WO1983002066A1 - Protective suit - Google Patents

Protective suit Download PDF

Info

Publication number
WO1983002066A1
WO1983002066A1 PCT/NO1982/000060 NO8200060W WO8302066A1 WO 1983002066 A1 WO1983002066 A1 WO 1983002066A1 NO 8200060 W NO8200060 W NO 8200060W WO 8302066 A1 WO8302066 A1 WO 8302066A1
Authority
WO
WIPO (PCT)
Prior art keywords
protective clothing
drop barrier
stated
barrier
absorbing layer
Prior art date
Application number
PCT/NO1982/000060
Other languages
French (fr)
Inventor
A/S Helly-Hansen
Original Assignee
Nilsen, Tor, S.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nilsen, Tor, S. filed Critical Nilsen, Tor, S.
Publication of WO1983002066A1 publication Critical patent/WO1983002066A1/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/02Physical, chemical or physicochemical properties
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62BDEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
    • A62B17/00Protective clothing affording protection against heat or harmful chemical agents or for use at high altitudes
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D5/00Composition of materials for coverings or clothing affording protection against harmful chemical agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/024Woven fabric
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00Condition, form or state of the layers or laminate
    • B32B2305/10Fibres of continuous length
    • B32B2305/18Fabrics, textiles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/724Permeability to gases, adsorption
    • B32B2307/7242Non-permeable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/726Permeability to liquids, absorption
    • B32B2307/7265Non-permeable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00Clothing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2571/00Protective equipment
    • B32B2571/02Protective equipment defensive, e.g. armour plates, anti-ballistic clothing

Landscapes

  • Health & Medical Sciences (AREA)
  • Emergency Management (AREA)
  • Business, Economics & Management (AREA)
  • General Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Toxicology (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Textile Engineering (AREA)
  • Respiratory Apparatuses And Protective Means (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Laminated Bodies (AREA)

Abstract

A protective suit is constructed of two layers, one of which forming an outer drop barrier consisting of a possible textile carrier laminated with a micro porous watertight film that is open to diffusion, and an inner gas absorbing layer known per se.

Description

PROTECTIVE SUIT
The present invention relates to a protective clothing system which combines high protective ability against skin penetrating means of chemical warfare, good airtightness and watertightness with low physiological strain on the user.
The previously known air permeable protective suits have a composition resulting from a compromise between different requirements, as:
High protective capability against skin penetrating means of chemical warfare or other skin irritants, and the requirement that the soldier should be able to keep up physical activities during a certain period of time.
such a suit is described in NO-PS 128 694 which corresponds to US-PS 3 818 507.
Chemical protection is essentially achieved by use of two barriers, a drop barrier and a gas barrier. The outer layer of the suit, its drop barrier, will intercept drops and pre¬ vent liquid from penetrating further into the clothing system. The vapors from drops deposited on the outer layer will diffuse into the suit and are intercepted by the gas barrier, an absorbent, e.g. bonded activated carbon. The two barriers are separated by an air layer.
Since it is also desirable to make the suit highly permeable to water vapor in order to reduce the physiological strain on the soldier, the fabric of the outer layer cannot be made so dense that it completely prevents large drops striking the outer layer with high velocity from penetrating the drop barrier. In such cases the liquid will rapidly saturate the absorption layer beneath eliminating the protective effect of the suit.
Said suits only offer sufficient protection when used outside the normal field service uniform, and they must be replaced by new ones a certain time after contamination. The present invention provides a clothing system which to a high degree- solves several of the problems of the known air permeable protective suits.
Said suit comprises a drop barrier outside a gas barrier, separated by an air layer.
Said drop barrier consists of a micro porous membrane that is laminated with a carrier fabric, the carrier fabric form¬ ing the outside. The carrier fabric imparts wear resistance and mechanical stability to the outer layer and may be treated so as to provide the suit with other qualities, as colour, flame baffling, etc. Said micro porous membrane has pores of such a magnitude that they let through water vapor., but not water, so as to provide good water vapor transmission and enable the soldier to ventilate excessive heat. At the same time said membrane will completely prevent liquid from penetrating the outer layer - even large drops having high collision energy and drops that could otherwise be forced through the outer layer. Due to the fact that said micro porous membrane keeps the drops back in the outer layer, the outer fabric may be subjected to a treatment that makes drops spread over a larger surface area. Evaporation to the atmos¬ phere is, thus, enhanced, the load on the absorption layer :.*= inside is reduced and the hazard of contact, which the contaminated surface constitutes, is considerably reduced.
By a micro porous membrane is meant a film, e.g. a polytetra- fluoroethylene, polyethylene, polyurethane film having throug pores of a magnitude of 0.1-3.0 μ, a pore number of 0.5 x 106 g
- 1.5 x 10 /cm, water vapor permeability: approx. 3000
2 g/m /24h, and showing no indications of penetration measured according to ISO/DIS 6530
If protection against heat radiation is desired, this may be achieved by the use of a micro porous membrane having a high- melting point and a white colour for good heat reflection. Underneath the outer layer/micro porous membrane the normal gas barrier is provided. The drop barrier and the gas barrie may be two separate pieces of clothing that can also be re¬ placed separately. The system does not require use of the regular field service uniform to provide the necessary protection.
The advantages of the present invention as compared with the previously known systems are that the micro porous membrane imparts considerable water vapor transmission to the suit and, thus, low physiological strain on the user.
The resulting suit is airtight and watertight.
It provides very high protection against means of chemical warfare due to the fact that drops cannot penetrate to the absorbing layer beneath, even under pressure. The absorbing layer is only subjected to vapors from liquid deposits on th outer layer.
The micro porous membrane permits the outer layer to be pro¬ vided with an impregnation that will spread drops of means of chemical warfare on the outside of the suit. In this man¬ ner evaporation to the atmosphere is enhanced, which reduces the load totally as well as- locally on the gas barrier. The lifetime of the absorbing layer is increased.
Spreading of drops on the outer layer results in consider¬ able reduction of the contact hazard which the contaminated surface of the suit would otherwise constitute. This has considerable operative advantages.
The outer fabric and the absorbing layer being impregnated to a flame baffling state and the micro porous membrane at the same time having a high melting point and excellent heat reflection due to its white colour, protection against pyrotechnical weapons and heat radiation' has been achieved as well. The suit does not require the normal field service uniform to be worn underneath to impart the necessary protection.
The principle of the micro porous membrane for a drop barrie over an absorption layer may also be utilized for protection of hands and feet against chemical warfare and at the same time to transport perspiration.
The invention is not exclusively intended for military use; it may also be useful for protective suits e. g. in indust¬ rial and similar environments.

Claims

CLAIMS:
1. A protective clothing against skin penetrating means of chemical warfare and skin irritant industrial gases, c h a r a c t e r i z e d i n that it comprises an outer drop barrier constructed with a carrier which may be a textile fabric having a micro porous watertight film open to diffusion laminated onto it, and an absorbing layer, e. g. a carrier known per se and coated with an absorbant, e.g. activated carbon, or a foamed material impregnated with a similar absorbing material, which absorbs the vapors of toxic substances that penetrate the drop barrier, and where the drop barrier has its textile fabric outside to offer'-. good protection against mechanical stress, which fabric may if desired be impregnated or dyed in order to impart e.g. a flame baffling or camouflage effect to the outside.
2. A protective clothing as stated in claim 1, c h a r a c t e r i z e d i n that there is an air layer between the drop barrier and the inner gas absorbing layer.
3. A protective clothing as stated in claim 1, c h a r a c t e r i z e d i n that the outside drop barrier and the gas absorbing layer are constructed into one layer.
4. A protective clothing as stated in claim 1, c h a r a c t e r i z e d i n that the drop barrier and the gas absorbing layer form two separate units.
5. A protective clothing as stated in claim 1, c h a r a c t e r i z e d i n that the micro porous film on the drop barrier is white to protect against heat radiation.
PCT/NO1982/000060 1981-12-11 1982-12-13 Protective suit WO1983002066A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NO814247811211 1981-12-11
NO814247A NO814247L (en) 1981-12-11 1981-12-11 PROTECTIVE SUIT.

Publications (1)

Publication Number Publication Date
WO1983002066A1 true WO1983002066A1 (en) 1983-06-23

Family

ID=19886343

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/NO1982/000060 WO1983002066A1 (en) 1981-12-11 1982-12-13 Protective suit

Country Status (4)

Country Link
CA (1) CA1188851A (en)
IT (1) IT1210959B (en)
NO (1) NO814247L (en)
WO (1) WO1983002066A1 (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0465817A1 (en) * 1990-06-29 1992-01-15 W.L. Gore & Associates, Inc. Protective materials
WO1993008024A2 (en) * 1991-10-15 1993-04-29 Freudenberg Nonwovens Ltd. Protective material
DE4310110A1 (en) * 1992-07-07 1994-01-13 Kaercher Gmbh & Co Alfred Multi-layer, textile, gas-permeable filter material against chemical pollutants
DE19501433A1 (en) * 1995-01-19 1996-07-25 Bundesrep Deutschland Use net-like flexible spacer in chemical protective clothing
DE19732205A1 (en) * 1997-07-26 1999-02-11 Bundesrep Deutschland Jacket part of NBC protective outfit
WO2004073798A1 (en) * 2003-02-24 2004-09-02 Forsvarets Forskningsinstitutt Protective garment
WO2005118280A1 (en) * 2004-05-26 2005-12-15 Gore Enterprise Holdings, Inc. Durable covering for chemical protection
WO2006019696A1 (en) * 2004-07-28 2006-02-23 Gore Enterprise Holdings, Inc. Protective garment ensemble
JP2014528828A (en) * 2011-09-30 2014-10-30 テイコク ファーマ ユーエスエー インコーポレーテッド Transdermal patch disposal system

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1127581A (en) * 1966-01-04 1968-09-18 Bondina Ltd Protective clothing
US3586596A (en) * 1965-09-20 1971-06-22 Technology Uk Protective clothing
EP0037745A1 (en) * 1980-04-09 1981-10-14 E.I. Du Pont De Nemours And Company Waterproof protective covers comprising a film of highly fluorinated ion exchange polymer

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3586596A (en) * 1965-09-20 1971-06-22 Technology Uk Protective clothing
GB1127581A (en) * 1966-01-04 1968-09-18 Bondina Ltd Protective clothing
EP0037745A1 (en) * 1980-04-09 1981-10-14 E.I. Du Pont De Nemours And Company Waterproof protective covers comprising a film of highly fluorinated ion exchange polymer

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0465817A1 (en) * 1990-06-29 1992-01-15 W.L. Gore & Associates, Inc. Protective materials
WO1993008024A2 (en) * 1991-10-15 1993-04-29 Freudenberg Nonwovens Ltd. Protective material
WO1993008024A3 (en) * 1991-10-15 1993-05-27 Freudenberg Nonwovens Ltd Protective material
GB2276121A (en) * 1991-10-15 1994-09-21 Freudenberg Nonwovens Ltd Protective material
DE4310110A1 (en) * 1992-07-07 1994-01-13 Kaercher Gmbh & Co Alfred Multi-layer, textile, gas-permeable filter material against chemical pollutants
DE19501433A1 (en) * 1995-01-19 1996-07-25 Bundesrep Deutschland Use net-like flexible spacer in chemical protective clothing
DE19732205A1 (en) * 1997-07-26 1999-02-11 Bundesrep Deutschland Jacket part of NBC protective outfit
DE19732205C2 (en) * 1997-07-26 1999-06-02 Bundesrep Deutschland Jacket part of an ABC protective suit
WO2004073798A1 (en) * 2003-02-24 2004-09-02 Forsvarets Forskningsinstitutt Protective garment
GB2413934A (en) * 2003-02-24 2005-11-16 Forsvarets Forsknings Protective garment
GB2413934B (en) * 2003-02-24 2006-12-27 Forsvarets Forsknings Protective garment
WO2005118280A1 (en) * 2004-05-26 2005-12-15 Gore Enterprise Holdings, Inc. Durable covering for chemical protection
AU2005249942B2 (en) * 2004-05-26 2009-09-10 W. L. Gore & Associates, Inc. Durable covering for chemical protection
US7704598B2 (en) 2004-05-26 2010-04-27 Gore Enterprise Holdings, Inc. Durable covering for chemical protection
AU2005249942C1 (en) * 2004-05-26 2010-04-29 W. L. Gore & Associates, Inc. Durable covering for chemical protection
WO2006019696A1 (en) * 2004-07-28 2006-02-23 Gore Enterprise Holdings, Inc. Protective garment ensemble
JP2014528828A (en) * 2011-09-30 2014-10-30 テイコク ファーマ ユーエスエー インコーポレーテッド Transdermal patch disposal system

Also Published As

Publication number Publication date
IT1210959B (en) 1989-09-29
NO814247L (en) 1983-06-13
IT8224699A0 (en) 1982-12-10
CA1188851A (en) 1985-06-18

Similar Documents

Publication Publication Date Title
US5471906A (en) Body armor cover and method for making the same
CA2567911C (en) Durable covering for chemical protection
US4872220A (en) Protective composite materials, their production and articles of protective clothing made therefrom
US5112666A (en) Cbw protective clothing
US4194041A (en) Waterproof laminate
EP0630279A1 (en) Polyalkyleneimine or polyallylamine coated material.
US10155357B2 (en) Textile material having increased mechanical strength, in particular having increased resistance to piercing or shooting
US5017424A (en) Skin tight chemical/biological protective suit
US4943475A (en) Multilayer composite protective fabric material and use in protective clothing
KR100543050B1 (en) Chemical protective covering
AU636754B2 (en) Protective materials
US4981738A (en) Almost impermeable chemically protective fabric
MXPA05002656A (en) Multiple hazard protection articles and methods for making them.
CN107584824A (en) A kind of multifunctional ventilating type frog suit fabric and preparation method thereof
WO1983002066A1 (en) Protective suit
DE3939373A1 (en) Material for breathing breathing breathing breathing breathing protective covering against harmful gases - comprising microporous teflon membrane against liquids and adsorbent layer against gases
US5162398A (en) Composite protective materials, their production and articles made thereof
EP1433394A1 (en) Air permeable garment and fabric with integral aerosol filtration
WO2002034998A3 (en) Chemical warfare proof tent shot fabric
GB2282779A (en) Composite fabrics for protection against chemical agents
Khan CBRN Personal Protective Clothing
NO764119L (en) IMPERMABLE MATERIAL.

Legal Events

Date Code Title Description
AK Designated states

Designated state(s): DK FI JP US

AL Designated countries for regional patents

Designated state(s): AT BE CH DE FR GB NL SE