WO1991004766A1 - Fire extinguishing composition and process - Google Patents
Fire extinguishing composition and process Download PDFInfo
- Publication number
- WO1991004766A1 WO1991004766A1 PCT/US1990/005506 US9005506W WO9104766A1 WO 1991004766 A1 WO1991004766 A1 WO 1991004766A1 US 9005506 W US9005506 W US 9005506W WO 9104766 A1 WO9104766 A1 WO 9104766A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- hcfc
- chloro
- hfc
- hexafluoropropane
- pentafluoropropane
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0071—Foams
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0028—Liquid extinguishing substances
- A62D1/0057—Polyhaloalkanes
Definitions
- This invention relates to compositions for use in preventing and extinguishing fires based on the combustion of combustible materials. More particularly, it relates to such compositions that are "safe / to use — as safe for humans as currently used extinguishants but absolutely safe for the environment. Specifically, the compositions of this invention have little or no effect on the ozone layer depletion process; and make no or very little contribution to the global warming process known as the "greenhouse effect , . Although these compositions have minimal effect in these areas, they are extremely effective in preventing and extinguishing fires, particularly fires in enclosed spaces.
- halogenated hydrocarbon fire extinguishing agents are currently preferred. These halogenated hydrocarbon fire extinguishing agents are not only effective for such fires, but also cause little, if any, damage to the room or its contents. This contrasts to the well-known • "water damage” that can sometimes exceed the fire damage when the customary water pouring process is used.
- the halogenated hydrocarbon fire extinguishing agents that are currently most popular are the bromine-containing halocarbons, e.g. bromotrifluoromethane (CF ⁇ Br, Halon 1301) and bromochlorodifluoromethane (CF 2 ClBr, Halon 1211) . It is believed that these bromine-containing fire extinguishing agents are highly effective in extinguishing fires in progress because, at the elevated temperatures involved in the combustion, these compounds decompose to form products containing bromine atoms which effectively interfere with the self-sustaining free radical combustion process and, thereby, extinguish the fire. These bromine-containing halocarbons may be dispensed from portable equipment or from an automatic room flooding system activated by a fire detector.
- bromine-containing halocarbons may be dispensed from portable equipment or from an automatic room flooding system activated by a fire detector.
- Patent 3,844,354 Larsen suggests the use of chloropentafluoroethane (CF 3 -CF 2 CI) in a total flooding system (TFS) to extinguish fires in a fixed enclosure, the chloropentafluoroethane being introduced into the fixed enclosure to maintain its concentration at less than 15%.
- TFS total flooding system
- Huggett discloses creating an atmosphere in a fixed enclosure which is habitable but, at the same time, does not sustain combustion. Huggett provides an atmosphere consisting essentially of air, a perfluorocarbon selected from carbon tetrafluoride, hexafluoroethane, octafluoropropane and mixtures thereof and make-up oxygen, as required.
- bromine- containing halocarbons such as Halon 1301 can be used to provide a habitable atmosphere that will not support combustion.
- the high cost due to bromine content and the toxicity to humans i.e. cardiac sensitization at relatively low levels make the bromine- containing materials unattractive for long term use.
- bromine-containing halocarbons such as Halon 1301 and Halon 1211 are at least as active as chlorofluorocarbons in the ozone layer depletion process.
- perfluorocarbons such as those suggested by Huggett, cited above, are believed not to have as much effect upon the ozone depletion process as chlorofluorocarbons, their extraordinarily high stability makes them suspect in another environmental area, that of "greenhouse effect". This effect is caused by accumulation of gases that provide a shield against heat transfer and results in the undesirable warming of the earth's surface.
- the present invention is based on the finding that an effective amount of a composition consisting essentially of at least one fluoro-partially substituted ethane selected from the group of pentafluoroethane (CF 3 -CHF 2 ) , also known as FC-125, and the tetrafluoroethanes (CHF 2 -CHF2 and CF 3 -CH2F) , also known as FC-134 and FC-134a, will prevent and/or extinguish fire based on the combustion of combustible materials, particularly in an enclosed space, without adversely affecting the atmosphere from the standpoint of toxicity to humans, ozone depletion or "greenhouse effect".
- the trifluoromethane may be used in conjunction with as little as 1% of at least one halogenated hydrocarbon selected from the group of difluoromethane (HFC-32) , chlorodifluoromethane (HCFC-22) , 2,2-dichloro-l,1,1-trifluoroethane HCFC-123) , 1,2-dichloro-l,1,2-trifluoroethane (HCFC-123a) , 2-chloro-l,1,1,2-tetrafluoroethane (HCFC-124) , l-chloro-1,1,2,2-tetrafluoroethane (HCFC-124a) , pentafluoroethane (HFC-125) , 1,1,2,2-tetrafluoroethane (HFC-134) , 1,1,1,2-tetrafluoroethane (HFC-134a) ,
- the invention would comprise a habitable atmosphere, which does not sustain combustion of combustible materials of the non-self-sustaining type, i.e.
- a material which does not contain an oxidizer component capable of supporting combustion, and which is capable of sustaining mammalian life consisting essentially of (a) air; (b) the fluoroethane (FC125, 134 and/or 134a) in an amount sufficient to suppress combustion of the combustible materials present in an enclosed compartment containing said atmosphere; and, optionally if necessary, (c) make-up oxygen in an amount from zero to the amount required to provide, together with the oxygen in the air, sufficient total oxygen to sustain mammalian life.
- the invention also comprises a process for preventing and controlling fire in an enclosed air- containing mammalian-habitable compartment which contains combustible materials of the non self- containing type which consists essentially of:
- the tri-fluoroalkane, CHF 3 when added in adequate amounts to the air in a confined space, eliminates the combustion-sustaining properties of the air and suppresses the combustion of flammable materials, such as paper, cloth, wood, flammable liquids, and plastic items, which may be present in the enclosed compartment, without detriment to normal mammalian activities.
- Tri-fluoromethane is extremely stable and chemically inert. CHF 3 does not decompose at temperatures as high as 400°C to produce corrosive or toxic products and cannot be ignited even in pure oxygen so that they continue to be effective as a flame suppressant at the ignition temperatures of the combustible items present in the compartment. CHF 3 is also physiologically inert.
- Tri-fluoromethane is additionally advantageous because of its low boiling points, i.e. a boiling point at normal atmospheric pressure of 82.1°C. Thus, at any low environmental temperature likely to be encountered, this gas will not liquefy and will not, thereby, diminish the fire preventive properties of the modified air. In fact, any material having such a low boiling point would be suitable as a refrigerant.
- Tri-fluoromethane is also characterized by an extremely low boiling point and a high vapor pressure, i.e. about 635 psig at 21°C. This permits CHF 3 to act as its own propellant in "hand-held” fire extinguishers. It may also be used with other materials such as those disclosed on pages 5 and 6 of this specification to act as the propellant and co-extinguishant for these materials of lower vapor pressure. Its lack of toxicity (comparable to nitrogen) and its short atmospheric lifetime (with little effect on the global warming potential) compared to the perfluoroalkanes (with lifetimes of over 500 years) make CHF 3 ideal for this portable fire-extinguisher use.
- the trifluoromethane may comprise anywhere from 0.5 weight percent to 99 weight percent of the mixture with one or more of the compounds listed on pages 5 and 6.
- the trifluoromethane acts as its own propellant, of course, it comprises 100% of the propellant-extinguisher mixture.
- the gas should be added in an amount which will impart to the modified air a heat capacity per mole of total oxygen present, including any make-up oxygen required, sufficient to suppress or prevent combustion of the flammable, non-self-sustaining materials present in the enclosed environment.
- the quantity of CHF 3 required to suppress combustion is sufficiently low as to eliminate the requirement for make-up oxygen.
- the minimum heat capacity required to suppress combustion varies with the combustibility of the particular flammable materials present in the confined space. It is well known that the combustibility of materials, namely their capability for igniting and maintaining sustained combustion under a given set of environmental conditions, varies according to chemical composition and certain physical properties, such as surface area relative to volume, heat capacity, porosity, and the like. Thus, thin, porous paper such as tissue paper is considerably more combustible than a block of wood.
- a heat capacity of about 40 cal./°C and constant pressure per mole of oxygen is more than adequate to prevent or suppress the combustion of materials of relatively moderate combustibility, such as wood and plastics. More combustible materials, such as paper, cloth, and some volatile flammable liquids, generally require that the CHF 3 be added in an amount sufficient to impart a higher heat capacity. It is also desirable to provide an extra margin of safety by imparting a heat capacity in excess of minimum requirements for the particular flammable materials. A minimum heat capacity of 45 cal./°C per mole of oxygen is generally adequate for moderately combustible materials and a minimum of about 50 cal./°C per mole of oxygen for highly flammable materials. More can be added if desired but, in general, an amount imparting a heat capacity higher than about 55 cal./°C per mole of total oxygen adds substantially to the cost and may create unnecessary physical discomfort without any substantial further increase in the fire safety factor.
- Heat capacity per mole of total oxygen can be determined by the formula:
- Cp* total heat capacity per mole of oxygen at constant pressure
- CHF 3 is not toxic at concentration up to about 80%.
- the concentration of oxygen available in the confined air space should be sufficient to sustain mammalian life.
- the amount of make-up oxygen, if required, is determined by such factors as degree of air dilution by the CHF 3 gas and depletion of the available oxygen in the air by human respiration.
- the amount of oxygen required to sustain human, and therefore mammalian life in general, at atmospheric, subatmospheric, and superatmospheric pressures, is well known and the necessary data are readily available. See, for example, Paul Webb, Bioastronautics Data Book, NASA SP-3006, National Aeronautics and Space Administration, 1964, p. 5.
- the minimum oxygen partial pressure is considered to be about 1.8 p.s.i.a., with amounts above 8.2 p.s.i.a. causing oxygen toxicity.
- the unimpaired performance zone is in the range of about 16 to 36 volume percent of oxygen.
- the normal amount of oxygen maintained in a confined space is about 16% to about 21% at normal atmospheric pressure.
- CHF 3 gas and any oxygen are easily provided for by metering appropriate quantities of the gas or gases into the enclosed air-containing compartment.
- the air in the compartment can be treated at any time that it appears desirable.
- the modified air can be used continuously if a threat of fire is constantly present or the particular environment is such that fire hazard must be kept at an absolute minimum, or it can be used as an emergency measure if a threat of fire develops.
- small amounts of one or more of the compounds set forth on pages 5 and 6 may be used along with the CHF 3 gas without upsetting the mammalian habitability or losing the other advantages of the CHF 3 .
- Example - 1014 grams of HCFC-123 was added to a container serving as an extinguisher. The container was then pressurized to 150 psig (equivalent to the Control) with 108.5 grams of CHF 3 . Thus, the extinguisher contained 90.3% HCFC-123 and 9.7% CHF 3 .
- CHF 3 as a propellant for portable fire extinguishers at an initial pressure of 150 psig (approximately 10.5 bars)
- lower pressures can be used.
- room temperature (20°C) it would not be advisable to pressurize the extinguisher with CHF 3 above 2.5 bars for a glass container, nor above 4.5 bars for one composed of tin.
- the starting weight percent of the CHF 3 propellant in the example was about 10%, anywhere from 0.5 to 100 weig ⁇ ft percent of CHF 3 may be used in this invention.
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU66199/90A AU656516B2 (en) | 1989-10-04 | 1990-10-03 | Fire extinguishing composition and process |
CA002067385A CA2067385C (en) | 1989-10-04 | 1990-10-03 | Fire extinguishing composition and process |
DE69024226T DE69024226T3 (en) | 1989-10-04 | 1990-10-03 | FIRE-FIGHTING COMPOSITION AND METHOD |
BR909007709A BR9007709A (en) | 1989-10-04 | 1990-10-03 | COMPOSITION AND FLAME EXTINGUISHING PROCESS |
EP90916214A EP0494987B2 (en) | 1989-10-04 | 1990-10-03 | Fire extinguishing composition and process |
SU905011275A RU2066560C1 (en) | 1989-10-04 | 1990-10-03 | Method for suppression of fire in closed air space inhabited with mammals (version) |
KR1019920700759A KR100281657B1 (en) | 1989-10-04 | 1990-10-03 | Digestive Compositions and Methods |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/417,654 US5040609A (en) | 1989-10-04 | 1989-10-04 | Fire extinguishing composition and process |
US417,654 | 1989-10-04 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1991004766A1 true WO1991004766A1 (en) | 1991-04-18 |
Family
ID=23654874
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1990/005506 WO1991004766A1 (en) | 1989-10-04 | 1990-10-03 | Fire extinguishing composition and process |
Country Status (16)
Country | Link |
---|---|
US (1) | US5040609A (en) |
EP (2) | EP0494987B2 (en) |
JP (1) | JP3558629B2 (en) |
KR (2) | KR100281657B1 (en) |
CN (1) | CN1051126A (en) |
AT (1) | ATE131396T1 (en) |
AU (1) | AU656516B2 (en) |
BR (1) | BR9007709A (en) |
CA (1) | CA2067385C (en) |
DE (1) | DE69024226T3 (en) |
ES (1) | ES2082011T5 (en) |
GR (1) | GR900100731A (en) |
MX (1) | MX169125B (en) |
RU (1) | RU2066560C1 (en) |
WO (1) | WO1991004766A1 (en) |
ZA (1) | ZA907929B (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0460992A1 (en) * | 1990-06-08 | 1991-12-11 | Elf Atochem S.A. | Use of a halogenoalkane-based composition as a fire-extinguishing agent |
EP0481618A1 (en) * | 1990-10-15 | 1992-04-22 | Imperial Chemical Industries Plc | Fire extinguishing compositions |
EP0562396A1 (en) * | 1992-03-24 | 1993-09-29 | Solvay Fluor und Derivate GmbH | Trifluoromethane-containing compositions and their use as expanding agent |
EP0562756A1 (en) * | 1992-03-21 | 1993-09-29 | Kidde-Graviner Limited | Fire extinguishing and explosion suppression substances |
EP0570367A1 (en) † | 1989-11-14 | 1993-11-24 | E.I. Du Pont De Nemours And Company | Fire extinguishing composition and process |
EP0617983A1 (en) * | 1993-03-31 | 1994-10-05 | Jan Andersson | Gas mixture |
US6182768B1 (en) | 1992-02-05 | 2001-02-06 | Halotron, Inc. | Gas-liquid mixture as well as fire-extinguishing unit and method for the use thereof |
US7151197B2 (en) | 2001-09-28 | 2006-12-19 | Great Lakes Chemical Corporation | Processes for purifying chlorofluorinated compounds and processes for purifying CF3CFHCF3 |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5141654A (en) * | 1989-11-14 | 1992-08-25 | E. I. Du Pont De Nemours And Company | Fire extinguishing composition and process |
FR2662945B1 (en) * | 1990-06-08 | 1995-03-24 | Atochem | USE OF A HYDROGENOFLUOROALKANE AS AN EXTINGUISHING AGENT. |
US5232618A (en) * | 1991-09-30 | 1993-08-03 | E. I. Du Pont De Nemours And Company | Substantially constant boiling compositions of difluoromethane and trifluoroethane or perfluoroethane |
US5759430A (en) * | 1991-11-27 | 1998-06-02 | Tapscott; Robert E. | Clean, tropodegradable agents with low ozone depletion and global warming potentials to protect against fires and explosions |
JP2714486B2 (en) * | 1993-03-02 | 1998-02-16 | イー・アイ・デュポン・ドゥ・ヌムール・アンド・カンパニー | Composition containing hexafluoropropane |
US5611210A (en) * | 1993-03-05 | 1997-03-18 | Ikon Corporation | Fluoroiodocarbon blends as CFC and halon replacements |
US5340490A (en) * | 1993-07-14 | 1994-08-23 | Alliedsignal Inc. | Azeotrope-like compositions of trifluoromethane and carbon dioxide or hexafluoroethane and carbon dioxide |
ES2079933T3 (en) * | 1993-08-24 | 1996-01-16 | Anlagen Und Reaktorsicherheit | ARRANGEMENT FOR THE PASSIVE INERTIZATION OF THE GAS MIXTURE IN THE SAFETY VESSEL OF A NUCLEAR POWER PLANT. |
US6548471B2 (en) | 1995-01-20 | 2003-04-15 | 3M Innovative Properties Company | Alkoxy-substituted perfluorocompounds |
US5718293A (en) * | 1995-01-20 | 1998-02-17 | Minnesota Mining And Manufacturing Company | Fire extinguishing process and composition |
US5925611A (en) | 1995-01-20 | 1999-07-20 | Minnesota Mining And Manufacturing Company | Cleaning process and composition |
US6506459B2 (en) | 1995-01-20 | 2003-01-14 | 3M Innovative Properties Company | Coating compositions containing alkoxy substituted perfluoro compounds |
JP3783047B2 (en) | 1995-12-15 | 2006-06-07 | スリーエム カンパニー | Cleaning method and composition |
ES2230125T5 (en) | 1999-07-20 | 2016-10-04 | 3M Innovative Properties Company | Use of fluorinated ketones in fire extinguishing compositions |
US6685764B2 (en) | 2000-05-04 | 2004-02-03 | 3M Innovative Properties Company | Processing molten reactive metals and alloys using fluorocarbons as cover gas |
US6780220B2 (en) * | 2000-05-04 | 2004-08-24 | 3M Innovative Properties Company | Method for generating pollution credits while processing reactive metals |
US7223351B2 (en) * | 2003-04-17 | 2007-05-29 | Great Lakes Chemical Corporation | Fire extinguishing mixtures, methods and systems |
US7537007B2 (en) * | 2003-05-01 | 2009-05-26 | Joseph Michael Bennett | Method of inerting high oxygen concentrations |
US20050038302A1 (en) * | 2003-08-13 | 2005-02-17 | Hedrick Vicki E. | Systems and methods for producing fluorocarbons |
CN104801001B (en) * | 2014-01-24 | 2018-10-26 | 上海汇友精密化学品有限公司 | A kind of mixture extinguishing chemical and its application |
RU2629559C1 (en) * | 2016-10-24 | 2017-08-30 | Российская Федерация, от имени которой выступает Государственная корпорация по атомной энергии "Росатом" | Additive to fuel |
Citations (4)
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US4233177A (en) * | 1977-07-30 | 1980-11-11 | Von Treu Ag | Propellant of reduced combustibility |
US4234432A (en) * | 1977-10-26 | 1980-11-18 | Energy And Minerals Research Co. | Powder dissemination composition |
US4446923A (en) * | 1979-04-30 | 1984-05-08 | Walter Kidde & Co., Inc. | Removal of explosive or combustible gas or vapors from tanks and other enclosed spaces |
US4807706A (en) * | 1987-07-31 | 1989-02-28 | Air Products And Chemicals, Inc. | Breathable fire extinguishing gas mixtures |
Family Cites Families (9)
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US446923A (en) * | 1891-02-24 | Burnish ing-machine | ||
US1926395A (en) * | 1930-07-31 | 1933-09-12 | Frigidaire Corp | Process of preventing fire by nontoxic substances |
US3840667A (en) * | 1968-06-12 | 1974-10-08 | Atlantic Res Corp | Oxygen-containing atmospheres |
US3715438A (en) * | 1970-07-22 | 1973-02-06 | Susquehanna Corp | Habitable combustion-suppressant atmosphere comprising air,a perfluoroalkane and optionally make-up oxygen |
US3844354A (en) * | 1973-07-11 | 1974-10-29 | Dow Chemical Co | Halogenated fire extinguishing agent for total flooding system |
JPS5878677A (en) * | 1981-11-04 | 1983-05-12 | 藤増 次郎 | Composite chemical fire fighting agent |
AU629975B2 (en) * | 1989-08-21 | 1992-10-15 | Great Lakes Chemical Corporation | Fire extinguishing methods and blends utilizing hydrofluorocarbons |
US5135054A (en) * | 1990-10-05 | 1992-08-04 | University Of New Mexico | Fire extinguishing agents for flooding applications |
JP3558630B2 (en) * | 1990-11-15 | 2004-08-25 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | Fire protection method and fire protection composition |
-
1989
- 1989-10-04 US US07/417,654 patent/US5040609A/en not_active Expired - Lifetime
-
1990
- 1990-10-03 GR GR900100731A patent/GR900100731A/en unknown
- 1990-10-03 RU SU905011275A patent/RU2066560C1/en active
- 1990-10-03 AT AT90916214T patent/ATE131396T1/en not_active IP Right Cessation
- 1990-10-03 JP JP51496690A patent/JP3558629B2/en not_active Expired - Lifetime
- 1990-10-03 CA CA002067385A patent/CA2067385C/en not_active Expired - Lifetime
- 1990-10-03 CN CN90109138A patent/CN1051126A/en active Pending
- 1990-10-03 AU AU66199/90A patent/AU656516B2/en not_active Ceased
- 1990-10-03 ES ES90916214T patent/ES2082011T5/en not_active Expired - Lifetime
- 1990-10-03 EP EP90916214A patent/EP0494987B2/en not_active Expired - Lifetime
- 1990-10-03 BR BR909007709A patent/BR9007709A/en not_active IP Right Cessation
- 1990-10-03 WO PCT/US1990/005506 patent/WO1991004766A1/en active IP Right Grant
- 1990-10-03 KR KR1019920700759A patent/KR100281657B1/en not_active IP Right Cessation
- 1990-10-03 DE DE69024226T patent/DE69024226T3/en not_active Expired - Lifetime
- 1990-10-03 EP EP93120845A patent/EP0592019A1/en not_active Ceased
- 1990-10-04 ZA ZA907929A patent/ZA907929B/en unknown
- 1990-10-04 MX MX022693A patent/MX169125B/en unknown
-
1992
- 1992-01-20 KR KR1019920000759A patent/KR930016336A/en not_active Application Discontinuation
Patent Citations (4)
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US4233177A (en) * | 1977-07-30 | 1980-11-11 | Von Treu Ag | Propellant of reduced combustibility |
US4234432A (en) * | 1977-10-26 | 1980-11-18 | Energy And Minerals Research Co. | Powder dissemination composition |
US4446923A (en) * | 1979-04-30 | 1984-05-08 | Walter Kidde & Co., Inc. | Removal of explosive or combustible gas or vapors from tanks and other enclosed spaces |
US4807706A (en) * | 1987-07-31 | 1989-02-28 | Air Products And Chemicals, Inc. | Breathable fire extinguishing gas mixtures |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0570367A1 (en) † | 1989-11-14 | 1993-11-24 | E.I. Du Pont De Nemours And Company | Fire extinguishing composition and process |
EP0570367B2 (en) † | 1989-11-14 | 2004-12-29 | E.I. Du Pont De Nemours And Company | A method for preventing a fire |
EP0460992A1 (en) * | 1990-06-08 | 1991-12-11 | Elf Atochem S.A. | Use of a halogenoalkane-based composition as a fire-extinguishing agent |
EP0481618A1 (en) * | 1990-10-15 | 1992-04-22 | Imperial Chemical Industries Plc | Fire extinguishing compositions |
US6182768B1 (en) | 1992-02-05 | 2001-02-06 | Halotron, Inc. | Gas-liquid mixture as well as fire-extinguishing unit and method for the use thereof |
US6267788B1 (en) | 1992-02-05 | 2001-07-31 | Halotron, Inc. | Gas-Liquid mixture as well as fire-extinguishing unit and method for the use thereof |
EP0562756A1 (en) * | 1992-03-21 | 1993-09-29 | Kidde-Graviner Limited | Fire extinguishing and explosion suppression substances |
EP0562396A1 (en) * | 1992-03-24 | 1993-09-29 | Solvay Fluor und Derivate GmbH | Trifluoromethane-containing compositions and their use as expanding agent |
EP0617983A1 (en) * | 1993-03-31 | 1994-10-05 | Jan Andersson | Gas mixture |
US7151197B2 (en) | 2001-09-28 | 2006-12-19 | Great Lakes Chemical Corporation | Processes for purifying chlorofluorinated compounds and processes for purifying CF3CFHCF3 |
Also Published As
Publication number | Publication date |
---|---|
ATE131396T1 (en) | 1995-12-15 |
KR930016336A (en) | 1993-08-26 |
BR9007709A (en) | 1992-11-17 |
EP0494987B1 (en) | 1995-12-13 |
ES2082011T3 (en) | 1996-03-16 |
CA2067385C (en) | 2004-12-28 |
KR100281657B1 (en) | 2001-02-15 |
CN1051126A (en) | 1991-05-08 |
DE69024226T3 (en) | 2000-02-03 |
MX169125B (en) | 1993-06-22 |
JPH05500920A (en) | 1993-02-25 |
JP3558629B2 (en) | 2004-08-25 |
DE69024226D1 (en) | 1996-01-25 |
KR920703155A (en) | 1992-12-17 |
EP0494987B2 (en) | 1999-07-21 |
US5040609A (en) | 1991-08-20 |
EP0592019A1 (en) | 1994-04-13 |
EP0494987A4 (en) | 1992-05-14 |
EP0494987A1 (en) | 1992-07-22 |
GR900100731A (en) | 1992-03-20 |
AU6619990A (en) | 1991-04-28 |
ZA907929B (en) | 1992-06-24 |
ES2082011T5 (en) | 1999-11-01 |
CA2067385A1 (en) | 1991-04-05 |
AU656516B2 (en) | 1995-02-09 |
RU2066560C1 (en) | 1996-09-20 |
DE69024226T2 (en) | 1996-07-18 |
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