USRE31883E - Resinoid grinding wheels containing nickel-coated cubic boron nitride particles - Google Patents

Resinoid grinding wheels containing nickel-coated cubic boron nitride particles Download PDF

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USRE31883E
USRE31883E US05/859,243 US85924377A USRE31883E US RE31883 E USRE31883 E US RE31883E US 85924377 A US85924377 A US 85924377A US RE31883 E USRE31883 E US RE31883E
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boron nitride
cubic boron
nickel
formaldehyde
coated
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US05/859,243
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Harold P. Bovenkerk
William A. Berecki
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General Electric Co
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General Electric Co
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • C09K3/14Anti-slip materials; Abrasives
    • C09K3/1436Composite particles, e.g. coated particles
    • C09K3/1445Composite particles, e.g. coated particles the coating consisting exclusively of metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D18/00Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D18/00Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
    • B24D18/0009Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for using moulds or presses
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/02Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
    • B24D3/20Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially organic
    • B24D3/28Resins or natural or synthetic macromolecular compounds

Definitions

  • Boron nitride is a compound which comes in a “soft” form and in two “hard” forms. In the “soft” form it is a material which crystallizes in the hexagonal system and cleaves readily in a manner similar to graphite and molybdenum disulfide. Like these materials it is a good dry lubricant.
  • boron nitride If boron nitride is subjected to ultrahigh pressures and elevated temperatures, it is converted to a cubic crystal similar to the crystal of zincblende to produce one of its "hard” forms.
  • the preparation of this form of boron nitride is disclosed and claimed in Wentorf U.S. Pat. No. 2,947,617 which is assigned to the same assignee as the present invention.
  • the zincblende form of boron nitride was discovered some years before the wurtzite form. Both the zincblende and wurtzite forms are useful in the practice of this invention and it is intended that the wurtzite form be included in the term "cubic boron nitride".
  • cubic boron nitride occurred several years after the discovery of a reproducible synthesis for diamond. Initially it was thought that cubic boron nitride was as hard as diamond but additional investigations revealed that cubic boron nitride is a close second to diamond in hardness. Both are considerably harder than other abrasive materials.
  • Synthetic diamond became commercially available as an abrasive in 1957. It was early established that the abrasive qualities of synthetic diamond were superior to those of natural diamond. The disparity in favor of synthetic has steadily increased as processes for tailoring the product to specific applications have been developed.
  • cubic boron nitride When cubic boron nitride was first discovered, it was thought that it would have widespread usage due to its hardness and other properties. For instance, cubic boron nitride can withstand temperatures of 2,500° F. whereas diamond begins to burn at 1,600° F. Nevertheless, cubic boron nitride proved to be inferior to diamond as an abrasive for tungsten carbides, ceramics, and natural stones. It offered advantages over diamond in the cutting of hardened steels and steel alloys but neither diamond nor cubic boron nitride was competitive with such abrasives as aluminum oxide for hardened steels and steel alloys.
  • cubic boron nitride is 21/2 times as hard as aluminum oxide, its cost per gram would inherently be about the same as the cost per kilogram of aluminum oxide. Even though other cost factors such as labor, wheel dressing, etc., favored cubic boron nitride, the disparity in material cost was too great for cubic boron nitride to compete in the aluminum oxide market.
  • metal-coated diamond was introduced to the market for use in resinoid grinding wheels.
  • the use of metal-coated diamond extended the effectiveness of grinding wheels by a factor of two.
  • Such wheels are described in Lindstrom and Lundblad South African Pat. No. 66/5310 advertised on Mar. 8, 1967 and assigned to Allmanna Svenska Elektriska Aktiebolaget.
  • Another document describing metal-coated diamond resinoid wheels is Sacco South African Pat. No. 67/2576 of the Norton Company.
  • the Sacco patent pointed out that it had been known to coat aluminum oxide abrasive grains with nickel to achieve improved bonding of abrasive particles in a resinoid wheel.
  • the Sacco patent gave examples of five resinoid wheels using diamond abrasives coated with various metals.
  • the improvement in grinding ratio versus wheels made with uncoated diamond varied from 37 percent to 280 percent.
  • the most-improved wheels removed 3.8 times as much material from workpieces as did wheels made with uncoated diamond from similar workpieces.
  • a resinoid grinding wheel employing abrasive particles of cubic boron nitride coated with nickel to the extent of 30 to 80 weight percent of the coated particles is much more effective than a similar wheel in which the particles are uncoated.
  • the resinoid grinding wheel of the present invention is characterized by the use of nickel-coated cubic boron nitride particles as the abrasive medium.
  • the use of such abrasive particles does not necessitate other alterations in wheel structure and so the resinoid wheel may otherwise be of conventional construction. This statement is not intended to mean that nickel-coated cubic boron nitride wheels do not give improved performance with certain resins or with particular methods of fabrication.
  • the resin most frequently used in resin-bonded grinding wheels is a phenol-formaldehyde reaction product.
  • resins or organic polymers such as melamine or urea-formaldehyde resins, epoxy resins, polyesters, polyamides, and polyimides.
  • Polyimides in particular have shown promising results.
  • the abrasive surface of nickel-coated cubic boron nitride grinding wheels will contain about 25 percent by volume of abrasive.
  • the size of the particles critical to the success of the invention. It is desirable that the entire surface of particles be coated and that the weight of the coating be 30 to 80 percent of the combined weight of the particle and coating. Generally, the particle size will range from 60 mesh to 325 mesh but larger or smaller particles may be used to advantage depending upon service requirements.
  • formulations and treatments may be varied widely to meet specific service requirements.
  • the mold pressure is reduced to about 5,000 pounds per square inch
  • the molding temperature is about 500° F.
  • the time in the mold is 10-15 minutes
  • the postmold treatment is about 21/2 hours at about 475° F. Accordingly, the procedures outlined above are given for purposes of illustration only and should not be considered as limiting the invention.
  • the grinding ratio achieved at 0.002 inch downfeed with the coated cubic boron nitride abrasive is considerably higher than that of the uncoated cubic boron nitride abrasive at 0.001 inch downfeed.
  • the wheel wear of coated cubic boron nitride at double the material removal rate is less than the wheel wear of uncoated cubic boron nitride at half that material removal rate.
  • Table II shows that the performance improvement obtainable on M-2 steel is maintained on A-2 steel.
  • cubic boron nitride is quite inferior to diamond in cutting tungsten carbides. The reverse is true, although not uniformly so, in the case of hardened steels and steel alloys.
  • Table IV below compares grinding ratios for aluminum oxide, nickel-coated cubic boron nitride and nickel-coated diamond on a number of hardened steels.
  • Table IV shows that nickel-coated cubic boron nitride is superior to nickel-coated diamond on all except the D-2 steel.
  • M-2 and O-1 steels the superiority of cubic boron nitride is dramatic and surprising. The reasons for the wide variation in performance are not clearly understood at the present time. However, as previously stated, the physical and chemical properties of the workpiece play a large role in wheel effectiveness.
  • Table IV also gives grinding ratios for aluminum oxide, the most commonly used commercial abrasive for hardened steels and steel alloys.
  • the vast superiority of nickel-coated cubic boron nitride over aluminum oxide emphasizes the importance of this invention in enabling cubic boron nitride to be competitive with aluminum oxide in spite of the great cost and price differential between the two.
  • Table V below compares the dry grinding ability of nickel-coated cubic boron nitride vs. nickel-coated diamond vs. aluminum oxide on three alloy steels.
  • the results listed in Table V are averaged and rounded off values from a number of tests made under comparable conditions of grinding.
  • the M-42 material differed from the M-2 material in having 1.5 percent tungsten vs. 6.00 percent of M-2; 9.5 percent molybdenum vs. 5.00 percent for M-2; .Iadd.1.10 percent carbon vs. 0.85 percent for M-2; 1.15 percent vanadium vs. 2.0 percent for M-2; 3.75 percent chromium vs. 4.00 percent for M-2; .Iaddend.and 8.00 percent cobalt vs. 0.00 percent for M-2.
  • Table IV shows a striking improvement for nickel-coated cubic boron nitride over nickel-coated diamond for most steels subject to wet grinding
  • Table V shows even a more striking improvement in the case of dry grinding.
  • nickel-coated diamond is .[.no better than.].

Abstract

An improved resinoid grinding wheel particularly useful for the wet or dry grinding of hardened steels and steel alloys utilizes nickel-coated cubic boron nitride particles as the abrasive medium.

Description

BACKGROUND OF THE INVENTION
Boron nitride is a compound which comes in a "soft" form and in two "hard" forms. In the "soft" form it is a material which crystallizes in the hexagonal system and cleaves readily in a manner similar to graphite and molybdenum disulfide. Like these materials it is a good dry lubricant.
If boron nitride is subjected to ultrahigh pressures and elevated temperatures, it is converted to a cubic crystal similar to the crystal of zincblende to produce one of its "hard" forms. The preparation of this form of boron nitride is disclosed and claimed in Wentorf U.S. Pat. No. 2,947,617 which is assigned to the same assignee as the present invention.
If "soft" boron nitride is subjected to pressures of at least about 113 kilobars preferably at a temperature somewhat higher than room temperature, it is converted to a densely packed form of "hard" boron nitride possessing the same hexagonal crystal structure as the mineral wurtzite. This form of "hard" boron nitride is disclosed and claimed in Bundy et al. U.S. Pat. No. 3,212,851 which also is assigned to the same assignee as the present invention.
The zincblende form of boron nitride was discovered some years before the wurtzite form. Both the zincblende and wurtzite forms are useful in the practice of this invention and it is intended that the wurtzite form be included in the term "cubic boron nitride".
The discovery of cubic boron nitride occurred several years after the discovery of a reproducible synthesis for diamond. Initially it was thought that cubic boron nitride was as hard as diamond but additional investigations revealed that cubic boron nitride is a close second to diamond in hardness. Both are considerably harder than other abrasive materials.
Synthetic diamond became commercially available as an abrasive in 1957. It was early established that the abrasive qualities of synthetic diamond were superior to those of natural diamond. The disparity in favor of synthetic has steadily increased as processes for tailoring the product to specific applications have been developed.
From the inception of its commercialization, synthetic diamond has been a growing industry. Its use in a resin-bonded wheel for grinding tungsten carbides has brought about great economies in the finishing of carbide tools. Its use in a metal bond has resulted in saws which bring about great improvement in the cutting of natural stones and ceramics.
When cubic boron nitride was first discovered, it was thought that it would have widespread usage due to its hardness and other properties. For instance, cubic boron nitride can withstand temperatures of 2,500° F. whereas diamond begins to burn at 1,600° F. Nevertheless, cubic boron nitride proved to be inferior to diamond as an abrasive for tungsten carbides, ceramics, and natural stones. It offered advantages over diamond in the cutting of hardened steels and steel alloys but neither diamond nor cubic boron nitride was competitive with such abrasives as aluminum oxide for hardened steels and steel alloys. Thus, although cubic boron nitride is 21/2 times as hard as aluminum oxide, its cost per gram would inherently be about the same as the cost per kilogram of aluminum oxide. Even though other cost factors such as labor, wheel dressing, etc., favored cubic boron nitride, the disparity in material cost was too great for cubic boron nitride to compete in the aluminum oxide market.
In 1967, metal-coated diamond was introduced to the market for use in resinoid grinding wheels. Typically, the use of metal-coated diamond extended the effectiveness of grinding wheels by a factor of two. Such wheels are described in Lindstrom and Lundblad South African Pat. No. 66/5310 advertised on Mar. 8, 1967 and assigned to Allmanna Svenska Elektriska Aktiebolaget. Another document describing metal-coated diamond resinoid wheels is Sacco South African Pat. No. 67/2576 of the Norton Company.
The Sacco patent pointed out that it had been known to coat aluminum oxide abrasive grains with nickel to achieve improved bonding of abrasive particles in a resinoid wheel. In addition, the patent postulated that the greater heat conductivity of heat capacity of diamond coated with metal prevented rapid deterioration of the resin matrix in the vicinity of the abrasive grit thereby allowing for longer retention of the abrasive grit in the resin matrix.
The Sacco patent gave examples of five resinoid wheels using diamond abrasives coated with various metals. The improvement in grinding ratio versus wheels made with uncoated diamond varied from 37 percent to 280 percent. Thus, the most-improved wheels removed 3.8 times as much material from workpieces as did wheels made with uncoated diamond from similar workpieces. These levels of improvement are typical of what has been achieved by metal-coated diamond.
SUMMARY OF THE INVENTION
In accordance with the present invention it has been discovered that a resinoid grinding wheel employing abrasive particles of cubic boron nitride coated with nickel to the extent of 30 to 80 weight percent of the coated particles is much more effective than a similar wheel in which the particles are uncoated.
DESCRIPTION OF THE PREFERRED EMBODIMENT
The resinoid grinding wheel of the present invention is characterized by the use of nickel-coated cubic boron nitride particles as the abrasive medium. The use of such abrasive particles does not necessitate other alterations in wheel structure and so the resinoid wheel may otherwise be of conventional construction. This statement is not intended to mean that nickel-coated cubic boron nitride wheels do not give improved performance with certain resins or with particular methods of fabrication.
In a typical preparation of a resin-bonded nickel-coated cubic boron nitride grinding wheel, a mixture of granulated resin, nickel-coated cubic boron nitride particles and filler is placed in a grinding wheel mold, a molding pressure appropriate to the particular resin--usually of the order of several thousand pounds per square inch--is applied and the mold is heated to a temperature sufficient to make the resin granules deform plastically and to cure in cases where the resin used is heat-curable.
The resin most frequently used in resin-bonded grinding wheels is a phenol-formaldehyde reaction product. However, other resins or organic polymers may be used such as melamine or urea-formaldehyde resins, epoxy resins, polyesters, polyamides, and polyimides. Polyimides in particular have shown promising results. Typically, the abrasive surface of nickel-coated cubic boron nitride grinding wheels will contain about 25 percent by volume of abrasive.
There is no novel technology involved in applying a nickel coating to the cubic boron nitride particles nor is the size of the particles critical to the success of the invention. It is desirable that the entire surface of particles be coated and that the weight of the coating be 30 to 80 percent of the combined weight of the particle and coating. Generally, the particle size will range from 60 mesh to 325 mesh but larger or smaller particles may be used to advantage depending upon service requirements.
Typical processes for applying a nickel coating to cubic boron nitride particles are by electroless deposition, well known in the art, but sputtering as disclosed and claimed in Vanderslice U.S. Pat. No. 3,351,543, which is assigned to the same assignee as the present invention, or by high vacuum deposition from a filament composed of nickel. In the latter case, it is necessary to agitate the cubic boron nitride particles in order to insure a nickel coating on all surfaces. After a thin film of nickel has been applied by one process, the film may be built up by another process such as conventional electrolytic deposition from an electrolyte solution. It is not necessary that the nickel have an extremely tenacious bond with the cubic boron nitride substrate.
The following is a typical procedure for formulating a resin-bonded cubic boron nitride grinding wheel:
1. Weight out the material as follows: 40 volume percent nickel-coated cubic boron nitride using density of 5.29 g./cc.; 39 volume percent phenolic resin using a density of 1.28 g./cc. (The phenolic resin powder is preferably less than 100 mesh). 21 volume percent filler composed of silicon carbide approximately 20 microns in size using 3.22 g./cc. as the density.
2. Premix or blend in a mortar and pestle the resin and filler until homogeneous. Mix cubic boron nitride with 1 percent of a wetting agent which is typically furfural. Combine cubic boron nitride, furfural and resin filler mixture and lightly mix with mortar and pestle until homogeneous.
3. Load mixture into mold cavity, hot press on heated platen press at 350° F. and 10,000 p.s.i. for 30 minutes. The molding process is typically done to a stop rather than at constant pressure using the amount of mixture to completely fill the cavity based on the above density calculation.
4. Cool mold and strip rim and hub from mold cavity. Post-cure phenolic at 375° F. Raise temperature at the rate of 25° per hour. Hold 375° F. for 12 hours. Cool at the rate of 25° per hour. Total time: 36 hours.
As those skilled in the art are aware, formulations and treatments may be varied widely to meet specific service requirements. For example, when a polyimide resin is substituted for the phenolic resin, the mold pressure is reduced to about 5,000 pounds per square inch, the molding temperature is about 500° F., the time in the mold is 10-15 minutes, and the postmold treatment is about 21/2 hours at about 475° F. Accordingly, the procedures outlined above are given for purposes of illustration only and should not be considered as limiting the invention.
Resin-bonded nickel-coated cubic boron nitride wheels have performed wet and dry grinding of Type A2 steel, which is commonly used for dies, high speed cutting tool steels, etc.; Type T-15 steel which has a high tungsten content; and Type M-2 steel which has molybdenum as the principal alloying ingredient. Table I below gives performance figures for an M-2 steel comparing nickel-coated cubic boron nitride wheels with uncoated cubic boron nitride wheels. The term "grinding ratio" is the unit volume of work material removed per unit volume of wheel wear.
              TABLE I                                                     
______________________________________                                    
WET SURFACE GRINDING                                                      
                                      Percent                             
                 Coating              Performance                         
                 Level    Down-       Improvement                         
                 (Weight  feed  Grind-                                    
                                      Over Similar                        
Borazon Mesh     %        Per   ing   Uncoated                            
Wheel No.                                                                 
        Size     Nickel)  Pass  Ratio Wheel                               
______________________________________                                    
ASD-177 80/100   0        .001  273   --                                  
ASD-175 80/100   59.6     .001  891   .[.226.]..Iadd. 227.Iaddend.        
ASD-177 80/100   0        .002   29   --                                  
ASD-175 80/100   59.6     .002  367   1165                                
B1A1-5-170                                                                
        140/170  0        .001  109   --                                  
ASD-182 140/170  64.6     .001  655   .[.502.]..Iadd. 501.Iaddend.        
B1Al-5-170                                                                
        140/170  0        .002   15   --                                  
ASD-182 140/170  64.6     .002  139   .[.828.]..Iadd. 827.Iaddend.        
______________________________________                                    
It will be noted from Table 1 that the minimum improvement brought about by applying a coating of nickel to the cubic boron nitride particles was .[.226.]. .Iadd.227 .Iaddend.percent. Even more spectacular is the relative performance improvement gained with nickel-coated cubic boron nitride where the material removal rate is doubled by increasing the downfeed from 0.001 to 0.002 inch. At the increased material removed rate conditions the grinding ratio achieved with the coated versus uncoated abrasive is .[.365.]. .Iadd.367 .Iaddend.and 29, respectively. In this case, the performance improvement is 1,165 percent. In fact, the grinding ratio achieved at 0.002 inch downfeed with the coated cubic boron nitride abrasive is considerably higher than that of the uncoated cubic boron nitride abrasive at 0.001 inch downfeed. Thus, the wheel wear of coated cubic boron nitride at double the material removal rate is less than the wheel wear of uncoated cubic boron nitride at half that material removal rate.
Table II below gives comparative test results on four additional samples of M-2 steel having a Rockwell C hardness of 60 and also four samples of A-2 steel having a Rockwell C hardness of 61:
              TABLE II                                                    
______________________________________                                    
WET SURFACE GRINDING                                                      
                 Coating                                                  
                 Level    Down-                                           
                 (%       feed  Grind-                                    
                                      Percent of                          
Borazon Wheel                                                             
          Ma-    Weight   Per   ing   Performance                         
and Mesh Size                                                             
          terial Nickel)  Pass  Ratio Improvement                         
______________________________________                                    
R5090, 100/120                                                            
          M-2    0        .001" 160   --                                  
R5091, 100/120                                                            
          M-2    60       .001" 593   .[.270.]..Iadd. 271.Iaddend.        
R5090, 100/120                                                            
          M-2    0        .002"  16   --                                  
R5091, 100/120                                                            
          M-2    60       .002" 340   .[.2010.]..Iadd. 2,025.Iaddend.     
R5090, 100/120                                                            
          A-2    0        .001"  25   --                                  
R5091, 100/120                                                            
          A-2    60       .001" 175   600                                 
R5090, 100/120                                                            
          A-2    0        .002" 12                                        
                                --                                        
R5091, 100/120                                                            
          A-2    60       .002"  35*  .[.190.]..Iadd. 192.Iaddend.        
______________________________________                                    
 *Wheel R5091 was nearly consumed by the time this test was begun and only
 one test point could be run at .002" downfeed on A2 material.            
 Consequently, the grinding ratio attained is at best questionable and is 
 included only to show that an improvement over uncoated cubic baron      
 nitride was attained even with a wheel having an extremely thin layer of 
 abrasive remaining.                                                      
Table II shows that the performance improvement obtainable on M-2 steel is maintained on A-2 steel.
Table III below gives comparative performance figures covering the dry grinding of samples of M-2 steel having a Rockwell C hardness of 64 and T-15 steel having a Rockwell C hardness of 65:
              TABLE III                                                   
______________________________________                                    
DRY GRINDING                                                              
         Coating                      Percent                             
         Level                        Performance                         
         (%                           Improvement                         
Borazon  Nickel          Infeed/                                          
                                Grind-                                    
                                      Over Similar                        
Wheel and                                                                 
         by       Ma-    Double-                                          
                                ing   Uncoated                            
Mesh Size                                                                 
         Weight   terial pass   Ratio Wheel                               
______________________________________                                    
FC911, 60/80                                                              
         0        M-2    .001"  126   --                                  
FC928, 60/80                                                              
         60       M-2    .001"  1849  .[.1370.]..Iadd. 1,367.Iaddend.     
FC911, 60/80                                                              
         0        M-2    .002"   19   --                                  
FC928, 60/80                                                              
         60       M-2    .002"  310   .[.1530 .]..Iadd. 1,532.Iaddend.    
FC911, 60/80                                                              
         0        T-15   .001"   51   --                                  
FC928, 60/80                                                              
         60       T-15   .001"  145   .[.165.]..Iadd. 184.Iaddend.        
FC911, 60/80                                                              
         0        T-15   .002"   60   --                                  
FC928, 60/80                                                              
         60       T-15   .002"   62   3                                   
______________________________________                                    
The results for M-2 steel shown in Table III further substantiate the exceptional increase in performance attained by the use of nickel-coated cubic boron nitride. In the case of T-15 steel, the improvement was not so appreciable at an infeed of 0.001 inch and at an infeed of 0.002 inch the grinding ratio was substantially the same whether the nickel coating was or was not present. The T-15 results show that there are many factors which enter into performance figures and the element of predictability is not very high. In addition to such items as wheel diameter, wheel width, wheel speed, etc., the feed rate and physical properties of the workpiece play an important part in determining optimum grinding conditions.
It was previously pointed out that cubic boron nitride is quite inferior to diamond in cutting tungsten carbides. The reverse is true, although not uniformly so, in the case of hardened steels and steel alloys. Table IV below compares grinding ratios for aluminum oxide, nickel-coated cubic boron nitride and nickel-coated diamond on a number of hardened steels.
              TABLE IV                                                    
______________________________________                                    
WET SURFACE GRINDING                                                      
                                    Percent                               
                                    Improvement                           
     Al.sub.2 O.sub.3                                                     
              Nickel-Coated                                               
                          Nickel-Coated                                   
                                    Borazon                               
Ma-  Grinding Borazon     Diamond   Over                                  
terial                                                                    
     Ratio    Grinding Ratio                                              
                          Grinding Ratio                                  
                                    Diamond                               
______________________________________                                    
M-2  4.5      1030         85       .[.1100.]..Iadd. 1,112.Iaddend.       
M-4  2.0      180          95       .[.90.]..Iadd. 89.Iaddend.            
T-15 .8       120         100       20                                    
0-1  50       750         135       455                                   
A-2  20       390         210       86                                    
W-1  40       420         270       55                                    
D-2  3.0      650         1000      -35                                   
______________________________________                                    
In Table IV, the M-4 material is a molybdenum alloy steel differing from the M-2 material in having a higher carbon content and a vanadium content of 4 percent instead of 2 percent.Iadd., tungsten content of 5.5 percent versus 6.00 percent and molybdenum content of 4.5 percent versus 5.00 percent .Iaddend..The O-1 material is a oil hardened cold work tool steel. The W-1 material is a water hardened tool steel. The D-2 material is a high carbon, high chromium type of cold work tool steel.
Table IV shows that nickel-coated cubic boron nitride is superior to nickel-coated diamond on all except the D-2 steel. In the case of M-2 and O-1 steels, the superiority of cubic boron nitride is dramatic and surprising. The reasons for the wide variation in performance are not clearly understood at the present time. However, as previously stated, the physical and chemical properties of the workpiece play a large role in wheel effectiveness.
Table IV also gives grinding ratios for aluminum oxide, the most commonly used commercial abrasive for hardened steels and steel alloys. The vast superiority of nickel-coated cubic boron nitride over aluminum oxide emphasizes the importance of this invention in enabling cubic boron nitride to be competitive with aluminum oxide in spite of the great cost and price differential between the two.
Table V below compares the dry grinding ability of nickel-coated cubic boron nitride vs. nickel-coated diamond vs. aluminum oxide on three alloy steels.
              TABLE V                                                     
______________________________________                                    
DRY SURFACE GRINDING                                                      
        Nickel-                                                           
        coated                                                            
        cubic    Nickel-           Improvement                            
        boron    coated            Percent                                
        nitride  diamond    Al.sub.2 O.sub.3                              
                                   nitride                                
        grinding grinding   grinding                                      
                                   over diamond                           
Material                                                                  
        ratio    ratio      ratio  and Al.sub.2 O.sub.3                   
______________________________________                                    
M-2     1,200    10         10     11,900                                 
M-42    900      10         10     8,900                                  
T-15    500      10         10     4,900                                  
______________________________________                                    
The results listed in Table V are averaged and rounded off values from a number of tests made under comparable conditions of grinding. The M-42 material differed from the M-2 material in having 1.5 percent tungsten vs. 6.00 percent of M-2; 9.5 percent molybdenum vs. 5.00 percent for M-2; .Iadd.1.10 percent carbon vs. 0.85 percent for M-2; 1.15 percent vanadium vs. 2.0 percent for M-2; 3.75 percent chromium vs. 4.00 percent for M-2; .Iaddend.and 8.00 percent cobalt vs. 0.00 percent for M-2. While Table IV shows a striking improvement for nickel-coated cubic boron nitride over nickel-coated diamond for most steels subject to wet grinding, Table V shows even a more striking improvement in the case of dry grinding. In fact, nickel-coated diamond is .[.no better than.]. .Iadd.only comparable to .Iaddend.aluminum oxide for the dry grinding of tool steels and is greatly inferior to its performance in wet grinding. This is in sharp contrast to nickel-coated cubic boron nitride which is as good in dry grinding applications as it is in wet grinding.
The data of Tables I-V show a surprising degree of superiority of nickel-coated cubic boron nitride over uncoated borazon as well as a surprising degree of superiority of nickel-coated cubic boron nitride over nickel-coated diamond in the grinding of most tool steels and steel alloys. Of particular interest and commercial importance is the ability of nickel-coated cubic boron nitride to grind alloy steels under dry grinding conditions. Nevertheless, these data are also contradictory in certain respects for they show that a superiority in grinding one material does not necessarily carry over to another material or, if it does carry over, that the degree of superiority is changed considerably. Diamond and cubic boron nitride share in common only the properties of extreme hardness and the cubic crystal system. (Both diamond and cubic boron nitride can be superhard in a hexagonal form but this form of both materials is relatively rare). From the standpoint of elemental composition and chemistry there is no relationship between the carbon of diamond and the boron nitride of cubic boron nitride. As was heretofore mentioned, cubic boron nitride can withstand temperatures of 2,500° F. whereas diamond begins to burn at 1,600° F. Sacco contended that the improvement brought about in resinoid wheels by the use of metal-coated diamond was due to the improved bond between the resin and metal and the different thermal properties of metal-coated diamond versus uncoated diamond. The data of Tables I-V suggest that, at best, Sacco's explanation is over-simplified and that there may be other, more important factors presently unidentified which are responsible. This is further borne out by the fact that copper-coated cubic boron nitride did not produce a significantly better grinding wheel for dry grinding than uncoated cubic boron nitride. Copper-coated and cobalt-coated cubic boron nitride wheels were superior to uncoated wheels for wet grinding but were inferior to nickel-coated wheels.
It might be supposed that the combination of boron and nickel is responsible for the results shown in Tables I-V. In order to test this, three wheels were made with boron carbide abrasive. These wheels were identical except that in one the abrasive had no coating. In another, the abrasive had a coating of 49 percent by weight of nickel and in the other, 58.8 percent nickel. All three wheels were tested on M-2 steel. The uncoated wheel had a grinding ratio of 1.00; the wheel with 49 percent nickel had a grinding ratio of 1.01; and the wheel with 58.8 percent nickel had a grinding ratio of 0.73. Thus, the experimental results achieved so far do not provide a clear explanation of the principles underlying the invention.

Claims (6)

What we claim as new and desire to secure by Letters Patent of the United States is:
1. In a grinding wheel for hardened steel and steel alloys, an abrasive surface consisting of nickel-coated cubic boron nitride particles, the nickel constituting from 30 to 80 weight percent of the coated particles, said coated particles being embedded in a matrix of resinous material selected from the group consisting of phenol-formaldehyde, urea-formaldehyde, melamine-formaldehyde, epoxy, polyester, polyamide and polyimide resins, and mixtures thereof.Iadd., said wheel being formed in a mold by pressing to a stop.Iaddend..
2. A grinding wheel as claimed in claim 1 wherein the resinous material is phenol formaldehyde.
3. A grinding wheel as claimed in claim 1 wherein the resinous material is a polyimide.
4. A method of making an abrasive wheel for hardened steel and steel alloys comprising applying a coating of nickel to a quantity of cubic boron nitride particles, the nickel constituting about 30 to 80 weight percent of the coated particles, mixing said coated particles with resinous material, selected from the group consisting of phenol-formaldehyde, urea-formaldehyde, melamine-formaldehyde, epoxy, polyester, polyamide and polyimide resins, and mixtures thereof and forming the coated cubic boron nitride resinous material mixture as the abrasive surface of a grinding wheel .Iadd.in a mold by pressing to a stop.Iaddend..
5. A .Iadd.method of making an abrasive .Iaddend.grinding wheel as claimed in claim 4 wherein the resinous material is phenol formaldehyde.
6. A .Iadd.method of making an abrasive .Iaddend.grinding wheel as claimed in claim 4 wherein the resinous material is a polyimide .Iadd.and said pressing to a stop step is carried out at 5000 p.s.i..Iaddend.. .Iadd.7. A method of grinding hardened steel and steel alloys comprising the steps of: providing an abrasive grinding wheel whose surface comprises nickel-coated cubic boron nitride particles, the nickel constituting about 30 to 80 weight percent of the coated particle, in a matrix of resinous material selected from the group consisting of phenol-formaldehyde, urea-formaldehyde, melamine-formaldehyde, epoxy, polyester, polyamide and polyimide resins, and mixtures thereof, said wheel being formed in a mold by pressing to a stop; providing a hardened steel or steel alloy workpiece; rotating said grinding wheel; and contacting said workpiece with said rotating abrasive surface, whereby said surface abrades said workpiece..Iaddend. .Iadd.8. The method of claim 7, wherein said resinous material is phenol formaldehyde..Iaddend. .Iadd.9. The method of claim 7, wherein said resinous material is a polyimide..Iaddend.
US05/859,243 1969-12-16 1977-12-09 Resinoid grinding wheels containing nickel-coated cubic boron nitride particles Expired - Lifetime USRE31883E (en)

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5104422A (en) * 1989-05-30 1992-04-14 General Electric Company Refractory metal oxide coated abrasives and grinding wheels made therefrom
EP0532261A1 (en) * 1991-09-12 1993-03-17 General Electric Company Process for making coated abrasives
US5355637A (en) * 1991-06-04 1994-10-18 Rolls-Royce Plc Abrasive medium
US5484665A (en) * 1991-04-15 1996-01-16 General Electric Company Rotary seal member and method for making
US5551840A (en) * 1993-12-08 1996-09-03 United Technologies Corporation Abrasive blade tip
US6524357B2 (en) 2000-06-30 2003-02-25 Saint-Gobain Abrasives Technology Company Process for coating superabrasive with metal
US6593391B2 (en) 2001-03-27 2003-07-15 General Electric Company Abrasive-filled thermoset composition and its preparation, and abrasive-filled articles and their preparation
US6663682B2 (en) 2000-06-30 2003-12-16 Saint-Gobain Abrasives Technology Company Article of superabrasive coated with metal
US20040106750A1 (en) * 1999-12-01 2004-06-03 General Electric Company Capped poly(arylene ether) composition and method
US20040122174A1 (en) * 2002-10-11 2004-06-24 Mather Patrick T. Blends of amorphous and semicrystalline polymers having shape memory properties
US20050109990A1 (en) * 2001-01-18 2005-05-26 Yeager Gary W. Electrically conductive thermoset composition, method for the preparation thereof, and articles derived therefrom
US20050137307A1 (en) * 2003-08-07 2005-06-23 Yeager Gary W. Thermoset composition, method for the preparation thereof, and articles prepared therefrom
US20090286914A1 (en) * 2004-12-17 2009-11-19 Solvay Advanced Polymers, L.L.C. Semi-crystalline polymer composition and article manufactured therefrom

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2947617A (en) * 1958-01-06 1960-08-02 Gen Electric Abrasive material and preparation thereof
US3351543A (en) * 1964-05-28 1967-11-07 Gen Electric Process of coating diamond with an adherent metal coating using cathode sputtering
BE698428A (en) * 1966-05-16 1967-11-13
US3408172A (en) * 1966-03-01 1968-10-29 Gen Electric Diamond and cubic boron nitride grains coated with photopolymerized material
BE724829A (en) * 1967-12-04 1969-05-16
US3528788A (en) * 1967-07-03 1970-09-15 Engelhard Ind Inc Etched metal coated diamond grains in grinding wheels
US3645706A (en) * 1969-12-16 1972-02-29 Gen Electric Resinoid grinding wheels containing nickel-coated cubic boron nitride particles
US3904391A (en) * 1965-09-22 1975-09-09 Asea Ab Metal-coated diamonds in synthetic resin bonded grinding wheels

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2947617A (en) * 1958-01-06 1960-08-02 Gen Electric Abrasive material and preparation thereof
US3351543A (en) * 1964-05-28 1967-11-07 Gen Electric Process of coating diamond with an adherent metal coating using cathode sputtering
US3904391A (en) * 1965-09-22 1975-09-09 Asea Ab Metal-coated diamonds in synthetic resin bonded grinding wheels
US3408172A (en) * 1966-03-01 1968-10-29 Gen Electric Diamond and cubic boron nitride grains coated with photopolymerized material
BE698428A (en) * 1966-05-16 1967-11-13
US3528788A (en) * 1967-07-03 1970-09-15 Engelhard Ind Inc Etched metal coated diamond grains in grinding wheels
BE724829A (en) * 1967-12-04 1969-05-16
US3518068A (en) * 1967-12-04 1970-06-30 Gen Electric Process for manufacturing grinding wheels containing coppercoated grains
US3645706A (en) * 1969-12-16 1972-02-29 Gen Electric Resinoid grinding wheels containing nickel-coated cubic boron nitride particles

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5104422A (en) * 1989-05-30 1992-04-14 General Electric Company Refractory metal oxide coated abrasives and grinding wheels made therefrom
US5484665A (en) * 1991-04-15 1996-01-16 General Electric Company Rotary seal member and method for making
US5545431A (en) * 1991-04-15 1996-08-13 General Electric Company Method for making a rotary seal membrane
US5355637A (en) * 1991-06-04 1994-10-18 Rolls-Royce Plc Abrasive medium
EP0532261A1 (en) * 1991-09-12 1993-03-17 General Electric Company Process for making coated abrasives
US5306318A (en) * 1991-09-12 1994-04-26 General Electric Company Process for making coated abrasives for grinding wheels
US5551840A (en) * 1993-12-08 1996-09-03 United Technologies Corporation Abrasive blade tip
US5603603A (en) * 1993-12-08 1997-02-18 United Technologies Corporation Abrasive blade tip
US20040106750A1 (en) * 1999-12-01 2004-06-03 General Electric Company Capped poly(arylene ether) composition and method
US7235192B2 (en) 1999-12-01 2007-06-26 General Electric Company Capped poly(arylene ether) composition and method
US8192649B2 (en) 1999-12-01 2012-06-05 Sabic Innovative Plastics Ip B.V. Capped poly(arylene ether) composition and method
US20070191577A1 (en) * 1999-12-01 2007-08-16 Yeager Gary W Capped poly(arylene ether) composition and method
US6663682B2 (en) 2000-06-30 2003-12-16 Saint-Gobain Abrasives Technology Company Article of superabrasive coated with metal
US6524357B2 (en) 2000-06-30 2003-02-25 Saint-Gobain Abrasives Technology Company Process for coating superabrasive with metal
US20050109990A1 (en) * 2001-01-18 2005-05-26 Yeager Gary W. Electrically conductive thermoset composition, method for the preparation thereof, and articles derived therefrom
US7354533B2 (en) 2001-01-18 2008-04-08 General Electric Company Electrically conductive thermoset composition, method for the preparation thereof, and articles derived therefrom
US6593391B2 (en) 2001-03-27 2003-07-15 General Electric Company Abrasive-filled thermoset composition and its preparation, and abrasive-filled articles and their preparation
US6770107B2 (en) 2001-03-27 2004-08-03 General Electric Company Abrasive-filled thermoset composition and its preparation, and abrasive-filled articles and their preparation
US20030153641A1 (en) * 2001-03-27 2003-08-14 Hua Guo Abrasive-filled thermoset composition and its preparation, and abrasive-filled articles and their preparation
US7208550B2 (en) 2002-10-11 2007-04-24 The University Of Connecticut Blends of amorphous and semicrystalline polymers having shape memory properties
US20040122174A1 (en) * 2002-10-11 2004-06-24 Mather Patrick T. Blends of amorphous and semicrystalline polymers having shape memory properties
US20050137307A1 (en) * 2003-08-07 2005-06-23 Yeager Gary W. Thermoset composition, method for the preparation thereof, and articles prepared therefrom
US7199213B2 (en) 2003-08-07 2007-04-03 General Electric Company Thermoset composition, method for the preparation thereof, and articles prepared therefrom
US20090286914A1 (en) * 2004-12-17 2009-11-19 Solvay Advanced Polymers, L.L.C. Semi-crystalline polymer composition and article manufactured therefrom

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