WO1992005026A1

WO1992005026A1 - Preform for polyester bottle

Info

Publication number: WO1992005026A1
Application number: PCT/NL1990/000131
Authority: WO
Inventors: Hubertus Mreijen
Original assignee: Wellstar Holding B.V.
Priority date: 1990-09-13
Filing date: 1990-09-13
Publication date: 1992-04-02
Also published as: DE69029402D1; FI922137A; ATE146120T1; CA2068517A1; FI922137A0; NO921867D0; US5976450A; ES2102985T3; EP0504146B1; NO921867L; CA2068517C; EP0504146A1; DE69029402T2; JPH06504961A

Abstract

The invention relates to a preform for a polyester bottle, having applied to its surface a coating of a material that lowers the coefficient of friction of the polyester and to a method of producing a preform for a polyester bottle, provided with a coating of a material that lowers the coefficient of friction of the polyester used, comprising producing a preform by means of extrusion or injection moulding, followed by applying said coating to the preform.

Description

Title: Preform for polyester bottle

This invention relates to a preform for a polyester bottle.

In the manufacture of bottles of polyester, such as polyethylene terephthalate (PET), in principle two different types of production methods can be distinguished. Both methods start from a preform. In the first method such a preform, while still in a warm state, is directly processed by means of blow moulding to form the bottle.

In the second method the preform, after cooling, is stored, transported and the like, to be processed to form the final bottle only at a later stage or elsewhere. This means that the preform is heated to a temperature higher than the glass transition temperature of the polyester and then blown to form the final bottle. This yields a biaxial stretch of the polyester, which is partly responsible for the good properties of the polyester or PET bottle.

In this second method, however, the problem is encountered that during transport, storage, handling and the like, the preforms come into contact with each other and are damaged, at least exhibit scratches at the surface. Such surface defects of the preforms lead to surface defects at the surface of the final bottle as well.

Careful handling of the preforms can prevent the occurrence of such damage, but that is very labour-intensive, and affects the speed of production and the cost price of the bottle.

Accordingly, a method of reducing or even completely preventing such damage has been contemplated.

Surprisingly, it has been found that a very simple treatment renders the preform substantially completely insensitive to surface damage as a result of mutual contact of the preforms.

The invention concerns a preform for a polyester bottle, having applied to its surface a coating of a material that lowers the coefficient of friction of the polyester.

The invention also relates to a method of producing a preform for a polyester, preferably a polyethylene terephthalate, bottle, provided with a coating of a material that lowers the coefficient of friction of the polyester used, comprising the steps of producing a preform by extrusion or injection moulding, followed by applying said coating to said preform.

As a coating various waxlike or fatty materials can be used, but preferably a material is used from the group consisting of polyethylene wax, polypropylene wax, paraffin wax, microcrystalline wax, fats and/or oils, fatty acids and silicone oil. This group of materials gives a good protection and is generally very easy to apply to the surface. Moreover, these materials have been approved for use in food-contact applications, so that no problems need arise on that count either.

The preforms according to the invention have the advantage that when they are processed to form bottles, hardly any surface defects occur, if at all, so that the final bottle has a considerably improved appearance. Moreover, and this is highly unexpected, the coating does not affect the processing or re-processing of the polyester bottle. The coating is easy to apply and very cheap in virtue of its simplicity. Nor does sticking the labels to the bottles present any problems. The coating can be applied to the preform in various manners, for instance by immersing the preform in a bath containing the coating. It is also possible to subject the preform to a spraying treatment with a fluid that contains the coating. Preferably, a bath is used, since the most uniform coating is obtained in that manner.

In a preferred embodiment of the invention the coating is applied in liquid form - namely, as an aqueous emulsion - to the preforms, which may optionally be still warm. The temperature of the preforms and.or the coating fluid is generally between 10 and 75°C. The emulsion to be used is preferably strongly diluted. A suitable solid matter content is between 0.01 and 1% by weight. This is preferred because in that way the desired amount of coating can be controlled optimally.

The application of the emulsion is followed by drying of the preforms. Drying may for instance be effected by external heating of the moist preform. However, it is also possible to subject the preform in a warm state to the treatment, so that the drying is effected by the heat present in the preform. Once dry, the preforms are eminently protected against the occurrence of damage during transport and storage. The amount of coating naturally depends on the total surface area of the preform and on the nature of the coating. The amount of coating in any case varies generally between 0.01 mg and 0.1 g. It is observed that the coating according to the invention cannot be compared with the known coatings on polyester bottles, as described for instance in European patent application 79.215. That application relates to a polyester bottle provided with a vinylidene chloride coating to improve the mechanical properties of the bottle. The present invention does not concern the application of a layer of a protective plastic on the final bottle, but a treatment of the preform to prevent any, particularly visual, defects. Indeed, the present invention does not generally yield a continuous plastic or other coating on the final polyester bottle. The preform according to the invention can be processed in a conventional manner to form bottles both refillable and disposable. The presence of the coating does not have any influence on the processing of the preform during blow moulding. In the conventional manner the preform can be heated to above T_g, for instance by IR heating, and be further processed in the usual manner. The invention will now be illustrated in and by some Examples, without any limitation being intended. Comparative Example

Polyethylene terephthalate preforms were produced by injection moulding of PET in a mould suitable for the purpose. These preforms were transported in the normal manner and packed in boxes for storage and transport. During these operations the surface of the preforms frequently sustained damage. The processing of these preforms to form PET bottles by heating them and blow moulding yielded bottles with many surface defects. Example

By the same method as used in the Comparative Example, preforms were produced. While still warm, these preforms were then sprayed with a 0.5% by weight emulsion of polypropylene wax in water. After drying, the preforms were handled and processed to form bottles in the same manner as in the Comparative Example.

These bottles did not show any trace of surface defects, which could already be observed from the preforms. Nor did the step of forming the bottles present any problems. It should be observed in particular that prolonged processing of coated preforms did not give any problems in the mould, although one would expect the use of a coat on the preform to eventually lead to precipitation in the mould. This in turn is likely to lead to yet other surface defects on the final bottles. Such defects have not been observed.

Claims

C AIMS

1. A preform for a polyester bottle, having applied to its surface a coating of a material that lowers the coefficient of friction of the polyester.

2. A preform according to claim 1, wherein the coating essentially consists of a material chosen from the group consisting of polyethylene wax, polypropylene wax, paraffin wax, microcrystalline wax, fats and/or oils, fatty acids and silicone oil.

3. A preform according to claim 1 or 2, wherein the amount of the coating is between 0.01 mg and 0.1 g.

4. A preform according to claims 1-3, wherein polyethylene terephthalate is chosen as a polyester.

5. A method of producing a preform for a polyester bottle, provided with a coating of a material which lowers the coefficient of friction of the polyester used, comprising producing a preform by extrusion or injection moulding, followed by applying said coating to the preform.

6. A method according to claim 5, wherein the coating is applied by spraying the preform with or immersing the preform in an aqueous emulsion of the coating agent, optionally followed by drying the treated preform.

7. A method according to claim 5 or 6, wherein the coating essentially consists of a material selected from the group consisting of polyethylene wax, polypropylene wax, paraffin wax, microcrystalline wax, fats and/or oils, fatty acids, and Silicone oil.

8. A method according to claims 5-7, wherein the polyester is polyethylene terephthalate.

9. A polyester bottle made from a preform according to claims 1-4 or from a preform manufactured by the method according to claims 5-8.