WO1992013120A1 - Improvements in polyester fibers - Google Patents
Improvements in polyester fibers Download PDFInfo
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- WO1992013120A1 WO1992013120A1 PCT/US1992/000231 US9200231W WO9213120A1 WO 1992013120 A1 WO1992013120 A1 WO 1992013120A1 US 9200231 W US9200231 W US 9200231W WO 9213120 A1 WO9213120 A1 WO 9213120A1
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- filament
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Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/78—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
- D01F6/86—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from polyetheresters
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/253—Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
Definitions
- This invention relates to improvements in polyester fibers, and more particularly to a unique combination of special polymer compositions with fiber cross-section/filament deniers that provide desirable fabric properties heretofore unavailable in fabrics produced of conventional 100% polyester and polyester- rich (i.e., at least 50% polyester) blended fabrics, such aB are suitable for conventional home washing and drying without loss of attractive appearance.
- PET polyethylene terephthalate
- Conventional polyethylene terephthalate (PET) apparel fibers are generally of round cross-section and have many attractive characteristics. These include but are not limited to: good physical properties for processing into fabric and thereafter into wearing apparel good durability after washing/drying by conventional means and good color light fastness.
- rayon f brics have other important disadvantages, e.g., they do not retain their desirable attributes after repeated subjection to conventional home wash/dry cycles, so preservation of such attributes requires that the fabrics and garments be cleaned by professional methods. It has long been desirable to modify conventional polyester fibers, to retain their important advantages, but to impart also some characteristics of new rayon fibers. Some techniques have been suggested to modify polyester polymers (e.g. reduction of polymer viscosity, and incorporation of modifiers, and special treatments) to reduce the tendency of the fabrics to "pill". This has had varying degrees of success with conventional round filament cross-sections. Because use of these modified polymers can lead to undesirable and even excessive spinning discontinuities, however, their use for non-round cross-sections has been more appropriate for high deniers per filament (dpf) that have been unacceptable for usage in apparel.
- dpf high deniers per filament
- Scalloped-oval cross-section ibers produced from conventional polyethylene terephthalate polymers have been used heretofore for specialty areas, e.g. pile fabrics, carpets, paper reinforcement and filters, but the deniers per filament (typically 6 and above) have been higher than what is needed for most apparel applications. Textile deniers of up to 3 dpf have been used, but their pilling performance has inhibited full commercial acceptance.
- the polymer modifier is polyethylene oxide (PEO) of molecular weight in the range 200-2000.
- PEO polyethylene oxide
- the viscosities of the polymers are indicated herein, and correspond to the molecular weights of the polymers.
- the fibers of the invention may be made conveniently by melt spinning and drawing un-delustered modified PET filaments of appropriate viscosity, denier per filament, and cross-section, as disclosed herein-after in the Examples.
- the filaments are generally cut to staple of whatever length is desired for the end-use contemplated, e.g., about 10 to about 100 mm. Deliberately mixed deniers are advantageous, and may be used. It will be understood that both the terms "filament” and “fiber” are used generically herein. While the primary application discussed here is staple, it is believed that continuous filament applications in the form of yarn or tow would provide similar desirable luster benefits when converted into fabrics, woven or knitted.
- Clear polymer means that the fiber is not 15 delustered, that is, contains essentially no added delustering pigment, generally less than 0.005 percent by weight of delusterant (typically titanium dioxide pigment) .
- a molecular weight of 600 for the PEO was 25 used because it was convenient, but may vary from about 200 to about 2000.
- the molecular weight must be high enough to be effective, but low enough to be applied practically. Heat can be used to effectively use a higher molecular weight PEO.
- each of the elements of the present invention namely the selected PET polymer(s) and modifier, the selected viscosity, r the absence of delusterant, the scalloped-oval filament cross-section, and the apparel deniers, 35 have been used separately for various textile and industrial end-uses but have not, so far as we know, been used in the present combination, nor for this purpose, and the results are surprising.
- the invention is further illustrated in the following Examples.
- the PEO was of molecular weight 600.
- the relative viscosity of the polyester was measured essentially as described in Hancock et al. U.S. Patent No. 4,704,329, col. 9, lines 6-11, but on a solution obtained by dissolving 0.80 gram fiber in 10.0 milliliters solvent.
- the DDR (Dye
- a commercial clear PET polymer with essentially no titanium dioxide, but containing 3.9 weight percent of polyethylene oxide (PEO) and 0.175 weight percent trimethylol propane, to provide a relative viscosity of 20.5 was utilized. It was melt spun at 290 C and 102 pounds per hour through a spinneret having 1653 capillaries.
- the capillary orifices were of the general configuration of that shown in Figure 2 of U.S. Patent 4,707,407, with the major axis length being 0.039 inches and the minor axis length being 0.019 inches.
- the filaments were conveniently collected at 1500 yards per minute on individual bobbins using a commercial wind-up device.
- Fiber from the Item 3 was cut to 1 1/2" on a standard cutter, baled and processed on commercial textile machinery to a ring spinning frame.
- the yarn count was 25/1 cc with a 4.0 twist factor.
- the yarn was woven into a 2 X 1 twill fabric on a standard loom using 112 ends per inch on the warp and 58 picks per inch in the fill. This fabric was dyed atmospherically with disperse dyes without carrier for one hour. Commercial fabric softener was applied. Without further treatment, the fabric was tested on the Random Tumble Pill Test Mechanism. After 10 and 60 minutes tumbling, respectively, the pill ratings were 4.2 and 2.6 (higher pill ratings indicating better resistance to pilling) .
- Example 2 The yarn count was 25/1 cc with a 4.0 twist factor.
- the yarn was woven into a 2 X 1 twill fabric on a standard loom using 112 ends per inch on the warp and 58 picks per inch in the fill. This fabric was dyed atmospherically with disperse dye
- Example 1 A commercial polymer similar to that used in Example 1 was melt spun at 285C and 68.5 pounds per hour through spinnerets having 1054 capillaries, but otherwise essentially similarly to Example 1, except that the major axis length for the capillary orifice was 0.030 inches.
- the filaments were conveniently collected at 1500 yards per minute from multiple positions using a commercial device.
- Nine hundred ends were combined as a creel for a commercial drawing machine. They were one-stage drawn, crimped, and relaxed in a hot air dryer. The results of this test are included as Item 1 of Table 2. 2.
- a heavier denier was produced at a spinning rate of 63 pounds per hour using spinneret of 450 capillaries.
- the capillary had the major axis length of 0.039 inches as in Example 1.
- Nine hundred eighty four ends were combined as a creel for a commercial drawing machine. They were one-stage drawn, crimped, and relaxed in a hot air dryer. The results are of this test are included as Item 2 of Table 2.
- Example 3 A commercial polymer similar to that used in Example 1, except for having an relative viscosity of 19.8, was melt spun essentially as in Example 2, except at 292C and 96 pounds per hour through spinnerets having 1653 capillaries into filaments that were conveniently collected at 1421 yards per minute .
- Six hundred thirty ends were combined as a creel for a commercial drawing machine. They were one-stage drawn, crimped, and relaxed in a hot air dryer at 124 C. The results of this test are included as Item 1 of Table 3. 2-3.
- To evaluate relaxation temperature effect on "pill resistance” material that was spun, drawn, and crimped as Item 1 of Table 3 was not allowed to enter the relaxation dryer. It was taken to a laboratory forced convection, hot-air oven, one sample was exposed to 130 C air for 5 minutes, the other to 160 C air for 5 minutes. These results are reported as Items 2 and 3 of Table 3 respectively.
- Filaments from the above four items were randomly selected from the processed but uncut filament bundle. Individual filaments were tested for flex life by being clamped between two bars having a 0.001 inch radius at the point of nip. A dead weight loading of one gram was applied and then the bars were oscillated in a manner calculated to flex the filaments in opposite directions until rupture occurred. This data is reported in the Table 3 as "flex life". A lower flex life indicates that the resistance to pilling is likely to be better.
- the pill ratings were, respectively, for Item 3.1; 4.5 and 4.4, for Item 3.4: 3.8 and 1.6, and more yarns, prepared from item 3 in Example 1, were similarly woven and tested to give RTP ratings, respectively, of 4.5 and 2.6.
- Example 2 A commercial polymer similar to that used in Example 1 (except for relative viscosity of 19.7), was melt spun at 293 C and 75 pounds per hour through spinnerets having 1054 capillaries, using capillary orifices as in Example 2.1. Four hundred forty eight ends were combined as a creel for a commercial drawing machine. They were one-stage drawn, crimped, and relaxed in a hot air dryer at 142 C. The results of this test are shown in Table 4. TABLE 4
- Fiber from Example 1, item 3 was blended 50/50 with combed cotton and ring spun into 28/1 cc. It was knit into a 22 cut Jersey fabric on a commercial machine. The fabric was atmospherically dyed and subjected to the standard Random Tumble Pill test method.
- T-107 W round, 11.5 RV homopolymer
- This comparison fiber was likewise blended 50/50 with combed cotton and ring spun to 28/1 cc. This yarn was knit on the same knitting machine into a 22 cut jersey, dyed with carrier and subjected to the standard Random Tumble Pill test method.
Abstract
Polyester filaments of 0.5 to 3 denier per filament having scalloped-oval cross-section, formed of clear ethylene terephthalate polymers of specified viscosity modified by inclusion of polyethylene oxide, provide fabrics having pleasing luster, greater drapeability, reduced pilling, and low temperature carrier-free dyeing when compared to existing round cross-section 100 % polyester and polyester-rich blended (cotton/wool/rayon/silk) polyester fabrics.
Description
TITLE
IMPROVEMENTS IN POLYESTER FIBERS
This invention relates to improvements in polyester fibers, and more particularly to a unique combination of special polymer compositions with fiber cross-section/filament deniers that provide desirable fabric properties heretofore unavailable in fabrics produced of conventional 100% polyester and polyester- rich (i.e., at least 50% polyester) blended fabrics, such aB are suitable for conventional home washing and drying without loss of attractive appearance.
Conventional polyethylene terephthalate (PET) apparel fibers are generally of round cross-section and have many attractive characteristics. These include but are not limited to: good physical properties for processing into fabric and thereafter into wearing apparel good durability after washing/drying by conventional means and good color light fastness. Some complaints, however, have also been reported in the art with regard to some properties of their fabrics/ garments. These include formation of "pills" upon encountering surface abrasion; unattractive appearance: requirement for super atmospheric pressure dyeing conditions; and fabric stiffness/poor drapeability. In contrast, more desirable fabric/garment properties have been provided when so-called "natural fibers", particularly some rayon types, have been used in apparel fabrics. However, rayon f brics have other important disadvantages, e.g., they do not retain their desirable attributes after repeated subjection to conventional home wash/dry cycles, so preservation of such attributes requires that the fabrics and garments be cleaned by
professional methods. It has long been desirable to modify conventional polyester fibers, to retain their important advantages, but to impart also some characteristics of new rayon fibers. Some techniques have been suggested to modify polyester polymers (e.g. reduction of polymer viscosity, and incorporation of modifiers, and special treatments) to reduce the tendency of the fabrics to "pill". This has had varying degrees of success with conventional round filament cross-sections. Because use of these modified polymers can lead to undesirable and even excessive spinning discontinuities, however, their use for non-round cross-sections has been more appropriate for high deniers per filament (dpf) that have been unacceptable for usage in apparel.
Scalloped-oval cross-section ibers produced from conventional polyethylene terephthalate polymers have been used heretofore for specialty areas, e.g. pile fabrics, carpets, paper reinforcement and filters, but the deniers per filament (typically 6 and above) have been higher than what is needed for most apparel applications. Textile deniers of up to 3 dpf have been used, but their pilling performance has inhibited full commercial acceptance.
Practically all commerical conventional PET apparel fibers of dpf up to about 3 have been delustered, generally with titanium dioxide (Tiθ2) pigment, because this has been considered, in practice, desirable to provide fabrics that are more attractive.
Clear (i.e., un-delustered) polymers have occasionally been used in round cross-section and various deniers per filament for some textile
applications to improve processing, but the resulting fabrics have been considered to have an unattractive luster.
According to the present invention, there is provided a novel combination of selected clear
(i.e., without delusterant) modified polymer with selected filament cross-section that provides fabric properties heretofore unattainable with existing polyester polymer/filament cross-section combinations. The polymer modifier is polyethylene oxide (PEO) of molecular weight in the range 200-2000. The viscosities of the polymers are indicated herein, and correspond to the molecular weights of the polymers. When we use this novel combination of scalloped-oval cross-section with selected clear (un-delustered) polymers (preferably one with enhanced dyeability) , a subtle fabric luster can be achieved similar to that of "natural fiber", without loss of the desirable characteristics which make polyester fiber attractive to the industry. This has been most surprising. The pilling performance has also been most surprising, especially in view of the viscosities of the polymers. The art has taught that low viscosity polymer is desired to improve pilling performance.
The fibers of the invention may be made conveniently by melt spinning and drawing un-delustered modified PET filaments of appropriate viscosity, denier per filament, and cross-section, as disclosed herein-after in the Examples. The filaments are generally cut to staple of whatever length is desired for the end-use contemplated, e.g., about 10 to about 100 mm. Deliberately mixed deniers are advantageous, and may be used. It will
be understood that both the terms "filament" and "fiber" are used generically herein. While the primary application discussed here is staple, it is believed that continuous filament applications in the form of yarn or tow would provide similar desirable luster benefits when converted into fabrics, woven or knitted.
The scalloped-oval cross-section of the filaments has been described in the art, such as Gorrafa U.S. Patent No. 3,914,488 and Clark et al
U.S. Patent No. 4,707,407, the disclosures of which are hereby specifically incorporated herein by reference, and this art also discloses general details of how filaments of such cross-section may be formed. As indicated herein, an essential element of the present invention, however, is selection of a specific composition of polymer that is spun into such a filament cross-section (known per se for other purposes from different compositions) at a textile denier suitable for the specific purposes and advantages disclosed for the present invention.
Polyethylene terephthalate containing polyethylene glycol has already been disclosed in the art, e.g., by Snyder in U.S. Patent No.
2,744,087 and by DeMartino in U.S. Patent No. 4,666,454, the disclosures of which are hereby incorporated herein by reference. Similarly, the disclosures of Griffing et al U.S. Patent No. 3,018,272, Vail U.S. Patent No. 3,816,486, and
Hancock et al. U.S. Patent No. 4,704,329 are hereby incorporated herein by reference to disclose various polymer compositions that may be modified by inclusion of PEO according to the present invention, and various processing techniques for
preparing drawn, annealed and drawn relaxed filaments. A viscosity builder, such as a trifunctional or tetrafunctional monomer, such as tetraethyl silicate, or as used in the Examples, 5 may be advantageously incorporated in the polymer j composition in effective amount to enhance spinning performance. Use of such monomers, as chain-branchers, is taught, e.g., by MacLean et al in U.S. Patents No. 4,092,299, and by Mead et al in 10 U.S. Patent No. 3,335,211. Many such prior art polymer compositions, however, contain delusterant, usually titanium dioxide, in contrast to the present invention.
Clear polymer means that the fiber is not 15 delustered, that is, contains essentially no added delustering pigment, generally less than 0.005 percent by weight of delusterant (typically titanium dioxide pigment) .
The addition of PEO increases dyeability of 20 the fiber, with larger amounts causing better dyeability. If fiber is made without PEO, it can, however, retain advantages of good luster and drapeability.
A molecular weight of 600 for the PEO was 25 used because it was convenient, but may vary from about 200 to about 2000. The molecular weight must be high enough to be effective, but low enough to be applied practically. Heat can be used to effectively use a higher molecular weight PEO. 30 As indicated above, each of the elements of the present invention, namely the selected PET polymer(s) and modifier, the selected viscosity, r the absence of delusterant, the scalloped-oval filament cross-section, and the apparel deniers, 35 have been used separately for various textile and
industrial end-uses but have not, so far as we know, been used in the present combination, nor for this purpose, and the results are surprising.
The invention is further illustrated in the following Examples. The PEO was of molecular weight 600. The relative viscosity of the polyester was measured essentially as described in Hancock et al. U.S. Patent No. 4,704,329, col. 9, lines 6-11, but on a solution obtained by dissolving 0.80 gram fiber in 10.0 milliliters solvent. The DDR (Dye
Rate) was measured as described in Frankfort et al. U.S. Patent No. 4,195,051, col. 12 (and in 4,134,882) in comparison with a filament of 1.5 dpf, scalloped-oval cross-section, of similar polymer except that it contained no PEO. The pilling results were from the Random Tumble Pilling
Test (RTPT) , essentially as described in ASTM D
3512, with ratings at the intervals indicated herein.
EXAMPLES
Example i
1-2. A commercial clear PET polymer with essentially no titanium dioxide, but containing 3.9 weight percent of polyethylene oxide (PEO) and 0.175 weight percent trimethylol propane, to provide a relative viscosity of 20.5 was utilized. It was melt spun at 290 C and 102 pounds per hour through a spinneret having 1653 capillaries. The capillary orifices were of the general configuration of that shown in Figure 2 of U.S. Patent 4,707,407, with the major axis length being 0.039 inches and the minor axis length being 0.019 inches. The filaments were conveniently collected at 1500 yards per minute on individual bobbins using a commercial wind-up device. Twenty five
bobbins were combined as a creel for a test drawing apparatus having the capability for one (1) and two (2) stages of drawing in saturating liquid spray(s) , crimping, and hot air relaxing. The results of these tests are included as Items 1 and 2, respectively, of Table 1.
3. An additional three hundred ninety bobbins were collected under the same conditions and combined as a creel for a commercial drawing machine. They were one-stage drawn, crimped, and relaxed in a hot air dryer. The results of this test are included as Item 3 of Table 1.
4. In like manner a heavier denier was produced at a spinning rate of 50.5 pounds per hour using a spinneret of 360 similar capillaries.
Thirty eight bobbins were combined as a creel for the same test drawing machine and the results are included as Item 4 of Table 1.
TABLE 1
Fiber from the Item 3 was cut to 1 1/2" on a standard cutter, baled and processed on commercial textile machinery to a ring spinning frame. The yarn count was 25/1 cc with a 4.0 twist factor. The yarn was woven into a 2 X 1 twill fabric on a standard loom using 112 ends per inch on the warp and 58 picks per inch in the fill. This fabric was dyed atmospherically with disperse dyes without carrier for one hour. Commercial fabric softener was applied. Without further treatment, the fabric was tested on the Random Tumble Pill Test Mechanism. After 10 and 60 minutes tumbling, respectively, the pill ratings were 4.2 and 2.6 (higher pill ratings indicating better resistance to pilling) . Example 2.
1. A commercial polymer similar to that used in Example 1 was melt spun at 285C and 68.5 pounds per hour through spinnerets having 1054 capillaries, but otherwise essentially similarly to Example 1, except that the major axis length for the capillary orifice was 0.030 inches. The filaments were conveniently collected at 1500 yards per minute from multiple positions using a commercial device. Nine hundred ends were combined as a creel for a commercial drawing machine. They were one-stage drawn, crimped, and relaxed in a hot air dryer. The results of this test are included as Item 1 of Table 2. 2. In like manner a heavier denier was produced at a spinning rate of 63 pounds per hour using spinneret of 450 capillaries. The capillary had the major axis length of 0.039 inches as in Example 1. Nine hundred eighty four ends were combined as a creel for a commercial drawing
machine. They were one-stage drawn, crimped, and relaxed in a hot air dryer. The results are of this test are included as Item 2 of Table 2.
Item No.
Spun Denier/Filament
Draw Ratio 1 Draw Ratio 2
Crimp Roll %
Total Draw Ratio
Relaxer Temp deg C
Denier/Filament Tenacity
Elongation %
Example 3 1. A commercial polymer similar to that used in Example 1, except for having an relative viscosity of 19.8, was melt spun essentially as in Example 2, except at 292C and 96 pounds per hour through spinnerets having 1653 capillaries into filaments that were conveniently collected at 1421 yards per minute . Six hundred thirty ends were combined as a creel for a commercial drawing machine. They were one-stage drawn, crimped, and relaxed in a hot air dryer at 124 C. The results of this test are included as Item 1 of Table 3. 2-3. To evaluate relaxation temperature effect on "pill resistance", material that was spun, drawn, and crimped as Item 1 of Table 3 was not allowed to enter the relaxation dryer. It was taken to a laboratory forced convection, hot-air oven, one sample was exposed to 130 C air for 5
minutes, the other to 160 C air for 5 minutes. These results are reported as Items 2 and 3 of Table 3 respectively.
4. To determine if temperature of the relaxation oven had a significant effect on the "pill resistance" of the fiber after drawing, another item was produced with a relaxer temperature of 154 C, other conditions being the same. The results of this test are included as Item 4 of Table 3.
Filaments from the above four items were randomly selected from the processed but uncut filament bundle. Individual filaments were tested for flex life by being clamped between two bars having a 0.001 inch radius at the point of nip. A dead weight loading of one gram was applied and then the bars were oscillated in a manner calculated to flex the filaments in opposite directions until rupture occurred. This data is reported in the Table 3 as "flex life". A lower flex life indicates that the resistance to pilling is likely to be better.
Data from Item 3 of Table 1 is reported in Table 3 as "Control". Fiber from the Items 1 and 4 were cut to 1
1/2" on a standard cutter, baled and processed on commercial textile machinery to a ring spinning frame. Yarn counts of 22/1 and 28/1, with a 3.75 twist factor were spun. Each Item yarn was woven into a 2 X 1 twill fabric on a standard loom using 112 ends per inch 28/1 cc in the warp and 58 picks per inch of 22/1 cc in the fill. This fabric was dyed atmospherically with disperse dyes without carrier for one hour. Commercial fabric softener was applied. Without further treatment, the fabric
was tested on the Random Tumble Pill Test Mechanism. After 15 and 120 minutes tumbling, the pill ratings were, respectively, for Item 3.1; 4.5 and 4.4, for Item 3.4: 3.8 and 1.6, and more yarns, prepared from item 3 in Example 1, were similarly woven and tested to give RTP ratings, respectively, of 4.5 and 2.6.
TABLE 3
A commercial polymer similar to that used in Example 1 (except for relative viscosity of 19.7), was melt spun at 293 C and 75 pounds per hour through spinnerets having 1054 capillaries, using capillary orifices as in Example 2.1. Four hundred forty eight ends were combined as a creel for a commercial drawing machine. They were one-stage drawn, crimped, and relaxed in a hot air dryer at 142 C. The results of this test are shown in Table 4.
TABLE 4
Spun Denier/Filament 2.77
Draw Ratio 1 2.62
Crimp Roll % 0.96 Total Draw Ratio 2.51
Relaxer Temp C 142
Denier/Filament 1.61
Tenacity 3.4 Elongation % 35.2
Dry Heat Shrinkage % 3.2
This product was not cut but was processed as continuous tow on a tow converter. Example 5
Fiber from Example 1, item 3 was blended 50/50 with combed cotton and ring spun into 28/1 cc. It was knit into a 22 cut Jersey fabric on a commercial machine. The fabric was atmospherically dyed and subjected to the standard Random Tumble Pill test method.
For comparison purposes, a commercial 1.5 denier per filament T-107 W (round, 11.5 RV homopolymer) staple fiber was chosen because it is commercially sold as a "pill resistant" product for knit end-uses. This comparison fiber was likewise blended 50/50 with combed cotton and ring spun to 28/1 cc. This yarn was knit on the same knitting machine into a 22 cut jersey, dyed with carrier and subjected to the standard Random Tumble Pill test method.
RTP test results after the indicated test times for the scalloped-oval and round cross-section yarns are in Table 6 below and clearly show the pilling advantage of the scalloped-oval fiber of the invention despite its
higher RV (20.5 vs 11.5), which normally gives more pilling, so the better pilling performance of the higher RV fiber of the invention was extremely surprising.
Claims
1. Textile fibers of about 0.5 to about 3 denier per filament, and of scalloped-oval cross-section, consisting essentially of clear ethylene terephthalate polymer of relative viscosity (LRV) in the range about 19 to 21, and containing about 1 to about 8% by weight of polyethylene oxide of molecular weight in the range about 200 to about 2000 .
2. Textile fibers of about 0.5 to about 3 denier per filament, and of scalloped-oval cross-section, consisting essentially of clear ethylene terephthalate polymer of relative viscosity (LRV) in the range about 15.5 to 17.5, containing about 1 to about 3 mol % of 5-(alkali metal sulfo) isophthalate groups in the polymer chain and about 1 to about 8% by weight of polyethylene oxide of molecular weight in the range about 200 to about 2000.
3. Fibers according to Claim 1 or 2, characterized in that they have been crimped and then relaxed at a temperature in the range of about
110-175 C.
4. Fibers according to Claim 1 or 2, characterized in that they have been annealed at a temperature in the range of about 160-230 C.
5. Fibers according to Claim 4, characterized in that they have been crimped and then relaxed at a temperature in the range of about 60-100 C.
6. Textile fibers according to Claim 1 or 2 that are of deliberately mixed denier.
7. Fibers according to Claim 1 or 2, that are staple fibers of cut length about 10 to about 100 mm.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US64592091A | 1991-01-25 | 1991-01-25 | |
US645,920 | 1991-01-25 |
Publications (1)
Publication Number | Publication Date |
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WO1992013120A1 true WO1992013120A1 (en) | 1992-08-06 |
Family
ID=24590994
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1992/000231 WO1992013120A1 (en) | 1991-01-25 | 1992-01-23 | Improvements in polyester fibers |
Country Status (3)
Country | Link |
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AU (1) | AU1199992A (en) |
MX (1) | MX9200304A (en) |
WO (1) | WO1992013120A1 (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997002372A1 (en) * | 1995-06-30 | 1997-01-23 | E.I. Du Pont De Nemours And Company | New polyester tow |
WO1997002374A1 (en) * | 1995-06-30 | 1997-01-23 | E.I. Du Pont De Nemours And Company | New polyester tows |
US5968649A (en) * | 1995-06-30 | 1999-10-19 | E. I. Du Pont De Nemours And Company | Drawing of polyester filaments |
WO1999055941A2 (en) * | 1998-04-24 | 1999-11-04 | Wellman, Inc. | Method of producing high quality dark dyeing polyester and resulting yarns and fabrics |
US6013368A (en) * | 1995-06-30 | 2000-01-11 | E. I. Du Pont De Nemours And Company | Comfort by mixing deniers |
WO2000012793A1 (en) * | 1998-08-28 | 2000-03-09 | Wellman, Inc. | Polyester modified with polyethylene glycol and pentaerythritol |
US6037055A (en) * | 1997-02-12 | 2000-03-14 | E. I. Du Pont De Nemours And Company | Low pill copolyester |
US6261686B1 (en) | 1998-09-10 | 2001-07-17 | Heinz-Dieter Schumann | Copolyester fiber |
US6623853B2 (en) | 1998-08-28 | 2003-09-23 | Wellman, Inc. | Polyethylene glycol modified polyester fibers and method for making the same |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3156607A (en) * | 1961-05-31 | 1964-11-10 | Du Pont | Lobed filament |
JPS5988915A (en) * | 1982-11-09 | 1984-05-23 | Toray Ind Inc | Modified polyester fiber and production thereof |
EP0125112A2 (en) * | 1983-05-04 | 1984-11-14 | E.I. Du Pont De Nemours And Company | Improved process for annealing polyester filaments and new products thereof |
US4634625A (en) * | 1984-10-25 | 1987-01-06 | E. I. Du Pont De Nemours And Company | New fabrics, yarns and process |
EP0372994A2 (en) * | 1988-12-09 | 1990-06-13 | Hoechst Celanese Corporation | Enhanced polyester copolymer fiber |
JPH03819A (en) * | 1989-05-30 | 1991-01-07 | Teijin Ltd | Polyester staple fiber |
JPH0319908A (en) * | 1989-06-15 | 1991-01-29 | Toray Ind Inc | Fiber having modified cross-section |
-
1992
- 1992-01-23 WO PCT/US1992/000231 patent/WO1992013120A1/en active Application Filing
- 1992-01-23 AU AU11999/92A patent/AU1199992A/en not_active Abandoned
- 1992-01-24 MX MX9200304A patent/MX9200304A/en unknown
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3156607A (en) * | 1961-05-31 | 1964-11-10 | Du Pont | Lobed filament |
JPS5988915A (en) * | 1982-11-09 | 1984-05-23 | Toray Ind Inc | Modified polyester fiber and production thereof |
EP0125112A2 (en) * | 1983-05-04 | 1984-11-14 | E.I. Du Pont De Nemours And Company | Improved process for annealing polyester filaments and new products thereof |
US4634625A (en) * | 1984-10-25 | 1987-01-06 | E. I. Du Pont De Nemours And Company | New fabrics, yarns and process |
EP0372994A2 (en) * | 1988-12-09 | 1990-06-13 | Hoechst Celanese Corporation | Enhanced polyester copolymer fiber |
JPH03819A (en) * | 1989-05-30 | 1991-01-07 | Teijin Ltd | Polyester staple fiber |
JPH0319908A (en) * | 1989-06-15 | 1991-01-29 | Toray Ind Inc | Fiber having modified cross-section |
Non-Patent Citations (3)
Title |
---|
PATENT ABSTRACTS OF JAPAN vol. 15, no. 104 (C-814)13 March 1991 & JP,A,3 000 819 ( TEIJIN LTD ) 7 January 1991 * |
PATENT ABSTRACTS OF JAPAN vol. 15, no. 137 (C-821)5 April 1991 & JP,A,3 019 908 ( TORAY IND INC ) 29 January 1991 * |
PATENT ABSTRACTS OF JAPAN vol. 8, no. 199 (C-242)12 September 1984 & JP,A,59 088 915 ( TORAY KK ) 23 May 1984 * |
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WO1997002374A1 (en) * | 1995-06-30 | 1997-01-23 | E.I. Du Pont De Nemours And Company | New polyester tows |
US5736243A (en) * | 1995-06-30 | 1998-04-07 | E. I. Du Pont De Nemours And Company | Polyester tows |
US5968649A (en) * | 1995-06-30 | 1999-10-19 | E. I. Du Pont De Nemours And Company | Drawing of polyester filaments |
US6214264B1 (en) * | 1995-06-30 | 2001-04-10 | E. I. Du Pont De Nemours And Company | Drawing of polyester filaments |
US6013368A (en) * | 1995-06-30 | 2000-01-11 | E. I. Du Pont De Nemours And Company | Comfort by mixing deniers |
WO1997002372A1 (en) * | 1995-06-30 | 1997-01-23 | E.I. Du Pont De Nemours And Company | New polyester tow |
US6037055A (en) * | 1997-02-12 | 2000-03-14 | E. I. Du Pont De Nemours And Company | Low pill copolyester |
WO1999055941A3 (en) * | 1998-04-24 | 2000-04-13 | Wellman Inc | Method of producing high quality dark dyeing polyester and resulting yarns and fabrics |
WO1999055941A2 (en) * | 1998-04-24 | 1999-11-04 | Wellman, Inc. | Method of producing high quality dark dyeing polyester and resulting yarns and fabrics |
US6218007B1 (en) | 1998-04-24 | 2001-04-17 | Wellman, Inc. | Method of producing high quality dark dyeing polyester and resulting yarns and fabrics |
WO2000012793A1 (en) * | 1998-08-28 | 2000-03-09 | Wellman, Inc. | Polyester modified with polyethylene glycol and pentaerythritol |
US6294254B1 (en) | 1998-08-28 | 2001-09-25 | Wellman, Inc. | Polyester modified with polyethylene glycol and pentaerythritol |
US6485829B2 (en) | 1998-08-28 | 2002-11-26 | Wellman, Inc. | Polyester modified with polyethylene glycol and pentaerythritol |
US6623853B2 (en) | 1998-08-28 | 2003-09-23 | Wellman, Inc. | Polyethylene glycol modified polyester fibers and method for making the same |
US6261686B1 (en) | 1998-09-10 | 2001-07-17 | Heinz-Dieter Schumann | Copolyester fiber |
US6383433B1 (en) | 1998-09-10 | 2002-05-07 | Zimmer Aktiengesellschaft | Copolyester fibers |
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