WO1990008020A1 - Process of producing a wood-plastic agglomerate and use thereof - Google Patents

Process of producing a wood-plastic agglomerate and use thereof Download PDF

Info

Publication number
WO1990008020A1
WO1990008020A1 PCT/SE1990/000014 SE9000014W WO9008020A1 WO 1990008020 A1 WO1990008020 A1 WO 1990008020A1 SE 9000014 W SE9000014 W SE 9000014W WO 9008020 A1 WO9008020 A1 WO 9008020A1
Authority
WO
WIPO (PCT)
Prior art keywords
plastic
wood waste
agglomerate
wood
added
Prior art date
Application number
PCT/SE1990/000014
Other languages
French (fr)
Inventor
Raimo Wuorela
Jan Erik Jansson
Original Assignee
Replast Vojens A/S
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Replast Vojens A/S filed Critical Replast Vojens A/S
Publication of WO1990008020A1 publication Critical patent/WO1990008020A1/en
Priority to NO91912691A priority Critical patent/NO912691L/en
Priority to FI913317A priority patent/FI913317A0/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
    • B27N3/08—Moulding or pressing
    • B27N3/28—Moulding or pressing characterised by using extrusion presses
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
    • B27N1/00—Pretreatment of moulding material
    • B27N1/02—Mixing the material with binding agent
    • B27N1/0209—Methods, e.g. characterised by the composition of the agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00—Compositions of lignin-containing materials
    • C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse

Definitions

  • the present invention relates to a process of pro ⁇ ducing an agglomerate of wood waste and plastic, as well as a use of this agglomerate for injection moulding or extrusion of products.
  • 5 GB-1,443,194 discloses a method for producing a product of wood waste and plastic, the wood waste and the plastic being intermixed simultaneously with the ac ⁇ tual injection moulding. The plastic and the wood waste are dosed directly into the injection moulding machine, Q and the wood waste is dried in connection therewith, so as not to form lumps and thus give an inhomogeneous pro ⁇ duct.
  • DE-2,305,150 also discloses a method for producing a product of wood waste and plastic, a mixture of dry saw- 5 dust and plastic being injection moulded to form various components. These methods have the disadvantage of requir ⁇ ing several dosing devices, as well as a drying device. The direct dosage also entails that the end product may become inhomogeneous. Q Therefore, there is need for a simple and economical process of producing a homogeneous wood-plastic material. Summary of the invention
  • the object of the present invention is to provide a process of producing an agglomerate of wood waste and 5 plastic, resulting in an extremely homogeneous end pro ⁇ duct.
  • Another object of the invention is to provide a pro ⁇ cess of producing an agglomerate which, in a simple and convenient manner, can be further worked, e.g. by injec ⁇ tion moulding, into various products.
  • the process according to the invention is charac ⁇ terised in that the plastic is decomposed into smaller frac ⁇ tions, or is supplied in a decomposed state, that the decomposed plastic is comminuted while being subjected to frictional heat, that moist wood waste is added during said comminu ⁇ tion, so that a mixture is formed, that this mixture is agglomerated, and that the agglomerate is recovered.
  • the agglomerate according to the invention is in ⁇ tended to be used in injection moulding, extrusion or other types of moulding, for the production of various products.
  • the invention thus provides a process of producing an agglomerate of wood waste and plastic, which may then be used as such for injection moulding or the like of various end products.
  • the moisture in the wood waste is used to bring about an agglomeration, and by admixing the wood waste during the actual agglome- ration a very homogeneous product is obtained.
  • the resulting agglomerate renders the injection moulding simpler and more economical than be ⁇ fore.
  • an agglo ⁇ merating device which chiefly comprises an upright cylindrical container with knives rotating at high speed at the bottom and, optionally, further knives fixedly mounted on the cylinder walls.
  • the agglomerating device is fed at the top and emptied at the bottom.
  • Agglomerating devices are, for example, available from REG-MAC s.r.l., Legnano, Italy.
  • the plastic film is manually fed into the cylindrical container where it is cut into strips by the rapidly ro ⁇ tating knives, at the same time as it is thrown towards the periphery of the container.
  • the rotation of the knives and also of the plastic particles generates frictional heat, and when the material has been reduced to a certain size, the temperature increases to a level at which the material begins to melt.
  • the moist wood waste is added. Due to the water in the wood waste, the melting process is inter ⁇ rupted, such that the heated plastic is cooled and con ⁇ tracts into so-called agglomerates, i.e. the wood waste and the plastic agglomerate. The cooling and the continued rotation of the knives cause the water in the wood waste to evaporate in the form of water vapour. Thus, the wood waste is dried and thoroughly mixed with the plastic. Most of the wood waste is enclosed in the agglomerate par ⁇ ticles, resulting in a very homogeneous and shelf-stable product. The degree of melting of the plastic can be checked visually through the feed opening at the top of the con ⁇ tainer.
  • the time required for the process depends on the amount of moisture to be evaporated from the wood waste, and this amount of moisture is a function of, inter alia, the size of the whole charge, the mixing ratios of sawdust and plastic, and the moisture content of the sawdust.
  • the size and appearance of the agglomerate depends, inter alia, on the temperature of the plastic when the moist wood waste is added, and on the types of plastic and addi- tives that are used.
  • the consistency and the dry content of the mixture can also be checked visually.
  • the container is emptied of the mixture which, by centrifugal action, is thrown out through the discharge opening of the agglomerating device to a receptacle from which it is conducted to a storage silo. Then, the agglomerate is ready for use in injection moulding or other types of moulding of sundry products. Naturally, the agglomerate may also be conducted directly to an injection moulding machine or the like.
  • the wood waste employed may be sawdust, wood flour, wooden chips, shavings, or a mixture thereof, and it should have a particle size of 0.02-10 mm, preferably 2-3 mm.
  • a suitable wood waste is sawdust, for example from a saw mill or other wood-working industry.
  • the wood waste should have a moisture content of 5-45% by weight, suitably 10-40% by weight, and most preferably 15-25% by weight.
  • the plastic employed is preferably a thermoplastic, such a HD, LD, MD polyethylene, polypropylene, or polyvinyl chloride plastic, or mixtures thereof.
  • a preferred ther ⁇ moplastic is polyethylene.
  • the agglomerate according to the invention may con ⁇ tain 5-90% by weight plastic and 95-10% by weight wood waste, suitably 40-60% by weight plastic and 60-40% by weight wood waste.
  • the plastic employed may consist of waste raw material of mixed quality and varying purity; a product which today often is destroyed or dumped.
  • plastic additives such as plasticisers
  • plasticisers may be added to or form part of the raw material employed.
  • the agglomerate may be used for producing injection moulded and extruded products, such as mouldings in the furniture and wood-working industries, and for manufactur ⁇ ing bobbins/sleeves.
  • the agglomerate according to the invention can be used as such or worked into a granulate.
  • Products formed from the agglomerate as such, or from a granulate produced thereof may replace, within the fur ⁇ niture and wood-working industries, parts of wood or par- ticle board components, and in doing so reduce the problem of gases emanating from phenolic resin glue etc.
  • the springiness and flexibility of these products also provide substantial advantages for the designer.
  • Such a product is moisture-resistant, it can be used for manufacturing bobbins/sleeves and, for example, window frames, which is very advantageous as to storage possibilities and weatherproofness.
  • a product formed of the agglomerate according to the invention may be lacquered, glued and coloured throughout, and it may also be worked in known wood-working machines.
  • the product is formable after heating and dimensionally stable after cooling.
  • Example 1 50 kg LD polyethylene film (suitable for recycling) is charged into an agglomerating device of the type desig ⁇ nated REG-MAC 430T manufactured by REG-MAX s.r.l., Legnano, Italy.
  • the polyethylene film is ground for about 4 min. in the agglomerating device and has, at that time, a temperature of about 125°C.
  • 50 kg 3-millimetre sawdust having a moisture content of 20% is added.
  • the mixture is agglomerated for 2-3 min. until no visible va ⁇ pour departs from the agglomerating device.
  • the re ⁇ sulting agglomerate is discharged at an end temperature of 80°C.
  • Example 2 50 kg polypropylene is charged into an agglomerating device identical with the one in Example 1, and is ground for 5 min. At this point, the propylene plastic has a tem- perature of about 130°C. Then, 60 kg wood flour (25 mesh) with a moisture content of 20% is added, and this mixture is agglomerated for 3 min. Then, the resulting agglomerate is discharged at an end temperature of 80°C.

Abstract

A process of producing an agglomerate of wood waste and plastic in which the plastic is decomposed into smaller fractions or is supplied in decomposed state, whereupon the decomposed plastic is comminuted and molten under the action of frictional heat, moist wood waste is added, the mixture is agglomerated, and the resulting agglomerate is recovered.

Description

PROCESS OF PRODUCING A WOOD-PLASTIC AGGLOMERATE
AND USE THEREOF
Field of the invention
The present invention relates to a process of pro¬ ducing an agglomerate of wood waste and plastic, as well as a use of this agglomerate for injection moulding or extrusion of products. 0 Prior art
It is known to injection mould plastic components, and it has also been tried to admix, for example, saw¬ dust or other wood waste to the plastic, above all in order to reduce the production costs. 5 GB-1,443,194 discloses a method for producing a product of wood waste and plastic, the wood waste and the plastic being intermixed simultaneously with the ac¬ tual injection moulding. The plastic and the wood waste are dosed directly into the injection moulding machine, Q and the wood waste is dried in connection therewith, so as not to form lumps and thus give an inhomogeneous pro¬ duct.
DE-2,305,150 also discloses a method for producing a product of wood waste and plastic, a mixture of dry saw- 5 dust and plastic being injection moulded to form various components. These methods have the disadvantage of requir¬ ing several dosing devices, as well as a drying device. The direct dosage also entails that the end product may become inhomogeneous. Q Therefore, there is need for a simple and economical process of producing a homogeneous wood-plastic material. Summary of the invention
The object of the present invention is to provide a process of producing an agglomerate of wood waste and 5 plastic, resulting in an extremely homogeneous end pro¬ duct. Another object of the invention is to provide a pro¬ cess of producing an agglomerate which, in a simple and convenient manner, can be further worked, e.g. by injec¬ tion moulding, into various products. The process according to the invention is charac¬ terised in that the plastic is decomposed into smaller frac¬ tions, or is supplied in a decomposed state, that the decomposed plastic is comminuted while being subjected to frictional heat, that moist wood waste is added during said comminu¬ tion, so that a mixture is formed, that this mixture is agglomerated, and that the agglomerate is recovered. The agglomerate according to the invention is in¬ tended to be used in injection moulding, extrusion or other types of moulding, for the production of various products.
The invention thus provides a process of producing an agglomerate of wood waste and plastic, which may then be used as such for injection moulding or the like of various end products. According to the invention, the moisture in the wood waste is used to bring about an agglomeration, and by admixing the wood waste during the actual agglome- ration a very homogeneous product is obtained.
Furthermore, the resulting agglomerate renders the injection moulding simpler and more economical than be¬ fore.
Detailed description of the invention In the process according to the invention, an agglo¬ merating device is used which chiefly comprises an upright cylindrical container with knives rotating at high speed at the bottom and, optionally, further knives fixedly mounted on the cylinder walls. The agglomerating device is fed at the top and emptied at the bottom. Agglomerating devices are, for example, available from REG-MAC s.r.l., Legnano, Italy. The plastic film is manually fed into the cylindrical container where it is cut into strips by the rapidly ro¬ tating knives, at the same time as it is thrown towards the periphery of the container. The rotation of the knives and also of the plastic particles generates frictional heat, and when the material has been reduced to a certain size, the temperature increases to a level at which the material begins to melt.
At this stage, the moist wood waste is added. Due to the water in the wood waste, the melting process is inter¬ rupted, such that the heated plastic is cooled and con¬ tracts into so-called agglomerates, i.e. the wood waste and the plastic agglomerate. The cooling and the continued rotation of the knives cause the water in the wood waste to evaporate in the form of water vapour. Thus, the wood waste is dried and thoroughly mixed with the plastic. Most of the wood waste is enclosed in the agglomerate par¬ ticles, resulting in a very homogeneous and shelf-stable product. The degree of melting of the plastic can be checked visually through the feed opening at the top of the con¬ tainer. The time required for the process depends on the amount of moisture to be evaporated from the wood waste, and this amount of moisture is a function of, inter alia, the size of the whole charge, the mixing ratios of sawdust and plastic, and the moisture content of the sawdust. The size and appearance of the agglomerate depends, inter alia, on the temperature of the plastic when the moist wood waste is added, and on the types of plastic and addi- tives that are used.
The consistency and the dry content of the mixture can also be checked visually. When the air in the con¬ tainer is deemed to be sufficiently dry, suitably when all visible vapour has departed, the container is emptied of the mixture which, by centrifugal action, is thrown out through the discharge opening of the agglomerating device to a receptacle from which it is conducted to a storage silo. Then, the agglomerate is ready for use in injection moulding or other types of moulding of sundry products. Naturally, the agglomerate may also be conducted directly to an injection moulding machine or the like. The wood waste employed may be sawdust, wood flour, wooden chips, shavings, or a mixture thereof, and it should have a particle size of 0.02-10 mm, preferably 2-3 mm. A suitable wood waste is sawdust, for example from a saw mill or other wood-working industry. At the time of agglomeration, the wood waste should have a moisture content of 5-45% by weight, suitably 10-40% by weight, and most preferably 15-25% by weight. The plastic employed is preferably a thermoplastic, such a HD, LD, MD polyethylene, polypropylene, or polyvinyl chloride plastic, or mixtures thereof. A preferred ther¬ moplastic is polyethylene.
The agglomerate according to the invention may con¬ tain 5-90% by weight plastic and 95-10% by weight wood waste, suitably 40-60% by weight plastic and 60-40% by weight wood waste.
Advantageously, the plastic employed may consist of waste raw material of mixed quality and varying purity; a product which today often is destroyed or dumped.
Conventional plastic additives, such as plasticisers, may be added to or form part of the raw material employed. The agglomerate may be used for producing injection moulded and extruded products, such as mouldings in the furniture and wood-working industries, and for manufactur¬ ing bobbins/sleeves. The agglomerate according to the invention can be used as such or worked into a granulate.
Products formed from the agglomerate as such, or from a granulate produced thereof, may replace, within the fur¬ niture and wood-working industries, parts of wood or par- ticle board components, and in doing so reduce the problem of gases emanating from phenolic resin glue etc. The springiness and flexibility of these products also provide substantial advantages for the designer.
Since such a product is moisture-resistant, it can be used for manufacturing bobbins/sleeves and, for example, window frames, which is very advantageous as to storage possibilities and weatherproofness.
A product formed of the agglomerate according to the invention may be lacquered, glued and coloured throughout, and it may also be worked in known wood-working machines. The product is formable after heating and dimensionally stable after cooling.
The process according to the invention is illustrated by the following, nonrestrictive Examples. Example 1 50 kg LD polyethylene film (suitable for recycling) is charged into an agglomerating device of the type desig¬ nated REG-MAC 430T manufactured by REG-MAX s.r.l., Legnano, Italy. The polyethylene film is ground for about 4 min. in the agglomerating device and has, at that time, a temperature of about 125°C. Then, 50 kg 3-millimetre sawdust having a moisture content of 20% is added. The mixture is agglomerated for 2-3 min. until no visible va¬ pour departs from the agglomerating device. Then, the re¬ sulting agglomerate is discharged at an end temperature of 80°C.
Example 2
50 kg polypropylene is charged into an agglomerating device identical with the one in Example 1, and is ground for 5 min. At this point, the propylene plastic has a tem- perature of about 130°C. Then, 60 kg wood flour (25 mesh) with a moisture content of 20% is added, and this mixture is agglomerated for 3 min. Then, the resulting agglomerate is discharged at an end temperature of 80°C.

Claims

1. A process of producing an agglomerate of wood waste and plastic, c h a r a c t e r i s e d in that the plastic is decomposed into smaller frac¬ tions, or is supplied in a decomposed state, that the decomposed plastic is comminuted while being subjected to frictional heat, that moist wood waste is added during said comminu¬ tion so that a mixture is formed, that this mixture is agglomerated, and that the agglomerate is recovered.
2. Process as claimed in claim 1, c h a r a c - t e r i s e d in that the added wood waste has a moisture content of 5-45% by weight, suitably 10-40% by weight, and especially 15-25% by weight.
3. Process as claimed in claim 1 or 2, c h a r a c ¬ t e r i s e d in that the added wood waste has a particle size of 0.02-10 mm, preferably 2-3 mm.
4. Process as claimed in claim 3, c h a r a c ¬ t e r i s e d in that the added wood waste is sawdust, wood flour, wooden chips, shavings, or mixtures thereof.
5. Process as claimed in any one of claims 1-4, c h a r a c t e r i s e d in that the plastic employed is a thermoplastic, such as LD, HD, or MD polyethylene, polypropylene, polyvinyl chloride plastic, or mixtures thereof.
6. Process as claimed in any one of claims 1-5, c h a r a c t e r i s e d in that the added wood waste amounts to 10-95% by weight of the total mixture, the ba¬ lance being plastic.
7. Process as claimed in claim 6, c h a r a c ¬ t e r i s e d in that the added wood waste amounts to 40-60% by weight of the total mixture.
8. Process as claimed in any one of claims 1-7, c h a r a c t e r i s e d in that the plastic employed is polyethylene, and the wood waste employed is sawdust.
9. Use of an agglomerate of wood waste and plastic, to mould a product by injection moulding, extrusion, or the like.
10. Use of an agglomerate of wood waste and plastic, to mould a granulate which, by injection moulding, extru¬ sion, or the like, is further worked into a product.
PCT/SE1990/000014 1989-01-10 1990-01-10 Process of producing a wood-plastic agglomerate and use thereof WO1990008020A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
NO91912691A NO912691L (en) 1989-01-10 1991-07-09 PROCEDURE FOR THE PREPARATION OF A TREE PLASTIC AGGLOMERATOGUE USING THEREOF.
FI913317A FI913317A0 (en) 1989-01-10 1991-07-09 FOERFARANDE FOER FRAMSTAELLNING AV TRAE-PLAST-AGGLOMERAT, SAMT ANVAENDNING DAERAV.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE8900052A SE463547B (en) 1989-01-10 1989-01-10 PROCEDURES FOR THE PREPARATION OF AN AGGLOMERATED SUBSTANCE OF TREE WASTE AND THERMOPLASTIC PLASTICS, AND APPLICATION THEREOF
SE8900052-5 1989-01-10

Publications (1)

Publication Number Publication Date
WO1990008020A1 true WO1990008020A1 (en) 1990-07-26

Family

ID=20374697

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/SE1990/000014 WO1990008020A1 (en) 1989-01-10 1990-01-10 Process of producing a wood-plastic agglomerate and use thereof

Country Status (5)

Country Link
EP (1) EP0473580A1 (en)
AU (1) AU4836490A (en)
FI (1) FI913317A0 (en)
SE (1) SE463547B (en)
WO (1) WO1990008020A1 (en)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0490017A1 (en) * 1989-06-08 1992-06-17 Woodfoot Oy Method for the production of press-formed objects
WO1992011987A1 (en) * 1991-01-08 1992-07-23 3P Consulting Inc. Manufacture of molded composite products from scrap plastics
EP0586213A1 (en) * 1992-09-01 1994-03-09 Andersen Corporation Polymer and wood fibre composite structural member
DE4415851A1 (en) * 1994-05-05 1995-11-09 Ljudmila Olegovna Dr In Bunina Wood chip prods. useful for prodn. of e.g. chipboard for high strength
WO1996013551A1 (en) * 1994-10-31 1996-05-09 Tower Technologies (Proprietary) Limited Method of preparing a lignocellulosic material for the manufacture of a finished product
GB2309699A (en) * 1996-02-02 1997-08-06 Ecobloc Ltd Constructional materials containing plastics and waste naterial
WO2001021367A1 (en) * 1999-09-22 2001-03-29 Sd-Konsult Stein Fr. Dietrichson Construction material comprising recycled pvb (polyvinyl butyral)
US6344504B1 (en) * 1996-10-31 2002-02-05 Crane Plastics Company Limited Partnership Extrusion of synthetic wood material
US6585452B1 (en) * 2002-06-27 2003-07-01 Rexius Forest By-Products, Inc. Organic composition for erosion control and barrier formation
US7713460B2 (en) 1995-04-27 2010-05-11 Tech-Wood International Ltd. Method and apparatus for manufacturing of plastic-based composite product
US7913960B1 (en) 2007-08-22 2011-03-29 The Crane Group Companies Limited Bracketing system
US8074339B1 (en) 2004-11-22 2011-12-13 The Crane Group Companies Limited Methods of manufacturing a lattice having a distressed appearance
US9109118B2 (en) 2008-01-15 2015-08-18 RheTech, Inc. Cellulosic inclusion thermoplastic composition and molding thereof
USD782698S1 (en) 2005-11-30 2017-03-28 Cpg International Llc Rail
WO2017207869A1 (en) * 2016-05-30 2017-12-07 Kompotek Oy Method and apparatus for treating a starting material

Citations (2)

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GB984170A (en) * 1962-06-21 1965-02-24 Conway Dolman Ltd Improvements in or relating to chipboard
US3671615A (en) * 1970-11-10 1972-06-20 Reynolds Metals Co Method of making a composite board product from scrap materials

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Publication number Priority date Publication date Assignee Title
GB984170A (en) * 1962-06-21 1965-02-24 Conway Dolman Ltd Improvements in or relating to chipboard
US3671615A (en) * 1970-11-10 1972-06-20 Reynolds Metals Co Method of making a composite board product from scrap materials

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Title
PATENT ABSTRACTS OF JAPAN, Vol 9, No 152, M391, Abstract of JP 60- 30304, publ 1985-02-15 (KOUBUNSHI GIKEN K.K.). *

Cited By (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0490017A1 (en) * 1989-06-08 1992-06-17 Woodfoot Oy Method for the production of press-formed objects
WO1992011987A1 (en) * 1991-01-08 1992-07-23 3P Consulting Inc. Manufacture of molded composite products from scrap plastics
EP0586213A1 (en) * 1992-09-01 1994-03-09 Andersen Corporation Polymer and wood fibre composite structural member
DE4415851A1 (en) * 1994-05-05 1995-11-09 Ljudmila Olegovna Dr In Bunina Wood chip prods. useful for prodn. of e.g. chipboard for high strength
WO1996013551A1 (en) * 1994-10-31 1996-05-09 Tower Technologies (Proprietary) Limited Method of preparing a lignocellulosic material for the manufacture of a finished product
US7713460B2 (en) 1995-04-27 2010-05-11 Tech-Wood International Ltd. Method and apparatus for manufacturing of plastic-based composite product
GB2309699A (en) * 1996-02-02 1997-08-06 Ecobloc Ltd Constructional materials containing plastics and waste naterial
US6344504B1 (en) * 1996-10-31 2002-02-05 Crane Plastics Company Limited Partnership Extrusion of synthetic wood material
WO2001021367A1 (en) * 1999-09-22 2001-03-29 Sd-Konsult Stein Fr. Dietrichson Construction material comprising recycled pvb (polyvinyl butyral)
US6585452B1 (en) * 2002-06-27 2003-07-01 Rexius Forest By-Products, Inc. Organic composition for erosion control and barrier formation
US8074339B1 (en) 2004-11-22 2011-12-13 The Crane Group Companies Limited Methods of manufacturing a lattice having a distressed appearance
USD788329S1 (en) 2005-11-30 2017-05-30 Cpg International Llc Post cover
US9822547B2 (en) 2005-11-30 2017-11-21 Cpg International Llc Rail system and method for assembly
USD782698S1 (en) 2005-11-30 2017-03-28 Cpg International Llc Rail
USD782697S1 (en) 2005-11-30 2017-03-28 Cpg International Llc Rail
USD784559S1 (en) 2005-11-30 2017-04-18 Cpg International Llc Rail
USD785199S1 (en) 2005-11-30 2017-04-25 Cpg International Llc Rail
USD787707S1 (en) 2005-11-30 2017-05-23 Cpg International Llc Rail
US10358841B2 (en) 2005-11-30 2019-07-23 Cpg International Llc Rail system and method for assembly
USD797307S1 (en) 2005-11-30 2017-09-12 Cpg International Llc Rail assembly
USD797953S1 (en) 2005-11-30 2017-09-19 Cpg International Llc Rail assembly
USD809157S1 (en) 2005-11-30 2018-01-30 Cpg International Llc Rail
USD807527S1 (en) 2005-11-30 2018-01-09 Cpg International Llc Rail
US7913960B1 (en) 2007-08-22 2011-03-29 The Crane Group Companies Limited Bracketing system
US9109118B2 (en) 2008-01-15 2015-08-18 RheTech, Inc. Cellulosic inclusion thermoplastic composition and molding thereof
WO2017207869A1 (en) * 2016-05-30 2017-12-07 Kompotek Oy Method and apparatus for treating a starting material
RU2736209C2 (en) * 2016-05-30 2020-11-12 Компопат Ой Method and apparatus for processing feed material

Also Published As

Publication number Publication date
SE8900052A (en) 1989-01-10
AU4836490A (en) 1990-08-13
SE8900052D0 (en) 1989-01-10
FI913317A0 (en) 1991-07-09
EP0473580A1 (en) 1992-03-11
SE463547B (en) 1990-12-10

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