WO1986001643A1 - Polymeric electrolytes - Google Patents

Polymeric electrolytes Download PDF

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Publication number
WO1986001643A1
WO1986001643A1 PCT/GB1985/000376 GB8500376W WO8601643A1 WO 1986001643 A1 WO1986001643 A1 WO 1986001643A1 GB 8500376 W GB8500376 W GB 8500376W WO 8601643 A1 WO8601643 A1 WO 8601643A1
Authority
WO
WIPO (PCT)
Prior art keywords
oligomer
polymer
oxyethylene
formula
attached
Prior art date
Application number
PCT/GB1985/000376
Other languages
French (fr)
Inventor
Jeremy Roger Martin Giles
John Knight
Colin Booth
Richard Henry Mobbs
John Robert Owen
John Ronald Craven
Ian Edward Kelly
Original Assignee
The Secretary Of State For Defence In Her Britanni
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27262448&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO1986001643(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from GB8421193A external-priority patent/GB8421193D0/en
Priority claimed from GB848421194A external-priority patent/GB8421194D0/en
Priority claimed from GB858501342A external-priority patent/GB8501342D0/en
Application filed by The Secretary Of State For Defence In Her Britanni filed Critical The Secretary Of State For Defence In Her Britanni
Priority to JP60503718A priority Critical patent/JPH0679490B2/en
Priority to DE8585904128T priority patent/DE3577950D1/en
Publication of WO1986001643A1 publication Critical patent/WO1986001643A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/336—Polymers modified by chemical after-treatment with organic compounds containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/337—Polymers modified by chemical after-treatment with organic compounds containing other elements
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/122—Ionic conductors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H01M6/18—Cells with non-aqueous electrolyte with solid electrolyte
    • H01M6/181—Cells with non-aqueous electrolyte with solid electrolyte with polymeric electrolytes

Abstract

A polymeric electrolyte comprising a solution of an ionic salt in a polymer X having a backbone of formula -A-B-, where A is an oligomeric chain and B is a chain extender group, attached to oligomer A, containing one or more linkage atoms Z selected from Si, C and P, wherein the polymer contains oxyethylene units which are present in one or more of the polymer backbone, sidechains or crosslinks, such that where A is an oxyethylene oligomer of formula (CH2CH2-O) n, n is an integer from 3 to 10 and where the oxyethylene oligomer is contained in a sidechain or crosslink attached at B, n is from 2 to 25.
PCT/GB1985/000376 1984-08-21 1985-08-21 Polymeric electrolytes WO1986001643A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP60503718A JPH0679490B2 (en) 1984-08-21 1985-08-21 Polyelectrolyte
DE8585904128T DE3577950D1 (en) 1984-08-21 1985-08-21 POLYMER ELECTROLYTE.

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
GB8421193A GB8421193D0 (en) 1984-08-21 1984-08-21 Polymer electrolytes
GB8421194 1984-08-21
GB8421193 1984-08-21
GB848421194A GB8421194D0 (en) 1984-08-21 1984-08-21 Polymer electrolytes
GB858501342A GB8501342D0 (en) 1985-01-18 1985-01-18 Polymer electrolytes
GB8501342 1985-01-18

Publications (1)

Publication Number Publication Date
WO1986001643A1 true WO1986001643A1 (en) 1986-03-13

Family

ID=27262448

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1985/000376 WO1986001643A1 (en) 1984-08-21 1985-08-21 Polymeric electrolytes

Country Status (6)

Country Link
US (1) US4737422A (en)
EP (1) EP0190306B2 (en)
JP (1) JPH0679490B2 (en)
DE (1) DE3577950D1 (en)
GB (1) GB2164047B (en)
WO (1) WO1986001643A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0269018A2 (en) * 1986-11-21 1988-06-01 Mitsubishi Petrochemical Co., Ltd. Solid polymer electrolyte composition
EP0378123A1 (en) * 1989-01-07 1990-07-18 Hitachi Maxell Ltd. Ionic conductive polymer electrolyte and cell comprising the same
WO1995013311A2 (en) * 1993-11-10 1995-05-18 Valence Technology, Inc. Capped compounds for solid polymeric electrolytes

Families Citing this family (44)

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GB8619049D0 (en) * 1986-08-05 1986-09-17 Secr Defence Electrolytic polymers
US4849311A (en) * 1986-09-24 1989-07-18 Toa Nenryo Kogyo Kabushiki Kaisha Immobilized electrolyte membrane
GB8625659D0 (en) * 1986-10-27 1986-11-26 Secr Defence Polymeric ion conductors
EP0572099A3 (en) * 1987-06-30 1996-04-24 Yuasa Battery Co Ltd Polymer solid electrolyte and polymer solid electrolyte battery
GB8716559D0 (en) * 1987-07-14 1987-08-19 Secr Defence Ion conductors
US5238758A (en) * 1987-10-30 1993-08-24 Mhb Joint Venture Badiation cured solid electrolytes and electrochemical devices employing the same
US4830939B1 (en) * 1987-10-30 1996-10-08 Mhb Joint Venture Radiation cured solid electrolytes and electrochemical devices employing the same
JP2684714B2 (en) * 1987-12-25 1997-12-03 大日本インキ化学工業株式会社 Silver halide photographic light-sensitive material and method for forming high-contrast photographic image using the same
US5019468A (en) * 1988-10-27 1991-05-28 Brother Kogyo Kabushiki Kaisha Sheet type storage battery and printed wiring board containing the same
US4882243A (en) * 1988-11-22 1989-11-21 Polytechnic University Preparation of metallic cation conducting polymers based on sterically hindered phenols containing polymeric systems
US5006431A (en) * 1989-02-23 1991-04-09 Hope Henry F Solid state polymer electrolyte for batteries
JPH0619923B2 (en) * 1990-05-02 1994-03-16 ナショナル サイエンス カウンシル Ionic conductive side chain liquid crystal polymer electrolyte
US5362493A (en) * 1990-05-04 1994-11-08 Associated Universities, Inc. Preparation of redox polymer cathodes for thin film rechargeable batteries
US5124508A (en) * 1990-08-14 1992-06-23 The Scabbard Corp. Application of sheet batteries as support base for electronic circuits
US5147985A (en) * 1990-08-14 1992-09-15 The Scabbard Corporation Sheet batteries as substrate for electronic circuit
US5209871A (en) * 1990-11-28 1993-05-11 Ford Motor Company Self-sealing liquid electrolyte useful in electrochromic device
US5166009A (en) * 1991-03-28 1992-11-24 The United States Of America As Represented By The Secretary Of The Navy Mixed polymer electrolyte and mixed polymer electrolyte battery
JP2851722B2 (en) * 1991-07-26 1999-01-27 日本石油株式会社 Polymer solid electrolyte and method for producing the same
DE69305878T2 (en) * 1992-01-20 1997-05-22 Nippon Telegraph & Telephone Solid polymer electrolyte and process for its manufacture
US5786110A (en) * 1992-06-22 1998-07-28 Arizona Board Of Regents Alkali-metal-ion conducting electrolytes
US5262253A (en) * 1992-07-22 1993-11-16 Valence Technology, Inc. Solid electrolytes derived by polymerization of vinyl sulfonate polyalkylene oxides
US5489491A (en) * 1992-07-22 1996-02-06 Golovin; Milton N. Curable polymer precursors for solid electrolytes
US5498491A (en) * 1992-07-22 1996-03-12 Golovin; Milton N. Solid electrolytes derived by polymerization of vinyl sulfonate derivatives
FR2694758B1 (en) * 1992-08-14 1994-10-21 Centre Nat Rech Scient Crosslinkable copolymers obtained by polycondensation and ionically conductive material containing them.
US5453335A (en) * 1992-12-23 1995-09-26 Arthur D Little, Inc. Ion-conductive polymer and electrolyte additives
EP0643434B1 (en) * 1993-02-23 1999-10-20 Yuasa Corporation Method of cell manufacture
US5346787A (en) * 1993-04-19 1994-09-13 Valence Technology, Inc. Allyl carbonate polymer solid electrolytes
US5294501A (en) * 1993-04-19 1994-03-15 Valence Technology, Inc. Silane acrylate monomer and solid electrolyte derived by the polymerization thereof
US5300375A (en) * 1993-04-19 1994-04-05 Valence Technology, Inc. Acrylic alkoxy silane monomer and solid electrolyte derived by the polymerization thereof
US5393621A (en) * 1993-10-20 1995-02-28 Valence Technology, Inc. Fire-resistant solid polymer electrolytes
US5521025A (en) * 1993-10-20 1996-05-28 Chaloner-Gill; Benjamin Electro chemical cell comprising non-radiation curable solid polymer electrolytes
US5419984A (en) * 1993-12-16 1995-05-30 Valence Technology Inc. Solid electrolytes containing polysiloxane acrylates
US5574127A (en) * 1995-04-05 1996-11-12 Aqualon Hydrophobically modified poly(acetal-polyethers)
US6610440B1 (en) * 1998-03-10 2003-08-26 Bipolar Technologies, Inc Microscopic batteries for MEMS systems
JP4416055B2 (en) * 1998-12-01 2010-02-17 ローム株式会社 Ferroelectric memory and manufacturing method thereof
US6413676B1 (en) 1999-06-28 2002-07-02 Lithium Power Technologies, Inc. Lithium ion polymer electrolytes
US6664006B1 (en) 1999-09-02 2003-12-16 Lithium Power Technologies, Inc. All-solid-state electrochemical device and method of manufacturing
US6645675B1 (en) 1999-09-02 2003-11-11 Lithium Power Technologies, Inc. Solid polymer electrolytes
TW527745B (en) * 2000-11-21 2003-04-11 Dainichiseika Color Chem Solidifying material for cell electrolyte solution, and cell comprising the solidifying material
DE112007001087B4 (en) * 2006-05-04 2019-11-28 Korea Research Institute Of Chemical Technology Active electrode material with high stability and cathode and electrochemical device using it
US9985292B2 (en) * 2012-11-27 2018-05-29 Seeo, Inc. Oxyphosphorus-containing polymers as binders for battery cathodes
WO2014200922A1 (en) * 2013-06-10 2014-12-18 Navitas Systems, Llc A gel electrolyte for an electrochemical cell
CN110073536B (en) * 2016-12-14 2022-10-28 出光兴产株式会社 Method for producing sulfide solid electrolyte
CN107793564B (en) * 2017-10-20 2020-07-10 萨尔法(武汉)新能源科技有限公司 Low-Tg polyether all-solid-state single-ion conductive polymer and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0037776A1 (en) * 1980-03-31 1981-10-14 ETAT-FRANCAIS représenté par le Délégué Général pour l' Armement Solid electrolyte based on macromolucular material with ionic conductivity
FR2493609A1 (en) * 1980-10-30 1982-05-07 Comp Generale Electricite Macromolecular solid electrolyte for lithium electrochemical generator - contg. elastomeric polyester matrix based on di:methyl:terephthalate, polyglycol and diol
EP0078505A1 (en) * 1981-11-03 1983-05-11 COMPAGNIE GENERALE D'ELECTRICITE Société anonyme dite: Process for manufacturing a polymeric solid electrolyte for an electrochemical generator
EP0090710A1 (en) * 1982-03-18 1983-10-05 ANVAR Agence Nationale de Valorisation de la Recherche Electrolytes formed of solid solutions of closoboranes in a plastic macromolecular material, and electrochemical generator containing such electrolytes
EP0119912A2 (en) * 1983-03-11 1984-09-26 Societe Nationale Elf Aquitaine Macromolecular material constituted by a salt in solution in a copolymer
WO1985002718A1 (en) * 1983-12-09 1985-06-20 National Research Development Corporation Polymeric materials

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FR2442512A1 (en) * 1978-11-22 1980-06-20 Anvar NEW ELASTOMERIC MATERIALS WITH ION CONDUCTION
US4353492A (en) * 1981-07-17 1982-10-12 Eastman Kodak Company Ends-down sensor device
FR2527611A1 (en) * 1982-06-01 1983-12-02 Anvar TETRAKIS TRIALKYL SILOXY ALKALINE METAL ALANATES, THEIR SOLID SOLUTIONS WITH PLASTIC MATERIALS AND THEIR APPLICATION TO THE CONSTITUTION OF CONDUCTIVE ELEMENTS FOR ELECTROCHEMICAL GENERATORS
FR2565413B1 (en) * 1984-05-29 1986-08-29 Elf Aquitaine ION CONDUCTING MACROMOLECULAR MATERIAL FOR PRODUCING ELECTROLYTES OR ELECTRODES

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0037776A1 (en) * 1980-03-31 1981-10-14 ETAT-FRANCAIS représenté par le Délégué Général pour l' Armement Solid electrolyte based on macromolucular material with ionic conductivity
FR2493609A1 (en) * 1980-10-30 1982-05-07 Comp Generale Electricite Macromolecular solid electrolyte for lithium electrochemical generator - contg. elastomeric polyester matrix based on di:methyl:terephthalate, polyglycol and diol
EP0078505A1 (en) * 1981-11-03 1983-05-11 COMPAGNIE GENERALE D'ELECTRICITE Société anonyme dite: Process for manufacturing a polymeric solid electrolyte for an electrochemical generator
EP0090710A1 (en) * 1982-03-18 1983-10-05 ANVAR Agence Nationale de Valorisation de la Recherche Electrolytes formed of solid solutions of closoboranes in a plastic macromolecular material, and electrochemical generator containing such electrolytes
EP0119912A2 (en) * 1983-03-11 1984-09-26 Societe Nationale Elf Aquitaine Macromolecular material constituted by a salt in solution in a copolymer
WO1985002718A1 (en) * 1983-12-09 1985-06-20 National Research Development Corporation Polymeric materials

Non-Patent Citations (4)

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Title
CHEMICAL ABSTRACTS, Volume 101, 9 July 1984, Columbus, Ohio, (US) TSUCHIDA EISHUN et al.: "Lithium Ion Conducting Polymeric Hybrids", page 531, Abstract Nr. 15552j & Mol. Cryst. Liq. Cryst. 1984, 106 (3-4), 361-9 (Eng) *
Journal of Polymer Science: Polym. Letters Ed. Volume 22, Nr. 11, November 1984, John Wiley & Sons Inc. DU WEI XIA et al.: "Solid Polymer Electrolyte Complexes of Polymethacrylates Carrying Pendant Oligo-Oxyethylne (Glyme) Chains", pages 617-621, see page 617; page 618: Results and Discussion; page 620, paragraphs 3 and 4 *
Journal of Power Sources, Volume 14, Nr. 1-3, January-March 1985, Lausanne, (CH) M. LEVEQUE et al.: "Cationic Transport Numbers in Polyether-Based Networks Containing Lithium Salts", pages 27-30, see page 28: Experimental; page 29, table I: last example *
Solid States Ionics, Volume 14, Nr. 3, November 1984 DU WEI XIA et al.: "Conductivities of Solid Polymer Electrolyte Complexes of Alkali Salts with Polymers of Methoxypoly-Ethyleneglycol Methacrylates", pages 221-224, see Abstract; Experimental; page 224; left-hand column *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0269018A2 (en) * 1986-11-21 1988-06-01 Mitsubishi Petrochemical Co., Ltd. Solid polymer electrolyte composition
EP0269018A3 (en) * 1986-11-21 1989-05-24 Mitsubishi Petrochemical Co., Ltd. Solid polymer electrolyte composition
EP0378123A1 (en) * 1989-01-07 1990-07-18 Hitachi Maxell Ltd. Ionic conductive polymer electrolyte and cell comprising the same
US5227043A (en) * 1989-01-07 1993-07-13 Hitachi Maxell, Ltd. Ionic conductive polymer electrolyte and cell comprising the same
WO1995013311A2 (en) * 1993-11-10 1995-05-18 Valence Technology, Inc. Capped compounds for solid polymeric electrolytes
WO1995013311A3 (en) * 1993-11-10 1995-06-22 Valence Technology Inc Capped compounds for solid polymeric electrolytes

Also Published As

Publication number Publication date
GB2164047A (en) 1986-03-12
GB8520902D0 (en) 1985-09-25
GB2164047B (en) 1989-05-24
EP0190306A1 (en) 1986-08-13
US4737422A (en) 1988-04-12
JPS62500334A (en) 1987-02-05
JPH0679490B2 (en) 1994-10-05
EP0190306B2 (en) 1993-12-22
EP0190306B1 (en) 1990-05-23
DE3577950D1 (en) 1990-06-28

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