|Número de publicación||USRE39218 E1|
|Tipo de publicación||Concesión|
|Número de solicitud||US 09/987,885|
|Fecha de publicación||1 Ago 2006|
|Fecha de presentación||16 Nov 2001|
|Fecha de prioridad||30 Sep 1994|
|Número de publicación||09987885, 987885, US RE39218 E1, US RE39218E1, US-E1-RE39218, USRE39218 E1, USRE39218E1|
|Inventores||Myriam Mellul, Paul Thau, Paul Fehn, Carlos Pinzon|
|Exportar cita||BiBTeX, EndNote, RefMan|
|Citas de patentes (105), Otras citas (57), Citada por (3), Clasificaciones (39), Eventos legales (5)|
|Enlaces externos: USPTO, Cesión de USPTO, Espacenet|
This is a continuation of application Ser. No. 08/882,298, filed Jun. 25, 1997 now U.S. Pat. No. 5,849,316, which is a continuation of application Ser. No. 08/538,046, filed Oct. 2, 1995, now abandoned.
The invention is directed to anhydrous and water-resistant make-up compositions comprising, inter alia, at least one silicone gum.
Water-resistant compositions in water-in-oil or water-in-silicone emulsion form are known in the prior art. The use of such emulsions relies on the fact that after spreading, the water evaporates and the oil or the silicone remains in contact with the skin, giving a water-resistant make-up. However, the application of such compositions has the drawback of leaving the skin with an oily appearance and of giving a greasy feel. The result obtained after application is not really natural, and the make-up shines or becomes shiny.
Another form of water-resistant cosmetic compositions is a composition in which fillers, including pigments, are introduced into a volatile or non-volatile silicone oil. The major drawback of this type of composition lies in the stretching effect on the skin, and in the unpleasant, dry sensation which appears after application. Furthermore, the effect sought in the use of such compositions containing pigments, namely a coloration of the skin, is often not achieved. The very nature of the composition is such that the distribution of the pigments in the composition after spreading is not homogeneous; the pigments spread more or less uniformly and tend to agglomerate in the pores and the folds in the skin. This effect runs counter to the search for a coloration close to that obtained naturally.
In all cases, the compositions obtained have faults both with regard to the stability and with regard to the homogeneity of the dispersion of the pigments. Solutions to these problems have been proposed, such as, for example, the use of water-soluble dyes or of dihydroxyacetone (DHA). In the case of water-soluble dyes, the make-ups obtained are not water-resistant and are not perfectly homogeneous.
Products using DHA are difficult to formulate, on account of the degradation and the incompatibility of DHA with many components usually used in compositions of this type. In addition, a major drawback of DHA, in its use in cosmetic compositions, lies in the development of unpleasant odors during ageing.
An object of the present invention is to provide solutions to the various problems encountered in the applications of the prior art and to propose a cosmetic composition possessing good water resistance and at the same time possessing good cosmetic properties.
The Inventors have been able to show, surprisingly and unexpectedly, that it is possible to obtain anhydrous, water-resistant make-up compositions which are highly homogeneous in particular with regard to spreading, by mixing together pigments and at least a large proportion of silicone gum and a silicone oil.
More particularly, a subject of the present invention is an anhydrous, water-resistant cosmetic composition preferably comprising from 2 to 50% of at least one silicone gum, from 10 to 90% of at least one silicone oil, from 0.5 to 15% of at least one pigment and from 0 to 30% of at least one filler.
The compositions according to the invention have the advantage of being stable over time. They are water-resistant since they are anhydrous, and do not contain any water-soluble dyes or solvent. They also have good staying power and do not cause any pulling effect on the skin.
It has furthermore been observed, surprisingly, that the pigments present in the compositions according to the invention were dispersed therein in an unexpectedly very homogeneous manner. This thus has the additional advantage of giving a very uniform and very homogeneous make-up of the skin.
In the following text, the percentages will always be given by weight of active material relative to the total weight of the composition.
In the compositions according to the invention, the silicone gum is preferably present in a proportion ranging from 2% to 50%, more preferably ranging from 4 to 15% and still more preferably ranging from 6% to 9%.
The silicone gum preferably has a molecular weight not greater than 1,500,000. More preferably, the silicone gum has a molecular weight ranging from 200,000 to 1,000,000.
The silicon gum preferably corresponds to the formula:
In general, n and p may have values preferably ranging from 0 to 5000, and more preferably ranging from 0 to 3000.
As silicone gum which may be used according to (the invention, there may preferably be mentioned those for which:
The composition according to the invention preferably also comprises at least one silicone oil, in a proportion preferably ranging from 10 to 90%.
A volatile or non-volatile silicone oil may be used.
There may be mentioned, for example:
According to a preferred embodiment of the invention, the silicone oil and gum are used in the form of a homogeneous premix consisting of the silicone gum solubilized in the silicone oil.
The composition according to the invention preferably also comprises pigments, in a proportion ranging from 0.5 to 15%, and more preferably ranging from 2 to 8%.
The pigments may be white or coloured and inorganic or organic.
The pigments used in the composition according to the invention may or may not be coated.
U.S. Pat. No. 4,578,566, the disclosure of which is incorporated herein by reference, describes a pretreatment of pigments in order to make them hydrophobic, as a solution in order to introduce large proportions thereof into silicone-based compositions, and in order to ensure better dispersion thereof in the composition. This pretreatment is carried out by coating the pigments with a polysiloxane. Obviously, this pretreatment increases not only the preparation time of the compositions but also their cost.
As has been mentioned above, a particular advantage of the invention lies in the fact that the compositions according to the invention allow a homogeneous and stable dispersion to be obtained, even when pigments which have not been precoated are used.
Among the pigments which may preferably be used, there may be mentioned, without any limiting effect, titanium dioxide (TiO2), zinc oxide (ZnO), zirconium dioxide (ZrO2), black, yellow, red and brown iron oxides, cerium dioxide (CeO2) or alternatively the organic pigments known as barium, strontium, calcium and aluminium lakes.
The composition according to the invention preferably contains 0 to 30% of fillers. These fillers may preferably be inorganic or synthetic and lamellar or non-lamellar.
Talc, mica, silica, kaolin, powders of nylon and of polyethylene, Telfon, starch, titanium mica, natural mother of pearl, boron nitride and hollow microspheres such as Expancel from Nobel Industrie may be mentioned.
The composition according to the invention may also comprise constituents usually used in cosmetic compositions of this type. These constituents are preferably chosen as a function of the desired cosmetic effect for the final composition, such as the covering power, the transparency, the matt quality and/or the satiny appearance.
There may be mentioned, without any limiting effects:
The processes for the manufacture of the compositions according to the invention do not differ in any way from the processes conventionally used in cosmetics and with which those skilled in the art are fully familiar.
The compositions according to the invention may be in the form of a product for making up the skin, such as a foundation, a blusher, an eyeshadow or a lipstick, or even in the form of a hair product such as a styling make-up gel.
Examples of compositions according to the invention will now be given by way of example, without any limiting nature being implied.
Make-up gels having the following compositions (in g) were prepared:
at a concentration
of 12-14% in
(Q2-1401 from Dow)
TiO2 + iron oxides*
bentone gel IMP (NL
bentone gel VS-5 PC
A) and B) were mixed together with a spatula and were passed 3 times through a cylinder mill. C), D) and E) were then added with moderate stirring.
Three formulae were obtained, which contained a large proportion of silicone-containing compounds and which made it possible to obtain, after spreading on the skin, a coloured and water-resistant make-up.
Although the pigments used were not precoated, the pigments were fully dispersed in the composition and the make-up obtained was homogeneous.
Self-tanning compositions having the following compositions (in g) were prepared:
at a concentration
of 12-14% in
TiO2 + iron oxides*
powder in a PDMS
(KSG 16 from Shin
bentone gel VS-5 PC
Thickened gelled creams were obtained, which were easy and pleasant to apply, and which gave a homogeneous and uniform coloration of natural appearance to the skin.
Water-resistant silicone-containing self-tanning compositions having the following compositions (in g) were prepared:
Silcone oil (AK 500,000
Polydimethylsiloxane at a
concentration of 12-14% is
cyclomethicone (Q2-1401 from
Polyphenylsiloxane at a
concentration of 15% in
(Silbione 71634 from Rhone-
TiO2 + iron oxides*
Crosslinked silicone powder
(KSG 16 from Shin Etsu)
Gelling agent (Bentone gel
VS38 from Rhéox)
beads (Tospearl 120 from
Coloured and water-resistant self-tanning compositions were obtained in the form of gels.
A lipstick having the following composition was prepared:
Polydimethylsiloxane at a concentration of
12-14% in cyclomethicone (Q2-1401)
Crosslinked silicone powder in PDMS (KSG 16
from Shin Etsu)
Silicone-coated titanium oxide
Silicone-coated iron oxides
D&C red No. 7
A fluid gelled cream of red-pink colour with an iridescent effect was obtained, which was smooth upon application and had good staying power.
A screening tanning fluid having the following composition was prepared:
Polydimethylsiloxane at a concentration
of 12-14% in cyclomethicone (Q2-1401)
UV screening agents Parsol MCX from BASF
FINSOLV TN (C12-C15 alkyl benzoate) from Finetax
Crosslinked silicone powder in PDMS (KSG 16
from Shin Etsu)
TiO2 + iron oxides (non-coated)
A shiny, smooth brown-coloured tanning fluid was obtained, which was easy to apply and gave a homogeneous and uniform coloration of natural appearance to the skin.
|Patente citada||Fecha de presentación||Fecha de publicación||Solicitante||Título|
|US2230063||23 Ene 1939||28 Ene 1941||Martin Gordon M||Liquid lip rouge preparation|
|US2548970||22 Oct 1948||17 Abr 1951||Grigsby Grate Lorene||Liquid lip-rouge composition|
|US2566722||26 Jun 1946||4 Sep 1951||Friedberg Leonard||Cosmetic stick and the like|
|US2578210||5 Dic 1949||11 Dic 1951||Silva Leola||Liquid face rouge|
|US2676182||13 Sep 1950||20 Abr 1954||Dow Corning||Copolymeric siloxanes and methods of preparing them|
|US2678878||6 Abr 1950||18 May 1954||Goodrich Co B F||Plant growth regulants containing aryl and haloaryl esters of aryl and haloaryl sulfonic and thiosulfonic acids|
|US2678893||21 Feb 1951||18 May 1954||Dow Corning||Method for rendering leather water repellent|
|US2681878||4 Sep 1951||22 Jun 1954||Dow Corning||Insect repellent compositions|
|US3541205||11 Abr 1966||17 Nov 1970||Dow Corning||Wash resistant lotion containing organosilicon resins|
|US3600186||23 Abr 1968||17 Ago 1971||Procter & Gamble||Low calorie fat-containing food compositions|
|US3642635||5 Mar 1970||15 Feb 1972||Exxon Research Engineering Co||Synthetic petrolatum compositions|
|US3646214||20 Ago 1968||29 Feb 1972||Laglenne Renee||Method of protecting eye makeup|
|US3836647||7 May 1973||17 Sep 1974||Dow Corning||Wash-resistant skin preparation|
|US3857805||25 Mar 1974||31 Dic 1974||Cities Service Oil Co||Hydrocarbon wax composition|
|US3927199||13 Ago 1973||16 Dic 1975||Nat Starch Chem Corp||Hair fixing compositions containing N-alkyl acrylamide or methacrylamide interpolymer|
|US4005195||12 Feb 1976||25 Ene 1977||The Procter & Gamble Company||Compositions for treating hypercholesterolemia|
|US4005196||12 Feb 1976||25 Ene 1977||The Procter & Gamble Company||Vitaminized compositions for treating hypercholesterolemia|
|US4119712||25 Jul 1977||10 Oct 1978||Revlon, Inc.||Makeup foundations|
|US4192861||5 May 1978||11 Mar 1980||National Starch And Chemical Corporation||Hydrocarbon propelled aerosol hair spray compositions|
|US4283384||23 Ene 1979||11 Ago 1981||L'oreal||Cosmetic compositions containing polymers produced in the presence of cerium ions|
|US4315910||5 Sep 1978||16 Feb 1982||National Starch And Chemical Corporation||Aerosol hair spray compositions|
|US4409203||13 May 1982||11 Oct 1983||Del Laboratories, Inc.||Non-nitrocellulose non-formaldehyde or formaldehyde resin nail polish employing an acrylate resin as the film former|
|US4421769||29 Sep 1981||20 Dic 1983||The Procter & Gamble Company||Skin conditioning composition|
|US4421881||19 Abr 1982||20 Dic 1983||Sol Benkendorf||Nitrocellulose lacquer composition containing gelatin and acrylic copolymers|
|US4425364||10 Oct 1979||10 Ene 1984||Societe Anonyme Dite: L'oreal||Compositions containing an organo-silicon compound|
|US4431673||28 Sep 1981||14 Feb 1984||Revlon, Inc.||Cosmetic compositions|
|US4486405||19 Abr 1983||4 Dic 1984||William H. Rorer, Inc.||Pigmented cosmetic vehicle containing a mixture of alkoxylated surfactants|
|US4515784||16 Nov 1983||7 May 1985||Richardson-Vicks Inc.||Reducing sebum spreading|
|US4534961||19 Oct 1981||13 Ago 1985||Liff Lawrence J||Wax base makeup composition|
|US4574082||29 Jul 1983||4 Mar 1986||Revlon, Inc.||One-phase silicone-based cosmetic products containing wax|
|US4578266||29 Jul 1983||25 Mar 1986||Revlon, Inc.||Silicone-based cosmetic products containing pigment|
|US4601757||7 Mar 1985||22 Jul 1986||Desoto, Inc.||Nonvolatile plasticizers and nail polish containing the same|
|US4649045||3 Abr 1986||10 Mar 1987||Desoto, Inc.||Coating compositions and nail polish compositions including the same|
|US4673570||20 Mar 1985||16 Jun 1987||Carter-Wallace, Inc.||Gelled antiperspirant compositions|
|US4678663||6 Feb 1984||7 Jul 1987||Nuetrogena Corporation||Hydroquinone composition having enhanced bio-availability and percutaneous adsorption|
|US4699780||29 May 1985||13 Oct 1987||Estee Lauder Inc.||Cosmetic composition|
|US4725495||30 Oct 1986||16 Feb 1988||Minnesota Mining And Manufacturing Company||Lipstick sampling device|
|US4725658||3 Nov 1986||16 Feb 1988||General Electric Company||Novel silicone-ester waxes|
|US4747419||17 Jun 1986||31 May 1988||Chesebrough-Pond's, Inc.||Nail polish compositions and means for applying same|
|US4777041||7 Ago 1986||11 Oct 1988||Charles Of The Ritz Group Ltd.||Wrinkle treatment formulation|
|US4792444||6 Jun 1986||20 Dic 1988||Kao Corporation||Cosmetic comprising fluoroalkyl (meth)acrylate copolymers|
|US4795631||26 Mar 1986||3 Ene 1989||Chesebrough-Pond's, Inc.||Water based lip color comprising an alkali soluble film-forming agent|
|US4797272||15 Nov 1985||10 Ene 1989||Eli Lilly And Company||Water-in-oil microemulsions for cosmetic uses|
|US4800076||13 Mar 1987||24 Ene 1989||Johnson & Johnson Consumer Products, Inc.||Skin care compositions|
|US4801447||13 Dic 1985||31 Ene 1989||Union Carbide Corporation||Water-in-volatile silicone emulsifier concentrates, water-in-volatile silicone emulsions that are useful in personal-care formulations and methods of making same|
|US4803067||26 Mar 1986||7 Feb 1989||Ausimont S.P.A.||Compositions for cosmetics and dermatology comprising perfluoropolyethers|
|US4826828||17 Abr 1986||2 May 1989||Avon Products, Inc.||Composition and method for reducing wrinkles|
|US4837011||11 Oct 1988||6 Jun 1989||Revlon, Inc.||Cosmetic powder employing spherical silica particles|
|US4839163||9 Sep 1986||13 Jun 1989||Laura Lupton Inc.||Facial cosmetic liquid containing crystalline silica and colors|
|US4855129||5 Nov 1987||8 Ago 1989||Bayer Aktiengesellschaft||Skin-protecting or skin-care composition|
|US4873078||22 Abr 1988||10 Oct 1989||Plough, Inc.||High-gloss, high-shine lipstick|
|US4888363||29 Jul 1987||19 Dic 1989||Avon Products, Inc.||Anhydrous cosmetic preparation|
|US4897261||19 May 1987||30 Ene 1990||Shiseido Company Ltd.||Fingernail cosmetic composition|
|US4904698||11 Feb 1988||27 Feb 1990||Ocusoft Inc.||Eyelid cleansing composition|
|US4935228||28 Dic 1987||19 Jun 1990||L'oreal S.A.||Lip gloss|
|US4946302||15 Dic 1989||7 Ago 1990||Mitsubishi Pencil Co., Ltd.||Liquid applicator with resilient brush mounting|
|US4950468||8 Sep 1988||21 Ago 1990||Sunstar Kabushiki Kaisha||Hair treating composition|
|US4954532||30 Ene 1985||4 Sep 1990||Beecham Group P.L.C.||Cosmetic formulaton|
|US4966933||5 Dic 1988||30 Oct 1990||Toray Industries, Inc.||Propylene polymer film|
|US4980167||24 Ene 1990||25 Dic 1990||Dow Corning Toray Silicone Company, Ltd.||Silicone cosmetic composition|
|US4983388||11 Sep 1989||8 Ene 1991||Shin-Etsu Chemical Co., Ltd.||Process of preparing silicone composition, and cosmetic and lustering materials containing silicone composition obtained|
|US4988503||24 Ene 1990||29 Ene 1991||Revlon, Inc.||Oil-in-water emulsions for foundation makeup composition|
|US4992477||4 Abr 1988||12 Feb 1991||Warner-Lambert Company||Skin moisturizing composition and method of preparing same|
|US4994264||15 Dic 1989||19 Feb 1991||Revlon, Inc.||Press molded cosmetic composition with pay off|
|US4996239||16 Sep 1988||26 Feb 1991||Neutrogena Corporation||Water resistant cream conditioner|
|US5002762||8 Sep 1989||26 Mar 1991||The Procter & Gamble Company||Volatile silicons in household and cosmetic products|
|US5011680||15 Jun 1988||30 Abr 1991||Kao Corporation||Solid cosmetic preparation|
|US5013763||30 Nov 1987||7 May 1991||The Andrew Jergens Company||Wash-off-resistant skin preparation|
|US5015469||23 Jul 1990||14 May 1991||Shideido Company Ltd.||Water-in-oil emulsion type cosmetics|
|US5023075||10 Oct 1989||11 Jun 1991||Revlon, Inc.||Microfine cosmetic powder comprising polymers, silicone, and lecithin|
|US5036108||13 Dic 1989||30 Jul 1991||Kao Corporation||Water-in-oil emulsion cosmetic|
|US5045309||27 Dic 1989||3 Sep 1991||Dell Aquila Louis||Quick drying nail polish|
|US5051489||25 Ene 1990||24 Sep 1991||Siltech Inc.||Novel silanol waxes|
|US5053221||20 Nov 1989||1 Oct 1991||Maybe Holding Co.||Novel mascara composition having very small particles|
|US5061481||3 Ene 1990||29 Oct 1991||Kobayashi Kose Co., Ltd.||Cosmetic composition having acryl-silicone graft copolymer|
|US5063057||26 Sep 1990||5 Nov 1991||Elizabeth Arden Co., Division Of Conopco, Inc.||Cosmetic capsules|
|US5073364||19 Jun 1990||17 Dic 1991||Revlon, Inc.||Pressed powder cosmetic product|
|US5073372||30 Nov 1990||17 Dic 1991||Richardson-Vicks, Inc.||Leave-on facial emulsion compositions|
|US5085855||18 Jul 1990||4 Feb 1992||Mary Kay Cosmetics, Inc.||Silicone based cosmetic product|
|US5085856||25 Jul 1990||4 Feb 1992||Elizabeth Arden Co., Division Of Conopco, Inc.||Cosmetic water-in-oil emulsion lipstick comprising a phospholipid and glycerol fatty acid esters emulsifying system|
|US5089256||12 Ene 1989||18 Feb 1992||Wurttembergische Parfumerie-Fabrik Gmbh||Process for preparing solid powder formulations having different colors|
|US5093108||18 Dic 1989||3 Mar 1992||Amalia, Inc.||Quick-drying nail enamel compositions and method for coating a surface|
|US5093111||11 Mar 1991||3 Mar 1992||Kolmar Laboratories Inc.||Lipstick composition comprising cetearyl isononanoate, a sesquistearate and isopropyl hydroxystearate|
|US5104586||23 Mar 1990||14 Abr 1992||Unilever Patent Holdings B.V.||Diesters and their use in waxes|
|US5106609||16 Jul 1990||21 Abr 1992||The Procter & Gamble Company||Vehicle systems for use in cosmetic compositions|
|US5106611||20 Nov 1989||21 Abr 1992||L'oreal||Use of modified diorganopolysiloxanes as antioxidants in cosmetics or in dermatology|
|US5106625||8 Ago 1990||21 Abr 1992||Kao Corporation||Composition for external application consisting essentially of a dextrin fatty acid ester, a glycerol fatty acid ester and an oil|
|US5108736||16 Feb 1988||28 Abr 1992||Schlossman Mitchell L||Method of incorporating cosmetic pigments and bases into products containing oil and water phases|
|US5118496||2 Oct 1990||2 Jun 1992||Morris Herstein||Coated cosmetic materials and method of coating cosmetic materials|
|US5118507||25 Jun 1991||2 Jun 1992||Elizabeth Arden Co., Division Of Conopco, Inc.||Silicone based cosmetic composition|
|US5126126||20 Nov 1990||30 Jun 1992||Dow Corning Corporation||Hair fixatives|
|US5141741||4 Dic 1989||25 Ago 1992||Lion Corporation||Anti-sunburn skin-care preparation|
|US5143722||12 Jun 1991||1 Sep 1992||Revlon, Inc.||Cosmetic makeup compositions comprising water-in-oil emulsions containing pigment|
|US5143723||5 Mar 1990||1 Sep 1992||Estee Lauder, Inc.||Colored cosmetic compositions|
|US5158772||23 Sep 1991||27 Oct 1992||Davis Walter B||Unique bacterial polysaccharide polymer gel in cosmetics, pharmaceuticals and foods|
|US5160738||9 Jul 1991||3 Nov 1992||Chesebrough-Pond's U.S.A. Co., Division Of Conopco Inc.||Cosmetic composition|
|US5183588||4 Abr 1990||2 Feb 1993||Yves Saint Laurent Parfums||Ternary system based on perfluorinated ethers|
|US5183589||30 Mar 1990||2 Feb 1993||Ausimont S.R.L.||Stable emulsions of perfluoropolyethers|
|US5196187||10 May 1991||23 Mar 1993||Chesebrough-Pond's Usa Co., Division Of Conopco, Inc.||Cosmetic composition|
|US5496544 *||5 Mar 1993||5 Mar 1996||L'oreal||Powdered cosmetic composition containing a silicone fatty binder|
|US5849316 *||25 Jun 1997||15 Dic 1998||L'oreal||Anhydrous and water resistant cosmetic compositions|
|EP0133963A2 *||27 Jul 1984||13 Mar 1985||Revlon, Inc.||Silicone-based cosmetic products containing pigment|
|EP0521647A2 *||24 Jun 1992||7 Ene 1993||Unilever Plc||Cosmetic composition|
|EP0548694A1 *||10 Dic 1992||30 Jun 1993||Kao Corporation||Oil-based solid cosmetic composition|
|FR2688134A1 *||Título no disponible|
|1||Abstract: JP 55028906, Feb. 29, 1980.|
|2||Abstract: JP 6107518, Apr. 19, 1994.|
|3||Abstract: JP 62298512, Dec. 12, 1987.|
|4||Abstract: JP 63230618, Sep. 27, 1988.|
|5||Al Disapio and Petrina Fridd, "Silicones: use of substantive properties on skin and hair", International Journal of Cosmetic Science, 10, 1988, pp. 75-89.|
|6||Amphomer-Polymer for Hard Holding Hair Fixative Formulations; National Starch and Chemical Company, Specialty Polymers.|
|7||Arndt Schlosser et al., "Resins: The Other Kind of Silicones", Cosmetics & Toiletries Magazine, vol. 118, No. 8, Aug. 2003.|
|8||*||Derwent Abstract of FR-A-2688134.|
|9||Dow Corning Corporation-Material Safety Data Sheet Jun. 1994.|
|10||English language abstract of JP 07-267820 A from Patent Abstracts of Japan.|
|11||English language abstract of JP 08-26936 A from Patent Abstracts of Japan.|
|12||English language abstract of JP 08-81335 A from Patent Abstracts of Japan.|
|13||English language abstract of JP 59-172495 A from Patent Abstracts of Japan.|
|14||English language abstract of JP 61-65809 A from Patent Abstracts of Japan.|
|15||English language abstract of JP 62-061911 A from Patent Abstracts of Japan.|
|16||English language Derwent Abstract of DE 1 913 569.|
|17||English language Derwent Abstract of EP 0 255 655 A2.|
|18||English language Derwent Abstract of EP 0 268 950 A2.|
|19||English language Derwent Abstract of FR 2 556 940 A.|
|20||English language Derwent Abstract of WO 91/12793 A1.|
|21||English language Derwent Abstract of WO 93/17660 A1.|
|22||English translation of CH 317302.|
|23||English translation of DE 1 012 730.|
|24||English translation of DE 1 018 194.|
|25||English translation of DE 967 031.|
|26||English translation of DE 968 535.|
|27||English translation of FR 1 301 966.|
|28||English translation of JP 01-143816 A.|
|29||English translation of JP 01-168607 A.|
|30||English translation of JP 01-250307 A.|
|31||English translation of JP 01-283209 A.|
|32||English translation of JP 05-32527 A.|
|33||English translation of JP 06-24932 A.|
|34||English translation of JP 07-258030 A.|
|35||English translation of JP 60-255714 A.|
|36||English translation of JP 61-161211 A.|
|37||English translation of JP 62-238212 A.|
|38||English translation of JP 62-298512 A.|
|39||English translation of JP 63-183516 A.|
|40||European Patent Office abstract and family listing of EP 0 255 655 A2.|
|41||European Patent Office abstract and family listing of EP 0 268 950 A2.|
|42||European Patent Office abstract and family listing of WO 91/12793 A1.|
|43||European Patent Office abstract and family listing of WO 93/17660 A1.|
|44||General Electric, GE Silicones, Patent Technology, 7 pp.|
|45||General Electric, GE Silicones, Preliminary Data Sheet, 4 pp.|
|46||Harry's Cosmeticology, pp. 332-333 (Coloured Make-up Preparation), 7<SUP>th </SUP>Ed., Chemical Publishing Co., 1982.|
|47||International Cosmetic Ingredient Dictionary and Handbook, vol. 1, p. 1434.|
|48||Japanese Patent Abstract JP 59122415 Jul. 1984.|
|49||Leo, A.J., "Methods of Calculating Partition Coefficients", Comprehensive Medicinal Chemistry, (Eds., Hansch, Sammens, Taylor and Ransden), vol. 4, pp. 295-319, 1990.|
|50||Mark, J.E., Physical Properties of Polymers Handbook, AIP Press., Amer. Inst. Of Physics, Chap. 16, pp. 227-239.|
|51||McGraw-Hil Book Co., "McGraw-Hill Dictionary of Chemistry", (Sybil P. Parker ed.), 1984, p. 319.|
|52||Origins Sunny Disposition, product labeling, Oct. 1993.|
|53||Skin Care by Dow Corning, Formulary of Product Applications, 1981.|
|54||The Cosmetic, Toiletry and Fragrance Association, "CTFA Ingredient Handbook," (John A. Wenninger 7 G.N. McEwen, Jr. eds.) 1988, p. 213.|
|55||Vaughan, C.D., "Solubility Effects in Product, Package, Penetration and Preservation", Cosmetics & Toiletries, vol. 103, pp. 47-69, 1988.|
|56||Von Nostrand Reinhold Co., "Hawleys Condensed Chemical Dictionary," (Richard J. Lewis, Sr. res. 12<SUP>th </SUP>ed.), 1993, p. 635.|
|57||WP Index 84-210426, Abstract JP 59122415.|
|Patente citante||Fecha de presentación||Fecha de publicación||Solicitante||Título|
|US7790202 *||9 Abr 2007||7 Sep 2010||Martell Helen D||Multi-purpose skin composition|
|US8003120||22 Oct 2008||23 Ago 2011||Elc Management Llc||Powder makeup compositions and methods|
|US20100098765 *||22 Oct 2008||22 Abr 2010||Mercado Clara G||Powder Makeup Compositions And Methods|
|Clasificación de EE.UU.||424/401, 424/62, 514/944, 424/78.05, 424/59, 424/70.1, 514/844|
|Clasificación internacional||A61Q19/04, A61K8/891, A61Q1/02, A61Q17/04, A61K8/58, A61K8/29, A61K8/89, A61K8/19, A61Q1/04, A61Q1/06, A61Q1/12, A61Q5/00|
|Clasificación cooperativa||A61Q19/04, A61K8/585, A61K8/19, A61K2800/43, A61K8/89, A61Q1/02, A61Q1/06, A61K8/29, A61K2800/31, A61K8/891, A61Q17/04|
|Clasificación europea||A61Q1/02, A61Q1/06, A61K8/19, A61K8/58C, A61Q19/04, A61Q17/04, A61K8/891, A61K8/89, A61K8/29|
|19 Feb 2002||AS||Assignment|
Owner name: L OREAL, FRANCE
Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:MELLUL, MYRIAM;THAU, PAUL;FEHN, PAUL;AND OTHERS;REEL/FRAME:012591/0821;SIGNING DATES FROM 20020102 TO 20020111
|3 May 2002||AS||Assignment|
Owner name: L OREAL, FRANCE
Free format text: CORRECTIVE ASSIGNMENT TO CORRECT THE 2ND ASSIGNOR S DOC DATE PREVIOUSLY RECORDED AT REEL 012591 FRAME 0821;ASSIGNORS:MELLUL, MYRIAM;THAU, PAUL;FEHN, PAUL;AND OTHERS;REEL/FRAME:012879/0049;SIGNING DATES FROM 20020107 TO 20020202
|26 Dic 2006||CC||Certificate of correction|
|20 Abr 2007||FPAY||Fee payment|
Year of fee payment: 8
|14 Abr 2011||FPAY||Fee payment|
Year of fee payment: 12