WO1988007189A1 - Diamond mapping - Google Patents
Diamond mapping Download PDFInfo
- Publication number
- WO1988007189A1 WO1988007189A1 PCT/GB1988/000188 GB8800188W WO8807189A1 WO 1988007189 A1 WO1988007189 A1 WO 1988007189A1 GB 8800188 W GB8800188 W GB 8800188W WO 8807189 A1 WO8807189 A1 WO 8807189A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- diamond
- raman radiation
- radiation
- intensity
- scattered
- Prior art date
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
- G01N21/63—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
- G01N21/65—Raman scattering
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/84—Systems specially adapted for particular applications
- G01N21/87—Investigating jewels
Definitions
- the present invention relates to diamond mapping and in particular to a method for mapping the crystal structure of a diamond.
- Diamonds have long been recognised as being of great value not only for decorative and industrial purposes but also as an investment. Their increasing value has presented problems of security for owners, insurance companies and police authorities. Identification of a recovered diamond which has been lost or stolen is made difficult because the superficial appearance of the diamond may have been changed by cutting, repolishing and the like.
- the Raman signal of diamond is much stronger than that of other materials because diamond only contains carbon to carbon bonding and its Raman signal occurs at a position well separated from those of other minerals. Also, as diamond only contains one type of carbon to carbon bond, there is only a single Raman signal which can be readily distinguished from associated broad band fluorescence. Thus the Raman signal is highly specific for diamond. The intensity of the Raman signal is affected by -the crystal structure of the diamond and hence by the presence or otherwise of imperfections or inclusions in the diamond. For example, it has been found that imperfections cause a broadening of the diamond Raman signal and inclusions do not give a diamond Raman signal.
- a method for mapping the crystal structure of a diamond comprising the steps of (a) placing the diamond in a beam of monochromatic laser radiation capable of causing Raman radiation to be scattered from the diamond, (b) passing the scattered Raman radiation from the diamond through a filter adapted to pass only scattered Raman radiation characteristic of diamond, and (c) measuring the intensity of the filtered Raman radiation at one or more different orientations of the diamond.
- a method for producing a record of a diamond comprising the steps of (a) placing the diamond in a beam of monochromatic laser radiation capable of causing Raman radiation to be scattered from the diamond, (b) passing the scattered Raman radiation from the diamond through a filter adapted- to pass only scattered Raman radiation characteristic of diamond, (c) measuring the intensity. of the filtered Raman radiation, and (d) recording the intensity of the filtered Raman radiation at one or more different orientations of the diamond.
- the invention also includes records whenever produced by the method as hereinbefore described.
- an apparatus for producing a record of a diamond comprising in combination (a) means for holding the diamond in a beam of monochromatic laser radiation capable of causing Raman radiation to be scattered from the diamond, (b) means for filtering the resultant scattered Raman radiation, said filter being adapted to pass only scattered Raman radiation characteristic of diamond, (c) means for measuring the intensity of the filtered Raman radiation, and (d) means for recording the intensity of the filtered Raman radiation at one or more different orientations of the diamond to produce a record of the diamond.
- the Raman intensities are recorded at three mutually perpendicular orientations of the diamond.
- the record of the diamond may be used for identification purposes.
- the record of a recovered diamond that has been lost or stolen may be compared with records of known diamonds so that it may be identified.
- a method for identifying a diamond comprising the steps of (a) placing the diamond to be identified in a beam of monochromatic laser radiation capable of causing Raman radiation to be scattered from the diamond, (b) passing the scattered Raman radiation from the diamond through a filter adapted to pass only scattered Raman radiation characteristic of diamond, (c) measuring the intensity of the filtered Raman radiation, (d) recording the intensity of the filtered Raman radiation at one or more different orientations of the diamond, and (e) comparing the recorded intensities with records of known diamonds whereby the diamond may be identified ⁇
- the monochromatic laser radiation has a wavelength in the range 450 to 650 nanometers.
- the filtering means may be a suitable optical arrangement such as a collection optic and monochromator.
- the scattered Raman radiation is focused by a suitable lens arrangement with a long depth of focus so that the scattered Raman radiation from throughout the diamond is in focus at the detector.
- the record may be a point-by-point record of the Raman intensities or may be a record of the Raman intensities from the whole of the diamond simultaneously.
- the record may be in the form of values stored on magnetic tape or in a computer etc. and in the latter case the record may be in the form of a photograph.
- a video or television camera may be adapted to dFsplay the scattered Raman intensities on a monitor or television screen. It is envisaged that in this embodiment the invention may enable the crystal structure of a diamond to be mapped far a large number of orientations of the diamond without the delay imposed by photographic developing or interpretation of diffraction patterns etc.
- a record may be made in the form of images stored by conventional means e.g. video tape, for different orientations of the diamond, and may be used for future identification purposes.
- a photomultiplier or multichannel detector may be adapted to scan the scattered Raman radiation.
- the means for holding the diamond in the laser radiation may be adapted so that the orientation of the diamond may be changed under automatic, microprocessor or computer control.
- a record of the diamond may be made in the form of stored Raman intensities which may be stored by conventional means, for example in a computer or on magnetic tape etc.
- the filtered Raman radiation may be measured and recorded by a camera with a photographic plate or film sensitive to the filtered Raman radiation.
- the plate or film is suitably processed to produce a• two-dimensional image of the scattered Raman intensity of the diamond in the selected orientation.
- the record of the diamond may take the form of several such photographic images at different orientations of the diamond and may be used for future identification purposes.
- Raman apectroscopy may be used to map the crystal structure of a diaraOnd to show an imperfection
- a series of Raman spectrograms were recorded in the region of an imperfection in a diamond.
- An argon ion laser was used to produce a beam of radiation having a wavelength of 514.5 nanometres. The beam was used to irradiate a 2 micron diameter spot on the diamond.
- Resultant scattered Raman radiation was measured using a Jobin-Yvon 3000S spectrometer which measured the intensity of the Raman radiation and recorded it as the spectrograms shown in Figures 1 to 4 as graphs of Raman intensity against Raman shift.
- the diamond had an imperfection which was a pit, 8 microns in diameter, on its surface.
- Figure 1 shows the Raman spectrogram from a region of the diamond distant from the pit. The spectral peak in Figure 1 is sharp.
- Figure 2 shows a spectrogram from the centre of the pit and this shows that the Raman spectral peak is broader due to the imperfection.
- Figures 3 and 4 show spectrograms from the the sides of the pit. They show the peak being broader but the broadening is asymmetric. It is envisaged that this peak broadening would, for example, show up as a reduction in the Raman intensity on a photographic record of the diamond produced by the method according to the present invention.
- Raman spectroscopy may be used to map the crystal structure of a diamond to show an inclusion
- the method according to the present invention was used to make a record of a diamond with a simulated inclusion.
- the diamond had a piece of potassium nitrate on it.
- the diamond was held in a holder and irradiated with laser radiation of wavelength 514.5 nanometres from a Spectra Physics 165 argon ion laser.
- the laser power at the laser head was about 300 mV which reduced to about 25 to 50 at the sample.
- the laser radiation was rotated using spinning mirrors and passed through an annular condenser surrounding a 50 times magnification microscope objective to irradiate an area -of the diamond 200 microns in diameter.
- Resultant scattered Raman radiation was collected by the microscope objective and passed to a Jobin-Yvon Raman spectrometer which was operated in its imaging mode (very wide slits and some lenses retracted) to ensure that the image was transmitted undistorted to a 2-dimensional intensified silicon intensified target (ISIT) camera for detection.
- ISIT 2-dimensional intensified silicon intensified target
- the spectrometer passed only radiation characteristic of diamond to the detector.
- the detector had a 2.5cm square target with a variable integration time from 1 second to a few minutes.
- the image on the detector was recorded photographically which showed a bright white image in the regions which were pure diamond and dark regions in the area of the non-diamond inclusion. It is envisaged that a record of the inclusions in the diamond may be produced by recording images from the detector for several orientations of the diamond.
- Figure 5 shows, in schematic form, an apparatus which may be used to map the crystal structure of a diamond and to produce a record of the diamond which may be used for identification purposes.
- a diamond (1) is placed in a holder (2) in a beam of monochromatic laser radiation (3).
- the radiation (3) is provided by a laser (4). It has a wavelength in the range 450 to 650 nanometres and is capable of causing Raman radiation (5) to be scattered from the diamond (1).
- the scattered Raman radiation (5) is collected by a lens (6), passed through a beam splitter (7) and to a filter (8) which only passes Raman radiation characteristic of diamond.
- the intensity of the filtered Raman radiation (9) is measured by a video camera (10) which produces an image on a video monitor (11).
- the image shows a bright white intensity corresponding to diamond with grey regions indicative of imperfections and black regions indicative of inclusions.
- a record of the image on the video monitor is made by photographing it with a camera (12). Several such photographs may be made for different orientations of the diamond to produce a record of the diamond. The record thus produced may be used for future identification purposes.
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL8820132A NL8820132A (en) | 1987-03-18 | 1988-03-10 | MAPING A DIAMOND. |
BR888806080A BR8806080A (en) | 1987-03-18 | 1988-03-10 | PROCESS TO MAP THE CRYSTALLINE STRUCTURE OF A DIAMOND, PROCESS AND APPARATUS TO PRODUCE A DIAMOND REGISTRATION, A DIAMOND REGISTRATION AND PROCESS TO IDENTIFY A DIAMOND |
DE883890288T DE3890288T1 (en) | 1987-03-18 | 1988-03-10 | DETECTION OF DIAMONDS |
GB8824662A GB2219392B (en) | 1987-03-18 | 1988-03-10 | Method and apparatus for producing a record of a diamond |
KR1019880701445A KR890700818A (en) | 1987-03-18 | 1988-03-10 | Diamond thought |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB878706422A GB8706422D0 (en) | 1987-03-18 | 1987-03-18 | Identification method |
GB8706422 | 1987-03-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1988007189A1 true WO1988007189A1 (en) | 1988-09-22 |
Family
ID=10614161
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB1988/000188 WO1988007189A1 (en) | 1987-03-18 | 1988-03-10 | Diamond mapping |
Country Status (12)
Country | Link |
---|---|
US (1) | US4900147A (en) |
EP (1) | EP0305440A1 (en) |
JP (1) | JPH01503561A (en) |
KR (1) | KR890700818A (en) |
AU (1) | AU604866B2 (en) |
BR (1) | BR8806080A (en) |
DE (1) | DE3890288T1 (en) |
GB (2) | GB8706422D0 (en) |
IN (1) | IN170639B (en) |
NL (1) | NL8820132A (en) |
WO (1) | WO1988007189A1 (en) |
ZA (1) | ZA881881B (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5505313A (en) * | 1991-02-20 | 1996-04-09 | Gersan Establishment | Method and apparatus for detecting diamonds in a plurality of objects |
US5835200A (en) * | 1990-04-24 | 1998-11-10 | Gersan Establishment | Method and apparatus for examining an object |
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DE4005878A1 (en) * | 1990-02-24 | 1991-08-29 | Bruker Analytische Messtechnik | RAMAN SPECTROMETER |
US5932119A (en) * | 1996-01-05 | 1999-08-03 | Lazare Kaplan International, Inc. | Laser marking system |
US6529612B1 (en) * | 1997-07-16 | 2003-03-04 | Diversified Scientific, Inc. | Method for acquiring, storing and analyzing crystal images |
US6020954A (en) * | 1997-12-18 | 2000-02-01 | Imagestatistics, Inc. | Method and associated apparatus for the standardized grading of gemstones |
US6980283B1 (en) * | 1997-12-18 | 2005-12-27 | Imagestatistics, Inc. | Method and associated apparatus for the standardized grading of gemstones |
US5983238A (en) * | 1997-12-26 | 1999-11-09 | Diamond Id | Gemstons identification tracking and recovery system |
US7214540B2 (en) * | 1999-04-06 | 2007-05-08 | Uab Research Foundation | Method for screening crystallization conditions in solution crystal growth |
DE60034033T2 (en) * | 1999-04-06 | 2007-12-06 | University of Alabama, Birmingham Research Foundation, Birmingham | DEVICE FOR SCREENING CRYSTALLIZATION CONDITIONS IN SOLUTIONS FOR CRYSTAL BREEDING |
US20020164812A1 (en) * | 1999-04-06 | 2002-11-07 | Uab Research Foundation | Method for screening crystallization conditions in solution crystal growth |
US7244396B2 (en) * | 1999-04-06 | 2007-07-17 | Uab Research Foundation | Method for preparation of microarrays for screening of crystal growth conditions |
US7247490B2 (en) * | 1999-04-06 | 2007-07-24 | Uab Research Foundation | Method for screening crystallization conditions in solution crystal growth |
US7250305B2 (en) * | 2001-07-30 | 2007-07-31 | Uab Research Foundation | Use of dye to distinguish salt and protein crystals under microcrystallization conditions |
US6450402B1 (en) | 1999-05-05 | 2002-09-17 | T.I.D. (The Identifying Diamond) Inc. | Identification device |
US6308891B1 (en) | 1999-05-05 | 2001-10-30 | T.I.D. (The Identifying Diamond) Inc. | Jewelry identification |
US6630006B2 (en) * | 1999-06-18 | 2003-10-07 | The Regents Of The University Of California | Method for screening microcrystallizations for crystal formation |
US7670429B2 (en) * | 2001-04-05 | 2010-03-02 | The California Institute Of Technology | High throughput screening of crystallization of materials |
ES2219483T3 (en) * | 2001-12-13 | 2004-12-01 | Overseas Diamonds Technologies N.V. | DEVICE FOR GENERATING DATA TO DETERMINE A PROPERTY OF A PRECIOUS STONE AND PROCEDURES TO DETERMINE A PROPERTY OF A PRECIOUS STONE. |
IL148256A0 (en) * | 2002-02-19 | 2002-09-12 | Dialit Ltd | Gemstone imaging system and apparatus and method of use thereof |
US20070026528A1 (en) * | 2002-05-30 | 2007-02-01 | Delucas Lawrence J | Method for screening crystallization conditions in solution crystal growth |
WO2003103434A2 (en) * | 2002-06-07 | 2003-12-18 | Bray William R | Diamond cut scoring system and method |
AU2003256469A1 (en) * | 2002-07-10 | 2004-01-23 | Uab Research Foundation | Method for distinguishing between biomolecule and non-biomolecule crystals |
US6786733B2 (en) * | 2002-10-15 | 2004-09-07 | Overseas Diamonds Inc. | Computer-implemented method of and system for teaching an untrained observer to evaluate a gemstone |
US20050117145A1 (en) * | 2003-11-28 | 2005-06-02 | Joshua Altman | Detection of imperfections in precious stones |
US7461017B2 (en) * | 2004-04-30 | 2008-12-02 | Yeko Sr Steven K | System and method for enabling jewelry certification at local jeweler sites |
US20100121769A1 (en) * | 2004-04-30 | 2010-05-13 | Yeko Sr Steven K | Method and System for Facilitating Verification of Ownership Status of a Jewelry-Related Item |
WO2006033102A1 (en) * | 2004-09-21 | 2006-03-30 | Zvi Porat | A system and method for three-dimensional location of inclusions in a gemstone |
EP1795888B1 (en) | 2005-12-09 | 2017-08-23 | Sarine Color Technologies Ltd. | Apparatus for generating data for determining a property of a gemstone |
US20090234754A1 (en) * | 2008-03-11 | 2009-09-17 | Dave Lapa | Apparatus, a method, and a system for gemstone evaluation and gemology tutoring over the internet |
JP5225235B2 (en) * | 2009-08-24 | 2013-07-03 | 株式会社エージーティ・ジェム・ラボラトリー | How to identify gem materials |
CA2778083A1 (en) * | 2011-05-24 | 2012-11-24 | Discovery Metals, Llc | Ambient reflectivity absorption system for identifying precious or semi-precious materials and associated methods |
SG10201609555YA (en) * | 2013-08-12 | 2017-01-27 | Caratell Pte Ltd | Method and system for certification and verification of gemstones |
AT514332B1 (en) | 2013-08-27 | 2014-12-15 | Swarovski D Kg | Arrangement for analyzing a light pattern caused by refraction and reflection on a gemstone |
CN107044973A (en) * | 2017-03-27 | 2017-08-15 | 胡章宏 | A kind of diamond quick determination method and device based on Raman spectrum |
US10552950B2 (en) | 2017-05-25 | 2020-02-04 | International Business Machines Corporation | Mapping and encoding gemological features |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3947120A (en) * | 1973-10-23 | 1976-03-30 | Yeda Research And Development Co. Ltd. | Gem identification |
US4030827A (en) * | 1973-12-03 | 1977-06-21 | Institut National De La Sante Et De La Recherche Medicale (Inserm) | Apparatus for the non-destructive examination of heterogeneous samples |
FR2496888A1 (en) * | 1980-12-22 | 1982-06-25 | Gemological Lab Antwerp | Automatic grading system for precious stones - comprises electronic weighing platform and laser optics and analysis equipment providing inputs for processor to resolve characteristics |
WO1986007457A1 (en) * | 1985-06-13 | 1986-12-18 | The British Petroleum Company P.L.C. | Method of diamond identification |
WO1987003963A1 (en) * | 1985-12-19 | 1987-07-02 | The British Petroleum Company P.L.C. | Method for assessing diamond quality |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1547371A (en) * | 1975-01-03 | 1979-06-13 | De Beers Cons Mines Ltd | Diamond identification |
DE2935812A1 (en) * | 1979-09-05 | 1981-03-12 | Fa. Carl Zeiss, 7920 Heidenheim | METHOD FOR TESTING MATERIAL |
FR2571144B1 (en) * | 1984-10-01 | 1986-12-19 | Centre Nat Rech Scient | DEVICE IN PARTICULAR FOR MULTI-MEASUREMENT FOR REMOTE AND IN SITU ANALYSIS OF A SAMPLE BY RAMAN SPECTROMETRY |
-
1987
- 1987-03-18 GB GB878706422A patent/GB8706422D0/en active Pending
-
1988
- 1988-03-10 KR KR1019880701445A patent/KR890700818A/en not_active Application Discontinuation
- 1988-03-10 JP JP63502237A patent/JPH01503561A/en active Pending
- 1988-03-10 DE DE883890288T patent/DE3890288T1/en not_active Withdrawn
- 1988-03-10 EP EP88902180A patent/EP0305440A1/en not_active Withdrawn
- 1988-03-10 GB GB8824662A patent/GB2219392B/en not_active Expired - Fee Related
- 1988-03-10 NL NL8820132A patent/NL8820132A/en unknown
- 1988-03-10 WO PCT/GB1988/000188 patent/WO1988007189A1/en not_active Application Discontinuation
- 1988-03-10 US US07/275,145 patent/US4900147A/en not_active Expired - Fee Related
- 1988-03-10 AU AU13923/88A patent/AU604866B2/en not_active Ceased
- 1988-03-10 BR BR888806080A patent/BR8806080A/en unknown
- 1988-03-14 IN IN161/MAS/88A patent/IN170639B/en unknown
- 1988-03-16 ZA ZA881881A patent/ZA881881B/en unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3947120A (en) * | 1973-10-23 | 1976-03-30 | Yeda Research And Development Co. Ltd. | Gem identification |
US4030827A (en) * | 1973-12-03 | 1977-06-21 | Institut National De La Sante Et De La Recherche Medicale (Inserm) | Apparatus for the non-destructive examination of heterogeneous samples |
FR2496888A1 (en) * | 1980-12-22 | 1982-06-25 | Gemological Lab Antwerp | Automatic grading system for precious stones - comprises electronic weighing platform and laser optics and analysis equipment providing inputs for processor to resolve characteristics |
WO1986007457A1 (en) * | 1985-06-13 | 1986-12-18 | The British Petroleum Company P.L.C. | Method of diamond identification |
WO1987003963A1 (en) * | 1985-12-19 | 1987-07-02 | The British Petroleum Company P.L.C. | Method for assessing diamond quality |
Non-Patent Citations (1)
Title |
---|
Physical Review B, vol. 1, no. 4, 15 February 1970, (New York, US) S.A. Solin et al.: "Raman spectrum of diamond" pages 1687-1698 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5835200A (en) * | 1990-04-24 | 1998-11-10 | Gersan Establishment | Method and apparatus for examining an object |
US5505313A (en) * | 1991-02-20 | 1996-04-09 | Gersan Establishment | Method and apparatus for detecting diamonds in a plurality of objects |
US5628410A (en) * | 1991-02-20 | 1997-05-13 | Gersan Establishment | Classifying or sorting |
Also Published As
Publication number | Publication date |
---|---|
GB2219392A (en) | 1989-12-06 |
NL8820132A (en) | 1989-02-01 |
EP0305440A1 (en) | 1989-03-08 |
GB8706422D0 (en) | 1987-04-23 |
DE3890288T1 (en) | 1989-03-23 |
GB8824662D0 (en) | 1989-01-05 |
ZA881881B (en) | 1989-11-29 |
US4900147A (en) | 1990-02-13 |
KR890700818A (en) | 1989-04-27 |
IN170639B (en) | 1992-04-25 |
AU604866B2 (en) | 1991-01-03 |
AU1392388A (en) | 1988-10-10 |
GB2219392B (en) | 1991-06-26 |
BR8806080A (en) | 1989-10-31 |
JPH01503561A (en) | 1989-11-30 |
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