USRE34255E - Static mixing device - Google Patents

Static mixing device Download PDF

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Publication number
USRE34255E
USRE34255E US07/882,325 US88232592A USRE34255E US RE34255 E USRE34255 E US RE34255E US 88232592 A US88232592 A US 88232592A US RE34255 E USRE34255 E US RE34255E
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United States
Prior art keywords
conduit
tubes
product
heat transfer
mixing device
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Expired - Lifetime
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US07/882,325
Inventor
Juergen Friedrich
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Krup Corp
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Krup Corp
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Filing date
Publication date
Priority claimed from US07/188,909 external-priority patent/US4865460A/en
Application filed by Krup Corp filed Critical Krup Corp
Priority to US07/882,325 priority Critical patent/USRE34255E/en
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Publication of USRE34255E publication Critical patent/USRE34255E/en
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/0058Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits for only one medium being tubes having different orientations to each other or crossing the conduit for the other heat exchange medium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40Static mixers
    • B01F25/42Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
    • B01F25/43Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
    • B01F25/431Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor
    • B01F25/4319Tubular elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40Static mixers
    • B01F25/42Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
    • B01F25/43Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
    • B01F25/431Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor
    • B01F25/43197Straight mixing tubes with baffles or obstructions that do not cause substantial pressure drop; Baffles therefor characterised by the mounting of the baffles or obstructions
    • B01F25/431971Mounted on the wall
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F35/00Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
    • B01F35/90Heating or cooling systems
    • B01F35/93Heating or cooling systems arranged inside the receptacle
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/08Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being otherwise bent, e.g. in a serpentine or zig-zag
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D21/00Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
    • F28D2021/0019Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for
    • F28D2021/0052Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for mixers

Definitions

  • the present invention is directed to a heat exchanger and mixing device wherein material directed through a conduit, such as, a viscous resin material, is kept in flowable state by a heat transfer medium directed through tubes that extend across the conduit.
  • material directed through a conduit such as, a viscous resin material
  • the present invention overcomes the above-described deficiencies of previous systems by providing a novel heat exchange and mixing system which consists of a plurality of spaced rows of tubes located within a conduit.
  • Each of the rows of tubes consists of a plurality of spaced parallel tubes that extend through and are welded to the exterior surface of the conduit.
  • the adjacent rows of tubes which while extending in a longitudinal direction, are disposed at an angle relative to the adjacent rows and thus the adjacent rows of tubes while providing for good heat transfer also provide for mixing, since the material flowing through the conduit is directed in a tortuous path around the adjacent rows of tubes.
  • the adjacent rows of tubes that extend through the outer walls of the conduit form an angle of approximately 90° with adjacent rows of tubes.
  • the tubes through which a heat transfer medium is directed act to maintain the material being directed through the conduit in a flowable condition.
  • a product such as, styrene
  • the heat transfer medium which is a standard heat transfer oil
  • the temperature of the heat transfer oil be sufficient to initiate and continue polymerization of the monomer flowing through the large size conduit.
  • the tubes are generally made of stainless steel, or some other heat-conductive material whereby the heat transfer medium being directed through the tubes acts to maintain the temperature of the resin material flowing through the conduit in a flowable condition.
  • the tubes are quite thin, which provides for excellent heat transfer between the heat transfer oil and the product flowing through the conduit. It is noted that the adjacent rows of tubes are in close contact with each other, but since they cross each other, the tubes form a tortuous path for the product being directed through the conduit. Accordingly, all volume zones of the flowing product are kept at a close distance relative to the heat transfer surface.
  • this arrangement not only provides for excellent heat transfer in view of the high heating area relative to the flowable material, it also provides for the material to be mixed by virtue of having to flow in a tortuous path through the conduit. In essence, excellent heat transfer is provided by continued close proximity of the hot oil to the material to be polymerized and the efficient transfer of heat to the product throughout the entire mixing device. This design eliminates the buildup of polymer of the walls of the conduit and overcomes the creating of "dead zones" in the reacting system.
  • FIG. 1 is a plan view of the conduit showing the heat transfer tubes extending therethrough;
  • FIG. 2 is a cross-sectional view showing two adjacent rows of tubes extending through the conduit.
  • FIG. 3 is an end view of the conduit and tube assembly shown in FIG. 1.
  • FIG. 1 there is shown a conduit 10 which includes a plurality of rows of tubes 12, 14, which extend therethrough.
  • a conduit 10 which includes a plurality of rows of tubes 12, 14, which extend therethrough.
  • FIG. 2 there are illustrated two adjacent rows of tubes 12, 14, which are located at approximately right angles relative to each other.
  • FIG. 3 which is an end view, illustrates the conduit 10 and alternate rows of tubes 12, 14 that have the same orientation. It can be particularly seen from FIGS. 2 and 3 that flowable material introduced into the conduit at the inlet 16 will initially contact the plurality of adjacent rows of tubes 12, 14, but will not be able to move in a straight line due to the orientation of rows 12, 14. As shown in FIG. 3, the rows 12, 14 abut each other, and thus any material entering the inlet 16 has to make a number of twists and turns before it comes to the outlet 18 of the conduit 10.
  • the tubes 12, 14 extend through the walls 11 of the conduit 10 and are welded to the exterior of the walls at 13 as shown in FIG. 1.
  • the adjacent rows of tubes are located at approximately a right angle relative to each other, but it is clear that this is merely but a preferred embodiment and the degree of angularity is not essential. It is just desirable that the adjacent rows cross each other, so that there is no straight-line path for the material to flow between the inlet 16 and the outlet 18 of the conduit 10. The arrangement of the adjacent rows of tubes clearly acts to enhance the mixing desired.
  • the material flowing into the conduit at approximately 200° C. is styrene and is to be maintained at this temperature.
  • the heat transfer medium is a standard heat transfer oil, which is introduced at 300° C., so that the heat transfer medium retains the product at the desired temperature for flowability, while at the same time creating the desired mixing required.

Abstract

A static mixing device comprising a conduit in which there are located a plurality of rows of spaced parallel tubes extending across the conduit. The tubes are located in rows in which the adjacent rows extend in a longitudinal direction, but are located at right angles to each other. The heat transfer medium flows through the tubes to maintain the product in the conduit within a preselected temperature range. The adjacent rows of tubes abut each other and thus provide a tortuous path for the product in the conduit to effect mixing thereof.

Description

.Iadd.This a continuation of U.S. patent application Ser. No. 07/658,262, filed on Feb. 20, 1991, now abandoned, which is a reissue of 07/188,909 filed May 2, 1988, U.S. Pat. No. 4,865,460. .Iaddend.
BACKGROUND OF THE INVENTION
The present invention is directed to a heat exchanger and mixing device wherein material directed through a conduit, such as, a viscous resin material, is kept in flowable state by a heat transfer medium directed through tubes that extend across the conduit.
It is to be noted that there are a number of heat transfer systems currently available, including those which use tubes extending across a conduit and through which a heat transfer medium is directed for maintaining the material flowing through a conduit within the requisite temperature range. However, these systems are deficient in that they do not provide for the requisite mixing and are not as efficient a heat transfer system as the instant invention. Patents directed to this sort of general configuration are as follows: Oakeley 33,849; Fox 551,489; Holland 609,935; Holt et al. 798,183; Harter 1,636,958; Wells 2,018,163; Behlau 4,235,286; Pranaitis 4,363,353; and Muller et al. 4,314,606. It is acknowledged that these prior art references do provide for heat transfer and in some cases even enhance the mixing of a viscous material. However, unsatisfactory heat exchange between the flowable material and the heat exchange medium is achieved and the desired mixing is not obtained thus requiring a more efficient system such as the type set forth in the present invention.
SUMMARY OF THE INVENTION
The present invention overcomes the above-described deficiencies of previous systems by providing a novel heat exchange and mixing system which consists of a plurality of spaced rows of tubes located within a conduit. Each of the rows of tubes consists of a plurality of spaced parallel tubes that extend through and are welded to the exterior surface of the conduit. The adjacent rows of tubes, which while extending in a longitudinal direction, are disposed at an angle relative to the adjacent rows and thus the adjacent rows of tubes while providing for good heat transfer also provide for mixing, since the material flowing through the conduit is directed in a tortuous path around the adjacent rows of tubes.
In the preferred embodiment, the adjacent rows of tubes that extend through the outer walls of the conduit, form an angle of approximately 90° with adjacent rows of tubes. Thus, you have a situation where there are adjacent rows of tubes that criss-cross each other. With this arrangement, the tubes through which a heat transfer medium is directed act to maintain the material being directed through the conduit in a flowable condition.
In a typical situation, a product, such as, styrene, entering the conduit is introduced at a temperature of approximately 200° C. and the heat transfer medium which is a standard heat transfer oil is introduced at a temperature of approximately 300° C. The important thing is that the temperature of the heat transfer oil be sufficient to initiate and continue polymerization of the monomer flowing through the large size conduit. With this arrangement, the project flowing through the conduit is maintained at the requisite viscosity. While in the present situation it is being used for the polymerization of styrene, it could be used for other materials. The tubes are generally made of stainless steel, or some other heat-conductive material whereby the heat transfer medium being directed through the tubes acts to maintain the temperature of the resin material flowing through the conduit in a flowable condition. The tubes are quite thin, which provides for excellent heat transfer between the heat transfer oil and the product flowing through the conduit. It is noted that the adjacent rows of tubes are in close contact with each other, but since they cross each other, the tubes form a tortuous path for the product being directed through the conduit. Accordingly, all volume zones of the flowing product are kept at a close distance relative to the heat transfer surface. Thus, this arrangement not only provides for excellent heat transfer in view of the high heating area relative to the flowable material, it also provides for the material to be mixed by virtue of having to flow in a tortuous path through the conduit. In essence, excellent heat transfer is provided by continued close proximity of the hot oil to the material to be polymerized and the efficient transfer of heat to the product throughout the entire mixing device. This design eliminates the buildup of polymer of the walls of the conduit and overcomes the creating of "dead zones" in the reacting system.
Numerous other features and advantages of the present invention will become readily apparent from the foregoing detailed description of the invention, from the claims, and from the accompanying drawings, in which:
FIG. 1 is a plan view of the conduit showing the heat transfer tubes extending therethrough;
FIG. 2 is a cross-sectional view showing two adjacent rows of tubes extending through the conduit; and
FIG. 3 is an end view of the conduit and tube assembly shown in FIG. 1.
Referring now to FIG. 1, there is shown a conduit 10 which includes a plurality of rows of tubes 12, 14, which extend therethrough. Referring more specifically to FIG. 2, there are illustrated two adjacent rows of tubes 12, 14, which are located at approximately right angles relative to each other.
FIG. 3, which is an end view, illustrates the conduit 10 and alternate rows of tubes 12, 14 that have the same orientation. It can be particularly seen from FIGS. 2 and 3 that flowable material introduced into the conduit at the inlet 16 will initially contact the plurality of adjacent rows of tubes 12, 14, but will not be able to move in a straight line due to the orientation of rows 12, 14. As shown in FIG. 3, the rows 12, 14 abut each other, and thus any material entering the inlet 16 has to make a number of twists and turns before it comes to the outlet 18 of the conduit 10.
The tubes 12, 14 extend through the walls 11 of the conduit 10 and are welded to the exterior of the walls at 13 as shown in FIG. 1.
With respect to FIG. 2, it is shown that the adjacent rows of tubes are located at approximately a right angle relative to each other, but it is clear that this is merely but a preferred embodiment and the degree of angularity is not essential. It is just desirable that the adjacent rows cross each other, so that there is no straight-line path for the material to flow between the inlet 16 and the outlet 18 of the conduit 10. The arrangement of the adjacent rows of tubes clearly acts to enhance the mixing desired.
Thus, it can be seen that with the aforementioned tube and conduit orientation, the maximum surface area for a given length and diameter of conduits and tubes is obtained to facilitate a highly efficient transfer of heat from the tubes to the material flowing in the conduit 10.
In an illustrative example, the material flowing into the conduit at approximately 200° C. is styrene and is to be maintained at this temperature. To accomplish this, the heat transfer medium is a standard heat transfer oil, which is introduced at 300° C., so that the heat transfer medium retains the product at the desired temperature for flowability, while at the same time creating the desired mixing required.
It is intended to cover by the following claims all modifications and embodiments which come within the true spirit and scope of the invention.

Claims (6)

What is claimed is:
1. A static mixing device comprising a tubular conduit .Iadd.consisting of a tubular wall defining a hollow tubular cross section .Iaddend.through which a viscous product to be maintained within a given temperature range is fed under substantial pressure, a plurality of rows of tubes extending across and filling a major portion of the cross section of said conduit through which a heat transfer medium flows to provide a greater interface between the heat transfer medium and viscous product to maintain said product within the preselected temperature range to help retain its homogeneity, .Iadd.each tube extending through the tubular wall of the conduit at an individual heat transfer medium entrance point for that tube and an individual heat transfer medium exit point for that tube, each tube being substantially linear between its entrance point and exit point, .Iaddend.each of said rows of tubes extending in a longitudinal direction relative to said conduit, the tubes in each of the rows abutting an adjacent row and extending at an angle relative to adjacent rows so that the product flowing through said conduit under high pressure is directed in a tortuous path around said tubes to effect uniform mixing of the product and prevent accumulation of the product on the tubes while the product is being maintained within the prescribed temperature range by the application of uniform heat to the viscous product to provide a more uniformly reacted viscous product flowing through the conduit.
2. A static mixing device as set forth in claim 1 in which the alternate rows of tubes are parallel to each other.
3. A static mixing device as set forth in claim 2 in which the immediately adjacent groups of tubes are disposed at right angles to each other.
4. A static mixing device as set forth in claim 1 in which the tubes extending through the conduit are welded to the outer surface of the conduit.
5. A static mixing device as set forth in claim 3 in which there are at least four groups of tubes.
6. A static mixing device as set forth in claim 1 in which said conduit has a relative small diameter whereby the flow of heat transfer medium flowing through the tubes occurs during a relatively short time span so that only a small variation of the temperature of the transfer medium takes place as it flows through the conduit.
US07/882,325 1988-05-02 1992-05-13 Static mixing device Expired - Lifetime USRE34255E (en)

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US07/188,909 US4865460A (en) 1988-05-02 1988-05-02 Static mixing device
US65826291A 1991-02-20 1991-02-20
US07/882,325 USRE34255E (en) 1988-05-02 1992-05-13 Static mixing device

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US65826291A Continuation 1988-05-02 1991-02-20

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5480589A (en) * 1994-09-27 1996-01-02 Nordson Corporation Method and apparatus for producing closed cell foam
US6203188B1 (en) * 1997-01-29 2001-03-20 Sulzer Chemtech Ag Module forming part of a static mixer arrangement for a plastically flowable material to be mixed having a critical dwell time
US6217208B1 (en) * 1998-06-23 2001-04-17 Bayer Aktiengesellschaft Heatable static mixing device with undulating or zigzag bars
US6334985B1 (en) * 1998-08-18 2002-01-01 Uop Llc Static mixing reactor for uniform reactant temperatures and concentrations
US6511635B2 (en) * 1998-05-25 2003-01-28 Total Raffinage Distribution S.A. Fluid state catalytic cracking reactor having solid fastened packing element for homogeneously distributing particle flow
US6595679B2 (en) * 2000-02-08 2003-07-22 Bayer Aktiengesellschaft Static mixer with at least three interleaved grids
US20050094482A1 (en) * 2003-10-31 2005-05-05 Nordson Corporation Method and apparatus for producing closed cell foam
US20050118343A1 (en) * 1998-12-29 2005-06-02 Pirelli Cavi E Sistemi S.P.A. Apparatus for introducing in continuous a substance in liquid phase into plastics granules
US20070096347A1 (en) * 2005-10-28 2007-05-03 Remi Bessettes Fixturing structure for a fluid exchange column
US20100202248A1 (en) * 2007-06-22 2010-08-12 Sebastian Hirschberg Static mixing element
US9957030B2 (en) 2013-03-14 2018-05-01 Duramax Marine, Llc Turbulence enhancer for keel cooler

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE144700C (en) * 1901-05-29 1903-10-09
US3483920A (en) * 1967-10-13 1969-12-16 Thermal Transfer Corp Heat exchangers
FR2134377A1 (en) * 1971-04-29 1972-12-08 Sulzer Ag
US4049241A (en) * 1975-01-21 1977-09-20 Reica Kogyo Kabushiki Kaisha Motionless mixing device
FR2374075A1 (en) * 1976-12-16 1978-07-13 Creal Tubular static mixer and heat exchanger - comprising shell with baffles formed by diametral rounded section bars, placed one after another, crossing one another
US4275177A (en) * 1978-09-12 1981-06-23 Hoechst Aktiengesellschaft Process for continuous mass polymerization of alkenyl-aromatic compounds
US4314606A (en) * 1978-09-12 1982-02-09 Hoechst Aktiengesellschaft Apparatus for a treatment of flowing media which causes heat exchange and mixing
WO1982002004A1 (en) * 1980-12-08 1982-06-24 Tribos Inc Armorflite Thermally controlled mixer and apparatus and methods of operating same
DE3212727A1 (en) * 1982-03-09 1983-09-22 Unipektin AG, 8034 Zürich HEAT EXCHANGER
EP0123653A1 (en) * 1983-04-22 1984-10-31 Kurier Holding AG Static heat exchanger with high efficiency in particular suitable for the cooling of viscous fluids
US4685514A (en) * 1985-12-23 1987-08-11 Aluminum Company Of America Planar heat exchange insert and method
US4692030A (en) * 1984-03-05 1987-09-08 Sulzer Brothers Limited Static mixing device for viscous melts
US4744928A (en) * 1981-07-30 1988-05-17 Sulzer Brothers Limited Regular packing for countercurrent mass and direct heat transfer columns
US4758098A (en) * 1985-12-11 1988-07-19 Sulzer Brothers Limited Static mixing device for fluids containing or consisting of solid particles

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE144700C (en) * 1901-05-29 1903-10-09
US3483920A (en) * 1967-10-13 1969-12-16 Thermal Transfer Corp Heat exchangers
FR2134377A1 (en) * 1971-04-29 1972-12-08 Sulzer Ag
US4049241A (en) * 1975-01-21 1977-09-20 Reica Kogyo Kabushiki Kaisha Motionless mixing device
FR2374075A1 (en) * 1976-12-16 1978-07-13 Creal Tubular static mixer and heat exchanger - comprising shell with baffles formed by diametral rounded section bars, placed one after another, crossing one another
US4314606A (en) * 1978-09-12 1982-02-09 Hoechst Aktiengesellschaft Apparatus for a treatment of flowing media which causes heat exchange and mixing
US4275177A (en) * 1978-09-12 1981-06-23 Hoechst Aktiengesellschaft Process for continuous mass polymerization of alkenyl-aromatic compounds
WO1982002004A1 (en) * 1980-12-08 1982-06-24 Tribos Inc Armorflite Thermally controlled mixer and apparatus and methods of operating same
US4744928A (en) * 1981-07-30 1988-05-17 Sulzer Brothers Limited Regular packing for countercurrent mass and direct heat transfer columns
DE3212727A1 (en) * 1982-03-09 1983-09-22 Unipektin AG, 8034 Zürich HEAT EXCHANGER
EP0123653A1 (en) * 1983-04-22 1984-10-31 Kurier Holding AG Static heat exchanger with high efficiency in particular suitable for the cooling of viscous fluids
US4692030A (en) * 1984-03-05 1987-09-08 Sulzer Brothers Limited Static mixing device for viscous melts
US4758098A (en) * 1985-12-11 1988-07-19 Sulzer Brothers Limited Static mixing device for fluids containing or consisting of solid particles
US4685514A (en) * 1985-12-23 1987-08-11 Aluminum Company Of America Planar heat exchange insert and method

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5480589A (en) * 1994-09-27 1996-01-02 Nordson Corporation Method and apparatus for producing closed cell foam
US6203188B1 (en) * 1997-01-29 2001-03-20 Sulzer Chemtech Ag Module forming part of a static mixer arrangement for a plastically flowable material to be mixed having a critical dwell time
US6511635B2 (en) * 1998-05-25 2003-01-28 Total Raffinage Distribution S.A. Fluid state catalytic cracking reactor having solid fastened packing element for homogeneously distributing particle flow
US6217208B1 (en) * 1998-06-23 2001-04-17 Bayer Aktiengesellschaft Heatable static mixing device with undulating or zigzag bars
US6334985B1 (en) * 1998-08-18 2002-01-01 Uop Llc Static mixing reactor for uniform reactant temperatures and concentrations
US7077906B2 (en) * 1998-12-29 2006-07-18 Pirelli Cavi E Sistemi S.P.A. Apparatus for continuously introducing a substance in liquid phase into plastics granules
US20050118343A1 (en) * 1998-12-29 2005-06-02 Pirelli Cavi E Sistemi S.P.A. Apparatus for introducing in continuous a substance in liquid phase into plastics granules
US6595679B2 (en) * 2000-02-08 2003-07-22 Bayer Aktiengesellschaft Static mixer with at least three interleaved grids
US20050094482A1 (en) * 2003-10-31 2005-05-05 Nordson Corporation Method and apparatus for producing closed cell foam
US20070096347A1 (en) * 2005-10-28 2007-05-03 Remi Bessettes Fixturing structure for a fluid exchange column
US7748688B2 (en) * 2005-10-28 2010-07-06 Snecma Propulsion Solide Fixturing structure for a fluid exchange column
US20100202248A1 (en) * 2007-06-22 2010-08-12 Sebastian Hirschberg Static mixing element
US8491180B2 (en) * 2007-06-22 2013-07-23 Sulzer Chemtech Ag Static mixing element
US9957030B2 (en) 2013-03-14 2018-05-01 Duramax Marine, Llc Turbulence enhancer for keel cooler
US10179637B2 (en) 2013-03-14 2019-01-15 Duramax Marine, Llc Turbulence enhancer for keel cooler

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