44-45

Sheets of the printed multi-layer decor paper of Examples 28 and 33 were saturated with a self-crosslinking acrylic resin in latex form. The water was evaporated and the resin cross-linked by heating at 130° C. The resultant product was suitable for such applications as wear resistant book covers, or could be adhered to a base or core to provide a thicker, laminated structure.

Abrasion resistance of the cured sheets, prior to any laminating or adhering step was as follows:

______________________________________Example number    44      45      Control______________________________________Decor from example number             33      28      39Percent acrylic resin             32      34      34Cycles to end point             400     600     140______________________________________

Again, the marked improvement in abrasion resistance attained with the printed multi-layer decor of this invention is evident.

Citas de patentes
Patente citada Fecha de presentación Fecha de publicación Solicitante Título
US1230095 *11 Feb 191619 Jun 1917James E Baum JrPaper.
US1672988 *12 Abr 192212 Jun 1928Raybestos CoPlied sheet and method of producing the same
US1953111 *16 Jun 19303 Abr 1934Westinghouse Electric & Mfg CoLaminated material and method of producing same
US2060824 *14 Jun 193317 Nov 1936Raffold Process CorpPaper manufacture
US2202488 *21 Feb 193828 May 1940Bird & SonFloor covering
US2599092 *30 Abr 19463 Jun 1952Vanderbilt Co R TMultiple layer paper containing pigmented pulp and method of making
US3123515 *18 Mar 19583 Mar 1964 Now by judicial change of name
US3135643 *31 May 19602 Jun 1964Gen ElectricDecorative laminates
US3190786 *10 May 196122 Jun 1965Fitchburg PaperDecorative laminated paper
US3223579 *1 Oct 196214 Dic 1965Stanley H BaldwinPigment coated paper including polyvinyl alcohol binder as hardboard overlay
US3287207 *17 Abr 196422 Nov 1966Huber Corp J MMethod of distributing siliceous fillers uniformly throughout a water-laid web while the web is on the fourdrinier wire
US3343975 *22 Ago 196326 Sep 1967Congoleum Nairn IncProcess of producing decorative surface covering
US3372084 *18 Jul 19665 Mar 1968Mead CorpPost-formable absorbent paper
US3373070 *1 May 196412 Mar 1968Gen ElectricLaminates
US3373071 *26 Mar 196412 Mar 1968Gen ElectricLaminates
US3445327 *26 Mar 196420 May 1969Gen ElectricAbrasive-resistant decorative laminates and method for making same
US3525664 *29 Nov 196725 Ago 1970Domtar LtdAbrasion resistant plastic laminate and method of making same
US3540978 *8 Nov 196717 Nov 1970Kimberly Clark CoAbrasion resistant laminates and coating therefor
US3551241 *23 Ago 196729 Dic 1970Formica CorpProcess for producing a decorative laminate comprising transferring a film of a transparent noble thermosetting resin to a decorative sheet from a flexible release transfer sheet and removing the flexible release sheet after the heat and pressure consolidation step
US3562076 *3 Mar 19679 Feb 1971Minnesota Mining & MfgFlooring with decorative filler
US3661673 *1 May 19699 May 1972Woodall Industries IncMethod of making plastic laminate having high abrasion resistance
US3716440 *29 Dic 197013 Feb 1973Ilrigawa Electric Ind Co LtdMethod of manufacturing a resinous decorative laminate having a lustrous pattern of really metallic surface
BE775555A1 Título no disponible
Citada por
Patente citante Fecha de presentación Fecha de publicación Solicitante Título
US4971855 *2 May 198820 Nov 1990Nevamar CorporationWear-resistant glossy laminates
US5141799 *20 Mar 199125 Ago 1992The Mead CorporationLow scratch, abrasion-resistant overlay and decor papers
US5252378 *13 May 199212 Oct 1993The Mead CorporationMethod of producing decorative sheets having localized patterns of color, decorative sheets produced by such method, and laminates employing such decorative sheets
US5266384 *18 Jul 199130 Nov 1993Nevamar CorporationAesthetic surface layer
US5344704 *7 Abr 19936 Sep 1994Nevamar CorporationAbrasion-resistant, aesthetic surface layer laminate
US5456949 *29 Dic 199410 Oct 1995Formica Technology Inc.Method of producing damage resistant decorative laminate
US5466511 *2 Sep 199314 Nov 1995Nevamar CorporationCoated transfer sheet and laminate produced therefrom
US5601930 *15 Feb 199511 Feb 1997The Mead CorporationDecor sheet and decorative laminates prepared therefrom
US5702806 *25 Abr 199630 Dic 1997O'dell; Robin D.Decorative laminate surface layer
US5820937 *6 Dic 199513 Oct 1998The Mead CorporationProcess for making high abrasion overlays
US5866207 *12 May 19972 Feb 1999International Paper CompanyProcess for producing aesthetic surface layer composition and aesthetic surface layer
US5866208 *12 May 19972 Feb 1999International Paper CompanyProcess for producing aesthetic surface layer composition and aesthetic surface layer
US5866209 *12 May 19972 Feb 1999International Paper CompanyProcess for producing aesthetic surface layer composition and aesthetic surface layer
US6551455 *8 Nov 200122 Abr 2003The Mead CorporationMulti-layer printable wear resistant papers including particle rich interior layer
US6568148 *14 Ago 199827 May 2003Akzenta Paneele + Profile GmbhCovering element for building surfaces or the like and method for the production thereof
US6994764 *13 Oct 20017 Feb 2006Munksjoe Paper Decor Gmbh & Co. KgMethod for producing a shaped part
US72494459 Nov 200631 Jul 2007Flooring Industries Ltd.Floor covering, floor panels for forming such floor covering, and method of realizing such floor panels
US7386963 *3 Feb 200517 Jun 2008Valinge Innovation AbLocking system and flooring board
US75845839 Jul 20078 Sep 2009Valinge Innovation AbResilient groove
US760121228 Ago 200613 Oct 2009E.I. Du Pont De Nemours And CompanyPigment particles coated with polysaccharides and having improved properties
US775745231 Mar 200320 Jul 2010Valinge Innovation AbMechanical locking system for floorboards
US784221210 Abr 200630 Nov 2010Flooring Industries Limited, SarlFloor covering, floor panels for forming such floor covering, and method for realizing such floor panels
US7866115 *9 Jul 200711 Ene 2011Valinge Innovation AbFloorboards with decorative grooves
US792623420 Mar 200319 Abr 2011Valinge Innovation AbFloorboards with decorative grooves
US79308625 Ene 200726 Abr 2011Valinge Innovation AbFloorboards having a resilent surface layer with a decorative groove
US79542959 Jul 20077 Jun 2011Valinge Innovation AbLocking system and flooring board
US802848626 Jul 20024 Oct 2011Valinge Innovation AbFloor panel with sealing means
US803307515 Ago 200711 Oct 2011Välinge Innovation ABLocking system and flooring board
US80424844 Oct 200525 Oct 2011Valinge Innovation AbAppliance and method for surface treatment of a board shaped material and floorboard
US80437156 Jun 200625 Oct 2011E. I. Du Pont De Nemours And CompanyPaper and paper laminates containing modified titanium dioxide
US821507815 Feb 200510 Jul 2012Välinge Innovation Belgium BVBABuilding panel with compressed edges and method of making same
US82454778 Abr 200321 Ago 2012Välinge Innovation ABFloorboards for floorings
US824547811 Mar 201121 Ago 2012Välinge Innovation ABSet of floorboards with sealing arrangement
US82615049 Jul 200711 Sep 2012Valinge Innovation AbV-groove
US832301615 Sep 20064 Dic 2012Valinge Innovation Belgium BvbaDevice and method for compressing an edge of a building panel and a building panel with compressed edges
US8365488 *23 Feb 20115 Feb 2013Mannington Mills, Inc.Methods and systems for decorating bevel and other surfaces of laminated floorings
US83814889 Jul 200726 Feb 2013Valinge Innovation AbFloorboards for floorings
US84298693 May 201130 Abr 2013Valinge Innovation AbLocking system and flooring board
US84298729 Jul 200730 Abr 2013Valinge Innovation Belgium BvbaBuilding panel with compressed edges and method of making same
US84755826 Mar 20082 Jul 2013E I Du Pont De Nemours And CompanyProcess for making a water dispersible titanium dioxide pigment useful in paper laminates
US851103118 Jul 201220 Ago 2013Valinge Innovation AbSet F floorboards with overlapping edges
US853558927 Sep 201017 Sep 2013Flooring Industries Limited, SarlFloor covering, floor panels for forming such floor covering, and method for realizing such floor panels
US858442321 Ene 201119 Nov 2013Valinge Innovation AbFloor panel with sealing means
US859169117 Dic 201026 Nov 2013Valinge Innovation AbMethods and arrangements relating to surface forming of building panels
US8597766 *6 Ene 20093 Dic 2013Pergo (Europe) AbProcess for manufacture of surface elements
US868369811 Mar 20111 Abr 2014Valinge Innovation AbMethod for making floorboards with decorative grooves
US87201514 Feb 201313 May 2014Valinge Innovation AbFloorboards for flooring
US886948629 Mar 201328 Oct 2014Valinge Innovation AbLocking system and flooring board
US887546425 Abr 20134 Nov 2014Valinge Innovation AbBuilding panels of solid wood
US888895624 Abr 201218 Nov 2014E I Du Pont De Nemours And CompanyTreated inorganic pigments having improved bulk flow and their use in paper slurries
US893589910 Ene 201320 Ene 2015Valinge Innovation AbLamella core and a method for producing it
US89402169 Jul 200727 Ene 2015Valinge Innovation AbDevice and method for compressing an edge of a building panel and a building panel with compressed edges
US911547020 Jun 201225 Ago 2015The Chemours Company Tt, LlcTreated inorganic pigments having reduced photoactivity and anti-microbial properties and their use in paper slurries
US9120074 *11 Oct 20121 Sep 2015The Chemours Company Tt, LlcLaminate paper treated with inorganic pigments having improved dispersability
US91400101 Jul 201322 Sep 2015Valinge Flooring Technology AbPanel forming
US916965422 Oct 201327 Oct 2015Valinge Innovation AbMethods and arrangements relating to surface forming of building panels
US91941358 Abr 201424 Nov 2015Valinge Innovation AbFloorboards for floorings
US93221839 Sep 201326 Abr 2016Valinge Innovation AbFloor covering and locking systems
US944758726 Ago 201520 Sep 2016Valinge Innovation AbMethods and arrangements relating to surface forming of building panels
US948201530 Mar 20161 Nov 2016Ceraloc Innovation AbPanel forming
US95282761 Oct 201427 Dic 2016Valinge Innovation AbLocking system and flooring board
US953955711 Oct 201210 Ene 2017The Chemours Company Tt, LlcTreated inorganic pigments having improved dispersability and use thereof in coating compositions
US955662325 May 201631 Ene 2017Ceraloc Innovation AbPanel forming
US95677535 Dic 201314 Feb 2017Valinge Innovation AbLocking system, floorboard comprising such a locking system, as well as method for making floorboards
US957310811 Oct 201221 Feb 2017The Chemours Company Tt, LlcTreated inorganic core particles having improved dispersability
US960543615 Nov 201328 Mar 2017Valinge Innovation AbFloorboard, system and method for forming a flooring, and a flooring formed thereof
US96234332 Nov 201218 Abr 2017Valinge Innovation AbAppliance and method for surface treatment of a board shaped material and floorboard
US966395613 Ago 201530 May 2017Ceraloc Innovation AbPanel forming
US97589669 Dic 201412 Sep 2017Valinge Innovation AbLamella core and a method for producing it
US20020117277 *8 Nov 200129 Ago 2002Johnson Mark A.Multi-layer printable wear resistant papers including particle rich interior layer
US20030024199 *26 Jul 20026 Feb 2003Darko PervanFloor panel with sealing means
US20040112515 *13 Oct 200117 Jun 2004Erich RathgebMethod for producing a shaped part
US20040200567 *6 May 200414 Oct 2004Laurence MottProcess for the manufacturing of an improved core for decorative laminates and a decorative laminate obtained by the process
US20050102937 *3 Feb 200519 May 2005Valinge Aluminium AbLocking System And Flooring Board
US20050208255 *8 Abr 200322 Sep 2005Valinge Aluminium AbFloorboards for floorings
US20060070333 *31 Mar 20036 Abr 2006Darko PervanMechanical locking system for floorboards
US20060073320 *4 Oct 20056 Abr 2006Valinge Aluminium AbAppliance And Method For Surface Treatment Of A Board Shaped Material And Floorboard
US20060179773 *15 Feb 200517 Ago 2006Valinge Aluminium AbBuilding Panel With Compressed Edges And Method Of Making Same
US20060179774 *10 Abr 200617 Ago 2006Flooring Industies Ltd.Floor covering, floor panels for forming such floor covering, and method for realizing such floor panels
US20060179776 *10 Abr 200617 Ago 2006Flooring Industries Ltd.Floor covering, floor panels for forming such floor covering, and method for realizing such floor panels
US20060275597 *6 Jun 20067 Dic 2006Thiele Erik SPaper and paper laminates containing modified titanium dioxide
US20070051064 *9 Nov 20068 Mar 2007Thiers Bernard P JFloor covering, floor panels for forming such floor covering, and method of realizing such floor panels
US20070068423 *27 Sep 200529 Mar 2007Thiele Erik STitanium dioxide pigment useful in paper laminates
US20070071989 *27 Sep 200529 Mar 2007Thiele Erik SPaper laminates
US20070175144 *22 Dic 20062 Ago 2007Valinge Innovation AbV-groove
US20070175148 *5 Ene 20072 Ago 2007Valinge Innovation AbResilient groove
US20070181038 *28 Ago 20069 Ago 2007Subramaniam SabesanPigment particles coated with polysaccharides and having improved properties
US20080000179 *9 Jul 20073 Ene 2008Valinge Innovation AbFloorboards with decorative grooves
US20080000182 *9 Jul 20073 Ene 2008Valinge Innovation AbLocking system and flooring board
US20080000190 *9 Jul 20073 Ene 2008Valinge Innovation AbV-groove
US20080000417 *9 Jul 20073 Ene 2008Valinge Innovation AbAppliance and method for surface treatment of a board shaped material and floorboard
US20080008871 *9 Jul 200710 Ene 2008Valinge Innovation AbFloorboards for floorings
US20080028707 *15 Ago 20077 Feb 2008Valinge Innovation AbLocking System And Flooring Board
US20080066425 *9 Jul 200720 Mar 2008Valinge Innovation AbDevice and method for compressing an edge of a building panel and a building panel with compressed edges
US20080120938 *15 Sep 200629 May 2008Jan JacobssonDevice and method for compressing an edge of a building panel and a building panel with compressed edges
US20080160267 *6 Mar 20083 Jul 2008Erik Shepard ThieleProcess for making a water dispersible titanium dioxide pigment useful in paper laminates
US20080308009 *15 Ago 200818 Dic 2008Erik Shepard ThieleTitanium dioxide pigment useful in paper laminates
US20090208705 *6 Ene 200920 Ago 2009Nilsson Magnus NProcess for manuafacture of surface elements
US20100040841 *29 Nov 200518 Feb 2010Kunz-Holding Gmbh & Co. KgWeb-like coating film
US20110131901 *21 Ene 20119 Jun 2011Valinge Innovation AbFloor panel with sealing means
US20110146188 *17 Dic 201023 Jun 2011Valinge Innovation AbMethods and arrangements relating to surface forming of building panels
US20110154665 *11 Mar 201130 Jun 2011Valinge Innovation AbFloorboards with decorative grooves
US20110154763 *11 Mar 201130 Jun 2011Valinge Innovation AbResilient groove
US20110203214 *3 May 201125 Ago 2011Valinge Innovation AbLocking system and flooring board
US20110219716 *23 Feb 201115 Sep 2011Mannington Mills, Inc.Methods and Systems For Decorating Bevel and Other Surfaces Of Laminated Floorings
US20140338852 *11 Oct 201220 Nov 2014E I Du Pont De Nemours And CompanyTreated inorganic pigments having improved dispersability and use thereof in paper products
WO1999009274A2 *14 Ago 199825 Feb 1999Akzenta Paneele + Profile GmbhCovering element for building surfaces or the like and method for the production thereof
WO1999009274A3 *14 Ago 199815 Abr 1999Akzenta Paneele & Profile GmbhCovering element for building surfaces or the like and method for the production thereof
WO2007027711A129 Ago 20068 Mar 2007E. I. Du Pont De Nemours And CompanyPigment particles coated with polysaccharides and having improved properties
Clasificaciones
Clasificación de EE.UU.428/207, 427/205, 427/203, 162/186, 428/329, 264/132, 428/219, 156/277, 442/412, 442/417, 162/181.6, 428/328
Clasificación internacionalB44C5/04, B32B29/00, D21H27/28
Clasificación cooperativaY10T442/699, Y10T442/693, B44C5/0476, Y10T428/24901, B32B29/00, D21H27/28, Y10T428/256, Y10T428/257
Clasificación europeaD21H27/28, B44C5/04R2, B32B29/00