WO1991016159A1 - Composite casting process - Google Patents

Composite casting process Download PDF

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Publication number
WO1991016159A1
WO1991016159A1 PCT/EP1991/000668 EP9100668W WO9116159A1 WO 1991016159 A1 WO1991016159 A1 WO 1991016159A1 EP 9100668 W EP9100668 W EP 9100668W WO 9116159 A1 WO9116159 A1 WO 9116159A1
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WO
WIPO (PCT)
Prior art keywords
casting
metal
preform
molten
casting process
Prior art date
Application number
PCT/EP1991/000668
Other languages
French (fr)
Inventor
Bernd Otte
Rudolf Schwarz
Original Assignee
Alcan Deutschland Gmbh
Alcan International Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6404342&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO1991016159(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Alcan Deutschland Gmbh, Alcan International Limited filed Critical Alcan Deutschland Gmbh
Priority to AT91907583T priority Critical patent/ATE97039T1/en
Priority to DE91907583T priority patent/DE69100631T2/en
Publication of WO1991016159A1 publication Critical patent/WO1991016159A1/en
Priority to US07/941,055 priority patent/US5381850A/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D19/00—Casting in, on, or around objects which form part of the product
    • B22D19/14—Casting in, on, or around objects which form part of the product the objects being filamentary or particulate in form

Definitions

  • the invention relates to a composite casting process for making castings consisting in particular of light metal alloys reinforced by inserts, for example, of fiber-shaped or open-pored materials or the like, in particular, motor parts such as pistons, cylinders, cylinder heads and motor blocks of internal combustion engines, for example, in which process, firstly, a preform reinforced by the insert or inserts is made by embedding and/or the penetration of the insert(s) or an insert bundle, for example a fiber bundle, in molten matrix metal or by a molten matrix meta] and subsequently solidifying it, then immersing it in a molten metal bath and subsequently inserting it into a casting mould for integrally casting or casting around the final casting.
  • a preform reinforced by the insert or inserts is made by embedding and/or the penetration of the insert(s) or an insert bundle, for example a fiber bundle, in molten matrix metal or by a molten matrix meta] and subsequently solidifying it, then immersing it in a molten
  • Such a composite casting process is known from DE-PS- 27 01 421 and DE-OS-35 11 542.
  • This known processing method is particularly useful for the manufacture of larger and complicatedly structured fiber-reinforced castings and enables the required orientation of the fibers or whiskers to the main loading direction in the casting which is to be manufactured to be carried out in a manner relatively simple.
  • the fiber or whisker reinforced preform must be made in a special casting process in which the matrix metal of the preform is forced into the fiber or whisker bundle at a controlled filling speed and at an exactly dosed pressure in order to ensure a faultless wetting of each individual fiber or whisker as well as the formation of a gap free substance-locked bond and/or force-locked composite action between the fiber or whisker material and the matrix metal.
  • the matrix metal is then allowed to solidify.
  • the subsequent integral casting or casting around of the final casting to or around the preform can then result by means of a simple casting process.
  • the casting of the entire, final casting by means of the specialized casting process necessary for the manufacture of the preform will not be useful for the manufacture of larger and complicatedly structured castings as the required casting device would be too complicated and the casting parameters hardly controllable.
  • the preform to be inserted into the casting mould is as a rule covered on its surface by an oxide skin which hinders or renders impossible a gapless metallurgical bond with the metal integrally cast or cast around.
  • the preform In order to have any chance at all of the formation of a metallurgical bond of the preform with the metal integrally cast or cast around, the preform must be inserted into the casting mould preheated to a relatively high temperature, which results in an increase in the oxide skin occuring on its surface.
  • only an intensive flowing around of the preform with the integrally cast or cast around metal can lead to an oxide free bond.
  • the preform is submerged into a melt of a lead alloy heated to 150°C - 400 C C before its insertion into the casting mould in order to release its oxide skin.
  • the lead alloy which adheres in this case is provided to prevent the renewed formation of an oxide layer on the metal surface of the preform prior to the integral casting or casting around of the final casting.
  • this known process has the disadvantage that the alloy elements of the lead melt enter into the bond layer between the precast and the integrally cast or cast around metal and can have an unforeseeable influence in this layer on the properties of the layer and under circumstances, even on the whole, final casting.
  • the preheating transmitted to the preform by a lead melt heated to only 150 - 400°C is as a rule not sufficient to ensure the complete bond of the preform with the integrally cast or cast around metal.
  • the melting regions of aluminium casting alloys lie between 540°C and 600°C.
  • a preform placed in the casting mould at a substantially lower temperature leads to the melt of the integrally cast or cast around solidifying immediately at the boundary surface to the preform so that the formation of a gapless metallurigal bond between this metal and the preform cannot be ensured in a sufficiently reliable manner.
  • the insert or the insert bundle in the preform such as, for example, a fiber bundle or an open-pored foamed body, in connection with the adhesion and cohesion forces of the matrix metal surrounding each fiber or the structure of the foamed material or the like, provides the entire composite of the preform with a sufficient stability for its conveyance into the casting mould and its subsequent integral casting or casting around.
  • This surprising stability goes so far that the preform can be subjected to a rotating or reciprocating movement in the molten metal bath in order to wash its surface free from adhering oxides without it disintegrating in the molten metal bath.
  • the insert or the insert bundle itself is composed in such a manner as to be able to withstand the thermic and chemical conditions during the immersion step.
  • This bond stability of the preform also in the substantially or entirely molten condition of its matrix metal is surprising, as one has assumed up to now that the softening or melting of the preform is to be avoided in every case for stability reasons.
  • the preform pretreated in accordance with the invention has after its transfer into the casting mould a temperature which still lies close to the casting temperature of the integrally cast or cast around metal, as the melting heat of the matrix metal in the preform prevents its quick recooling to below the melting temperature.
  • the oxide skin unavoidably forming on the molten surface of the preform after its removal from the molten metal bath can be easily washed off by the flow of the casting metal during the integral casting or casting around process so that a clean bondage of the molten alloys in the matrix, the surface layer and the casting metal can be achieved with the greatest possible certainty without disturbing alloy elements being drawn into this composite.
  • the integral casting into the final casting of the pretreated preform reinforced by the inserts can result by means of any desired casting process such as sand casting, chill casting, low-pressure casting or pressure casting and the variants thereof in accordance with the inventive composite casting process.
  • an aluminium-silicon-alloy for example, G Al Si 12 Cu Ni Mg, can be used as the integrally cast or cast around metal.
  • the insert or the insert bundle can be impregnated under pressure with the matrix metal and be embedded in this metal during the manufacture of the preform in such a manner that its volume amounts to at least 10% of the entire volume of the preform.
  • an insert of, for example, open-pored foamed graphite, foamed ceramic, foamed metal or the like or a fiber bundle can be used, the fibers of which, for example, consist of the predominant amount, as for example 95%, of aluminium oxide (A1 2 0_) and of smaller amounts, as for example 5%, of silicon oxide (SiO_).
  • the matrix metal of the preform can be aluminium with a melting point of ca. 660°C.
  • an aluminium-silicon-alloy such as AlSilO can be used which can be brought up to a bath temperature of over 700°C, preferably approximately 780°C.
  • the preform can be immersed in accordance with its size for one or several minutes until it has been fully heated throughout.
  • the matrix metal of the preform is completely or substantially in a molten state after its immersion bath treatment, like the casting, the preform is subjected to normal solidification shrinkage during the solidification of the entire, final casting.
  • precautions are to be taken in the casting mould by means of which the matrix metal in the insert body or in the insert bundle or the like are included in the controlled solidification progression of the final casting.

Abstract

Composite casting process for making castings, consisting in particular of light metal alloys reinforced by fiber or foamed material inserts, in particular motor parts such as pistons, cylinders, cylinder heads and motor blocks of internal combustion engines. In this process, firstly, a preform reinforced by the fiber or foamed material inserts is made by embedding and the penetration of a fiber bundle or a foamed material body in molten matrix metal or by a molten matrix metal and subsequently solidifying it. Then, the preform is immersed in a molten metal bath and subsequently inserted into a casting mould for integrally casting or casting around the final casting. In accordance with the invention, the preform is immersed into a molten metal bath which consists of the same or a similar metal or the same or similar metal alloy as the matrix metal of the preform or the metal used for integral casting or casting around the final casting and which is heated to a temperature which is higher than the melting point of the matrix material.

Description

Composite Casting Process
The invention relates to a composite casting process for making castings consisting in particular of light metal alloys reinforced by inserts, for example, of fiber-shaped or open-pored materials or the like, in particular, motor parts such as pistons, cylinders, cylinder heads and motor blocks of internal combustion engines, for example, in which process, firstly, a preform reinforced by the insert or inserts is made by embedding and/or the penetration of the insert(s) or an insert bundle, for example a fiber bundle, in molten matrix metal or by a molten matrix meta] and subsequently solidifying it, then immersing it in a molten metal bath and subsequently inserting it into a casting mould for integrally casting or casting around the final casting.
Such a composite casting process is known from DE-PS- 27 01 421 and DE-OS-35 11 542. This known processing method is particularly useful for the manufacture of larger and complicatedly structured fiber-reinforced castings and enables the required orientation of the fibers or whiskers to the main loading direction in the casting which is to be manufactured to be carried out in a manner relatively simple.
Therefore, the fiber or whisker reinforced preform must be made in a special casting process in which the matrix metal of the preform is forced into the fiber or whisker bundle at a controlled filling speed and at an exactly dosed pressure in order to ensure a faultless wetting of each individual fiber or whisker as well as the formation of a gap free substance-locked bond and/or force-locked composite action between the fiber or whisker material and the matrix metal. The matrix metal is then allowed to solidify. The subsequent integral casting or casting around of the final casting to or around the preform can then result by means of a simple casting process. The casting of the entire, final casting by means of the specialized casting process necessary for the manufacture of the preform will not be useful for the manufacture of larger and complicatedly structured castings as the required casting device would be too complicated and the casting parameters hardly controllable.
The initially described known composite casting process is, however, equally not without problems. Thus, the preform to be inserted into the casting mould is as a rule covered on its surface by an oxide skin which hinders or renders impossible a gapless metallurgical bond with the metal integrally cast or cast around. In order to have any chance at all of the formation of a metallurgical bond of the preform with the metal integrally cast or cast around, the preform must be inserted into the casting mould preheated to a relatively high temperature, which results in an increase in the oxide skin occuring on its surface. Thus, only an intensive flowing around of the preform with the integrally cast or cast around metal can lead to an oxide free bond.
In order to achieve such a faultless bond, in the known process according to DE-OS 35 11 542, the preform is submerged into a melt of a lead alloy heated to 150°C - 400CC before its insertion into the casting mould in order to release its oxide skin. The lead alloy which adheres in this case is provided to prevent the renewed formation of an oxide layer on the metal surface of the preform prior to the integral casting or casting around of the final casting. However, this known process has the disadvantage that the alloy elements of the lead melt enter into the bond layer between the precast and the integrally cast or cast around metal and can have an unforeseeable influence in this layer on the properties of the layer and under circumstances, even on the whole, final casting. Additionally, the preheating transmitted to the preform by a lead melt heated to only 150 - 400°C is as a rule not sufficient to ensure the complete bond of the preform with the integrally cast or cast around metal.
The melting regions of aluminium casting alloys lie between 540°C and 600°C. A preform placed in the casting mould at a substantially lower temperature leads to the melt of the integrally cast or cast around solidifying immediately at the boundary surface to the preform so that the formation of a gapless metallurigal bond between this metal and the preform cannot be ensured in a sufficiently reliable manner.
It is therefore an object of the invention to ensure in a simple a manner as possible, a gapless, acceptable metallurgical bond between the preform and the integrally cast or cast around metal in a composite casting process of the type initially revealed. This is achieved in accordance with the invention in that the preform is immersed prior to its insertion into the casting mould into a molten metal bath which consists of the same or a similar metal or the same or similar metal alloy as the matrix metal of the preform or the metal used for the final casting and which is heated to a temperature which is higher than the melting point of the matrix material. With this, it is taken into account that the matrix metal of the preform in the melt bath is at least substantially molten. However, the invention is based en the - -
recognition that in this case, the insert or the insert bundle in the preform such as, for example, a fiber bundle or an open-pored foamed body, in connection with the adhesion and cohesion forces of the matrix metal surrounding each fiber or the structure of the foamed material or the like, provides the entire composite of the preform with a sufficient stability for its conveyance into the casting mould and its subsequent integral casting or casting around. This surprising stability goes so far that the preform can be subjected to a rotating or reciprocating movement in the molten metal bath in order to wash its surface free from adhering oxides without it disintegrating in the molten metal bath. It is naturally a prequisite that the insert or the insert bundle itself is composed in such a manner as to be able to withstand the thermic and chemical conditions during the immersion step. This bond stability of the preform also in the substantially or entirely molten condition of its matrix metal is surprising, as one has assumed up to now that the softening or melting of the preform is to be avoided in every case for stability reasons.
The preform pretreated in accordance with the invention has after its transfer into the casting mould a temperature which still lies close to the casting temperature of the integrally cast or cast around metal, as the melting heat of the matrix metal in the preform prevents its quick recooling to below the melting temperature.
The oxide skin unavoidably forming on the molten surface of the preform after its removal from the molten metal bath can be easily washed off by the flow of the casting metal during the integral casting or casting around process so that a clean bondage of the molten alloys in the matrix, the surface layer and the casting metal can be achieved with the greatest possible certainty without disturbing alloy elements being drawn into this composite.
The integral casting into the final casting of the pretreated preform reinforced by the inserts can result by means of any desired casting process such as sand casting, chill casting, low-pressure casting or pressure casting and the variants thereof in accordance with the inventive composite casting process. With this, an aluminium-silicon-alloy, for example, G Al Si 12 Cu Ni Mg, can be used as the integrally cast or cast around metal.
The insert or the insert bundle can be impregnated under pressure with the matrix metal and be embedded in this metal during the manufacture of the preform in such a manner that its volume amounts to at least 10% of the entire volume of the preform. For the preform, an insert of, for example, open-pored foamed graphite, foamed ceramic, foamed metal or the like or a fiber bundle can be used, the fibers of which, for example, consist of the predominant amount, as for example 95%, of aluminium oxide (A120_) and of smaller amounts, as for example 5%, of silicon oxide (SiO_). The matrix metal of the preform can be aluminium with a melting point of ca. 660°C.
For the immersion melt bath, for example, an aluminium-silicon-alloy such as AlSilO can be used which can be brought up to a bath temperature of over 700°C, preferably approximately 780°C. In this melt bath, the preform can be immersed in accordance with its size for one or several minutes until it has been fully heated throughout. s the matrix metal of the preform is completely or substantially in a molten state after its immersion bath treatment, like the casting, the preform is subjected to normal solidification shrinkage during the solidification of the entire, final casting. In order to avoid the occurance of shrinkage cavities within the casting, precautions are to be taken in the casting mould by means of which the matrix metal in the insert body or in the insert bundle or the like are included in the controlled solidification progression of the final casting.

Claims

Claims
1. Composite casting process for making castings consisting in particular of light metal alloys reinforced by inserts, for example, of fiber-shaped or open-pored materials or the like, in particular, motor parts such as pistons, cylinders, cylinder heads and motor blocks of internal combustion engines, for example, in which process, firstly, a preform reinforced by the insert or inserts is made by embedding and/or the penetration of the insert(s) or an insert bundle, for example a fiber bundle, in molten matrix metal or by a molten matrix metal and subsequently solidifying it, then immersing it in a molten metal bath and subsequently inserting it into a casting mould for integrally casting or casting around the final casting, characterized in that the preform is immersed into a molten metal bath which consists of the same or a similar metal or the same or similar metal alloy as the matrix metal of the preform or the metal used for the final casting and which is heated to a temperature which is higher than the melting point of the matrix material.
2. Composite casting process according to claim 1, characterized in that the immersion of the preform into the molten metal bath ensues in such a manner that its matrix metal is completely or substantially molten in the bath, and that this preform is subsequently inserted in this molten condition into the casting mould for integrally casting or casting around the final casting.
3. Composite casting process according to claim 1, characterized in that the preform is moved in a rotary or reciprocating manner in the molten metal bath.
4. Composite casting process according to claim 1, characterized in that the insert or the insert bundle is impregnated with matrix metal under pressure and embedded in this metal in such a manner that its volume amounts to least 10% of the total volume of the preform.
5. Composite casting process according to claim 1, characterized in that a fiber bundle is used, the fibers of which consist to the predominating amount, for example 95%, of aluminium oxide (Al20_) and to the lesser amount, for example 5%, of silicon oxide (SiO_) .
6. Composite casting process according to claim 1, characterized in that an insert of open-pored foamed graphite, foamed ceramic, foamed metal or like is used.
7. Composite casting process acording to claim 1, characterized in that the oxide skin forming at the molten surface of the preform to be inserted into the casting mould is washed from the preform in the ensuing integral casting or casting around of the metal of the final casting by the flow of this metal.
8. Composite casting process according to claim 1, characterized in that an aluminium with a melting point of ca. 660°C is used as the matrix material of the preform.
9. Composite casting process according to claim 1, characterized in that an aluminium-silicon-alloy, for example AlSilO, which is raised to a bath temperature of over 700°C, preferably approximately 780°C, is used for the immersion bath melt.
10. Composite casting process according to claim 1, characterized in that the preform is immersed into the molten metal bath for one or several minutes depending on its size until it is completely heated through.
11. Composite casting process according to claim 1, characterized in that the integrally cast or cast around metal consists of an aluminium-silicon-alloy, for example of G Al Si 12 Cu Ni Mg.
PCT/EP1991/000668 1990-04-12 1991-04-09 Composite casting process WO1991016159A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
AT91907583T ATE97039T1 (en) 1990-04-12 1991-04-09 COMPOSITE CASTING PROCESS.
DE91907583T DE69100631T2 (en) 1990-04-12 1991-04-09 COMPOSITE CASTING METHOD.
US07/941,055 US5381850A (en) 1990-04-12 1992-04-09 Composite casting process

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4011948A DE4011948A1 (en) 1990-04-12 1990-04-12 COMPOSITE CASTING PROCESS
DEP4011948.3 1990-04-12

Publications (1)

Publication Number Publication Date
WO1991016159A1 true WO1991016159A1 (en) 1991-10-31

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PCT/EP1991/000668 WO1991016159A1 (en) 1990-04-12 1991-04-09 Composite casting process

Country Status (10)

Country Link
US (1) US5381850A (en)
EP (1) EP0524233B1 (en)
AU (1) AU7667291A (en)
CA (1) CA2080377A1 (en)
CS (1) CS103891A2 (en)
DE (2) DE4011948A1 (en)
ES (1) ES2046052T3 (en)
PT (1) PT97345A (en)
TR (1) TR25639A (en)
WO (1) WO1991016159A1 (en)

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GB2254814A (en) * 1991-04-18 1992-10-21 Gkn Sankey Ltd Reinforced light metal article and method for its production
GB2259878A (en) * 1991-09-25 1993-03-31 Alcon Components Ltd Brake caliper
WO1994009931A1 (en) * 1992-11-04 1994-05-11 Alcan International Limited Process and apparatus for shape casting of particle stabilized metal foam
GB2291370A (en) * 1994-07-20 1996-01-24 Gkn Sankey Ltd Casting around a rigid porous ceramic material
CN109128037A (en) * 2018-07-20 2019-01-04 江苏大学 A kind of composite modified ceramic shell and preparation method thereof

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US5765624A (en) * 1994-04-07 1998-06-16 Oshkosh Truck Corporation Process for casting a light-weight iron-based material
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US5934357A (en) * 1996-11-13 1999-08-10 Aluminum Company Of America System for manufacturing metal matrix composites
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DE19650613B4 (en) * 1996-12-06 2005-12-29 Daimlerchrysler Ag Component with a metal foam core
DE19653149A1 (en) * 1996-12-19 1998-06-25 Bayerische Motoren Werke Ag Workpiece made of a lightweight material and process for producing the workpiece
US5921333A (en) * 1997-08-06 1999-07-13 Naco, Inc. Casting having in-situ cast inserts and method of manufacturing
DE19746164B4 (en) * 1997-10-18 2005-09-15 Volkswagen Ag Composite material with an at least partially hollow profile and use thereof
DE29809241U1 (en) * 1998-05-26 1998-08-27 Benteler Werke Ag Twist beam axle
DE19826848C5 (en) * 1998-06-16 2006-02-23 Borbet Gmbh Alloy wheel for motor vehicles
DE19908867A1 (en) * 1999-03-01 2000-09-07 Arved Huebler Composite body useful in machine construction comprises metal foam and solid parts joined together by a metallurgical bond of fused adjoining material layers
DE10140332C1 (en) * 2001-08-16 2003-04-24 Daimler Chrysler Ag lightweight crankshaft
DE102004039306A1 (en) * 2004-08-12 2006-02-23 Bayerische Motoren Werke Ag Process to manufacture automotive crankcase with embedded supra-eutectic lightweight metal containing silicon
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DE112006003073A5 (en) 2005-09-13 2008-09-11 Ksm Castings Gmbh Subframe, in particular for motor vehicles
US8943663B2 (en) 2009-04-15 2015-02-03 Baker Hughes Incorporated Methods of forming and repairing cutting element pockets in earth-boring tools with depth-of-cut control features, and tools and structures formed by such methods
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2254814A (en) * 1991-04-18 1992-10-21 Gkn Sankey Ltd Reinforced light metal article and method for its production
GB2259878A (en) * 1991-09-25 1993-03-31 Alcon Components Ltd Brake caliper
GB2259878B (en) * 1991-09-25 1995-01-11 Alcon Components Ltd Brake caliper
WO1994009931A1 (en) * 1992-11-04 1994-05-11 Alcan International Limited Process and apparatus for shape casting of particle stabilized metal foam
GB2291370A (en) * 1994-07-20 1996-01-24 Gkn Sankey Ltd Casting around a rigid porous ceramic material
GB2291370B (en) * 1994-07-20 1997-11-12 Gkn Sankey Ltd An article and method for its production
CN109128037A (en) * 2018-07-20 2019-01-04 江苏大学 A kind of composite modified ceramic shell and preparation method thereof

Also Published As

Publication number Publication date
TR25639A (en) 1993-07-01
CS103891A2 (en) 1991-11-12
AU7667291A (en) 1991-11-11
ES2046052T3 (en) 1994-01-16
EP0524233A1 (en) 1993-01-27
CA2080377A1 (en) 1991-10-13
DE69100631D1 (en) 1993-12-16
DE69100631T2 (en) 1994-04-28
US5381850A (en) 1995-01-17
PT97345A (en) 1993-07-30
EP0524233B1 (en) 1993-11-10
DE4011948A1 (en) 1991-10-17

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